JP6788891B2 - Adhesive tape and manufacturing method of adhesive tape - Google Patents

Adhesive tape and manufacturing method of adhesive tape Download PDF

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JP6788891B2
JP6788891B2 JP2016232862A JP2016232862A JP6788891B2 JP 6788891 B2 JP6788891 B2 JP 6788891B2 JP 2016232862 A JP2016232862 A JP 2016232862A JP 2016232862 A JP2016232862 A JP 2016232862A JP 6788891 B2 JP6788891 B2 JP 6788891B2
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adhesive tape
sensitive adhesive
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尚吉 濱野
尚吉 濱野
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Kyodo Giken Chemical Co Ltd
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本発明は,粘着テープ及び粘着テープの製造方法に関し,より詳細には,建築内外装,建築塗装,車両塗装等においてマスキングや養生用に使用される粘着テープ,梱包等に使用される粘着テープのように,手切れ性を有することが求められる粘着テープにおいて,手切れ性を維持しつつ,基材層の伸縮防止と引張り強さの向上を図ることで,貼着後の位置ずれ及び剥離,ロール状に巻き取った際のテレスコープ状(竹の子状)の変型を防止し得る粘着テープ及びその製造方法に関する。 The present invention relates to an adhesive tape and a method for manufacturing an adhesive tape, and more specifically, an adhesive tape used for masking and curing in building interior / exterior, building painting, vehicle painting, etc., and an adhesive tape used for packaging, etc. As described above, in adhesive tapes that are required to have hand-cutting property, by preventing expansion and contraction of the base material layer and improving tensile strength while maintaining hand-cutting property, misalignment and peeling after sticking, The present invention relates to an adhesive tape capable of preventing deformation of a telescope-like (bamboo child-like) when wound into a roll, and a method for producing the same.

前述した建築内外装,建築塗装,車両塗装等においてマスキング及び養生のために使用される粘着テープは,一般に,基材層となるフィルムの片面に粘着剤を塗布した片面テープが使用されている。 As the adhesive tape used for masking and curing in the above-mentioned interior / exterior of buildings, architectural painting, vehicle painting, etc., a single-sided tape in which an adhesive is applied to one side of a film to be a base material layer is generally used.

このような粘着テープ100は,図5に示すように,粘着剤層130が内側,基材層120が外側となるように巻き芯140等にロール状に巻かれた状態で提供されており,使用時,ユーザーは粘着テープ100をロールから必要な長さ引き出し,被着物に貼着した後,所望の箇所で切断して貼着する。 As shown in FIG. 5, such an adhesive tape 100 is provided in a state of being rolled into a winding core 140 or the like so that the adhesive layer 130 is on the inside and the base material layer 120 is on the outside. At the time of use, the user pulls out the adhesive tape 100 from the roll for a required length, attaches it to the adherend, and then cuts and attaches it at a desired portion.

このような粘着テープ100の切断に際しては,鋸歯状の刃を持つ専用のカッターの使用又は,はさみあるいはカッターナイフ等の刃物の使用により切断することもできるが,切断する度にこのような刃物等を使用することの煩雑さを回避するために,手でも簡単に切ることができる「手切れ性」を有する粘着テープが要望されている。 When cutting such an adhesive tape 100, it is possible to cut by using a dedicated cutter having a sawtooth-shaped blade, or by using a blade such as scissors or a cutter knife, but such a blade or the like each time it is cut. In order to avoid the complexity of using the adhesive tape, there is a demand for an adhesive tape having "hand-cutting property" that can be easily cut by hand.

このような手切れ性を有する粘着テープとして,和紙,繊維織物(以下「割布」と言う。),及び,切れ目となるエンボスを付けた合成樹脂フィルムを基材層とした粘着テープ等がある。 Adhesive tapes having such hand-cutting properties include Japanese paper, textile fabrics (hereinafter referred to as "split cloth"), and adhesive tapes using an embossed synthetic resin film as a base material. ..

特に,粘着テープを手で切る場合,粘着テープの長手方向に対し直交する方向に直線状に切断できることが要望されており,このような要求を満たす粘着テープとしては,基材層を前述した割布によって構成した,所謂「布テープ」が主流で,一部に,粘着テープの長手方向と直交する方向に凹溝を形成して手切れ性を付与したポリオレフィン系樹脂フィルムを基材層としたものが提供されている。 In particular, when the adhesive tape is cut by hand, it is required that the adhesive tape can be cut linearly in a direction orthogonal to the longitudinal direction of the adhesive tape. As an adhesive tape satisfying such a requirement, the base material layer is divided as described above. The so-called "cloth tape" composed of cloth is the mainstream, and a polyolefin-based resin film having a concave groove formed in a direction orthogonal to the longitudinal direction of the adhesive tape to impart hand-cutting property is used as a base material layer. Things are provided.

前述の布テープでは,スフ(レーヨン)又は,ポリエステル等の繊維を,経糸と緯糸を異なる太さで織って形成した割布の両面又は片面に,厚さ10〜40μ程度のPEフィルムをラミネートしたものが基材層として使用されている。 In the above-mentioned cloth tape, a PE film having a thickness of about 10 to 40 μm is laminated on both sides or one side of a split cloth formed by weaving fibers such as suhu (rayon) or polyester with different thicknesses of warp and weft. Is used as a base layer.

このように経糸と緯糸を織ることによって製造される割布を備えた基材層を使用した布テープでは,手で切った場合でも,割布の経糸又は緯糸の長さ方向に直線状に切断することができる。 With a cloth tape using a base material layer provided with a split cloth produced by weaving warp threads and weft threads in this way, even when cut by hand, the warp threads or weft threads of the split cloth are cut linearly in the length direction. can do.

しかし,このような布テープでは,前述した構造から,基材層を得るためには,予め織っておいた割布を,PEフィルムとラミネートする工程が必要となり,製造工程が多工程となる結果,布テープは高価となる。 However, with such a cloth tape, in order to obtain a base material layer from the above-mentioned structure, a step of laminating a pre-woven split cloth with a PE film is required, resulting in a multi-step manufacturing process. , Cloth tape is expensive.

そこで,単層の合成樹脂フィルムを基材層としつつ,手で切った場合であっても,幅方向に直線状に切断することができる工夫がされた粘着テープも提案されている。 Therefore, an adhesive tape has been proposed in which a single-layer synthetic resin film is used as a base material and can be cut linearly in the width direction even when cut by hand.

このような粘着テープ100として,図6に示すように一方の面を平滑面121と成すと共に,他方の面を粘着テープの長手方向と直交する方向に多数の凹溝123が所定間隔で形成された凹凸面122としたポリオレフィン樹脂フィルムを基材層120とし,この基材層120の前記凹凸面122に,粘着剤を塗布して粘着剤層130を形成した粘着テープが提案されている(特許文献1)。 As such an adhesive tape 100, as shown in FIG. 6, one surface is formed as a smooth surface 121, and a large number of concave grooves 123 are formed on the other surface in a direction orthogonal to the longitudinal direction of the adhesive tape at predetermined intervals. An adhesive tape has been proposed in which a polyolefin resin film having an uneven surface 122 is used as a base material layer 120, and an adhesive is applied to the uneven surface 122 of the base material layer 120 to form an adhesive layer 130 (Patent). Document 1).

また,前述したように凹凸面122を備えたポリオレフィン樹脂フィルムを基材層120とした粘着テープ100において,手切れ性を維持しつつ,粘着テープ100の長手方向への伸びを低減させるための構造を備えた粘着テープ100も提案されている。 Further, as described above, in the adhesive tape 100 using the polyolefin resin film having the uneven surface 122 as the base material layer 120, the structure for reducing the elongation of the adhesive tape 100 in the longitudinal direction while maintaining the hand-cutting property. The adhesive tape 100 provided with the above is also proposed.

このような粘着テープ100として,図7に示すように,ポリオレフィン樹脂フィルム製基材層120の凹凸面122上に形成する粘着剤層130を,不織布又は割布135と粘着剤131とによって形成することを提案したものがある(特許文献2)。 As such an adhesive tape 100, as shown in FIG. 7, the adhesive layer 130 formed on the uneven surface 122 of the polyolefin resin film base material layer 120 is formed by the non-woven fabric or the split cloth 135 and the adhesive 131. There is one that has proposed this (Patent Document 2).

また,図8に示すように,ポリオレフィン樹脂フィルム製基材層120の凹凸面122に,数平均分子量が10,000以上でガラス転移温度が0〜80℃であるポリエステル系樹脂136を塗布した後に,アクリル系の粘着剤を塗布して,粘着剤層130を形成した粘着テープも提案されている(特許文献3)。 Further, as shown in FIG. 8, after applying a polyester resin 136 having a number average molecular weight of 10,000 or more and a glass transition temperature of 0 to 80 ° C. on the uneven surface 122 of the polyolefin resin film base material layer 120. , An adhesive tape in which an adhesive layer 130 is formed by applying an acrylic adhesive is also proposed (Patent Document 3).

特開平3−47885号公報Japanese Unexamined Patent Publication No. 3-47885 特開平9−137133号公報Japanese Unexamined Patent Publication No. 9-137133 実開2001−172586号公報Actual Opening 2001-172586

前掲の特許文献1として紹介した粘着テープ100(図6)では,基材層120として使用するポリオレフィン樹脂フィルムの凹凸面122に,粘着テープ100の長手方向と直交する方向に凹溝123が形成されていることから,粘着テープ100を手で切った場合であっても,基材層120が凹溝123に沿って裂けることで,直線状にきれいに切断することができるようになっている。 In the adhesive tape 100 (FIG. 6) introduced as Patent Document 1 described above, a concave groove 123 is formed on the uneven surface 122 of the polyolefin resin film used as the base material layer 120 in a direction orthogonal to the longitudinal direction of the adhesive tape 100. Therefore, even when the adhesive tape 100 is cut by hand, the base material layer 120 can be cut neatly in a straight line by tearing along the concave groove 123.

しかし,特許文献1に記載の粘着テープ100が基材層120として採用するポリオレフィン樹脂フィルムは,無延伸でありそれ自体,紙又は割布等に比較して伸縮性に富んでいるだけでなく,粘着テープ100の長手方向と直交方向に凹溝123が形成されていることで,肉薄となっている凹溝123の形成部分で基材層120は更に伸び易くなっている。 However, the polyolefin resin film adopted by the adhesive tape 100 described in Patent Document 1 as the base material layer 120 is not only non-stretched and is itself rich in elasticity as compared with paper or split cloth. Since the concave groove 123 is formed in the direction orthogonal to the longitudinal direction of the adhesive tape 100, the base material layer 120 is more easily stretched in the formed portion of the concave groove 123 which is thin.

その結果,このような粘着テープ100にあっては,図5に示したようなロール状に巻かれている状態から必要な長さのテープを引き出す際,あるいは手で切断する際に粘着テープ100の基材層120が長手方向に伸びてしまい,このようにして伸びた状態で被着物に貼着されることとなる。 As a result, in such an adhesive tape 100, when the tape of a required length is pulled out from the state of being wound in a roll shape as shown in FIG. 5, or when the tape is cut by hand, the adhesive tape 100 The base material layer 120 of the above is stretched in the longitudinal direction, and is attached to the adherend in the stretched state in this way.

そして,基材層が伸びた状態で貼着された粘着テープ100は,基材層120が元の形状に復帰しようとして縮むことで,経時と共に被着物上の貼着位置にずれが生じ,あるいは,粘着テープ100の端部が浮きあがって剥離してしまう等の問題が生じ,このような粘着テープを塗装の際のマスキングに使用すれば,塗装位置がずれてしまう。 Then, the adhesive tape 100 attached with the base material layer stretched shrinks in an attempt to return to the original shape of the base material layer 120, so that the attachment position on the adherend shifts with time, or , The end of the adhesive tape 100 is lifted and peeled off, and if such an adhesive tape is used for masking during painting, the coating position will shift.

また,特許文献1に記載の粘着テープ100で基材層120として使用するポリオレフィン樹脂フィルムは,前述したように長手方向に伸びやすく,しかも,基材層に対する粘着剤の塗布時に90〜110℃に加熱して乾燥されることから,その後にロール状に巻き取る際の張力によって,0.3〜1%程度延伸された状態で巻き芯140に巻き取られる。 Further, the polyolefin resin film used as the base material layer 120 in the adhesive tape 100 described in Patent Document 1 is easily stretched in the longitudinal direction as described above, and is heated to 90 to 110 ° C. when the pressure-sensitive adhesive is applied to the base material layer. Since it is heated and dried, it is wound around the winding core 140 in a state of being stretched by about 0.3 to 1% due to the tension when it is subsequently wound into a roll.

その結果,ロール状に巻き取った後に粘着テープ100が長手方向に収縮することで,粘着テープ100のロールは図9に示すようにテレスコープ状(竹の子状)に変型する不良が生じ易くなっている。 As a result, the adhesive tape 100 contracts in the longitudinal direction after being wound into a roll shape, so that the roll of the adhesive tape 100 tends to be deformed into a telescope shape (bamboo shoot shape) as shown in FIG. There is.

一方,このようなテレスコープ状(竹の子状)の変形を防止するために粘着テープ100を低張力で巻き取ると,空気の巻き込みにより巻き巣(空洞)が生じ易くなり,何れも外観不良となって製品としては出荷できず,このようにして生じる不良率は,最大で約1〜7%に及ぶために歩留りが悪い。 On the other hand, if the adhesive tape 100 is wound with low tension in order to prevent such deformation of the telescope shape (bamboo shoot shape), cavities (cavities) are likely to occur due to the entrainment of air, and both of them have a poor appearance. It cannot be shipped as a product, and the defective rate generated in this way reaches a maximum of about 1 to 7%, resulting in poor yield.

さらに,マスキング又は養生用に使用される粘着テープでは,塗装等の作業が完了した後は,これを被着物より剥離・除去することが必要となるが,手切れ性を付与するために長手方向と直交する方向に前述した凹溝123が形成されたポリオレフィン樹脂フィルムを基材層120とした前述の粘着テープ100は,被着物から剥離する作業中にも伸びやすく,かつ,切れやすいことから,剥離作業が煩雑となる。 Furthermore, with adhesive tapes used for masking or curing, it is necessary to peel off and remove the adhesive tape from the adherend after the work such as painting is completed, but in order to impart hand-cutting property, it is necessary to remove it in the longitudinal direction. The adhesive tape 100 having the polyolefin resin film having the concave groove 123 formed in the direction orthogonal to the substrate layer 120 is easy to stretch and cut even during the work of peeling from the adherend. The peeling work becomes complicated.

このように,片面に凹溝123が形成されたポリオレフィン樹脂フィルムを基材層120とした特許文献1に記載の粘着テープ100では,長手方向に伸び易く,その結果,前述した各種の問題が生じることから,このような粘着テープ100の長手方向の伸びを抑制することが要望されている。 As described above, the adhesive tape 100 described in Patent Document 1 in which the polyolefin resin film having the concave groove 123 formed on one side as the base material layer 120 easily stretches in the longitudinal direction, and as a result, the above-mentioned various problems occur. Therefore, it is required to suppress the elongation of the adhesive tape 100 in the longitudinal direction.

このような伸びを抑制する方法としては,凹溝123の深さを浅くすることあるいは,基材層120とするポリオレフィン樹脂フィルム全体を厚くすることも考えられるが,この構成では,粘着テープ100の長手方向の伸びを抑制することはできるものの,粘着テープ100の手切れ性が低下してしまい,特にポリオレフィン樹脂フィルム全体の厚みを厚くする構成では,被着物の表面に対する追従性が低下することで剥離等が生じ易くなる。 As a method of suppressing such elongation, it is conceivable to make the depth of the concave groove 123 shallow or to make the entire polyolefin resin film used as the base material layer 120 thick, but in this configuration, the adhesive tape 100 Although it is possible to suppress elongation in the longitudinal direction, the hand-cutting property of the adhesive tape 100 is reduced, and particularly in a configuration in which the thickness of the entire polyolefin resin film is increased, the followability to the surface of the adherend is reduced. Peeling or the like is likely to occur.

これに対し,前掲の特許文献2に記載されている粘着テープ(図7)では,粘着剤層130に不織布又は割布135を埋設して粘着剤層130を強化することにより,粘着テープ100の長手方向における伸びの発生を抑制している。 On the other hand, in the adhesive tape (FIG. 7) described in Patent Document 2 described above, the adhesive tape 100 is strengthened by embedding a non-woven fabric or a split cloth 135 in the adhesive layer 130 to strengthen the adhesive layer 130. The occurrence of elongation in the longitudinal direction is suppressed.

しかし,この構成では,不織布又は割布135と粘着剤131を一体化させて粘着剤層130を形成する作業が必要で,図10に示すように,不織布又は割布135と粘着剤131を工程紙150上にラミネートするなどして粘着剤層130を形成した後,基材層120となるポリオレフィン樹脂フィルムに積層する等の作業が必要となることから,前述した布テープの場合と同様,製造時の工程数が増えて製造コストが嵩む結果,粘着テープ100が高価なものとなる。 However, in this configuration, it is necessary to integrate the non-woven fabric or the split cloth 135 and the adhesive 131 to form the pressure-sensitive adhesive layer 130, and as shown in FIG. 10, the non-woven fabric or the split cloth 135 and the pressure-sensitive adhesive 131 are stepped. Since it is necessary to form the adhesive layer 130 by laminating it on the paper 150 and then laminating it on the polyolefin resin film to be the base material layer 120, it is manufactured in the same manner as in the case of the cloth tape described above. As a result of the increase in the number of steps and the increase in manufacturing cost, the adhesive tape 100 becomes expensive.

しかも,粘着剤層130に不織布又は割布135を埋没させた構造では,伸びを抑制することはできるものの,手切れ性が大幅に低下する。 Moreover, in the structure in which the non-woven fabric or the split cloth 135 is embedded in the pressure-sensitive adhesive layer 130, the elongation can be suppressed, but the hand-cutting property is significantly reduced.

しかも,不織布又は割布135の埋没によって粘着剤層130の変形性が大幅に低下することから,被着部の表面に対する追従性が低下し,剥離又は浮きが生じ易く,マスキングテープとしての機能が損なわれる可能性もある。 Moreover, since the deformability of the adhesive layer 130 is significantly reduced by burying the non-woven fabric or the split cloth 135, the followability of the adherend to the surface is lowered, peeling or floating is likely to occur, and the function as a masking tape is provided. It can also be compromised.

更に,図8に示したようにポリオレフィン樹脂フィルム製の基材層120に設けた凹凸面122に,粘着剤を塗布する前にポリエステル系樹脂136を塗布した前掲の特許文献3に記載の構成では,伸びは抑制できるかもしれないが,手切れ性は大幅に低下するか,または殆ど失われてしまうと考えられる。 Further, as shown in FIG. 8, in the configuration described in Patent Document 3 described above, the polyester resin 136 is applied to the uneven surface 122 provided on the base material layer 120 made of the polyolefin resin film before the adhesive is applied. , Elongation may be suppressed, but it is considered that the hand-cutting property is significantly reduced or almost lost.

また,下地層としてポリエステル系樹脂136を塗布した後に,これに続けて溶剤型の粘着剤を塗布して粘着剤層130を形成すると,下地のポリエステル系樹脂136が粘着剤131内の溶剤に侵され,異常を生じる,所謂「ソルベントアタック」によりポリエステル系樹脂層136が軟化してしまい,伸びの抑制効果が得られなくなることから,製造方法あるいは材質等についても制約を受けるものと考えられる。 Further, when the polyester resin 136 is applied as the base layer and then the solvent-type pressure-sensitive adhesive is applied to form the pressure-sensitive adhesive layer 130, the base polyester-based resin 136 invades the solvent in the pressure-sensitive adhesive 131. Therefore, the polyester-based resin layer 136 is softened by the so-called "solvent attack" that causes an abnormality, and the effect of suppressing elongation cannot be obtained. Therefore, it is considered that the manufacturing method or the material is also restricted.

そこで本発明は,上記従来技術における欠点を解消するためになされたものであり,前述したように一方の面を平滑面に,他方の面を凹凸面に形成したポリオレフィン樹脂フィルムを基材層とし,該基材層の凹凸面に粘着剤層を形成した粘着テープにおいて,該粘着テープの幅方向の手切れ性を維持しつつ,長手方向の伸びの抑制,具体的には伸びを70%以下,好ましくは50%以下,より好ましくは30%以下に抑制するとともに,引張強度が向上,具体的には100 (N/50mm幅)以上,好ましくは130(N/50mm幅)以上に向上された粘着テープを提供することにより,貼着後の位置ずれ又は剥離を防止すると共に,ロール状に巻かれた粘着テープが図9に示すようなテレスコープ状(竹の子状)に変形することを防止でき,かつ,塗装作業等の終了後,被着物より剥離する際の作業性が良好な粘着テープ及び粘着テープの製造方法を提供することを目的とする。 Therefore, the present invention has been made to eliminate the above-mentioned drawbacks in the prior art, and as described above, a polyolefin resin film having one surface formed as a smooth surface and the other surface as an uneven surface is used as a base material layer. In an adhesive tape in which an adhesive layer is formed on the uneven surface of the base material layer, the elongation in the longitudinal direction is suppressed while maintaining the hand-cutting property in the width direction of the adhesive tape, specifically, the elongation is 70% or less. , Preferably suppressed to 50% or less, more preferably 30% or less, and the tensile strength was improved, specifically 100 (N / 50 mm width) or more, preferably 130 (N / 50 mm width) or more. By providing the adhesive tape, it is possible to prevent the adhesive tape from being displaced or peeled off after being attached, and to prevent the adhesive tape wound in a roll shape from being deformed into a telescope shape (bamboo child shape) as shown in FIG. Moreover, it is an object of the present invention to provide an adhesive tape and a method for producing an adhesive tape, which have good workability when peeled from an adherend after completion of painting work or the like.

以下に,課題を解決するための手段を,発明を実施するための形態で使用する符号と共に記載する。この符号は,特許請求の範囲の記載と発明を実施するための形態の記載との対応を明らかにするために記載したものであり,言うまでもなく,本願発明の技術的範囲の解釈に制限的に用いられるものではない。 The means for solving the problem are described below together with the reference numerals used in the embodiment of the invention. This reference numeral is described in order to clarify the correspondence between the description of the claims and the description of the form for carrying out the invention. Needless to say, this reference numeral is limited to the interpretation of the technical scope of the present invention. Not used.

上記目的を達成するために,本発明の粘着テープ10は,
片面に長手方向と直交する方向に複数本の凹溝23が所定間隔で形成された凹凸面22を有する未延伸のポリオレフィン樹脂製フィルム基材層20と,前記基材層20の前記凹凸面22上に形成された粘着剤層30を備え,前記基材層及び/又は前記粘着剤層30の粘着剤中に繊維片32が分散されていることを特徴とする(請求項1,図1〜3参照)。
In order to achieve the above object, the adhesive tape 10 of the present invention is used.
An unstretched polyolefin resin film base material layer 20 having a concavo-convex surface 22 in which a plurality of concave grooves 23 are formed at predetermined intervals on one surface in a direction orthogonal to the longitudinal direction, and the concavo-convex surface 22 of the base material layer 20. The pressure-sensitive adhesive layer 30 formed above is provided, and the fiber pieces 32 are dispersed in the pressure-sensitive adhesive of the base material layer and / or the pressure-sensitive adhesive layer 30 (claim 1, FIGS. 1 to 1). 3).

なお,本発明において『繊維片』には,短繊維の単体又は,短繊維又は長繊維の断片等から成るモノフィラメントの他,モノフィラメントを撚り合わせて得たマルチフィラメント(糸)の断片を含む。 In the present invention, the "fiber piece" includes a monofilament composed of a simple substance of a short fiber, a fragment of a short fiber or a long fiber, and a fragment of a multifilament (thread) obtained by twisting a monofilament.

前記粘着剤層30が,前記粘着剤31の固形分100重量部に対し,前記繊維片32を0.5〜10重量部,好ましくは1〜5重量部含有することを特徴とする(請求項2,図1(A))。 The pressure-sensitive adhesive layer 30 is characterized by containing 0.5 to 10 parts by weight, preferably 1 to 5 parts by weight, of the fiber piece 32 with respect to 100 parts by weight of the solid content of the pressure-sensitive adhesive 31 (claim). 2, Fig. 1 (A)).

前記繊維片32としては,繊維径が0.05〜100デニール(0.01〜200μm径),好ましくは1〜10デニール(15〜60μm)より好ましくは0.5〜4デニール(3〜40μm)のものを使用することができる(請求項3)。 The fiber piece 32 has a fiber diameter of 0.05 to 100 denier (0.01 to 200 μm diameter), preferably 1 to 10 denier (15 to 60 μm), more preferably 0.5 to 4 denier (3 to 40 μm). Can be used (claim 3).

なお,「デニール」とは,9000mの糸の質量をグラム単位で表したものであり,上記「デニール」の1/9の値が,JIS及びISOで使用する「テックス」(1000mの糸の質量をグラム単位で表したもの)に対応する。 The "denier" is the mass of a 9000 m thread expressed in grams, and the value of 1/9 of the above "denier" is the "tex" (mass of a 1000 m thread) used in JIS and ISO. Is expressed in grams).

また,前記繊維片32の長さは,1〜10mm,好ましくは1〜7mm,より好ましくは2〜5mmのものが使用可能である(請求項4)。 Further, the length of the fiber piece 32 can be 1 to 10 mm, preferably 1 to 7 mm, and more preferably 2 to 5 mm (claim 4).

なお,前記繊維径及び繊維長は,各種のものを混合して用いることができる。 It should be noted that various fiber diameters and fiber lengths can be mixed and used.

更に,前記基材層が,前記基材層固形分100重量部に対し,前記繊維片を0.2〜10重量部,好ましくは0.5〜3重量部含有することを特徴とする(請求項5,図1(B))。 Further, the base material layer is characterized by containing 0.2 to 10 parts by weight, preferably 0.5 to 3 parts by weight, of the fiber pieces with respect to 100 parts by weight of the solid content of the base material layer (claimed). Item 5, FIG. 1 (B)).

上記本発明の粘着テープ10は,長手方向の伸びを30%以下,好ましくは20%以下,より好ましくは16%以下である(請求項6)。 The adhesive tape 10 of the present invention has an elongation in the longitudinal direction of 30% or less, preferably 20% or less, and more preferably 16% or less (claim 6).

また,長手方向の引張強さが100(N/50mm幅)以上であることが好ましい(請求項7)。 Further, it is preferable that the tensile strength in the longitudinal direction is 100 (N / 50 mm width) or more (claim 7).

本発明の粘着テープ10の前記粘着剤層30は,厚み方向の全体に亘り繊維片32が均一に分散されたものとしても良いが(図1(A)参照),好ましくは,被着物に対する貼着側(紙面下側)において前記繊維片32の分散量が減少する,又は,前記繊維片32を含まない構成とすることが好ましい(請求項8,図2及び3参照)。 The pressure-sensitive adhesive layer 30 of the pressure-sensitive adhesive tape 10 of the present invention may have fiber pieces 32 uniformly dispersed over the entire thickness direction (see FIG. 1A), but is preferably attached to an adherend. It is preferable that the amount of dispersion of the fiber pieces 32 is reduced on the landing side (lower side of the paper surface), or that the fiber pieces 32 are not included (see claims 8, FIGS. 2 and 3).

更に,前記粘着剤層30は,基材層20との貼着側(紙面上側)において前記繊維片32の分散量が減少する,又は,前記繊維片32を含まない構成とすることが好ましい(請求項9,図3参照)。 Further, it is preferable that the pressure-sensitive adhesive layer 30 has a structure in which the amount of dispersion of the fiber pieces 32 is reduced on the side of attachment (upper side of the paper surface) to the base material layer 20 or the fiber pieces 32 are not contained. Claim 9, see FIG. 3).

なお,粘着剤層30に分散させる前記繊維片32としては,アクリル系,PET,オレフィン系樹脂,レーヨン,ビニロン,ナイロンの群から選択されたいずれかの材質から成るものを使用でき,該繊維片32の一種を,又は二種以上を混合したものを,前記粘着剤層30に分散させるものとしても良い(請求項10)。 As the fiber piece 32 to be dispersed in the pressure-sensitive adhesive layer 30, one made of any material selected from the group of acrylic, PET, olefin resin, rayon, vinylon, and nylon can be used, and the fiber piece can be used. One of 32 types, or a mixture of two or more types, may be dispersed in the pressure-sensitive adhesive layer 30 (claim 10).

また,本発明の粘着テープ10の製造方法は,
片面に長手方向と直交する方向に複数本の凹溝23が所定間隔で形成された凹凸面22を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層20の前記凹凸面22に,粘着剤を積層して粘着剤層30を形成すると共に,前記基材層及び/又は前記粘着剤層に,繊維片32を分散させたことを特徴とする(請求項11)。
Further, the method for manufacturing the adhesive tape 10 of the present invention is as follows.
An adhesive is applied to the uneven surface 22 of the base material layer 20 made of an unstretched polyolefin resin film having uneven surfaces 22 having a plurality of concave grooves 23 formed at predetermined intervals on one side in a direction orthogonal to the longitudinal direction. It is characterized in that the pressure-sensitive adhesive layer 30 is formed by laminating, and the fiber pieces 32 are dispersed in the base material layer and / or the pressure-sensitive adhesive layer (claim 11).

前記粘着剤層30の形成は,前記繊維片32の分散量を変化させた複数種類の粘着剤を多層に積層することにより,被着物との接着面側で前記繊維片32の分散量が減少する,又は被着物との接着面側で前記繊維片32を含まない前記粘着剤層30を形成するものとしても良い(請求項12,図2及び図3参照)。 In the formation of the pressure-sensitive adhesive layer 30, the dispersion amount of the fiber pieces 32 is reduced on the adhesive surface side with the adherend by laminating a plurality of types of pressure-sensitive adhesives in which the dispersion amount of the fiber pieces 32 is changed in multiple layers. Alternatively, the pressure-sensitive adhesive layer 30 that does not contain the fiber piece 32 may be formed on the adhesive surface side with the adherend (see claim 12, FIGS. 2 and 3).

また,同様に繊維片32の分散量を変化させた複数種類の粘着剤を多層に積層して,前記基材層20の前記凹凸面22との接着面側で前記繊維片32の分散量が減少する,又は前記基材層20の前記凹凸面22との接着面側で前記繊維片を含まない前記粘着剤層30を形成するものとしても良い(請求項13,図3参照)。 Similarly, a plurality of types of pressure-sensitive adhesives in which the dispersion amount of the fiber pieces 32 is changed are laminated in multiple layers, and the dispersion amount of the fiber pieces 32 is increased on the adhesive surface side of the base material layer 20 with the uneven surface 22. The amount may be reduced, or the pressure-sensitive adhesive layer 30 containing no fiber pieces may be formed on the adhesive surface side of the base material layer 20 with the uneven surface 22 (see claims 13 and 3).

以上で説明した本発明の構成により,本発明の粘着テープ10では,以下の顕著な効果を得ることかできた。 With the configuration of the present invention described above, the adhesive tape 10 of the present invention could obtain the following remarkable effects.

片面に凹溝23が形成された凹凸面22を備えた未延伸のポリオレフィン樹脂フィルムを基材層20として使用すると共に,該基材層20の前記凹凸面22上に,粘着剤31を積層して粘着剤層30を形成すると共に,前記基材層及び/又は前記粘着剤層に繊維片32を分散することで,幅方向の手切れ性を維持しつつ,長手方向の伸びを小さくした粘着テープ10を得ることができた。 An unstretched polyolefin resin film having an uneven surface 22 having a concave groove 23 formed on one surface is used as the base material layer 20, and an adhesive 31 is laminated on the uneven surface 22 of the base material layer 20. By forming the pressure-sensitive adhesive layer 30 and dispersing the fiber pieces 32 in the base material layer and / or the pressure-sensitive adhesive layer, adhesiveness with reduced elongation in the longitudinal direction while maintaining hand-cutting property in the width direction. The tape 10 could be obtained.

このような繊維片の分散による伸びの抑制は,繊維の分散によって前記基材層及び/又は前記粘着剤層が高架橋となったかのような挙動を示す,(本明細書においてこのような挙動を示す状態を「疑似架橋状態」という)ことで,物理的に伸びが抑制されるものであり,化学的な架橋と比べて,粘着力に寄与する官能基等を塞ぐことがなく,粘着力の発現を低下させることがない点で有利である。 The suppression of elongation by the dispersion of the fiber pieces behaves as if the base material layer and / or the pressure-sensitive adhesive layer is hypercrosslinked by the dispersion of the fibers (these behavior is exhibited in the present specification). By (the state is called a "pseudo-crosslinked state"), the elongation is physically suppressed, and compared to chemical cross-linking, the functional groups that contribute to the adhesive force are not blocked, and the adhesive force is developed. It is advantageous in that it does not reduce.

このように,本発明の粘着テープ10は,長手方向の伸びを小さくできたことで,ロール状に巻かれた状態から引き出す際に伸び難く,伸びた状態で貼着された粘着テープが縮むことで生じる貼着位置のずれ,端部の浮き上がりによる剥離の発生を防止でき,また,巻き巣の発生を防止するためにテンションを掛けて巻き取った場合であっても伸びが生じ難いことから,ロール状に巻き取られた後に粘着テープ10が縮むことで生じるテレスコープ状(竹の子状)の変形についても好適に防止することができ,これにより不良品の発生を抑制して歩留りを向上させることができた。 As described above, the adhesive tape 10 of the present invention can be stretched less in the longitudinal direction, so that it is difficult to stretch when it is pulled out from the rolled state, and the adhesive tape attached in the stretched state shrinks. It is possible to prevent the sticking position from shifting and the edge from rising due to peeling, and even when the tape is wound with tension to prevent the formation of cavities, it is unlikely to stretch. It is also possible to suitably prevent the deformation of the telescope shape (bamboo shoot shape) caused by the shrinkage of the adhesive tape 10 after being wound into a roll shape, thereby suppressing the occurrence of defective products and improving the yield. Was made.

また,粘着テープ10の長手方向における引張り強度を向上させることができたことから,例えば塗装等の作業が終了した後,マスキングテープとして使用していた粘着テープ10を被着物から剥離・除去する際に,粘着テープを破断等させることなく容易に剥離・除去することが可能である。 Further, since the tensile strength of the adhesive tape 10 in the longitudinal direction could be improved, for example, when the adhesive tape 10 used as the masking tape is peeled off / removed from the adherend after the work such as painting is completed. In addition, the adhesive tape can be easily peeled off and removed without breaking.

特に,繊維片32の添加量を粘着剤31の固形分100重量部に対し,0.5〜10重量部,好ましくは1〜5重量部又は,前記基材層が,前記基材層固形分100重量部に対し,前記繊維片を0.2〜10重量部含有するのみでよいという,比較的少量であり,また,分散させる繊維片32として0.05〜100デニールという比較的細径のものを使用することで,粘着テープ10の手切れ性を殆ど犠牲にすることなく,粘着テープ10の伸びの抑制と引張り強度の向上を得ることができた。 In particular, the amount of the fiber piece 32 added is 0.5 to 10 parts by weight, preferably 1 to 5 parts by weight, or the base material layer is the base material layer solid content with respect to 100 parts by weight of the solid content of the pressure-sensitive adhesive 31. It is a relatively small amount that only 0.2 to 10 parts by weight of the fiber piece needs to be contained with respect to 100 parts by weight, and the fiber piece 32 to be dispersed has a relatively small diameter of 0.05 to 100 denier. By using the adhesive tape 10, it was possible to suppress the elongation of the adhesive tape 10 and improve the tensile strength without sacrificing the hand-cutting property of the adhesive tape 10.

粘着剤31に添加する繊維片32を,1〜10mm,好ましくは1〜7mm,より好ましくは2〜5mmという比較的短いものを使用したことで,粘着剤に対する繊維片32の分散が容易である一方,この長さの繊維片の分散でも必要な伸び率の抑制と引張強さの向上を得ることができた。 By using a relatively short fiber piece 32 to be added to the pressure-sensitive adhesive 31, which is 1 to 10 mm, preferably 1 to 7 mm, and more preferably 2 to 5 mm, the fiber piece 32 can be easily dispersed in the pressure-sensitive adhesive. On the other hand, even with the dispersion of fiber pieces of this length, it was possible to obtain the necessary suppression of elongation and improvement of tensile strength.

前記基材層20の凹凸面22に,前記粘着テープ10の長手方向と平行な方向に複数本の凹溝(図示せず)を所定間隔で形成した構成では,粘着テープ10の幅方向の手切れ性のみならず,長手方向の手切れ性についても付与することができた。 In the configuration in which a plurality of concave grooves (not shown) are formed on the uneven surface 22 of the base material layer 20 in a direction parallel to the longitudinal direction of the adhesive tape 10 at predetermined intervals, the hands in the width direction of the adhesive tape 10 are formed. Not only the cutability but also the hand cutability in the longitudinal direction could be imparted.

前記粘着剤層30中の前記繊維片32の分散量を,被着物との接着面側で減少させ,又は,前記繊維片32を含まない構成とした例では,繊維片32の分散によっても被着物に対する良好な接着性を維持することができた。 In the example in which the dispersion amount of the fiber pieces 32 in the pressure-sensitive adhesive layer 30 is reduced on the adhesive surface side with the adherend, or the structure does not include the fiber pieces 32, the fibers pieces 32 are also dispersed. It was possible to maintain good adhesiveness to the kimono.

また,粘着剤層30中の前記繊維片32の分散量を,基材層20の凹凸面22との接着面側でも減少させ,又は繊維片32を含まない構成とした例では,基材層20の凹凸面22と粘着剤層30間の強固な接着を得ることができ,被着物より粘着テープ10を剥がす際に,層間剥離が生じて粘着剤層30の一部が被着物の表面に付着したまま残る,所謂「糊残り」の発生についても好適に防止することができた。 Further, in the example in which the amount of the fiber pieces 32 dispersed in the pressure-sensitive adhesive layer 30 is also reduced on the adhesive surface side of the base material layer 20 with the uneven surface 22, or the fiber pieces 32 are not included, the base material layer is used. Strong adhesion between the uneven surface 22 of 20 and the pressure-sensitive adhesive layer 30 can be obtained, and when the pressure-sensitive adhesive tape 10 is peeled off from the adherend, delamination occurs and a part of the pressure-sensitive adhesive layer 30 is on the surface of the adherend. It was also possible to suitably prevent the occurrence of so-called "glue residue" that remains attached.

さらに,従来の基材層としての工程が多く,コストの高い繊維を縦横(経緯)に織る事なく,既存の織物型テープの代替ともなる粘着テープが得られ,高い経済効果をもたらす。 Furthermore, since there are many processes as a conventional base material layer, an adhesive tape that can replace the existing woven tape can be obtained without weaving expensive fibers vertically and horizontally (warp and weft), which brings about a high economic effect.

なお,上記課題を解決するため基材層として過去に試みられたポリプロピレンとポリエチレンの混合樹脂においては,融点の違いから,押し出しフィルムに発生するたわみ,巻取りのしわ,ラインでのしわ(アバラ,フレアとも呼ばれる)が多発していたが,ポリプロピレンに代替する本願の繊維片により,上記効果を達成すると共に,このようなしわの発生をきわめて少ないものとすることができた。 In the polypropylene and polyethylene mixed resin that has been tried in the past as a base material layer to solve the above problems, the deflection generated in the extruded film, the wrinkles in the winding, and the wrinkles in the line (Abara,) due to the difference in melting point. Although flare (also called flare) occurred frequently, the fiber pieces of the present application that replaced polypropylene were able to achieve the above effects and minimize the occurrence of such wrinkles.

本発明の粘着テープの断面模式図で,同図(A)は,粘着剤層が繊維片を有する実施形態を示し,同図(B)は基材層及び粘着剤層に繊維片を有する実施形態を示す。In the schematic cross-sectional view of the adhesive tape of the present invention, FIG. 3A shows an embodiment in which the pressure-sensitive adhesive layer has fiber pieces, and FIG. 3B shows an embodiment in which the base material layer and the pressure-sensitive adhesive layer have fiber pieces. Shows the morphology. 本発明の別の粘着テープの断面模式図。FIG. 6 is a schematic cross-sectional view of another adhesive tape of the present invention. 本発明のさらに別の粘着テープの断面模式図。FIG. 6 is a schematic cross-sectional view of still another adhesive tape of the present invention. 基材層となるポリオレフィン樹脂フィルムの製造方法の説明図。The explanatory view of the manufacturing method of the polyolefin resin film which becomes a base material layer. ロール状に巻き取った状態の粘着テープの斜視図。A perspective view of the adhesive tape wound into a roll. 従来の粘着テープの説明図(特許文献1に対応)。Explanatory drawing of a conventional adhesive tape (corresponding to Patent Document 1). 従来の粘着テープの説明図(特許文献2に対応)。Explanatory drawing of a conventional adhesive tape (corresponding to Patent Document 2). 従来の粘着テープの説明図(特許文献3に対応)。Explanatory drawing of the conventional adhesive tape (corresponding to Patent Document 3). テレスコープ状(竹の子状)に変形した粘着テープの説明図。Explanatory drawing of the adhesive tape deformed into a telescope shape (bamboo shoot shape). 従来の粘着テープの製造方法の説明図(特許文献2の図3に対応)。Explanatory drawing of the conventional method of manufacturing an adhesive tape (corresponding to FIG. 3 of Patent Document 2).

次に,本発明の実施形態につき添付図面を参照しながら説明する。 Next, an embodiment of the present invention will be described with reference to the accompanying drawings.

〔全体構造〕
本発明の粘着テープ10は,図1〜3に示すように一方の面を平滑面21とし,他方の面に粘着テープ10の長手方向と直交する方向の多数の凹溝23が形成された凹凸面22としたポリオレフィン樹脂フィルムを基材層20とし,この基材層20の凹凸面22に,粘着剤層30を設けた,手切れ性を有する粘着テープ10である点では,前掲の特許文献1〜3として挙げた従来の粘着テープと同様の構成である。
[Overall structure]
As shown in FIGS. 1 to 3, the adhesive tape 10 of the present invention has a smooth surface 21 on one surface and a large number of concave grooves 23 formed on the other surface in a direction orthogonal to the longitudinal direction of the adhesive tape 10. The above-mentioned patent document is a self-cutting adhesive tape 10 in which a polyolefin resin film as a surface 22 is used as a base material layer 20 and an adhesive layer 30 is provided on the uneven surface 22 of the base material layer 20. It has the same configuration as the conventional adhesive tapes listed as 1 to 3.

本発明の粘着テープ10は,前述の粘着剤層30の少なくとも一部に繊維片32を分散させることにより,手切れ性を維持しつつ粘着テープ10の長手方向の伸びの抑制と,引張強さを向上させた,一例として総厚み120〜300μmの粘着テープである。 In the adhesive tape 10 of the present invention, the fiber pieces 32 are dispersed in at least a part of the above-mentioned adhesive layer 30, so that the adhesive tape 10 can be stretched in the longitudinal direction while maintaining hand-cutting property, and the tensile strength can be suppressed. As an example, it is an adhesive tape having a total thickness of 120 to 300 μm.

〔基材層〕
本発明の粘着テープ10で基材層20として使用するフィルムは,未延伸のポリオレフィン樹脂のフィルムであり,これは公知のポリオレフィン樹脂を使用して製造することかできる。
[Base layer]
The film used as the base material layer 20 in the adhesive tape 10 of the present invention is an unstretched polyolefin resin film, which can be produced by using a known polyolefin resin.

このようなポリオレフィン樹脂としては,例えばポリエチレン樹脂,ポリプロピレン樹脂,エチレンとプロピレンとの共重合体樹脂,エチレン及び/又はプロピレンと他の一種または二種以上のα−オレフィンとの共重合体樹脂などを例示することができる。 Examples of such polyolefin resins include polyethylene resins, polypropylene resins, copolymer resins of ethylene and propylene, and copolymer resins of ethylene and / or propylene and one or more other α-olefins. It can be exemplified.

このうちのα−オレフィンとしては,例えばブテン−1,ペンテン−1,ヘキセン−1,ヘプテン−1,オクテン−1,ノネン−1,4−メチルペンテン−1,デセン−1等を挙げることができる。 Examples of the α-olefin include butene-1, penten-1, hexene-1, heptene-1, octene-1, nonene-1, 4-methylpentene-1, and decene-1. ..

好ましいポリオレフィン樹脂の例としては,ポリエチレン樹脂を挙げることかできる。 A polyethylene resin can be mentioned as an example of a preferable polyolefin resin.

ポリオレフィン樹脂の分子量は,フィルムに成形し得る範囲であれば特に制限されないが,樹脂の流れ性を表す尺度であるメルトインデックスで表すと,一般に0.2〜20g/10分の範囲,好ましくは1〜10g/10分(いずれも荷重2.16kg,温度190℃)の範囲である。 The molecular weight of the polyolefin resin is not particularly limited as long as it can be molded into a film, but when expressed by the melt index, which is a measure of the flowability of the resin, it is generally in the range of 0.2 to 20 g / 10 minutes, preferably 1. The range is 10 g / 10 minutes (load 2.16 kg, temperature 190 ° C.).

本発明の粘着テープ10の基材層20となる前述のポリオレフィン樹脂のシートの厚さは,一例として40〜400μmの範囲であるが,この厚さに限定されず,用途等に応じて適宜の厚さに設定し得る。 The thickness of the above-mentioned polyolefin resin sheet serving as the base material layer 20 of the adhesive tape 10 of the present invention is, for example, in the range of 40 to 400 μm, but is not limited to this thickness, and is appropriately used depending on the application and the like. Can be set to thickness.

このポリオレフィン樹脂シートは,一方の面を平滑面21とし,他方の面を凹凸面22としており,この凹凸面22に,粘着テープ10の長手方向に対し直交方向を成す凹溝23が多数形成されている。 In this polyolefin resin sheet, one surface is a smooth surface 21 and the other surface is an uneven surface 22, and a large number of concave grooves 23 forming orthogonal to the longitudinal direction of the adhesive tape 10 are formed on the uneven surface 22. ing.

この凹溝23は,粘着テープ10を手で切断する際に基材層20に破断が生じる位置となるもので,このような手による切断を可能と成すものであれば,その断面形状は,図示したようなV字状の他,矩形状,(半)円形状等,如何なる形状であっても良く,その深さも,特に限定されるものではないが,前述したシート厚40〜400μmのポリオレフィン樹脂のシートを基材層20として使用する場合,深さは,30μm未満では手切れ性が損なわれることから,30〜300μm,好ましくは40〜120μmの凹溝23を形成し,凹溝23の形成部分における肉厚を,10〜100μmとすることが好ましい。 The concave groove 23 is a position where the base material layer 20 is broken when the adhesive tape 10 is cut by hand. If the groove 23 can be cut by hand, the cross-sectional shape thereof is In addition to the V-shape as shown in the figure, any shape such as a rectangular shape or a (semi-) circular shape may be used, and the depth thereof is not particularly limited, but the above-mentioned polyolefin having a sheet thickness of 40 to 400 μm. When the resin sheet is used as the base material layer 20, if the depth is less than 30 μm, the hand-cutting property is impaired. Therefore, a concave groove 23 of 30 to 300 μm, preferably 40 to 120 μm is formed, and the concave groove 23 is formed. The wall thickness at the formed portion is preferably 10 to 100 μm.

この凹溝23の間隔は,0.5mm未満では粘着テープ10の長手方向に強度が不足し,5mmを超えると本来の手切れ性が不十分となる可能性があることから,一例として0.5〜5mm,好ましくは0.6〜1.4mm間隔に設定することができる。但し,これよりも広く,又は狭く形成しても良い。 If the distance between the concave grooves 23 is less than 0.5 mm, the strength is insufficient in the longitudinal direction of the adhesive tape 10, and if it exceeds 5 mm, the original hand-cutting property may be insufficient. Therefore, as an example, 0. It can be set at intervals of 5 to 5 mm, preferably 0.6 to 1.4 mm. However, it may be formed wider or narrower than this.

前述したポリオレフィン樹脂を原料として,一方の面を平滑面21,他方の面を凹凸面22としたポリオレフィン樹脂シートを製造する方法の一例を,図4に示す。 FIG. 4 shows an example of a method for producing a polyolefin resin sheet using the above-mentioned polyolefin resin as a raw material, with one surface as a smooth surface 21 and the other surface as an uneven surface 22.

図4に示す例では,溶融されたポリオレフィン樹脂を押出機50の押出ダイ51よりフィルム状に押出した後,押し出されたフィルムが未だ完全に室温まで冷却されていない状態でエンボスロール61とゴムロール62間を通過させることにより,ゴムロール62との接触側に平滑面21,エンボスロール61との接触側にエンボスロール61の表面に設けた凸条61aに対応する形状の凹溝23を形成している。 In the example shown in FIG. 4, after the molten polyolefin resin is extruded into a film from the extrusion die 51 of the extruder 50, the embossed roll 61 and the rubber roll 62 are in a state where the extruded film has not yet been completely cooled to room temperature. By passing through the space, a smooth surface 21 is formed on the contact side with the rubber roll 62, and a concave groove 23 having a shape corresponding to the ridge 61a provided on the surface of the emboss roll 61 is formed on the contact side with the emboss roll 61. ..

粘着剤との馴染みを良好なものとして層間剥離が生じることを防止するために,ポリオレフィン樹脂フィルムに形成した凹凸面22には,図4に示すように,放電電極64と,平滑な表面を有する処理ロール65間を通過させる際にコロナ放電処理を行うものとしても良い。 As shown in FIG. 4, the uneven surface 22 formed on the polyolefin resin film has a discharge electrode 64 and a smooth surface in order to improve the compatibility with the adhesive and prevent delamination from occurring. The corona discharge treatment may be performed when passing between the treatment rolls 65.

このようにコロナ放電処理を行うことで,凹凸面22と後述する粘着剤31との親和性(凹凸面に対する接着剤の投錨性,凹凸面のぬれ性)を向上させることができ,粘着テープ10を被着物より剥離する際に層間剥離が生じて粘着剤が被着物の表面上に残る,所謂「糊残り」の発生を防止することができる。 By performing the corona discharge treatment in this way, the affinity between the uneven surface 22 and the adhesive 31 described later (the anchoring property of the adhesive on the uneven surface and the wettability of the uneven surface) can be improved, and the adhesive tape 10 can be improved. It is possible to prevent the occurrence of so-called "glue residue" in which delamination occurs and the adhesive remains on the surface of the adherend when the adhesive is peeled off from the adherend.

なお,前述したように凹凸面22に対するコロナ放電処理は,粘着剤層30との馴染みを良好とする上で好ましいが,本発明の粘着テープ10においてこのコロナ放電処理は必須ではなく,必要に応じて処理を行うものすれば良い。 As described above, the corona discharge treatment on the uneven surface 22 is preferable in order to improve the compatibility with the pressure-sensitive adhesive layer 30, but the corona discharge treatment is not essential for the adhesive tape 10 of the present invention, and if necessary. It suffices to process it.

基材層20のダイン数(濡れ指数)は,平滑面21に対し凹凸面22の方が大きくなっていることが好ましく,好ましいダイン数(濡れ指数)は一例として平滑面21で30Dyn/cm以下,凹凸面22で35Dyn/cm以上であり,平滑面21の濡れ指数が30Dyn/cmより大きいと,粘着テープ10をロール状に巻き取った際に平滑面21と粘着剤層30が必要以上に強固に接着してしまう,所謂「ブロッキング現象」の発生によって,粘着テープ10を展開することが困難となる。 The number of dyne (wetting index) of the base material layer 20 is preferably larger on the uneven surface 22 than on the smooth surface 21, and the preferable number of dyne (wetting index) is 30 Dyn / cm or less on the smooth surface 21 as an example. If the uneven surface 22 is 35 Dyn / cm or more and the wetting index of the smooth surface 21 is larger than 30 Dyn / cm, the smooth surface 21 and the adhesive layer 30 become more than necessary when the adhesive tape 10 is wound into a roll. The occurrence of the so-called "blocking phenomenon" in which the adhesive tape 10 is firmly adhered makes it difficult to deploy the adhesive tape 10.

一方,凹凸面22のぬれ指数が35Dyn/cm未満であると,凹凸面22に対する粘着剤31の接着力が不足して,前述した「糊残り」等が生じる原因となる。 On the other hand, if the wetting index of the uneven surface 22 is less than 35 Dyn / cm, the adhesive force of the adhesive 31 to the uneven surface 22 is insufficient, which causes the above-mentioned “glue residue” and the like.

なお,凹凸面22に対する粘着剤層30の親和性を高めるための方法としては,前述したコロナ放電処理の他に,プライマーを塗布する方法もある。 In addition to the corona discharge treatment described above, there is also a method of applying a primer as a method for increasing the affinity of the pressure-sensitive adhesive layer 30 with respect to the uneven surface 22.

このようなプライマーの塗布による親和性の向上も良く知られた方法であり,プライマーとしては既知の各種のもの,例えばニトリルゴム等のゴム系のプライマー,アクリル樹脂系のプライマーなどを使用することができる。 Improving the affinity by applying such a primer is also a well-known method, and it is possible to use various known primers such as rubber-based primers such as nitrile rubber and acrylic resin-based primers. it can.

なお,前述したコロナ放電処理と同様,本発明ではプライマーの塗布も必須ではなく,必要に応じて適宜行うことができ,また,前述したコロナ放電処理に代え,又はコロナ放電処理と併用してプライマー塗布を行っても良い。 As with the corona discharge treatment described above, the application of a primer is not essential in the present invention and can be appropriately performed as needed, and the primer can be used instead of the corona discharge treatment described above or in combination with the corona discharge treatment. You may apply it.

基材層に繊維片を添加する場合,繊維片の一次分散は,マスターバッチでポリオレフィン樹脂と混練を得て,押出機ホッパーへと供給される。用いられる繊維片は,ポリオレフィン樹脂の熱溶融温度200℃域を超えていなければならず,これらから,ポリエステル系(Tg220℃),ナイロン(Tg220℃),アクリル系(熱硬化),で最も好ましいのは熱溶融とは無縁なレーヨンが好ましいが防水性からは,ポリプロピレン系,ポリエステル系が好ましい。 When fiber pieces are added to the substrate layer, the primary dispersion of the fiber pieces is kneaded with the polyolefin resin in a masterbatch and supplied to the extruder hopper. The fiber pieces used must exceed the thermal melting temperature of the polyolefin resin in the range of 200 ° C., and from these, polyester-based (Tg220 ° C.), nylon (Tg220 ° C.), and acrylic-based (thermosetting) are most preferable. Rayon, which is unrelated to thermosetting, is preferable, but polypropylene and polyester are preferable from the viewpoint of waterproofness.

繊維片の分散した基材層20は,未延伸のポリオレフィン樹脂のフィルムであり,これは公知のポリオレフィン樹脂を使用して製造することができる。 The base material layer 20 in which the fiber pieces are dispersed is an unstretched polyolefin resin film, which can be produced by using a known polyolefin resin.

〔粘着剤層〕
以上のように構成されたポリオレフィン樹脂のフィルムから成る基材層20及び/又はこの基材層20の凹凸面22には,繊維片32が分散される粘着剤層30が形成される。
[Adhesive layer]
An adhesive layer 30 in which the fiber pieces 32 are dispersed is formed on the base material layer 20 made of the polyolefin resin film configured as described above and / or the uneven surface 22 of the base material layer 20.

繊維片
基材層20又は粘着剤層30中に分散される前述の繊維片32としては,アクリル,ポリエチレン,ポリプロピレン,ポリエチレンテレフタレート,6−ナイロン,6,6−ナイロン,ポリパラフェニレンテレフタルアミド,ポリアクリルニトリル,ビニロン,レーヨン,麻,絹,毛等の繊維を挙げることができる。
Fiber pieces Examples of the above-mentioned fiber pieces 32 dispersed in the base material layer 20 or the pressure-sensitive adhesive layer 30 include acrylic, polyethylene, polypropylene, polyethylene terephthalate, 6-nylon, 6,6-nylon, polyparaphenylene terephthalamide, and poly. Fibers such as acrylic nitrile, vinylon, rayon, hemp, silk, and hair can be mentioned.

この繊維片32は,綿又は麻,羊毛等の短繊維の単体又は,これら短繊維又は絹又は化学繊維等の長繊維の断片等から成るモノフィラメントであっても良く,又は,モノフィラメントを撚り合わせて得たマルチフィラメント(糸)の断片であっても良い。 The fiber piece 32 may be a simple substance of short fibers such as cotton or hemp, wool, or a monofilament composed of fragments of these short fibers or long fibers such as silk or chemical fibers, or the monofilaments are twisted together. It may be a fragment of the obtained multifilament (thread).

これらのうち特にレーヨン,ポリエチレン,ポリプロピレン,ポリエチレンテレフタレートの使用は,基材層とするポリオレフィン樹脂フィルムとの接着性,耐熱性,耐溶剤性等の観点から好ましい。 Of these, the use of rayon, polyethylene, polypropylene, and polyethylene terephthalate is particularly preferable from the viewpoints of adhesiveness, heat resistance, solvent resistance, etc. to the polyolefin resin film used as the base material layer.

これらの原料から成る繊維片32は,単一の原料から成る繊維片32のみを単独で使用してもよいが,異なる原料で製造された複数種類の繊維片32を2種類以上混ぜて使用するものとしても良い。 As the fiber piece 32 made of these raw materials, only the fiber piece 32 made of a single raw material may be used alone, but a plurality of types of fiber pieces 32 manufactured from different raw materials may be mixed and used. It may be a thing.

また,繊維片32は,着色したものを使用することもでき,あるいは予め着色しておいた原料を使用して製造した繊維片32を使用することもできる。 Further, as the fiber piece 32, a colored one can be used, or a fiber piece 32 manufactured by using a pre-colored raw material can be used.

繊維片32の添加量は,得られる粘着テープ10の,粘着力,靱性,手切れ性・手触り(柔らかさ)等の観点から,粘着テープの粘着剤固形分100重量部に対し,0.5〜10重量部とすることが好ましく,より好ましくは1〜5重量部である。 The amount of the fiber piece 32 added is 0.5 with respect to 100 parts by weight of the adhesive solid content of the adhesive tape from the viewpoint of adhesive strength, toughness, hand cutting property, touch (softness), etc. of the obtained adhesive tape 10. The amount is preferably 10 parts by weight, more preferably 1 to 5 parts by weight.

基材層における繊維片の添加量としては,前記基材層固形分100重量部に対し,0.2〜10重量部,ここでは,0.5〜3重量部である。 The amount of the fiber pieces added to the base material layer is 0.2 to 10 parts by weight, here 0.5 to 3 parts by weight, with respect to 100 parts by weight of the solid content of the base material layer.

なお,本発明で繊維片32として使用する材質としては,粘着剤として後述のアクリル系のものを使用する場合,アクリル系のものの使用が好ましく,また,アクリル系の繊維片の使用は耐熱性,耐水性の点でも好ましい。 As the material used as the fiber piece 32 in the present invention, when an acrylic material described later is used as the adhesive, it is preferable to use an acrylic material, and the acrylic fiber piece is heat resistant. It is also preferable in terms of water resistance.

また,耐水性の点ではポリエステル系のものの使用も好ましく,また,耐熱性の点ではレーヨン繊維も好適に使用できる。 Further, polyester fiber is preferably used in terms of water resistance, and rayon fiber can also be preferably used in terms of heat resistance.

粘着剤
粘着剤層30を構成する粘着剤としては,既知の各種の粘着剤を使用可能であり,一例としてアクリル系粘着剤,ビニルエーテル系粘着剤,シリコン系粘着剤,ゴム系粘着剤等を挙げることができる。
Adhesives As the adhesives constituting the adhesive layer 30, various known adhesives can be used, and examples thereof include acrylic adhesives, vinyl ether adhesives, silicone adhesives, and rubber adhesives. be able to.

使用する粘着剤の形態も特に制限されず,溶液型粘着剤,エマルジョン型粘着剤,ホットメルト型粘着剤等のいずれの型のものを使用しても良い。 The form of the pressure-sensitive adhesive to be used is not particularly limited, and any type of pressure-sensitive adhesive, emulsion-type pressure-sensitive adhesive, hot-melt-type pressure-sensitive adhesive, or the like may be used.

粘着剤層の積層方法
前述した粘着剤層30の形成は,予め繊維を分散させておいた粘着剤を,前述した基材層20の凹凸面22に塗布することにより,あるいは工程紙上に塗布した後,前記基材層20の凹凸面22に転写することにより形成する。
Method of Laminating the Adhesive Layer The above-mentioned adhesive layer 30 is formed by applying an adhesive in which fibers are dispersed in advance to the above-mentioned uneven surface 22 of the base material layer 20 or on process paper. After that, it is formed by transferring to the uneven surface 22 of the base material layer 20.

この粘着剤層30は,例えば図1(A)に示すように繊維片32が分散された粘着剤を1層塗工することにより形成した単層の粘着剤層30によって形成するものとしても良いが,好ましくは,図2及び図3に示すように繊維片32の分散量が異なる複数種類の粘着剤(繊維片を含まない粘着剤を含む)を2層以上塗工して,粘着剤層30の厚み方向における繊維片32の分散量に勾配を持たせるものとしても良い。 The pressure-sensitive adhesive layer 30 may be formed by, for example, a single-layer pressure-sensitive adhesive layer 30 formed by applying one layer of a pressure-sensitive adhesive in which fiber pieces 32 are dispersed, as shown in FIG. 1 (A). However, preferably, as shown in FIGS. 2 and 3, two or more layers of a plurality of types of pressure-sensitive adhesives (including a pressure-sensitive adhesive containing no fiber pieces) having different dispersion amounts of the fiber pieces 32 are applied to form a pressure-sensitive adhesive layer. The amount of dispersion of the fiber pieces 32 in the thickness direction of 30 may be provided with a gradient.

前述した繊維片32は,これを基材層20及び/又は粘着剤層30中に分散させることにより,基材層20及び/又は粘着剤層30が補強されて伸びが低減すると共に引張強さの向上を得ることができる一方で,粘着剤層30に前述した疑似架橋を生じさせ,被着物の表面に対する追従性及び接着力を低下させる原因となり得る。 By dispersing the above-mentioned fiber piece 32 in the base material layer 20 and / or the pressure-sensitive adhesive layer 30, the base material layer 20 and / or the pressure-sensitive adhesive layer 30 is reinforced to reduce elongation and tensile strength. On the other hand, the pressure-sensitive adhesive layer 30 may cause the above-mentioned pseudo-crosslinking, which may cause a decrease in followability and adhesive strength to the surface of the adherend.

そこで,図2に示すように粘着剤層30のうち,基材層20側(紙面上側)を相対的の繊維片32の含有量が多い粘着剤を積層して形成した粘着剤層(図示の例では繊維片含有粘着剤層301)とする一方,被着物と接着する側(紙面下側)を繊維片32の添加量が少ない粘着剤,又は,繊維片32を添加していない粘着剤を積層して形成した粘着剤層(図示の例では繊維片被含有粘着剤層302)とした,複層構造の粘着剤層を形成するものとしても良い。 Therefore, as shown in FIG. 2, of the pressure-sensitive adhesive layer 30, the pressure-sensitive adhesive layer (shown) is formed by laminating a pressure-sensitive adhesive having a large content of relative fiber pieces 32 on the base material layer 20 side (upper side of the paper surface). In the example, the fiber piece-containing pressure-sensitive adhesive layer 301) is used, while the side that adheres to the adherend (lower side of the paper surface) is a pressure-sensitive adhesive with a small amount of the fiber piece 32 added, or a pressure-sensitive adhesive to which the fiber piece 32 is not added. A multi-layered pressure-sensitive adhesive layer may be formed as a pressure-sensitive adhesive layer (fiber piece-covered pressure-sensitive adhesive layer 302 in the illustrated example) formed by laminating.

また,図3に示すように,基材層と粘着剤層間の層間剥離を防止するために,粘着剤層30の厚み方向中央部に繊維片32の分散量が相対的に多い粘着剤を積層して形成した粘着剤層(図示の例では繊維片含有粘着剤層301)を設ける一方,これを中心としてその外側に繊維片の分散量が少ない,又は繊維片を分散させていない粘着剤を塗布,積層して形成した粘着剤層(図示の例では第1の繊維片非含有粘着剤層302a,第2の繊維片非含有粘着剤層302b)を形成した三層構造の粘着剤層30を形成し,被着物との接着性を向上させるのみならず,基材層20との接着性を向上させるものとしても良い。 Further, as shown in FIG. 3, in order to prevent delamination between the base material layer and the pressure-sensitive adhesive layer, a pressure-sensitive adhesive having a relatively large amount of dispersed fiber pieces 32 is laminated on the central portion of the pressure-sensitive adhesive layer 30 in the thickness direction. A pressure-sensitive adhesive layer (fiber piece-containing pressure-sensitive adhesive layer 301 in the illustrated example) is provided, while a pressure-sensitive adhesive having a small amount of fiber pieces dispersed or no fiber pieces dispersed around the adhesive layer is provided. A three-layered pressure-sensitive adhesive layer 30 on which a pressure-sensitive adhesive layer (first fiber piece-free pressure-sensitive adhesive layer 302a and second fiber-piece-free pressure-sensitive adhesive layer 302b in the illustrated example) formed by coating and laminating is formed. , Not only improving the adhesiveness with the adherend, but also improving the adhesiveness with the base material layer 20.

このようにして得られた粘着テープ10は,既知の粘着テープと同様,図5に示すように例えば25m,50mといった所定の長さを巻き取って形成したロールの状態で提供される。 The adhesive tape 10 thus obtained is provided in the form of a roll formed by winding a predetermined length such as 25 m or 50 m as shown in FIG. 5, similarly to the known adhesive tape.

ロール状に巻き取った状態で粘着テープを提供する場合,粘着剤としてゴム系粘着剤を使用する場合又は,粘着剤の塗布量が多い場合等には,粘着テープ10の展開性を向上させるために,基材層20の平滑面21に既知の剥離剤を塗布する等しても良い。 To improve the expandability of the adhesive tape 10 when the adhesive tape is provided in a rolled state, when a rubber-based adhesive is used as the adhesive, or when the amount of the adhesive applied is large. A known release agent may be applied to the smooth surface 21 of the base material layer 20.

以下に本発明の粘着テープ(実施例1〜3)と,従来の粘着テープ(比較例1)の性能評価試験を行った結果を実施例として記載するが,本発明はこれら実施例によりその範囲を限定されるものではない。 The results of performance evaluation tests of the adhesive tape of the present invention (Examples 1 to 3) and the conventional adhesive tape (Comparative Example 1) are described below as examples, and the present invention is within the scope of these examples. Is not limited.

試験方法
本発明の粘着テープ(実施例1〜3)と,従来の粘着テープ(比較例1:特許文献1に記載のものに対応)を作成し,各粘着テープの引きはがし粘着力(N/25mm),長手方向の引張強さ(N/50mm幅),及び伸び(%)を測定すると共に,手切れ性を評価した。
Test method An adhesive tape of the present invention (Examples 1 to 3) and a conventional adhesive tape (Comparative Example 1: corresponding to those described in Patent Document 1) are prepared, and the peeling adhesive strength (N /) of each adhesive tape is prepared. 25 mm), longitudinal tensile strength (N / 50 mm width), and elongation (%) were measured, and hand-cutting property was evaluated.

なお,上記の試験において,粘着テープの引きはがし粘着力(N/25mm),引張強さ(N/50mm幅)及び伸び(%)は,JIS Z 0237-1991に基づき測定した。 In the above test, the peeling adhesive strength (N / 25 mm), tensile strength (N / 50 mm width) and elongation (%) of the adhesive tape were measured based on JIS Z 0237-1991.

なお,引きはがし粘着力(N/25mm),引張強さ(N/50mm幅)及び伸び(%)とは概略,下記の通りである。 The peeling adhesive strength (N / 25 mm), tensile strength (N / 50 mm width) and elongation (%) are roughly as follows.

引きはがし粘着力
SUS304鋼板〔表面仕上げBA(bright annealed finish/冷間圧延後,光輝熱処理したもの),表面粗さRa50±2.5nm〕に貼着した粘着テープ(幅25mm)を,SUS304鋼板に対し180°の角度で50mmの長さ引きはがした際に要した力の平均値を引きはがし接着力として測定した。
Peeling adhesive strength SUS304 steel sheet [surface finish BA (bright annealed finish / brightly heat-treated after cold rolling), surface roughness Ra50 ± 2.5 nm] adhesive tape (width 25 mm) attached to SUS304 steel sheet The average value of the force required when the length of 50 mm was peeled off at an angle of 180 ° was measured as the peeling adhesive force.

引張強さ及び伸び
粘着テープ(幅50mm)をつかみ間隔100mmで把持したチャックを5±0.2mm/sの速さで離間させて粘着テープを引っ張り,粘着テープが切断するまでの荷重及び伸びを測定し,切断するまでの最大荷重P(N)を引張強さ(N/50mm幅)とした。
Tensile strength and elongation The chuck that grips the adhesive tape (width 50 mm) with an interval of 100 mm is separated at a speed of 5 ± 0.2 mm / s to pull the adhesive tape, and the load and elongation until the adhesive tape is cut are applied. The maximum load P (N) until cutting was taken as the tensile strength (N / 50 mm width).

また,試験片とした粘着テープの,試験開始時の長さに対する伸びた長さ(切断時の長さから試験開始時の長さを引いた値)を百分率で表したものを「伸び」とした。 In addition, the length of the adhesive tape used as the test piece, which is the length of the adhesive tape at the start of the test (the length at the time of cutting minus the length at the start of the test), is expressed as a percentage. did.

また,手切れ性の評価は,粘着テープを手(指先)のみで幅方向に切断した時の「切断箇所の直線性」と「切断の容易性」を評価したもので,切断が容易で,かつ,切断箇所が直線状であるものを「○」,それ以外を「×」と評価した。 In addition, the evaluation of hand-cutting property is to evaluate the "straightness of the cutting point" and "easiness of cutting" when the adhesive tape is cut in the width direction only with the hand (fingertip), and it is easy to cut. In addition, those with straight cuts were evaluated as "○", and those with other cut points were evaluated as "×".

実施例及び比較例
〔実施例1〕
基材層
ポリオレフィン樹脂として,密度が0.96g/cm3,メルトインデックスが7.0g/10分(190℃,2.16kg/cm2)のポリエチレン樹脂1重量部と,密度が0.92g/cm3,メルトインデックスが4.0g/10分(190℃,2.16kg/cm2)のポリエチレン樹脂3重量部との混合物を使用した。
Example and Comparative Example [Example 1]
Base material layer As a polyolefin resin, 1 part by weight of polyethylene resin with a density of 0.96 g / cm 3 and a melt index of 7.0 g / 10 minutes (190 ° C, 2.16 kg / cm 2 ) and a density of 0.92 g / cm 3, a melt index was used a mixture of polyethylene resin 3 parts by weight of 4.0 g / 10 min (190 ℃, 2.16kg / cm 2 ).

上記樹脂を160〜190℃で押出加工して得られる溶融シートを,平滑な表面を有するゴムロールとエンボスロール間を通過させ,一方の面を平坦面,他方の面に深さ0.08mmの凹溝が1.2mm間隔で形成された凹凸面が形成された厚さ0.11mmのフィルムを得た。 A molten sheet obtained by extruding the above resin at 160 to 190 ° C. is passed between a rubber roll having a smooth surface and an embossed roll, and one surface is a flat surface and the other surface is a recess of 0.08 mm in depth. A film having a thickness of 0.11 mm was obtained in which uneven surfaces having grooves formed at intervals of 1.2 mm were formed.

上記フィルムの凹凸面に対し,濡れ指数が45Dynとなるようコロナ放電処理を行い,基材層フィルムとした。 The uneven surface of the film was subjected to corona discharge treatment so that the wetting index was 45 Dyn to obtain a base film.

粘着剤層
前記基材層20の凹凸面22に,粘着剤固形分100重量部に対し繊維片を1重量部分散させた粘着剤を塗布し,80〜120℃に設定された乾燥炉を5分間通過させて,図1(A)に示すように単層の粘着剤層30を,仕上がり厚みで25μmとなるように形成した。
Adhesive layer The uneven surface 22 of the base material layer 20 is coated with an adhesive in which 1 part by weight of fiber pieces is dispersed with respect to 100 parts by weight of the adhesive solid content, and a drying furnace set at 80 to 120 ° C. is applied to 5 parts. After passing for a minute, as shown in FIG. 1 (A), the single-layer pressure-sensitive adhesive layer 30 was formed so that the finished thickness was 25 μm.

使用した粘着剤は,アクリル系粘着剤〔サイデン化学株式会社製「#AT−40D」(溶液状の粘着剤であり,溶媒はトルエンと酢酸エチルを重量比で9対1に混合したもの。濃度は45重量%〕100重量部と,ポリイソシアネート系の架橋剤〔日本ポリウレタン株式会社製「コロネートL75」〕0.5重量部とからなる粘着剤である。 The pressure-sensitive adhesive used was an acrylic pressure-sensitive adhesive [“# AT-40D” manufactured by Saiden Chemical Co., Ltd. (a solution-type pressure-sensitive adhesive, and the solvent was a mixture of toluene and ethyl acetate in a weight ratio of 9: 1). Is a pressure-sensitive adhesive composed of 100 parts by weight [45% by weight] and 0.5 parts by weight of a polyisocyanate-based cross-linking agent [“Coronate L75” manufactured by Nippon Polyurethane Co., Ltd.].

上記の粘着剤固形分100重量部比に対して繊維片として1重量部,太さ1.2デニール,長さ5mmのポリエステル系繊維を分散した。 A polyester fiber having a thickness of 1.2 denier and a length of 5 mm was dispersed as a fiber piece with respect to the above-mentioned pressure-sensitive adhesive solid content ratio of 100 parts by weight.

〔実施例2〕
基材層
実施例1と同じである。
粘着剤層
前記基材層20の凹凸面22に繊維片が分散された粘着剤を塗布すると共に,前記繊維片が分散された粘着剤層上に,更に繊維片を含まない粘着剤を塗布し,実施例1と同様の方法で乾燥させて,図2に示すように,繊維片含有粘着剤層301と繊維片非含有粘着剤層302の二層構造を有する仕上がり厚み(総厚み)25μmの粘着剤層30を形成した。
[Example 2]
Base material layer Same as in Example 1.
Adhesive layer A pressure-sensitive adhesive in which fiber pieces are dispersed is applied to the uneven surface 22 of the base material layer 20, and a pressure-sensitive adhesive containing no fiber pieces is further applied on the pressure-sensitive adhesive layer in which the fiber pieces are dispersed. , Dryed in the same manner as in Example 1, and as shown in FIG. 2, has a finished thickness (total thickness) of 25 μm having a two-layer structure of a fiber piece-containing adhesive layer 301 and a fiber piece-free adhesive layer 302. The pressure-sensitive adhesive layer 30 was formed.

繊維片含有粘着剤層301は,実施例1で使用した粘着剤(繊維片を分散したもの)を塗布して形成されたものであり,仕上がり厚み15μmである。 The fiber piece-containing pressure-sensitive adhesive layer 301 is formed by applying the pressure-sensitive adhesive (dispersed fiber pieces) used in Example 1, and has a finished thickness of 15 μm.

また,繊維片非含有粘着剤層302は,繊維片を含まない点を除き実施例1の粘着剤と同じ組成の粘着剤を塗布して形成されたもので,仕上がり厚み10μmである。 The fiber piece-free pressure-sensitive adhesive layer 302 is formed by applying a pressure-sensitive adhesive having the same composition as the pressure-sensitive adhesive of Example 1 except that it does not contain fiber pieces, and has a finished thickness of 10 μm.

上記繊維片含有粘着剤層301と繊維片非含有粘着剤層302は,多層ダイス(二層)を使用した共押出によって,基材層20の凹凸面22上に形成した。 The fiber piece-containing pressure-sensitive adhesive layer 301 and the fiber piece-free pressure-sensitive adhesive layer 302 were formed on the uneven surface 22 of the base material layer 20 by coextrusion using a multilayer die (two layers).

〔実施例3〕
基材層
実施例1と同じである。
粘着剤層
前記基材層20の凹凸面22に,繊維片を含まない粘着剤を塗布し,この繊維片を含まない粘着剤上に,繊維片32が分散された粘着剤を塗布し,前記繊維片32が分散された粘着剤上にさらに繊維片を含まない粘着剤を塗布し,実施例1と同様の方法で乾燥させて,図3に示すように基材層20の凹凸面22に積層された第1の繊維片非含有粘着剤層302a,前記第1の繊維片非含有粘着剤層302a上に積層された繊維片含有粘着剤層301,及び前記繊維片含有粘着剤層301上に積層された第2の繊維片非含有粘着剤層302bの三層構造を有する,仕上がり厚み(総厚み)30μmの粘着剤層30を形成した。
[Example 3]
Base material layer Same as in Example 1.
Adhesive layer A pressure-sensitive adhesive containing no fiber pieces is applied to the uneven surface 22 of the base material layer 20, and a pressure-sensitive adhesive in which the fiber pieces 32 are dispersed is applied onto the pressure-sensitive adhesive containing no fiber pieces. A pressure-sensitive adhesive containing no fiber pieces is further applied onto the pressure-sensitive adhesive in which the fiber pieces 32 are dispersed, dried in the same manner as in Example 1, and applied to the uneven surface 22 of the base material layer 20 as shown in FIG. On the laminated first fiber piece-free pressure-sensitive adhesive layer 302a, the fiber piece-containing pressure-sensitive adhesive layer 301 laminated on the first fiber piece-free pressure-sensitive adhesive layer 302a, and the fiber-piece-containing pressure-sensitive adhesive layer 301. A pressure-sensitive adhesive layer 30 having a finished thickness (total thickness) of 30 μm having a three-layer structure of a second fiber piece-free pressure-sensitive adhesive layer 302b laminated on the surface was formed.

第1の繊維片非含有粘着剤層302aは,繊維片32を含まない点を除き実施例1の粘着剤と同じ組成の粘着剤を塗布して形成したもので,仕上がり厚み7μmである。 The first fiber piece-free pressure-sensitive adhesive layer 302a is formed by applying a pressure-sensitive adhesive having the same composition as the pressure-sensitive adhesive of Example 1 except that the fiber piece 32 is not contained, and has a finished thickness of 7 μm.

繊維片含有粘着剤層301は,粘着剤固形分100重量部に対し,繊維片を1.5重量部分散させた粘着剤を塗布して仕上がり厚み15μmに形成したもので,使用した粘着剤は,繊維片の配合量を0.5重量部増量した点を除き,実施例1で説明したものと同様である。 The fiber piece-containing pressure-sensitive adhesive layer 301 was formed by applying a pressure-sensitive adhesive in which 1.5 parts by weight of fiber pieces were dispersed to 100 parts by weight of the pressure-sensitive adhesive solid content to form a finished thickness of 15 μm. The pressure-sensitive adhesive used was , The same as that described in Example 1 except that the blending amount of the fiber pieces was increased by 0.5 parts by weight.

更に,第2の繊維片非含有粘着剤層302bは,繊維片32を含まない点を除き実施例1の粘着剤と同じ組成の粘着剤を塗布して形成されたもので,仕上がり厚み8μmである。 Further, the second fiber piece-free pressure-sensitive adhesive layer 302b is formed by applying a pressure-sensitive adhesive having the same composition as the pressure-sensitive adhesive of Example 1 except that the fiber piece 32 is not contained, and has a finished thickness of 8 μm. is there.

上記第1の繊維片非含有粘着剤層302a,繊維片含有粘着剤層301及び第2の繊維片非含有粘着剤層302bは,多層ダイス(三層)を使用した共押出によって,基材層20の凹凸面22上に形成した。 The first fiber piece-free pressure-sensitive adhesive layer 302a, the fiber piece-containing pressure-sensitive adhesive layer 301, and the second fiber-piece-free pressure-sensitive adhesive layer 302b are coextruded using a multilayer die (three layers) to form a base material layer. It was formed on the uneven surface 22 of 20.

〔比較例1〕
基材層
実施例1と同じである。
粘着剤層
基材層の凹凸面に,繊維片を含まない粘着剤を塗布すると共に,実施例1で説明したと同様の方法で乾燥させて,仕上がり厚み25μmの粘着剤層を形成した。
[Comparative Example 1]
Base material layer Same as in Example 1.
Adhesive layer A pressure-sensitive adhesive containing no fiber fragments was applied to the uneven surface of the base material layer and dried in the same manner as described in Example 1 to form a pressure-sensitive adhesive layer having a finished thickness of 25 μm.

粘着剤層の形成に使用した粘着剤は,繊維片を含まない点を除き実施例1で使用した粘着剤と同様である。 The pressure-sensitive adhesive used to form the pressure-sensitive adhesive layer is the same as the pressure-sensitive adhesive used in Example 1 except that it does not contain fiber fragments.

試験結果
以上で説明した実施例1〜3,及び比較例1の粘着テープを使用して,引きはがし粘着力(N/25mm),引張強さ(N/50mm幅)及び伸び(%)を測定すると共に,手切れ性を評価した結果を下記の表1に示す。
Test Results Using the adhesive tapes of Examples 1 to 3 and Comparative Example 1 described above, the peeling adhesive strength (N / 25 mm), tensile strength (N / 50 mm width) and elongation (%) were measured. The results of evaluating the hand-cutting property are shown in Table 1 below.

Figure 0006788891
Figure 0006788891

〔実施例4〕
基材層
図1(B)に示すように,ポリオレフィン樹脂として,密度が0.96g/cm3,メルトインデックスが7.0g/10分(190℃,2.16kg/cm2)のポリエチレン樹脂1重量部と,密度が0.92g/cm3,メルトインデックスが4.0g/10分(190℃,2.16kg/cm2)のポリエチレン樹脂3重量部とこれらのポリオレフィン樹脂100重量部に対してポリエステル系繊維片を1重量,繊維太さ1.2デニール,長さ3mmを混練した。
[Example 4]
Base material layer As shown in FIG. 1 (B), as a polyolefin resin, a polyethylene resin having a density of 0.96 g / cm 3 and a melt index of 7.0 g / 10 minutes (190 ° C., 2.16 kg / cm 2 ) 1 For 3 parts by weight of polyethylene resin with a density of 0.92 g / cm 3 and a melt index of 4.0 g / 10 minutes (190 ° C, 2.16 kg / cm 2 ) and 100 parts by weight of these polyolefin resins. One weight of a polyester fiber piece, a fiber thickness of 1.2 denier, and a length of 3 mm were kneaded.

上記からなる樹脂を160〜190℃で押出加工して得られる溶融シートを,平滑な表面を有するゴムロールとエンボスロール間を通過させ,一方の面を平坦面,他方の面に深さ0.08mmの凹溝が1.2mm間隔で形成された凹凸面が形成された厚さ0.11mmのフィルムを得た。 A molten sheet obtained by extruding the above resin at 160 to 190 ° C. is passed between a rubber roll having a smooth surface and an embossed roll, and one surface is a flat surface and the other surface is 0.08 mm deep. A film having a thickness of 0.11 mm was obtained, in which uneven surfaces were formed in which the concave grooves were formed at intervals of 1.2 mm.

上記フィルムの凹凸面に対し,濡れ指数が45Dynとなるようコロナ放電処理を行い,基材層フィルムとした。 The uneven surface of the film was subjected to corona discharge treatment so that the wetting index was 45 Dyn to obtain a base film.

粘着剤層
実施例1と同じ。
Adhesive layer Same as Example 1.

〔実施例5〕 粘着剤層に繊維片を含まない例
基材層
実施例4と同じ
粘着剤層
前記基材層20の凹凸面22に,粘着剤を塗布し,80〜120℃に設定された乾燥炉を5分間通過させて,図1に示すように単層の粘着剤層30を,仕上がり厚みで25μmとなるように形成した。
[Example 5] Example in which the pressure-sensitive adhesive layer does not contain fiber fragments Base material layer The same pressure-sensitive adhesive layer as in Example 4 The pressure-sensitive adhesive is applied to the uneven surface 22 of the base material layer 20 and set at 80 to 120 ° C. After passing through the drying oven for 5 minutes, a single-layer adhesive layer 30 was formed so as to have a finished thickness of 25 μm as shown in FIG.

使用した粘着剤は,アクリル系粘着剤〔サイデン化学株式会社製「#AT−40D」(溶液状の粘着剤であり,溶媒はトルエンと酢酸エチルを重量比で9対1に混合したもの。濃度は45重量%〕100重量部と,ポリイソシアネート系の架橋剤〔日本ポリウレタン株式会社製「コロネートL75」〕0.5重量部とからなる粘着剤である。 The pressure-sensitive adhesive used was an acrylic pressure-sensitive adhesive [“# AT-40D” manufactured by Saiden Chemical Co., Ltd. (a solution-type pressure-sensitive adhesive, and the solvent was a mixture of toluene and ethyl acetate in a weight ratio of 9: 1). Is a pressure-sensitive adhesive composed of 100 parts by weight [45% by weight] and 0.5 parts by weight of a polyisocyanate-based cross-linking agent [“Coronate L75” manufactured by Nippon Polyurethane Co., Ltd.].

Figure 0006788891
Figure 0006788891

試験結果の考察
前出表1及び表2に示す以上の試験結果から,本発明の粘着テープは,実施例1〜3のいずれともに,比較例1の粘着テープに比較して引張強さが50N(約63%)向上していると共に,伸びが40%から14〜16%(減少率約60〜65%)に減少し,実施例4及び5では,引張り強さが60〜70N(約75〜87.5%)向上していると共に,伸びが40%から11〜12%以下(減少率約70〜72.5%)と大幅に減少していることが確認された。
Consideration of Test Results From the above test results shown in Tables 1 and 2 above, the adhesive tape of the present invention has a tensile strength of 50 N as compared with the adhesive tape of Comparative Example 1 in both Examples 1 to 3. With the improvement (about 63%), the elongation decreased from 40% to 14 to 16% (decrease rate of about 60 to 65%), and in Examples 4 and 5, the tensile strength was 60 to 70 N (about 75). It was confirmed that the growth was improved from 40% to 11 to 12% or less (decrease rate of about 70 to 72.5%), and the growth was significantly reduced.

一方,このような引張り強さの増大又は伸びの減少に拘わらず,実施例1〜5の粘着テープは,いずれも比較例1の粘着テープと同等の手切れ性を発揮している。 On the other hand, in spite of such an increase in tensile strength or a decrease in elongation, the adhesive tapes of Examples 1 to 5 all exhibit the same hand-cutting property as the adhesive tape of Comparative Example 1.

なお,実施例1〜3の粘着テープは,比較例1の粘着テープに比較して,引きはがし粘着力が0.5〜1N低下しているが,この程度の接着力の低下は,実用上,問題とならない程度の低下である。 The adhesive tapes of Examples 1 to 3 have a peeling adhesive strength of 0.5 to 1 N lower than that of the adhesive tape of Comparative Example 1, but such a decrease in adhesive strength is practically possible. , The decrease is not a problem.

以上の結果から,本発明の粘着テープで採用した,粘着剤層に繊維片を分散させる構造が,粘着テープの手切れ性を維持しつつ,引張り強さの増大又は伸びを減少させる上で有効であることが確認された。 From the above results, the structure in which the fiber pieces are dispersed in the adhesive layer adopted in the adhesive tape of the present invention is effective in increasing the tensile strength or reducing the elongation while maintaining the hand-cutting property of the adhesive tape. It was confirmed that.

このように,本発明の粘着テープでは,伸びが大幅に低減された結果,ロール状に巻き取った状態から引き出す際又は,手で切断する際に伸びが生じ難く,その結果,被着物に貼着した後に縮むこともなく,このような縮みに伴う貼着位置のずれ又は剥離が防止できるものと考えられる。 As described above, as a result of the adhesive tape of the present invention being significantly reduced in elongation, it is difficult for elongation to occur when the adhesive tape is pulled out from the rolled state or when it is cut by hand, and as a result, it is attached to an adherend. It is considered that the attachment position does not shrink after being worn, and the attachment position can be prevented from shifting or peeling due to such shrinkage.

また,空気の巻き込みにより巻き巣(空洞)が生じることを防止するためにテンションを掛けてロール状に巻き取った場合であっても粘着テープに伸びが生じ難いことから,ロール状に巻き取った後に粘着テープが長手方向に縮むことによって生じるテレスコープ状(竹の子状)の変形も生じ難くなると考えられ,歩留りの向上が期待される。 In addition, since the adhesive tape is unlikely to stretch even when it is wound in a roll shape by applying tension to prevent the formation of a cavity (cavity) due to the entrainment of air, the adhesive tape is wound in a roll shape. It is thought that the telescope-like (bamboo shoot-like) deformation caused by the adhesive tape shrinking in the longitudinal direction will be less likely to occur later, and the yield is expected to improve.

更に,引張り強さが増大したことにより,破断等し難くなっていることから,例えば塗装作業の終了後に被着面よりマスキング等に使用された粘着テープを引き剥がす際の作業性が向上する。 Further, since the tensile strength is increased, it is difficult to break or the like, so that the workability when peeling off the adhesive tape used for masking or the like from the adherend surface after the completion of the painting work is improved.

しかも,繊維片による補強により,引張強さを130(N/50mm幅)と大幅に向上させることができたことから,本発明は,工程が多く,コストの高い繊維を縦横(経緯)に織る事なく,既存の織物系基材層のテープの代替ともなる粘着テープが得られ,塗装等の際に使用するマスキングテープ又は養生用のテープとしての用途のみならず,例えば資材等の結束又は梱包等に使用する粘着テープとしての使用にも十分に耐え得るものとなっている。 Moreover, since the tensile strength could be significantly improved to 130 (N / 50 mm width) by reinforcement with fiber pieces, the present invention weaves fibers with many steps and high cost in the vertical and horizontal directions (warp and weft). Adhesive tape that can be used as a substitute for the tape of the existing woven fabric base layer can be obtained without any problem, and it can be used not only as a masking tape or a curing tape used for painting, but also for bundling or packing materials, for example. It is sufficiently durable to be used as an adhesive tape used for such purposes.

10 粘着テープ
20 基材層(ポリオレフィン樹脂シート)
21 平滑面
22 凹凸面
23 凹溝
30 粘着剤層
301 繊維片含有粘着剤層
302 繊維片非含有粘着剤層
302a 第1の繊維片非含有粘着剤層
302b 第2の繊維片非含有粘着剤層
31 粘着剤
32 繊維片
40 巻き芯
50 押出機
51 押出ダイ
61 エンボスロール
61a 凸条
62 ゴムロール
64 放電電極
65 処理ロール
100 粘着テープ
120 基材層
121 平滑面
122 凹凸面
123 凹溝
130 粘着剤層
131 粘着剤
135 不織布又は割布
136 ポリエステル系樹脂
140 巻き芯
150 工程紙
10 Adhesive tape 20 Base material layer (polyolefin resin sheet)
21 Smooth surface 22 Concavo-convex surface 23 Concave groove 30 Adhesive layer 301 Fiber fragment-containing adhesive layer 302 Fiber fragment-free adhesive layer 302a First fiber fragment-free adhesive layer 302b Second fiber fragment-free adhesive layer 31 Adhesive 32 Fiber Piece 40 Winding Core 50 Extruder 51 Extruding Die 61 Embossing Roll 61a Convex 62 Rubber Roll 64 Discharge Electrode 65 Treatment Roll 100 Adhesive Tape 120 Base Material Layer 121 Smooth Surface 122 Concavo-convex Surface 123 Concave Groove 130 Adhesive Layer 131 Adhesive 135 Non-woven fabric or split cloth 136 Polyester resin 140 Roll core 150 Process paper

Claims (13)

片面に長手方向と直交する方向に複数本の凹溝が所定間隔で形成された凹凸面を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層と,
前記基材層の前記凹凸面上に形成された粘着剤層を備え,
前記基材層及び/又は前記粘着剤層の粘着剤中に,繊維片が分散されていることを特徴とする粘着テープ。
A base material layer made of an unstretched polyolefin resin film having an uneven surface in which a plurality of concave grooves are formed at predetermined intervals on one side in a direction orthogonal to the longitudinal direction.
A pressure-sensitive adhesive layer formed on the uneven surface of the base material layer is provided.
An adhesive tape characterized in that fiber pieces are dispersed in the pressure-sensitive adhesive of the base material layer and / or the pressure-sensitive adhesive layer.
前記粘着剤層が,前記粘着剤の固形分100重量部に対し,前記繊維片を0.5〜10重量部含有することを特徴とする請求項1記載の粘着テープ。 The pressure-sensitive adhesive tape according to claim 1, wherein the pressure-sensitive adhesive layer contains 0.5 to 10 parts by weight of the fiber pieces with respect to 100 parts by weight of the solid content of the pressure-sensitive adhesive. 前記繊維片の繊維径が,0.05〜100デニールであることを特徴とする請求項1又は2記載の粘着テープ。 The adhesive tape according to claim 1 or 2, wherein the fiber diameter of the fiber piece is 0.05 to 100 denier. 前記繊維片の長さが1〜10mmであることを特徴とする請求項1〜3いずれか1項記載の粘着テープ。 The adhesive tape according to any one of claims 1 to 3, wherein the length of the fiber piece is 1 to 10 mm. 前記基材層が,前記基材層固形分100重量部に対し,前記繊維片を0.2〜10重量部含有することを特徴とする請求項1,3又は4いずれか1項記載の粘着テープ。 The adhesive according to any one of claims 1, 3 or 4, wherein the base material layer contains 0.2 to 10 parts by weight of the fiber piece with respect to 100 parts by weight of the solid content of the base material layer. tape. 長手方向の伸びが30%以下である請求項1〜5いずれか1項記載の粘着テープ。 The adhesive tape according to any one of claims 1 to 5, wherein the elongation in the longitudinal direction is 30% or less. 長手方向の引張強さが100(N/50mm幅)以上であることを特徴とする請求項1〜6いずれか1項記載の粘着テープ。 The adhesive tape according to any one of claims 1 to 6, wherein the tensile strength in the longitudinal direction is 100 (N / 50 mm width) or more. 前記粘着剤層が,被着物に対する貼着側において前記繊維片の分散量が減少する,又は,前記繊維片を含まない構成であることを特徴とする請求項1〜4又は6〜7いずれか1項記載の粘着テープ。 Any of claims 1 to 4 or 6 to 7, wherein the pressure-sensitive adhesive layer has a structure in which the dispersion amount of the fiber pieces is reduced on the side to be attached to the adherend or does not contain the fiber pieces. The adhesive tape according to item 1. 前記粘着剤層が,基材層との貼着側において前記繊維片の分散量が減少する,又は,前記繊維片を含まない構成であることを特徴とする請求項8記載の粘着テープ。 The adhesive tape according to claim 8, wherein the pressure-sensitive adhesive layer has a structure in which the dispersion amount of the fiber pieces is reduced on the side to be adhered to the base material layer or the pressure-sensitive adhesive layer does not contain the fiber pieces. 前記繊維片が,PET,オレフィン系樹脂,レーヨン,ビニロン,ナイロンの群から選択されたいずれかの材質から成り,該繊維片の一種を,又は二種以上を混合したものを,前記粘着剤層に分散させたことを特徴とする請求項1〜9いずれか1項記載の粘着テープ。 The fiber piece is made of any material selected from the group of PET, olefin resin, rayon, vinylon, and nylon, and one type of the fiber piece or a mixture of two or more kinds is used as the pressure-sensitive adhesive layer. The adhesive tape according to any one of claims 1 to 9, wherein the adhesive tape is dispersed in. 片面に粘着テープの長手方向と直交する方向に複数本の凹溝が所定間隔で形成された凹凸面を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層の前記凹凸面に,粘着剤を積層して粘着剤層を形成する共に,前記基材層及び/又は前記粘着剤層に,繊維片を分散させたことを特徴とする粘着テープの製造方法。
The adhesive is laminated on the uneven surface of the base material layer made of an unstretched polyolefin resin film having an uneven surface in which a plurality of concave grooves are formed at predetermined intervals in a direction orthogonal to the longitudinal direction of the adhesive tape on one side. When to form a pressure-sensitive adhesive layer together with the base layer and / or the pressure-sensitive adhesive layer, the production method of the adhesive tape, characterized in that to disperse the fiber pieces.
前記繊維片の分散量を変化させた複数種類の粘着剤を多層に積層して,被着物との接着面側で前記繊維片の分散量が減少する,又は被着物との接着面側で前記繊維片を含まない前記粘着剤層を形成したことを特徴とする請求項11記載の粘着テープの製造方法。 A plurality of types of adhesives having different dispersion amounts of the fiber pieces are laminated in multiple layers to reduce the dispersion amount of the fiber pieces on the adhesive surface side with the adherend, or the adhesive surface side with the adherend. The method for producing an adhesive tape according to claim 11, wherein the pressure-sensitive adhesive layer containing no fiber pieces is formed. 前記繊維片の分散量を変化させた複数種類の粘着剤を多層に積層して,前記基材層の前記凹凸面との接着面側で前記繊維片の分散量が減少する,又は前記基材層の前記凹凸面との接着面側で前記繊維片を含まない前記粘着剤層を形成したことを特徴とする請求項11又は12記載の粘着テープの製造方法。 A plurality of types of pressure-sensitive adhesives in which the dispersion amount of the fiber pieces is changed are laminated in multiple layers to reduce the dispersion amount of the fiber pieces on the adhesive surface side of the base material layer with the uneven surface, or the base material. The method for producing an adhesive tape according to claim 11 or 12, wherein the pressure-sensitive adhesive layer containing no fiber pieces is formed on the adhesive surface side of the layer with the uneven surface.
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