JP7031836B2 - Aqueous makeup remover composition - Google Patents

Description

Article 30, Paragraph 2 of the Patent Act Applicable Date of publication announced through telecommunication lines January 26, 2017 Publication address http: // www. Kracie. co. jp / release / 10131418_3833. html

The present invention relates to an aqueous makeup remover composition for removing makeup stains, and more particularly, polyoxyethylene (caprylic acid / capric acid) glyceryl having an average added molar number of ethylene oxide of 6 to 8 is 3.0. ~ 5.0% by mass, sodium glutamate, sodium hydrogencarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, tartrate acid , One or more selected from citric acid and water, the slope of the linear function obtained from the L * value at 50 ° C ± 2 ° C and the L * value at 23 ° C ± 2 ° C is greater than 10 89 The present invention relates to an aqueous makeup remover composition having the following characteristics, which is excellent in makeup remover and storage stability.

Conventionally, a cleansing composition that removes makeup contains a surfactant oil solution type in which a surfactant is dissolved in an oil agent and a small amount of water in order to remove hard-to-remove eye makeup and lipstick from the skin. So-called cleansing oils such as reverse micelle oil solution type are the mainstream (for example, Patent Document 1). However, while cleansing oil is difficult to remove and has an excellent makeup removing effect, there is a problem that an oil film remains on the skin when it is washed away, and a refreshing feel cannot be obtained unless it is washed again with a facial cleanser. Furthermore, since the oil of cleansing oil is compatible with the sebum of the skin, it removes even the sebum necessary for washing, and the skin feels dry after use, which causes a heavy burden on the skin.

On the other hand, in recent years, the trend of light make-up that emphasizes natural skin feeling, the female consciousness that wants to remove the entire face gently, and the lifestyle of women who are busy with child-rearing and work, etc. Makeup remover compositions that remove water-based makeup that can be easily refreshed by wiping or rinsing are becoming mainstream.

Specifically, it is wiped off containing a nonionic surfactant and an unneutralized anionic surfactant (for example, Patent Document 2), polyoxyethylene fatty acid glyceryl 3 to 10% by mass, and amphoteric surfactant. A water-based wipe cleansing cosmetic containing 0.005 to 2% by mass of the agent (for example, Patent Document 3) has been proposed.

However, although it is proposed that these aqueous cleansing cosmetics have good make-up removal by combining two or more kinds of surfactants, the make-up removal function is not sufficient and the storage stability is stable. It did not sufficiently solve the problem of compatibility with sex.

Japanese Patent No. 4757446 Japanese Unexamined Patent Publication No. 2011-37782 Japanese Unexamined Patent Publication No. 2014-201561

The present invention has been made in view of the above circumstances, and by controlling the size of micelles of one type of surfactant and efficiently using the surfactant, the present invention is compared with the conventional aqueous detergent composition. The present invention is to provide an aqueous makeup remover composition having excellent makeup remover and storage stability.

As a result of diligent research to achieve the object of the present invention, the present inventors have obtained polyoxyethylene (caprylic acid / capric acid) glyceryl having an average addition molar number of 6 to 8 of ethylene oxide from 3.0 to 3.0. 5.0% by mass, sodium glutamate, sodium hydrogencarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, tartaric acid, The slope of the linear function obtained from one or more selected from citric acid and water, and the L * value at 50 ° C ± 2 ° C and the L * value at 23 ° C ± 2 ° C is greater than 10 and 89 or less. It has been found that the aqueous makeup remover composition characterized by the above is excellent in makeup remover and storage stability, and the present invention has been completed.

That is, the present invention contains the following components (A), component (B), and water, and is a linear function obtained from the L * value at 50 ° C. ± 2 ° C. and the L * value at 23 ° C. ± 2 ° C. A water-based makeup remover composition having an inclination of more than 10 and 89 or less.
Component (A) Polyoxyethylene (caprylic acid / capric acid) glyceryl 3.0 to 5.0% by mass with an average number of moles of ethylene oxide added of 6 to 8.
Ingredients (B) From sodium glutamate, sodium hydrogencarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, tartaric acid, citric acid One or more selected

The water-based makeup remover composition of the present invention has the effect of maximizing the makeup-removing effect of one type of surfactant and being excellent in removing makeup stains, as compared with the conventional water-based detergent composition. Play.

It is a graph which shows the linear function obtained from the L * value of the solution at the time of 50 degreeC ± 2 degreeC, and the L * value at the time of 23 degreeC ± 2 degreeC of Examples 1 and commercial products 1-4 of this invention.

Here, the L * value is a measure of the degree of turbidity, and is when purified water is put into a glass cell and light is transmitted using a color meter ZE6000 (manufactured by Nippon Denshoku Kogyo Co., Ltd.). It is a value when the transparency is set to 100 and the transparency when the light is completely blocked and there is no transmitted light is set to 0.

Hereinafter, the aqueous makeup remover composition of the present invention will be described in detail.

As the component (A) of the present invention, 3.0 to 5.0% by mass of polyoxyethylene (caprylic acid / capric acid) glyceryl having an average addition molar number of ethylene oxide of 6 to 8 is used. In the aqueous cleansing cosmetic of the present invention, when the component (A) is less than 3.0% by mass, the solubility in water is poor and the make-up removal is not good. On the other hand, when it is 5.0% by mass or more, the amount of the surfactant is large and the burden on the skin becomes large.

The component (B) of the present invention is sodium glutamate, sodium hydrogencarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, Examples include tartrate acid and citric acid. As these components (B), one kind may be used alone, or two or more kinds may be used in combination as appropriate.

The component (B) used in the present invention is used to control the size of micelles in a solution, keeps the size of micelles stable in a temperature range normally used, and thereby obtains a good makeup stain removing effect. It is used from the viewpoint of.

By using the component (B) used in the present invention, the slope of the linear function obtained from the L * value of the solution at 50 ° C. ± 2 ° C. and the L * value at 23 ° C. ± 2 ° C. is larger than 10. It may be 89 or less. The linear function is obtained when X is 50 ° C. ± 2 ° C., 23 ° C. ± 2 ° C., and Y is an L * value.

When the slope of this linear function is greater than 10 and in the range of 89 or less, the surfactant micelle in the aqueous makeup remover composition of the present invention has a size that improves makeup removal and storage stability. When the gradient of the linear function is 10 or less, the micellar size at 23 ° C ± 2 ° C becomes relatively small, so that make-up removal at 23 ° C ± 2 ° C becomes worse, and when the gradient of the linear function is larger than 89, Since the micelle size at 50 ° C. ± 2 ° C. becomes relatively large, the stability at 50 ° C. ± 2 ° C. may deteriorate and separation may occur.

In addition to the above-mentioned components, the cleaning composition of the present invention contains other components, such as physiologically active components, antioxidants, sequestrants, preservatives, and UV absorbers, as long as the object of the present invention is not impaired. , Fragrances, moisturizers, salts, solvents, neutralizers, insect repellents, enzymes and the like can be appropriately blended.

Examples of the bioactive component include substances that give some bioactivity to the skin when applied to the skin. For example, anti-inflammatory agents, anti-aging agents, UV protection agents, tightening agents, antioxidants, moisturizers, blood circulation promoters, antibacterial agents, bactericidal agents, desiccants, cooling agents, warming agents, vitamins, amino acids, Wound healing promoters, stimulant relievers, analgesics, cell activators, enzyme components and the like can be mentioned. Examples of the bioactive component include natural plant extract components, seaweed extract components, crude drug components, compounds, etc. Among these, natural plant extract components, seaweed extract components, and crude drug components are particularly safe. Preferred in terms of points.

Examples of the above-mentioned natural plant extract component, seaweed extract component, and raw medicine component include, for example, Ashitaba extract, Amacha extract, Artea extract, Aloe extract, Anzu extract, Ginkgo extract, Wikyo extract, Woolong tea extract, Agetsu extract, Ogon extract, Oubaku extract, Otogirisou extract, Dutch mustard extract, orange extract, dried seawater, seaweed extract, hydrolyzed wheat powder, hydrolyzed silk, chamomile extract, carrot extract, kawarayomogi extract, licorice extract, kakyoku extract, kiwi extract, cucumber extract, Kuchinashi extract, Kumazasa extract, Clara extract, Walnut extract, Grapefruit extract, Chlorella extract, Kuwa extract, Tea extract, Yeast extract, Collagen, Salvia extract, Sabonsou extract, Sanzashi extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shakuyaku extract, White hippo extract, sugina extract, sardine extract, sardine extract, sardine extract, sardine extract, sardine extract, sage extract, senkyu extract, senburi extract, soybean extract, taiso extract, thyme extract, tea extract, chowji extract, chimpi extract , Touki extract, Tounin extract, Dokudami extract, Tomato extract, Natto extract, Carrot extract, Garlic extract, Novara extract, Honey, Hamamelis extract, Hikiokoshi extract, Visabolol, Biwa extract, Bukuryo extract, Propolis, Hechima extract, Peppermint extract, Bodaiju extract, Hop Examples thereof include extract, madonna lily flower extract, marronnier extract, mukuroji extract, melissa extract, peach extract, yukinoshita extract, yuzu extract, yomogi extract, lavender extract, lemon extract, lotus soybean extract, rosemary extract, royal jelly extract and the like.

Natural fragrances include amiris oil, ambrette seed oil, ylang ylang oil, ylang ylang absolute, iris resinoid, iris absolute, iris oil, winter green oil, estragon oil, elemioleoledin, elemiresinoid absolute, elemitinki, oak moss concrete. , Oak Moss Absolute, Oak Moss Resin, Oak Moss Reginoid, Osmanthus Absolute, Osmanthus Concrete, Opopanax Resinoid, Opopanax Absolute, Opopanax Oil, Olivevanum Reginoid, Olivanum Absolute, Olivernum Oil, All Spice Oil, Olegano Oil, Olegano Ole Oledin, Orange Oil, Orange Flower Absolute, Orange Flower Concrete, Kananga Oil, Garjun Balsam, Garjun Balsam Oil, Cassie Absolute, Cassie Flower Oil, Cassia Oil, Gardenia Absolute, Carnation Absolute, Cabreva Oil , Camomill oil, cardamon oil, galvanum oil, galvanum resin, galvanum resinoid, caraway seed oil, carrot seed oil, cubeba oil, guayak wood oil, guayak resin, guayak concrete, kusunoki oil, cumin oil, cumin absolute, cumin oleole Gin, Clarisage Oil, Grapefruit Oil, Clove Oil, Costas Oil, Copai Babalsam, Copai Babalsam Oil, Copai Babalsam Resin, Coriander Oil, Sandalwood Oil, Sisso Oil, Cedarwood Oil, Citronella Oil, Jasmine Oil, Jasmine Absolute, Jasmine Concrete, Juniper Berry oil, Gene absolute, John Kill absolute, Ginger oil, Cinnamon oil, Cinnamon bark oil, Cinnamon leaf oil, Sugi oil, Staranis oil, Stilax oil, Stilax resinoid, Spike lavender oil, Spare mint oil, Savory oil, Sage oil, Cedar oil, cedar leaf oil, geranium oil, celery seed oil, thyme oil, tagget oil, tangerine oil, tuberose absolute, tea tree oil, tree Moss Absolute, Tonka Bean Oil, Trubal Sam, Natsumeg Oil, Narcissus Absolute, Neroli Oil, Violet Leaf Absolute, Pine Oil, Pine Needle Oil, Basil Oil, Parsley Leaf Oil, Parsley Seed Oil, Parsley Herb Oil, Pachori Oil, Hacker Oil, Vanilla Absolute, Honeysuckle Absolute, Palmarosa Oil, Valerian Oil, Bitter Orange Oil, Hisop Oil, Hiba Oil, Hinoki Oil, Hyacinth Absolute, Fennel Oil, Figabsolute, Petit Glen Oil, Butch Oil, Bay Oil, Vetiva Oil, Pepper Oil, Pepper Mint Absolute , Peppermint oil, Bergamot oil, Peruvian balsam, benzoin tincture, benzoin resinoid, peppermint oil, marjoram oil, mandarin oil, orange oil, mimosa concrete, mimosa absolute, mimosa oil, mill resinoid, mill absolute, mill oil, musk absolute, musktinki, Eucalyptus oil, yuzu oil, lime oil, lovedanum oil, lovedanum resinoid, lavender oil, lavender absolute, lavandin oil, lavandin absolute, lemon oil, lemongrass oil, rose oil, rose absolute, rose concrete, rosemary oil, laurel oil , Laurel leaf oil and the like.

Synthetic fragrances include ambredlide, aldehydes C6 to C12, anisaldehyde, acetal R, acetophenone, acetylsedrene, adxal, allylamylglycolate, allylcyclohexanepropionate, ambroxane, amilcinnamic aldehyde, and amylcinnamic. Aldehyde dimethyl acetal, amylvalerianate, amylsalicylate, acetyleugenol, isoamylacetate, isoamylsalicylate, indol, ionone, isobornylacetate, isocyclocitral, isoE super, isooigenol, isononylacetate, isobutylquinolin, γ-un Decalactone, ethylene brush rate, ethylene dodecandioate, ethyl wanillin, 2-ethylhexanol, aulanthiol, 10-oxahexadecanolide, 11-oxahexadecanolide, 12-oxahexadecanolide, oxahexadecene-2 -On, Eugenol, Oribbon, Oxypheniron, Galaxolide, Cariophyllene, Cashmerelan, Carvone, β-Cariophyllene, Caron, Cmarin, p-Cresyl Methyl Ether, Geraniol, Geranyl Acetate, Geranyl Formate, Geranyl nitrile, Corebon, Sandaroa, Sandera, Santalex, Synamic Alcohol, Synamic Aldehyde, Sisjasmon, Citral, Citral Dimethyl Acetal, Citrasar, Citroneral, Citronerol, Citroneryl Acetate, Citroneryl Formate, Citroneryl nitrile, Cyclaset, Cyclamenaldehyde, Cyclaprop, Dimethylbenzyl carbinol, dihydrojasmon, dihydrolinalol, dihydromilsenol, dimethol, dimilsetol, diphenyloxide, jasmar, jasmolactone, jasmophyllan, cinnamylacetate, cyclopentadecanone, cyclohexadecanoli, cyclopentadecanoli Do, cyclohexadecanolide, dimethylbenzyl carvinyl acetate, jasmacyclene, styralyl acetate, stylaryl propionate, sedro amber, sedrill acetate, sedrol, cerestrid, α-damascon, β-damascon, δ-Damascon, Damasenone, Tarpineol, Tarpinylacetate, Timor, Tetrahydrolinalol, Tetrahydrolinalylace Tate, Tetrahydrogeraniol, Tetrahydrogeranyl Acetate, Tonalid, Tratheolide, Triplar, Neryl Acetate, Nerol, Neobergamate, γ-Nonalactone Nopill Alcohol, Nopill Acetate, Bacdanol, Hydrotropic Alcohol, α-Pinen, β-Pinen, Hydroxycitroneral, hyacinthdimethylacetal, butylbutyrate, pt-butylcyclohexanol, pt-butylcyclohexanol, ot-butylcyclohexanol, ot-butylcyclohexylacetate, fluorite, fentyl alcohol , Phenylethyl phenylacetate, phenylethyl acetate, pentalid, veldox, benzyl acetate, benzyl alcohol, benzyl salicylate, bergamil acetate, benzaldehyde, benzylformate, hedion, helional, heliotropin, cis-3-hexenol, cis-3 -Hexenil acetate, cis-3-Hexenil salicylate, hexyl cinnamic aldehyde, hexyl salicylate, Bornyl acetate, Borneol, Manzanate, Mayor, Milsen, Millac aldehyde, Mugaldehyde, Mugor, Musk TM-11, Musk 781, Musk C14, Muscon, Musk Ketone, Musc Tivetin, Mensanil Acetate, Mensonate, Methyl Anthranilate, Methyl Eugenol, Mentor, α-Methyl Ionone, β-Methyl Ionone, γ-Methyl Ionone, Methyl Isooigenol, Methyl Lavender Ketone, Methyl Salicylate, 14-Methyl-hexadecenolide, 14-methyl-hexadecanolide, methylnaphthylketone, methylphenylacetate, yarayara, δ-C6-C13 lactone, lime oxide, γ-C6-C13 lactone, raspberry ketone, limonene, ligstraal, lilial, linalol, linalol Examples thereof include oxides, linalyl acetates, lylars, ruvafrans, rose phenones, rose oxides and wanillins.

As a blended fragrance that combines fragrance components, there are the following fragrance-like bases. Citrus type bass such as lemon, lime, orange, sweet orange, mandarin, bergamot, petitgrain, neroli, lemongrass, agourmet, etc., fresh type bass, apple, peach, strawberry Fruity type bass such as tone, coconut tone, pineapple tone, raspberry tone, water melon tone, grape tone, mango tone, fruit mix tone, tropical fruit tone, rose tone, jasmine tone, muguet tone, lilac tone, carnation tone, hyacinth Floral type bass such as tone, tuberose tone, gardenia tone, mimosa tone, narcisus tone, violet tone, Iran tone, floral bouquet tone, cinnamon bark tone, cinnamon leaf tone, clove tone, pimentoberry tone, nutmeg tone, pepper tone, Cardamom-like, coriander-like, cumin-like spicy type bass, cedarwood-like, vetiver-like, sandalwood-like, guaiacwood-like, woody bar-like, woody-iris-like woody type bass, smoky-like, quinoline-like leather Sweet type base such as type, vanilla style, tonka style, honey style, pure balsam style, other butter flavor, milk flavor, aldeheidic type base, amber type base, animal type base, anis type base, aromatic herbal type base , Agar type base, aqua type base, camphor cineole type base, green type base, seed type base, herb type base, pine type base, patchouli type base, balsamic type base, mint type base, musk type base, moss type base, Examples include lavender type base, linalool type base, and resin type base.

Further, diethyl phthalate, dipropylene glycol, benzyl benzoate, isopropyl myristate, harcholine, isopentane, orange terpene and the like can be used as a solvent or a fixative for the fragrance.

Examples of components other than the above-mentioned natural plant extract component, seaweed extract component, and biopharmaceutical component include deoxyribonucleic acid, mucopolysaccharide, sodium hyaluronate, sodium chondroitin sulfate, collagen, elastin, chitin, chitosan, and hydrolyzed eggshell membrane. Biopolymers such as amino acids, amino acids, sodium lactate, urea, sodium pyrrolidone carboxylate, betaine, moisturizing ingredients such as whey, oily ingredients such as sphingolipids, ceramides, cholesterol, cholesterol derivatives, phospholipids, ε-aminocaproic acid, glycyrrhizinic acid , Β-Glycyrrhetinic acid, lysoteam chloride, guaiazulene, hydrocortisone and other anti-inflammatory agents, vitamins (A, B2, B6, C, D, E), calcium pantothenate, biotin, nicotinic acid amide, vitamin C ester and other vitamins , Allantin, active ingredients such as diisopropylamine dichloroacetate, 4-aminomethylcyclohexanecarboxylic acid, antioxidants such as tocopherol, carotinoid, flavonoid, tannin, lignan, saponin, cells such as α-hydroxy acid and β-hydroxy acid. Activator, blood circulation promoter such as γ-orizanol, vitamin E derivative, bactericidal agent such as isopropylmethylphenol, triclosan, hinokithiol, benzalconium chloride, cold sensitizer such as l-menthol, peppermint oil, retinol, retinol derivative, etc. Wound healing agents and the like can be mentioned.

Each aromatic water, plant water, hot spring water, etc. can be appropriately included.

Further, it is preferable that the aqueous makeup remover composition of the present invention does not substantially contain a lower alcohol, a water-soluble polyhydric alcohol or a sugar alcohol.

The aqueous makeup remover composition of the present invention can be used without rinsing after wiping, or may be used for rinsing. Preferred usage methods include impregnating cotton, tissue paper, non-woven fabric, etc. with a water-based cleansing cosmetic and applying the water-based makeup remover composition to the application site, cotton, tissue paper, non-woven fabric, etc. An example of a method of wiping with a cloth can be exemplified.

Next, the aqueous makeup remover composition of the present invention will be described in detail with reference to Examples, but the present invention is not limited thereto. In addition, the compounding amount in all the following Examples and Comparative Examples is mass%.

The test methods of the sensory test and the storage stability test carried out in Examples 1 to 15 and Comparative Examples 1 to 4 are shown below.

<Makeup removal evaluation test>
Twenty panelists applied lipstick (Shiseido Integrate Gracy Lipstick Red 465) to their faces in an environment of room temperature of 23 ° C, left it for 30 minutes, and then impregnated cotton with the aqueous makeup remover compositions of Examples and Comparative Examples. I wiped it off and used it. The make-up removal at that time was evaluated on a 5-point scale, and further judged from the average score according to the following criteria.

<5-grade evaluation>
5 points: Very good 4 points: Good 3 points: Normal 2 points: Slightly bad 1 point: Bad

<Judgment criteria>
⊚: Average score is 4.5 or more ○: Average score is 3.5 or more and less than 4.5 Δ: Average score is 2.5 or more and less than 3.5 ×: Average score is less than 2.5

(2) Storage stability test The state of the system after storage in a constant temperature bath at 45 ° C. for 1 month was visually observed and evaluated according to the following evaluation criteria.

<Evaluation criteria>
◯: Good condition. It is translucent or slightly turbid, but it is not separated and exhibits a uniform liquid phase state.
Δ: The condition is slightly poor. It is turbid and partially separated.
×: Poor condition. Clearly separated.

As is clear from Table 1, the aqueous makeup remover compositions of Examples 1 to 15 all showed excellent performance as compared with the compositions of Comparative Examples 1 to 4.

Claims (1)

Contains the following component (A), component (B) and water,
In a coordinate system in which the L * value is arranged on the vertical axis, the horizontal axis is 50 ° C on the left side, and the two data on the right side is 23 ° C.
The L * value at 23 ° C is larger than the L * value at 50 ° C.
It is characterized in that the slope of a straight line rising to the right (L * value at 23 ° C.-50 ° C. L * value) connecting the L * value at 50 ° C. and the L * value at 23 ° C. is greater than 10 and 89 or less. Aqueous makeup remover composition.
(A): Polyoxyethylene (caprylic acid / capric acid) glyceryl 3.0 to 5.0% by mass with an average number of moles of ethylene oxide added of 6 to 8.
(B): From sodium glutamate, sodium hydrogencarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, tartaric acid, citric acid One or more selected

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