JP6865561B2 - 非確率論抵抗性スイッチングメモリデバイス及び製造方法 - Google Patents
非確率論抵抗性スイッチングメモリデバイス及び製造方法 Download PDFInfo
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/20—Multistable switching devices, e.g. memristors
- H10N70/24—Multistable switching devices, e.g. memristors based on migration or redistribution of ionic species, e.g. anions, vacancies
- H10N70/245—Multistable switching devices, e.g. memristors based on migration or redistribution of ionic species, e.g. anions, vacancies the species being metal cations, e.g. programmable metallization cells
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/801—Constructional details of multistable switching devices
- H10N70/881—Switching materials
- H10N70/883—Oxides or nitrides
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/011—Manufacture or treatment of multistable switching devices
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/011—Manufacture or treatment of multistable switching devices
- H10N70/021—Formation of switching materials, e.g. deposition of layers
- H10N70/026—Formation of switching materials, e.g. deposition of layers by physical vapor deposition, e.g. sputtering
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/801—Constructional details of multistable switching devices
- H10N70/821—Device geometry
- H10N70/826—Device geometry adapted for essentially vertical current flow, e.g. sandwich or pillar type devices
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/801—Constructional details of multistable switching devices
- H10N70/841—Electrodes
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Description
Claims (11)
- 抵抗性スイッチングデバイスであって、
半導体基板上に配置された下部電極と、
前記下部電極上に配置され、アルミニウム及び窒素材料:AlNyを含む抵抗性スイッチング材料と、
前記抵抗性スイッチング材料上に配置され、非化学量論比のアルミニウム及び窒素材料:xが0.60〜0.80の範囲にあるAlNx(y>x)を含む導体材料と、
前記導体材料上に配置された上部電極とを備える抵抗性スイッチングデバイス。 - 前記下部電極は、金属窒化物を含む、請求項1に記載の抵抗性スイッチングデバイス。
- AlNyは、化学量論比又は非化学量論比のアルミニウム窒化物であり、yは、1.00〜1.50の範囲である、請求項1に記載の抵抗性スイッチングデバイス。
- yは、1.00〜1.50の範囲である、請求項1に記載の抵抗性スイッチングデバイス。
- 前記抵抗性スイッチング材料は、2nm〜20nmの厚みを備える、請求項1に記載の抵抗性スイッチングデバイス。
- 前記導体材料は、4nm〜100nmの厚みを備える、請求項1に記載の抵抗性スイッチングデバイス。
- 前記抵抗性スイッチング材料は、1メガオーム(MOhms)〜100メガオーム(MOhms)の範囲内で初期抵抗と関連する、請求項1に記載の抵抗性スイッチングデバイス。
- 前記導体材料は、1キロオーム(KOhms)〜100キロオーム(KOhms)の範囲内で初期抵抗と関連する、請求項1に記載の抵抗性スイッチングデバイス。
- 前記下部電極は、銅、窒化チタン、窒化タンタルからなる群から選択された材料を含む、請求項1に記載の抵抗性スイッチングデバイス。
- 半導体デバイスの形成方法であって、
半導体基板上に下部電極を形成する工程と、
前記下部電極上に、アルミニウム及び窒素材料:AlNyを含む抵抗性スイッチング材料層を形成する工程と、
前記抵抗性スイッチング材料層上に、非化学量論比のアルミニウム及び窒素材料:xが0.60〜0.80の範囲にあるAlNx(y>x)を含む導体材料を形成する工程と、
前記導体材料上に上部電極を形成する工程を備える半導体デバイスの形成方法。 - 前記抵抗性スイッチング材料層を形成する工程は、窒素ガスの第一濃度に関連するアルゴンガス及び窒素ガス環境中に前記アルミニウム材料を配置する工程を備え、
前記導体材料を形成する工程は、窒素ガスの第二濃度に関連する第二アルゴンガス及び窒素ガス環境中に前記アルミニウム材料を配置する工程を備え、
窒素ガスの前記第一濃度は、窒素ガスの前記第二濃度を超えてなる、請求項10に記載の半導体デバイスの形成方法。
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