JP2018127419A - Aqueous makeup removing composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an aqueous makeup removing composition that brings about an excellent effect of removing oil stains such as makeup, has excellent storage stability, and that contains substantially no water-soluble polyhydric alcohol or sugar alcohol.SOLUTION: The aqueous makeup removing composition comprises the following components (A) and (B) as well as water and the slope of the linear function obtained from L*value at 50°C±2°C and L*value at 23°C±2°C is greater than 10 and less than or equal to 89. Component (A) 3.0 to 5.0% by mass of polyoxyethylene (caprylic/capric acid) glyceryl having an average addition mole number of ethylene oxide of 6 to 8. Component (B) one or more selected from sodium glutamate, sodium hydrogencarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, tartaric acid and citric acid.SELECTED DRAWING: Figure 1

Description

The present invention relates to an aqueous makeup remover composition for removing makeup stains, and more particularly, polyoxyethylene (caprylic acid / capric acid) glyceryl having an average addition mole number of ethylene oxide of from 6 to 3.0. ~ 5.0% by mass, sodium glutamate, sodium bicarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, tartaric acid 1 or more selected from citric acid and water, and the slope of the linear function obtained from the L * value at 50 ° C. ± 2 ° C. and the L * value at 23 ° C. ± 2 ° C. is greater than 10 89 The present invention relates to an aqueous makeup remover composition excellent in makeup removal and storage stability characterized by the following.

  A conventional detergent composition that removes makeup contains a surfactant oil solution type in which a surfactant is dissolved in an oil agent and a small amount of water in order to remove eye makeup and lipstick that are difficult to remove from the skin. So-called cleansing oil such as reverse micelle oil solution type is the mainstream (for example, Patent Document 1). However, while cleansing oil is excellent in the effect of removing makeup that is difficult to remove, there is a problem that an oil film remains on the skin at the time of washing, and a refreshing feel cannot be obtained unless it is washed again with a facial cleanser. Furthermore, since the oil of cleansing oil is compatible with the sebum of the skin, it removes even the sebum necessary for washing, resulting in a great dry feeling of the skin after use, thereby increasing the burden on the skin.

  On the other hand, in recent years, because of the trend of light makeup that emphasizes natural skin feeling, women's consciousness to gently remove the entire face and the lifestyle of women who are busy with childcare and work, etc. Makeup remover compositions that remove aqueous makeup that can be easily refreshed by wiping or washing off are becoming mainstream.

  Specifically, a cleansing material (for example, Patent Document 2), polyoxyethylene fatty acid glyceryl 3 to 10% by mass, and amphoteric surface activity are wiped out containing a nonionic surfactant and an unneutralized anionic surfactant. An aqueous wiping cleansing cosmetic (for example, Patent Document 3) containing 0.005 to 2% by mass of an agent has been proposed.

However, these water-based cleansing cosmetics are a proposal that two or more surfactants are combined to provide good makeup removal, but the makeup removal function is at a level that is not sufficient, and storage stability is also provided. The problem of coexistence with sex was not fully solved.

Japanese Patent No. 4757446 JP 2011-37782 A JP 2014-201561 A

  The present invention has been made in view of the above circumstances, and by using the surfactant efficiently by controlling the size of the micelle of one surfactant, in contrast to the conventional aqueous detergent composition. An object of the present invention is to provide an aqueous makeup remover composition that is excellent in makeup removal and storage stability.

As a result of intensive studies in order to achieve the object of the present invention, the present inventors have determined that polyoxyethylene (caprylic acid / capric acid) glyceryl having an average added mole number of ethylene oxide of 6 to 8 is 3.0 to 3.0. 5.0% by mass, sodium glutamate, sodium bicarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, tartaric acid, Including one or more selected from citric acid and water, the slope of the linear function obtained from the L * value at 50 ° C ± 2 ° C and the L * value at 23 ° C ± 2 ° C is greater than 10 and less than 89 As a result, the present inventors have found that an aqueous makeup remover characterized by being excellent in makeup removal and storage stability has led to the completion of the present invention.

That is, the present invention contains the following component (A), component (B), and water, and a linear function obtained from an L * value at 50 ° C. ± 2 ° C. and an L * value at 23 ° C. ± 2 ° C. An aqueous makeup remover characterized by an inclination of greater than 10 and 89 or less.
Component (A) Polyoxyethylene (caprylic acid / capric acid) glyceryl having an average added mole number of ethylene oxide of 6 to 8 3.0 to 5.0% by mass
Component (B) From sodium glutamate, sodium bicarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, tartaric acid, citric acid One or more selected

The aqueous makeup remover composition of the present invention has the effect of maximizing the makeup removal effect of one surfactant and removing makeup stains, as compared to conventional aqueous detergent compositions. Play.

It is a graph which shows the linear function obtained from the L * value of the solution in Example 1 of this invention and the commercial products 1-4 at 50 degreeC +/- 2 degreeC, and the L * value in 23 degreeC +/- 2 degreeC.

Here, the L * value is a scale representing the degree of turbidity, and when a colorimetric color difference meter (Color meter ZE6000: manufactured by Nippon Denshoku Industries Co., Ltd.) is used, purified water is put into a glass cell and light is transmitted. It is a value when the transparency is 100, the transparency is 0 when the light is completely blocked and there is no transmitted light.

Hereinafter, the aqueous makeup remover composition of the present invention will be described in detail.

In the component (A) of the present invention, 3.0 to 5.0% by mass of polyoxyethylene (caprylic acid / capric acid) glyceryl having an average added mole number of ethylene oxide of 6 to 8 is used. In the aqueous cleansing cosmetic of the present invention, when the component (A) is less than 3.0% by mass, the solubility in water is poor and the makeup removal is not good. On the other hand, when the content is 5.0% by mass or more, the amount of the surfactant is large and the burden on the skin is increased.

Component (B) of the present invention is sodium glutamate, sodium bicarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, Examples include tartaric acid and citric acid. These components (B) may be used individually by 1 type, or may be used in combination of 2 or more types as appropriate.

  Component (B) used in the present invention is used to control the size of micelles in the solution, and the micelle size is kept stable in the temperature range where it is normally used, thereby obtaining a good makeup stain removal effect. It is used from the point of view.

By using the component (B) used in the present invention, the slope of the linear function obtained from the L * value of the solution at 50 ° C. ± 2 ° C. and the L * value at 23 ° C. ± 2 ° C. is greater than 10. It may be 89 or less. The linear function is obtained when X is 50 ° C. ± 2 ° C., 23 ° C. ± 2 ° C., and Y is an L * value.

  When the slope of this linear function is in the range of more than 10 and 89 or less, the micelle of the surfactant in the aqueous makeup remover composition of the present invention has a size that makes the makeup removal and storage stability good, When the slope of the linear function is 10 or less, the micelle size at 23 ° C. ± 2 ° C. becomes relatively small, so the makeup removal at 23 ° C. ± 2 ° C. becomes worse, and when the slope of the linear function is greater than 89, Since the micelle size at 50 ° C. ± 2 ° C. becomes relatively large, the stability at 50 ° C. ± 2 ° C. becomes worse and may be separated.

In addition to the above-described components, the cleaning composition of the present invention includes other components within a range that does not impair the object of the present invention, such as physiologically active components, antioxidants, sequestering agents, antiseptics, and ultraviolet absorbers. Ingredients such as perfumes, moisturizers, salts, solvents, neutralizers, insect repellents, enzymes and the like can be appropriately blended.

Examples of the physiologically active ingredient include substances that impart some physiological activity to the skin when applied to the skin. For example, anti-inflammatory agents, anti-aging agents, UV protection agents, tanning agents, antioxidants, moisturizers, blood circulation promoters, antibacterial agents, bactericides, desiccants, cooling agents, warming agents, vitamins, amino acids, Examples include wound healing promoters, stimulus-relieving agents, analgesics, cell activators, enzyme components, and the like. Examples of the physiologically active component include natural plant extract components, seaweed extract components, herbal medicine components, and compounds. Among these, natural plant extract components, seaweed extract components, herbal medicine components are particularly safe. This is preferable.

Examples of the above-mentioned natural plant extract components, seaweed extract components, herbal medicine components include, for example, Ashitaba extract, Achacha extract, Altea extract, Aloe extract, Apricot extract, Ginkgo biloba extract, Fennel extract, Oolong tea extract, Ages extract, Ogon extract, Oat extract, Hypericum extract, Dutch mustard extract, Orange extract, Seawater dried product, Seaweed extract, Hydrolyzed wheat powder, Hydrolyzed silk, Chamomile extract, Carrot extract, Kawara mugwort extract, Licorice extract, Kiwi extract, Cucumber extract, Gardenia extract, Kumazasa extract, Clara extract, Walnut extract, Grapefruit extract, Chlorella extract, Mulberry extract, Black tea extract, Yeast extract, Collagen, Salvia extract, Soap extract, Hawthorn Kiss, Giant extract, Shikon extract, Perilla extract, Linden extract, Peonies extract, Birch extract, Horsetail extract, Horseshoe extract, Hawthorn extract, Horseshoe extract, Pepper extract, Sage extract, Senkyu extract, Assembly extract, Soybean extract , Tiso extract, thyme extract, tea extract, clove extract, chimpi extract, toki extract, tonin extract, dokudami extract, tomato extract, natto extract, carrot extract, garlic extract, wild rose extract, honey, hamamelis extract, cassava extract, bisabolol, loquat extract, bukuryu Extract, Propolis, Loofah extract, Peppermint extract, Bodaige extract, Hop extract, Madonna lily flower Ex , Mention may be made of horse chestnut extract, Sapindus extract, Melissa extract, peach, strawberry geranium extract, Yuzuekisu, mugwort extract, lavender extract, lemon extract, Astragalus Saw extract, rosemary extract, royal jelly extract, and the like.

Natural flavors include Amyris Oil, Ambret Seed Oil, Ylang Ylang Oil, Ylang Ylang Absolute, Iris Resinoid, Iris Absolute, Iris Oil, Winter Green Oil, Estragon Oil, Elemioleoresin, Elemiresinoid Absolute, Elemitinki, Oak Moth Concrete , Oakmoth Absolute, Oakmoth Resin, Oakmoth Resinoid, Ottomans Absolute, Ottomans Concrete, Opopanax Resinoid, Opopanax Absolute, Opopanax Oil, Olivenum Resinoid, Olivenum Absolute, Olivenum Oil, Allspice Oil, Origanum Oil, Oregano oil, oregano oleoresin, orange oil, orange Lower Absolute, Orange Flower Concrete, Cananga Oil, Garjun Balsam, Garjun Balsam Oil, Cassie Absolute, Cassie Flower Oil, Cassia Oil, Gardenia Absolute, Carnation Absolute, Cabruba Oil, Camomile Oil, Cardamom Oil, Galvanam Oil, Galvanam Resin , Galvanum resinoid, caraway seed oil, carrot seed oil, cuba oil, guayak wood oil, guayac resin, guayak concrete, camphor oil, cumin oil, cumin absolute, cumin oleoresin, clary sage oil, grapefruit oil, clove oil, Costaus oil, copaiba balsam, copaiba balsam oil Copaiba balsam resin, coriander oil, sandalwood oil, perilla oil, cedarwood oil, citronella oil, jasmine oil, jasmine absolute, jasmine concrete, juniper berry oil, june absolute, john kill absolute, ginger oil, cinnamon oil, cinnamon bark oil, cinnamon leaf Oil, cedar oil, star anise oil, stylax oil, stylax resinoid, spike lavender oil, spearmint oil, savory oil, sage oil, cedar oil, cedar leaf oil, geranium oil, celery seed oil, thyme oil, tagget oil, tangerine Oil, tuberose absolute, tea tree oil, tree Moss absolute, tonka bean oil, trubal sum, nutmeg oil, narcissus absolute, neroli oil, violet leaf absolute, pine oil, pine needle oil, basil oil, parsley leaf oil, parsley seed oil, parsley herb oil, patchouli oil, mint oil, Vanilla absolute, honeysuckle absolute, palmarosa oil, valerian oil, bitter orange oil, hyssop oil, hiba oil, hinoki oil, hyacinth absolute, fennel oil, fig absolute, petitgren oil, butch oil, bay oil, vetiver oil, pepper oil, peppermint absolute , Peppermint oil, bergamot oil, peruvian balsa , Benzoin tincture, benzoin resinoid, pepper oil, marjoram oil, mandarin oil, mandarin oil, mimosa concrete, mimosa absolute, mimosa oil, milresinoid, mil absolute, mill oil, musk absolute, mustinki, eucalyptus oil, yuzu oil, lime oil, rub Examples include Danum Oil, Love Danum Resinoid, Lavender Oil, Lavender Absolute, Lavandin Oil, Lavandin Absolute, Lemon Oil, Lemongrass Oil, Rose Oil, Rose Absolute, Rose Concrete, Rosemary Oil, Laurel Oil and Laurel Leaf Oil.

Synthetic fragrances include amblylide, aldehydes C6 to C12, anisaldehyde, acetal R, acetophenone, acetyl cedrene, adoxal, allyl amyl glycolate, allyl cyclohexane propionate, ambroxan, amyl cinnamamic aldehyde, amyl cinnamic Aldehyde dimethyl acetal, amyl valeric acid, amyl salicylate, acetyl eugenol, isoamyl acetate, isoamyl salicylate, indole, ionone, isobornyl acetate, isocyclocitral, iso E super, isoeugenol, isononyl acetate, isobutyl quinoline, γ-un Decalactone, ethylene brushate, ethylene dodecanedioate, ethyl vanillin, 2-ethylhexanol, o Thiol, 10-oxahexadecanolide, 11-oxahexadecanolide, 12-oxahexadecanolide, oxahexadecen-2-one, eugenol, olibon, oxyphenylone, galaxolide, caryophyllene, cachemelan, carvone, β -Caryophyllene, caron, coumarin, p-cresyl methyl ether, geraniol, geranyl acetate, geranyl formate, geranyl nitrile, coabon, sandaroa, sandera, santa rex, cinnamic alcohol, cinnamic aldehyde, cis jasmon, citral, citral dimethyl Acetal, citrasal, citronellal, citronellol, citronellyl acetate, citronellyl formate, citronellil nitrile, cyclaset, cyclame Aldehyde, cyclaprop, dimethylbenzylcarbinol, dihydrojasmon, dihydrolinalol, dihydromyrsenol, dimethol, dimyrcetol, diphenyl oxide, jasmar, jasmolactone, jasmofilan, cinnamyl acetate, cyclopentadecanone, cyclohexadecenone , Cyclopentadecanolide, Cyclohexadecanolide, Dimethylbenzyl Carvinyl Acetate, Jasma Cyclen, Stylal Acetate, Stylal Propionate, Cedro Amber, Cedryl Acetate, Cedrol, Celestolide, α-Damascon , Β-damascone, δ-damascone, damacenone, terpineol, terpinyl acetate, thymol, tetrahydrolinalol, tetrahydrolinalylacete , Tetrahydrogeraniol, tetrahydrogeranyl acetate, tonalid, traseolide, tripral, neryl acetate, nerol, neobergamate, γ-nonalactone nopyrual alcohol, nopylacetate, bacdanol, hydrotropic alcohol, α-pinene, β-pinene, Hydroxycitronellal, hyacinth dimethyl acetal, butyl butyrate, pt-butyl cyclohexanol, pt-butyl cyclohexyl acetate, ot-butyl cyclohexanol, ot-butyl cyclohexyl acetate, fluitate, fentyl alcohol , Phenylethylphenylacetate, phenylethylacetate, pentalid, bellodox, benzylacetate, benzyl alcohol, benzylsali Sylate, bergamyl acetate, benzaldehyde, benzyl formate, hedion, helional, heliotropin, cis-3-hexenol, cis-3-hexenyl acetate, cis-3-hexenyl salicylate, hexylcinnamic aldehyde, hexyl salicylate Bornyl acetate, Borneol, Manzanate, Mayolate, Myrcene, Milac aldehyde, Mugealdehyde, Mugor, Musk TM-11, Musk 781, Musk C14, Muscone, Musk ketone, Muskivetine, Mensanil acetate, Mentsonate, Methylanthranilate, Methyl eugenol, menthol, α-methyl ionone, β-methyl ionone, γ-methyl ionone, methyl isoeugenol, methyl lavender , Methyl salicylate, 14-methyl-hexadecenolide, 14-methyl-hexadecanolide, methyl naphthyl ketone, methyl phenyl acetate, yarayara, δ-C6-C13 lactone, lime oxide, γ-C6-C13 lactone, raspberry ketone, limonene, ligustral, Examples include linal, linalool, linalool oxide, linalyl acetate, laral, rubafuran, rosephenone, rose oxide, and vanillin.

Examples of blended fragrances that combine fragrance ingredients include the following incense-based bases. Lemon-like, lime-like, orange-like, sweet orange-like, mandarin-like, bergamot-like citrus-type base, petit-glen-like, neroli-like, lemongrass-like, aggluten-like, etc. Fresh-type base, apple-like, peach-like, strawberry Tone, coconut tone, pineapple tone, raspberry tone, water melon tone, grape tone, mango tone, fruit mix tone, tropical fruit tone and other fruity type base, rose tone, jasmine tone, mugue tone, lilac tone, carnation tone, hyacinth Tone, tuberose tone, gardenia tone, mimosa tone, narciss tone, violet tone, Iranian tone, floral bouquet tone and other floral type bases, cinnamon bark tone, cinnamon leaf tone, clove tone, pimentoberry tone, nutmeg tone, pep -Tone, cardamom tone, coriander tone, cumin tone, etc., spicy type bass, cedarwood tone, vetiver tone, sandalwood tone, guaiac wood tone, woody bar tone, woody iris tone, etc. Leather type such as vanilla, tonka, honey, pure balsam, etc., butter flavor, milk flavor, aldehydic type base, amber type base, animal type base, anise type base, aromatic Herbal type base, agar type base, aqua type base, camphor cineole type base, green type base, seed type base, herb type base, pine type base, patchouli type base Vinegar, balsamic type base, mint type base, musk type base, Moss type base, lavender type base, linalool type base, and a resin-type base and the like.

Further, diethyl phthalate, dipropylene glycol, benzyl benzoate, isopropyl myristate, hercoline, isopentane, orange terpene, etc. can be used as a solvent or a retaining agent for the fragrance.

Examples of components other than the above-mentioned natural plant extract components, seaweed extract components, and herbal medicine components include deoxyribonucleic acid, mucopolysaccharide, sodium hyaluronate, sodium chondroitin sulfate, collagen, elastin, chitin, chitosan, hydrolyzed eggshell membrane Moisturizing ingredients such as biopolymers such as amino acids, sodium lactate, urea, sodium pyrrolidone carboxylate, betaine, whey, oily ingredients such as sphingolipids, ceramides, cholesterol, cholesterol derivatives, phospholipids, ε-aminocaproic acid, glycyrrhizic acid , Β-glycyrrhetinic acid, lysozyme chloride, guaiazulene, hydrocortisone and other anti-inflammatory agents, vitamins (A, B2, B6, C, D, E), calcium pantothenate, biotin, nicotinamide, vitamin C esters, etc. Active ingredients such as amines, allantoin, diisopropylamine dichloroacetate, 4-aminomethylcyclohexanecarboxylic acid, antioxidants such as tocopherol, carotenoid, flavonoid, tannin, lignan, saponin, α-hydroxy acid, β-hydroxy acid, etc. Cell activators, blood circulation promoters such as γ-oryzanol, vitamin E derivatives, fungicides such as isopropylmethylphenol, triclosan, hinokitiol, benzalkonium chloride, cooling agents such as l-menthol and mint oil, retinol, retinol derivatives And wound healing agents.

Each aromatic water, vegetable water, hot spring water, etc. can be included as appropriate.

The aqueous makeup remover composition of the present invention preferably contains substantially no lower alcohol, water-soluble polyhydric alcohol or sugar alcohol.

The aqueous makeup remover composition of the present invention can be used without rinsing after wiping, or may be used in rinsing. As a preferred method of use, cotton, tissue paper or nonwoven fabric is impregnated with aqueous cleansing cosmetics and applied to the application site, or after applying the aqueous makeup remover composition to the application site, cotton, tissue paper or nonwoven fabric, etc. The method of wiping off with can be illustrated.

Next, the aqueous makeup remover composition of the present invention will be described in detail with reference to examples, but the present invention is not limited thereto. In addition, the compounding quantity in all the following examples and comparative examples is the mass%.

The test methods of the sensory test and the storage stability test performed in Examples 1 to 15 and Comparative Examples 1 to 4 are shown below.

<Makeup evaluation test>
20 panelists applied lipstick (Shiseido Integrate Gracie Lipstick Red 465) to their faces in an environment of room temperature 23 ° C. and left for 30 minutes, and then impregnated cotton with the aqueous makeup remover composition of Examples and Comparative Examples. Wiped off and used. The makeup removal at that time was evaluated in five stages, and further, the average score was determined according to the following criteria.

<5-level evaluation>
5 points: Very good 4 points: Good 3 points: Normal 2 points: Slightly bad 1 point: Bad

<Criteria>
◎: Average score is 4.5 or more ○: Average score is 3.5 or more and less than 4.5 Δ: Average score is 2.5 or more and less than 3.5 ×: Average score is less than 2.5

(2) Storage stability test The state of the system when stored in a 45 ° C constant temperature bath for 1 month was visually observed and evaluated according to the following evaluation criteria.

<Evaluation criteria>
○: Good state. Translucent or slightly turbid but not separated and presents a uniform liquid phase.
Δ: Slightly poor state. Turbidity is observed and partly separated.
X: Bad state. Clearly separated.

As is clear from Table 1, the aqueous makeup remover compositions of Examples 1 to 15 all showed superior performance as compared to the compositions of Comparative Examples 1 to 4.

Claims (1)

It contains the following component (A), component (B), and water, and the slope of the linear function obtained from the L * value at 50 ° C. ± 2 ° C. and the L * value at 23 ° C. ± 2 ° C. is greater than 10 89 An aqueous makeup remover characterized by the following:
Component (A) Polyoxyethylene (caprylic acid / capric acid) glyceryl having an average added mole number of ethylene oxide of 6 to 8 3.0 to 5.0% by mass
Component (B) From sodium glutamate, sodium bicarbonate, magnesium sulfate, sodium acetate, calcium chloride, sodium citrate, sodium chloride, potassium chloride, monosodium phosphate, monopotassium phosphate, disodium phosphate, tartaric acid, citric acid One or more selected

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