JP7089066B2 - Temperature lowering filter rod, its use, and cigarette - Google Patents

Temperature lowering filter rod, its use, and cigarette Download PDF

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JP7089066B2
JP7089066B2 JP2020563976A JP2020563976A JP7089066B2 JP 7089066 B2 JP7089066 B2 JP 7089066B2 JP 2020563976 A JP2020563976 A JP 2020563976A JP 2020563976 A JP2020563976 A JP 2020563976A JP 7089066 B2 JP7089066 B2 JP 7089066B2
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temperature
filter rod
powder
temperature lowering
granules
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JP2021523716A (en
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潜 陳
勇 金
海風 譚
克 李
詩太 王
超 譚
賽波 ▲喩▼
紅梅 范
▲チー▼ 劉
建華 易
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チャイナ タバコ フーナン インダストリアル カンパニー リミテッド
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Priority claimed from CN201810486861.3A external-priority patent/CN110506991B/en
Priority claimed from CN201810486835.0A external-priority patent/CN110506990A/en
Priority claimed from CN201810486815.3A external-priority patent/CN110506989A/en
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/067Use of materials for tobacco smoke filters characterised by functional properties
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/186Treatment of tobacco products or tobacco substitutes by coating with a coating composition, encapsulation of tobacco particles
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • A24D3/0204Preliminary operations before the filter rod forming process, e.g. crimping, blooming
    • A24D3/0212Applying additives to filter materials
    • A24D3/0216Applying additives to filter materials the additive being in the form of capsules, beads or the like
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/061Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/08Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/14Use of materials for tobacco smoke filters of organic materials as additive
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/16Use of materials for tobacco smoke filters of inorganic materials
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/16Use of materials for tobacco smoke filters of inorganic materials
    • A24D3/163Carbon
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/20Cigarettes specially adapted for simulated smoking devices

Description

本発明は、降温フィルタロッド、その使用、及びシガレットに関し、シガレット生産の技術分野に属する。 The present invention belongs to the technical field of cigarette production with respect to the temperature lowering filter rod, its use, and the cigarette.

従来のシガレットでは、パフするときに、シガレットの燃焼コーンが生じた熱量が主流煙によりフィルタに送られ、シガレットのパフが進むに伴い、フィルタを流れる煙の温度が高くなる。研究から、パフが終了しようとするときに、フィルタ側の煙の温度が70~80℃と高くなり、フィルタの温度が高すぎると、フィルタの遮断効果が損なわれ、また、タバコの品質への消費者の官能評価も悪影響を受けることが明らかになる。煙温度を適切に低下させることが求められる。 In a conventional cigarette, when puffing, the amount of heat generated by the combustion cone of the cigarette is sent to the filter by mainstream smoke, and as the cigarette puff progresses, the temperature of the smoke flowing through the filter rises. Studies have shown that when the puff is about to finish, the temperature of the smoke on the filter side is as high as 70-80 ° C, and if the temperature of the filter is too high, the blocking effect of the filter will be impaired and the quality of the cigarette will be affected. It becomes clear that the sensory evaluation of consumers is also adversely affected. It is required to appropriately lower the smoke temperature.

加熱不燃シガレットは、外部加熱部材を通じてタバコ製品を加熱することにより煙を発生させるものであり、通常、タバコ製品は、250~350℃では霧化条件を満たすようになり、煙量を確保するために、通常、フィルタ側には低吸着、さらに非吸着が必要であり、高温霧化煙がフィルタを介して口腔に入るときの温度が、従来のシガレットの燃焼温度よりも高くなる。したがって、煙温度を適切に低下させることは、低温シガレットについて研究される重要な技術でもある。 The heated non-combustible cigarette generates smoke by heating the tobacco product through an external heating member. Normally, the tobacco product meets the atomization condition at 250 to 350 ° C. to secure the amount of smoke. In addition, low adsorption and non-adsorption are usually required on the filter side, and the temperature at which high-temperature atomized smoke enters the oral cavity through the filter becomes higher than the combustion temperature of conventional cigarettes. Therefore, proper reduction of smoke temperature is also an important technique studied for cold cigarettes.

中国特許CN201510045745.4は、フィルタ側に相変化材料を添加することで煙温度を低下させるフィルタ、及びシガレットを提供しており、使用される相変化材料は水和無機塩と尿素との混合物であり、使用方式としては、アセテート繊維製フィルタにスプレーするか、又は結晶物を2つのフィルタの間に配置し、本分野で公知するのは、このような水和塩の使用方式であるが、この効果が不十分である。 Chinese patent CN201510045745.4 provides a filter and cigarette that lowers the smoke temperature by adding a phase change material on the filter side, and the phase change material used is a mixture of hydrated inorganic salt and urea. There is a method of using such a hydrated salt, which is known in the art by spraying on an acetate fiber filter or placing crystals between two filters. This effect is inadequate.

中国特許CN101396173は、シガレットのボルテックによる降温保香方法、及びそのシガレット構造を提供しており、空気に連通しているボルテックスチャネルがシガレットのフィルタの前方に設置され、それにより降温効果を果たすが、構造が複雑であり、低温加熱型の不燃シガレットに不適である。 Chinese patent CN101396173 provides a method of cooling and retaining the temperature of a cigarette by vortexing, and a cigarette structure thereof, in which a vortex channel communicating with air is installed in front of the cigarette filter, thereby achieving a temperature lowering effect. It has a complicated structure and is not suitable for low temperature heating type non-combustible cigarettes.

フィルタへの加香処理には、通常、加香顆粒、加香ワイヤやカプセルの形態が使用されている。中国特許CN101390657は、ミント徐放型のタバコ用フィルタ棒及びその生産プロセスを開示しており、香料を浸漬した綿糸を用いるような加香手段が使用されているが、持続的な加香が不可能である。 The form of perfume granules, perfume wire or capsule is usually used for the perfume treatment on the filter. Chinese patent CN101390657 discloses a mint sustained release type filter rod for cigarettes and its production process, in which a fragrance means such as using cotton yarn soaked in fragrance is used, but continuous fragrance is not achieved. It is possible.

本発明が解決しようとする技術的課題は、シガレット(従来のシガレット、及び加熱不燃シガレットを含む)のパフ時に、燃焼により生じた煙の温度が高く、消費者の口腔へ灼熱感を与え、パフのエクスペリエンスに悪影響を与えることである。 The technical problem to be solved by the present invention is that when puffing cigarettes (including conventional cigarettes and non-combustible cigarettes), the temperature of smoke generated by combustion is high, giving a burning sensation to the consumer's oral cavity and puffing. It has a negative impact on the experience of.

上記技術的課題を解決するために、本発明の技術案は以下のとおりである。 In order to solve the above technical problems, the technical proposal of the present invention is as follows.

降温フィルタロッドであって、主に降温顆粒を硬化成形させてなり、前記降温顆粒は顆粒本体と顆粒本体に被覆されたシェル層とを含み、前記シェル層/又は顆粒本体は相変化材料を含むことを特徴とする。 It is a temperature lowering filter rod, which is mainly formed by curing and molding the temperature lowering granules, the temperature lowering granules include a granule body and a shell layer coated on the granule body, and the shell layer / or the granule body contains a phase change material. It is characterized by that.

このようにして、使用される降温顆粒はコアシェル構造を有し、表層のシェル層には、降温機能を有する相変化材料が分布している。降温フィルタロッドは、降温顆粒を必要な形状に応じて硬化成形させることにより製造でき、一定の形状で積み上げられることにより形成される降温フィルタロッドは、全体として多孔質構造になり、シガレット製品に用いると、高温煙が降温フィルタロッドを通過するときに、煙はスムーズに通過できる一方、他方では、高温煙とシェル層との接触面積が大きく、それにより、降温効率が高まり、良好な降温効果を奏することに有利となり、喫煙者のエクスペリエンスが向上する。 In this way, the temperature-decreasing granules used have a core-shell structure, and a phase-changing material having a temperature-decreasing function is distributed in the surface shell layer. The temperature lowering filter rod can be manufactured by curing and molding the temperature lowering granules according to the required shape, and the temperature lowering filter rod formed by stacking them in a certain shape has a porous structure as a whole and is used for cigarette products. And, when the high temperature smoke passes through the temperature lowering filter rod, the smoke can pass smoothly, while on the other hand, the contact area between the high temperature smoke and the shell layer is large, which increases the temperature lowering efficiency and provides a good temperature lowering effect. It is beneficial to play and improves the smoker's experience.

好適には、シェル層だけが相変化材料を含み、好適には、顆粒本体だけが相変化材料を含有し、好適には、シェル層と顆粒本体の両方が相変化材料を含有する。 Preferably, only the shell layer contains the phase change material, preferably only the granule body contains the phase change material, and preferably both the shell layer and the granule body contain the phase change material.

本発明のいくつかの実施形態では、前記シェル層は相変化材料で構成される。 In some embodiments of the invention, the shell layer is composed of a phase change material.

さらに、前記相変化材料は、PLA、ポリエチレングリコール、ステアリン酸、パルミチン酸、パラフィン、微結晶ワックス、EVA、ペンタエリスリトール、ステアリン酸-イソプロパノールエステル、ステアリン酸-グリセロールトリエステルのうちの少なくとも1種を含む。適切な相変化材料を選択することにより、コード効果を確保するとともに、良好な降温効果を奏し、それによって、降温フィルタロッド全体の降温性能が高まる。好ましくは、前記相変化材料は、PLA、ポリエチレングリコール、ステアリン酸(ステアリン酸シリーズとEVAとの混合物を含む)を含む。 Further, the phase change material contains at least one of PLA, polyethylene glycol, stearic acid, palmitic acid, paraffin, microcrystalline wax, EVA, pentaerythritol, stearic acid-isopropanol ester, and stearic acid-glycerol triester. .. By selecting an appropriate phase change material, the chord effect is ensured and a good temperature lowering effect is exhibited, thereby enhancing the temperature lowering performance of the entire temperature lowering filter rod. Preferably, the phase change material comprises PLA, polyethylene glycol, stearic acid, including a mixture of stearic acid series and EVA.

本発明のいくつかの実施形態では、前記シェル層は香味剤をさらに含む。このようにして、降温顆粒のシェルには相変化材料と香味剤が含まれており、降温顆粒を一定の形状で積み上げてなる降温フィルタロッドは、全体として、煙がスムーズに通過できる多孔質構造となり、また、シガレット製品に用いると、高温煙は、降温フィルタロッドを通過するときに、シェル層との接触面積が大きくなり、煙の熱量に対する相変化材料の吸収効率が高く、降温効率が高く、良好な降温効果を奏することに有利となり、喫煙者のエクスペリエンスが向上し、また、シェル層中の香味剤は熱を受けると香りを徐々に放出し、煙とともに喫煙者の口腔に送られ、煙へ特有の味を付与し、使用者それぞれのパフ時のニーズに応えられ、相変化材料が吸熱して相変化すると、その内部の香り成分が徐々に放出され、それにより、持続的な加香作用が果たされる。一般には、香味剤が揮発して香りを発生させることは、吸熱プロセスであり、このため、煙温度の低下にも有利である。 In some embodiments of the invention, the shell layer further comprises a flavoring agent. In this way, the shell of the temperature-decreasing granules contains the phase change material and the flavoring agent, and the temperature-decreasing filter rod, which is made by stacking the temperature-decreasing granules in a certain shape, has a porous structure through which smoke can pass smoothly as a whole. Also, when used in cigarette products, high-temperature smoke has a large contact area with the shell layer when passing through the temperature-decreasing filter rod, and the absorption efficiency of the phase change material with respect to the heat of the smoke is high, and the temperature-decreasing efficiency is high. The flavoring agent in the shell layer gradually releases the scent when it receives heat and is sent to the smoker's oral cavity with smoke, which is advantageous for achieving a good temperature lowering effect and improving the smoker's experience. It gives a unique taste to smoke, meets the needs of each user at the time of puffing, and when the phase change material absorbs heat and undergoes a phase change, the scent component inside it is gradually released, thereby sustaining addition. The scent effect is achieved. In general, the volatilization of a flavoring agent to generate an aroma is an endothermic process, which is also advantageous for lowering the smoke temperature.

さらに、前記香味剤は、香料及び/又はタバコ抽出物を含み、好ましくは、前記相変化材料と香味剤との質量比が100:(0.5~10)である。 Further, the flavoring agent contains a flavoring and / or a tobacco extract, and the mass ratio of the phase changing material to the flavoring agent is preferably 100: (0.5 to 10).

好適には、前記香料は、メントン、コーヒーフレーバーのうちの少なくとも1種を含み、具体的には、必要に応じて選択してもよく、また必要に応じてほかの香料としてもよい。 Preferably, the flavoring contains at least one of menthone and coffee flavor, and specifically, it may be selected as needed, or may be another flavoring as needed.

さらに、前記シェル層の質量は降温顆粒の総質量の0.5~30%、好ましくは1~20%を占める。相変化材料の使用量を適切にすることにより、降温効果が要件を満たし、パフ中に相変化が繰り返したときにフィルタロッドのチャンネルの詰まりが回避される。 Further, the mass of the shell layer occupies 0.5 to 30%, preferably 1 to 20% of the total mass of the temperature-decreasing granules. By adjusting the amount of phase change material used, the temperature lowering effect meets the requirements and clogging of the filter rod channel is avoided when the phase change is repeated during the puff.

本発明のいくつかの実施形態では、前記顆粒本体は植物繊維粉末及び/又は無機材料粉末を含み、またさらに、前記植物繊維粉末及び/又は無機材料粉末の粒子径が、80~200メッシュ、好ましくは100~180メッシュである。 In some embodiments of the present invention, the granule body comprises a plant fiber powder and / or an inorganic material powder, and further, the particle size of the plant fiber powder and / or the inorganic material powder is preferably 80 to 200 mesh. Is 100 to 180 mesh.

さらに、前記植物繊維粉末は、タバコ粉末、トウモロコシの穂軸粉末、籾殻粉末、クルミ殻粉末、ココナッツの殻粉末、乾燥みかん皮の粉末、グレープフルーツピール粉末のうちの少なくとも1種を含み、植物粉末は、天然のものであり、汚染がなく、低価であり、緻密な顆粒を製造して吸着効率を低下させることができ、低温シガレットにより適用でき、また、降温フィルタロッド及びシガレット製造によるナイフへの損耗を低減できる。さらに、前記無機材料粉末は、炭酸カルシウム、炭素粉末、セラミック、シリカゲル、分子篩のうちの少なくとも1種を含み、無機材料の使用は、異臭を招くことがなく、また多孔性が部分的に活用されて、降温フィルタロッドの吸着性能を向上させ、通常のシガレットにより適用できる。さらに、前記顆粒本体は成形補助材料をさらに含み、前記成形補助材料は、粘着剤、湿潤剤、賦形補助材料のうちの少なくとも1種を含む。 Further, the plant fiber powder contains at least one of tobacco powder, corn cob powder, rice husk powder, walnut husk powder, coconut husk powder, dried tangerine peel powder, and grapefruit peel powder. , Natural, clean, low cost, capable of producing dense granules to reduce adsorption efficiency, applicable with low temperature cigarettes, and to knives by cooling filter rods and cigarette production. Wear can be reduced. Further, the inorganic material powder contains at least one of calcium carbonate, carbon powder, ceramic, silica gel, and molecular sieve, and the use of the inorganic material does not cause an offensive odor, and the porosity is partially utilized. Therefore, the adsorption performance of the temperature lowering filter rod is improved, and it can be applied by a normal cigarette. Further, the granule body further contains a molding auxiliary material, and the molding auxiliary material contains at least one of a pressure-sensitive adhesive, a wetting agent, and a shaping auxiliary material.

またさらに、前記接着剤は、PVP、HPC、HPMC、SCMC、変性澱粉のうちの少なくとも1種を含み、前記湿潤剤は水又はアルコールを含み、前記賦形補助材料は微結晶性セルロース及び乳糖を含む。適切な粘着剤及び湿潤剤は、製造された顆粒に良好な形態及び強度を付与できる。 Furthermore, the adhesive comprises at least one of PVP, HPC, HPMC, SCMC, modified starch, the wetting agent comprises water or alcohol, and the excipient auxiliary material is microcrystalline cellulose and lactose. include. Suitable adhesives and wetting agents can impart good morphology and strength to the produced granules.

植物繊維粉末と無機材料粉末の配合比を合理的に調整することにより、降温フィルタロッドの吸着性を適切な範囲に調整するとともに、さまざまなシガレットによるニーズに応えられる。 By rationally adjusting the blending ratio of the plant fiber powder and the inorganic material powder, the adsorptivity of the temperature lowering filter rod can be adjusted to an appropriate range, and the needs of various cigarettes can be met.

本発明のいくつかの実施形態では、前記顆粒本体は、基体粉末、ホットメルト接着剤粉末、賦形剤、水を十分に混合した後、造粒、乾燥、篩分けをすることにより製造され、前記基体粉末は、植物材料、無機材料、金属粉末のうちの少なくとも1種を含み、さらに、前記植物材料は、タバコ原料、わら、ピーナッツの殻、バガス、トウモロコシの穂軸、果皮、香料植物のうちの少なくとも1種を含み、前記無機材料は、炭粉、粘土、炭酸カルシウム、酸化ケイ素のうちの少なくとも1種を含み、前記金属粉末は、鉄粉、アルミナ、銅粉のうちの少なくとも1種を含む。一般には、基体粉末、ホットメルト接着剤粉末、賦形剤、水の配合比については必要に応じて設定することができ、順調に造粒成形可能であればよい。植物材料を使用すると、コストをできるだけ削減させる一方、香料植物はフィルタロッドに香りを付与する役割も果たす。無機材料も金属粉末も異臭を招くことがなく、しかも、金属性粉末は降温効果の発揮により有利である。さらに、前記香料植物は、ビャクダン、沈香、チョウジ、コーヒー、ウイキョウのうちの少なくとも1種を含む。 In some embodiments of the present invention, the granule body is manufactured by thoroughly mixing a substrate powder, a hot melt adhesive powder, an excipient, and water, and then granulating, drying, and sieving. The substrate powder contains at least one of a plant material, an inorganic material and a metal powder, and further, the plant material includes tobacco raw material, straw, peanut shell, bagus, corn cob, fruit bark and fragrant plant. The inorganic material contains at least one of carbon powder, clay, calcium carbonate, and silicon oxide, and the metal powder contains at least one of iron powder, alumina, and copper powder. including. In general, the mixing ratio of the substrate powder, the hot melt adhesive powder, the excipient, and the water can be set as needed, and it is sufficient if the granulation and molding can be smoothly performed. The use of plant materials reduces costs as much as possible, while perfume plants also serve to add fragrance to the filter rods. Neither the inorganic material nor the metal powder causes an offensive odor, and the metallic powder is more advantageous due to the effect of lowering the temperature. Further, the perfume plant contains at least one of sandalwood, agarwood, clove, coffee and fennel.

さらに、前記ホットメルト接着剤粉末は、EVA、TPU、PE、PA、PESのうちの少なくとも1種を含む。顆粒の成形及び顆粒棒の成形を確保するとともに、これら自体にも一定の相変化能力を有するので、相変化による降温作用をある程度果たす。降温顆粒に対する前記ホットメルト接着剤粉末の質量比が、5%~50%、好ましくは10%~40%であり、ほかの成分の含有量については必要に応じて調整することができる。ホットメルト接着剤の用量を適切にすることにより、十分な粘着力が確保され、過剰になると、溶融時にチャンネルの詰まりを引き起こし、降温効果を損なう恐れがある。 Further, the hot melt adhesive powder contains at least one of EVA, TPU, PE, PA and PES. In addition to ensuring the molding of granules and the molding of granule rods, they also have a certain phase change ability, so that they have a certain degree of temperature lowering effect due to the phase change. The mass ratio of the hot melt adhesive powder to the temperature-decreasing granules is 5% to 50%, preferably 10% to 40%, and the content of other components can be adjusted as necessary. Sufficient adhesive strength is ensured by adjusting the dose of hot melt adhesive, and if it becomes excessive, it may cause channel clogging at the time of melting and impair the temperature lowering effect.

好適には、前記賦形剤は微結晶性セルロース、アルファ化澱粉を含む。 Preferably, the excipient comprises microcrystalline cellulose, pregelatinized starch.

さらに、前記降温顆粒の粒子径が、10~50メッシュ、好ましくは20~35メッシュである。 Further, the particle size of the temperature-decreasing granules is 10 to 50 mesh, preferably 20 to 35 mesh.

さらに、加熱不燃シガレットの降温に用いる場合、前記降温顆粒は、押出・球状化造粒法を用い、その形状が球形又は略球形顆粒であり、降温顆粒のかさ密度が0.8~2.5g/mlである。球形又は略球形とすると、降温フィルタロッドの内部には、十分に複雑で連続的な煙チャンネルが形成され、顆粒密度が十分に高いと、吸着性能が最低になり、タバコの発煙量への悪影響がなくなる。 Further, when used for lowering the temperature of a heated non-combustible cigarette, the lowered temperature granules use an extrusion / spheroidizing granulation method, and the shape is spherical or substantially spherical granules, and the bulk density of the lowered temperature granules is 0.8 to 2.5 g. / Ml. When spherical or substantially spherical, a sufficiently complex and continuous smoke channel is formed inside the temperature lowering filter rod, and when the granule density is sufficiently high, the adsorption performance is minimized, which adversely affects the amount of smoke emitted from cigarettes. Is gone.

さらに、通常のシガレットの降温に用いる場合、前記降温顆粒は、球形又は不定形であり、降温顆粒のかさ密度が0.4~1.6g/mlである。降温フィルタロッドの内部には、十分に複雑で連続的な煙チャンネルが形成され、顆粒密度を低くすると、顆粒の内部の空隙がすべて詰まることを回避し、一定の吸着性能を維持できる。好ましくは、前記降温顆粒の水含有量が、5~15wt%、さらに7~12wt%である。水含有量を適切な範囲に保持することによって、パフ中にシガレットの喫煙感を良好に維持し、また、植物繊維粉末を含有する降温フィルタロッドの場合、カビの発生を防止できる。 Further, when used for lowering the temperature of a normal cigarette, the lowered temperature granules are spherical or amorphous, and the bulk density of the lowered temperature granules is 0.4 to 1.6 g / ml. A sufficiently complex and continuous smoke channel is formed inside the temperature lowering filter rod, and when the granule density is lowered, it is possible to prevent all the voids inside the granules from being clogged and maintain a constant adsorption performance. Preferably, the water content of the temperature-decreasing granules is 5 to 15 wt%, more preferably 7 to 12 wt%. By keeping the water content in an appropriate range, the smoking feeling of the cigarette can be kept good in the puff, and in the case of the temperature lowering filter rod containing the plant fiber powder, the generation of mold can be prevented.

粒子径が適切な顆粒を含ませることによって、フィルタロッドの内部に十分な通気性を付与し、水分を適切とすると、保管しやすく、成形制御を容易にする。 By including granules having an appropriate particle size, sufficient air permeability is imparted to the inside of the filter rod, and when the moisture is appropriate, storage is easy and molding control is facilitated.

さらに、前記降温フィルタロッドの内部の有効空隙率が65~95%である。このようにして、降温フィルタロッドは全体として多孔質構造となり、内部には複雑で連続的なチャンネルが形成されており、高温煙が降温フィルタロッドの一端から降温フィルタロッドに入ると、降温フィルタロッド内の孔隙に素早く拡散し、降温顆粒と十分に接触して熱交換し、このようにして降温が実現され、また、降温フィルタロッドにおける高温煙の移動距離が大きく、降温効果が高くなる。有効空隙率を十分にすると、フィルタロッドの内部に要求される通気性を満たす。 Further, the effective porosity inside the temperature lowering filter rod is 65 to 95%. In this way, the temperature lowering filter rod has a porous structure as a whole, and a complicated and continuous channel is formed inside. When high temperature smoke enters the temperature lowering filter rod from one end of the temperature lowering filter rod, the temperature lowering filter rod is formed. It diffuses quickly into the pores inside and exchanges heat sufficiently in contact with the temperature-decreasing granules, thereby achieving temperature reduction, and the moving distance of the high-temperature smoke in the temperature-decreasing filter rod is large, so that the temperature-decreasing effect is enhanced. A sufficient effective porosity satisfies the air permeability required inside the filter rod.

さらに、前記降温フィルタロッドの内部の有効空隙率が80~95%である。 Further, the effective porosity inside the temperature lowering filter rod is 80 to 95%.

さらに、前記多孔質構造はハニカムのような形状である。 Further, the porous structure has a honeycomb-like shape.

好適には、前記降温フィルタロッドは通気性の良好な多孔質円柱体である。 Preferably, the temperature lowering filter rod is a porous columnar body having good air permeability.

さらに、前記降温フィルタロッドは、降温顆粒を粘着剤で粘着して硬化成形させたものである。 Further, the temperature lowering filter rod is obtained by adhering the temperature lowering granules with an adhesive and curing and molding them.

さらに、前記降温フィルタロッドは主に降温顆粒をマイクロ波又は熱で硬化成形させて得る。 Further, the temperature lowering filter rod is mainly obtained by curing and molding the temperature lowering granules by microwave or heat.

さらに、前記降温フィルタロッドには、パフ用の刻みタバコ部又は発煙部が接続され、ここで、降温フィルタロッドは刻みタバコ/発煙部に近い。 Further, a puff chopped tobacco portion or a smoke emitting portion is connected to the temperature lowering filter rod, where the temperature lowering filter rod is close to the chopped tobacco / smoke emitting portion.

好適には、前記降温フィルタロッドの製造方法は、
植物繊維粉末及び/又は無機材料粉末を関連する成形補助材料と混合し、造粒、ベーク、篩掛けをして、顆粒本体を得て、次に、相変化材料を用いて顆粒本体をコード処理し、降温顆粒を得るステップ(1)と、
ステップ(1)で得た降温顆粒を硬化成形させ、降温フィルタロッドを得るステップ(2)と、を含むか、
又は、
植物材料/無機材料/金属粉末のうちの少なくとも1種、ホットメルト接着剤粉末、微結晶性セルロース、アルファ化澱粉、水などを十分に混合し、造粒、乾燥、篩掛けをして、顆粒本体を得て、相変化材料を用いて顆粒本体をコード処理し、粒子径が適切な降温顆粒を得るステップ1)と、
製造した降温顆粒を一定のサイズの円柱体、つまり所望の降温フィルタロッドに成形するステップ2)と、を含むか、
又は、
植物繊維粉末及び/又は無機材料粉末を関連する成形補助材料と混合し、造粒、ベーク、篩掛けをして、基礎顆粒を得るステップ1)と、
相変化材料を加熱して溶融し、適量の香味剤を秤量して液体相変化材料に加え、高速で撹拌してせん断し、均一に混合し、混合液体材料を得て、使用に備えるステップ2)と、
ステップ2)で製造した混合液体材料をコード材料として、ステップ1)で製造した基礎顆粒をコード処理し、降温顆粒を得るステップ3)と、
ステップ3)で製造した降温顆粒を硬化成形させ、一定のサイズの円柱体にすると、加香型降温フィルタロッドを得るステップ4)と、を含む。
Preferably, the method for manufacturing the temperature lowering filter rod is
The plant fiber powder and / or the inorganic material powder is mixed with the relevant molding aids and granulated, baked and sieved to give the granule body, then the granule body is coded with a phase change material. Then, in step (1) to obtain the temperature-decreased granules,
The step (2) of obtaining a temperature-decreasing filter rod by curing and molding the temperature-decreasing granules obtained in step (1) is included.
Or,
Thoroughly mix at least one of plant material / inorganic material / metal powder, hot melt adhesive powder, microcrystalline cellulose, pregelatinized starch, water, etc., granulate, dry, sieve and granule. Step 1) to obtain the main body and code the granule main body using a phase change material to obtain a temperature-decreased granule with an appropriate particle size.
Whether to include or include step 2) in which the produced temperature-decreasing granules are formed into a cylinder of a certain size, that is, a desired temperature-decreasing filter rod.
Or,
Step 1) of mixing plant fiber powder and / or inorganic material powder with related molding aids and granulating, baking and sieving to obtain basic granules.
The phase change material is heated and melted, an appropriate amount of flavoring agent is weighed and added to the liquid phase change material, stirred at high speed and sheared, mixed uniformly to obtain a mixed liquid material, and prepared for use. Step 2 )When,
Using the mixed liquid material produced in step 2) as a coding material, the basic granules produced in step 1) are code-treated to obtain temperature-decreased granules, and step 3).
The temperature-decreasing granules produced in step 3) are hard-molded into a cylinder of a certain size to obtain an incense-type temperature-decreasing filter rod, and the like is included.

同じ発明構造に基づき、本発明は、前記降温フィルタロッドのシガレットの生産における使用をさらに提供する。 Based on the same invention structure, the present invention further provides the use of the temperature lowering filter rod in the production of cigarettes.

同じ発明構造に基づき、本発明は、前記降温フィルタロッドを備えるシガレットをさらに提供する。 Based on the same invention structure, the present invention further provides a cigarette with the temperature lowering filter rod.

さらに、シガレットであって、順次接続される発煙部とフィルタを備え、前記フィルタ内には前記降温フィルタロッドが設けられている。 Further, the cigarette is provided with a smoke generating portion and a filter which are sequentially connected, and the temperature lowering filter rod is provided in the filter.

好適には、前記降温フィルタロッドは、通常のフィルタロッドとを一定の割合で組み合わせると、フィルタとして通常のシガレットにも、加熱不燃シガレットにも適用でき、たとえば、2つの通常のフィルタロッドの間に配置されて、3つからシガレットろ過部(フィルタ)が構成され、この場合、すべての高温煙は口腔に入るには降温フィルタロッドを通過することになり、降温効果が確保される。使用のニーズに応じて、さまざまな通常のフィルタロッドが使用される。 Preferably, the temperature lowering filter rod can be applied to both a normal cigarette and a heated non-combustible cigarette as a filter when combined with a normal filter rod in a certain ratio, for example, between two normal filter rods. Arranged, a cigarette filter unit (filter) is configured from three, and in this case, all the high-temperature smoke passes through the temperature lowering filter rod to enter the oral cavity, and the temperature lowering effect is ensured. A variety of regular filter rods are used, depending on the needs of use.

さらに、前記通常のフィルタロッドは、アセテート繊維製フィルタロッド、ポリプロピレン繊維製フィルタロッド、紙質フィルタロッド、中空棒などである。 Further, the ordinary filter rod is an acetate fiber filter rod, a polypropylene fiber filter rod, a paper quality filter rod, a hollow rod, or the like.

従来技術に比べて、本発明の技術案の技術的効果は以下のとおりである。 Compared with the prior art, the technical effect of the technical proposal of the present invention is as follows.

(1)相変化材料を顆粒材料の表面に被覆して降温顆粒を製造し、該降温顆粒を全体として降温フィルタロッドに成形し、通常のフィルタロッドと組み合わせて、直接シガレットの生産に用いる。
(2)相変化材料と降温フィルタロッドの用量により降温効果を制御することができ、形態が簡単で新規であり、この新型フィルタロッドの形態は、工業的生産が実現されやすく、低価であり、降温効果が高い。
(3)パフ抵抗が小さく、煙と相変化材料との接触面積が大きく、降温効率が高く、喫煙者の口腔に入った煙の温度が大幅に低下し、エクスペリエンスが向上する。
(4)香味剤と相変化材料を組み合わせることにより、初めて降温フィルタロッドに加香機能も付与し、その使用価値が大幅に高まる。
(5)降温フィルタロッドの有効空隙率を制御し、非通気の希釈手段を用いて、物理的降温原理に基づいて煙の口腔に入るときの温度を大幅に低下させ、降温の程度が50%以上に達する。
(1) A phase change material is coated on the surface of the granule material to produce temperature-decreasing granules, and the temperature-decreasing granules are formed into a temperature-decreasing filter rod as a whole and used in combination with a normal filter rod for direct cigarette production.
(2) The temperature lowering effect can be controlled by the phase change material and the dose of the temperature lowering filter rod, and the form is simple and novel. The form of this new filter rod is easy to realize industrial production and is inexpensive. , High temperature lowering effect.
(3) The puff resistance is small, the contact area between the smoke and the phase change material is large, the temperature lowering efficiency is high, the temperature of the smoke entering the smoker's mouth is significantly lowered, and the experience is improved.
(4) By combining the flavoring agent and the phase change material, the temperature lowering filter rod is given a fragrance function for the first time, and its utility value is greatly increased.
(5) The effective porosity of the temperature lowering filter rod is controlled, and the temperature when smoke enters the oral cavity is drastically reduced based on the physical temperature lowering principle by using a non-ventilated dilution means, and the degree of temperature lowering is 50%. Reach the above.

以下の実施例は、本発明の内容を説明することを意図し、本発明の特許範囲をさらに限定するものではない。 The following examples are intended to illustrate the content of the invention and do not further limit the scope of the invention.

実施例1
本実施例では、試験過程は、
100~150メッシュのタバコ原料粉末100質量部、変性澱粉20質量部、微結晶性セルロース30質量部を準備し、均一に混合し、水30質量部をスプレーし、均一に混合し、混合軟材を製造するステップ1)と、
上記軟材を押出して球状化により造粒し、ベークして篩掛けし、20~50メッシュのタバコ顆粒を使用に備えるステップ2)と、
PEG1500を溶融した後、タバコ顆粒の質量の10%で製造したタバコ顆粒をコードし、篩掛けして、20~40メッシュのものとして降温タバコ顆粒を得るステップ3)と、
製造した降温タバコ顆粒を連続的にマイクロ波により硬化成形させ、周長23.5mmの多孔質円柱体とし、120mm長の降温フィルタロッドに切断するステップ4)と、
降温フィルタロッドとアセテート繊維部とを10:15の長さ比で組み合わせて、降温部が刻みタバコ側に近くなるようにシガレットに接続し、また、アセテート繊維製フィルタロッドを同じ仕様のシガレットに接続して対照とするステップ5)と、を含む。
2種のフィルタロッド付きのシガレットを点火して吸い、5番目のパフ時のフィルタロッドの出口端の温度をそれぞれ測定し、結果を表1に示す。
Example 1
In this example, the test process is
Prepare 100 parts by mass of 100-150 mesh tobacco raw material powder, 20 parts by mass of modified starch, and 30 parts by mass of microcrystalline cellulose, mix them uniformly, spray 30 parts by mass of water, mix them uniformly, and mix soft materials. 1) and
Step 2), in which the soft material is extruded, granulated by spheroidization, baked and sieved, and 20 to 50 mesh of tobacco granules are prepared for use.
After melting PEG1500, the tobacco granules produced at 10% of the mass of the tobacco granules are encoded and sieved to obtain a cooled tobacco granule as a 20-40 mesh step 3).
The produced temperature-decreasing tobacco granules are continuously cured and molded by microwaves to form a porous cylinder having a circumference of 23.5 mm, and the granules are cut into a temperature-decreasing filter rod having a circumference of 120 mm in step 4).
The temperature lowering filter rod and the acetate fiber part are combined in a length ratio of 10:15 and connected to the cigarette so that the temperature lowering part is closer to the chopped tobacco side, and the acetate fiber filter rod is connected to the cigarette with the same specifications. Step 5), which is used as a control, and the like.
Cigarettes with two types of filter rods are ignited and sucked, and the temperature at the outlet end of the filter rod at the time of the fifth puff is measured, and the results are shown in Table 1.

実施例2
本実施例では、試験過程は、
100~150メッシュのトウモロコシの穂軸粉末80質量部、炭酸カルシウム20質量部、HPMC10質量部、微結晶性セルロース40質量部を準備し、均一に混合し、水25質量部をスプレーし、均一に混合し、混合軟材を製造するステップ1)と、
上記軟材を押出して球状化により造粒し、ベークして篩掛けし、20~50メッシュのトウモロコシの穂軸顆粒を使用に備えるステップ2)と、
質量比が1:1のステアリン酸とペンタエリスリトールを溶融し、トウモロコシの穂軸顆粒の質量の5%で製造したトウモロコシの穂軸顆粒をコードし、篩掛けして、10~50メッシュのものとして降温トウモロコシの穂軸顆粒を得るステップ3)と、
製造した降温トウモロコシの穂軸顆粒を連続して熱硬化成形させ、周長23.5mmの多孔質円柱体とし、84mm長の降温フィルタロッドに切断するステップ4)と、
降温フィルタロッドとアセテート繊維部を7:18の長さ比を組み合わせて、降温部が刻みタバコ側に近くなるようにシガレットに接続し、また、アセテート繊維製フィルタロッドを同じ仕様のシガレットに接続して対照とするステップ5)と、を含む。
2種のフィルタロッド付きのシガレットを点火して吸い、5番目のパフ時のフィルタロッドの出口端の温度をそれぞれ測定し、結果を表1に示す。
Example 2
In this example, the test process is
Prepare 80 parts by mass of 100-150 mesh corn cob powder, 20 parts by mass of calcium carbonate, 10 parts by mass of HPMC, and 40 parts by mass of microcrystalline cellulose, mix them uniformly, and spray 25 parts by mass of water to make them uniform. In step 1) of mixing and producing a mixed soft material,
Step 2), in which the soft material is extruded, granulated by spheroidization, baked and sieved, and 20 to 50 mesh corn cob granules are prepared for use.
Melt stearic acid with a mass ratio of 1: 1 and pentaerythritol to encode and sieve corn cochlear granules produced at 5% of the mass of the maize cochlear granules to form a 10-50 mesh. Step 3) to obtain the cochlear granules of warmed corn,
The produced cob granules of temperature-decreasing corn are continuously thermoset to form a porous cylinder with a circumference of 23.5 mm, which is cut into a temperature-decreasing filter rod of 84 mm in length 4).
Combine the temperature lowering filter rod and the acetate fiber part with a length ratio of 7:18, and connect the temperature lowering part to the cigarette so that it is closer to the chopped tobacco side, and connect the acetate fiber filter rod to the cigarette with the same specifications. Step 5), which is used as a control, and the like.
Cigarettes with two types of filter rods are ignited and sucked, and the temperature at the outlet end of the filter rod at the time of the fifth puff is measured, and the results are shown in Table 1.

実施例3
本実施例では、試験過程は、
100~150メッシュのグレープフルーツピール粉末60質量部、炭素粉末40質量部、変性澱粉20質量部、微結晶性セルロース20質量部、乳糖10質量部を準備し、均一に混合し、水25質量部をスプレーし、均一に混合し、混合軟材を製造するステップ1)と、
上記軟材を押出して球状化により造粒し、ベークして篩掛けし、20~50メッシュの顆粒を使用に備えるステップ2)と、
質量比が1:1:1のPEG3000、パルミチン酸、ステアリン酸-イソプロパノールエステルを溶融し、顆粒の質量の15%で製造した顆粒コード、篩掛けして、20~40メッシュのものとして降温顆粒を得るステップ3)と、
製造した降温顆粒を連続してマイクロ波により硬化成形させ、周長23.5mmの多孔質円柱体とし、120mm長の降温フィルタロッドに切断するステップ4)と、
降温フィルタロッドと紙質中空管部を10:15の長さ比で組み合わせて、降温部が刻みタバコ側に近くなるように低温シガレットに接続し、また、アセテート繊維製フィルタロッドを同じ仕様の低温シガレットに接続して対照とするステップ5)と、を含む。
2種のフィルタロッド付きのシガレットを点火して吸い、5番目のパフ時のフィルタロッドの出口端の温度をそれぞれ測定し、結果を表1に示す。
Example 3
In this example, the test process is
Prepare 60 parts by mass of 100-150 mesh grapefruit peel powder, 40 parts by mass of carbon powder, 20 parts by mass of modified starch, 20 parts by mass of microcrystalline cellulose, and 10 parts by mass of lactose, mix them uniformly, and add 25 parts by mass of water. In step 1) of spraying, mixing evenly, and producing a mixed soft material,
Step 2), in which the soft material is extruded, granulated by spheroidization, baked and sieved, and 20 to 50 mesh granules are prepared for use.
Granule cords prepared by melting PEG3000, palmitic acid, stearic acid-isopropanol ester with a mass ratio of 1: 1: 1 and sieving at 15% of the mass of the granules, sieving into 20-40 mesh granules. Step 3) to get and
The manufactured temperature-decreasing granules are continuously cured and molded by microwave to form a porous cylinder with a circumference of 23.5 mm, which is cut into a temperature-decreasing filter rod of 120 mm in length 4).
The temperature lowering filter rod and the paper hollow tube part are combined in a length ratio of 10:15 and connected to the low temperature cigarette so that the temperature lowering part is closer to the chopped tobacco side, and the acetate fiber filter rod is connected to the low temperature of the same specifications. Step 5), which is connected to a cigarette and used as a control, is included.
Cigarettes with two types of filter rods are ignited and sucked, and the temperature at the outlet end of the filter rod at the time of the fifth puff is measured, and the results are shown in Table 1.

Figure 0007089066000001
Figure 0007089066000001

検出から、本発明による降温フィルタロッドは、顕著な降温効果を奏し、従来のフィルタロッド付きシガレットに比べて、出口端の温度が50%以上低下したことが明らかになった。 From the detection, it was clarified that the temperature lowering filter rod according to the present invention exerted a remarkable temperature lowering effect, and the temperature at the outlet end was lowered by 50% or more as compared with the conventional cigarette with a filter rod.

実施例4
本実施例では、試験過程は、
100~150メッシュのタバコ原料粉末100質量部、変性澱粉20質量部、微結晶性セルロース30質量部を準備し、均一に混合し、水30質量部をスプレーし、均一に混合し、混合軟材を製造するステップ1)と、
混合軟材を押出して球状化により造粒し、ベークして篩掛けし、20~50メッシュの降温顆粒コアを使用に備えるステップ2)と、
PEG2000を加熱して溶融し、質量比100:0.5でメントンと均一に混合し、混合液体材料を得るステップ3)と、
降温顆粒の質量の10%で上記混合液体材料を用いて、製造した降温顆粒コアをコード処理し、篩掛けして、30~50メッシュのものとしてメントン含有降温顆粒を得るステップ4)と、
製造した降温顆粒を連続してマイクロ波により硬化成形させ、周長23.5mmの多孔質円柱体とし、120mm長の降温フィルタロッド部に切断するステップ5)と、
降温フィルタロッド部とアセテート繊維部を10:15の長さ比で組み合わせて、降温部が刻みタバコ側に近くなるようにシガレットに接続し、また、アセテート繊維製フィルタロッドを同じ仕様のシガレットに接続して対照とするステップ6)と、を含む。
2種のフィルタロッド付きのシガレットを点火して吸い、5番目のパフ時のフィルタロッドの出口端の温度をそれぞれ測定し、検出結果を表2に示し、また、2種のシガレットを吸って比較して評価し、結果を表3に示す。
Example 4
In this example, the test process is
Prepare 100 parts by mass of 100-150 mesh tobacco raw material powder, 20 parts by mass of modified starch, and 30 parts by mass of microcrystalline cellulose, mix them uniformly, spray 30 parts by mass of water, mix them uniformly, and mix soft materials. 1) and
Step 2), in which the mixed soft material is extruded, granulated by spheroidization, baked and sieved, and a 20-50 mesh de-heated granule core is prepared for use.
PEG2000 is heated and melted and mixed uniformly with Menthone at a mass ratio of 100: 0.5 to obtain a mixed liquid material.
Using the above mixed liquid material at 10% of the mass of the temperature-decreasing granules, the produced temperature-decreasing granule core is code-treated and sieved to obtain menthone-containing temperature-decreasing granules as 30 to 50 mesh.
The manufactured temperature-decreasing granules are continuously cured and molded by microwaves to form a porous cylinder with a circumference of 23.5 mm, which is cut into a temperature-decreasing filter rod portion of 120 mm in length 5).
The temperature lowering filter rod part and the acetate fiber part are combined in a length ratio of 10:15 and connected to the cigarette so that the temperature lowering part is closer to the chopped tobacco side, and the acetate fiber filter rod is connected to the cigarette with the same specifications. And as a control, step 6) and.
Ignite and suck cigarettes with two types of filter rods, measure the temperature at the outlet end of the filter rod at the fifth puff, and show the detection results in Table 2, and also suck and compare the two types of cigarettes. The results are shown in Table 3.

実施例5
本実施例では、試験過程は、
100~150メッシュのトウモロコシの穂軸粉末80質量部、炭酸カルシウム20質量部、HPMC10質量部、微結晶性セルロース40質量部を準備し、均一に混合し、水25質量部をスプレーし、均一に混合し、混合軟材を製造するステップ1)と、
上記混合軟材を押出して球状化により造粒し、ベークして篩掛けし、20~50メッシュの降温顆粒コアを使用に備えるステップ2)と、
質量比が1:1のステアリン酸とペンタエリスリトールを加熱して溶融し、質量比100:5でタバコ抽出物と均一に混合し、混合液体材料を得るステップ3)と、
降温顆粒の質量の5%で上記混合液体材料を用いて、製造した降温顆粒をコード処理し、篩掛けして、20~40メッシュのものとしてタバコ抽出物含有の加香型降温顆粒を得るステップ4)と、
製造した降温顆粒を連続して熱硬化成形させ、周長23.5mmの多孔質円柱体とし、84mm長の降温フィルタロッド部に切断するステップ5)と、
降温フィルタロッド部とアセテート繊維部を7:18の長さ比で組み合わせて、降温部が刻みタバコ側に近くなるようにシガレットに接続し、また、アセテート繊維製フィルタロッドを同じ仕様のシガレットに接続して対照とするステップ6)と、を含む。
2種のフィルタロッド付きのシガレットを点火して吸い、5番目のパフ時のフィルタロッドの出口端の温度をそれぞれ測定し、結果を表2に示し、また、2種のシガレットを吸って比較して評価し、結果を表3に示す。
Example 5
In this example, the test process is
Prepare 80 parts by mass of 100-150 mesh corn cob powder, 20 parts by mass of calcium carbonate, 10 parts by mass of HPMC, and 40 parts by mass of microcrystalline cellulose, mix them uniformly, and spray 25 parts by mass of water to make them uniform. In step 1) of mixing and producing a mixed soft material,
Step 2), in which the mixed soft material is extruded, granulated by spheroidization, baked and sieved, and a 20 to 50 mesh temperature-decreasing granule core is prepared for use.
Step 3), in which stearic acid having a mass ratio of 1: 1 and pentaerythritol are heated and melted and uniformly mixed with the tobacco extract at a mass ratio of 100: 5 to obtain a mixed liquid material.
Using the above mixed liquid material at 5% of the mass of the temperature-decreasing granules, the produced temperature-decreasing granules are code-treated and sieved to obtain aroma-type temperature-decreasing granules containing tobacco extract as 20-40 mesh. 4) and
The manufactured temperature-decreasing granules are continuously thermosetting to form a porous cylinder having a circumference of 23.5 mm, and the granules are cut into a temperature-decreasing filter rod portion having a circumference of 84 mm in step 5).
The temperature lowering filter rod part and the acetate fiber part are combined in a length ratio of 7:18, and the temperature lowering part is connected to the cigarette so that it is closer to the chopped tobacco side, and the acetate fiber filter rod is connected to the cigarette with the same specifications. And as a control, step 6) and.
Ignite and suck cigarettes with two types of filter rods, measure the temperature at the outlet end of the filter rod at the fifth puff, and show the results in Table 2, and also suck and compare the two types of cigarettes. The results are shown in Table 3.

実施例6
本実施例では、試験過程は、
100~150メッシュのグレープフルーツピール粉末60質量部、炭素粉末40質量部、変性澱粉20質量部、微結晶性セルロース20質量部、乳糖10質量部を準備し、均一に混合し、水25質量部をスプレーし、均一に混合し、混合軟材を製造するステップ1)と、
上記混合軟材を押出して球状化により造粒し、ベークして篩掛けし、20~50メッシュの降温顆粒コアを使用に備えるステップ2)と、
質量比が1:1:1のPEG3000、パルミチン酸、ステアリン酸-イソプロパノールエステルを加熱して溶融し、質量比100:2でコーヒーフレーバーと均一に混合し、混合液体材料を得るステップ3)と、
降温顆粒の質量の15%で上記混合液体材料を用いて、製造した降温顆粒コアをコード処理し、篩掛けして、20~40メッシュのものとして降温顆粒を得るステップ4)と、
製造した降温顆粒を連続してマイクロ波により硬化成形させ、周長23.5mmの多孔質円柱体とし、120mm長の降温フィルタロッド部に切断するステップ5)と、
降温フィルタロッド部と紙質中空管部を10:15の長さ比で組み合わせて、降温部が刻みタバコ側に近くなるように低温シガレットに切断し、また、アセテート繊維製フィルタロッドを同じ仕様の低温シガレットに接続して対照とするステップ6)と、を含む。
2種のフィルタロッド付きのシガレットを点火して吸い、5番目のパフ時のフィルタロッドの出口端の温度をそれぞれ測定し、結果を表2に示し、また、2種のシガレットを吸って比較して評価し、結果を表3に示す。
Example 6
In this example, the test process is
Prepare 60 parts by mass of 100-150 mesh grapefruit peel powder, 40 parts by mass of carbon powder, 20 parts by mass of modified starch, 20 parts by mass of microcrystalline cellulose, and 10 parts by mass of lactose, mix them uniformly, and add 25 parts by mass of water. In step 1) of spraying, mixing evenly, and producing a mixed soft material,
Step 2), in which the mixed soft material is extruded, granulated by spheroidization, baked and sieved, and a 20 to 50 mesh temperature-decreasing granule core is prepared for use.
Step 3) to heat and melt PEG3000, palmitic acid, stearic acid-isopropanol ester with a mass ratio of 1: 1: 1 and mix uniformly with coffee flavor at a mass ratio of 100: 2 to obtain a mixed liquid material.
Using the above mixed liquid material at 15% of the mass of the temperature-decreased granules, the produced temperature-decreased granule core is code-treated and sieved to obtain a temperature-decreased granule having a mesh of 20 to 40 mesh 4).
The manufactured temperature-decreasing granules are continuously cured and molded by microwaves to form a porous cylinder with a circumference of 23.5 mm, which is cut into a temperature-decreasing filter rod portion of 120 mm in length 5).
The temperature lowering filter rod part and the paper hollow tube part are combined at a length ratio of 10:15, cut into low temperature cigarettes so that the temperature lowering part is closer to the chopped tobacco side, and the acetate fiber filter rod has the same specifications. Step 6), which is connected to a low temperature cigarette and used as a control, is included.
Ignite and suck cigarettes with two types of filter rods, measure the temperature at the outlet end of the filter rod at the fifth puff, and show the results in Table 2, and also suck and compare the two types of cigarettes. The results are shown in Table 3.

Figure 0007089066000002
Figure 0007089066000002

検出したところ、本発明による降温フィルタロッドには、非常に明らかな降温効果があることが明らかになった。 Upon detection, it was revealed that the temperature lowering filter rod according to the present invention has a very clear temperature lowering effect.

Figure 0007089066000003
Figure 0007089066000003

上記実施例で記載された内容については、これらの実施例が本発明を明確に説明するために過ぎず、本発明の範囲を制限しないとみなされるべきであり、当業者が本発明を閲覧して本発明に対して行うさまざまな同等の形態の修正はすべて本願の添付の特許請求の範囲により制限される範囲に属するものとする。 With respect to the content described in the above examples, it should be considered that these examples are merely for the purpose of clearly explaining the present invention and do not limit the scope of the present invention, and those skilled in the art will browse the present invention. All of the various equivalent modifications made to the present invention shall fall within the scope of the claims of the present application.

Claims (10)

降温フィルタロッドであって、
主に降温顆粒を硬化成形させてなり、前記降温顆粒は顆粒本体と顆粒本体に被覆されたシェル層とを含み、シェル層は相変化材料を含み、
前記相変化材料は、ポリエチレングリコール、ステアリン酸、パルミチン酸、パラフィン、微結晶ワックス、EVA、ペンタエリスリトール、ステアリン酸-イソプロパノールエステル、ステアリン酸-グリセロールトリエステルのうちの少なくとも1種を含む、ことを特徴とする降温フィルタロッド。
It is a temperature lowering filter rod
The temperature-decreasing granules are mainly cured and molded, and the temperature-decreasing granules include a granule body and a shell layer coated on the granule body, and the shell layer contains a phase change material.
The phase change material comprises at least one of polyethylene glycol, stearic acid, palmitic acid, paraffin, microcrystalline wax, EVA, pentaerythritol, stearic acid-isopropanol ester, stearic acid-glycerol triester . Characterized temperature lowering filter rod.
前記シェル層は香味剤をさらに含み、前記香味剤は、香料及び/又はタバコ抽出物を含み、前記相変化材料と香味剤との質量比が100:(0.5~10)である、ことを特徴とする請求項1に記載の降温フィルタロッド。 The shell layer further contains a flavoring agent, the flavoring agent contains a flavoring and / or a tobacco extract, and the mass ratio of the phase changing material to the flavoring agent is 100: (0.5 to 10). The temperature lowering filter rod according to claim 1, wherein the temperature lowering filter rod is characterized by the above. 前記シェル層の質量が降温顆粒の総質量の0.5~30%を占める、ことを特徴とする請求項1に記載の降温フィルタロッド。 The temperature lowering filter rod according to claim 1, wherein the mass of the shell layer occupies 0.5 to 30% of the total mass of the temperature lowering granules. 前記顆粒本体は、植物繊維粉末及び/又は無機材料粉末を含み、前記植物繊維粉末は、タバコ粉末、トウモロコシの穂軸粉末、籾殻粉末、クルミ殻粉末、ココナッツの殻粉末、乾燥みかん皮の粉末、グレープフルーツピール粉末のうちの少なくとも1種を含み、前記無機材料粉末は、炭酸カルシウム、炭素粉末、セラミック、シリカゲル、分子篩のうちの少なくとも1種を含み、前記顆粒本体は、成形補助材料をさらに含み、前記成形補助材料は粘着剤、湿潤剤、賦形補助材料のうちの少なくとも1種を含む、ことを特徴とする請求項1に記載の降温フィルタロッド。 The granule body contains a plant fiber powder and / or an inorganic material powder, and the plant fiber powder includes tobacco powder, corn cob powder, rice husk powder, walnut husk powder, coconut husk powder, and dried tangerine peel powder. The inorganic material powder contains at least one of calcium carbonate, carbon powder, ceramic, silica gel, and molecular sieve, and the granule body contains a molding auxiliary material. The temperature lowering filter rod according to claim 1, further comprising, wherein the molding auxiliary material contains at least one of a pressure-sensitive adhesive, a wetting agent, and a shaping auxiliary material. 前記顆粒本体は、基体粉末、ホットメルト接着剤粉末、賦形剤、水を十分に混合した後、造粒、乾燥、篩分けをして得るものであり、前記基体粉末は、植物材料、無機材料、金属粉末のうちの少なくとも1種を含み、前記植物材料は、タバコ原料、わら、ピーナッツの殻、バガス、トウモロコシの穂軸、果皮、香料植物のうちの少なくとも1種を含み、前記無機材料は、炭粉、粘土、炭酸カルシウム、酸化ケイ素のうちの少なくとも1種を含み、前記金属粉末は、鉄粉、アルミナ、銅粉のうちの少なくとも1種を含む、ことを特徴とする請求項1に記載の降温フィルタロッド。 The main body of the granules is obtained by thoroughly mixing a substrate powder, a hot melt adhesive powder, an excipient, and water, and then granulating, drying, and sieving. The substrate powder is a plant material or an inorganic substance. The plant material comprises at least one of a material, a metal powder, and the plant material comprises at least one of tobacco raw material, straw, peanut shell, bagus, corn cob, peel, fragrance plant and said inorganic. The material is characterized by comprising at least one of charcoal powder, clay, calcium carbonate and silicon oxide, and the metal powder containing at least one of iron powder, alumina and copper powder. The temperature lowering filter rod according to 1. 前記降温顆粒の粒子径が10~50メッシュである、ことを特徴とする請求項1~のいずれか1項に記載の降温フィルタロッド。 The temperature lowering filter rod according to any one of claims 1 to 5 , wherein the temperature lowering granules have a particle size of 10 to 50 mesh. 前記降温フィルタロッドの内部の有効空隙率が65~95%である、ことを特徴とする請求項1~のいずれか1項に記載の降温フィルタロッド。 The temperature lowering filter rod according to any one of claims 1 to 5 , wherein the effective porosity inside the temperature lowering filter rod is 65 to 95%. 前記降温顆粒が加熱不燃シガレットに用いられる場合、造粒方法は、押出・球状化造粒法であり、前記降温顆粒は球形又は略球形であり、かさ密度が0.8~2.5g/mlである、ことを特徴とする請求項に記載の降温フィルタロッド。 When the temperature-decreasing granules are used for a heated non-combustible cigarette, the granulation method is an extrusion / spheroidizing granulation method, the temperature-decreasing granules are spherical or substantially spherical, and the bulk density is 0.8 to 2.5 g / ml. The temperature lowering filter rod according to claim 6 , wherein the temperature lowering filter rod is characterized by the above. 前記降温顆粒が通常のシガレットに用いられる場合、前記降温顆粒は球形又は不定形であり、かさ密度が0.4~1.6g/mlである、ことを特徴とする請求項に記載の降温フィルタロッド。 The temperature reduction according to claim 6 , wherein when the temperature lowering granules are used for a normal cigarette, the temperature lowering granules are spherical or amorphous and have a bulk density of 0.4 to 1.6 g / ml. Filter rod. 請求項1~のいずれか1項に記載の降温フィルタロッドを備えることを特徴とするシガレット。 A cigarette comprising the temperature lowering filter rod according to any one of claims 1 to 9 .
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