JP6938922B2 - Food additives - Google Patents

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JP6938922B2
JP6938922B2 JP2017008678A JP2017008678A JP6938922B2 JP 6938922 B2 JP6938922 B2 JP 6938922B2 JP 2017008678 A JP2017008678 A JP 2017008678A JP 2017008678 A JP2017008678 A JP 2017008678A JP 6938922 B2 JP6938922 B2 JP 6938922B2
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JP2017131217A (en
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薫 佐治
薫 佐治
歩 田上
歩 田上
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Nippon Paper Industries Co Ltd
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Description

本発明は、食品添加剤に関する。 The present invention relates to food additives.

一般的な粉末状セルロースは、平均粒子径5〜60μm、見掛け比重 0.10〜0.50g/cm3程度であり、平均粒子径が大きくなるにつれて、見掛け比重が小さくなる白色粒子である。 General powdered cellulose has an average particle size of 5 to 60 μm and an apparent specific gravity of about 0.10 to 0.50 g / cm3, and is white particles whose apparent specific gravity decreases as the average particle size increases.

この粉末状セルロースを得る方法としては、化学的処理と機械的処理による方法が知られている。化学的処理としてはセルロース原料に硫酸または塩酸等の鉱酸を作用させ加水分解反応を行い、粉末状セルロースを得る方法が公知である。 As a method for obtaining this powdered cellulose, a method by chemical treatment and mechanical treatment is known. As a chemical treatment, a method of reacting a cellulose raw material with a mineral acid such as sulfuric acid or hydrochloric acid to carry out a hydrolysis reaction to obtain powdered cellulose is known.

例えば、120〜160℃という高温下、20〜45分間希酸で酸加水分解し、粉末状セルロースを得る方法(特許文献1参照)。2.5規定(以下、規定はNと省略)の塩酸で約15分間酸加水分解し、粉末状セルロースを得る方法(特許文献2参照)。各種濃度の塩酸水溶液で高温処理し、粉末状セルロースを得る方法(特許文献3参照)等がある。 For example, a method of obtaining powdered cellulose by acid hydrolysis with a dilute acid for 20 to 45 minutes at a high temperature of 120 to 160 ° C. (see Patent Document 1). A method for obtaining powdered cellulose by acid hydrolysis for about 15 minutes with hydrochloric acid of 2.5 regulation (hereinafter, the regulation is abbreviated as N) (see Patent Document 2). There is a method of obtaining powdered cellulose by high-temperature treatment with aqueous hydrochloric acid solutions of various concentrations (see Patent Document 3).

酸加水分解法で得られる粉末状セルロースの特徴としては、酸濃度を適宜コントロールすることで、粉末状セルロースの重合度および平均粒子径を容易に調節できる。したがって、酸濃度を変化させることにより、見掛け比重や粉体流動性を変更することが可能であるという、利点を有する。 The characteristic of powdered cellulose obtained by the acid hydrolysis method is that the degree of polymerization and average particle size of powdered cellulose can be easily adjusted by appropriately controlling the acid concentration. Therefore, there is an advantage that the apparent specific gravity and the powder fluidity can be changed by changing the acid concentration.

また、機械的処理としては公知の分級、および粉砕技術が利用されている。機械的処理では原料のロスが殆ど無いために高収率であること、薬品コストが生じないこと等の利点を有している。 Further, as the mechanical treatment, known classification and pulverization techniques are used. Mechanical processing has advantages such as high yield because there is almost no loss of raw materials and no chemical cost.

この様に粉末状セルロースは用途に適したコントロールが簡便に行えるため、各種食品添加剤として用いられることが知られている(特許文献4参照)。 As described above, powdered cellulose is known to be used as various food additives because it can be easily controlled according to the application (see Patent Document 4).

米国特許第3954727号U.S. Pat. No. 3954727 米国特許第3141875号U.S. Pat. No. 3,141,875 特開昭53−127553号JP-A-53-1275553 特開2015−183018号JP 2015-183018

しかしながら、特許文献4では食品に用いた際の食感や粉舞いを抑制することが記載されているが、食品添加剤としては未だ改善点があった。 However, although Patent Document 4 describes that it suppresses texture and powdering when used in foods, there are still some improvements as food additives.

そこで本発明は、食感、吸水/吸油性、結着防止性、着色性、保形成に優れる粉末状セルロースを含む食品添加剤を提供することを目的とする。 Therefore, an object of the present invention is to provide a food additive containing powdered cellulose having excellent texture, water / oil absorption, anti-binding property, coloring property, and retention.

本願発明者らは鋭意努力の結果、以下の粉末状セルロースを用いることで本発明が達成できることを明らかにした。
すなわち、本発明は下記(1)〜(2)である。
(1)粉末状セルロースを含む食品添加剤であって、該粉末状セルロースが下記条件(A)〜(E)を満たすことを特徴する食品添加剤。
(A)平均粒子径が5〜75μm
(B)粒子径100μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜45.0体積%の範囲にある。
(C)粒子径200μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜25.0体積%の範囲にある。
(D)粒子径300μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜12.0体積%以下の範囲にある。
(E)粒子径600μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜2.0体積%以下の範囲にある。
(2)前記記載の粉末状セルロースが、平均重合度100〜2500、結晶化度60〜90%であることを特徴とする、(1)記載の食品添加剤。
As a result of diligent efforts, the inventors of the present application have clarified that the present invention can be achieved by using the following powdered cellulose.
That is, the present invention is the following (1) to (2).
(1) A food additive containing powdered cellulose, wherein the powdered cellulose satisfies the following conditions (A) to (E).
(A) Average particle size is 5 to 75 μm
(B) Powdered cellulose having a particle size of 100 μm or more is in the range of 0 to 45.0% by volume in the accumulation distribution calculated from the particle size distribution.
(C) Powdered cellulose having a particle size of 200 μm or more is in the range of 0 to 25.0% by volume in the accumulation distribution calculated from the particle size distribution.
(D) Powdered cellulose having a particle size of 300 μm or more is in the range of 0 to 12.0% by volume or less in the accumulation distribution calculated from the particle size distribution.
(E) Powdered cellulose having a particle size of 600 μm or more is in the range of 0 to 2.0% by volume or less in the accumulation distribution calculated from the particle size distribution.
(2) The food additive according to (1), wherein the powdered cellulose according to the above has an average degree of polymerization of 100 to 2500 and a crystallinity of 60 to 90%.

本発明は、食感、吸水/吸油性、結着防止性、着色性、保形成に優れる粉末状セルロースを含む食品添加剤を提供することができる。
The present invention can provide a food additive containing powdered cellulose having excellent texture, water / oil absorption, anti-binding property, coloring property, and retention.

以下本発明の詳細を説明するが、特に記載のない場合「AA〜BB%」等という記載は、「AA%以上BB%以下」をあらわすものとする。 The details of the present invention will be described below, but unless otherwise specified, the description such as "AA to BB%" means "AA% or more and BB% or less".

すなわち本発明は、粉末状セルロースを含む食品添加剤であって、該粉末状セルロースが下記(A)〜(E)を満たすことを特徴する食品添加剤に関する。
(A)平均粒子径が5〜75μm
(B)粒子径100μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜45.0体積%の範囲にある。
(C)粒子径200μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜25.0体積%の範囲にある。
(D)粒子径300μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜12.0体積%以下の範囲にある。
(E)粒子径600μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜2.0体積%以下の範囲にある。
That is, the present invention relates to a food additive containing powdered cellulose, wherein the powdered cellulose satisfies the following (A) to (E).
(A) Average particle size is 5 to 75 μm
(B) Powdered cellulose having a particle size of 100 μm or more is in the range of 0 to 45.0% by volume in the accumulation distribution calculated from the particle size distribution.
(C) Powdered cellulose having a particle size of 200 μm or more is in the range of 0 to 25.0% by volume in the accumulation distribution calculated from the particle size distribution.
(D) Powdered cellulose having a particle size of 300 μm or more is in the range of 0 to 12.0% by volume or less in the accumulation distribution calculated from the particle size distribution.
(E) Powdered cellulose having a particle size of 600 μm or more is in the range of 0 to 2.0% by volume or less in the accumulation distribution calculated from the particle size distribution.

本発明における食品添加剤とは、食品に特定の効用・機能を持たせるために添加される物である。その様な物としては、吸水/吸油助剤、結着防止剤、着色助剤、保形助剤、食感改良剤などがある。 The food additive in the present invention is an additive added to give a food a specific effect / function. Such products include water / oil absorption aids, anti-binding agents, coloring aids, shape-retaining aids, texture improvers and the like.

吸水/吸油助剤としては、例えばハンバーグ、ドウ、パン、麺、蒲鉾などの練り製品、春巻きなどの餡(具)、唐揚げの衣、ハムやソーセージなどに用いた場合、粉末状セルロースが水及び油分を保持することができるため、吸水による湯戻りや、食品のうまみ保持や、しっとりした食感を与えることができる。 As a water / oil absorption aid, for example, when used for paste products such as hamburger, dough, bread, noodles, and kamaboko, bean paste (ingredients) such as spring rolls, fried batter, ham and sausage, powdered cellulose is used as water and Since the oil content can be retained, it is possible to rehydrate the noodles by absorbing water, retain the taste of the food, and give a moist texture.

結着防止剤としては、例えばチーズや調味料などに用いた場合、それぞれの食品同士が長時間接触していても、剥離性を保持できることができる。 When used as an anti-binding agent for, for example, cheese or seasonings, the peelability can be maintained even if the foods are in contact with each other for a long time.

着色助剤としては、例えば焼き菓子や糖衣錠などに用いる場合、焼き加減等により適度な焦げ目が付与でき見た目の改善ができること、又は着色剤等が適度に浸透し保持できることができる。 As the coloring aid, for example, when it is used for baked confectionery, sugar-coated tablets, etc., it is possible to impart an appropriate browning by adjusting the baking or the like to improve the appearance, or it is possible to appropriately permeate and retain the coloring agent or the like.

食感改良剤としては、例えばゼリー、鮭そぼろ、山葵(調味添加料)、成型スナック菓子などに用いる場合には、例えば食品の硬さ向上や、繊維の3次元的な立体構造形成により、ふっくらとした食感を付与できることができる。 As a texture improving agent, for example, when used for jelly, salmon soboro, wasabi (seasoning additive), molded snack confectionery, etc., for example, by improving the hardness of foods and forming a three-dimensional three-dimensional structure of fibers, it becomes plump. It is possible to give a smooth texture.

保形助剤としては、例えばホイップクリーム、(フリーズドライ)ソフトクリーム、成型スナック菓子等に用いる場合、継時的に3次元的な食品形を維持することができる。 When used as a shape-retaining aid, for example, in whipped cream, (freeze-dried) soft serve ice cream, molded snack confectionery, etc., it is possible to maintain a three-dimensional food shape over time.

本発明の食品添加剤は、その様な機能を得るために粉末状セルロースを含有することを特徴とする。 The food additive of the present invention is characterized by containing powdered cellulose in order to obtain such a function.

本発明の食品添加剤に含まれる粉末状セルロースは、パルプ原料を塩酸、硫酸、硝酸などの鉱酸で酸加水分解処理したパルプを粉砕処理、あるいは酸加水分解処理を施さないパルプを機械粉砕して得ることができる。 The powdered cellulose contained in the food additive of the present invention is obtained by pulverizing a pulp obtained by acid-hydrolyzing a pulp raw material with a mineral acid such as hydrochloric acid, sulfuric acid or nitric acid, or mechanically pulverizing a pulp not subjected to acid hydrolysis. Can be obtained.

その様なパルプ原料としては、広葉樹由来のパルプ、針葉樹由来のパルプ、リンター由来のパルプ、非木材由来のパルプなど特に限定されるものではない。 Such pulp raw materials are not particularly limited, such as hardwood-derived pulp, softwood-derived pulp, linter-derived pulp, and non-wood-derived pulp.

また、本発明において、パルプ化法(蒸解法)は特に限定されるものではなく、サルファイト蒸解法、クラフト蒸解法、ソーダ・キノン蒸解法、オルガノソルブ蒸解法などを例示することができるが、これらの中では、環境面の点から、クラフトパルプが好ましい。 Further, in the present invention, the pulping method (melting method) is not particularly limited, and examples thereof include a sulfite cooking method, a kraft cooking method, a soda-quinone cooking method, and an organosolve cooking method. Of these, kraft pulp is preferable from the viewpoint of the environment.

本発明のパルプ原料はスラリー状の湿式パルプ、又はスラリーを脱水・乾燥させシート状にした乾式パルプのどちらでもよく特に限定されるものではないが、取扱いの簡便さから乾式パルプ(パルプシート)を用いるのが好ましい。 The pulp raw material of the present invention may be either a wet pulp in the form of a slurry or a dry pulp obtained by dehydrating and drying the slurry into a sheet, and is not particularly limited. It is preferable to use it.

その様にして得られた本発明の食品添加剤に含まれる粉末状セルロースは、平均粒子径は5〜75μmであることが重要である。平均粒子径が5μm未満であるとセルロース繊維が細かい為、食品に用いた際の保形性を得られ難い。また平均粒子径が75μmを超えると、セルロース繊維を感じやすくなるため、食感が低下する。 It is important that the powdered cellulose contained in the food additive of the present invention thus obtained has an average particle size of 5 to 75 μm. If the average particle size is less than 5 μm, the cellulose fibers are fine, and it is difficult to obtain shape retention when used in foods. Further, when the average particle size exceeds 75 μm, the cellulose fibers are easily felt, and the texture is deteriorated.

本発明の食品添加剤に含まれる粉末状セルロースは、粒度分布から算出される蓄積分布で、粒子径100μm以上の粉末状セルロースが0〜45.0体積%の範囲にあり、粒子径200μm以上の粉末状セルロースが0〜25.0体積%の範囲にあり、粒子径300μm以上の粉末状セルロースが0〜12.0体積%以下の範囲にあり、粒子径600μm以上の粉末状セルロースが0〜2.0体積%以下の範囲にあることが重要である。 The powdered cellulose contained in the food additive of the present invention has an accumulation distribution calculated from the particle size distribution, and the powdered cellulose having a particle size of 100 μm or more is in the range of 0 to 45.0% by volume, and the particle size is 200 μm or more. Powdered cellulose is in the range of 0 to 25.0% by volume, powdered cellulose having a particle size of 300 μm or more is in the range of 0 to 12.0% by volume or less, and powdered cellulose having a particle size of 600 μm or more is in the range of 0 to 2. It is important that it is in the range of 0.0% by volume or less.

また本発明の食品添加剤に含まれる粉末状セルロースは、平均重合度が100〜2500、結晶化度が60〜90%であることが望ましく、さらに平均繊維長が0.1〜1.0mmであることが望ましい。 The powdered cellulose contained in the food additive of the present invention preferably has an average degree of polymerization of 100 to 2500 and a crystallinity of 60 to 90%, and further has an average fiber length of 0.1 to 1.0 mm. It is desirable to have.

本発明の食品添加剤が、吸水/吸油助剤として用いられる場合には、以下の条件(A1)〜(E1)を満たすことが特に好ましい。
(A1)粉末状セルロースの平均粒子径が30〜67μm、
(B1)粒子径100μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で16.0〜37.0体積%の範囲にある。
(C1)粒子径200μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で4.0〜16.0体積%の範囲にある。
(D1)粒子径300μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜10.0体積%以下の範囲にある。
(E1)粒子径600μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜2.0体積%以下の範囲にある。
When the food additive of the present invention is used as a water absorption / oil absorption aid, it is particularly preferable that the following conditions (A1) to (E1) are satisfied.
(A1) The average particle size of powdered cellulose is 30 to 67 μm,
(B1) Powdered cellulose having a particle size of 100 μm or more is in the range of 16.0 to 37.0% by volume in the accumulation distribution calculated from the particle size distribution.
(C1) Powdered cellulose having a particle size of 200 μm or more is in the range of 4.0 to 16.0% by volume in the accumulation distribution calculated from the particle size distribution.
(D1) Powdered cellulose having a particle size of 300 μm or more is in the range of 0 to 10.0% by volume or less in the accumulation distribution calculated from the particle size distribution.
(E1) Powdered cellulose having a particle size of 600 μm or more is in the range of 0 to 2.0% by volume or less in the accumulation distribution calculated from the particle size distribution.

またその様な粉末状セルロースは、さらに平均重合度が300〜1500、結晶化度が75〜90%の範囲にあることが望ましく、平均繊維長が0.2〜1.0mmの範囲にあることがより望ましい。 Further, it is desirable that such powdered cellulose has an average degree of polymerization in the range of 300 to 1500 and a crystallinity in the range of 75 to 90%, and the average fiber length is in the range of 0.2 to 1.0 mm. Is more desirable.

本発明の食品添加剤が、結着防止剤又は着色助剤として用いられる場合には、以下の条件(A2)〜(E2)を満たすことが特に好ましい。
(A2)粉末状セルロースの平均粒子径が26〜45μm、
(B2)粒子径100μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で6.0〜45.0体積%の範囲にある。
(C2)粒子径200μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0.5〜14.0体積%の範囲にある。
(D2)粒子径300μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜10.0体積%以下の範囲にある。
(E2)粒子径600μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜1.0体積%以下の範囲にある。
When the food additive of the present invention is used as an anti-binding agent or a coloring aid, it is particularly preferable to satisfy the following conditions (A2) to (E2).
(A2) The average particle size of powdered cellulose is 26 to 45 μm,
(B2) Powdered cellulose having a particle size of 100 μm or more is in the range of 6.0 to 45.0% by volume in the accumulation distribution calculated from the particle size distribution.
(C2) Powdered cellulose having a particle size of 200 μm or more is in the range of 0.5 to 14.0% by volume in the accumulation distribution calculated from the particle size distribution.
(D2) Powdered cellulose having a particle size of 300 μm or more is in the range of 0 to 10.0% by volume or less in the accumulation distribution calculated from the particle size distribution.
(E2) Powdered cellulose having a particle size of 600 μm or more is in the range of 0 to 1.0% by volume or less in the accumulation distribution calculated from the particle size distribution.

またその様な粉末状セルロースは、さらに平均重合度が200〜1000、結晶化度が75〜90%の範囲にあることが望ましく、平均繊維長が0.2〜0.8mmの範囲にあることがより望ましい。 Further, such powdered cellulose preferably has an average degree of polymerization of 200 to 1000 and a crystallinity of 75 to 90%, and an average fiber length of 0.2 to 0.8 mm. Is more desirable.

本発明の食品添加剤が、食感改良剤又は保形助剤として用いられる場合には、以下の条件(A3)〜(E3)を満たすことが特に好ましい。
(A3)粉末状セルロースの平均粒子径が10〜40μm、
(B3)粒子径100μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で2.0〜45.0体積%の範囲にある。
(C3)粒子径200μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜14.0体積%の範囲にある。
(D3)粒子径300μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜10.0体積%以下の範囲にある。
(E3)粒子径600μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜1.0体積%以下の範囲にある。
When the food additive of the present invention is used as a texture improving agent or a shape-retaining aid, it is particularly preferable that the following conditions (A3) to (E3) are satisfied.
(A3) The average particle size of powdered cellulose is 10 to 40 μm,
(B3) Powdered cellulose having a particle size of 100 μm or more is in the range of 2.0 to 45.0% by volume in the accumulation distribution calculated from the particle size distribution.
(C3) Powdered cellulose having a particle size of 200 μm or more is in the range of 0 to 14.0% by volume in the accumulation distribution calculated from the particle size distribution.
(D3) Powdered cellulose having a particle size of 300 μm or more is in the range of 0 to 10.0% by volume or less in the accumulation distribution calculated from the particle size distribution.
(E3) Powdered cellulose having a particle size of 600 μm or more is in the range of 0 to 1.0% by volume or less in the accumulation distribution calculated from the particle size distribution.

またその様な粉末状セルロースは、さらに平均重合度が100〜1000、結晶化度が70〜90%の範囲にあることが望ましく、平均繊維長が0.1〜0.8mmの範囲にあることがより望ましい。 Further, it is desirable that such powdered cellulose has an average degree of polymerization in the range of 100 to 1000 and a crystallinity in the range of 70 to 90%, and the average fiber length is in the range of 0.1 to 0.8 mm. Is more desirable.

本発明における粉末状セルロースに、機能性付与、もしくは機能性向上を目的に、粉末状セルロースの原料とその他有機および/または無機成分を単独もしくは2種類以上任意の割合で混合し、粉砕することも可能である。また、原料に使用する天然セルロースの重合度を大幅に損なわない範囲で、化学的処理を施すことが可能である。 For the purpose of imparting functionality or improving functionality to the powdered cellulose in the present invention, the raw material of the powdered cellulose and other organic and / or inorganic components may be mixed alone or in an arbitrary ratio of two or more and pulverized. It is possible. In addition, it is possible to carry out chemical treatment within a range that does not significantly impair the degree of polymerization of natural cellulose used as a raw material.

その様な粉末状セルロースを含む食品添加剤の添加量は、各食品用途に対し期待される効果に応じて適宜調整することができる。 The amount of the food additive containing such powdered cellulose can be appropriately adjusted according to the expected effect for each food application.

以下に具体的な製造方法を示すが、本発明は該方法に限定されるものではない。なお使用した粉末状セルロースは、下記の方法にて測定を行った。 The specific production method is shown below, but the present invention is not limited to this method. The powdered cellulose used was measured by the following method.

<粉末状セルロースの平均粒子径及び粒子径分布測定>
レーザー回析式粒度分布測定装置(マスターサイザー2000、スペクトリス株式会社、マルバーン事業本部社製)を使用した。測定に用いる試料を0.5g、100mlビーカーに採取し、0.5%ヘキサメタリン酸溶液60mlを加え、Dr. Hielscher Gmbh社の超音波処理装置で、出力20%の条件で2分間処理し、処理した試料を測定に用いた。測定原理としてはレーザー散乱法を用いており、粒度分布を蓄積分布として表し、蓄積分布が50%となる値を平均粒子径とした。
<Measurement of average particle size and particle size distribution of powdered cellulose>
A laser diffraction type particle size distribution measuring device (Master Sizar 2000, Spectris Co., Ltd., manufactured by Malvern Business Headquarters) was used. The sample used for the measurement was collected in a 0.5 g, 100 ml beaker, 60 ml of a 0.5% hexametaphosphate solution was added, and the sample was treated with an ultrasonic processing device manufactured by Dr. Hielscher GmbH for 2 minutes under the condition of an output of 20%. Was used for the measurement. The laser scattering method was used as the measurement principle, the particle size distribution was represented as an accumulation distribution, and the value at which the accumulation distribution was 50% was defined as the average particle size.

また、粒子径が100μm以上の粉末状セルロースの割合、粒子径が200μm以上の粉末状セルロースの割合、粒子径が300μm以上の粉末状セルロースの割合、粒子径が600μm以上の粉末状セルロースの割合を、それぞれ蓄積分布の合計から算出した。 Further, the proportion of powdered cellulose having a particle size of 100 μm or more, the proportion of powdered cellulose having a particle diameter of 200 μm or more, the proportion of powdered cellulose having a particle diameter of 300 μm or more, and the proportion of powdered cellulose having a particle diameter of 600 μm or more. , Each was calculated from the total of the accumulated distribution.

<粉末状セルロースの重合度>
第16改正日本薬局方解説書、結晶セルロース確認試験(2)記載の銅エチレンジアミンを用いた粘度測定法により、セルロース重合度を求めた。
<Degree of polymerization of powdered cellulose>
The degree of cellulose polymerization was determined by the viscosity measurement method using copper ethylenediamine described in the 16th revised Japanese Pharmacopoeia Manual, Crystalline Cellulose Confirmation Test (2).

<粉末状セルロースの結晶化度>
結晶化度は、試料のX線回折を測定することで求めた。X線回折の測定は、適当量の試料をガラスセルに乗せ、X線回折測定装置(LabX XRD−6000、島津製作所製)を用いて測定した。結晶化度の算出は(L.Segal,J.J.Greely,etal,Text.Res.J.,29,786,1959)、および、Kamideらの手法(K.Kamide et al,Polymer J.,17,909,1985)を用いて行い、X線回折図の2θ=10°〜30°の回折強度をベースラインとして、2θ=22.6°の002面の回折強度と2θ=18.5°のアモルファス部分の回折強度から次式により算出した。
Xc=(I002c―Ia)/I002c×100
Xc=セルロースの結晶化度(%)
I002c:2θ=22.6°、002面の回折強度
Ia:2θ=18.5°、アモルファス部分の回折強度
<Crystallinity of powdered cellulose>
The crystallinity was determined by measuring the X-ray diffraction of the sample. The X-ray diffraction was measured by placing an appropriate amount of a sample on a glass cell and using an X-ray diffraction measuring device (LabX XRD-6000, manufactured by Shimadzu Corporation). The degree of crystallinity was calculated by (L. Segal, JJ Greery, amorphous, Text. Res. J., 29, 786, 1959) and the method of Kamide et al. (K. Kamide et al, Polymer J., 17,909,1985), with the diffraction intensity of 2θ = 10 ° to 30 ° in the X-ray diffraction diagram as the baseline, the diffraction intensity of the 002 surface of 2θ = 22.6 ° and 2θ = 18.5 °. It was calculated by the following formula from the diffraction intensity of the amorphous part of.
Xc = (I002c-Ia) / I002c × 100
Xc = Cellulose crystallinity (%)
I002c: 2θ = 22.6 °, diffraction intensity of 002 surface Ia: 2θ = 18.5 °, diffraction intensity of amorphous part

<粉末状セルロースの平均繊維長>
ファイバーテスター(Lorentzen & Wettre社製)を用いて、平均繊維長を測定した。本発明において、平均繊維長とは、長さ加重平均繊維長のことを示す。
<Average fiber length of powdered cellulose>
The average fiber length was measured using a fiber tester (manufactured by Lorentzen & Wettre). In the present invention, the average fiber length indicates a length-weighted average fiber length.

<粉末状セルロースの粉体落下速度>
上記製造例で得られた粉末状セルロース5gの試料を、パウダテスタ(PT−N型、ホソカワミクロン株式会社製)を用いて振動落下させ、全粉体が落下するのに必要な時間を測定した。この値が大きいほど、粉体流動性が良好であることを意味する。
<Powder falling speed of powdered cellulose>
The sample of 5 g of powdered cellulose obtained in the above production example was vibrated and dropped using a powder tester (PT-N type, manufactured by Hosokawa Micron Co., Ltd.), and the time required for the total powder to drop was measured. The larger this value is, the better the powder fluidity is.

(製造例1)
広葉樹由来パルプを、パルプ濃度5.5%、塩酸濃度を1.2Nに調整した条件下において95℃で2時間反応させた。反応が終了した後、水酸化ナトリウムで中和し、十分に水洗した後、60℃の温度条件化で約1日、送風乾燥した。乾燥後のサンプルを、ハンマーミル(ホソカワミクロン社製、AP−S型)を用いて機械的に粉砕を行い、粉末状セルロースA(平均粒子径24μm、平均重合度170、結晶化度86%、平均繊維長0.7mm、粉体落下速度0.37g/secであって、粒子径100μm以上が3.5体積%、粒子径200μm以上が0体積%)を得た。
(Manufacturing Example 1)
The hardwood-derived pulp was reacted at 95 ° C. for 2 hours under the conditions where the pulp concentration was adjusted to 5.5% and the hydrochloric acid concentration was adjusted to 1.2N. After the reaction was completed, the mixture was neutralized with sodium hydroxide, washed thoroughly with water, and then air-dried under a temperature condition of 60 ° C. for about 1 day. The dried sample is mechanically pulverized using a hammer mill (AP-S type manufactured by Hosokawa Micron), and powdered cellulose A (average particle size 24 μm, average degree of polymerization 170, degree of crystallization 86%, average). The fiber length was 0.7 mm, the powder falling speed was 0.37 g / sec, 3.5% by volume was obtained when the particle size was 100 μm or more, and 0% by volume was obtained when the particle size was 200 μm or more).

(製造例2)
広葉樹由来パルプを、パルプ濃度5.5%、塩酸濃度を0.15Nに調整した条件下において95℃で2時間反応させた。反応が終了した後、水酸化ナトリウムで中和し、十分に水洗した後、60℃の温度条件化で約1日、送風乾燥した。乾燥後のサンプルを、ハンマーミル(ホソカワミクロン社製、AP−S型)を用いて機械的に粉砕を行い、粉末状セルロースB(平均粒子径36μm、平均重合度470、結晶化度86%、平均繊維長0.7mm、粉体落下速度0.14g/secであって、粒子径100μm以上が17.0体積%、粒子径200μm以上が5.0体積%、粒子径300μm以上が2.0体積%、粒子径600μm以上が0体積%)を得た。
(Manufacturing Example 2)
The hardwood-derived pulp was reacted at 95 ° C. for 2 hours under the conditions where the pulp concentration was adjusted to 5.5% and the hydrochloric acid concentration was adjusted to 0.15 N. After the reaction was completed, the mixture was neutralized with sodium hydroxide, washed thoroughly with water, and then air-dried under a temperature condition of 60 ° C. for about 1 day. The dried sample is mechanically pulverized using a hammer mill (AP-S type manufactured by Hosokawa Micron), and powdered cellulose B (average particle size 36 μm, average degree of polymerization 470, degree of crystallization 86%, average). The fiber length is 0.7 mm, the powder drop rate is 0.14 g / sec, the particle size is 100 μm or more, 17.0% by volume, the particle size of 200 μm or more is 5.0% by volume, and the particle size of 300 μm or more is 2.0 volume. %, 0% by volume when the particle size is 600 μm or more) was obtained.

(製造例3)
広葉樹由来パルプを、パルプ濃度5.5%、塩酸濃度を0.15Nに調整した条件下において95℃で2時間反応させた。反応が終了した後、水酸化ナトリウムで中和し、十分に水洗した後、60℃の温度条件化で約1日、送風乾燥した。乾燥後のサンプルを、ハンマーミル(ホソカワミクロン社製、AP−S型)を用いて機械的に粉砕を行い、粉末状セルロースC(平均粒子径26.3μm、平均重合度440、結晶化度85.3%、平均繊維長0.23mmであって、粒子径100μm以上が5.1体積%、粒子径200μm以上が0.5体積%、粒子径300μm以上が0体積%)を得た。
(Manufacturing Example 3)
The hardwood-derived pulp was reacted at 95 ° C. for 2 hours under the conditions where the pulp concentration was adjusted to 5.5% and the hydrochloric acid concentration was adjusted to 0.15 N. After the reaction was completed, the mixture was neutralized with sodium hydroxide, washed thoroughly with water, and then air-dried under a temperature condition of 60 ° C. for about 1 day. The dried sample was mechanically pulverized using a hammer mill (AP-S type manufactured by Hosokawa Micron) to obtain powdered cellulose C (average particle size 26.3 μm, average polymerization degree 440, crystallinity degree 85. 3%, the average fiber length was 0.23 mm, 5.1% by volume was obtained with a particle size of 100 μm or more, 0.5% by volume was obtained with a particle size of 200 μm or more, and 0% by volume was obtained with a particle size of 300 μm or more.

(製造例4)
広葉樹由来パルプを、パルプ濃度5.5%、塩酸濃度を0.15Nに調整した条件下において95℃で2時間反応させた。反応が終了した後、水酸化ナトリウムで中和し、十分に水洗した後、60℃の温度条件化で約1日、送風乾燥した。乾燥後のサンプルを、ハンマーミル(ホソカワミクロン社製、AP−S型)を用いて機械的に粉砕を行い、粉末状セルロースD(平均粒子径42.3μm、平均重合度980、結晶化度83.3%、平均繊維長0.32mmであって、粒子径100μm以上が19.2体積%、粒子径200μm以上が7.1体積%、粒子径300μm以上が2.0体積%、粒子径600μm以上が0.3体積%)を得た。
(Manufacturing Example 4)
The hardwood-derived pulp was reacted at 95 ° C. for 2 hours under the conditions where the pulp concentration was adjusted to 5.5% and the hydrochloric acid concentration was adjusted to 0.15 N. After the reaction was completed, the mixture was neutralized with sodium hydroxide, washed thoroughly with water, and then air-dried under a temperature condition of 60 ° C. for about 1 day. The dried sample was mechanically pulverized using a hammer mill (AP-S type manufactured by Hosokawa Micron Co., Ltd.), and powdered cellulose D (average particle size 42.3 μm, average degree of polymerization 980, degree of crystallization 83. 3%, average fiber length 0.32 mm, particle size 100 μm or more is 19.2% by volume, particle size 200 μm or more is 7.1% by volume, particle size 300 μm or more is 2.0% by volume, particle size 600 μm or more. Was obtained (0.3% by volume).

(製造例5)
広葉樹由来パルプを、パルプ濃度5.5%、塩酸濃度を0.15Nに調整した条件下において95℃で2時間反応させた。反応が終了した後、水酸化ナトリウムで中和し、十分に水洗した後、60℃の温度条件化で約1日、送風乾燥した。乾燥後のサンプルを、ハンマーミル(ホソカワミクロン社製、AP−S型)を用いて機械的に粉砕を行い、粉末状セルロースE(平均粒子径62.1μm、平均重合度1221、結晶化度82.2%、平均繊維長0.34mmであって、粒子径100μm以上が28.2体積%、粒子径200μm以上が11.1体積%、粒子径300μm以上が4.1体積%、粒子径600μm以上が1.1体積%)を得た。
(Manufacturing Example 5)
The hardwood-derived pulp was reacted at 95 ° C. for 2 hours under the conditions where the pulp concentration was adjusted to 5.5% and the hydrochloric acid concentration was adjusted to 0.15 N. After the reaction was completed, the mixture was neutralized with sodium hydroxide, washed thoroughly with water, and then air-dried under a temperature condition of 60 ° C. for about 1 day. The dried sample was mechanically pulverized using a hammer mill (AP-S type manufactured by Hosokawa Micron) to obtain powdered cellulose E (average particle size 62.1 μm, average degree of polymerization 1221, degree of crystallization 82. 2%, average fiber length 0.34 mm, particle size 100 μm or more is 28.2% by volume, particle size 200 μm or more is 11.1% by volume, particle size 300 μm or more is 4.1% by volume, particle size 600 μm or more. Was 1.1% by volume).

(製造例6)
広葉樹由来パルプを、パルプ濃度5.5%、塩酸濃度を1.2Nに調整した条件下において95℃で2時間反応させた。反応が終了した後、水酸化ナトリウムで中和し、十分に水洗した後、60℃の温度条件化で約1日、送風乾燥した。乾燥後のサンプルを、ハンマーミル(ホソカワミクロン社製、AP−S型)を用いて機械的に粉砕を行い、粉末状セルロースF(平均粒子径10.4μm、平均重合度158、結晶化度73.3%、平均繊維長0.14mmであって、粒子径100μm以上が2.1体積%、粒子径200μm以上が0体積%)を得た。
(Manufacturing Example 6)
The hardwood-derived pulp was reacted at 95 ° C. for 2 hours under the conditions where the pulp concentration was adjusted to 5.5% and the hydrochloric acid concentration was adjusted to 1.2N. After the reaction was completed, the mixture was neutralized with sodium hydroxide, washed thoroughly with water, and then air-dried under a temperature condition of 60 ° C. for about 1 day. The dried sample was mechanically pulverized using a hammer mill (AP-S type manufactured by Hosokawa Micron) to obtain powdered cellulose F (average particle size 10.4 μm, average degree of polymerization 158, crystallinity 73. 3%, the average fiber length was 0.14 mm, 2.1% by volume was obtained with a particle size of 100 μm or more, and 0% by volume was obtained with a particle size of 200 μm or more).

以下に実施例及び比較例を示すが、特段の明記がない限りこれらに用いられた食品材料は市販のものを用いたことを意味する。 Examples and comparative examples are shown below, but unless otherwise specified, it means that the food materials used for these are commercially available ones.

<実施例1>
挽肉53.1部、玉ねぎ21.1部、パン粉10.5部、卵6.3部、食塩0.8部、粉末状セルロースB5.0部、水3.2部からなるハンバーグ処方のうち、
挽肉、玉ねぎ、パン粉、卵、食塩、水をSKミキサーで3分間混合した後、粉末状セルロースAを加えてよく混ぜ、100gずつ小判型に成形した。このハンバーグをフライパン中で、強火で両面を計2分、その後弱火にしてからフタをして両面を計12分加熱調理し、ハンバーグを得た。
<Example 1>
Of the hamburger formula consisting of 53.1 parts of minced meat, 21.1 parts of onions, 10.5 parts of bread crumbs, 6.3 parts of eggs, 0.8 parts of salt, 5.0 parts of powdered cellulose B, and 3.2 parts of water.
Minced meat, onions, bread crumbs, eggs, salt, and water were mixed with an SK mixer for 3 minutes, then powdered cellulose A was added and mixed well, and 100 g each was formed into an oval shape. This hamburger was cooked in a frying pan over high heat for a total of 2 minutes on both sides, then on low heat, covered and cooked on both sides for a total of 12 minutes to obtain a hamburger.

得られたハンバーグ10gを、20人のパネラーによる試食評価を行い、下記の基準にて評価を行い平均値を得た。結果を表1に示す。
○:肉汁の保ちがよくジューシーであり、食感に優れる。
×:肉汁の保ちが劣りパサパサし、食感に劣る。
The obtained hamburger steak (10 g) was tasted and evaluated by 20 panelists, and evaluated according to the following criteria to obtain an average value. The results are shown in Table 1.
◯: The gravy is well preserved and juicy, and the texture is excellent.
X: Poor retention of gravy, dry and inferior texture.

<実施例2>
強力小麦粉100.0部、砂糖6.0部、食塩2.0部、粉乳2.0部、ドライイースト1.5部、ショートニング5.0部、粉末状セルロースB5.0部、 水 62.0部からなるパン処方のうち、
強力小麦粉にドライイースト、食塩、砂糖を混合し、よくこねた。ショートニング、粉末状セルロースAを加水しながら混ぜ、生地を小さくまとめる。生地を30℃、40分間発酵させる。発酵生地を200℃、30分間オーブンで焼き、パンを得た。
<Example 2>
10.0 parts of strong wheat flour, 6.0 parts of sugar, 2.0 parts of salt, 2.0 parts of milk powder, 1.5 parts of dry yeast, 5.0 parts of shortening, 5.0 parts of powdered cellulose B, 62.0 parts of water Of the bread prescription consisting of parts
Dry yeast, salt and sugar were mixed with strong wheat flour and kneaded well. Mix the shortening and powdered cellulose A while adding water to make the dough into small pieces. Ferment the dough at 30 ° C for 40 minutes. The fermented dough was baked in an oven at 200 ° C. for 30 minutes to obtain bread.

得られたパン10gを、20人のパネラーによる試食評価を行い、下記の基準にて評価を行い平均値を得た。結果を表1に示す。
○:生地に水分が保たれしっとりとしており、食感に優れる。
×:生地がパサパサしており、食感に劣る。
The obtained bread was evaluated for tasting by 20 panelists, and evaluated according to the following criteria to obtain an average value. The results are shown in Table 1.
◯: The dough retains moisture and is moist, and has an excellent texture.
X: The dough is dry and the texture is inferior.

<実施例3>
白身魚100.0部、食塩 2.0部、味醂3.0部、粉末状セルロースB3.0部 からなる蒲鉾処方のうち、
白身魚を三枚におろし、骨、内蔵、皮を取り除いた。身をみじん切りにし、水気を取った。粉末セルロースを混ぜ、フードプロセッサーですり潰した。塩、味醂を混ぜ、成形後冷蔵庫で1日寝かせた。寝かせたものを20分蒸し、その後冷水で冷やし、蒲鉾を得た。
<Example 3>
Of the Kamaboko prescription consisting of 100.0 parts of white fish, 2.0 parts of salt, 3.0 parts of mirin, and 3.0 parts of powdered cellulose B
The white fish was cut into three pieces and the bones, internal organs and skin were removed. I chopped myself and drained it. Powdered cellulose was mixed and ground in a food processor. Salt and mirin were mixed, and after molding, they were left in the refrigerator for one day. The laid one was steamed for 20 minutes and then cooled with cold water to obtain Kamaboko.

得られた蒲鉾10gを、20人のパネラーによる試食評価を行い、下記の基準にて評価を行い平均値を得た。結果を表1に示す。
○:蒲鉾に水分が保たれしっとりとしており、食感に優れる。
×:蒲鉾がパサパサしており、食感に劣る。
The obtained 10 g of Kamaboko was tasted and evaluated by 20 panelists, and evaluated according to the following criteria to obtain an average value. The results are shown in Table 1.
◯: The kamaboko retains moisture and is moist, and has an excellent texture.
×: Kamaboko is dry and has a poor texture.

<実施例4>
唐揚げ粉95.0部、粉末状セルロースB5.0部 からなる唐揚げ衣処方のうち、
市販の唐揚げ粉に粉末状セルロースBを混ぜ合わせた。混ぜ合わせた粉を同量の水で溶き、バッター液を作成した。その後、鶏肉をバッター液に付け込み、170℃で4分間フライし、唐揚げを得た。
<Example 4>
Of the fried batter prescription consisting of 95.0 parts of fried chicken powder and 5.0 parts of powdered cellulose B
Powdered cellulose B was mixed with commercially available fried chicken powder. The mixed powder was dissolved in the same amount of water to prepare a batter solution. Then, the chicken was soaked in a batter solution and fried at 170 ° C. for 4 minutes to obtain fried chicken.

得られた唐揚げ10gを、20人のパネラーによる試食評価を行い、下記の基準にて評価を行い平均値を得た。結果を表1に示す。
○:唐揚げの衣に油がしみてよく揚がってサクサクしており、食感に優れる。
×:唐揚げの衣が粉っぽく、食感に劣る。
The obtained fried chicken was evaluated for tasting by 20 panelists, and evaluated according to the following criteria to obtain an average value. The results are shown in Table 1.
◯: The fried batter is soaked with oil and is well fried and crispy, and has an excellent texture.
×: The fried batter is powdery and has a poor texture.

<実施例5>
豚ひき肉80.0部、玉ねぎ15.0部、食塩1.0部、胡椒1.0部、粉末状セルロースB3.0部 からなるソーセージ処方のうち、
豚ひき肉、玉ねぎをみじん切りにし、食塩、胡椒、粉末状セルロースBを混ぜ込んだ。混ぜたものをスプーンでラップにとり、ソーセージの形に成形した。その後蒸し器で15分蒸し、ソーセージを得た。
<Example 5>
Of the sausage formula consisting of 80.0 parts of minced pork, 15.0 parts of onion, 1.0 part of salt, 1.0 part of pepper, and 3.0 parts of powdered cellulose B.
Minced pork and onions were chopped and mixed with salt, pepper and powdered cellulose B. The mixture was wrapped with a spoon and molded into a sausage shape. Then, it was steamed in a steamer for 15 minutes to obtain sausage.

得られたソーセージは、20人のパネラーによる試食評価を行い、下記の基準にて評価を行い平均値を得た。結果を表1に示す。
○:肉汁の保ちが良くジューシーであり、食感に優れる。
×:肉汁の保ちが劣り、食感に劣る。
The obtained sausages were tasted and evaluated by 20 panelists, and evaluated according to the following criteria to obtain an average value. The results are shown in Table 1.
◯: Good retention of gravy, juicy, and excellent texture.
X: Poor retention of gravy and poor texture.

<比較例1〜5>
実施例1〜5において、粉末状セルロースを添加しなかったこと以外は、実施例1〜5と同様にして評価を行った。
<Comparative Examples 1 to 5>
Evaluation was carried out in the same manner as in Examples 1 to 5 except that powdered cellulose was not added in Examples 1 to 5.

Figure 0006938922
Figure 0006938922

<実施例6>
チーズ100重量部に対して、粉末状セルロースB1.5重量部をまぶし、試験チーズを得た。得られた試験チーズを積層し、50gの重しをさらに乗せ1時間静置した後、下記の基準で結着防止性を評価し平均値を得た。結果を表2に示す。
○:チーズ同士を簡単にはがせ、結着防止効果に優れる。
×:チーズ同士が結着し、剥がした際にチーズ形の変形を伴う。
<Example 6>
A test cheese was obtained by sprinkling 1.5 parts by weight of powdered cellulose B on 100 parts by weight of cheese. The obtained test cheeses were laminated, a weight of 50 g was further placed on the cheese, and the mixture was allowed to stand for 1 hour, and then the anti-binding property was evaluated according to the following criteria to obtain an average value. The results are shown in Table 2.
◯: Cheese can be easily peeled off from each other and has an excellent effect of preventing binding.
X: Cheeses are bound to each other, and when they are peeled off, the cheese shape is deformed.

<比較例6>
粉末状セルロースを用いなかった以外は実施例6と同様にして評価を行った。
<Comparative Example 6>
The evaluation was carried out in the same manner as in Example 6 except that powdered cellulose was not used.

Figure 0006938922
Figure 0006938922

<実施例7>
ホットケーキミックス80部、砂糖5部 、牛乳10部 、卵1個 、粉末セルロースA5部からなる焼き菓子処方のうち、ホットケーキミックス、砂糖、牛乳、卵、粉末状セルロースBをかき混ぜた。型に生地を流し込み、オーブンを用いて180℃、20分で焼き上げホットケーキを得た。
<Example 7>
Of the baked confectionery formula consisting of 80 parts of hot cake mix, 5 parts of sugar, 10 parts of milk, 1 egg, and 5 parts of powdered cellulose A, the hot cake mix, sugar, milk, eggs, and powdered cellulose B were stirred. The dough was poured into a mold and baked in an oven at 180 ° C. for 20 minutes to obtain a panque.

得られたホットケーキを20人のパネラーで目視観察し、下記の基準で焼き色を評価し平均値を得た。結果を表3に示す。
○:焼き上げ前後でしっかりとした変色が起こり、焼き色に優れる。
×:焼き上げ前後であまり変色が起こらなく、焼き色に劣る。
The obtained hot cake was visually observed by 20 panelists, and the baking color was evaluated according to the following criteria to obtain an average value. The results are shown in Table 3.
◯: Firm discoloration occurs before and after baking, and the baking color is excellent.
X: The color does not change much before and after baking, and the color is inferior to the baking color.

<比較例7>
実施例7において、粉末状セルロースを添加しなかったこと以外は、実施例7と同様にして評価を行った。
<Comparative Example 7>
Evaluation was carried out in the same manner as in Example 7 except that powdered cellulose was not added in Example 7.

Figure 0006938922
Figure 0006938922

<実施例8>
みかんジュース(果汁100%)90.0部 、ゼラチン 7.0部 、粉末セルロースA3.0部からなるゼリー処方の内、
みかんジュース(果汁100%)、ゼラチン、粉末状セルロースAをかき混ぜた。型に生地を流し込み、冷蔵庫で1時間冷やし、ゼリーを得た。
<Example 8>
Of the jelly formula consisting of 90.0 parts of tangerine juice (100% fruit juice), 7.0 parts of gelatin, and 3.0 parts of powdered cellulose A,
Mandarin juice (100% fruit juice), gelatin, and powdered cellulose A were stirred. The dough was poured into a mold and chilled in the refrigerator for 1 hour to obtain jelly.

得られたゼリーを20人のパネラーで試食評価を行い、下記の基準にて評価し平均値を得た。結果を表4に示す。
○:繊維質の食感を感じ、食感が増す。
×:食感の変化を感じない。
The obtained jelly was tasted and evaluated by 20 panelists, and evaluated according to the following criteria to obtain an average value. The results are shown in Table 4.
◯: Feel the texture of fiber, and the texture increases.
×: No change in texture is felt.

<実施例9>
鮭そぼろ98重量部に、粉末状セルロースAを2重量部混ぜ、鮭そぼろ組成物を得た。
得られた鮭そぼろ組成物は20人のパネラーに試食評価を行い、下記の基準にて食感を評価し平均値を得た。
○:繊維感を増しふっくらとした食感となり、食感に優れる。
×:触感の変化を感じない。
<Example 9>
2 parts by weight of powdered cellulose A was mixed with 98 parts by weight of salmon soboro to obtain a salmon soboro composition.
The obtained salmon soboro composition was tasted and evaluated by 20 panelists, and the texture was evaluated according to the following criteria to obtain an average value.
◯: The texture is increased and the texture becomes plump, and the texture is excellent.
×: No change in tactile sensation is felt.

<実施例10>
山葵98重量部に、粉末状セルロースAを2重量部混ぜ、山葵組成物を得た。得られた山葵組成物は20人のパネラーに試食評価を行い、下記の基準にて食感を評価し平均値を得た。
○:繊維感の食感を感じ、食感が増す。
×:食感の変化を感じない。
<Example 10>
2 parts by weight of powdered cellulose A was mixed with 98 parts by weight of wasabi to obtain a wasabi composition. The obtained wasabi composition was tasted and evaluated by 20 panelists, and the texture was evaluated according to the following criteria to obtain an average value.
◯: Feel the texture of fiber, and the texture increases.
×: No change in texture is felt.

<比較例8〜10>
実施例8〜10において、粉末状セルロースを添加しなかったこと以外は、実施例8〜10と同様にして評価を行った。
<Comparative Examples 8 to 10>
Evaluation was carried out in the same manner as in Examples 8 to 10 except that powdered cellulose was not added in Examples 8 to 10.

Figure 0006938922
Figure 0006938922

<実施例11>
ホイップクリーム原液90.0部 、砂糖8.0部、粉末セルロースA2.0部からなるホイップクリーム処方の内、ホイップクリーム原液に砂糖と粉末セルロースAを添加し、10分間ハンドミキサーで10℃に調温しながら撹拌し、ホイップクリーム組成物を調整した。
得られたホイップクリーム組成物10gを、直径2cmの円柱状の型に詰めたのち、型を外し、25℃で10分間静置し、下記の基準にて保形性を目視評価し平均値を得た。
○:円柱形状を保ち、保形性に優れる。
×:円柱形状が崩れ始め、保形性に劣る。
<Example 11>
Of the whipped cream formulation consisting of 90.0 parts of whipped cream stock solution, 8.0 parts of sugar, and 2.0 parts of powdered cellulose A, sugar and powdered cellulose A are added to the whipped cream stock solution, and the temperature is adjusted to 10 ° C with a hand mixer for 10 minutes. The whipped cream composition was adjusted by stirring with warmth.
After packing 10 g of the obtained whipped cream composition into a columnar mold having a diameter of 2 cm, the mold is removed, and the mixture is allowed to stand at 25 ° C. for 10 minutes. Obtained.
◯: Maintains a cylindrical shape and has excellent shape retention.
X: The cylindrical shape begins to collapse and the shape retention is inferior.

<実施例12>
フリーズドライソフトクリーム粉末 50.0重量部、卵白30.0重量部、砂糖20.0重量部、粉末セルロースA2.0重量部からなるフリーズドライソフトクリーム処方の内、フリーズドライソフトクリーム粉末に卵白、砂糖、粉末セルロースAを添加し、10分間ハンドミキサーで10℃に調温しながら撹拌し、その後0℃以下で冷やし、フリーズドライソフトクリーム組成物を得た。
得られたフリーズドライソフトクリーム組成物10gを、直径2cmの円柱状の型に詰めたのち、型を外し、25℃で10分間静置し、下記の基準にて保形性を目視評価し平均値を得た。
○:円柱形状を保ち、保形性に優れる。
×:円柱形状が崩れ始め、保形性に劣る。
<Example 12>
Freeze-dried soft serve ice cream powder 50.0 parts by weight, egg white 30.0 parts by weight, sugar 20.0 parts by weight, powdered cellulose A 2.0 parts by weight Sugar and powdered cellulose A were added, and the mixture was stirred with a hand mixer for 10 minutes while adjusting the temperature to 10 ° C., and then cooled at 0 ° C. or lower to obtain a freeze-dried soft serve ice cream composition.
10 g of the obtained freeze-dried soft serve ice cream composition was packed in a columnar mold having a diameter of 2 cm, then the mold was removed, and the mixture was allowed to stand at 25 ° C. for 10 minutes. Got a value.
◯: Maintains a cylindrical shape and has excellent shape retention.
X: The cylindrical shape begins to collapse and the shape retention is inferior.

<比較例11〜12>
実施例11〜12において、粉末状セルロースを添加しなかったこと以外は、実施例11〜12と同様にして評価を行った。
<Comparative Examples 11-12>
Evaluation was carried out in the same manner as in Examples 11 to 12 except that powdered cellulose was not added in Examples 11 to 12.

Figure 0006938922
Figure 0006938922

<実施例13>
ポテトフレーク60質量部、食塩1.5重量部、うまみ調味料(製品名:味の素株式会社)1.2質量部、粉末状セルロースC2.5質量部を配合し、次に水60質量部を添加しながら混練しポテト生地を得た。得られたポテト生地を押出し式成形機(型番:DK524;貝印産業社製)を用いて直径7mmの円筒形に成形し、次いで−20℃で3時間冷凍した後に、長さ約7cmにカットして円筒状の成型したポテト生地を得た。得られた円筒状に成型したポテト生地を、サラダ油で170℃、25秒間揚げて、成型スナック菓子(ポテトスナック)を得た。
実施例13成型スナック菓子は、下記の評価を実施した。
<Example 13>
60 parts by mass of potato flakes, 1.5 parts by mass of salt, 1.2 parts by mass of flavor seasoning (product name: Ajinomoto Co., Inc.), 2.5 parts by mass of powdered cellulose C are mixed, and then 60 parts by mass of water is added. While kneading, a potato dough was obtained. The obtained potato dough was formed into a cylindrical shape with a diameter of 7 mm using an extrusion molding machine (model number: DK524; manufactured by Kai Sangyo Co., Ltd.), then frozen at -20 ° C for 3 hours, and then cut to a length of about 7 cm. To obtain a cylindrical molded potato dough. The obtained cylindrically molded potato dough was fried in salad oil at 170 ° C. for 25 seconds to obtain a molded snack (potato snack).
Example 13 The molded snack confectionery was evaluated as follows.

<評価:成型時のひび割れ>
10枚の円筒状に成型したポテト生地(試験片)を水平面に並べ、表面及び裏面の両方を目視にて確認し、試験片一枚あたりのひび割れの発生数の平均値を下記の基準に従い評価した。
◎:ひび割れの発生個数の平均値が0〜5個
○:ひび割れの発生個数の平均値が5〜10個
×:ひび割れの発生個数の平均値が10個超
<Evaluation: Cracks during molding>
Ten potato dough (test pieces) molded into a cylindrical shape are arranged on a horizontal plane, both the front surface and the back surface are visually confirmed, and the average value of the number of cracks generated per test piece is evaluated according to the following criteria. bottom.
⊚: The average number of cracks is 0 to 5 ○: The average number of cracks is 5 to 10 ×: The average number of cracks is more than 10.

<評価:食感>
熟練した20名のパネラーに対し、実施例及び比較例で得られた成型ポテトスナックを独立したパネルで食味するランダムテスト方式にて、歯ごたえのある食感を有するかのテストを実施し、各パネラーが結果を1〜10点で記した。点数が高いほど歯ごたえのある食感であり、下記の平均点を基準とし、食感の評価とした。
◎:平均点が8〜10点であり、サクサクした食感に優れる。
○:平均点が5〜8点であり、サクサクした食感を感じることができる。
×:平均点が5点未満であり、サクサクした食感が薄い。
<Evaluation: Texture>
Twenty skilled panelists were tested to see if they had a chewy texture by a random test method in which the molded potato snacks obtained in the examples and comparative examples were tasted on independent panels, and each panelist. Wrote the results on a scale of 1-10. The higher the score, the more chewy the texture, and the texture was evaluated based on the following average score.
⊚: The average score is 8 to 10, and the texture is crispy.
◯: The average score is 5 to 8, and a crispy texture can be felt.
X: The average score is less than 5, and the crispy texture is light.

<実施例14>
粉末状セルロースDを用いた以外は、実施例13と同様にして成型スナック菓子(ポテトスナック)を得た。
<Example 14>
Molded snacks (potato snacks) were obtained in the same manner as in Example 13 except that powdered cellulose D was used.

<実施例15>
粉末状セルロースEを用いた以外は、実施例13と同様にして成型スナック菓子(ポテトスナック)を得た。
<Example 15>
Molded snacks (potato snacks) were obtained in the same manner as in Example 13 except that powdered cellulose E was used.

<比較例13>
粉末状セルロースを配合しなかった以外は、実施例13と同様に成型スナック菓子(ポテトスナック)を得た。
<Comparative Example 13>
Molded snacks (potato snacks) were obtained in the same manner as in Example 13 except that powdered cellulose was not blended.

実施例14〜15及び比較例13の成型スナック菓子は、下記の評価を実施した。
<評価:成型時のひび割れ>
実施例13と同様にして実施した。
The molded snack foods of Examples 14 to 15 and Comparative Example 13 were evaluated as follows.
<Evaluation: Cracks during molding>
It was carried out in the same manner as in Example 13.

<評価:食感>
熟練した20名のパネラーに対し、実施例及び比較例で得られた成型ポテトスナックを独立したパネルで食味するランダムテスト方式にて、歯ごたえのある食感を有するかのテストを実施し、各パネラーが結果を1〜10点で記した。点数が高いほど歯ごたえのある食感であり、下記の平均点を基準とし、食感の評価とした。
◎:平均点が8〜10点であり、歯ごたえのある食感に優れる。
○:平均点が5〜8点であり、歯ごたえのある食感を感じることができる。
×:平均点が5点未満であり、歯ごたえのある食感が薄い。
<Evaluation: Texture>
Twenty skilled panelists were tested to see if they had a chewy texture by a random test method in which the molded potato snacks obtained in the examples and comparative examples were tasted on independent panels, and each panelist. Wrote the results on a scale of 1-10. The higher the score, the more chewy the texture, and the texture was evaluated based on the following average score.
⊚: The average score is 8 to 10, and the texture is excellent.
◯: The average score is 5 to 8, and a chewy texture can be felt.
X: The average score is less than 5, and the texture is light and chewy.

<評価:硬さ>
熟練した20名のパネラーにて、独立したパネルで実施例及び比較例で得られた成型ポテトスナックの両端を左右両方の親指と人差し指ではさんでもち、力をこめ割り、割れたさいの触感(抵抗感)を、ランダムテスト方式により実施し、下記の通り硬さの評価とした。
◎:力を込めなければ割れず、抵抗感が強い。
○:力を込めると割れるが、抵抗感がある。
×:軽い力で割れ、抵抗感が少ない。
<Evaluation: Hardness>
Twenty skilled panelists sandwiched both ends of the molded potato snacks obtained in the examples and comparative examples with independent panels between the left and right thumbs and index fingers, and squeezed them with force to create a cracked tactile sensation. Resistance) was performed by a random test method, and the hardness was evaluated as follows.
⊚: It will not crack unless force is applied, and there is a strong sense of resistance.
◯: It cracks when force is applied, but there is a feeling of resistance.
×: It cracks with a light force and there is little resistance.

Figure 0006938922
Figure 0006938922

<実施例16>
市販の強力粉60重量部、薄力粉30重量部、馬鈴薯澱粉5%、加工澱粉5%、卵白粉末2.5重量部、小麦タンパク2重量部、食塩3重量部、粉末状セルロースC1.5重量に、練り水40.5重量部及びかんすい2.5重量部を添加しながらよく混合し麺生地を作製した。次に製麺ロールで伸ばし、所定の方法に従い麺線を作製し、100℃の上記で蒸したのち、130〜160℃の油で乾燥させた後、即席麺を得た。
<Example 16>
60 parts by weight of commercially available strong flour, 30 parts by weight of weak flour, 5% of potato starch, 5% of processed starch, 2.5 parts by weight of egg white powder, 2 parts by weight of wheat protein, 3 parts by weight of salt, 1.5 parts by weight of powdered cellulose C , 40.5 parts by weight of kneaded water and 2.5 parts by weight of starch were added and mixed well to prepare a noodle dough. Next, the noodles were stretched with a noodle-making roll to prepare noodle strings according to a predetermined method, steamed at 100 ° C. above, and dried with oil at 130 to 160 ° C. to obtain instant noodles.

<実施例17>
粉末状セルロースFを用いた以外は、実施例16と同様にして即席麺を得た。
<Example 17>
Instant noodles were obtained in the same manner as in Example 16 except that powdered cellulose F was used.

<比較例14>
粉末状セルロースを用いなかったこと以外は、実施例16と同様にして、即席麺を得た。
<Comparative Example 14>
Instant noodles were obtained in the same manner as in Example 16 except that powdered cellulose was not used.

<評価>
実施例16〜17及び比較例14で得られた即席麺は、容器に即席麺(70g)を入れ、熱湯(350g)を注ぎ3分間復元させ(湯戻し)、麺の復元性と食感を評価した。
<Evaluation>
For the instant noodles obtained in Examples 16 to 17 and Comparative Example 14, the instant noodles (70 g) were put in a container, and boiling water (350 g) was poured to restore the noodles for 3 minutes (rehydrated) to improve the stability and texture of the noodles. evaluated.

<即席麺の復元性>
3分放置後の湯中での麺のほぐれ具合(湯戻し)について、熟練した20名のパネラーがさいばしを用いかき混ぜた際のほぐれ具合をもとに、目視にて1〜10点で評価し、20名の平均点を算出した。点数が高いほど麺のほぐれ具合が良好である。
○:平均点が7〜10であり、湯戻しによる復元性が良好。
△:平均点が4〜6であり、湯戻しによる復元性が認められる。
×:平均点が4未満であり、湯戻しによる復元性に劣る。
<Stability of instant noodles>
The degree of loosening (returning) of noodles in hot water after leaving for 3 minutes was visually evaluated on a scale of 1 to 10 based on the degree of loosening when agitated by 20 skilled panelists using Saibashi. , The average score of 20 people was calculated. The higher the score, the better the loosening of the noodles.
◯: The average score is 7 to 10, and the stability by reconstitution with hot water is good.
Δ: The average score is 4 to 6, and the stability by reconstitution with hot water is recognized.
X: The average score is less than 4, and the stability by reconstitution with hot water is inferior.

<即席麺の食感>
3分放置後の麺を20名のパネラーが独立したパネルで食味するランダムテスト方式を行い、粉っぽさやコシ、硬さからの食味を総合的に1〜10点で評価し、20名の平均値を算出した。点数が高いほど麺の食感が良好な評価である。
○:平均点が7〜10であり、食感が良好。
△:平均点が4〜6であり、若干食感が劣る。
×:平均点が4未満であり、食感に劣る。
<Texture of instant noodles>
A random test method was conducted in which 20 panelists tasted the noodles after leaving them for 3 minutes on an independent panel, and the taste from powderiness, firmness, and hardness was evaluated comprehensively on a scale of 1 to 10, and 20 people evaluated the noodles. The average value was calculated. The higher the score, the better the texture of the noodles.
◯: The average score is 7 to 10, and the texture is good.
Δ: The average score is 4 to 6, and the texture is slightly inferior.
X: The average score is less than 4, and the texture is inferior.

Figure 0006938922
Figure 0006938922

Claims (2)

粉末状セルロースを含む吸水助剤又は吸油助剤である食品添加剤であって、該粉末状セルロースが下記条件(A1)〜(E1)を満たし、且つ平均重合度が300〜1500であり、結晶化度75〜90%であり、平均繊維長が0.1〜1.0mmであることを特徴する吸水助剤又は吸油助剤である食品添加剤
(A1)平均粒子径が30〜67μm
(B1)粒子径100μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で16.0〜37.0体積%の範囲にある。
(C1)粒子径200μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で4.0〜16.0体積%の範囲にある。
(D1)粒子径300μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜10.0体積%以下の範囲にある。
(E1)粒子径600μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜2.0体積%以下の範囲にある。
A food additive that is a water-absorbing aid or an oil-absorbing aid containing powdered cellulose, wherein the powdered cellulose satisfies the following conditions (A1) to (E1), has an average degree of polymerization of 300 to 1500, and has crystals. A food additive that is a water-absorbing aid or an oil-absorbing aid , characterized by having a degree of polymerization of 75 to 90% and an average fiber length of 0.1 to 1.0 mm.
(A1) Average particle size is 30 to 67 μm
(B1) Powdered cellulose having a particle size of 100 μm or more is in the range of 16.0 to 37.0% by volume in the accumulation distribution calculated from the particle size distribution.
(C1) Powdered cellulose having a particle size of 200 μm or more is in the range of 4.0 to 16.0% by volume in the accumulation distribution calculated from the particle size distribution.
(D1) Powdered cellulose having a particle size of 300 μm or more is in the range of 0 to 10.0% by volume or less in the accumulation distribution calculated from the particle size distribution.
(E1) Powdered cellulose having a particle size of 600 μm or more is in the range of 0 to 2.0% by volume or less in the accumulation distribution calculated from the particle size distribution.
粉末状セルロースを含む結着防止剤又は着色助剤である食品添加剤であって、該粉末状セルロースが下記条件(A2)〜(E2)を満たし、且つ平均重合度が200〜1000であり、結晶化度75〜90%であり、平均繊維長が0.2〜0.8mmであることを特徴する結着防止剤又は着色助剤である食品添加剤
(A2)平均粒子径が26〜45μm
(B2)粒子径100μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で6.0〜45.0体積%の範囲にある。
(C2)粒子径200μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0.5〜14.0体積%の範囲にある。
(D2)粒子径300μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜10.0体積%以下の範囲にある。
(E2)粒子径600μm以上の粉末状セルロースが、粒度分布から算出される蓄積分布で0〜1.0体積%以下の範囲にある。
A food additive that is a binding inhibitor or coloring aid containing powdered cellulose, wherein the powdered cellulose satisfies the following conditions (A2) to (E2) and has an average degree of polymerization of 200 to 1000. A food additive which is an anti-binding agent or a coloring aid, characterized by having a crystallinity of 75 to 90% and an average fiber length of 0.2 to 0.8 mm.
(A2) Average particle size is 26-45 μm
(B2) Powdered cellulose having a particle size of 100 μm or more is in the range of 6.0 to 45.0% by volume in the accumulation distribution calculated from the particle size distribution.
(C2) Powdered cellulose having a particle size of 200 μm or more is in the range of 0.5 to 14.0% by volume in the accumulation distribution calculated from the particle size distribution.
(D2) Powdered cellulose having a particle size of 300 μm or more is in the range of 0 to 10.0% by volume or less in the accumulation distribution calculated from the particle size distribution.
(E2) Powdered cellulose having a particle size of 600 μm or more is in the range of 0 to 1.0% by volume or less in the accumulation distribution calculated from the particle size distribution.
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