JP6959979B2 - 希土類メタロセンを含む予備形成触媒系 - Google Patents
希土類メタロセンを含む予備形成触媒系 Download PDFInfo
- Publication number
- JP6959979B2 JP6959979B2 JP2019504066A JP2019504066A JP6959979B2 JP 6959979 B2 JP6959979 B2 JP 6959979B2 JP 2019504066 A JP2019504066 A JP 2019504066A JP 2019504066 A JP2019504066 A JP 2019504066A JP 6959979 B2 JP6959979 B2 JP 6959979B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- catalyst system
- catalyst
- monomer
- rare earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/08—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/01—Cp or analog bridged to a non-Cp X neutral donor
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1657102A FR3054221A1 (fr) | 2016-07-25 | 2016-07-25 | Systeme catalytique preforme comprenant un metallocene de terre rare |
| FR16/57102 | 2016-07-25 | ||
| PCT/FR2017/052040 WO2018020123A1 (fr) | 2016-07-25 | 2017-07-24 | Systeme catalytique preforme comprenant un metallocene de terre rare |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019531364A JP2019531364A (ja) | 2019-10-31 |
| JP2019531364A5 JP2019531364A5 (OSRAM) | 2020-09-03 |
| JP6959979B2 true JP6959979B2 (ja) | 2021-11-05 |
Family
ID=56943827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019504066A Active JP6959979B2 (ja) | 2016-07-25 | 2017-07-24 | 希土類メタロセンを含む予備形成触媒系 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20190233566A1 (OSRAM) |
| JP (1) | JP6959979B2 (OSRAM) |
| FR (1) | FR3054221A1 (OSRAM) |
| WO (1) | WO2018020123A1 (OSRAM) |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3082205B1 (fr) * | 2018-06-06 | 2020-12-04 | Michelin & Cie | Copolymere d'ethylene et d'isoprene |
| FR3085683B1 (fr) | 2018-09-11 | 2020-10-23 | Michelin & Cie | Pneumatique |
| FR3085684B1 (fr) | 2018-09-11 | 2021-06-04 | Michelin & Cie | Composition de caoutchouc |
| FR3086949B1 (fr) | 2018-10-09 | 2020-12-04 | Michelin & Cie | Composition de caoutchouc |
| FR3086948B1 (fr) | 2018-10-09 | 2020-12-04 | Michelin & Cie | Composition de caoutchouc |
| FR3087443B3 (fr) | 2018-10-23 | 2020-10-23 | Michelin & Cie | Composition de caoutchouc |
| FR3090663A3 (fr) | 2018-12-21 | 2020-06-26 | Michelin & Cie | Bande de roulement pour pneumatique |
| FR3090659A3 (fr) | 2018-12-21 | 2020-06-26 | Michelin & Cie | Bande de roulement pour pneumatique |
| FR3090654A3 (fr) | 2018-12-21 | 2020-06-26 | Michelin & Cie | Composition de caoutchouc |
| FR3090656A3 (fr) | 2018-12-21 | 2020-06-26 | Michelin & Cie | Bande de roulement pour pneumatique |
| FR3090661A3 (fr) | 2018-12-21 | 2020-06-26 | Michelin & Cie | Bande de roulement pour pneumatique |
| FR3104597B1 (fr) | 2019-12-16 | 2021-11-12 | Michelin & Cie | Composition de caoutchouc |
| FR3104585B1 (fr) * | 2019-12-17 | 2021-12-03 | Michelin & Cie | Système catalytique à base d’un métallocène et d’un diorganomagnésien |
| FR3104595B1 (fr) | 2019-12-17 | 2021-11-12 | Michelin & Cie | Pneumatique avec une bande de roulement comportant des elements de renforcement |
| FR3108117B1 (fr) | 2020-03-10 | 2022-03-25 | Michelin & Cie | Procédé de fabrication d’une composition de caoutchouc. |
| FR3111352B1 (fr) | 2020-06-11 | 2023-02-10 | Michelin & Cie | Composition de caoutchouc presentant une resistance aux agressions amelioree |
| FR3113905B1 (fr) | 2020-09-04 | 2022-08-05 | Michelin & Cie | Composition de caoutchouc a base d’elastomere dienique fortement sature |
| FR3113906B1 (fr) | 2020-09-04 | 2022-08-05 | Michelin & Cie | Composition de caoutchouc a base d’elastomere dienique fortement sature |
| FR3117404B1 (fr) | 2020-12-16 | 2024-02-16 | Michelin & Cie | Stratifié élastomère présentant une excellente adhésion entre une couche diénique fortement saturé réticulé et une couche diénique vulcanisé |
| FR3118048B1 (fr) | 2020-12-22 | 2023-01-13 | Michelin & Cie | Composition de caoutchouc comprenant une poudrette de caoutchouc |
| FR3118047B1 (fr) | 2020-12-23 | 2022-12-30 | Michelin & Cie | Composition de caoutchouc comprenant un élastomère diénique fortement saturé |
| FR3118046B1 (fr) | 2020-12-23 | 2022-12-30 | Michelin & Cie | Composition de caoutchouc comprenant un élastomère diénique fortement saturé |
| FR3118044B1 (fr) | 2020-12-23 | 2022-12-30 | Michelin & Cie | Composition de caoutchouc |
| FR3118045B1 (fr) | 2020-12-23 | 2022-12-30 | Michelin & Cie | Composition de caoutchouc |
| FR3123654B1 (fr) | 2021-06-07 | 2023-04-28 | Michelin & Cie | Composition de caoutchouc base d’élastomère fortement saturé et de compolymère de butadiene-styrene |
| FR3123655B1 (fr) | 2021-06-07 | 2023-04-28 | Michelin & Cie | Bande transporteuse comprenant une composition à base d’élastomère fortement saturé |
| FR3123920B1 (fr) | 2021-06-15 | 2023-04-28 | Michelin & Cie | Composition de caoutchouc a base de copolymere contenant des unites ethylene et des unites dieniques, et de polyethylene |
| FR3123919B1 (fr) | 2021-06-15 | 2023-04-28 | Michelin & Cie | Composition de caoutchouc a base de copolymere contenant des unites ethylene et des unites dieniques, et de polyethylene |
| FR3124514B1 (fr) | 2021-06-25 | 2023-06-02 | Michelin & Cie | Composition de caoutchouc presentant une resistance aux agressions amelioree |
| FR3129397B1 (fr) | 2021-11-22 | 2023-11-10 | Michelin & Cie | Composition de caoutchouc |
| FR3129401B1 (fr) | 2021-11-22 | 2023-11-10 | Michelin & Cie | Composition de caoutchouc |
| FR3129396B1 (fr) | 2021-11-22 | 2023-11-10 | Michelin & Cie | Composition de caoutchouc |
| FR3129398B1 (fr) | 2021-11-22 | 2025-05-23 | Michelin & Cie | Composition de caoutchouc |
| FR3129399B1 (fr) | 2021-11-22 | 2023-11-10 | Michelin & Cie | Composition de caoutchouc |
| FR3129400B1 (fr) | 2021-11-22 | 2023-11-10 | Michelin & Cie | Composition de caoutchouc |
| FR3130281B1 (fr) | 2021-12-10 | 2025-07-25 | Michelin & Cie | Composition de caoutchouc antivibratoire |
| FR3130807B1 (fr) | 2021-12-16 | 2025-08-29 | Michelin & Cie | Composition de caoutchouc comprenant un élastomère diénique fortement saturé |
| FR3135723B1 (fr) | 2022-05-17 | 2024-04-19 | Michelin & Cie | Composition de caoutchouc a base d’un elastomere fortement sature et d’un plastifiant liquide polaire |
| FR3135722B1 (fr) | 2022-05-17 | 2024-04-19 | Michelin & Cie | Composition de caoutchouc a base d’un elastomere fortement sature et d’un plastifiant liquide |
| FR3136473A1 (fr) | 2022-06-14 | 2023-12-15 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant un élastomère diénique fortement saturé |
| FR3136768B1 (fr) | 2022-06-20 | 2024-05-31 | Michelin & Cie | Composition de caoutchouc diénique comportant une microsilice. |
| FR3136771B1 (fr) | 2022-06-21 | 2024-05-10 | Michelin & Cie | Composition de caoutchouc comprenant un élastomère diénique fortement saturé |
| FR3143035B1 (fr) | 2022-12-08 | 2024-11-29 | Michelin & Cie | Composition de caoutchouc |
| FR3143032A1 (fr) | 2022-12-08 | 2024-06-14 | Compagnie Generale Des Etablissements Michelin | Composite pour article de caoutchouc |
| FR3143033B1 (fr) | 2022-12-12 | 2024-11-29 | Michelin & Cie | Pneumatique pour véhicule portant de lourdes charges |
| FR3143034B1 (fr) | 2022-12-13 | 2025-05-02 | Michelin & Cie | Composition de caoutchouc |
| FR3143613B1 (fr) | 2022-12-15 | 2024-11-15 | Michelin & Cie | Composition de caoutchouc comprenant un élastomère diénique fortement saturé |
| FR3143612B1 (fr) | 2022-12-15 | 2024-11-15 | Michelin & Cie | Composition de caoutchouc comprenant un élastomère diénique fortement saturé |
| FR3144145A1 (fr) | 2022-12-21 | 2024-06-28 | Compagnie Generale Des Etablissements Michelin | Compositions elastomeriques comprenant un noir de carbone de pyrolyse |
| FR3145755B1 (fr) | 2023-02-09 | 2025-02-07 | Michelin & Cie | Composition de caoutchouc a base d’elastomere dienique fortement sature et d’une resine renforçante |
| FR3145756A1 (fr) | 2023-02-09 | 2024-08-16 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc a base d’elastomere dienique fortement sature et d’un derive d’imidazole |
| FR3148030A1 (fr) | 2023-04-24 | 2024-10-25 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc |
| FR3148429B1 (fr) | 2023-05-04 | 2025-05-02 | Michelin & Cie | Composition de caoutchouc |
| FR3148598A1 (fr) | 2023-05-10 | 2024-11-15 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc |
| FR3149322B1 (fr) | 2023-05-31 | 2025-05-02 | Michelin & Cie | Composition de caoutchouc comprenant un élastomère diénique fortement saturé |
| FR3149614B1 (fr) | 2023-06-09 | 2025-05-02 | Michelin & Cie | Composition de caoutchouc antivibratoire |
| FR3149613B1 (fr) | 2023-06-09 | 2025-05-02 | Michelin & Cie | Composition de caoutchouc antivibratoire |
| FR3156448B1 (fr) | 2023-12-12 | 2025-10-31 | Michelin & Cie | Composition de caoutchouc a base d’elastomere dienique fortement sature |
| FR3159971A1 (fr) | 2024-03-05 | 2025-09-12 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant un elastomere dienique fortement sature |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6004677A (en) * | 1997-08-08 | 1999-12-21 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase production of polydienes with pre-activated nickel catalysts |
| FR2799468B1 (fr) * | 1999-10-12 | 2006-04-28 | Michelin Soc Tech | Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue |
| WO2004035639A1 (fr) | 2002-10-16 | 2004-04-29 | Societe De Technologie Michelin | Copolymères éthylène/ butadiène, system catalytique et les produires et production desdits polymers |
| FR2893029B1 (fr) | 2005-11-09 | 2009-01-16 | Michelin Soc Tech | Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede |
| FR2893028B1 (fr) | 2005-11-09 | 2008-02-15 | Michelin Soc Tech | Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede |
| EP2363303A1 (de) * | 2010-02-19 | 2011-09-07 | LANXESS Deutschland GmbH | Bimodales NdBR |
| FR2978152B1 (fr) * | 2011-07-22 | 2015-02-20 | Univ Lille 1 Sciences & Technologies | Nouveau procede de preparation de dialkylmagnesiens par polymerisation de l'ethylene et leurs applications |
| FR3001223B1 (fr) | 2013-01-22 | 2015-03-06 | Michelin & Cie | Composition de caoutchouc comprenant un elastomere dienique fortement sature |
| FR3044662B1 (fr) * | 2015-12-03 | 2017-12-08 | Michelin & Cie | Systeme catalytique preforme comprenant un metallocene de terre rare |
| FR3054222A1 (fr) * | 2016-07-25 | 2018-01-26 | Compagnie Generale Des Etablissements Michelin | Procede de preparation d'un systeme catalytique a base d'un metallocene de terre rare |
| FR3054220A1 (fr) * | 2016-07-25 | 2018-01-26 | Compagnie Generale Des Etablissements Michelin | Systeme catalytique preforme comprenant un metallocene de terre rare |
| FR3059254A1 (fr) * | 2016-11-30 | 2018-06-01 | Compagnie Generale Des Etablissements Michelin | Systeme catalytique preforme comprenant un metallocene de terre rare |
-
2016
- 2016-07-25 FR FR1657102A patent/FR3054221A1/fr not_active Withdrawn
-
2017
- 2017-07-24 US US16/320,211 patent/US20190233566A1/en not_active Abandoned
- 2017-07-24 JP JP2019504066A patent/JP6959979B2/ja active Active
- 2017-07-24 WO PCT/FR2017/052040 patent/WO2018020123A1/fr not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JP2019531364A (ja) | 2019-10-31 |
| US20190233566A1 (en) | 2019-08-01 |
| WO2018020123A1 (fr) | 2018-02-01 |
| FR3054221A1 (fr) | 2018-01-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6959979B2 (ja) | 希土類メタロセンを含む予備形成触媒系 | |
| CN109563116B (zh) | 包含稀土金属茂的预形成催化体系 | |
| JP6903660B2 (ja) | 希土類メタロセンを含む触媒予備形成系 | |
| RU2312870C2 (ru) | Сополимеры этилена и бутадиена, каталитическая система и способ их синтеза | |
| KR100722171B1 (ko) | 촉매 시스템, 이의 제조방법, 및 에틸렌과 공액 디엔과의공중합체의 제조방법 | |
| CN101341163B (zh) | 镧系元素的氢硼化茂金属配合物、包括所述配合物的催化体系、使用相同配合物的聚合方法和使用所述方法获得的乙烯-丁二烯共聚物 | |
| EP2017280B1 (en) | Metallocene complex and polymerization catalyst composition containing the same | |
| JP6946322B2 (ja) | 希土類メタロセンを含む触媒系 | |
| US11130826B2 (en) | Preformed catalytic system comprising a rare earth metal metallocene | |
| JP2007063240A (ja) | メタロセン錯体、およびそれを含む重合触媒組成物 | |
| CN101400707A (zh) | 用于异戊二烯系化合物聚合的聚合催化剂组合物 | |
| KR20230129398A (ko) | 통계적 블럭 및 2개의 말단 폴리에틸렌 블럭을 갖는 에틸렌-풍부 디엔 트리블럭 중합체 | |
| CN116615477A (zh) | 基于1,3-二烯和乙烯的嵌段聚合物的合成 | |
| JP4831488B2 (ja) | アイソタクチック3,4−イソプレン系重合体 | |
| CN114829418B (zh) | 用于催化体系的二有机镁化合物 | |
| CN114829420B (zh) | 二有机镁化合物 | |
| CN105683230A (zh) | 来自立构规整聚合的具有1,4-顺式/间同立构1,2结构的有规立构的二嵌段聚丁二烯 | |
| CN119487092A (zh) | 具有聚乙烯吡啶嵌段的富含乙烯的二烯聚合物及其在发动机润滑组合物中的用途 | |
| JP2002537449A (ja) | ヘテロレプチックアルカリ土類金属化合物及び立体選択性アニオン重合法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200727 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20200727 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20210512 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210520 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20210908 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20211008 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6959979 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |