JP7214992B2 - Deodorant sealant film and deodorant packaging material - Google Patents

Description

In the present invention, the elutable organic matter originally contained in the packaging material and the odorous components generated from the packaging material during sterilization and sterilization are transferred to the contents in the package, causing the contents to change in taste. A packaging material that prevents offensive odors, has an odor-improving effect on odor components generated from the content itself, and is excellent in resistance to change in odor and taste over a long period of time, and a production using the packaging material The present invention relates to a deodorizing package.

Among packaging materials, a packaging material containing an odor adsorbent that adsorbs odors has been proposed (Patent Document 1). In such packaging materials, an odor adsorbent such as synthetic zeolite or activated carbon is kneaded into the resin material.

However, such packaging materials have the problem that they adsorb not only odors but also moisture in the air, and desorb the odors once adsorbed. not

A packaging material containing an odor adsorbent in which a chemical adsorbent is supported on an inorganic porous material is also known (Patent Document 2), but the main adsorption target adsorbs an odor component having a specific functional group. However, if the resin material is not selected, the amount of organic matter that does not have a functional group cannot be suppressed, and the odor component cannot be sufficiently adsorbed.

Japanese Patent No. 2538487 Japanese Patent Application Laid-Open No. 2014-233408

The present invention solves the above-mentioned problems, is excellent in manufacturing suitability, and uses odorous organic matter originally contained in the sealant film and sterilization and sterilization treatments such as UV irradiation, hot pack, boiling, γ-ray irradiation, and EB irradiation. When the sealant film of the present invention is used to produce a packaging bag filled body, a high degree of adsorption or To provide a sealant film exhibiting a deodorizing effect over a long period of time due to a decomposition action and excellent in long-term odor and taste change resistance to contents, and a packaging material and a packaging body using the sealant film. aim.

As a result of various investigations, the present inventors have found that a sealant film having at least a sealant layer containing a specific deodorant and a heat-sealable thermoplastic resin achieves the above objects.

That is, the present invention is characterized by the following points.
1. A deodorant sealant film comprising at least a sealant layer,
The sealant layer contains a deodorant and a heat-sealable thermoplastic resin,
The deodorant is one or two selected from the group consisting of a hydrophobic zeolite having a SiO ₂ /Al ₂ O ₃ molar ratio of 30/1 to 8000/1, an inorganic porous material supporting a chemical adsorbent, and an inorganic odor decomposing agent. including more than one species,
The inorganic odor decomposition agent is obtained by kneading or carrying a metal oxide or metal salt with an inorganic substance,
The total content of the deodorant in the sealant layer is 0.2% by mass or more and 15% by mass or less,
Deodorant sealant film.
2. The deodorant is melt-kneaded in advance with a thermoplastic resin and a deodorant/thermoplastic resin mass ratio of 0.5/99.5 to 40/60.
as described in 1 above,
Deodorant sealant film.
3. The heat-sealable thermoplastic resin has a melt flow rate of 0.2 g/10 minutes or more and 10.0 g/10 minutes or less.
as described in 1 or 2 above,
Deodorant sealant film.
4. The sealant layer includes a deodorant sealant layer containing the deodorant and a non-deodorant sealant layer not containing the deodorant,
The non-deodorant sealant layer is laminated in contact with one side and/or both sides of the deodorant sealant layer,
4. The deodorant sealant film according to any one of 1 to 3 above.
5. The chemical adsorbent-supporting inorganic porous material contains one or more elements selected from the group consisting of copper, zinc, silver, platinum, iron, and cobalt.
according to any one of 1 to 4 above,
Deodorant sealant film.
6. The inorganic odor decomposition agent contains one or more elements selected from the group consisting of copper, zinc, silver, platinum, iron, and cobalt.
according to any one of 1 to 5 above,
Deodorant sealant film.
7. The deodorant contains two or three selected from the group consisting of the hydrophobic zeolite, the chemical adsorbent-supporting inorganic porous material, and the inorganic odor decomposing agent,
The total content of the deodorant in the sealant layer is 0.2% by mass or more and 10% by mass or less,
according to any one of 1 to 6 above,
Deodorant sealant film.
8. A deodorant laminate comprising a base layer and the deodorant sealant film according to any one of 1 to 7 above.
9. Further comprising an intermediate layer,
The intermediate layer comprises one or more gas barrier layers selected from the group consisting of metal foil, vapor-deposited metal film, and vapor-deposited metal oxide film.
9. The deodorant laminate as described in 8 above.
10. Furthermore, as an intermediate layer, containing aluminum foil,
9. The deodorant laminate as described in 8 above.
11. A deodorant packaging material produced from the deodorant laminate according to any one of 8 to 10 above.
12. 12. A deodorant package made from the deodorant package material described in 11 above.
13. 12. A deodorant package for liquid contents, which is produced from the deodorant package material according to 11 above.
14. 12. A deodorant package for alcoholic beverages, which is produced from the deodorant package material according to 11 above.

Since the deodorant sealant film of the present invention has a sealant layer containing a specific deodorant and a heat-sealable thermoplastic resin, it efficiently adsorbs or decomposes odors to deodorize and is excellent. It is possible to exhibit a heat-sealing property.

Odors include odorous organic substances originally contained in the sealant film, UV irradiation, γ-ray irradiation, EB irradiation, decomposition of the resin that makes up the sealant film during sterilization and sterilization such as hot packs and boiling. and the like, and the odor caused by the odor and taste components generated from the contents themselves in the case of producing a packaging bag filled body using the deodorant sealant film of the present invention. It is possible to suppress the odor from transferring or remaining in the contents, and suppress the change in the odor of the contents.

In addition, once adsorbed odors are difficult to desorb, odors can be efficiently adsorbed and odors can be decomposed.

Therefore, the deodorant sealant film of the present invention is suitable for use as a packaging material for foods, pharmaceuticals, and medical products that are subjected to sterilization and sterilization treatments.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic cross-sectional view showing one example of the layer structure of the deodorant sealant film of the present invention. FIG. 2 is a schematic cross-sectional view showing an example of the layer structure of the deodorant laminate of the present invention. FIG. 4 is a schematic cross-sectional view showing another example of the layer structure of the deodorant laminate of the present invention. FIG. 4 is a diagram showing the adsorption mechanism of the chemical adsorbent-supporting inorganic porous material for odorous substances.

The deodorant sealant film of the present invention, and the deodorant packaging material and deodorant package produced using the deodorant sealant film will be described in more detail below. The present invention will be described by showing a specific example, but the present invention is not limited to this.

<Layer structure of deodorant sealant film>
The deodorant sealant film of the present invention, as shown in FIG. 1, includes at least a sealant layer containing a deodorant and a heat-sealable thermoplastic resin. Furthermore, if necessary, as shown in FIGS. 2 and 3, other layers such as a substrate layer, an intermediate layer, and an adhesive layer can be included.

<Base material layer>
The base material layer in the present invention can contain a thermoplastic resin or the like, but is not limited to these. Furthermore, the substrate layer can also include one layer or two or more layers of each of the layers including the above.

In addition, an adhesive layer may be provided between each layer constituting the base material layer in order to improve adhesion, or a desired surface treatment layer may be provided in advance on the surface of each layer as necessary. can be done.

For example, pretreatment such as corona discharge treatment, ozone treatment, low-temperature plasma treatment using oxygen gas or nitrogen gas, glow discharge treatment, oxidation treatment using chemicals, etc. is optionally applied to the corona treatment layer and ozone treatment. Layers, plasma-treated layers, oxidation-treated layers, etc. can be formed and provided.

Alternatively, various coating agent layers such as a primer coating agent layer, an undercoat agent layer, an anchor coating agent layer, an adhesive layer, and a vapor deposition anchor coating agent layer can be arbitrarily formed on the surface to serve as the surface treatment layer. .

The various coating agent layers include, for example, polyester-based resins, polyamide-based resins, polyurethane-based resins, epoxy-based resins, phenol-based resins, (meth)acrylic-based resins, polyvinyl acetate-based resins, and polyolefins such as polyethylene and polypropylene. A resin composition containing a base resin, a copolymer thereof, a modified resin, a cellulose resin, or the like as a main component of a vehicle can be used.

The thickness of the substrate layer depends on the material, but in the case of a resin film, it is preferably 5 to 30 μm, more preferably 10 to 30 μm.

A film for the substrate layer that satisfies the above requirements is also commercially available, and examples of films suitably used in the present invention include biaxially oriented PET film E5100 (thickness: 12 μm) manufactured by Toyobo Co., Ltd. , single-sided corona treatment), biaxially oriented PET film E5200 (thickness 12 μm, double-sided corona treatment), and biaxially oriented nylon film ONBC manufactured by Unitika Ltd. (thickness 15 μm, double-sided corona treatment).

(Thermoplastic resin of base material layer)
The thermoplastic resin used for the base material layer is used after being molded into a film, and preferably has excellent chemical or physical strength.

Examples of such resins include polyolefin-based resins such as polyethylene-based resins or polypropylene-based resins, cyclic polyolefin-based resins, polystyrene-based resins, acrylonitrile-styrene copolymers (AS resins), and acrylonitrile-butadiene-styrene copolymers. (ABS resin), poly(meth)acrylic resins, polycarbonate resins, polyester resins such as polyethylene terephthalate and polyethylene naphthalate, polyamide resins such as various nylons, polyurethane resins, acetal resins, cellulose resins, etc. and various resins.

In the present invention, among the above resins, it is preferable to use films or sheets of polyester resins, polyolefin resins, or polyamide resins.

In the present invention, the thermoplastic resin used for the substrate layer can be formed into a film by various known film-forming methods.

For example, using one type of resin, a method of forming a film using a film forming method such as an extrusion method, a cast molding method, a T-die method, a cutting method, or an inflation method, or a method of forming a film using two or more types of resin. A method of forming a film by multilayer co-extrusion, a method of forming a film by mixing two or more kinds of resins before forming the film, and the like. Furthermore, it is possible to form a film uniaxially or biaxially stretched by using a tenter system, a tubular system, or the like.

When the thermoplastic resin is formed into a film, for example, film processability, heat resistance, weather resistance, mechanical properties, dimensional stability, oxidation resistance, slipperiness, releasability, flame retardancy, For the purpose of improving and modifying antifungal properties, electrical properties, strength, etc., various plastic compounding agents and additives can be added. It can be optionally added depending on the purpose.

In the above, as general additives, for example, lubricants, cross-linking agents, antioxidants, ultraviolet absorbers, light stabilizers, fillers, reinforcing agents, antistatic agents, pigments, modifying resins, etc. are used. be able to.

<Adhesive layer>
In the present invention, as shown in FIG. 2, each layer can be adhered by an adhesive layer.

The adhesive layer may be a layer made of an adhesive for dry lamination, an adhesive for EC (extrusion coating), an adhesive for non-solvent lamination, an arbitrary anchor coating agent, or the like.

The adhesive may be of a thermosetting type, an ultraviolet curable type, an electron beam curable type, or the like, and may be in any form such as an aqueous type, a solution type, an emulsion type, or a dispersion type. It may be in any form such as shape, powder, solid, etc. Further, the adhesion mechanism may be in any form such as chemical reaction type, solvent volatilization type, heat fusion type, heat pressure type, or the like.

Components for forming such an adhesive layer include polyvinyl acetate-based adhesives such as polyvinyl acetate and vinyl acetate-ethylene copolymers, and copolymers of polyacrylic acid and polystyrene, polyester, polyvinyl acetate, and the like. Polyacrylic acid-based adhesives, cyanoacrylate-based adhesives, ethylene copolymer-based adhesives composed of copolymers of ethylene and monomers such as vinyl acetate, ethyl acrylate, acrylic acid, and methacrylic acid, cellulose-based adhesives, Polyurethane-based adhesives, polyester-based adhesives, polyamide-based adhesives, polyimide-based adhesives, polyolefin-based adhesives such as LDPE, amino resin-based adhesives made of urea resin or melamine resin, phenolic resin-based adhesives, epoxy-based adhesives Adhesives, reactive (meth)acrylic adhesives, elastomer adhesives such as chloroprene rubber, nitrile rubber, styrene-butadiene rubber, silicone adhesives, alkali metal silicates, inorganic adhesives such as low-melting glass etc.

When dry lamination coating, for example, the resin composition for the adhesive layer is applied on one layer and dried, and after laminating the other layer to be adhered, it is heated at 30 to 120 ° C. for several hours to several hours. Aging for days allows the adhesive to cure and laminate.

When using an EC adhesive, the extrusion coating adhesive is heated and melted, expanded and stretched in the required width direction with a T-die, and extruded in a curtain shape, and the melted material is allowed to flow down onto the layer to be bonded. Then, by sandwiching between the rubber roll and the cooled metal roll, the formation of the adhesive layer, the adhesion to the layer to be adhered, and the lamination are performed at the same time.

Since the deodorant adhesive layer is formed by the extrusion method, it is easy to form the deodorant adhesive layer without a solvent, and solvent odor can be prevented.

A known extrusion coating adhesive can be used as the EC adhesive.

For example, thermoplastic resins such as general-purpose polyethylene, polypropylene, methylpentene polymer, acid-modified polyolefin resin, and mixtures thereof are suitable, but the resin is not limited to these resins.

When using an adhesive for non-solvent lamination, a known adhesive for non-solvent lamination is applied onto a layer without dispersing or dissolving in a solvent, the adhesive itself is dried, and the other layer to be adhered is laminated. After lamination, the adhesive is cured and laminated by aging at 30 to 120° C. for several hours to several days.

Examples of anchor coating agents that can be used include organic titanium-based, isocyanate-based, polyethyleneimine-based, acid-modified polyethylene-based, and polybutadiene-based anchor coating agents.

Examples of coating means include roll coating, gravure roll coating, and kiss coating, and the coating amount is preferably about 0.1 to 10 g/m ² (dry state). Good adhesiveness can be obtained by setting the coating amount of the adhesive within the above range.

<Deodorant body>
In the present invention, the deodorant is a compound that exerts a deodorant action, and includes hydrophobic zeolite having a SiO ₂ /Al ₂ O ₃ molar ratio of 30/1 to 8000/1, chemical adsorbent-carrying inorganic porous material, inorganic It contains one or more selected from the group of odor decomposing agents.

[Hydrophobic zeolite]
The hydrophobic zeolite used in the present invention preferably has a SiO ₂ /Al ₂ O ₃ molar ratio of 30/1 to 8000/1. Generally, the higher the SiO ₂ /Al ₂ O ₃ molar ratio, the higher the hydrophobicity of the zeolite.

Hydrophobic zeolite maintains its effect of adsorbing malodorous components even when the deodorant laminate of the present invention is exposed to temperatures of 230° C. or higher.

The hydrophobic zeolite may have any external shape such as spherical, rod-like, or elliptical, and may have any shape such as powder, block, or granular. From the viewpoint of dispersibility, kneading properties, film-forming properties, etc., a powder form is preferred.

In the present invention, the average particle size of the hydrophobic zeolite can be appropriately selected depending on the application, but the average particle size is preferably 0.01 μm to 10 μm. Here, the average particle size is a value measured by a dynamic light scattering method.

If the average particle size is less than 0.01 µm, the hydrophobic zeolite tends to aggregate and the dispersibility tends to decrease. In addition, when the average particle size is larger than 10 μm, the layer containing the hydrophobic zeolite tends to have poor film-forming properties, so it tends to be difficult to add a large amount of the hydrophobic zeolite, and the surface area also decreases. Therefore, there is a possibility that a sufficient deodorizing effect cannot be obtained.

Hydrophobic zeolite is hydrophobic, so it is difficult to adsorb highly polar water molecules, and on the contrary, it has an affinity with odor molecules, hydrophobic gases, and lipophilic gases (including solvent-based gases), which have low polarity. is high and easily adsorbs them. Furthermore, the zeolite surface exhibits basicity due to the effects of alkali metals such as Ca, Na, K, and alkaline earth metals present on the zeolite surface, and readily adsorbs acid gases through a neutralization reaction.
[Chemical adsorbent-supporting inorganic porous material]
In the present invention, the chemical adsorbent-supporting inorganic porous material is an inorganic porous material that supports a chemical adsorbent, and can be used for elutable organic substances, UV irradiation, γ-ray irradiation, EB irradiation, hot packs, boiling It has the function of adsorbing odorous substances generated from the package during sterilization and sterilization.

As the supporting method, a known or commonly used supporting method can be applied. For example, an inorganic porous material can be impregnated with a solution containing a chemical adsorbent described below and dried to support the inorganic porous material. can.

In the present invention, by using the chemical adsorbent-supporting inorganic porous material, the adsorption capacity per unit mass of the chemical adsorbent can be greatly increased. content can be reduced. In addition, physical adsorption properties to the pores of the inorganic porous material can also be expected.

As a result, high adhesive strength and seal strength can be obtained, and excellent adhesiveness, coatability, and film-forming properties required for adhesive layers can be maintained, and excellent heat-sealing properties and film-forming properties required for sealant layers. can be held.

The chemical adsorbent-supporting inorganic porous material preferably contains one or more elements selected from the group consisting of copper, zinc, silver, platinum, iron and cobalt.

In addition, the chemical adsorbent-supporting inorganic porous material may have any outer shape such as spherical, rod-like, or elliptical, and may have any shape such as powdery, lumpy, or granular. From the viewpoint of uniform dispersibility, kneading properties, etc., a powder form is preferred.

The chemical adsorbent-supporting inorganic porous material can be appropriately selected to have any average particle size depending on the application. .1 μm to 8 μm is more preferred, and 1 μm to 7 μm is even more preferred. Here, the average particle size is a value measured by a dynamic light scattering method.

If the average particle size is less than 0.01 μm, the chemical adsorbent-carrying inorganic porous material tends to aggregate, resulting in a decrease in dispersibility.

On the other hand, when the average particle size is larger than 10 μm, the above-mentioned film-forming property is inferior, so it tends to be difficult to contain a large amount of the chemical adsorbent-supporting inorganic porous material, and there is a possibility that a sufficient adsorption effect cannot be obtained. .

Specific examples of commercially available products include NS-241 and NS-231 (amino group-containing compound-supporting inorganic porous material) manufactured by Toagosei Co., Ltd., and Dashlite M (amino group-containing compound) manufactured by Sinanen Zeomic Co., Ltd. supported inorganic porous material), Dashlite CZU (chemical adsorbent-supported copper-zinc-containing inorganic porous material), and the like can be used as a suitable deodorant in the present invention.

(Inorganic porous material)
In the present invention, any inorganic compound having a large number of pores on its surface can be used as the inorganic porous material. Salts, alumina, aluminum hydroxide, magnesium hydroxide, and mixtures thereof.

In particular, it is preferable to use aluminum hydroxide, zeolite, and silicate from the viewpoint of having a porous state with a pore size effective for the molecular size and cluster size of the substance to be adsorbed and from the viewpoint of safety.

In addition, these may have any external shape such as spherical, rod-like, or elliptical, and may be in any form such as powdery, lumpy, or granular. After making the inorganic porous material, powder form is preferable from the viewpoint of the film-forming properties, uniform dispersion, kneading properties, and the like.

The inorganic porous material can be appropriately selected to have any average particle size depending on the application. 01 μm to 10 μm is preferable, 0.1 μm to 8 μm is more preferable, and 1 μm to 7 μm is even more preferable.

(chemisorbent)
In the present invention, the chemical adsorbent has a reactive functional group that causes a chemical reaction and bonds with elutable organic substances and odorous substances generated by decomposition of resin during sterilization and sterilization, and the above inorganic It is a compound that can be supported on a porous body.

More specifically, functional groups having reactivity to bind to various aldehydes, ketones, carboxylic acids, etc. generated during sterilization and sterilization such as UV irradiation, γ-ray irradiation, EB irradiation, hot pack, boiling, etc. It is a compound having

Examples of such compounds include compounds containing amino groups, polyamines such as alkylamines and tetramethylenediamine, ethanolamine, piperidine, compounds having basic functional groups such as hydroxyl groups, such as sodium hydroxide, Potassium, magnesium hydroxide, hydroxides such as iron hydroxide, sodium carbonate, sodium hydrogen carbonate, carbonates such as calcium carbonate, hydrogen carbonates, amide group-containing compounds such as 2-acrylamido-2-methylpropanesulfonic acid, etc. is mentioned.

In the present invention, chemical adsorbents exhibiting particularly excellent adsorption effects include compounds having amino groups, such as polyamines such as ethylenediamine, diethylenetriamine, triethylenetriamine, tetraethylenepentamine, piperazine, and metaphenylenediamine. but not limited to these.

The adsorption mechanism of chemical adsorbents for adsorption target substances such as eluted organic matter and odorous substances will be described in more detail using specific examples in FIGS.

For example, when the substance to be adsorbed is an acid-type odorant, as shown in FIG. An inorganic porous material can be used. As a result, the carboxyl group and the hydroxyl group undergo a chemical reaction and bond together, thereby adsorbing the substance to be adsorbed.

Further, when the substance to be adsorbed is an aldehyde, as shown in FIG. You can use your body. As a result, the aldehyde group and the amino group undergo a chemical reaction and bond, thereby adsorbing the substance to be adsorbed.

At this time, since it is chemical adsorption, the substance to be adsorbed once adsorbed does not desorb, and the odor can be efficiently adsorbed.

Furthermore, unlike physical adsorbents in which odor and water vapor are adsorbed at the same adsorption site, the chemical adsorbent in the present invention has an adsorption target substance that binds to a specific functional group of the chemical adsorbent. It is insensitive to various substances that lower the , such as water vapor.

[Inorganic odor decomposing agent]
The inorganic odor decomposing agent in the present invention is obtained by kneading or supporting a metal oxide or metal salt with an inorganic substance, and preferably contains at least copper (II) oxide, silicon oxide, and alkali metal oxide. It is formed from an inorganic odor decomposer composition comprising

The inorganic odor decomposing agent in the present invention is capable of eliminating sulfur-based malodorous substances by ionizing the metal components held in the inorganic odor-decomposing agent and exhibiting a catalytic action that promotes the decomposition reaction of sulfur-based malodorous substances. It has an odor effect. Among sulfur-based malodorous substances, it has a particularly high deodorizing effect on hydrophilic compounds such as hydrogen sulfide.

The inorganic odor decomposer composition preferably further contains one or more elements selected from the group consisting of copper, zinc, silver, platinum, gold, iron, and cobalt as the ionizable component, particularly , copper, zinc, and silver. Each element is preferably contained in the inorganic odor decomposing agent composition as a metal, metal oxide, metal ion, metal complex, or the like.

Examples of metal oxides include CuO, Cu2O, ZnO, _Ag2O , _PtO2 , _Au2O3 , FeO, _{Fe3O4 , Fe2O3 , CoO , Co2O3 , Co3O 4} , etc.

In addition, the inorganic odor decomposing agent composition further contains boron oxide, and may further contain alkaline earth metal oxide, aluminum oxide, etc., as necessary, in order to adjust chemical performance and physical performance. .

The powdery inorganic odor decomposing agent is mixed with each raw material to prepare an inorganic odor decomposing agent composition, melted and homogenized in the same manner as in the production of general-purpose glass such as bottle glass, cooled and then pulverized. can be obtained by

Since the inorganic odor decomposing agent acts as a catalyst to promote the decomposition reaction of sulfur-based malodorous substances, it is possible to increase the deodorizing capacity compared to the conventional technology that depends on the surface area using chemical adsorption and physical adsorption. The odor effect can be exhibited stably over a long period of time.

The content of copper (II) oxide (CuO) in the inorganic odor decomposing agent composition is preferably 0.01 to 23 mol%, more preferably 1 to 13 mol%, and even more preferably 4 to 13 mol%. If the amount is less than the above range, the deodorizing effect tends to be insufficient, and if the amount is more than the above range, metallic copper tends to precipitate, which is not preferable.

Silicon oxide (SiO ₂ ) is the main component forming the structural skeleton of the inorganic odor decomposing agent. The content of silicon oxide in the inorganic odor decomposing agent composition is preferably 46 to 70 mol %, more preferably 51 to 70 mol %.

If the amount is less than the above range, the chemical durability and water resistance of the inorganic odor decomposing agent tend to be insufficient, and the deodorizing effect due to the catalytic action of copper (II) oxide tends to decrease. If the amount is more than the above range, the melting point and melt viscosity of the inorganic odor decomposing agent are too high, and the inorganic odor decomposing agent tends to become non-uniform.

The alkali metal oxide is one or more selected from the group consisting of Li ₂ O, Na ₂ O and K ₂ O, and is a component that lowers the melting point and melt viscosity of the inorganic odor decomposing agent.

The content of the alkali metal oxide in the inorganic odor decomposing agent composition is preferably 10 to 33 mol%, more preferably 12 to 24 mol%, even more preferably 12 to 20 mol%.

If the amount is less than the above range, the effect of lowering the melting point and melt viscosity of the inorganic odor decomposing agent tends to be insufficient. If the amount is more than the above range, the chemical durability and water resistance of the inorganic odor decomposing agent tend to be insufficient, and the deodorant effect tends to decrease.

The alkaline earth metal oxide is one or two or more selected from the group consisting of MgO, CaO, SrO and BaO, and is a component contained in the inorganic odor decomposing agent composition as necessary. It has the effect of improving the chemical durability of the agent.

When the inorganic odor decomposer composition contains the alkaline earth metal oxide, the content of the alkaline earth metal oxide in the inorganic odor decomposer composition is preferably 2 to 10 mol%, more preferably 2 to 7 mol%. is more preferred.

When the amount is less than the above range, it is likely to be difficult to sufficiently exhibit the effect of containing the alkaline earth metal oxide. easy to become

Boron oxide (B ₂ O ₃ ) has the effect of lowering the melting point and melt viscosity of the inorganic odor decomposing agent and chemically stabilizing the inorganic odor decomposing agent.

When boron oxide is contained in the inorganic odor decomposing agent composition, the content of boron oxide in the inorganic odor decomposing agent composition is preferably 5 to 20 mol %, more preferably 8 to 17 mol %.

If the amount is less than the above range, it is likely to be difficult to sufficiently exhibit the effect of containing boron oxide. Furthermore, the deodorizing effect tends to be lowered.

Boron oxide, like alkali metal oxide, has the effect of lowering the melting point and melt viscosity of the inorganic odor decomposing agent. The total content of boron oxide and alkali metal oxide in the decomposer composition is preferably 15 to 50 mol %, more preferably 21 to 39 mol %.

If the amount is less than the above range, the effect of lowering the melting point and melt viscosity of the inorganic odor decomposing agent tends to be insufficient. If the amount is more than the above range, the inorganic odor decomposing agent tends to be uneven, the water resistance of the inorganic odor decomposing agent tends to be insufficient, and the deodorizing effect tends to be lowered.

Aluminum oxide (Al ₂ O ₃ ) is a component that is optionally contained in the inorganic odor decomposing agent composition, and has the effect of increasing the homogeneity of the inorganic odor decomposing agent and improving its chemical durability.

When aluminum oxide is contained in the inorganic odor decomposing agent composition, the content of aluminum oxide in the inorganic odor decomposing agent composition is preferably 0.1 to 6 mol%, more preferably 0.1 to 5.5 mol%. is more preferred, and 0.1 to 4.5 mol % is even more preferred.

If it is less than the above range, it is likely to be difficult to sufficiently exhibit the effect of containing aluminum oxide. .

_In addition to the above components, trace components such as _TiO2 , _ZrO2 , _{Nb2O5 , P2O5} , _Cs2O , _Rb2O , _TeO2 , _BeO , _GeO2 , _Bi2O3 , _{La2O 3} , Y ₂ O ₃ , WO ₃ , MoO ₃ , Sb ₂ O ₃ , SnO ₂ and the like.

The particle size distribution of the inorganic odor decomposing agent is preferably a powder having a weight average particle size of 1 μm or more and 30 μm or less and a D ₉₆ of 40 μm or less. Here, the average particle size is a value measured by performing particle size distribution measurement by a dynamic light scattering method, and D96 means a particle size corresponding to an integrated value of ₉₆ % by mass when cumulatively distributed.

If the average particle size is less than 1 μm, the inorganic odor decomposing agent tends to aggregate, and the dispersibility in the sealant layer tends to decrease. In addition, when the average particle size is larger than 30 μm, the film forming property of the sealant layer tends to be inferior, so it tends to be difficult to add a large amount of the inorganic odor decomposing agent. It may be difficult to obtain an odor effect.

If D ₉₆ exceeds 40 μm, uniform dispersion in the heat-sealing resin tends to become difficult, and there is a possibility that the film formability may deteriorate.

<Sealant layer>
The sealant layer in the present invention contains a heat-sealable thermoplastic resin and a deodorant.

Since the sealant layer contains a heat-sealing thermal facial resin, the deodorizing sealant film of the present invention can exhibit excellent heat-sealing properties. It can have an odor effect.

The deodorant in the deodorant adhesive layer can be used as the deodorant contained in the sealant layer. Also, deodorants having different compositions may be used.

The sealant layer may be only a deodorant sealant layer containing a deodorant as shown in FIG. 1, or a deodorant sealant layer and a non-deodorant sealant layer containing no deodorant as shown in FIG. may be a multilayer structure.

Non-deodorizing sealant layer. It is preferably laminated on one side and/or both sides of the deodorant sealant layer so as to be in contact therewith, since the seal strength and interlayer adhesive strength can be improved.

When the package is produced, the innermost layer in contact with the contents of the package may be a deodorant sealant layer or a non-deodorant sealant layer. When the non-deodorant sealant layer is the innermost layer, the seal strength of the package can be improved, and when the deodorant sealant layer is the innermost layer, the interlayer adhesive strength within the package can be improved.

In the deodorant sealant layer, the deodorant is selected from the group consisting of hydrophobic zeolite having a SiO ₂ /Al ₂ O ₃ molar ratio of 30/1 to 8000/1, inorganic porous material supporting a chemical adsorbent, and an inorganic odor decomposing agent. The total content of the deodorant in the sealant layer including the deodorant sealant layer and the non-deodorant sealant layer is 0.2% by mass or more and 15% by mass. The following are preferred.

If the content of the deodorant is less than the above range, it will be difficult to exhibit a sufficient deodorizing effect, and if it is more than the above range, it will be difficult to exhibit good film-forming properties and heat-sealing properties.

When two or three selected from the above group are used as the deodorant, the deodorant efficiency is improved, so that the content of the deodorant in the sealant layer containing the deodorant sealant layer is 0. A sufficient deodorizing effect can be obtained even when the content is 2% by mass or more and 10% by mass or less.

[Heat-sealable thermoplastic resin]
Specific examples of heat-sealable thermoplastic resins include low density polyethylene (LDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE), linear low density polyethylene (LLDPE), ethylene-acetic acid. Low elution of vinyl copolymers, ethylene-ethyl acrylate copolymers, ethylene-acrylic acid copolymers, ethylene-methacrylic acid copolymers, ethylene-methyl methacrylic acid copolymers, ethylene-propylene copolymers, etc. and mixtures of these resins, but are not limited to these resins.

Among the above, polyethylene is preferable in that it is resistant to sterilization and sterilization treatments such as UV and has properties that are difficult to decompose, and among polyethylenes, LLDPE is more preferable.

Additionally, the sealant layer may contain lubricants, antioxidants, antiblock agents, and other additives.

The heat-sealable thermoplastic resin contained in the sealant layer preferably has excellent resistance to pinholes caused by bending when formed into a film by itself.

Packages may develop pinholes as a result of repeated local bending due to vibration during the packaging process or transportation. is important.

The pinhole resistance of the heat-sealable thermoplastic resin contained in the sealant layer is, for example, a film of a 50 μm thick film made of a single heat-sealable thermoplastic resin after 5000 times of gelboflex at 23 ° C. The number of occurrences is preferably 0, or 1 or more and 160 or less.

When the number of pinholes generated in the film is within the above range, it is possible to produce a package that can withstand practical use in applications where pinhole resistance is required.

[Non-deodorant sealant layer]
The non-deodorant sealant layer in the sealant layer in the present invention is a sealant layer containing a heat-sealable thermoplastic resin but not containing a deodorant.

[Deodorant sealant layer]
The deodorant sealant layer is a sealant layer containing a deodorant and a heat-sealable thermoplastic resin.

The deodorizing sealant layer may have a multi-layer structure consisting of layers having the same or different types of heat-sealable thermoplastic resin as the main component and types and content of deodorants.

Furthermore, although not shown, the deodorant sealant layer may consist of three or more layers that are the same or different in the type of heat-sealable thermoplastic resin as the main component and the type and content of the deodorant.

In the deodorant sealant layer, the deodorant may be uniformly dispersed in the layer, or may be dispersed with a concentration gradient.

For example, it may be dispersed with an increasing concentration gradient from the inner surface toward the outer surface when the package is formed, and this configuration improves the heat-sealability. Conversely, it may be dispersed with a decreasing concentration gradient from the inner surface toward the outer surface when the package is formed, and this configuration improves the interlaminar bond strength.

Furthermore, the deodorant sealant layer may be dispersed with a decreasing concentration gradient from the center in the thickness direction toward both surfaces, and this configuration improves the heat-sealing property and interlayer adhesive strength.

Film formation is possible with a deodorant sealant layer thickness of 5 μm or more, but a thickness of 10 μm to 200 μm is preferable in order to obtain good film-forming properties, heat-sealing properties, interlayer adhesive strength, and deodorizing properties.

[Formation of deodorant sealant layer or non-deodorant sealant layer]
(Method of dispersing deodorant)
As a method for kneading the deodorant and the heat-sealable thermoplastic resin, a known or commonly used kneading method can be applied.

The deodorant can be directly mixed with the heat-sealable thermoplastic resin and kneaded, or the deodorant can be mixed with the thermoplastic resin at a high concentration and then melt kneaded (melt blended) to form a masterbatch. is prepared, and this is mixed with a heat-sealable thermoplastic resin at a ratio according to the target content rate, and melt-kneaded.

The content of the hydrophobic zeolite in the masterbatch is preferably 0.5% by mass or more and 40% by mass or less, more preferably 1% by mass or more and 20% by mass or less.
The content of the chemical adsorbent-supporting inorganic porous material in the masterbatch is preferably 0.5% by mass or more and 40% by mass or less, more preferably 1% by mass or more and 20% by mass or less.
The content of the inorganic odor decomposing agent in the masterbatch is preferably 0.5% by mass or more and 40% by mass or less, more preferably 1% by mass or more and 20% by mass or less.

In the case of the masterbatch method, even a combination of a deodorant and a heat-sealable thermoplastic resin, which tend to aggregate easily, can be dispersed efficiently and homogeneously.

At this time, the thermoplastic resin in the masterbatch may be the same as or different from the heat-sealable thermoplastic resin in the deodorant sealant layer. It is possible to combine types of plastic resins.

For example, if the deodorant and the heat-sealing thermoplastic resin are melt-mixed in advance, when mixed or melt-kneaded with the heat-sealing thermoplastic resin again, a homogeneous, good film-forming property and heat-sealing property can be obtained. , interlayer adhesion strength and deodorant properties can be obtained efficiently.

Examples of the thermoplastic resin used in the masterbatch include general-purpose polyethylene, polypropylene, methylpentene polymer, polyolefin resins such as acid-modified polyolefin resins, and mixtures of these resins, but are not limited to these resins.

The thermoplastic resin preferably has a heat-sealing property equivalent to that of the heat-sealable thermoplastic resin in the present invention, but is used within a range that does not have a large adverse effect on the heat-sealing property and film-forming property of the entire sealant layer. be able to.

(Method of forming and laminating sealant layer)
In the present invention, the method of film formation and lamination of each layer in the sealant layer is not particularly limited, and known or commonly used film formation methods and lamination methods can be applied.

A deodorant sealant layer and a non-deodorant sealant layer, optionally via an adhesive layer, are laminated on another layer by an extrusion coating method, or, for example, a plurality of deodorant sealant layers and non-deodorant sealant layers. and can also be formed by co-extrusion using an inflation method or a casting method.

When laminating by the extrusion coating method, first, the resin composition forming the deodorant sealant layer and the resin composition forming the non-deodorant sealant layer are heated and melted, and the width direction required by the T-die. It is expanded and stretched to a curtain shape, the molten resin is allowed to flow down onto the surface to be laminated, and is sandwiched between a rubber roll and a cooled metal roll to form a deodorant sealant layer or a non-deodorant sealant layer and to form a coating. Adhesion to the lamination surface and lamination are performed at the same time.

The melt flow rate (MFR) of the heat-sealable thermoplastic resin contained in the deodorant sealant layer and the non-deodorant sealant layer when laminated by the extrusion coating method is 0.2 to 50 g / 10 minutes. It is preferably 0.5 to 30 g/10 minutes, more preferably 0.5 to 30 g/10 minutes. In addition, in this specification, MFR is the value measured by the method based on JISK7210.
If the MFR is less than 0.2 g/min or more than 50 g/min, it is difficult to be effective in terms of processing suitability.

When using the inflation method, the melt flow rate (MFR) of the heat-sealable thermoplastic resin contained in the deodorant sealant layer and the non-deodorant sealant layer is preferably 0.2 to 10 g/10 minutes, More preferably, it is 0.2 to 9.5 g/10 minutes.

When the MFR is less than 0.2 g/10 minutes or more than 10 g/10 minutes, there is a tendency for poor processing suitability.

Alternatively, a deodorant sealant layer and a non-deodorant sealant layer formed in advance may be laminated via an adhesive layer by an adhesive extrusion coating method, dry lamination method, non-solvent lamination method, or the like. .

<Middle layer>
As shown in FIG. 3, the deodorant laminate of the present invention can contain an intermediate layer and can be given various functions as necessary.

For example, the barrier layer may include a thermoplastic resin film on which a metal foil, a metal vapor deposition film layer or a metal oxide vapor deposition film layer is formed, and a barrier coat resin layer on the metal vapor deposition film layer.

Specific examples of the barrier layer include aluminum foil, vapor-deposited aluminum film, vapor-deposited aluminum oxide film, vapor-deposited silicon oxide film, and the like.

By including the barrier layer as described above, the gas barrier property of the laminate can be improved, the effect of preventing the oxidation of the contents and the dissipation of the flavor components can be enhanced, and the effect of maintaining the flavor of the contents can be enhanced. can.

In particular, in luxury goods such as liquid drinks and alcoholic beverages, it is important to maintain the flavor, and it is very effective.

Furthermore, the film for the intermediate layer that satisfies the above requirements is also commercially available, and a film preferably used in the present invention is, for example, a PET film in which alumina is vapor-deposited on one side by the PVD method. , alumina deposition IB-PET-PIR (thickness 12 μm) manufactured by Dai Nippon Printing Co., Ltd., and silica deposition IB-ON-UB (thickness 15 μm).

<Deodorant laminate>
The deodorant laminate of the present invention is produced from the deodorant sealant film of the present invention, and if necessary, known substrate layers, intermediate layers, printed layers, and other laminates are laminated by known methods. It can be used by laminating.

<Deodorizing packaging material>
The deodorant packaging material of the present invention is produced from the deodorant sealant film or deodorant laminate of the present invention.

<Deodorizing package>
The deodorizing package of the present invention is, for example, made by making a bag from the deodorant packaging material of the present invention, and the packaging material is folded or two sheets are folded so that the surfaces having good heat-sealing property face each other. Overlapping the peripheral edge, for example, side seal type, two side seal type, three side seal type, four side seal type, envelope pasted seal type, palm pasted seal type (pillow seal type), pleated seal type, flat bottom seal type , a square bottom seal type, a gusset type, or the like.

As the heat sealing method, known methods such as bar sealing, rotary roll sealing, belt sealing, impulse sealing, high frequency sealing, and ultrasonic sealing can be applied.

The deodorant package of the present invention can be used as a deodorant package for contents to be filled with contents.

<Contents>
In the present invention, the contents mainly refer to foodstuffs in general.

<Raw materials>
The details of the raw materials used in the examples are as follows.
[Base material layer]
- PET film 1: PET film manufactured by Toyobo Co., Ltd., Espet T4102. 12 μm thick.
[Middle layer]
- Aluminum foil 1: thickness 7 μm.
[Hydrophobic zeolite]
- Mizuka Sieves EX-122: manufactured by Mizusawa Chemical Industry Co., Ltd. SiO ₂ /AL ₂ O ₃ molar ratio=32/1, average particle size=2.5-5.5 μm.
・Silton MT400: manufactured by Mizusawa Chemical Industry Co., Ltd. SiO ₂ /AL ₂ O ₃ molar ratio = 400/1, average particle size = 5 to 7 µm.
・Silton MT-8000: manufactured by Mizusawa Chemical Industry Co., Ltd. SiO ₂ /AL ₂ O ₃ molar ratio=8000/1, average particle size=0.8 μm.
[Chemical adsorbent-supporting inorganic porous material]
- Dashlight CZU1721: manufactured by Sinanen Zeomic Co., Ltd. Copper oxide/zinc oxide composite aluminosilicate, average particle size = 3 to 5 μm.
[Inorganic odor decomposing agent]
- Inorganic odor decomposing agent 1: manufactured by Ishizuka Glass Co., Ltd. Copper oxide kneaded glass, average particle size = 3 to 4 µm. [Adhesive for dry lamination]
- Polyester-based adhesive 1: Adlock RU004/H1 manufactured by Rock Paint Co., Ltd. [Heat-sealable thermoplastic resin, thermoplastic resin, EC adhesive]
· ULTZEX 1520L: manufactured by Prime Polymer Co., Ltd. LLDPE, density = 0.916 g/ ^cm3 , MFR = 2.3.
- Novatec LC600A: manufactured by Japan Polyethylene Co., Ltd. LDPE, density = 0.918 g/ ^cm3 , MFR = 7.0.

<Adjustment of deodorant sealant layer masterbatch>
The thermoplastic resin and the deodorant were melt-blended according to the proportions shown in Table 1 to obtain deodorant sealant layer masterbatches 1 to 10 (MB1 to 10).

<Preparation of deodorant sealant layer resin composition>
The heat-sealable thermoplastic resin and the deodorant sealant layer masterbatch were melt-blended according to the compounding ratio shown in Table 2 to obtain deodorant sealant layer compositions 1 to 15.

[Example 1]
A PET film 1 for the base layer and an aluminum foil 1 for the intermediate layer are laminated by a dry lamination method using a polyester adhesive 1 at a dry coating amount of 3.5 g/m ² , and a laminate having the following structure is obtained. got a body
PET film 1 (12 μm)/polyester adhesive 1 (3.5 g/m ² )/aluminum foil 1 (7 μm)

Next, using ULTZEX 1520L, which is a heat-sealable thermoplastic resin, for the non-deodorant sealant layer, and using deodorant sealant layer resin composition 1 for the deodorant sealant layer, inflation film formation is performed at 160 ° C. A deodorizing sealant film having a thickness of 50 μm in total was prepared with the following three-layer structure.
Non-deodorant sealant layer (10 μm)/deodorant sealant layer (30 μm)/non-deodorant sealant layer (10 μm)

A polyester-based adhesive 1 is applied to one surface of the aluminum foil of the laminate obtained above and dried, and a deodorant sealant film is adhered by a dry lamination method to obtain a deodorant packaging material having the following constitution. An evaluation was carried out. Table 3 shows the detailed configuration and evaluation results of the deodorant packaging material.
PET film 1 (12 μm)/polyester adhesive 1 (3.5 g/m ² )/aluminum foil 1 (7 μm)/dry laminate adhesive layer (3.5 g/m ² )/non-deodorant sealant layer (10 μm)/ Deodorant sealant layer (30 μm)/non-deodorant sealant layer (10 μm)

[Examples 2-10, 15-18]
A deodorant sealant layer resin composition was selected according to the description in Table 3 and operated in the same manner as in Example 1 to obtain a deodorant sealant film and a deodorant packaging material, and various evaluations were carried out. Table 3 shows the detailed configuration and evaluation results of the deodorant packaging material.

[Example 11]
A deodorant packaging material was obtained in the same manner as in Example 1, except that the deodorant sealant film was made into a single layer structure with a thickness of 50 μm using the deodorant sealant layer resin composition 10, and various evaluations were performed. bottom. Table 3 shows the detailed configuration and evaluation results of the deodorant packaging material.

[Examples 12 to 14]
A laminate was produced in the same manner as in Example 1, and a deodorant sealant layer resin composition was selected according to Table 3 to produce a deodorant sealant film.

Next, the obtained laminate and the deodorant sealant film are bonded together by forming an adhesive layer with a thickness of 15 μm by an extrusion coating method using Novatec LC600A to obtain a deodorant packaging material. An evaluation was carried out. Table 3 shows the detailed configuration and evaluation results of the deodorant packaging material.

[Comparative Example 1]
A laminate was produced in the same manner as in Example 1.

Next, ULTZEX 1520L was laminated as a sealant layer on one surface of the aluminum foil of the obtained laminate by extrusion lamination to obtain a packaging material. Table 3 shows the detailed configuration and evaluation results of the packaging material.

[Comparative Example 2]
A packaging material was obtained in the same manner as in Comparative Example 1 except that the deodorizing sealant layer resin composition 10 was used as the sealant layer, and various evaluations were performed in the same manner as in Example 1. Table 3 shows the detailed configuration and evaluation results of the packaging material.

<Evaluation>
[Heat sealability of sealant layer]
The packaging materials obtained in Examples and Comparative Examples were cut into 10 cm × 10 cm pieces, folded in half and overlapped, and a 1 cm × 10 cm area was cut using a heat seal tester (manufactured by Tester Sangyo Co., Ltd.: TP-701-A). After heat-sealing, the end portion was not heat-sealed and not adhered, and a sample in which it was divided into two was prepared.

This sample was cut into strips with a width of 15 mm, each of the bifurcated ends was attached to a tensile tester, and the tensile strength (N/15 mm) was measured to determine pass/fail.
(Heat sealing conditions)
Temperature: 160°C
Pressure: 1 kgf/ ^cm2
Time: 1 second (tensile strength test conditions)
Test speed: 300mm/min Load range: 50N
(Pass/Fail Judgment Criteria)
◯: 30 N/15 mm or more, passed.
x: Less than 30 N/15 mm, failing.

[odor concentration]
The packaging materials (11 cm × 15 cm × 2 sheets) obtained in Examples and Comparative Examples are placed in a pouch (13 cm × 17 cm) made from a gas sampling bag (Tedlar bag), and the following evaluation gas is injected into the pouch bag with a syringe. An evaluation pouch was prepared for each evaluation gas, and 25 days for 2 days.
After leaving at ° C., the air in each evaluation pouch bag is sampled with a syringe, and the concentrations of dimethyltrisulfide, hydrogen sulfide, and acetaldehyde are measured with GC and a detector tube, and the dimethyltrisulfide and hydrogen sulfide in the pouch bag are measured. , the concentration of each of acetaldehyde was measured.

(evaluation gas)
Dimethyl trisulfide: 35 ppm
Hydrogen sulfide: 25ppm
Acetaldehyde: 30ppm
Other ingredients: air

<Summary of results>
All examples showed excellent seal strength and excellent odor concentration reduction.
However, Comparative Example 1, which does not contain a deodorant in the sealant layer, has excellent sealing strength, but hardly reduces the odor concentration. inferior in quality.

1 Deodorant sealant film 2 Base layer 3 Adhesive layer 4 Intermediate layer 4c Metal foil layer 6 Sealant layer 6a Non-deodorant sealant layer 6b Deodorant sealant layer 20 Inorganic porous body supporting chemical adsorbent

Claims (13)

A deodorant sealant film comprising at least a sealant layer,
The sealant layer contains a deodorant and a heat-sealable thermoplastic resin,
The deodorant contains one or two selected from the group consisting of a chemical adsorbent-supporting inorganic porous body and an inorganic odor decomposing agent,
When the deodorant contains the chemical adsorbent-supporting inorganic porous material, the chemical adsorbent-supporting inorganic porous material is one or two selected from the group consisting of copper, zinc, silver, platinum, and cobalt. containing the above elements,
When the deodorant contains the inorganic odor decomposing agent, the inorganic odor decomposing agent is a metal oxide kneaded or supported on an inorganic substance, and is copper, zinc, silver, platinum, or cobalt. containing one or more elements selected from the group
The deodorant sealant film, wherein the total content of the deodorants in the sealant layer is 0.2% by mass or more and 15% by mass or less. The deodorant is melt-kneaded in advance with a thermoplastic resin and a deodorant/thermoplastic resin mass ratio of 0.5/99.5 to 40/60.
The deodorant sealant film according to claim 1. The heat-sealable thermoplastic resin has a melt flow rate of 0.2 g/10 minutes or more and 10.0 g/10 minutes or less.
The deodorant sealant film according to claim 1 or 2. The sealant layer includes a deodorant sealant layer containing the deodorant and a non-deodorant sealant layer not containing the deodorant,
The non-deodorant sealant layer is laminated in contact with one side and/or both sides of the deodorant sealant layer,
A deodorant sealant film according to any one of claims 1 to 3. The deodorant contains the chemical adsorbent-supporting inorganic porous body and the inorganic odor decomposing agent,
The total content of the deodorant in the sealant layer is 0.2% by mass or more and 10% by mass or less,
A deodorant sealant film according to any one of claims 1 to 4. The deodorant further contains a hydrophobic zeolite having a SiO ₂ /Al ₂ O ₃ molar ratio of 30/1 to 8000/1.
A deodorant sealant film according to any one of claims 1 to 5. A deodorant laminate comprising a base layer and the deodorant sealant film according to any one of claims 1 to 6. Further comprising an intermediate layer,
The intermediate layer comprises one or more gas barrier layers selected from the group consisting of metal foil, vapor-deposited metal film, and vapor-deposited metal oxide film.
The deodorant laminate according to claim 7. The deodorant laminate according to claim 7, further comprising an aluminum foil as an intermediate layer. A deodorant packaging material produced from the deodorant laminate according to any one of claims 7 to 9. A deodorizing package made from the deodorizing packaging material according to claim 10. A deodorant package for liquid contents, which is produced from the deodorant package material according to claim 10. A deodorant package for alcoholic beverages, which is produced from the deodorant package material according to claim 10.

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