JP6921106B2 - Z−1233zdの共沸及び共沸様組成物 - Google Patents
Z−1233zdの共沸及び共沸様組成物 Download PDFInfo
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- JP6921106B2 JP6921106B2 JP2018550367A JP2018550367A JP6921106B2 JP 6921106 B2 JP6921106 B2 JP 6921106B2 JP 2018550367 A JP2018550367 A JP 2018550367A JP 2018550367 A JP2018550367 A JP 2018550367A JP 6921106 B2 JP6921106 B2 JP 6921106B2
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
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- C—CHEMISTRY; METALLURGY
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- C—CHEMISTRY; METALLURGY
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- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
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- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
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- C09K5/02—Materials undergoing a change of physical state when used
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- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
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Description
a)ギ酸メチル、
b)ジメトキシメタン、
c)HFC−43−10−mee、及び
d)HFC−245faからなる群から選択される第2の成分と、を含む組成物であって、
第2の成分が、Z−1233zdと共沸混合物又は共沸様混合物を形成するための有効量で存在する、組成物が提供される。
(a)発泡剤に発泡性組成物を添加する工程と、
(b)発泡体を形成するのに有効な条件下で、当該発泡性組成物を反応させる工程と、を含み、
発泡剤が、実施形態1.0に記載の組成物を含む、プロセスが提供される。
(a)発泡剤に発泡性組成物を添加する工程と、
(b)発泡体を形成するのに有効な条件下で、当該発泡性組成物を反応させる工程と、を含み、
発泡剤が、実施形態2.0に記載の組成物を含む、プロセスが提供される。
(a)発泡剤に発泡性組成物を添加する工程と、
(b)発泡体を形成するのに有効な条件下で、当該発泡性組成物を反応させる工程と、を含み、
発泡剤が、実施形態3.0に記載の組成物を含む、プロセスが提供される。
(a)発泡剤に発泡性組成物を添加する工程と、
(b)発泡体を形成するのに有効な条件下で、当該発泡性組成物を反応させる工程と、を含み、
発泡剤が、実施形態4.0に記載の組成物を含む、プロセスが提供される。
(a)発泡剤に発泡性組成物を添加する工程と、
(b)発泡体を形成するのに有効な条件下で、当該発泡性組成物を反応させる工程と、を含み、
発泡剤が、実施形態5.0に記載の組成物を含む、プロセスが提供される。
開示する組成物は、熱源からヒートシンクに熱を運ぶために使用される作動流体として作用することができる。そのような伝熱組成物は、流体が相転移するサイクル、すなわち、流体が液体から気体に変化し、再び液体に戻る、又はその逆に変化するサイクルにおける冷媒としても有用であり得る。
一実施形態では、Z−1233zdと少なくとも1種類の添加剤とを含む本組成物の1つが提供される。最も一般的な添加剤は潤滑剤である。潤滑剤及び他の添加剤については、Fuels and Lubricants Handbook:Technology,Properties,Performance and Testing,Ch.15,「Refrigeration Lubricants−Properties and Applications,」Michels,H.Harvey及びSeinel,Tobias H.著MNL37WCD−EB,ASTM International,(2003年6月)に述べられており、当該文献を参照により援用するものである。潤滑剤としては、ポリオールエステル類(POE)、ナフテン系鉱油類(NMO)及びポリアルキレングリコール類(PAG)、並びに合成潤滑剤が挙げられる。他の添加剤は、分散剤、酸化阻害剤、極圧添加剤、腐食防止剤、洗剤、酸捕捉剤を含む、系内の金属と、又は潤滑剤中の夾雑物と反応することができるという意味で、化学的な活性を有する群から選択される。酸化阻害剤の選択は、潤滑剤の選択に応じて決めることができる。アルキルフェノール類(例えばジブチルヒドロキシトルエン)が、ポリオールエステル潤滑剤において有用であり得る。窒素含有阻害剤(例えばアリールアミン類及びフェノール類)が、鉱油潤滑剤において有用であり得る。酸捕捉剤は、合成潤滑剤系において特に重要であり、アルカノールアミン類、長鎖アミド及びイミン、炭酸塩、及びエポキシドが挙げられる。更なる他の添加剤は、流動点改変剤、消泡剤、粘度改善剤、及び乳化剤からなる群から選択される物理特性を変化させる群から選択される。消泡剤としては、ポリジメチルシロキサン、ポリアルコキシアミン及びポリアクリレートが挙げられる。
本発明は更に、(a)発泡性組成物に本発明の組成物を添加する工程と、(b)発泡体を形成するのに有効な条件下で発泡性組成物を反応させる工程と、を含む、発泡体を形成する方法に関する。
(a)発泡性組成物に上記に述べた発泡剤を添加する工程と、
(b)発泡体を形成するのに有効な条件下で、発泡性組成物を反応させる工程と、を含む方法についてのものである。
本発明の別の実施形態は、噴霧可能な組成物中の推進剤としての本発明の組成物の使用に関する。更に、本発明は、本明細書に述べられる本発明の組成物を含む、噴霧可能な組成物に関する。不活性成分、溶媒及び他の材料と共に噴霧される活性成分が、噴霧可能な組成物中に存在してもよい。好ましくは、噴霧可能な組成物はエアゾールである。噴霧するのに好適な活性物質としては、これらに限定されるものではないが、防臭剤、香料、ヘアスプレー、洗浄剤、及び研磨剤などの化粧品原料、並びに抗喘息薬及び口臭防止薬などの医薬品が挙げられる。
更なる一態様は、火炎を抑制する方法であって、火炎を、本開示の本発明の組成物を含む流体と接触させる工程を含む、方法を提供する。火炎を本組成物と接触させるための任意の好適な方法を使用することができる。例えば、本開示の本発明の組成物を火炎に噴霧する、注ぐ、といったことを行うか、又は火炎の少なくとも一部を火炎抑制組成物中に浸漬することができる。本明細書の教示を考慮することで、当業者であれば、本発明で使用するために様々な従来の火炎抑制の装置及び方法を容易に適合することが可能であろう。
1)トータルフラッド消火及び抑火用途では、薬剤は存在する火災を消火又は抑制するのに充分な濃度が得られるように空間内に放出される。トータルフラッド用途としては、コンピュータルームなどの閉鎖された、場合により占有された空間、並びに航空機のエンジンナセル及び車両のエンジンコンパートメントのような専用の、しばしば占有されていない空間が挙げられる。
2)ストリーミング用途では、薬剤は火災に対して又は火災の領域内に直接適用される。これは通常、手動操作される車輪付き又は携帯型ユニットを使用して行われる。ストリーミング用途として含まれる第2の方法では、1つ又は2つ以上の固定ノズルから火災に向かって薬剤を放出する「局所」システムが使用される。局所システムは、手動又は自動で作動させることができる。
3)爆発の抑制では、本開示の本発明の組成物は、既に起爆された爆発を抑制するために放出される。爆発は通常、自己制限的であることから、この用途では「抑制」という用語が通常は用いられる。しかしながら、この用語の使用は、爆発が薬剤によって消火されないことを必ずしも意味しない。この用途では、通常、検出器を用いて爆発から膨張する火球を検出し、速やかに薬剤を放出して爆発を抑制する。爆発の抑制は、防御用途において主に用いられる(ただし単独では用いられない)。
4)不活化では、本開示の本発明の組成物は、爆発又は火災の開始を防止するために空間内に放出される。トータルフラッド式の消火又は抑火で使用されるものと同様の、又は同じシステムがしばしば用いられる。通常、危険な状態(例えば可燃性又は爆発性のガス)の存在が検出された後、状況を改善することができるようになるまで爆発又は火災が発生することを防止するために本開示の本発明の組成物が放出される。
誘電体ガス又は絶縁性ガスは、ガス状の誘電体材料である。その主たる目的は、放電を防止又は速やかに消失させることである。誘電体ガスは、例えば、変圧器、サーキットブレーカー、スイッチギア(すなわち高電圧スイッチギア)、及びレーダー導波管などの高電圧用途において電気絶縁体として使用される。本明細書で使用される際、「高電圧」という用語は、交流電流では1000Vよりも高い電圧、直流電流では少なくとも1500Vを意味するものとして理解される。本発明の組成物は、高電圧用途においてガス状誘電体として有用である。
本発明の組成物は、重合反応用の不活性媒質、金属表面から微粒子を除去するための流体として、例えば、金属部品上に潤滑剤の薄膜を配置するために使用可能なキャリア流体として、又は金属などの研磨された表面からバフ磨き研磨コンパウンドを除去するためのバフ磨き研磨剤としても使用することができる。これらの組成物はまた、宝石若しくは金属部品などから水を除去するための置換乾燥剤として、塩素系の現像剤を含む従来の回路製造技術におけるレジスト現像剤として、又は、1,1,1−トリクロロエタン又はトリクロロエチレンのようなクロロ炭化水素とともに使用される場合には、フォトレジスト用剥離剤としても使用される。地球温暖化への影響が少ない、これらの用途における新規な物質を特定することが望ましい。
Z−1233zd/ギ酸メチルの2成分系を、潜在的な共沸及び近共沸挙動について調べた。この2成分系の相対揮発度を判定するため、上記に述べたPTx法を用いた。既知の体積のPTxセル内の圧力を、異なる2成分の組成について30℃の一定温度で測定した。収集した実験データを下記表1.1に示す。
Z−1233zd/ジメトキシメタンの2成分系を潜在的な共沸及び近共沸挙動について調べた。この2成分系の相対揮発度を判定するため、上記に述べたPTx法を用いた。既知の体積のPTxセル内の圧力を、異なる2成分の組成について29.9℃の一定温度で測定した。収集した実験データを下記表2.1に示す。
Z−1233zd/HFC−43−10−meeの2成分系を、潜在的な共沸及び近共沸挙動について調べた。この2成分系の相対揮発度を判定するため、上記に述べたPTx法を用いた。既知の体積のPTxセル内の圧力を、異なる2成分の組成について30℃の一定温度で測定した。収集した実験データを下記表3.1に示す。
Z−1233zd/HFC−245faの2成分系を、潜在的な共沸及び近共沸挙動について調べた。この2成分系の相対揮発度を判定するため、上記に述べたPTx法を用いた。既知の体積のPTxセル内の圧力を、異なる2成分の組成について30℃の一定温度で測定した。収集した実験データを下記表4.1に示す。
Claims (17)
- Z−1233zdと、第2の成分と、を含む、共沸又は共沸様組成物であって、前記第2の成分が、HFC−43−10−meeであり、
−40℃〜140℃の温度で1〜5mol%及び78〜99mol%の1233zdと99〜95mol%及び1〜22mol%のHFC−43−10meeとを含む、共沸又は共沸様組成物。 - Z−1233zdと、第2の成分と、を含む、共沸又は共沸様組成物であって、前記第2の成分が、HFC−245faであり、
−40℃〜140℃の温度で1〜12mol%の1233zdと99〜88mol%のHFC−245faとを含む、共沸又は共沸様組成物。 - 潤滑剤、流動点改変剤、消泡剤、粘度改善剤、乳化剤、分散剤、酸化阻害剤、極圧添加剤、腐食防止剤、洗剤、触媒、界面活性剤、難燃剤、防腐剤、着色剤、酸化防止剤、強化剤、充填剤、帯電防止剤、可溶化剤、IR減衰剤、核形成剤、気泡調整剤、押出助剤、安定化剤、断熱剤、可塑剤、粘度調整剤、耐衝撃性改良剤、ガス遮断樹脂、ポリマー改質剤、レオロジー改質剤、抗菌剤、蒸気圧改変剤、UV吸収剤、架橋剤、浸透性改変剤、苦味剤、噴射剤、及び酸捕捉剤からなる群から選択される添加剤を更に含む、請求項1または2に記載の組成物。
- 発泡体を形成するプロセスであって、
(a)発泡剤に発泡性組成物を添加する工程と、
(b)発泡体を形成するのに有効な条件下で、前記発泡性組成物を反応させる工程と、
を含み、
前記発泡剤が、請求項1または2に記載の組成物を含む、プロセス。 - 請求項4に記載のプロセスによって形成された発泡体。
- ポリマーと、請求項1または2に記載の組成物と、を含む、発泡体。
- 発泡性成分と、発泡剤と、を含む、プレミックス組成物であって、前記発泡剤が、請求項1または2に記載の組成物を含む、プレミックス組成物。
- 冷却を生じさせるためのプロセスであって、
(a)請求項1または2に記載の組成物を凝縮する工程と、
(b)前記組成物を冷却すべき物体の付近で蒸発させる工程と、
を含む、プロセス。 - 伝熱媒体を含む、伝熱システムであって、前記伝熱媒体が、請求項1または2に記載の組成物を含む、伝熱システム。
- 表面を洗浄する方法であって、請求項1または2に記載の前記組成物を前記表面と接触させる工程を含む、方法。
- 分配される成分と、噴射剤と、を含む、エアゾール製品であって、前記噴射剤が、請求項1または2に記載の前記組成物を含む、エアゾール製品。
- 火炎を消火又は抑制するための方法であって、前記火炎に請求項1または2に記載の前記組成物を分配する工程を含む、方法。
- 火炎を防止又は抑制するためのシステムであって、請求項1または2に記載の前記組成物を含有する容器と、前記組成物を前記火炎の予想される、又は実際の場所に向かって分配するためのノズルと、を含む、システム。
- 溶質を溶解するためのプロセスであって、前記溶質を、充分な量の請求項1または2に記載の前記組成物と接触及び混合する工程を含む、プロセス。
- 高電圧装置内の空間内の放電を防止又は速やかに消失させるための方法であって、前記空間内にガス状誘電体を注入する工程を含み、前記ガス状誘電体が、請求項1または2に記載の前記組成物を含む、方法。
- ガス状誘電体を含む、高電圧装置であって、前記ガス状誘電体が、請求項1または2に記載の組成物を含む、高電圧装置。
- 変圧器、サーキットブレーカー、スイッチ、及びレーダー導波管からなる群から選択される、請求項16に記載の高電圧装置。
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US201662312694P | 2016-03-24 | 2016-03-24 | |
US62/312,694 | 2016-03-24 | ||
PCT/US2017/023001 WO2017165225A1 (en) | 2016-03-24 | 2017-03-17 | AZEOTROPIC AND AZEOTROPE-LIKE COMPOSITIONS OF Z-1233zd |
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JP2019513173A JP2019513173A (ja) | 2019-05-23 |
JP6921106B2 true JP6921106B2 (ja) | 2021-08-18 |
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JP2018550367A Active JP6921106B2 (ja) | 2016-03-24 | 2017-03-17 | Z−1233zdの共沸及び共沸様組成物 |
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US (1) | US20190070447A1 (ja) |
EP (1) | EP3433333A1 (ja) |
JP (1) | JP6921106B2 (ja) |
CN (1) | CN108779384A (ja) |
WO (1) | WO2017165225A1 (ja) |
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CA3119716A1 (en) * | 2018-11-13 | 2020-05-22 | Invista Textiles (U.K.) Limited | Azeotropically-modified blowing agents for forming foams |
US11655328B2 (en) | 2020-09-02 | 2023-05-23 | Ventrex Systems, LLC | Dimensionally stable closed-cell and rigid foams produced with methylal blowing agent |
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US5759430A (en) | 1991-11-27 | 1998-06-02 | Tapscott; Robert E. | Clean, tropodegradable agents with low ozone depletion and global warming potentials to protect against fires and explosions |
US5332761A (en) | 1992-06-09 | 1994-07-26 | The Dow Chemical Company | Flexible bimodal foam structures |
US5977271A (en) | 1994-09-02 | 1999-11-02 | The Dow Chemical Company | Process for preparing thermoset interpolymers and foams |
CN1259878A (zh) | 1997-06-11 | 2000-07-12 | 陶氏化学公司 | 吸收性挤出热塑性泡沫材料 |
JP2004512406A (ja) | 2000-10-24 | 2004-04-22 | ダウ グローバル テクノロジーズ インコーポレイティド | 水を必要としないマルチモーダル熱可塑性ポリマーフォームの調製方法およびそれより調製されたフォーム |
DE10055084A1 (de) | 2000-11-07 | 2002-06-13 | Basf Ag | Flexible, offenzellige, mikrozelluläre Polymerschäume |
US20090253820A1 (en) * | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
US9499729B2 (en) * | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
MX2009011471A (es) * | 2007-04-27 | 2009-11-10 | Du Pont | Composiciones azeotropicas y semejantes a un azeotropo de z-1,1,1,4,4,4-hexafluoro-2-buteno. |
US7736529B2 (en) * | 2007-10-12 | 2010-06-15 | Honeywell International Inc | Azeotrope-like compositions containing sulfur hexafluoride and uses thereof |
US7479238B1 (en) * | 2007-11-06 | 2009-01-20 | Arkema Inc. | Azeotrope-like composition of 1,1,1-trifluoro-3-chloropropene and methyl formate |
US7438825B1 (en) * | 2008-03-07 | 2008-10-21 | Arkema Inc. | Azeotrope-like composition of 1,1,1-trifluoro-3-chloropropene and dimethoxymethane |
US8820079B2 (en) * | 2008-12-05 | 2014-09-02 | Honeywell International Inc. | Chloro- and bromo-fluoro olefin compounds useful as organic rankine cycle working fluids |
US8163196B2 (en) * | 2008-10-28 | 2012-04-24 | Honeywell International Inc. | Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene |
US20130109771A1 (en) * | 2008-10-28 | 2013-05-02 | Honeywell International Inc. | Azeotrope-like compositions including cis-1-chloro-3,3,3-trifluoropropene |
SI3812360T1 (sl) * | 2009-09-09 | 2024-02-29 | Honeywell International Inc. | Monoklorotrifluoropropenske spojine in sestavki ter postopki, ki jih uporabljajo |
FR2957350B1 (fr) * | 2010-03-09 | 2013-06-14 | Arkema France | Compositions d'agent d'expansion a base d'hydrochlorofluoroolefine |
JP6213194B2 (ja) * | 2013-11-29 | 2017-10-18 | セントラル硝子株式会社 | 熱エネルギーを機械エネルギーへ変換する方法、有機ランキンサイクル装置、及び作動流体を置換える方法 |
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2017
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- 2017-03-17 EP EP17714369.0A patent/EP3433333A1/en active Pending
- 2017-03-17 WO PCT/US2017/023001 patent/WO2017165225A1/en active Application Filing
- 2017-03-17 JP JP2018550367A patent/JP6921106B2/ja active Active
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US20190070447A1 (en) | 2019-03-07 |
EP3433333A1 (en) | 2019-01-30 |
JP2019513173A (ja) | 2019-05-23 |
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