JP7121562B2 - Method for improving quality of gel composition - Google Patents

Method for improving quality of gel composition Download PDF

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JP7121562B2
JP7121562B2 JP2018123953A JP2018123953A JP7121562B2 JP 7121562 B2 JP7121562 B2 JP 7121562B2 JP 2018123953 A JP2018123953 A JP 2018123953A JP 2018123953 A JP2018123953 A JP 2018123953A JP 7121562 B2 JP7121562 B2 JP 7121562B2
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JP2019141026A (en
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佳也 深津
寿夫 清水
勇夫 有馬
竜 溝口
亜理沙 柴立
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Shimizu Chemical Corp
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Description

本発明は、一般的にはゲル状組成物の品質改良方法に関し、特定的には、食物繊維を含むゲル状組成物の品質改良方法に関する。 TECHNICAL FIELD The present invention generally relates to a method for improving the quality of a gel composition, and specifically to a method for improving the quality of a gel composition containing dietary fiber.

食物繊維は、血清コレステロール濃度の調整作用や血糖調節作用などに優れている。食物繊維をゲル状組成物にしたものは、整腸作用などの機能性を有する食品として活用されている。 Dietary fiber is excellent in regulating action of serum cholesterol concentration, blood sugar control action, and the like. Gelled compositions of dietary fiber are utilized as foods having functions such as intestinal regulation.

しかし、ゲル状組成物は、独特の風味や物性から、特定の料理にしか使用されず、用途が限られていた。 However, due to their unique flavor and physical properties, gel compositions have been used only for specific dishes and have limited uses.

食品の品質改良方法としては、例えば、特開平8-238074号公報(特許文献1)には、魚肉落とし身に、約0.7倍~等量の重曹ピロリン酸ナトリウム混合水溶液を加え、減圧下で晒しを行い、脱脂脱水することよりなる落とし身の品質改良法が記載されている。 As a method for improving food quality, for example, Japanese Patent Application Laid-Open No. 8-238074 (Patent Document 1) discloses that a mixed aqueous solution of sodium bicarbonate pyrophosphate in an amount of about 0.7 times to the same amount is added to fish meat drop, and then under reduced pressure. A method for improving the quality of slaughtered meat is described, which consists of exposing at 200° C. and degreasing and dehydrating.

また、特開2003-284522号公報(特許文献2)には、生あるいは加熱した植物食品素材を凍結した後、解凍し、酵素液に浸漬して減圧下に放置する植物組織への酵素急速導入法が記載されている。 In addition, Japanese Patent Application Laid-Open No. 2003-284522 (Patent Document 2) describes the rapid introduction of enzymes into plant tissues by freezing raw or heated plant food materials, thawing them, immersing them in an enzyme solution, and leaving them under reduced pressure. law is stated.

特開2009-89668号公報(特許文献3)には、食品素材の表面に接触させた分解酵素を圧力処理により食品素材の内部に均一に含有させる分解酵素導入工程であって、食品素材を減圧工程により形状を保持した状態で膨張させる膨張工程と、膨張した食品素材を元の食品素材の体積より小さい体積に圧縮させる圧縮工程とを有する分解酵素導入工程を含む熟成食品の製造方法が記載されている。 Japanese Patent Application Laid-Open No. 2009-89668 (Patent Document 3) discloses a degrading enzyme introduction step in which the degrading enzyme brought into contact with the surface of the food material is uniformly contained inside the food material by pressure treatment, wherein the food material is decompressed. A method for producing an aged food is described, which includes a step of introducing a degrading enzyme, which includes an expansion step of expanding the food material while maintaining its shape through the process, and a compression step of compressing the expanded food material to a volume smaller than that of the original food material. ing.

特開平8-238074号公報JP-A-8-238074 特開2003-284522号公報JP-A-2003-284522 特開2009-89668号公報JP-A-2009-89668

しかしながら、特許文献1~3に記載されているような方法は、ゲル状組成物の品質改良には適していない。ゲル状組成物を減圧しても、それだけでは、水分量を十分に低減することができず、室温では長期保管ができず、十分な冷凍耐性を得ることもできない。また、例えば、特許文献2に記載されているような凍結乾燥では、ゲル状組成物に鬆が入ってしまい、凍結乾燥後に調味液等に浸しても、水分が内部まで浸みこまない。 However, the methods described in Patent Documents 1 to 3 are not suitable for quality improvement of gel compositions. Even if the gel composition is decompressed, the moisture content cannot be sufficiently reduced, the composition cannot be stored for a long period of time at room temperature, and sufficient freezing resistance cannot be obtained. In addition, for example, in freeze-drying as described in Patent Document 2, voids are formed in the gel composition, and even if it is immersed in a seasoning liquid or the like after freeze-drying, moisture does not penetrate to the inside.

また、ゲル状組成物としてこんにゃくを用いる場合には、冷凍耐性を付与する目的で、ブドウ糖、ショ糖、麦芽糖、乳糖、果糖類のうち1種または数種をこんにゃくに含浸させることが知られている。しかしながら、含浸後の固形分が少ないので、水分活性が高くカビなどが発生しやすく、室温で長期保管できない。さらに、含浸物質が糖類である場合、できあがった製品に甘みが強く残り、調理用として不向きな素材となる場合がある。また、この糖類を含浸しても、水分が多く、所望の冷凍耐性を得ることができない。例えば、冷凍後には、冷凍前の弾力性がなくなり、所望のテクスチャー(食感)を得ることができない。 In addition, when using konjac as a gel composition, it is known to impregnate konjac with one or several of glucose, sucrose, maltose, lactose, and fructose for the purpose of imparting freeze resistance. there is However, since the solid content after impregnation is small, the water activity is high and mold is likely to occur, and long-term storage at room temperature is not possible. Furthermore, when the impregnating substance is sugars, the finished product retains a strong sweetness, which may make the material unsuitable for cooking. Moreover, even if it is impregnated with this saccharide, it contains a large amount of moisture, and the desired freeze resistance cannot be obtained. For example, after freezing, the elasticity before freezing is lost, and the desired texture cannot be obtained.

そこで、本発明の目的は、ゲル状組成物の保存性を向上させ、含浸液の特性を生かした機能性を付与することが可能なゲル状組成物の品質改良方法を提供することである。 SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a method for improving the quality of a gel composition capable of improving the storage stability of the gel composition and imparting functionality utilizing the characteristics of the impregnating liquid.

本発明に従ったゲル状組成物の品質改良方法は、食物繊維を含むゲル状組成物の水分の少なくとも一部を除去する水分除去工程と、水分の少なくとも一部を除去されたゲル状組成物を含浸液に含浸する含浸工程と、含浸物質に含浸されたゲル状組成物を減圧する減圧工程とを含む。 A method for improving the quality of a gel composition according to the present invention comprises a water removal step of removing at least part of the water from a gel composition containing dietary fiber, and a gel composition from which at least part of the water has been removed. is impregnated with an impregnating liquid, and a decompression step of decompressing the gel composition impregnated with the impregnating substance.

本発明に従ったゲル状組成物の品質改良方法においては、水分除去工程は、遠心分離、ドラム型真空式ろ過、ベルトフィルターろ過、または、自然ろ過によって行われることが好ましい。 In the gel composition quality improvement method according to the present invention, the water removal step is preferably carried out by centrifugation, drum vacuum filtration, belt filter filtration, or gravity filtration.

本発明に従ったゲル状組成物の品質改良方法においては、含浸液は、練乳、糖類、油脂類の少なくとも1つを含むことが好ましい。 In the method for improving the quality of a gel composition according to the present invention, the impregnating liquid preferably contains at least one of condensed milk, saccharides, and fats and oils.

本発明に従ったゲル状組成物の品質改良方法においては、減圧工程は、ゲル状組成物を加熱しながら行われることが好ましい。 In the method for improving the quality of a gel composition according to the present invention, the decompression step is preferably performed while heating the gel composition.

本発明に従ったゲル状組成物の品質改良方法においては、減圧されたゲル状組成物を冷却する冷却工程をさらに含むことが好ましい。 Preferably, the method for improving the quality of a gel composition according to the present invention further includes a cooling step of cooling the depressurized gel composition.

本発明に従ったゲル状組成物の品質改良方法においては、ゲル状組成物は、グルコマンナンと、グルコマンナン以外の増粘多糖類との混合物にアルカリ凝固剤を添加して製造されることが好ましい。 In the method for improving the quality of a gel composition according to the present invention, the gel composition may be produced by adding an alkaline coagulant to a mixture of glucomannan and a thickening polysaccharide other than glucomannan. preferable.

本発明に従ったゲル状組成物の品質改良方法においては、ゲル状組成物は熱不可逆性ゲルであることが好ましい。 In the gel composition quality improvement method according to the present invention, the gel composition is preferably a thermo-irreversible gel.

本発明に従ったゲル状組成物の品質改良方法においては、ゲル状組成物はこんにゃくであることが好ましい。 In the gel composition quality improvement method according to the present invention, the gel composition is preferably konjac.

本発明に従ったゲル状組成物の品質改良方法においては、ゲル状組成物は、グルコマンナンまたはこんにゃく粉1部に対して、澱粉15部以下、水100部以下、および、アルカリ凝固剤を含むことが好ましい。 In the method for improving the quality of a gel composition according to the present invention, the gel composition contains 1 part of glucomannan or konjac flour, 15 parts or less of starch, 100 parts or less of water, and an alkaline coagulant. is preferred.

本発明に従ったゲル状組成物の品質改良方法においては、ゲル状組成物は、食品であることが好ましい。 In the gel composition quality improvement method according to the present invention, the gel composition is preferably a food.

本発明に従ったゲル状組成物の品質改良方法においては、ゲル状組成物は、疑似餌であることが好ましい。 In the gel composition quality improvement method according to the present invention, the gel composition is preferably a lure.

本発明に従ったゲル状組成物の品質改良方法においては、ゲル状組成物は、薬剤を含む医薬組成物であることが好ましい。 In the gel composition quality improvement method according to the present invention, the gel composition is preferably a pharmaceutical composition containing a drug.

本発明に従ったゲル状組成物の品質改良方法においては、水分除去工程において水分の少なくとも一部を除去され、含浸工程において含浸液に含浸されるゲル状組成物は、90重量%以上の水分を含むことが好ましい。 In the method for improving the quality of a gel composition according to the present invention, the gel composition from which at least part of the water is removed in the water removal step and impregnated with the impregnation liquid in the impregnation step has a water content of 90% by weight or more. is preferably included.

以上のように、本発明に従えば、ゲル状組成物の保存性を向上させ、含浸液の特性を生かした機能性を付与することが可能なゲル状組成物の品質改良方法を提供することができる。 As described above, according to the present invention, there is provided a method for improving the quality of a gel composition capable of improving the storage stability of the gel composition and imparting functionality that takes advantage of the characteristics of the impregnation liquid. can be done.

ゲル状組成物(こんにゃく)の処理前後のこんにゃくと含浸液の全重量の減少率の時間変化を示す図である。[ Fig. 10] Fig. 10 is a diagram showing time-varying rate of decrease in the total weight of konjac and impregnated liquid before and after treatment with a gel composition (konjac). ゲル状組成物の処理前後のこんにゃくの重量の減少率の時間変化を示す図である。FIG. 10 is a graph showing temporal changes in the weight reduction rate of konjac before and after treatment with a gel composition. ゲル状組成物の糖液(含浸液)Bx(%)の時間変化を示す図である。FIG. 10 is a diagram showing a time change of sugar solution (impregnation solution) Bx (%) of the gel composition. ゲル状組成物の固形分の時間変化を示す図である。It is a figure which shows the time change of the solid content of a gel-like composition. ゲル状組成物の乾燥重量100gあたりの糖質含量を示す図である。FIG. 2 is a diagram showing the sugar content per 100 g of dry weight of the gel composition. ゲル状組成物の乾燥重量1gあたりの色素含有量を吸光度によって示す図である。FIG. 3 is a diagram showing the dye content per 1 g of dry weight of the gel composition by absorbance. ゲル状組成物の体積の時間変化を示す図である。FIG. 4 is a diagram showing changes in the volume of the gel composition over time. 本発明に従った品質改良方法によって品質改良したゲル状組成物(試料15)のSEM像を示す写真である。1 is a photograph showing an SEM image of a gel composition (Sample 15) improved in quality by the method for improving quality according to the present invention. 減圧工程を行っていないゲル状組成物(試料16)のSEM像を示す写真である。FIG. 10 is a photograph showing an SEM image of a gel composition (Sample 16) that was not subjected to a depressurization step. FIG.

本発明に従ったゲル状組成物の品質改良方法は、食物繊維を含むゲル状組成物の水分の少なくとも一部を除去する水分除去工程と、水分の少なくとも一部を除去されたゲル状組成物を含浸液に含浸する含浸工程と、含浸物質に含浸されたゲル状組成物を減圧する減圧工程とを含む。 A method for improving the quality of a gel composition according to the present invention comprises a water removal step of removing at least part of the water from a gel composition containing dietary fiber, and a gel composition from which at least part of the water has been removed. is impregnated with an impregnating liquid, and a decompression step of decompressing the gel composition impregnated with the impregnating substance.

食物繊維を含むゲル状組成物としては、例えば、グルコマンナンを主成分とし、アルカリ凝固されたこんにゃくや、耐熱性のゼリーなどが挙げられる。ゲル状組成物は熱不可逆性ゲルであることが好ましく、特に、こんにゃくであることが好ましい。 Gel compositions containing dietary fiber include, for example, konjac coagulated with alkali containing glucomannan as a main component, heat-resistant jelly, and the like. The gel composition is preferably a heat-irreversible gel, particularly preferably konjac.

ゲル状組成物は、例えば、グルコマンナンと、グルコマンナン以外の増粘多糖類との混合物に、アルカリ凝固剤を添加して製造される。また、澱粉がさらに添加されてもよい。 A gel composition is produced, for example, by adding an alkaline coagulant to a mixture of glucomannan and a polysaccharide thickener other than glucomannan. Also, starch may be further added.

増粘多糖類は、1種、または、2種含まれることが好ましい。増粘多糖類としては、例えば、果物または植物系のグアガム、グルコマンナン、ローカストビーンガム、タラガム、澱粉等、海藻系のカラギーナン、アルギン酸、寒天等、微生物系のジェランガム、キサンタンガム、カードラン等、その他のメチルセルロース等の化学修飾体が挙げられる。 It is preferable that one or two thickening polysaccharides are contained. Examples of thickening polysaccharides include fruit or plant-based guar gum, glucomannan, locust bean gum, tara gum, starch, etc., seaweed-based carrageenan, alginic acid, agar, etc., microbial-based gellan gum, xanthan gum, curdlan, etc. and chemically modified products such as methyl cellulose.

澱粉は、1種、または、2種含まれることが好ましい。澱粉としては、例えば、穀類のとうもろこし、小麦、米等、イモ類のジャガイモ、キャッサバ、サツマイモ等、根や幹類のサゴヤシ、レンコン等、豆類の緑豆、小豆、インゲン等が挙げられる。 One or two types of starch are preferably included. Examples of starch include cereals such as corn, wheat, and rice; tubers such as potato, cassava, and sweet potato; roots and stems such as sago palm and lotus root;

アルカリ凝固剤としては、例えば、炭酸ナトリウム、水酸化カルシウム、炭酸カリウム、水酸化ナトリウム、リン酸三ナトリウム、リン酸三カリウム、ホタテ貝の殻や牡蠣殻や卵殻の粉末を焼成したもの、塩基性アミノ酸としてアルギニン、ヒスチジン、リジン等、ピロリン酸ナトリウム、重炭酸ナトリウム等が挙げられる。 Alkaline coagulants include, for example, sodium carbonate, calcium hydroxide, potassium carbonate, sodium hydroxide, trisodium phosphate, tripotassium phosphate, baked scallop shell, oyster shell, and egg shell powder, basic Amino acids include arginine, histidine, lysine and the like, sodium pyrophosphate, sodium bicarbonate and the like.

より具体的には、ゲル状組成物は、グルコマンナンまたはこんにゃく粉1部に対して、澱粉15部以下、水100部以下と、アルカリ凝固剤を含むことが好ましい。 More specifically, the gel composition preferably contains 15 parts or less of starch, 100 parts or less of water, and an alkaline coagulant per 1 part of glucomannan or konjac powder.

ゲル状組成物の水分除去工程は、遠心分離、ドラム型真空式ろ過、ベルトフィルターろ過、または、自然ろ過によって行われることが好ましい。遠心分離は、スクリューデカンター、ポールセパレーター、バスケット遠心機等、公知の手段が用いられ得る。自然ろ過は、フィルターろ過、布ろ過等、公知の手段が用いられ得る。 The step of removing water from the gel composition is preferably carried out by centrifugation, drum-type vacuum filtration, belt filter filtration, or gravity filtration. For centrifugation, known means such as screw decanter, pole separator, and basket centrifuge can be used. For natural filtration, known means such as filter filtration and cloth filtration can be used.

水分除去工程の後、含浸工程が行われる。含浸工程では、水分の少なくとも一部を除去されたゲル状組成物を含浸液に含浸する。 After the water removal step, an impregnation step is performed. In the impregnation step, the gel composition from which at least part of the moisture has been removed is impregnated with an impregnation liquid.

含浸液は、ゲル状組成物に風味や特性を付与するための液体である。含浸液は、練乳、糖類、油脂類の少なくとも1つを含むことが好ましい。練乳としては、例えば、加糖練乳、加糖脱脂練乳、調整練乳が挙げられる。糖類としては、例えば、ブドウ糖、ショ糖、麦芽糖、黒糖、乳糖、果糖、オリゴ糖、トレハロース、希少糖等が挙げられる。油脂類としては、バター、ヤシ油、ココナッツ油、オリーブ油、菜種油、ベニバナ油、大豆油、ひまわり油、綿実油、アマニ油、魚油、動物脂、n-3系脂肪酸、n-6系脂肪酸、n-9系脂肪酸等が挙げられる。また、含浸液は、リキュール、ワイン、梅酒等のアルコール類、牛乳、はちみつ、黒蜜、羅漢果等のガムシロップ、ココナッツ、ビタミンプレミックス、ミネラルプレミックス、魚エキスを含んでいてもよい。含浸液は、これらの含浸物質の1種または2種以上を含むことが好ましい。 The impregnating liquid is a liquid for imparting flavor and properties to the gel composition. The impregnating liquid preferably contains at least one of condensed milk, saccharides, and fats and oils. Examples of condensed milk include sweetened condensed milk, sweetened condensed skimmed milk, and adjusted condensed milk. Sugars include, for example, glucose, sucrose, maltose, brown sugar, lactose, fructose, oligosaccharides, trehalose, and rare sugars. Fats and oils include butter, coconut oil, coconut oil, olive oil, rapeseed oil, safflower oil, soybean oil, sunflower oil, cottonseed oil, linseed oil, fish oil, animal fat, n-3 fatty acids, n-6 fatty acids, n- 9-series fatty acids and the like. The impregnating liquid may also contain alcohols such as liqueur, wine, and plum wine, milk, honey, black honey, gum syrup such as monk fruit, coconut, vitamin premix, mineral premix, and fish extract. The impregnating liquid preferably contains one or more of these impregnating substances.

含浸工程の後、含浸物質に含浸されたゲル状組成物を減圧する減圧工程が行われる。減圧工程によって、ゲル状組成物中の水分量がさらに低減され、ゲル状組成物中の固形分が濃縮される。真空圧範囲は、-0.099MPa~-0.0036MPaであることが好ましい。 After the impregnation step, a decompression step is performed to depressurize the gel composition impregnated with the impregnating substance. The decompression step further reduces the water content in the gel composition and concentrates the solid content in the gel composition. The vacuum pressure range is preferably -0.099 MPa to -0.0036 MPa.

減圧工程は、ゲル状組成物を加熱しながら行われることが好ましい。減圧工程の温度は、20℃~99℃であることが好ましい。 The decompression step is preferably performed while heating the gel composition. The temperature of the decompression step is preferably 20°C to 99°C.

減圧工程、または、加熱しながらの減圧工程は、例えば、多重効用缶、泡末濃縮機、レオニーダー、グローバル濃縮機、バッチ式真空濃縮機、蒸発濃縮装置、ギスティーミックスタンク、加圧真空釜、加圧真空ケトミキサー等によって行われ得る。 The decompression process or the decompression process while heating is performed, for example, by a multi-effect tank, a foam concentrator, a rheo kneader, a global concentrator, a batch-type vacuum concentrator, an evaporative concentrator, a Gistie mix tank, a pressurized vacuum pot, It can be done with a pressurized vacuum ketomixer or the like.

減圧工程の圧力や温度の条件は、含浸液の特性、例えば、密度、比重、溶解度、融点、沸点、凝固点、pHや、最終製品のpH、塩濃度・糖濃度による水分活性、充填方法(アセプティック充填であるかどうか)、充填温度等によって設定される。 The pressure and temperature conditions in the decompression process are determined by the properties of the impregnating liquid, such as density, specific gravity, solubility, melting point, boiling point, freezing point, pH, pH of the final product, water activity depending on salt concentration and sugar concentration, filling method (aseptic whether it is filling), filling temperature, etc.

減圧工程の後、特に、減圧工程においてゲル状組成物が加熱された場合には、減圧されたゲル状組成物を冷却する冷却工程をさらに含むことが好ましい。 After the depressurizing step, it is preferable to further include a cooling step of cooling the depressurized gel composition, particularly when the gel composition is heated in the depressurizing step.

冷却工程の圧力や温度の条件は、含浸液の特性、例えば、密度、比重、溶解度、融点、沸点、凝固点、pH等によって設定される。 The pressure and temperature conditions for the cooling process are set according to the properties of the impregnating liquid, such as density, specific gravity, solubility, melting point, boiling point, freezing point, pH, and the like.

このようにすることにより、ゲル状組成物の風味の改良、テクスチャの改良、耐酸性、耐塩性、耐熱性、冷凍耐性等の付与、賞味期限の延長、常温保管可能食品としての保存性の向上が可能になる。 By doing so, it is possible to improve the flavor of the gel composition, improve the texture, impart acid resistance, salt resistance, heat resistance, freeze resistance, etc., extend the expiration date, and improve the storage stability as a food that can be stored at room temperature. becomes possible.

本発明の品質改良方法によって品質改良されたゲル状組成物は、調理材料、製菓原料、機能性素材として用いることができる。機能性素材としては、例えば、含浸液として魚エキスを用いて、生分解性を有する疑似餌とすることができる。また、含浸液としてビタミン、ミネラル、オリゴ糖、DHA等を用いることによって、機能性食品とすることができる。また、ゲル状組成物に薬剤を含ませ、徐放性を備える医薬組成物として用いることもできる。 A gel composition whose quality has been improved by the quality improvement method of the present invention can be used as a cooking ingredient, a confectionery ingredient, or a functional ingredient. As a functional material, for example, fish extract can be used as an impregnating liquid to make a biodegradable artificial bait. Also, by using vitamins, minerals, oligosaccharides, DHA, etc. as the impregnating liquid, functional foods can be obtained. In addition, a drug can be contained in the gel composition and used as a pharmaceutical composition having sustained release properties.

本発明の品質改良方法によって品質改良されたゲル状組成物は、より具体的には、例えば、ソフトクリーム、シャーベット、アイスクリーム等の冷菓にミックス、フィリング、トッピングして用いることができる。また、ケーキや饅頭の生地にミックス、フィリング、トッピングして用いることもできる。また、飲料やゼリーに用いることもできる。さらに、疑似梅干しなどの疑似食品として用いることもできる。 More specifically, the gel composition whose quality has been improved by the method for improving quality of the present invention can be used, for example, by mixing, filling, or topping frozen desserts such as soft ice cream, sherbet, and ice cream. It can also be used as a mix, filling, or topping for cakes and steamed buns. It can also be used in beverages and jelly. Furthermore, it can also be used as a simulated food such as a simulated umeboshi.

また、本発明の品質改良方法によって品質改良されたゲル状組成物を乾燥させることによって、保存性をさらに向上させることができる。また、このようにすることにより、グミのような食感を与えることができる。 In addition, the storage stability can be further improved by drying the gel composition whose quality has been improved by the method for improving quality of the present invention. Moreover, by doing so, it is possible to impart a gummy-like texture.

以下、実施例等により本発明を詳細に説明するが、本発明はこれに限定されるものではない。 EXAMPLES The present invention will be described in detail below with reference to Examples and the like, but the present invention is not limited to these.

[ゲル状組成物]
ゲル状組成物としてこんにゃくを用いた。こんにゃくは、こんにゃく粉1.9%、白玉粉0.1%、加工でんぷん粉8.7%、食用加工油脂0.9%、増粘多糖類0.9%、水を残部入れ合計100%とした配合比で原材料を混合し、凝固剤(水酸化カルシウム)を添加して混練し、押出し、切断、加熱成形(85±3℃、5±1分)、熟成(30分以上)して調製した。こんにゃくの大きさは、1粒が長辺9.5mm、短辺8.2mm、体積363mmであった。以下の実施例と試験例では、それぞれ、このこんにゃく10粒をゲル状組成物として使用した。
[Gel composition]
Konjac was used as the gel composition. Konnyaku is 1.9% konjac flour, 0.1% shiratama flour, 8.7% processed starch powder, 0.9% edible processed oil, 0.9% polysaccharide thickener, and the rest of water to make a total of 100%. It was prepared by mixing raw materials at a compounding ratio, adding a coagulant (calcium hydroxide), kneading, extruding, cutting, thermoforming (85±3° C., 5±1 minutes), and aging (30 minutes or more). . As for the size of the konjac, one grain had a long side of 9.5 mm, a short side of 8.2 mm, and a volume of 363 mm 3 . In the following examples and test examples, 10 konjac granules were used as a gel composition.

上述のこんにゃくの水分量は、上述の熱成後の時点では97.7重量%であった。また、このこんにゃくを3,000Gで20分間、遠心分離器で遠心分離したところ、水分量は92.4重量%であった。水分量の測定は、常圧乾燥法(海砂法)を用いた。 The moisture content of the above-mentioned konjac was 97.7% by weight after the above-mentioned thermal aging. Further, when this konjac was centrifuged at 3,000 G for 20 minutes using a centrifuge, the water content was 92.4% by weight. The normal pressure drying method (sea sand method) was used to measure the water content.

なお、本願発明のゲル状組成物はこんにゃくに限定されるものではない。ゲル状組成物がこんにゃくである場合には、こんにゃく原料はこんにゃく粉5%以下、白玉粉3%以下、加工でんぷん粉15%以下、増粘多糖類3%以下であることが好ましく、その他の成分として食用加工油脂、水酸化カルシウム、pH調整剤を適量含み、残部として水を加えて100%とすることが好ましい。 The gel composition of the present invention is not limited to konjac. When the gel composition is konjac, the konjac raw material is preferably 5% or less konjac flour, 3% or less shiratama flour, 15% or less modified starch powder, and 3% or less polysaccharide thickener. Appropriate amounts of edible processed oil, calcium hydroxide, and a pH adjuster are included, and water is preferably added as the balance to make 100%.

[実施例1]
[水分除去工程]
ゲル状組成物として上述のこんにゃくを用い、バスケット型遠心分離機で遠心分離(遠心効果:500G、時間:10分間以上)によって水分除去工程を行った。水分除去工程後のこんにゃくの水分量は、90重量%以上(実測値;96.6重量%)であった。水分量の測定は、常圧乾燥法(海砂法)を用いた。
[Example 1]
[Moisture removal step]
Using the above konjac as the gel composition, a water removal step was performed by centrifugation in a basket type centrifuge (centrifugal effect: 500 G, time: 10 minutes or longer). The water content of the konjac after the water removal step was 90% by weight or more (measured value: 96.6% by weight). The normal pressure drying method (sea sand method) was used to measure the water content.

[含浸工程]
含浸液として、加糖練乳を用いた。ゲル状組成物と加糖練乳を混合して、ゲル状組成物に加糖練乳を含浸させた。
[Impregnation process]
Sweetened condensed milk was used as the impregnation liquid. The gel composition and sweetened condensed milk were mixed to impregnate the gel composition with the sweetened condensed milk.

[減圧工程]
次に、85℃、真空圧-0.0435Mpaの減圧濃縮装置を用いて、ゲル状組成物を減圧した。濃縮終点を固形分73%以上とした。
[Decompression step]
Next, the gel composition was decompressed using a vacuum concentrator at 85° C. and a vacuum pressure of −0.0435 MPa. The concentration end point was set at a solid content of 73% or more.

[冷却工程]
ゲル状組成物の濃縮終了後、急冷を行った。これは、品質保持、さらには冷却の過程で過飽和となった乳糖をできるだけ細かな結晶として析出させることを目的としている。冷却温度は38℃であった。
[Cooling process]
After completing the concentration of the gel composition, it was rapidly cooled. This is aimed at preserving the quality and furthermore precipitating lactose, which has become supersaturated during the cooling process, as fine crystals as possible. The cooling temperature was 38°C.

[シーディング工程]
ゲル状組成物が冷却温度に達した後、微細な乳糖結晶を生成させるため、撹拌冷却しながら乳糖の微細結晶を添加し、20℃以下に除冷した。その後さらに1時間程度撹拌を続け、過飽和の乳糖をすべて結晶化させた。
[Seeding process]
After the gel composition reached the cooling temperature, fine crystals of lactose were added while stirring and cooling in order to generate fine crystals of lactose, and the mixture was slowly cooled to 20°C or less. After that, the stirring was further continued for about 1 hour to crystallize all the supersaturated lactose.

[充填工程]
ゲル状組成物を冷却後8時間以上静置し、あらかじめ滅菌、乾燥した容器(缶)に充填した。なお、充填方法はアセプティック充填であってもよい。
[Filling process]
After cooling, the gel composition was allowed to stand for 8 hours or more, and filled in a previously sterilized and dried container (can). The filling method may be aseptic filling.

[実施例2]
[水分除去工程]
ゲル状組成物として上述のこんにゃくを用い、バスケット型遠心分離機で遠心分離(遠心効果:500G、時間:10分間以上)によって水分除去工程を行った。水分除去工程後のこんにゃくの水分量は、90重量%以上(実測値;96.6重量%)であった。水分量の測定は、常圧乾燥法(海砂法)を用いた。
[Example 2]
[Moisture removal step]
Using the above konjac as the gel composition, a water removal step was performed by centrifugation in a basket type centrifuge (centrifugal effect: 500 G, time: 10 minutes or longer). The water content of the konjac after the water removal step was 90% by weight or more (measured value: 96.6% by weight). The normal pressure drying method (sea sand method) was used to measure the water content.

[含浸工程]
含浸液として、砂糖40%、トレハロース15%、果糖ぶどう糖液糖15%、レモン果汁30%の混合液に、レモンエキス適量、酸味料適量を加えた液を用いた。ゲル状組成物と含浸液を混合して、ゲル状組成物に含浸液を含浸させた。
[Impregnation process]
As the impregnating liquid, a mixture of 40% sugar, 15% trehalose, 15% fructose-glucose liquid sugar, and 30% lemon juice was added with an appropriate amount of lemon extract and an appropriate amount of acidulant. The gel composition and the impregnation liquid were mixed to impregnate the gel composition with the impregnation liquid.

[減圧工程]
次に、85℃、真空圧-0.0435Mpaの減圧濃縮装置を用いて、ゲル状組成物を減圧した。濃縮終点を固形分73%以上とした。濃縮終点において、ゲル状組成物はpH4.0以下であった。
[Decompression step]
Next, the gel composition was decompressed using a vacuum concentrator at 85° C. and a vacuum pressure of −0.0435 MPa. The concentration end point was set at a solid content of 73% or more. At the concentration end point, the pH of the gel composition was 4.0 or less.

[冷却工程]
ゲル状組成物の濃縮終了後、急冷を行った。冷却温度は10℃以下であった。
[Cooling process]
After completing the concentration of the gel composition, it was rapidly cooled. The cooling temperature was 10°C or less.

[充填工程]
ゲル状組成物を冷却後、あらかじめ滅菌、乾燥した容器(缶)に充填した。なお、充填方法はアセプティック充填、ホット充填であってもよい。
[Filling process]
After cooling the gel composition, it was filled in a previously sterilized and dried container (can). The filling method may be aseptic filling or hot filling.

[実施例3]
[水分除去工程]
ゲル状組成物として上述のこんにゃくを用い、バスケット型遠心分離機で遠心分離(遠心効果:500G、時間:10分間以上)によって水分除去工程を行った。水分除去工程後のこんにゃくの水分量は、90重量%以上(実測値;96.6重量%)であった。水分量の測定は、常圧乾燥法(海砂法)を用いた。
[Example 3]
[Moisture removal step]
Using the above konjac as the gel composition, a water removal step was performed by centrifugation in a basket type centrifuge (centrifugal effect: 500 G, time: 10 minutes or longer). The water content of the konjac after the water removal step was 90% by weight or more (measured value: 96.6% by weight). The normal pressure drying method (sea sand method) was used to measure the water content.

[含浸工程]
含浸液として、オリーブオイル71%、米黒酢25%、バジルエキス3%、食塩1%の混合液に、スパイス適量、pH調整剤適量を加えた液を用いた。ゲル状組成物と含浸液を混合して、ゲル状組成物に含浸液を含浸させた。
[Impregnation process]
As the impregnating liquid, a mixture of 71% olive oil, 25% rice black vinegar, 3% basil extract, and 1% salt was added with an appropriate amount of spice and an appropriate amount of pH adjuster. The gel composition and the impregnation liquid were mixed to impregnate the gel composition with the impregnation liquid.

[減圧工程]
次に、85℃、真空圧-0.0435Mpaの減圧濃縮装置を用いて、ゲル状組成物を減圧した。濃縮終点を固形分73%以上とした。
[Decompression step]
Next, the gel composition was decompressed using a vacuum concentrator at 85° C. and a vacuum pressure of −0.0435 MPa. The concentration end point was set at a solid content of 73% or more.

[冷却工程]
ゲル状組成物の濃縮終了後、急冷を行った。冷却温度は25℃であった。
[Cooling process]
After completing the concentration of the gel composition, it was rapidly cooled. The cooling temperature was 25°C.

[充填工程]
ゲル状組成物を冷却後、あらかじめ滅菌、乾燥した容器(缶)に充填した。なお、充填方法はアセプティック充填、ホット充填であってもよい。
[Filling process]
After cooling the gel composition, it was filled in a previously sterilized and dried container (can). The filling method may be aseptic filling or hot filling.

[実施例4]
[水分除去工程]
ゲル状組成物として上述のこんにゃくを用い、バスケット型遠心分離機で遠心分離(遠心効果:500G、時間:10分間以上)によって水分除去工程を行った。水分除去工程後のこんにゃくの水分量は、90重量%以上(実測値;96.6重量%)であった。水分量の測定は、常圧乾燥法(海砂法)を用いた。
[Example 4]
[Moisture removal step]
Using the above konjac as the gel composition, a water removal step was performed by centrifugation in a basket type centrifuge (centrifugal effect: 500 G, time: 10 minutes or longer). The water content of the konjac after the water removal step was 90% by weight or more (measured value: 96.6% by weight). The normal pressure drying method (sea sand method) was used to measure the water content.

[含浸工程]
含浸液として、加糖練乳60%、オリゴ糖40%の混合液に、pH調整剤適量を加えた液を用いた。ゲル状組成物と含浸液を混合して、ゲル状組成物に含浸液を含浸させた。
[Impregnation process]
As the impregnating liquid, a mixed liquid of 60% sweetened condensed milk and 40% oligosaccharide to which an appropriate amount of pH adjuster was added was used. The gel composition and the impregnation liquid were mixed to impregnate the gel composition with the impregnation liquid.

[減圧工程]
次に、85℃、真空圧-0.0435Mpaの減圧濃縮装置を用いて、ゲル状組成物を減圧した。濃縮終点を固形分73%以上とした。
[Decompression step]
Next, the gel composition was decompressed using a vacuum concentrator at 85° C. and a vacuum pressure of −0.0435 MPa. The concentration end point was set at a solid content of 73% or more.

[冷却工程]
ゲル状組成物の濃縮終了後、急冷を行った。冷却温度は38℃であった。
[Cooling process]
After completing the concentration of the gel composition, it was rapidly cooled. The cooling temperature was 38°C.

[シーディング工程]
ゲル状組成物が冷却温度に達した後、微細な乳糖結晶を生成させるため、撹拌冷却しながら乳糖の微細結晶を添加し、20℃以下に除冷した。その後さらに1時間程度撹拌を続け、過飽和の乳糖をすべて結晶化させた。
[Seeding process]
After the gel composition reached the cooling temperature, fine crystals of lactose were added while stirring and cooling in order to generate fine crystals of lactose, and the mixture was slowly cooled to 20°C or less. After that, the stirring was further continued for about 1 hour to crystallize all the supersaturated lactose.

[充填工程]
ゲル状組成物を冷却後8時間以上静置し、あらかじめ滅菌、乾燥した容器(缶)に充填した。なお、充填方法はアセプティック充填、ホット充填であってもよい。
[Filling process]
After cooling, the gel composition was allowed to stand for 8 hours or more, and filled in a previously sterilized and dried container (can). The filling method may be aseptic filling or hot filling.

[試験例1]
ゲル状組成物として上述のこんにゃくを用いた。遠心分離によってこんにゃくの水分量の少なくとも一部を低減させた。水分除去工程として、3,000Gで20分間、遠心分離器で遠心分離した。水分除去工程後のこんにゃくの水分量は、試料1~6のいずれの試料でも、90重量%以上(実測値;92.4重量%)であった。水分量の測定は、常圧乾燥法(海砂法)を用いた。果糖ぶどう糖液糖に純水、及び、食用合成着色料(赤色40号)を0.0165%加え、糖度(Bx)70の糖液を調整して含浸液とした。この含浸液に遠心分離したこんにゃく、または、遠心分離していないこんにゃくを、含浸液の重量:含浸するこんにゃくの重量を2:1として含浸させた。
[Test Example 1]
The above konjac was used as the gel composition. At least a portion of the water content of the konjac was reduced by centrifugation. As a water removal step, centrifugation was performed with a centrifuge at 3,000 G for 20 minutes. The water content of the konjac after the water removal step was 90% by weight or more (measured value: 92.4% by weight) for any of Samples 1 to 6. The normal pressure drying method (sea sand method) was used to measure the water content. Purified water and 0.0165% of edible synthetic coloring (Red No. 40) were added to fructose-glucose liquid sugar to prepare a sugar solution with a sugar content (Bx) of 70 to prepare an impregnating solution. Centrifuged konjac or non-centrifuged konjac was impregnated with this impregnation solution at a ratio of 2:1: weight of impregnation solution: weight of konjac to be impregnated.

次の表1の条件で各試料を作製し、減圧した。減圧は、各試料100gを200mLのナス型フラスコに量り、ウォーターバス(YAMATO BT-15)にて各条件の温度まで昇温させた後、エバポレータ(ロータリーエバポレーター Buchi Rotavapor(登録商標)R-300)にて減圧を開始した。 Each sample was prepared under the conditions shown in Table 1 below, and the pressure was reduced. Decompression is performed by weighing 100 g of each sample into a 200 mL eggplant-shaped flask, heating it to the temperature of each condition in a water bath (YAMATO BT-15), and then using an evaporator (rotary evaporator Buchi Rotavapor (registered trademark) R-300). Depressurization was started at .

Figure 0007121562000001
Figure 0007121562000001

各条件の真空度に達した時点を処理時間開始とし、規定の処理時間、減圧工程を行った。処理終了後はシリコン栓によって密栓し、測定試料とした。 The treatment time started when the degree of vacuum of each condition was reached, and the decompression step was performed for the prescribed treatment time. After the treatment was completed, the container was tightly sealed with a silicon plug and used as a measurement sample.

[重量測定]
試料の混合直後(こんにゃくの含浸液への含浸直後)と、減圧工程の終了後のそれぞれにおいて、含浸液とゲル状組成物(こんにゃく)の全重量と、ゲル状組成物の重量を測定した。ゲル状組成物の重量は、100メッシュ(ステンレスメッシュ)ろ過後、ペーパーにて表面の水分を拭き取って測定した。重量の測定は、電気式はかり(新光電気(株)製)を用いた。結果を表2と図1,2に示す。
[Weight measurement]
Immediately after mixing the sample (immediately after impregnating the konjac with the impregnating liquid) and after the decompression step, the total weight of the impregnating liquid and the gel composition (konjac) and the weight of the gel composition were measured. The weight of the gel composition was measured by wiping the surface water with paper after filtration through 100 mesh (stainless mesh). An electric scale (manufactured by Shinko Electric Co., Ltd.) was used for weight measurement. The results are shown in Table 2 and FIGS.

Figure 0007121562000002
Figure 0007121562000002

表2と図1,2に示されているように、減圧工程をしない(常圧)場合には、60分間加熱しても、全重量も、こんにゃく重量も、減少率に変化が見られなかった。一方、減圧工程を行った場合には、加熱時間の経過とともに全重量も、こんにゃくの重量も、減少率が上昇した。 As shown in Table 2 and FIGS. 1 and 2, when the decompression process is not performed (normal pressure), even if heated for 60 minutes, the reduction rate of the total weight and the weight of konjac did not change. rice field. On the other hand, when the decompression step was performed, the rate of decrease in both the total weight and the weight of the konjac increased with the lapse of heating time.

[糖度(Bx)および固形分の測定]
試験例1の減圧工程後、100メッシュろ過にてこんにゃくを取り除いた糖液について20℃におけるBxを測定した。測定は、デジタル屈折計(アタゴ RX-5000α)とpHメーター(東亜DKK HM-30S)を用いた。
[Measurement of sugar content (Bx) and solid content]
After the depressurization step in Test Example 1, Bx at 20° C. was measured for the sugar solution from which the konjac was removed by 100-mesh filtration. For the measurement, a digital refractometer (Atago RX-5000α) and a pH meter (Toa DKK HM-30S) were used.

また、減圧工程の終了後、表面の水分を拭き取ったこんにゃくを15g量り、ホモジナイザー(エースホモジナイザー 日本精機(株)製)で10,000rpm、2分間破砕を行った。破砕したものについて、常圧乾燥法(海砂法)にて固形分を測定した。常圧乾燥法(海砂法)は、102℃の乾熱器(ADVANTEC FS-33)中で乾燥し、恒量とした海砂入りのアルミニウム製平底ひょう量ざらに試料約3~5gを採取し精ひょうした。水浴上で注意しながら加熱し、大部分の水分を蒸発させたのち、乾熱器にいれ、恒量となるまで乾燥させた。結果を表3と図3,4に示す。 After the decompression step, 15 g of the konjac from which the surface moisture was wiped was weighed and crushed with a homogenizer (Ace Homogenizer manufactured by Nippon Seiki Co., Ltd.) at 10,000 rpm for 2 minutes. The solid content of the crushed product was measured by the normal pressure drying method (sea sand method). In the normal pressure drying method (sea sand method), dry in a dry heat device (ADVANTEC FS-33) at 102°C and take about 3 to 5 g of a sample in a constant weight aluminum flat-bottomed weighing dish containing sea sand. I was fine. After careful heating on a water bath to evaporate most of the water, it was placed in an oven and dried to constant weight. The results are shown in Table 3 and FIGS.

Figure 0007121562000003
Figure 0007121562000003

表3と図3,4に示すように、常圧条件では、60分間の加熱において糖液Bx、こんにゃく固形分の顕著な上昇は見られなかった。一方、減圧工程した場合には、加熱時間の経過とともに糖液Bx、こんにゃく固形分が上昇した。 As shown in Table 3 and FIGS. 3 and 4, under normal pressure conditions, no significant increase in sugar solution Bx and konjac solid content was observed after heating for 60 minutes. On the other hand, when the pressure reduction step was performed, the sugar liquid Bx and the konjac solid content increased with the lapse of the heating time.

[ゲル状組成物中の糖含量の測定]
表4に示す各試料の減圧工程の終了後、表面の水分を拭き取ったこんにゃくを15g量り、ホモジナイザー(エースホモジナイザー 日本精機(株)製)で10,000rpm、2分間破砕を行った。破砕したものを0.5g精秤し、水を7mL添加後、アセトニトリルにて25mLに定容した。遠心分離機(サーモフィッシャーサイエンティフィク(株)製 LYNX6000)にて8,000rpm、10分間、20℃で処理後、上澄み液をHPLC(Agilent 1100シリーズ)にて測定した。HPLCの条件は以下の通りであった。
カラム:Nucleosil 5NH2 4.6×250mm
溶媒:70%アセトニトリル
流量:1.0mL/min
検出器:視差屈折率計
結果を表5と図5に示す。
[Measurement of Sugar Content in Gel Composition]
After the depressurization step for each sample shown in Table 4, 15 g of konjac was weighed after wiping off moisture from the surface, and crushed for 2 minutes at 10,000 rpm with a homogenizer (Ace Homogenizer manufactured by Nippon Seiki Co., Ltd.). 0.5 g of the crushed material was accurately weighed, 7 mL of water was added, and the volume was adjusted to 25 mL with acetonitrile. After centrifugation (LYNX6000, manufactured by Thermo Fisher Scientific Co., Ltd.) at 8,000 rpm for 10 minutes at 20°C, the supernatant was measured by HPLC (Agilent 1100 series). The HPLC conditions were as follows.
Column: Nucleosil 5NH2 4.6 x 250mm
Solvent: 70% acetonitrile Flow rate: 1.0 mL/min
Detector: parallax refractometer The results are shown in Table 5 and FIG.

Figure 0007121562000004
Figure 0007121562000004

Figure 0007121562000005
Figure 0007121562000005

[ゲル状組成物中の色素含量測定]
表4に示す各試料の減圧工程の終了後、表面の水分を拭き取ったこんにゃくを15g量り、ホモジナイザー(エースホモジナイザー 日本精機(株)製)で10,000rpm、2分間破砕を行った。破砕したものを0.6~0.8g精秤し、1N塩酸を5mL、99.5%エタノールを5mL添加し、室温で1時間放置した。遠心分離機にて10,000G、10分間、20℃で処理後、上澄み液を50%エタノールで20mLに定容し、510nmの吸光度を測定した。結果を表6と図6に示す。
[Measurement of pigment content in gel composition]
After the depressurization step for each sample shown in Table 4, 15 g of konjac was weighed after wiping off moisture from the surface, and crushed for 2 minutes at 10,000 rpm with a homogenizer (Ace Homogenizer manufactured by Nippon Seiki Co., Ltd.). 0.6 to 0.8 g of the crushed material was precisely weighed, 5 mL of 1N hydrochloric acid and 5 mL of 99.5% ethanol were added, and left at room temperature for 1 hour. After centrifugation at 10,000 G for 10 minutes at 20° C., the supernatant was adjusted to 20 mL with 50% ethanol, and the absorbance at 510 nm was measured. Results are shown in Table 6 and FIG.

Figure 0007121562000006
Figure 0007121562000006

[ゲル状組成物の寸法の測定]
表1の試料1~6の減圧工程後、表面の水分を拭き取ったこんにゃく10粒について、長辺と短辺の長さを測定し、その平均値を求めた。結果を表7と図7に示す。
[Measurement of dimensions of gel composition]
After the depressurization process of samples 1 to 6 in Table 1, the length of the long side and the short side of 10 konjac grains whose surface was wiped off was measured, and the average value was obtained. The results are shown in Table 7 and FIG.

Figure 0007121562000007
Figure 0007121562000007

表7と図7に示されているように、減圧工程を行うことによって、時間の経過とともにこんにゃくの体積が減少した。 As shown in Table 7 and FIG. 7, the decompression step reduced the volume of konjac over time.

以上のように、本発明に従ったゲル状組成物の品質改良方法によれば、ゲル組成物中の含水率が減少するが、これは、糖分が水分と置換されることによるものではなく、ゲル状組成物が収縮するためであると考えられる。この収縮と、含浸液の特性との相乗効果によって、耐酸性、耐塩性、耐熱性、耐冷凍性の機能性の付与が可能となっていると考えられる。 As described above, according to the method for improving the quality of a gel composition according to the present invention, the water content in the gel composition is reduced, but this is not due to replacement of sugar with water, This is believed to be due to shrinkage of the gel composition. The synergistic effect of this shrinkage and the properties of the impregnating liquid is considered to be capable of imparting functionality such as acid resistance, salt resistance, heat resistance, and freeze resistance.

[試験例2]
ゲル状組成物として上述のこんにゃくを用いた。遠心分離によってこんにゃくの水分量の少なくとも一部を低減させた。水分除去工程として、3,000Gで20分間、遠心分離器で遠心分離した。水分除去工程後のこんにゃくの水分量は、いずれの試料でも、90重量%以上(実測値;92.4重量%)であった。水分量の測定は、常圧乾燥法(海砂法)を用いた。果糖ぶどう糖液糖に純水を加え、糖度(Bx)70の糖液を調整して含浸液とした。この含浸液に遠心分離したこんにゃくを、含浸液の重量:含浸するこんにゃくの重量を2:1として含浸させた。減圧は、各試料100gを200mLのナス型フラスコに量り、ウォーターバス(YAMATO BT-15)にて各条件の温度まで昇温させた後、エバポレータ(ロータリーエバポレーター Buchi Rotavapor(登録商標)R-300)にて85℃で60分間、真空度260mbarにて減圧を行い、試料15のゲル状組成物を得た。一方、ゲル状組成物としてこんにゃくを用い、含浸液として果糖ブドウ糖液糖を用いて同様に含浸工程を行い、85℃で60分間に保って減圧工程を行わないものを、試料16のゲル状組成物とした。得られた試料15,16のゲル状組成物をSEMで観察した。SEMは、走査型電子顕微鏡(日本電子(株)製、JSM-6010LA)を使用した。SEM像を図8,9に示す。
[Test Example 2]
The above konjac was used as the gel composition. At least a portion of the water content of the konjac was reduced by centrifugation. As a water removal step, centrifugation was performed with a centrifuge at 3,000 G for 20 minutes. The water content of the konjac after the water removal step was 90% by weight or more (measured value: 92.4% by weight) for all samples. The normal pressure drying method (sea sand method) was used to measure the water content. Purified water was added to fructose-glucose liquid sugar to prepare a sugar liquid having a sugar content (Bx) of 70 to prepare an impregnating liquid. The centrifugally separated konjac was impregnated with this impregnation solution at a ratio of 2:1: weight of impregnation solution: weight of konjac to be impregnated. Decompression is performed by weighing 100 g of each sample into a 200 mL eggplant-shaped flask, heating it to the temperature of each condition in a water bath (YAMATO BT-15), and then using an evaporator (rotary evaporator Buchi Rotavapor (registered trademark) R-300). The pressure was reduced at 85° C. for 60 minutes at a degree of vacuum of 260 mbar, and a gel composition of sample 15 was obtained. On the other hand, using konjac as the gel composition, performing the same impregnation step using fructose glucose liquid sugar as the impregnation solution, maintaining at 85 ° C. for 60 minutes and not performing the decompression step, the gel composition of sample 16 I made it. The obtained gel compositions of Samples 15 and 16 were observed by SEM. For SEM, a scanning electron microscope (manufactured by JEOL Ltd., JSM-6010LA) was used. SEM images are shown in FIGS.

図8,9において、白い部分はこんにゃくの表面である。図8,9に示されているように、減圧処理がされたゲル状組成物(試料15)は、全体に果糖ブドウ糖液糖が浸透していることがわかった。 In FIGS. 8 and 9, the white portion is the surface of the konjac. As shown in FIGS. 8 and 9, it was found that fructose-glucose liquid sugar permeates the gel composition (Sample 15) subjected to vacuum treatment.

以上に開示された実施の形態と実施例はすべての点で例示であって制限的なものではないと考慮されるべきである。本発明の範囲は、以上の説明ではなく、特許請求の範囲によって示され、特許請求の範囲と均等の意味および範囲内でのすべての変形を含むものである。 It should be considered that the embodiments and examples disclosed above are illustrative in all respects and not restrictive. The scope of the present invention is indicated by the scope of the claims rather than the above description, and includes all modifications within the scope and meaning equivalent to the scope of the claims.

Claims (10)

食物繊維を含むゲル状組成物の水分の少なくとも一部を除去する水分除去工程と、
水分の少なくとも一部を除去された前記ゲル状組成物を、乳糖を含む含浸液に含浸する含浸工程と、
前記含浸に含浸された前記ゲル状組成物を加熱しながら減圧して前記ゲル状組成物の固形分が73%以上になるまで濃縮する減圧工程と、
濃縮された前記ゲル状組成物を冷却して前記含浸液に含まれる乳糖を結晶として析出させる冷却工程とを含み、
前記冷却工程において乳糖の微細結晶を添加し、20℃以下に徐冷するシーディング工程をさらに含む、ゲル状組成物の品質改良方法。
a water removing step of removing at least part of the water of the gel composition containing dietary fiber;
an impregnation step of impregnating the gel composition from which at least part of the water has been removed with an impregnation solution containing lactose ;
A depressurizing step of depressurizing the gel composition impregnated with the impregnation liquid while heating to concentrate until the solid content of the gel composition becomes 73% or more ;
a cooling step of cooling the concentrated gel composition to precipitate lactose contained in the impregnation liquid as crystals,
A method for improving the quality of a gel composition, further comprising a seeding step of adding fine crystals of lactose in the cooling step and slowly cooling to 20°C or less .
前記水分除去工程は、遠心分離、ドラム型真空式ろ過、ベルトフィルターろ過、または、自然ろ過によって行われる、請求項1に記載のゲル状組成物の品質改良方法。 2. The method for improving the quality of a gel composition according to claim 1, wherein the water removal step is performed by centrifugation, drum-type vacuum filtration, belt filter filtration, or gravity filtration. 前記ゲル状組成物は、グルコマンナンと、グルコマンナン以外の増粘多糖類との混合物にアルカリ凝固剤を添加して製造される、請求項1または請求項2に記載のゲル状組成物の品質改良方法。 The quality of the gel composition according to claim 1 or 2 , wherein the gel composition is produced by adding an alkaline coagulant to a mixture of glucomannan and a polysaccharide thickener other than glucomannan. How to improve. 前記ゲル状組成物は熱不可逆性ゲルである、請求項1から請求項までのいずれか1項に記載のゲル状組成物の品質改良方法。 The method for improving the quality of a gel composition according to any one of claims 1 to 3 , wherein the gel composition is a thermo-irreversible gel. 前記ゲル状組成物はこんにゃくである、請求項1から請求項までのいずれか1項に記載のゲル状組成物の品質改良方法。 The method for improving the quality of a gel composition according to any one of claims 1 to 4 , wherein the gel composition is konjac. 前記ゲル状組成物は、グルコマンナンまたはこんにゃく粉1部に対して、澱粉15部以下、水100部以下、および、アルカリ凝固剤を含む、請求項1から請求項までのいずれか1項に記載のゲル状組成物の品質改良方法。 6. Any one of claims 1 to 5 , wherein the gel composition comprises 1 part of glucomannan or konjac powder, 15 parts of starch or less, 100 parts or less of water, and an alkaline coagulant. A method for upgrading the described gel composition. 前記ゲル状組成物は、食品である、請求項1から請求項までのいずれか1項に記載のゲル状組成物の品質改良方法。 The method for improving the quality of a gel composition according to any one of claims 1 to 6 , wherein the gel composition is food. 前記ゲル状組成物は、疑似餌である、請求項1から請求項までのいずれか1項に記載のゲル状組成物の品質改良方法。 The method for improving the quality of a gel composition according to any one of claims 1 to 6 , wherein the gel composition is a lure. 前記ゲル状組成物は、薬剤を含む医薬組成物である、請求項1から請求項までのいずれか1項に記載のゲル状組成物の品質改良方法。 The method for improving the quality of a gel composition according to any one of claims 1 to 6 , wherein the gel composition is a pharmaceutical composition containing a drug. 前記水分除去工程において水分の少なくとも一部を除去され、前記含浸工程において前記含浸液に含浸される前記ゲル状組成物は、90重量%以上の水分を含む、請求項1から請求項までのいずれか1項に記載のゲル状組成物の品質改良方法。 The gel composition from which at least part of water is removed in the water removal step and is impregnated with the impregnation liquid in the impregnation step contains 90 % by weight or more of water. A method for improving the quality of the gel composition according to any one of claims 1 to 3.
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