JP6831728B2 - Hair cosmetics - Google Patents

Description

The present invention relates to a hair cosmetic having an excellent finishing effect when applied to hair, and more specifically, a cationic surfactant, a fatty acid polyglyceryl having 8 to 18 carbon atoms having HLB 12 to 18, and poly. By containing one or more polyhydric alcohols selected from oxyethylene alkyl glucoside, di or tripropylene glycol, 1,2-propanediol and 1,3-propanediol, it has excellent foam retention during use. It relates to hair cosmetics that are excellent in smoothness, cohesiveness, and non-stickiness as hair finishing effects.

Hair cosmetics include various items such as hair shampoos, hair rinses, hair treatments, and hair styling products, and have a wide range of required functions. Examples of the finishing effect given to the hair include smoothness, suppleness, firmness, and glossiness, and examples of the hair styling effect include a feeling of cohesiveness of the hair and a sustained effect of styling.
Various formulations of hair cosmetics that impart these finishing effects and styling functions, such as an aqueous solubilizer type, an O / W emulsified type, and an oil type, have been put on the market.

In addition, various components have been additionally studied for the purpose of imparting usability and smoothness to hair with respect to these various dosage forms, and techniques containing a cationic polymer (see, for example, Patent Document 1), sugars, etc. There is a technique containing alcohol (see, for example, Patent Document 2).

On the other hand, also in the container form, in consideration of usability for hair, a mist container or an aerosol spray container that not only picks up the composition of hair cosmetic and applies it to hair but also directly applies it to hair is used. Or, when the composition of hair cosmetics is used, it has been made into a foam (foam).
Among them, when using the composition of hair cosmetics, it is possible to easily apply the composition to the hair by making it foamy (foamable), and it is excellent in usability. Therefore, aerosol foam dosage form or non-aerosol Proposals for foam dosage forms (pump former containers) have been made (see, for example, Patent Documents 3 and 4).

In addition, various studies have been conducted on non-aerosol foam type (pump former container) hair cosmetics in order to improve foam quality and usability. For example, a specific nonionic surfactant is contained in a specific amount. Proposals (see Patent Document 5) and proposals containing specific water-soluble components (see Patent Document 6) have been made.

Japanese Unexamined Patent Publication No. 10-182362 JP-A-2010-163387 Japanese Unexamined Patent Publication No. 2014-125477 Japanese Unexamined Patent Publication No. 2012-6915 Japanese Unexamined Patent Publication No. 2012-31072 Japanese Unexamined Patent Publication No. 2013-253046

The hair cosmetics described in Patent Document 1 contain a specific amidamine, an amine oxide-type surfactant, and a cationic polymer, so that they can be easily combed during use and after drying, and the hair is smooth. However, due to the influence of the cationic polymer, it may not be possible to obtain a sufficient sense of cohesiveness and non-stickiness. Further, the hair treatment agent composition described in Patent Document 2 contains a specific tertiary amine, a quaternary ammonium type surfactant, a polyether-modified silicone, a sugar and / or a sugar alcohol, so that the hair may be treated. It imparts moistness, smoothness, and suppleness, but due to the influence of sugar alcohol, it sometimes feels sticky.
The foam-like hair cosmetics described in Patent Document 3 provide smoothness and moist feeling without stickiness of hair, but since they contain oils and silicone oils as constituents, a feeling of cohesiveness of hair is required when a light finish is required. In some cases, a sufficient usability could not be obtained. Further, the hair styling agent in a non-aerosol former container described in Patent Document 4 has high hair styling properties and discharges good bubbles, but has high hair styling properties by containing a film-forming polymer. However, there were cases where the smoothness and suppleness of the hair was insufficient.
Further, the hair cosmetic composition described in Patent Document 5 has a high-quality foam and does not drip when applied, but contains 10% by mass or more of a specific nonionic surfactant and cationic surfactant. It contains an agent and an anionic surfactant or an amphoteric surfactant, and although it has a good foam quality, it may be insufficient in terms of usability such as suppleness, smoothness, and non-stickiness. The non-aerosol former container-filled hair styling agent described in Patent Document 6 contains a specific water-soluble component, a film-forming polymer, and a surfactant, and is excellent in foam quality such as foam retention and foam bulkiness. However, there were cases where the smoothness and non-stickiness of the hair were insufficient.

Although such a problem exists, when the hair cosmetic is used, it is applied evenly to the entire hair, so that the number of times of use may increase. For this reason, although the ease of spreading can be improved by using a container specification such as a pump former, there are cases where the smoothness is not excellent depending on the surfactant used for foam retention during use. For this reason, there has never been a hair cosmetic that has excellent foam retention during use, but that satisfies all of the hair finish effects such as smoothness, cohesiveness, and non-stickiness, and the development of such hair cosmetics is desired. Was there.

In view of such circumstances, the present inventors have diligently studied to solve the above problems, and as a result, a cationic surfactant is effective as a surfactant that imparts a smooth and supple finish to hair in hair cosmetics. By using polyoxyethylene alkyl glucoside in combination with one or more polyhydric alcohols selected from di or tripropylene glycol, 1,2-propanediol and 1,3-propanediol, there is no stickiness. It was found that the hair can be given a cohesive feeling and the smoothness is improved. Further, it has been found that by using the fatty acid polyglyceryl having 8 to 18 carbon atoms, which is HLB 12 to 18, in combination, a hair cosmetic having particularly excellent foam retention during use can be obtained without impairing the finishing effect. By using the pump former container, a particularly excellent effect can be obtained.
Thus, from the cationic surfactant, HLB 12-18, fatty acid polyglyceryl having 8 to 18 carbon atoms, polyoxyethylene alkyl glucoside, di or tripropylene glycol, 1,2-propanediol and 1,3-propanediol. The present invention has been found to be excellent in all of smoothness, cohesiveness, and non-stickiness as foam retention and hair finish effect at the time of use by containing one or more selected polyhydric alcohols. The product was completed.

That is, the present invention describes the following components (A) to (D);
(A) Cationic surfactant (B) Fatty acid polyglyceryl (C) polyoxyethylene alkyl glucoside (D) di or tripropylene glycol having 8 to 18 carbon atoms, which is HLB 12 to 18, 1,2-propanediol, 1, It provides a hair cosmetic containing one or more polyhydric alcohols selected from 3-propanediol.

It provides a hair cosmetic having a content mass ratio (B) / (C) of the components (B) and (C) in the range of 0.05 to 2.

It provides a hair cosmetic having a content mass ratio (B) / (D) of the components (B) and (D) in the range of 0.05 to 1.

It provides hair cosmetics, which are hair styling products.

It provides hair cosmetics to be used by filling them in a former container.

The hair cosmetic of the present invention is excellent in foam retention during use, and can provide an excellent hair cosmetic that imparts smoothness, cohesiveness, and non-stickiness as a hair finishing effect.

Hereinafter, the present invention will be described in detail. In this specification, when a numerical range is expressed by using "~", the range includes the numerical values at both ends.

The cationic surfactant of the component (A) used in the present invention is a surfactant having a structure having a hydrophilic group which is ion-dissociated in water and exhibits cationic properties and a hydrophobic group such as a fatty acid.
The cationic surfactant of the component (A) used in the present invention can be used without particular limitation as long as it is a cationic surfactant usually used in cosmetics for hair. Examples thereof include quaternary ammonium salts, tertiary amines, fatty acid amidamines and their neutralized products, and ester amines. Examples of the structure having a hydrophobic group such as a fatty acid include a mono-long chain alkyl type, a di-long chain alkyl type, an ethylene oxide-added type, and the like, and examples of the hydrophilic group exhibiting cationic properties include an ammonium salt and benzalco. Nium salts and the like can be mentioned, and examples of the counterion include chlorine ion, bromine ion, methyl sulfate ion, ethyl sulfate ion and the like.
Specifically, as the ammoniu salt, stearyltrimethylammonium chloride, stearyltrimethylammonium bromide, behenyltrimethylammonium chloride, behenyltrimethylammonium bromide, cetyltrimethylammonium chloride, cetyltrimethylammonium bromide, distearyldimethylammonium chloride, odor Distearyldimethylammonium bromide, dibehenyldimethylammonium chloride, dibehenyldimethylammonium bromide, disetyldimethylammonium chloride, disetyldimethylammonium bromide, dilauryldimethylammonium chloride, dilauryldimethylammonium bromide, stearyldimethylbenzylammonium chloride , Dipolyoxyethylene chloride (15EO.) Palm oil alkylmethylammonium, dipolyoxyethylene chloride (4EO.) Lauryl ether dimethylammonium, amidopropyltrimethylammonium chloride stearate and the like. Examples of sulfates include dicocoyl ethyl hydroxyethyl methyl ammonium methyl sulfate, distearoyl ethyl hydroxyethyl methyl ammonium methyl sulfate, lanolin fatty acid aminopropyl ethyl dimethyl ammonium ethyl sulfate, and dipalmitoyl ethyl hydroxyethyl monium methyl sulfate. Examples include salt. Further, examples of the benzalkonium salt include benzalkonium chloride. Examples of the tertiary amine include stellaamide propyl dimethylamine, isostearamid propyl dimethylamine, behenamide propyl dimethylamine, cocamido propyl dimethylamine and the like. These can be used alone or in combination of two or more. Of these, stearyltrimethylammonium chloride, stearyltrimethylammonium bromide, distearyldimethylammonium chloride, behenyltrimethylammonium chloride, behenyltrimethylammonium bromide, and dicocoyl ethylhydroxyethylmonium metosulfate give the hair a smooth finish. It is particularly preferable to obtain the effect.
In the present invention, the use of the component (A) is preferable in that it has good affinity and adsorptivity for hair, has a function of giving smoothness to hair, and imparts an excellent finishing effect.

The content of the component (A) in the hair cosmetic of the present invention is not particularly limited, but is approximately 0.1 to 2.5% by mass (hereinafter, "mass%") from the viewpoint of obtaining an excellent usability. Is simply abbreviated as "%"), more preferably 0.2 to 1.0%.

The fatty acid polyglyceryl having 8 to 18 carbon atoms, which is HLB 12 to 18 of the component (B) used in the present invention, is an ester of hydrophilic polyglycerin and a fatty acid having a lipophilic structure. Here, the degree of polymerization of the constituent glycerin of polyglycerin is 7 to 12, but it is preferably 9 to 10. Further, this polyglycerin may be polymerized to form a ring, but preferably, glycerin is polymerized in a chain shape. The fatty acid polyglyceryl having 8 to 18 carbon atoms, which is HLB 12 to 18 of the component (B) used in the present invention, is not particularly limited, but is preferably a fatty acid polyglyceryl having 10 to 18 carbon atoms, and more preferably has a carbon number of 10 to 18. 12-18 fatty acid polyglycers. Specific examples thereof include polyglyceryl-6 caprice, polyglyceryl-10 caprate, polyglyceryl laurate-6, polyglyceryl laurate-10, polyglyceryl myristate-10, polyglyceryl stearate-10, polyglyceryl oleate-10 and the like. Examples of commercially available products include NIKKOL Hexaglin 1-L (manufactured by Nikko Chemicals Co., Ltd., HLB 14.5) and Sunsoft M-12J (manufactured by Taiyo Kagaku Co., Ltd., HLB 15.5). These can be used alone or in combination of two or more. Among these, polyglyceryl laurate-10 is particularly preferable for obtaining excellent foam retention and a feeling of cohesiveness of hair.
In the present invention, HLB is a value representing the balance between hydrophilicity and lipophilicity of the surfactant, and can be specifically obtained by the following upstream formula.
HLB = 7 + 11.7log (Mw / Mo)
(Here, Mw represents the molecular weight of the hydrophilic base, and Mo represents the molecular weight of the base oil base.)
If the HLB is less than 12 or more than 18, the effect of improving the foam retention is not sufficient, and the hair cohesive effect when used in combination with the component (C) is not sufficient, which is not preferable. In view of use in a former container, the component (B) is HLB 12-18.
In the present invention, the component (B) is preferable in that it improves the excellent foam retention in the former container without impairing the finishing effect on the hair. When used in combination with the above-mentioned component (A) and component (B), it also has an effect of improving foam retention during discharge, which is particularly preferable in a pump former container.

The content of the component (B) in the hair cosmetic of the present invention is not particularly limited, but is approximately 0.1 to 5.0% from the viewpoint of excellent foam retention and the effect of obtaining a cohesive feeling of hair. Is preferable, and 0.5 to 3.0% is more preferable.

The polyoxyethylene alkyl glucoside of the component (C) used in the present invention is obtained by adding polyoxyethylene to the alkyl glucoside skeleton. The number of polyoxyethylene to be added is not particularly limited, but is preferably 2 to 50 mol, more preferably 10 to 30 mol, and most preferably 10 to 20 mol per molecule. It is a molecule. The alkyl group is not particularly limited, but preferably has 1 to 4 carbon atoms, and more preferably a methyl group.
The component (C) polyoxyethylene alkyl glucoside used in the present invention is not particularly limited, and specific examples thereof include methylgluces-10 and methylgluces-20. These are commercially available products such as McBiobride MG-10E (manufactured by NOF), McBiobride MG-20E (manufactured by NOF), GLUCAM E-10 (manufactured by Lubrizol), and GLUCAM E-20 (manufactured by NOF). You can have a Glucan). These can be used alone or in combination of two or more. Among these, Methylgluces-10 is particularly preferable in order to obtain an excellent hair cohesive effect.
In the present invention, the component (C) mainly imparts an excellent hair cohesive effect without impairing the smoothness and non-stickiness of the hair. In addition, the component (C) is also preferable in that the cohesiveness of the hair is remarkably improved by using it in combination with the above-mentioned component (B).

The content of the component (C) in the hair cosmetic of the present invention is not particularly limited, but is approximately 0.5 to 20.0% from the viewpoint of excellent foam retention and the effect of obtaining a cohesive feeling of hair. Is preferable, and 1.0 to 15.0% is more preferable.

One or more polyhydric alcohols selected from the component (D) di or tripropylene glycol, 1,2-propanediol, and 1,3-propanediol used in the present invention are usually used in cosmetics. If it is a thing, it is not particularly limited and can be used. Among these, dipropylene glycol, 1,2-propanediol, and 1,3-propanediol are more preferable in order to obtain an excellent hair finishing effect.
In the present invention, the component (D) is preferable in that it imparts no stickiness to the hair, mainly as a hair finishing effect. Further, when used in combination with the above-mentioned component (B), the cohesiveness of hair is improved without impairing the effect of foam retention.

The content of the component (D) in the hair cosmetic of the present invention is not particularly limited, but is preferably about 0.5 to 20.0% from the viewpoint of obtaining an excellent hair finishing effect. More preferably 1.0 to 15.0%.

The contents of the above-mentioned component (B) and component (C) can be arbitrarily selected, and the content ratio is not particularly limited, but the mass ratio of these contents should be within a specific range. This makes it possible to further enhance the effect of the present invention, which is preferable. The content mass ratio of the component (B) and the component (C) is not particularly limited, but the effect of imparting excellent foam retention and the effect of synergistically improving the cohesiveness of the hair by the component (C). From the point of view, the content mass ratio (B) / (C) is preferably about 0.02 to 2.0, more preferably 0.1 to 1.0.

The contents of the above-mentioned component (B) and component (D) can be arbitrarily selected, and the content ratio is not particularly limited, but the mass ratio of these contents should be within a specific range. This makes it possible to further enhance the effect of the present invention, which is preferable. The content mass ratio of the component (B) and the component (D) is not particularly limited, but synergistically improves the effect of imparting excellent foam retention and the non-stickiness of the hair due to the component (D). From the viewpoint of the effect, the content mass ratio (B) / (D) is preferably about 0.05 to 1.0, more preferably 0.1 to 0.5.

Further, the hair cosmetic of the present invention can be used without particular limitation as long as it is used as a normal hair cosmetic. Above all, an out bath hair treatment that does not wash away is preferable in order to obtain an excellent hair finishing effect and an excellent hair cohesiveness. Further, a hair styling product is particularly preferable from the viewpoint of exerting an excellent effect of cohesiveness of hair.

Further, the hair cosmetic of the present invention is not particularly limited in the dosage form as long as it satisfies the constituent requirements, and can be used in a liquid solubilized type, an emulsifier type and the like. The container form is not particularly limited as long as it is an ordinary hair cosmetic, but from the viewpoint of usability to be applied to hair, a container used in the form of foam (foam) is preferable, for example, an aerosol former container or a container. Especially preferred for use in non-aerosol pump former containers. Here, when used as an aerosol former container, the gas (propellant) to be filled is not particularly limited, but as those usually used for cosmetics, for example, hydrocarbons, halogenated hydrocarbons, etc. Can be used. Specifically, propane, isobutane, normal butane, isopentane, liquefied petroleum gas (hereinafter abbreviated as "LPG"), dimethyl ether (hereinafter abbreviated as "DME"), dichlorodifluorethane, trichloromonofluorethane, Examples thereof include nitrogen and carbon dioxide. Among them, LPG and DME can be sprayed uniformly on the skin, and preferably one or two or more of these propellants can be appropriately selected and used. In the present invention, such a propellant may be used, but the effect of the invention can be obtained by putting it in a former container without using it, and it is used in a non-aerosol former container. Is particularly preferred.
The non-aerosol former container is not particularly limited as long as it has a mechanism capable of mixing the composition with air and discharging it in the form of bubbles, and a container provided with a pump mechanism, a squeeze container, or the like can be used. .. For example, a pump container having a mechanism in which the composition passes through a porous body such as a mesh and becomes foamy by pushing the head (pressing portion) of the pump container can be mentioned.
Here, the former container has a porous membrane for the purpose of homogenizing bubbles, and examples of the porous membrane include a net and the like. In this case, the net mesh size is not particularly limited, and a commercially available container can be used, but it is preferable to use a container having a net mesh size of about 50 to 400 mesh.
In the present invention, those used in a pump former container are particularly preferable.

In addition to the above-mentioned ingredients, the hair cosmetics of the present invention include ordinary cosmetics, non-pharmaceutical products, external pharmaceuticals, etc. Ingredients used in the formulation of, for example, purified water, hot spring water, deep water and other water, alcohols other than ingredient (D), higher alcohols, oils, powders for tactile adjustment or coloring, ingredient (A), General-purpose ingredients such as surfactants other than ingredient (B), water-soluble polymers, film-forming agents, oil-based gelling agents, resins, inclusion compounds, moisturizers, antibacterial / preservatives, deodorants, salts, ultraviolet rays Absorbents, antioxidants, chelating agents, anti-fading agents, defoamers, refreshing agents, components other than the component (C) of the present invention, aqueous components other than the component (D), propellants, fragrances, pigments, etc. As the agent, liquefied petroleum gas, propane, butane, isobutane, isopentane, dimethyl ether, carbon dioxide, nitrogen and the like can be contained.

The method for producing the hair cosmetic of the present invention is not particularly limited and is prepared by a conventional method. For example, it can be prepared by uniformly mixing and dissolving the components (A) to (D) and other components as required.

Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.

Hereinafter, hair cosmetics were manufactured and evaluated.
Products 1 to 34 of the present invention and Comparative products 1 to 5; Hair cosmetics Hair cosmetics were prepared according to the compositions shown in Tables 1 to 4 and the following production methods. 2> Hair finish (smoothness), <3> Hair finish (cohesiveness), and <4> Hair finish (no stickiness) were evaluated and judged by the following evaluation methods and criteria. .. The results are also shown in Tables 1 to 4.

(Production method)
A: No. 1 to 17 were uniformly mixed and dissolved, and filled in a pump former container to obtain a hair cosmetic.
As the pump former container, a G3 pump former manufactured by Daiwa Kan Co., Ltd. was used.

[Evaluation method 1]: <1> Foam retention, <2> Hair finish (smoothness), <3> Hair finish (cohesiveness), <4> Hair finish (no stickiness)
We asked 20 cosmetics specialist panels to use the hair cosmetics shown in Tables 1 to 3, and regarding the foam discharged from the pump former container, the items of foam retention and hair finish (smoothness) are as follows (a). ) And (b) were evaluated on a 5-point scale according to the evaluation criteria. In addition, the hair finish (cohesiveness) and (non-stickiness) were evaluated on a 5-point scale according to the following evaluation criteria (c) and (d). Then, each evaluation red hair was judged according to the following (e) judgment criteria.

(B) [Evaluation Criteria] <1> When the foam-holding hair cosmetic is discharged from the pump former container and applied to the hair, the foam-holding evaluation is performed based on the number of discharges until the hair can be evenly applied to the entire hair. did.
Five-level evaluation criteria:
[Score]: [Evaluation result]
5 points: Can be applied evenly to the entire hair with one ejection 4 points: Can be applied evenly to the entire hair with 2 ejections 3: Can be applied evenly to the entire hair with 3 ejections 2 points : Can be applied evenly to the entire hair with 4 discharges 1 point: Can be applied evenly to the entire hair with 5 or more discharges

(B) [Evaluation criteria] <2> Hair finish (smoothness)
Five-level evaluation criteria:
[Score]: [Evaluation result]
5 points: The finished hair is smooth enough 4 points: The finished hair is almost smooth 3 points: The finished hair is a little lacking 2 points: The finished hair is quite smooth No 1: The finished hair is not smooth enough

(C) [Evaluation criteria] <3> Hair finish (cohesiveness)
Five-level evaluation criteria:
A commercially available hair bundle (10 g) having a length of 20 cm and having the upper end tied in one place and a width of the tip of the hair tip of 3 cm was applied with 2 g of hair cosmetic and spread evenly. The width of the tip of the hair after finishing was compared with that before use, and the feeling of cohesiveness of the hair was evaluated from the rate of decrease in width.
[Score]: [Evaluation result]
5 points: The reduction rate of the width of the tip of the hair is 40% or more 4 points: The reduction rate of the width of the tip of the hair is 40 to 30% or more 3 points: The reduction rate of the width of the tip of the hair is 30 to 20 % Or more 2 points: The reduction rate of the width of the tip of the hair is 20 to 10% or more 1 point: The reduction rate of the width of the tip of the hair is less than 10%

(D) [Evaluation criteria] <4> Hair finish (no stickiness)
Five-level evaluation criteria:
2 g of hair cosmetic was applied to a commercially available hair bundle (10 g) having a length of 20 cm and a width of 5 cm, and the hair was uniformly blended. After applying 1 g of plate-like powder (Metashine 5480PS) to the finished hair bundle, a dryer was sprayed for 10 seconds. Then, the non-stickiness of the hair was evaluated by the ratio of the amount of powder remaining attached to the hair.

[Score]: [Evaluation result]
5 points: The amount of adhered powder is 0 to 10% or less 4 points: The amount of adhered powder is 10 to 20% or less 3 points: The amount of adhered powder is 20 to 30% or less 2 points: Adhered Powder amount is 30-40% or less 1 point: Adhered powder amount is 40% or more

(E) Judgment criteria [Judgment]: [Average score]
◎: 4.5 or more ○: 3.5 or more and less than 4.5 Δ: 1.5 or more and less than 3.5 ×: less than 1.5

As is clear from the results of Tables 1 to 4, the hair cosmetics of the products 1 to 34 of the present invention have "foam retention", the hair finish effect after use "smoothness", "cohesiveness", and "stickiness". It was good for each item of "nothing".
The comparative product 1 containing no component (A) was extremely inferior in "hair finish (smoothness)" and had insufficient "foam retention". The comparative product 2 containing no component (B) had a very poor "hair finish (cohesiveness)" and was not sufficient. Although HLB corresponds to the component (B), the comparative product 3 containing a component whose structure deviates was very inferior in "foam retention" and "hair finish (cohesiveness)", and was not sufficient. .. The comparative product 4 which does not contain the component (C) is very inferior in "hair finish (cohesiveness)", and has "foam retention", "hair finish (smoothness)", and "hair finish (stickiness)". Nothing) ”was not enough either. The comparative product 5 which does not contain the component (D) is very inferior in "hair finish (non-stickiness)", and is "hair finish (smoothness)" and "hair finish (cohesiveness)". Was not enough.

Example 2: Hair styling product containing pump former (ingredient) (%)
1. 1. Stearyl trimethylammonium chloride 0.5
2. 2. Behenyl trimethylammonium chloride 0.1
3. 3. Stearyl trimethylammonium bromide 0.1
4. Ethanol 10.0
5. Methylparaben 0.1
6. Phenoxyethanol 0.1
7. PEG-50 hydrogenated castor oil isostearate 0.5
8. Fragrance 0.3
9. Polyglyceryl laurate-10 0.8
10. Polyglyceryl oleate-10 0.1
11. Polyglyceryl stearate-10 0.1
12. Polyglyceryl myristate-10 0.1
13. Methylgluces-10 5.0
14. Methylgluces-20 0.5
15. Dipropylene glycol 3.0
16.1,2-Propanediol 1.0
17.1,3-Propanediol 1.0
18. Tripropylene glycol 0.5
19. Citric acid 0.01
20. Na citrate 0.01
21. Glycine 0.1
22. Lysine dilauroyl glutamate Na 0.1
23. Phosphoryl choline glycol polyacrylate 0.1
24. Purified water balance (manufacturing method)
A: No. 1 to 24 were uniformly mixed and dissolved, and filled in a pump former container (G3 pump former manufactured by Daiwa Kan Co., Ltd.) to obtain a hair styling product.

The hair styling products containing the pump former of Example 2 obtained as described above have "foam retention", "smoothness", "cohesiveness", and "non-stickiness" of the hair finish effect after use. The items were good.

Example 3: Hair styling product containing pump former (ingredient) (%)
1. 1. Stearyl trimethylammonium chloride 0.3
2. 2. Distearyl Chloride Dimethyl Ammonim 0.05
3. 3. Dicocoyl ethyl hydroxyethylmonium metosulfate 0.05
4. Ethanol 10.0
5. Methylparaben 0.1
6. Phenoxyethanol 0.1
7. PEG-50 hydrogenated castor oil isostearate 1.0
8. Fragrance 0.1
9. Isopropyl myristate 0.3
10. Ethylhexyl methoxycinnamate 0.1
11. Ethyl oleate 0.1
12. Tocopherol acetate 0.1
13. Polyglyceryl laurate-10 0.8
14. Methylgluces-10 5.0
15. Dipropylene glycol 5.0
16.1,2-Propanediol 1.0
17.1,3-Propanediol 1.0
18. Tripropylene glycol 1.0
19. Na Phosphate 0.01
20. Phosphoric acid 2Na 0.01
21. Polyquaternium-7 0.01
22. Hydrolyzed soy protein 0.1
23. (Dihydroxymethylsilylpropoxy) Hydroxy
Propyl hydrolyzed silk 0.1
24. Isostearoyl Hydrolyzed Collagen AMPD 0.1
25. Purified water balance (manufacturing method)
A: No. 1 to 25 were uniformly mixed and dissolved, and filled in a pump former container (F5M pump former manufactured by Daiwa Kan Co., Ltd.) to obtain a hair styling product.

The hair styling products containing the pump former of Example 3 obtained as described above have "foam retention", "smoothness", "cohesiveness", and "non-stickiness" of the hair finish effect after use. The items were good.

Example 4: Aerosol foam hair styling product stock solution (composition) (%)
1. 1. Stearyl trimethylammonium chloride 0.5
2. 2. Behenyltrimethylammonim bromide 0.1
3. 3. Dicocoyl ethyl hydroxyethylmonium metosulfate 0.05
4. Ethanol 5.0
5. Methylparaben 0.1
6. Phenoxyethanol 0.1
7. PEG-50 hydrogenated castor oil isostearate 0.9
8. Fragrance 0.2
9. Polyglyceryl laurate-10 0.9
10. Polyglyceryl laurate-6 0.1
11. Methylgluces-10 5.0
12. Dipropylene glycol 5.0
13.1,2-Propanediol 0.5
14.1,3-Propanediol 0.5
15. Tripropylene glycol 0.5
16. Citric acid 0.01
17. Sodium citrate 0.01
18. Polyquaternium-7 0.02
19. Polyquaternium-10 0.02
20. (Vinylpyrrolidone / VA) Copolymer 0.1
21. Polyquaternium-11 0.1
22. Polyquatanim-51 0.1
23. Hydroxypropyltrimonium hyaluronate 0.1
24. Arginine 0.1
25. Succinic acid 0.01
26. Purified water balance (manufacturing method)
A: No. 1 to 26 were uniformly mixed and dissolved to obtain a stock solution.
B: The undiluted solution and the propellant LPG 0.45 were filled in an aerosol can with the undiluted solution: propellant = 90:10 to obtain an aerosol foam hair styling product.

The aerosol foam hair styling product of Example 4 obtained as described above has the following items of "foam retention", "smoothness", "cohesiveness", and "non-stickiness" of the hair finish effect after use. It was good.

Example 5: Hair treatment lotion (ingredient) (%)
1. 1. Stearyl trimethylammonium chloride 0.5
2. 2. Ethanol 15.0
3. 3. Methylparaben 0.1
4. Phenoxyethanol 0.1
5. PEG-50 hydrogenated castor oil isostearate 0.2
6. Fragrance 0.1
7. Polyglyceryl laurate-10 0.9
8. Methylgluces-10 5.0
9. Dipropylene glycol 6.0
10. Lactic acid 0.01
11. Na lactate 0.01
12. Na hyaluronate 0.1
13. Water-soluble collagen 0.1
14. PCA-Na 0.1
15. Phosphoryl choline glycol polyacrylate 0.1
16. Purified water balance (manufacturing method)
A: No. 1 to 16 were uniformly mixed and dissolved, and filled in a bottle container to obtain a hair treatment lotion.

The hair treatment lotion of Example 5 obtained as described above was good for each item of the hair finishing effect "smoothness", "cohesiveness", and "non-stickiness" after use.

Claims (4)

The following components (A) to (D);
(A) Cationic surfactant (B) Fatty acid polyglyceryl (C) polyoxyethylene alkyl glucoside (D) di or tripropylene glycol having 8 to 18 carbon atoms, which is HLB 12 to 18, 1,2-propanediol, 1, Contains one or more polyhydric alcohols selected from 3-propanediol ,
The content mass ratio (B) / (C) of the component (B) and the component (C) is 0.02 to 2.0.
A hair cosmetic having a content mass ratio (B) / (D) of the component (B) and the component (D) of 0.05 to 1.0 . The hair cosmetic according to claim 1, wherein the content of the component (A) is 0.1 to 2.5% by mass. The hair cosmetic according to claim 1 or 2 , which is a hair styling product. The hair cosmetic according to any one of claims 1 to 3, which is used by filling it in a former container.