JP2019194279A - Adhesive tape and method for producing adhesive tape - Google Patents

Adhesive tape and method for producing adhesive tape Download PDF

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JP2019194279A
JP2019194279A JP2018088224A JP2018088224A JP2019194279A JP 2019194279 A JP2019194279 A JP 2019194279A JP 2018088224 A JP2018088224 A JP 2018088224A JP 2018088224 A JP2018088224 A JP 2018088224A JP 2019194279 A JP2019194279 A JP 2019194279A
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pressure
sensitive adhesive
adhesive tape
base material
material layer
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JP7011820B2 (en
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尚吉 濱野
Shokichi Hamano
尚吉 濱野
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Kyodo Giken Chemical Co Ltd
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Kyodo Giken Chemical Co Ltd
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Priority to KR1020190048165A priority patent/KR102210182B1/en
Priority to DE102019110753.9A priority patent/DE102019110753B4/en
Priority to CN201910353200.8A priority patent/CN110423565B/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/24Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/241Polyolefin, e.g.rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2477/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/31Applications of adhesives in processes or use of adhesives in the form of films or foils as a masking tape for painting
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/26Presence of textile or fabric
    • C09J2400/263Presence of textile or fabric in the substrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Adhesive Tapes (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

To suppress elongation in a longitudinal direction with good hand tearability, and to prevent positional deviation and peeling after sticking and telescope (bamboo)-shaped deformation when being wound in a roll shape.SOLUTION: An adhesive tape 10 has an adhesive layer 30 formed on an uneven surface 22, in which a plurality of recessed grooves 23 are formed at predetermined intervals in a direction perpendicular to the longitudinal direction on one surface, of a base material layer 20 formed of a non-stretched polyolefin resin film. Due to distribution of a fiber piece 32 containing 0.2-10 pts.wt. of a fiber piece with a length of 1-10 mm and a thickness of 0.05-100 denier with respect to 100 pts.wt. of a solid content of the base material layer or adhesive layer, the adhesive tape has air permeability, increases a mechanical strength, can greatly suppress elongation in a longitudinal direction while maintaining hand tearability, as a result, positional deviation and peeling after sticking and telescope-shaped deformation when being wound in a roll shape are prevented.SELECTED DRAWING: Figure 1

Description

本発明は,粘着テープ(両面粘着テープを含む)及び粘着テープの製造方法に関し,より詳細には,建築内外装,建築塗装,車両塗装等においてマスキングや養生用に使用される粘着テープ,梱包等に使用される粘着テープのように,手切れ性を有することが求められる粘着テープにおいて,手切れ性を維持しつつ,基材層の伸縮防止と引張り強さの向上を図ることで,貼着後の位置ずれ及び剥離,ロール状に巻き取った際のテレスコープ状(竹の子状)の変型を防止し得る粘着テープ及びその製造方法に関する。   The present invention relates to a pressure-sensitive adhesive tape (including a double-sided pressure-sensitive adhesive tape) and a method for producing a pressure-sensitive adhesive tape, and more specifically, a pressure-sensitive adhesive tape used for masking or curing, packaging, etc. in architectural interior / exterior, architectural painting, vehicle painting, etc. For adhesive tapes that are required to have hand-cutting properties, such as those used in coatings, it is possible to prevent the expansion and contraction of the base material layer and improve the tensile strength while maintaining hand-cutting properties. The present invention relates to a pressure-sensitive adhesive tape capable of preventing a later position shift and peeling, and a telescope-like (bamboo shoot-like) deformation when wound into a roll, and a method for producing the same.

前述した建築内外装,建築塗装,車両塗装等においてマスキング及び養生のために使用される粘着テープは,一般に,基材層となるフィルムの片面に粘着剤を塗布した片面テープが使用されている。   As the adhesive tape used for masking and curing in the above-described interior / exterior of buildings, architectural painting, vehicle painting, etc., a single-sided tape in which an adhesive is applied to one side of a film serving as a base material layer is generally used.

このような粘着テープ100は,図8に示すように,粘着剤層130が内側,基材層120が外側となるように巻き芯140等にロール状に巻かれた状態で提供されており,使用時,ユーザーは粘着テープ100をロールから必要な長さを引き出し,被着物に貼着した後,所望の箇所で切断して貼着する。   As shown in FIG. 8, such an adhesive tape 100 is provided in a state of being wound around a winding core 140 or the like so that the adhesive layer 130 is on the inside and the base material layer 120 is on the outside. At the time of use, the user pulls out the required length of the adhesive tape 100 from the roll, attaches it to the adherend, and then cuts and attaches it at a desired location.

このような粘着テープ100の切断に際しては,鋸歯状の刃を持つ専用のカッターの使用又は,はさみあるいはカッターナイフ等の刃物の使用により切断することもできるが,切断する度にこのような刃物等を使用することの煩雑さを回避するために,手でも簡単に切ることができる「手切れ性」を有する粘着テープが要望されている。   The adhesive tape 100 can be cut by using a dedicated cutter having a serrated blade, or by using a blade such as scissors or a cutter knife. In order to avoid the complication of using the adhesive tape, there is a demand for an adhesive tape having “hand cutting ability” that can be easily cut by hand.

このような手切れ性を有する粘着テープとして,和紙,繊維織物(以下「割布」と言う。),及び,切れ目となるエンボスを付けた合成樹脂フィルムを基材層とした粘着テープ等がある。   Examples of such adhesive tapes having a hand cutting property include Japanese paper, fiber woven fabric (hereinafter referred to as “split cloth”), and adhesive tapes using a synthetic resin film with a cut emboss as a base layer. .

特に,粘着テープを手で切る場合,粘着テープの長手方向に対し直交する方向に直線状に切断できることが要望されており,このような要求を満たす粘着テープとしては,基材層を前述した割布によって構成した,所謂「布テープ」が主流で,一部に,粘着テープの長手方向と直交する方向に凹溝を形成して手切れ性を付与したポリオレフィン系樹脂フィルムを基材層としたものが提供されている。   In particular, when the adhesive tape is cut by hand, it is desired that the adhesive tape can be cut linearly in a direction perpendicular to the longitudinal direction of the adhesive tape. The so-called “cloth tape” made of cloth is the mainstream, and a polyolefin resin film with a groove formed in a direction perpendicular to the longitudinal direction of the adhesive tape to provide hand-cutting properties is used as the base layer. Things are offered.

前述の布テープでは,スフ(レーヨン)又は,ポリエステル等の繊維を,経糸と緯糸を異なる太さで織って形成した割布の両面又は片面に,厚さ10〜40μm程度のPEフィルムをラミネートしたものが基材層として使用されている。   In the above-mentioned fabric tape, PE film having a thickness of about 10 to 40 μm is laminated on both sides or one side of a split fabric formed by weaving fibers such as suf (rayon) or polyester with different thicknesses of warp and weft. A thing is used as a base material layer.

このように経糸と緯糸を織ることによって製造される割布を備えた基材層を使用した布テープでは,手で切った場合でも,割布の経糸又は緯糸の長さ方向に直線状に切断することができる。   In the case of a cloth tape using a base material layer with a split cloth manufactured by weaving warp and weft in this way, even when it is cut by hand, it is cut linearly in the length direction of the warp or weft of the split cloth can do.

しかし,このような布テープでは,前述した構造から,基材層を得るためには,予め織っておいた割布を,PEフィルムとラミネートする工程が必要となり,製造工程が多工程となる結果,布テープは高価となる。   However, in such a fabric tape, in order to obtain a base material layer from the above-described structure, a process of laminating a previously woven split cloth with a PE film is required, resulting in a multi-step manufacturing process. , Cloth tape is expensive.

そこで,単層の合成樹脂フィルムを基材層としつつ,手で切った場合であっても,幅方向に直線状に切断することができる工夫がされた粘着テープも提案されている。   In view of this, an adhesive tape has been proposed in which a single layer synthetic resin film is used as a base material layer and can be cut linearly in the width direction even when it is cut by hand.

このような粘着テープ100として,図9に示すように一方の面を平滑面121と成すと共に,他方の面を粘着テープの長手方向と直交する方向に多数の凹溝123が所定間隔で形成された凹凸面122としたポリオレフィン樹脂フィルムを基材層120とし,この基材層120の前記凹凸面122に,粘着剤を塗布して粘着剤層130を形成した粘着テープが提案されている(特許文献1)。   As such an adhesive tape 100, as shown in FIG. 9, one surface is formed with a smooth surface 121, and the other surface is formed with a large number of concave grooves 123 in a direction perpendicular to the longitudinal direction of the adhesive tape. A pressure-sensitive adhesive tape has been proposed in which a polyolefin resin film having an uneven surface 122 is used as a base material layer 120, and an adhesive is applied to the uneven surface 122 of the base material layer 120 to form an adhesive layer 130 (patent). Reference 1).

また,前述したように凹凸面122を備えたポリオレフィン樹脂フィルムを基材層120とした粘着テープ100において,手切れ性を維持しつつ,粘着テープ100の長手方向への伸びを低減させるための構造を備えた粘着テープ100も提案されている。   Further, as described above, in the pressure-sensitive adhesive tape 100 using the polyolefin resin film having the uneven surface 122 as the base material layer 120, a structure for reducing the elongation in the longitudinal direction of the pressure-sensitive adhesive tape 100 while maintaining hand tearability. A pressure-sensitive adhesive tape 100 having the above has also been proposed.

このような粘着テープ100として,図10に示すように,ポリオレフィン樹脂フィルム製基材層120の凹凸面122上に形成する粘着剤層130を,不織布又は割布135と粘着剤131とによって形成することを提案したものがある(特許文献2)。   As such an adhesive tape 100, as shown in FIG. 10, an adhesive layer 130 formed on the uneven surface 122 of the polyolefin resin film substrate layer 120 is formed of a nonwoven fabric or a split cloth 135 and an adhesive 131. There is a thing which proposed this (patent document 2).

また,図11に示すように,ポリオレフィン樹脂フィルム製基材層120の凹凸面122に,数平均分子量が10,000以上でガラス転移温度が0〜80℃であるポリエステル系樹脂136を塗布した後に,アクリル系の粘着剤を塗布して,粘着剤層130を形成した粘着テープも提案されている(特許文献3)。   Further, as shown in FIG. 11, after applying a polyester resin 136 having a number average molecular weight of 10,000 or more and a glass transition temperature of 0 to 80 ° C. on the uneven surface 122 of the polyolefin resin film substrate layer 120. An adhesive tape in which an adhesive layer 130 is formed by applying an acrylic adhesive has also been proposed (Patent Document 3).

特開平3−47885号公報Japanese Patent Laid-Open No. 3-47885 特開平9−137133号公報JP-A-9-137133 実開2001−172586号公報Japanese Utility Model Publication No. 2001-172586

前掲の特許文献1として紹介した粘着テープ100(図9)では,基材層120として使用するポリオレフィン樹脂フィルムの凹凸面122に,粘着テープ100の長手方向と直交する方向に凹溝123が形成されていることから,粘着テープ100を手で切った場合であっても,基材層120が凹溝123に沿って裂けることで,直線状にきれいに切断することができるようになっている。   In the pressure-sensitive adhesive tape 100 (FIG. 9) introduced as the above-mentioned Patent Document 1, a concave groove 123 is formed on the uneven surface 122 of the polyolefin resin film used as the base material layer 120 in a direction perpendicular to the longitudinal direction of the pressure-sensitive adhesive tape 100. Therefore, even when the adhesive tape 100 is cut by hand, the base material layer 120 is torn along the concave groove 123 so that it can be cut cleanly in a straight line.

しかし,特許文献1に記載の粘着テープ100が基材層120として採用するポリオレフィン樹脂フィルムは,無延伸でありそれ自体,紙又は割布等に比較して伸縮性に富んでいるだけでなく,粘着テープ100の長手方向と直交方向に凹溝123が形成されていることで,肉薄となっている凹溝123の形成部分で基材層120は更に伸び易くなっている。   However, the polyolefin resin film employed as the base material layer 120 by the pressure-sensitive adhesive tape 100 described in Patent Document 1 is not stretched and itself is not only rich in elasticity compared to paper or split cloth, Since the concave groove 123 is formed in a direction orthogonal to the longitudinal direction of the adhesive tape 100, the base material layer 120 is further easily extended at the portion where the thin concave groove 123 is formed.

その結果,このような粘着テープ100にあっては,図8に示したようなロール状に巻かれている状態から必要な長さのテープを引き出す際,あるいは手で切断する際に粘着テープ100の基材層120が長手方向に伸びてしまい,このようにして伸びた状態で被着物に貼着されることとなる。   As a result, in such an adhesive tape 100, the adhesive tape 100 is drawn when a tape having a required length is drawn out from the state wound in a roll shape as shown in FIG. The base material layer 120 extends in the longitudinal direction and is attached to the adherend in such a stretched state.

そして,基材層が伸びた状態で貼着された粘着テープ100は,基材層120が元の形状に復帰しようとして縮むことで,経時と共に被着物上の貼着位置にずれが生じ,あるいは,粘着テープ100の端部が浮きあがって剥離してしまう等の問題が生じ,このような粘着テープを塗装の際のマスキングに使用すれば,塗装位置がずれてしまう。   And the adhesive tape 100 stuck with the base material layer stretched causes the base material layer 120 to shrink in an attempt to return to its original shape, resulting in a shift in the sticking position on the adherend over time, or The problem arises that the end of the adhesive tape 100 is lifted and peeled off. If such an adhesive tape is used for masking during painting, the coating position will be shifted.

また,特許文献1に記載の粘着テープ100で基材層120として使用するポリオレフィン樹脂フィルムは,前述したように長手方向に伸びやすく,しかも,基材層に対する粘着剤の塗布時に90〜110℃に加熱して乾燥されることから,その後にロール状に巻き取る際の張力によって,0.3〜1%程度延伸された状態で巻き芯140に巻き取られる。   Moreover, the polyolefin resin film used as the base material layer 120 in the pressure-sensitive adhesive tape 100 described in Patent Document 1 is easily stretched in the longitudinal direction as described above, and at 90 to 110 ° C. when the adhesive is applied to the base material layer. Since it is heated and dried, it is wound around the core 140 in a stretched state by about 0.3 to 1% due to the tension at the time of winding into a roll.

その結果,ロール状に巻き取った後に粘着テープ100が長手方向に収縮することで,粘着テープ100のロールは図12に示すようにテレスコープ状(竹の子状)に変型する不良が生じ易くなっている。   As a result, the adhesive tape 100 shrinks in the longitudinal direction after being wound into a roll shape, so that the roll of the adhesive tape 100 is liable to be deformed into a telescope shape (bamboo child shape) as shown in FIG. Yes.

一方,このようなテレスコープ状(竹の子状)の変形を防止するために粘着テープ100を低張力で巻き取ると,空気の巻き込みにより巻き巣(空洞)が生じ易くなり,何れも外観不良となって製品としては出荷できず,このようにして生じる不良率は,最大で約1〜7%に及ぶために歩留りが悪い。   On the other hand, if the adhesive tape 100 is wound at a low tension in order to prevent such a telescope-like (bamboo shoot-like) deformation, a nest (cavity) is likely to occur due to air entrainment, and both of them have poor appearance. The product cannot be shipped, and the defective rate generated in this way reaches about 1 to 7% at the maximum, so the yield is poor.

さらに,マスキング又は養生用に使用される粘着テープでは,塗装等の作業が完了した後は,これを被着物より剥離・除去することが必要となるが,手切れ性を付与するために長手方向と直交する方向に前述した凹溝123が形成されたポリオレフィン樹脂フィルムを基材層120とした前述の粘着テープ100は,被着物から剥離する作業中にも伸びやすく,かつ,切れやすいことから,剥離作業が煩雑となる。   In addition, with adhesive tapes used for masking or curing, it is necessary to remove and remove this from the adherend after the work such as painting has been completed. The above-mentioned adhesive tape 100 using the polyolefin resin film in which the above-mentioned concave groove 123 is formed in a direction orthogonal to the base material layer 120 is easy to stretch during work of peeling from the adherend, and is easy to cut. The peeling work becomes complicated.

このように,片面に凹溝123が形成されたポリオレフィン樹脂フィルムを基材層120とした特許文献1に記載の粘着テープ100では,長手方向に伸び易く,その結果,前述した各種の問題が生じることから,このような粘着テープ100の長手方向の伸びを抑制することが要望されている。   Thus, in the adhesive tape 100 of patent document 1 which used the polyolefin resin film in which the concave groove 123 was formed in the single side | surface as the base material layer 120, it is easy to extend in a longitudinal direction, As a result, the various problems mentioned above arise. Therefore, it is desired to suppress such elongation in the longitudinal direction of the adhesive tape 100.

このような伸びを抑制する方法としては,凹溝123の深さを浅くすることあるいは,基材層120とするポリオレフィン樹脂フィルム全体を厚くすることも考えられるが,この構成では,粘着テープ100の長手方向の伸びを抑制することはできるものの,粘着テープ100の手切れ性が低下してしまい,特にポリオレフィン樹脂フィルム全体の厚みを厚くする構成では,被着物の表面に対する追従性が低下することで剥離等が生じ易くなる。   As a method for suppressing such elongation, it is conceivable to reduce the depth of the concave groove 123 or to increase the thickness of the entire polyolefin resin film as the base material layer 120. Although the elongation in the longitudinal direction can be suppressed, the hand cutting property of the pressure-sensitive adhesive tape 100 is lowered, and particularly in the configuration in which the thickness of the entire polyolefin resin film is increased, the followability to the surface of the adherend is lowered. Peeling is likely to occur.

これに対し,前掲の特許文献2に記載されている粘着テープ(図10)では,粘着剤層130に不織布又は割布135を埋設して粘着剤層130を強化することにより,粘着テープ100の長手方向における伸びの発生を抑制している。   On the other hand, in the pressure-sensitive adhesive tape described in the above-mentioned Patent Document 2 (FIG. 10), the non-woven fabric or the split cloth 135 is embedded in the pressure-sensitive adhesive layer 130 to reinforce the pressure-sensitive adhesive layer 130. Occurrence of elongation in the longitudinal direction is suppressed.

しかし,この構成では,不織布又は割布135と粘着剤131を一体化させて粘着剤層130を形成する作業が必要で,図13に示すように,不織布又は割布135と粘着剤131を工程紙150上にラミネートするなどして粘着剤層130を形成した後,基材層120となるポリオレフィン樹脂フィルムに積層する等の作業が必要となることから,前述した布テープの場合と同様,製造時の工程数が増えて製造コストが嵩む結果,粘着テープ100が高価なものとなる。   However, in this configuration, an operation of forming the adhesive layer 130 by integrating the nonwoven fabric or the split cloth 135 and the adhesive 131 is necessary, and as shown in FIG. Since the pressure-sensitive adhesive layer 130 is formed by laminating on the paper 150 and the like, it is necessary to perform the operation such as laminating on the polyolefin resin film to be the base material layer 120. As a result of an increase in the number of processes at the time and an increase in manufacturing cost, the pressure-sensitive adhesive tape 100 becomes expensive.

しかも,粘着剤層130に不織布又は割布135を埋没させた構造では,伸びを抑制することはできるものの,手切れ性が大幅に低下する。   Moreover, in the structure in which the nonwoven fabric or the split cloth 135 is embedded in the pressure-sensitive adhesive layer 130, the stretchability can be suppressed, but the hand cutting property is greatly reduced.

しかも,不織布又は割布135の埋没によって粘着剤層130の変形性が大幅に低下することから,被着部の表面に対する追従性が低下し,剥離又は浮きが生じ易く,マスキングテープとしての機能が損なわれる可能性もある。   Moreover, since the deformability of the pressure-sensitive adhesive layer 130 is greatly reduced by burying the non-woven fabric or the split cloth 135, the followability to the surface of the adherend is reduced, peeling or floating is likely to occur, and the function as a masking tape is achieved. There is also the possibility of damage.

更に,図11に示したようにポリオレフィン樹脂フィルム製の基材層120に設けた凹凸面122に,粘着剤を塗布する前にポリエステル系樹脂136を塗布した前掲の特許文献3に記載の構成では,伸びは抑制できるかもしれないが,手切れ性は大幅に低下するか,または殆ど失われてしまうと考えられる。   Furthermore, as shown in FIG. 11, in the structure described in the above-mentioned Patent Document 3, the polyester resin 136 is applied to the uneven surface 122 provided on the base layer 120 made of a polyolefin resin film before the adhesive is applied. , Elongation may be able to be suppressed, but it is considered that the hand cutting property is greatly reduced or almost lost.

また,下地層としてポリエステル系樹脂136を塗布した後に,これに続けて溶剤型の粘着剤を塗布して粘着剤層130を形成すると,下地のポリエステル系樹脂136が粘着剤131内の溶剤に侵され,異常を生じる,所謂「ソルベントアタック」によりポリエステル系樹脂136が軟化してしまい,伸びの抑制効果が得られなくなることから,製造方法あるいは材質等についても制約を受けるものと考えられる。   In addition, after the polyester resin 136 is applied as a base layer, a solvent-type adhesive is subsequently applied to form the adhesive layer 130, so that the base polyester resin 136 is affected by the solvent in the adhesive 131. The polyester resin 136 is softened by a so-called “solvent attack” that causes an abnormality, and the effect of suppressing elongation cannot be obtained. Therefore, it is considered that the manufacturing method or the material is also restricted.

また,特許文献1〜3に記載の粘着テープは,基材にポリオリフェン系のプラスチックを使用しており,通気性が不十分であるため,貼着時に被着の表面と粘着テープ100間にエアーを抱き込み易く,見た目の美しさに欠けると共に,抱き込まれたエアーの膨張や,被着物からのアウトガス,基材の熱膨張などが複合し,粘着テープ100の膨れや剥離の要因となり易い問題が有った。   In addition, the pressure-sensitive adhesive tapes described in Patent Documents 1 to 3 use a polyolefin resin as a base material and have insufficient air permeability. Easily embraced with air, lacking in beauty, and combined with the expansion of entrapped air, outgas from the adherend, and thermal expansion of the substrate, easily causing swelling and peeling of the adhesive tape 100 There was a problem.

そこで本発明は,上記従来技術における欠点を解消するためになされたものであり,前述したように一方の面を平滑面に,他方の面を凹凸面に形成したポリオレフィン樹脂フィルムを基材層とし,該基材層の凹凸面に粘着剤層を形成した粘着テープにおいて,該粘着テープの幅方向の手切れ性を維持しつつ,長手方向の伸びの抑制,具体的には伸びを70%以下,好ましくは50%以下,より好ましくは30%以下に抑制するとともに,引張強度が向上,具体的には100 (N/50mm幅)以上,好ましくは130(N/50mm幅)以上に向上された粘着テープを提供することにより,貼着後の位置ずれ又は剥離を防止すると共に,ロール状に巻かれた粘着テープが図12に示すようなテレスコープ状(竹の子状)に変形することを防止でき,かつ,塗装作業等の終了後,被着物より剥離する際の作業性が良好で,さらに,通気性を有する粘着テープ(両面粘着テープを含む)及び粘着テープの製造方法を提供することを目的とする。   Accordingly, the present invention has been made to eliminate the above-mentioned drawbacks of the prior art, and as described above, a polyolefin resin film in which one surface is a smooth surface and the other surface is an uneven surface is used as a base material layer. In the pressure-sensitive adhesive tape in which the pressure-sensitive adhesive layer is formed on the uneven surface of the base material layer, the elongation in the longitudinal direction is suppressed, specifically, the elongation is 70% or less while maintaining the hand-cut property in the width direction of the pressure-sensitive adhesive tape. , Preferably 50% or less, more preferably 30% or less, and improved tensile strength, specifically 100 (N / 50mm width) or more, preferably 130 (N / 50mm width) or more By providing an adhesive tape, it is possible to prevent displacement and peeling after sticking, and it is possible to prevent the adhesive tape wound in a roll shape from being deformed into a telescope shape (bamboo child shape) as shown in FIG. And painting work After completion etc., a good workability during peeling from an adherend, further an object to provide an adhesive tape (including a double-sided adhesive tape) and the adhesive tape manufacturing method of having air permeability.

以下に,課題を解決するための手段を,発明を実施するための形態で使用する符号と共に記載する。この符号は,特許請求の範囲の記載と発明を実施するための形態の記載との対応を明らかにするために記載したものであり,言うまでもなく,本願発明の技術的範囲の解釈に制限的に用いられるものではない。   Hereinafter, means for solving the problem will be described together with reference numerals used in the embodiment for carrying out the invention. This code is used to clarify the correspondence between the description of the scope of claims and the description of the mode for carrying out the invention. Needless to say, this code is limited to the interpretation of the technical scope of the present invention. Not used.

上記目的を達成するために,本発明の粘着テープ10は,
片面に粘着テープの長手方向と直交する方向に複数本の凹溝23が所定間隔で形成された凹凸面22を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層20と,前記基材層20の前記凹凸面22上に形成された粘着剤層30を備え,前記基材層20及び前記粘着剤層30に繊維片32が分散され,通気性を有していることを特徴とする(請求項1,図1参照)。
In order to achieve the above object, the pressure-sensitive adhesive tape 10 of the present invention comprises:
A base material layer 20 made of an unstretched polyolefin resin film having a concavo-convex surface 22 having a plurality of concave grooves 23 formed at predetermined intervals in a direction orthogonal to the longitudinal direction of the adhesive tape on one side; The pressure-sensitive adhesive layer 30 is formed on the concavo-convex surface 22, and the fiber pieces 32 are dispersed in the base material layer 20 and the pressure-sensitive adhesive layer 30, thereby having air permeability (invention). Item 1, see FIG.

また,本発明の粘着テープ10は,前記粘着剤層30,30’を前記基材層20の両面に形成し,前記基材層20及び前記粘着剤層30,30’に繊維片32が分散され,通気性を有した両面粘着テープ10’としてもよい(請求項2,図2参照)。   In the pressure-sensitive adhesive tape 10 of the present invention, the pressure-sensitive adhesive layers 30 and 30 ′ are formed on both surfaces of the base material layer 20, and the fiber pieces 32 are dispersed in the base material layer 20 and the pressure-sensitive adhesive layers 30 and 30 ′. Alternatively, a double-sided pressure-sensitive adhesive tape 10 ′ having air permeability may be used (see claim 2 and FIG. 2).

さらに,前記両面粘着テープ10’は,前記基材層20が,両面に前記凹凸面22,22’を有するものとしても良い。(請求項3,図3参照)。   Further, in the double-sided pressure-sensitive adhesive tape 10 ′, the base material layer 20 may have the uneven surfaces 22 and 22 ′ on both surfaces. (See claim 3, FIG. 3).

なお,本発明において『繊維片』には,短繊維の単体又は,短繊維又は長繊維の断片等から成るモノフィラメントの他,モノフィラメントを撚り合わせて得たマルチフィラメント(糸)の断片を含む。   In the present invention, the “fiber piece” includes a single filament of a short fiber, a monofilament made of a short fiber or a fragment of long fiber, and a multifilament (yarn) fragment obtained by twisting monofilaments.

前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)が,粘着剤31の固形分100重量部に対し,前記繊維片32を0.5〜10重量部,好ましくは1〜5重量部含有することを特徴とする(請求項4,図1)。   The pressure-sensitive adhesive layer 30 (in the case of the double-sided pressure-sensitive adhesive tape 10 ′, the pressure-sensitive adhesive layers 30, 30 ′) is 0.5 to 10 parts by weight of the fiber pieces 32, preferably 100 parts by weight of the solid content of the pressure-sensitive adhesive 31 Contains 1 to 5 parts by weight (claim 4, FIG. 1).

前記繊維片32としては,繊維径が0.05〜100デニール(0.01〜200μm径),好ましくは1〜10デニール(15〜60μm)より好ましくは0.5〜4デニール(3〜40μm)のものを使用することができる(請求項5)。   The fiber pieces 32 have a fiber diameter of 0.05 to 100 denier (0.01 to 200 μm diameter), preferably 1 to 10 denier (15 to 60 μm), more preferably 0.5 to 4 denier (3 to 40 μm). Can be used (Claim 5).

なお,「デニール」とは,9000mの糸の質量をグラム単位で表したものであり,上記「デニール」の1/9の値が,JIS及びISOで使用する「テックス」(1000mの糸の質量をグラム単位で表したもの)に対応する。   “Denier” is the mass of a 9000 m yarn expressed in grams. The value of 1/9 of the above “denier” is the “tex” used in JIS and ISO (1000 m yarn mass). In gram)).

また,前記繊維片32の長さは,1〜10mm,好ましくは1〜7mm,より好ましくは2〜5mmのものが使用可能である(請求項6)。   The length of the fiber piece 32 may be 1 to 10 mm, preferably 1 to 7 mm, more preferably 2 to 5 mm (Claim 6).

なお,前記繊維径及び繊維長は,各種のものを混合して用いることができる。   In addition, the said fiber diameter and fiber length can mix and use various things.

更に,前記基材層が,前記基材層固形分100重量部に対し,前記繊維片を0.2〜10重量部,好ましくは0.5〜3重量部含有することを特徴とする(請求項7,図1)。   Furthermore, the base material layer contains 0.2 to 10 parts by weight, preferably 0.5 to 3 parts by weight of the fiber pieces with respect to 100 parts by weight of the solid content of the base material layer. Item 7, FIG. 1).

上記本発明の粘着テープ10及び両面粘着テープ10’は,粘着テープの長手方向の伸びを30%以下,好ましくは20%以下,より好ましくは16%以下とする(請求項8)。   The pressure-sensitive adhesive tape 10 and the double-sided pressure-sensitive adhesive tape 10 ′ of the present invention have an elongation in the longitudinal direction of the pressure-sensitive adhesive tape of 30% or less, preferably 20% or less, more preferably 16% or less.

また,粘着テープの長手方向の引張強さが100(N/50mm幅)以上であることが好ましい(請求項9)。   Moreover, it is preferable that the tensile strength of the longitudinal direction of an adhesive tape is 100 (N / 50mm width) or more.

本発明の粘着テープ10の前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)は,厚み方向の全体に亘り繊維片32が均一に分散されたものとしても良いが(図1参照),好ましくは,被着物に対する貼着側(紙面下側)において前記繊維片32の分散量が減少する構成とすることが好ましい(請求項10,図4及び5参照,両面粘着テープ10’については図示せず。)。   The pressure-sensitive adhesive layer 30 of the pressure-sensitive adhesive tape 10 of the present invention (in the case of the double-sided pressure-sensitive adhesive tape 10 ′, the pressure-sensitive adhesive layers 30 and 30 ′) may have the fiber pieces 32 uniformly dispersed throughout the thickness direction. (Refer to FIG. 1), preferably, the dispersion amount of the fiber pieces 32 is preferably reduced on the sticking side (lower side of the paper) to the adherend (see claim 10, FIG. 4 and FIG. 5, double-sided). The adhesive tape 10 'is not shown.)

更に,前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)は,基材層20との貼着側(図面上側)において前記繊維片32の分散量が減少する構成とすることが好ましい(請求項11,図5参照,両面粘着テープ10’については図示せず。)。   Furthermore, in the pressure-sensitive adhesive layer 30 (in the case of the double-sided pressure-sensitive adhesive tape 10 ′, the pressure-sensitive adhesive layers 30 and 30 ′), the dispersion amount of the fiber pieces 32 is reduced on the sticking side (upper side in the drawing) with the base material layer 20. It is preferable to have a configuration (see claim 11, FIG. 5, double-sided adhesive tape 10 ′ is not shown).

なお,基材層20及び粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)に分散させる前記繊維片32としては,アクリル系,PET,オレフィン系樹脂,レーヨン,ビニロン,ナイロンの群から選択されたいずれかの材質から成るものを使用でき,該繊維片32の一種を,又は二種以上を混合したものを,前記粘着剤層30に分散させるものとしても良い(請求項12)。   The fiber pieces 32 dispersed in the base material layer 20 and the pressure-sensitive adhesive layer 30 (the pressure-sensitive adhesive layers 30 and 30 ′ in the case of the double-sided pressure-sensitive adhesive tape 10 ′) include acrylic, PET, olefinic resin, rayon, and vinylon. A material made of any material selected from the group of nylon can be used, and one or a mixture of two or more of the fiber pieces 32 may be dispersed in the pressure-sensitive adhesive layer 30 ( Claim 12).

前記繊維片32が,中空繊維片であることが好ましい(請求項13)。   It is preferable that the fiber piece 32 is a hollow fiber piece.

前記繊維片32が,粘着テープの長手方向に沿って層状に分散されたものとしても良い(請求項14,図6参照)。   The fiber pieces 32 may be dispersed in layers along the longitudinal direction of the adhesive tape (see claim 14 and FIG. 6).

また,本発明の粘着テープ10の製造方法は,
片面に粘着テープの長手方向と直交する方向に複数本の凹溝23が所定間隔で形成された凹凸面22を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層20の前記凹凸面22に,粘着剤を積層して粘着剤層30を形成すると共に,前記基材層20及び前記粘着剤層30に,繊維片32を分散させたことを特徴とする(請求項15)。
Moreover, the manufacturing method of the adhesive tape 10 of this invention is as follows.
On the concavo-convex surface 22 of the base layer 20 made of an unstretched polyolefin resin film having a concavo-convex surface 22 having a plurality of concave grooves 23 formed at predetermined intervals in a direction orthogonal to the longitudinal direction of the adhesive tape on one side, The pressure-sensitive adhesive is laminated to form the pressure-sensitive adhesive layer 30, and fiber pieces 32 are dispersed in the base material layer 20 and the pressure-sensitive adhesive layer 30 (claim 15).

また,前記基材層20の両面に,粘着剤を積層して粘着剤層30,30’を形成すると共に,前記基材層20及び前記粘着剤層30,30’に,繊維片32を分散させても良い(請求項16)。   In addition, pressure-sensitive adhesive is laminated on both surfaces of the base material layer 20 to form pressure-sensitive adhesive layers 30 and 30 ′, and fiber pieces 32 are dispersed in the base material layer 20 and the pressure-sensitive adhesive layers 30 and 30 ′. (Claim 16).

さらに,前記基材層20が両面に粘着テープの長手方向と直交する方向に複数本の凹溝23が所定間隔で形成された凹凸面22を有する未延伸のポリオレフィン樹脂製フィルムから成るものでも良い(請求項17)。   Furthermore, the base material layer 20 may be made of an unstretched polyolefin resin film having a concavo-convex surface 22 in which a plurality of concave grooves 23 are formed at predetermined intervals in a direction orthogonal to the longitudinal direction of the adhesive tape on both surfaces. (Claim 17).

前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)の形成は,前記繊維片32の分散量を変化させた複数種類の粘着剤を多層に積層することにより,被着物との接着面側で前記繊維片32の分散量が減少する前記粘着剤層30を形成するものとしても良い(請求項18,図4及び図5参照,両面粘着テープ10’については図示せず。)。   Formation of the pressure-sensitive adhesive layer 30 (in the case of the double-sided pressure-sensitive adhesive tape 10 ′, pressure-sensitive adhesive layers 30, 30 ′) is performed by laminating a plurality of types of pressure-sensitive adhesives in which the dispersion amount of the fiber pieces 32 is changed in multiple layers. It is good also as what forms the said adhesive layer 30 in which the dispersion amount of the said fiber piece 32 reduces by the adhesion surface side with a to-be-adhered body (refer Claim 18, FIG.4 and FIG.5, about double-sided adhesive tape 10 ') Not shown.)

また,同様に繊維片32の分散量を変化させた複数種類の粘着剤を多層に積層して,前記基材層20の前記凹凸面22との接着面側で前記繊維片32の分散量が減少する前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)を形成するものとしても良い(請求項19,図5参照,両面粘着テープ10’については図示せず。)。   Similarly, a plurality of types of pressure-sensitive adhesives in which the dispersion amount of the fiber pieces 32 is changed are laminated in multiple layers, and the dispersion amount of the fiber pieces 32 is increased on the adhesive surface side of the base material layer 20 with the uneven surface 22. The decreasing pressure-sensitive adhesive layer 30 (in the case of double-sided pressure-sensitive adhesive tape 10 ', pressure-sensitive adhesive layers 30, 30') may be formed (see claim 19, FIG. 5, double-sided pressure-sensitive adhesive tape 10 'not shown). .)

以上で説明した本発明の構成により,本発明の粘着テープ10(両面粘着テープ10’を含む)では,以下の顕著な効果を得ることかできた。   With the configuration of the present invention described above, the following remarkable effects could be obtained with the pressure-sensitive adhesive tape 10 (including the double-sided pressure-sensitive adhesive tape 10 ') of the present invention.

上述の構成を有する本発明の粘着テープ10(及び両面粘着テープ10’)は,幅方向の手切れ性を維持しつつ,長手方向の伸びを小さくし,さらに,通気性を有することができた。   The pressure-sensitive adhesive tape 10 (and the double-sided pressure-sensitive adhesive tape 10 ') having the above-described configuration can reduce the elongation in the longitudinal direction while maintaining the hand-cut property in the width direction, and further has air permeability. .

このような繊維片の分散による伸びの抑制は,繊維の分散によって前記基材層及び前記粘着剤層が高架橋となったかのような挙動を示す(本明細書においてこのような挙動を示す状態を「疑似架橋状態」という)ことで,物理的に伸びが抑制されるものであり,化学的な架橋と比べて,粘着力に寄与する官能基等を塞ぐことがなく,粘着力の発現を低下させることがない点で有利である。   Such suppression of elongation due to the dispersion of the fiber pieces exhibits a behavior as if the base material layer and the pressure-sensitive adhesive layer were highly crosslinked by the dispersion of the fibers (in this specification, the state indicating such a behavior is referred to as “ It is called “pseudo-crosslinked state”, and the physical elongation is suppressed. Compared with chemical cross-linking, it does not block functional groups that contribute to adhesive strength and reduces the expression of adhesive strength. This is advantageous in that it does not occur.

このように,本発明の粘着テープ10(及び両面粘着テープ10’)は,長手方向の伸びを小さくできたことで,ロール状に巻かれた状態から引き出す際に伸び難く,伸びた状態で貼着された粘着テープが縮むことで生じる貼着位置のずれ,端部の浮き上がりによる剥離の発生を防止でき,また,巻き巣の発生を防止するためにテンションを掛けて巻き取った場合であっても伸びが生じ難いことから,ロール状に巻き取られた後に粘着テープ10(及び,両面粘着テープ10’)が縮むことで生じるテレスコープ状(竹の子状)の変形についても好適に防止することができ,これにより不良品の発生を抑制して歩留りを向上させることができた。   Thus, the pressure-sensitive adhesive tape 10 (and the double-sided pressure-sensitive adhesive tape 10 ') of the present invention has been able to reduce the elongation in the longitudinal direction, so that it is difficult to stretch when pulled out from the rolled state, and is stuck in the stretched state. It is possible to prevent the occurrence of peeling due to the sticking position shift caused by shrinking of the attached adhesive tape and the lifting of the end, and also when winding with tension to prevent the formation of a winding nest. Since it is difficult to cause elongation, it is possible to suitably prevent a telescope-like (bamboo-child-like) deformation caused by shrinkage of the adhesive tape 10 (and the double-sided adhesive tape 10 ′) after being wound into a roll. As a result, the yield was improved by suppressing the occurrence of defective products.

また,粘着テープ10(及び,両面粘着テープ10’)の長手方向における引張り強度を向上させることができたことから,例えば塗装等の作業が終了した後,マスキングテープとして使用していた粘着テープ10(及び,両面粘着テープ10’)を被着物から剥離・除去する際に,粘着テープを破断等させることなく容易に剥離・除去することが可能である。   In addition, since the tensile strength in the longitudinal direction of the adhesive tape 10 (and the double-sided adhesive tape 10 ′) can be improved, the adhesive tape 10 used as a masking tape after the work such as painting is completed, for example. When peeling (and removing) the double-sided pressure-sensitive adhesive tape 10 'from the adherend, the pressure-sensitive adhesive tape can be easily peeled and removed without breaking the pressure-sensitive adhesive tape.

また,本発明の粘着テープ10(及び両面粘着テープ10’)は,通気性を有することから,貼着時に発生するエアーの抱き込みを防止することができ,貼着後の見た目が綺麗であるだけでなく被着物のアウトガスや抱き込んだエアーの膨張等による剥離の問題も生じない粘着テープ10(及び両面粘着テープ10’)を提供することができた。   In addition, since the pressure-sensitive adhesive tape 10 (and the double-sided pressure-sensitive adhesive tape 10 ') of the present invention has air permeability, it can prevent air entrainment generated at the time of sticking and has a beautiful appearance after sticking. In addition, the adhesive tape 10 (and the double-sided adhesive tape 10 ′) that does not cause the problem of peeling due to the outgassing of the adherend and the expansion of the air embraced can be provided.

本発明の粘着テープ10(及び両面粘着テープ10’)の通気性については,例えば,基材層及び粘着剤層を構成する樹脂と分散された繊維片32との間に生じた僅かな隙間又は,繊維片が有する孔等に沿って空気が抜けていくことが推察される。   Regarding the air permeability of the pressure-sensitive adhesive tape 10 (and the double-sided pressure-sensitive adhesive tape 10 ') of the present invention, for example, a slight gap generated between the resin constituting the base material layer and the pressure-sensitive adhesive layer and the dispersed fiber pieces 32 or , It is assumed that air escapes along the holes and the like of the fiber pieces.

また,特に,繊維片32の添加量を粘着剤31の固形分100重量部に対し,0.5〜10重量部,好ましくは1〜5重量部又は,前記基材層固形分100重量部に対し,前記繊維片を0.2〜10重量部含有するのみでよいという,比較的少量であり,また,分散させる繊維片32として0.05〜100デニールという比較的細径のものを使用することで,粘着テープ10(及び両面粘着テープ10’)の手切れ性を殆ど犠牲にすることなく,粘着テープ10(及び両面粘着テープ10’)の伸びの抑制と引張り強度の向上を得ることができた。   In particular, the addition amount of the fiber pieces 32 is 0.5 to 10 parts by weight, preferably 1 to 5 parts by weight, or 100 parts by weight of the base layer solids with respect to 100 parts by weight of the solid content of the pressure-sensitive adhesive 31. On the other hand, a relatively small amount that only contains 0.2 to 10 parts by weight of the fiber piece is used, and a fiber piece 32 having a relatively small diameter of 0.05 to 100 denier is used as the fiber piece 32 to be dispersed. Thus, the elongation of the adhesive tape 10 (and the double-sided adhesive tape 10 ′) can be suppressed and the tensile strength can be improved without sacrificing the hand cutting property of the adhesive tape 10 (and the double-sided adhesive tape 10 ′). did it.

粘着剤31に添加する繊維片32を,1〜10mm,好ましくは1〜7mm,より好ましくは2〜5mmという比較的短いものを使用したことで,粘着剤に対する繊維片32の分散が容易である一方,この長さの繊維片の分散でも必要な伸び率の抑制と引張強さの向上を得ることができた。   The fiber pieces 32 to be added to the adhesive 31 have a relatively short length of 1 to 10 mm, preferably 1 to 7 mm, more preferably 2 to 5 mm. On the other hand, even when the fiber pieces having this length are dispersed, the required elongation rate can be suppressed and the tensile strength can be improved.

前記基材層20の凹凸面22に,前記粘着テープ10の長手方向と平行な方向に複数本の凹溝(図示せず)を所定間隔で形成した構成では,粘着テープ10の幅方向の手切れ性のみならず,長手方向の手切れ性についても付与することができた。   In a configuration in which a plurality of concave grooves (not shown) are formed on the uneven surface 22 of the base material layer 20 at a predetermined interval in a direction parallel to the longitudinal direction of the adhesive tape 10, Not only the cutting ability but also the longitudinal cutting ability could be given.

前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)中の前記繊維片32の分散量を,被着物との接着面側で減少させた構成とした例では,繊維片32の分散によっても被着物に対する良好な接着性を維持することができた。   In the example in which the amount of dispersion of the fiber pieces 32 in the pressure-sensitive adhesive layer 30 (in the case of the double-sided pressure-sensitive adhesive tape 10 ′, the pressure-sensitive adhesive layer 30, 30 ′) is reduced on the adhesion surface side with the adherend, Good adhesion to the adherend could also be maintained by the dispersion of the fiber pieces 32.

また,粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)中の前記繊維片32の分散量を,基材層20の凹凸面22との接着面側でも減少させた構成とした例では,基材層20の凹凸面22と粘着剤層30間の強固な接着を得ることができ,被着物より粘着テープ10を剥がす際に,層間剥離が生じて粘着剤層30の一部が被着物の表面に付着したまま残る,所謂「糊残り」の発生についても好適に防止することができた。   Further, the dispersion amount of the fiber pieces 32 in the pressure-sensitive adhesive layer 30 (in the case of the double-sided pressure-sensitive adhesive tape 10 ′, the pressure-sensitive adhesive layer 30, 30 ′) is also reduced on the adhesive surface side of the base material layer 20 with the uneven surface 22. In the example having the above configuration, strong adhesion between the uneven surface 22 of the base material layer 20 and the pressure-sensitive adhesive layer 30 can be obtained, and when the pressure-sensitive adhesive tape 10 is peeled off from the adherend, delamination occurs and the pressure-sensitive adhesive layer Occurrence of the so-called “glue residue” in which a part of 30 remains attached to the surface of the adherend can be suitably prevented.

さらに,従来の基材層としての工程が多く,コストの高い繊維を縦横(経緯)に織る事なく,既存の織物型テープの代替ともなる粘着テープが得られ,高い経済効果をもたらす。   In addition, there are many processes as a conventional base material layer, and an adhesive tape that can be used as an alternative to an existing woven tape can be obtained without weaving high-cost fibers in length and breadth (background), resulting in high economic effects.

なお,上記課題を解決するため基材層として過去に試みられたポリプロピレンとポリエチレンの混合樹脂においては,融点の違いから,押し出しフィルムに発生するたわみ,巻取りのしわ,ラインでのしわ(アバラ,フレアとも呼ばれる)が多発していたが,ポリプロピレンに代替する本願の繊維片により,上記効果を達成すると共に,このようなしわの発生をきわめて少ないものとすることができた。   In addition, in the mixed resin of polypropylene and polyethylene that has been tried in the past as a base material layer in order to solve the above problems, due to the difference in melting point, the deflection generated in the extruded film, the wrinkle of winding, the wrinkle in the line (Abara, The flakes of the present application substituting for polypropylene were able to achieve the above-mentioned effect and extremely reduce the occurrence of such wrinkles.

本発明の第1実施形態の粘着テープ10の断面模式図。The cross-sectional schematic diagram of the adhesive tape 10 of 1st Embodiment of this invention. 本発明の第2実施形態の両面粘着テープ10’の断面模式図。The cross-sectional schematic diagram of the double-sided adhesive tape 10 'of 2nd Embodiment of this invention. 本発明の第3実施形態の両面粘着テープ10’の断面模式図。The cross-sectional schematic diagram of the double-sided adhesive tape 10 'of 3rd Embodiment of this invention. 本発明のさらに別の実施形態の粘着テープ10の断面模式図。The cross-sectional schematic diagram of the adhesive tape 10 of another embodiment of this invention. 本発明のさらに別の実施形態の粘着テープ10の断面模式図。The cross-sectional schematic diagram of the adhesive tape 10 of another embodiment of this invention. 本発明のさらに別の実施形態の粘着テープ10の断面模式図。The cross-sectional schematic diagram of the adhesive tape 10 of another embodiment of this invention. 基材層となるポリオレフィン樹脂フィルムの製造方法の説明図。Explanatory drawing of the manufacturing method of the polyolefin resin film used as a base material layer. ロール状に巻き取った状態の粘着テープの斜視図。The perspective view of the adhesive tape of the state wound up in roll shape. 従来の粘着テープの説明図(特許文献1に対応)。Explanatory drawing of the conventional adhesive tape (corresponding to patent document 1). 従来の粘着テープの説明図(特許文献2に対応)。Explanatory drawing of the conventional adhesive tape (corresponding to patent document 2). 従来の粘着テープの説明図(特許文献3に対応)。Explanatory drawing of the conventional adhesive tape (corresponding to patent document 3). テレスコープ状(竹の子状)に変形した粘着テープの説明図。Explanatory drawing of the adhesive tape deform | transformed into the telescope shape (bamboo child shape). 従来の粘着テープの製造方法の説明図(特許文献2の図3に対応)。Explanatory drawing of the manufacturing method of the conventional adhesive tape (corresponding to FIG. 3 of patent document 2).

次に,本発明の実施形態につき添付図面を参照しながら説明する。   Next, embodiments of the present invention will be described with reference to the accompanying drawings.

〔全体構造〕
本発明の第1実施形態としては,例えば,図1に示すように一方の面を平滑面21とし,他方の面に粘着テープの長手方向と直交する方向の多数の凹溝23が形成された凹凸面22としたポリオレフィン樹脂フィルムを基材層20とし,この基材層20の凹凸面22に,粘着剤層30を設けた,手切れ性を有する粘着テープ10とすることができる。
[Overall structure]
In the first embodiment of the present invention, for example, as shown in FIG. 1, one surface is a smooth surface 21, and the other surface is formed with a number of concave grooves 23 in a direction perpendicular to the longitudinal direction of the adhesive tape. The polyolefin resin film having the concavo-convex surface 22 can be used as the base material layer 20, and the adhesive tape 30 having the adhesive layer 30 can be provided on the concavo-convex surface 22 of the base material layer 20.

そして,本発明の粘着テープ10は,前述の基材層20及び粘着剤層30に繊維片32を分散させることにより,手切れ性を維持しつつ粘着テープ10の長手方向の伸びの抑制と,引張強さを向上させ,さらに,通気性を持たせた,一例として総厚み120〜600μmの粘着テープである。なお,総厚みはこれに限定されず,用途等に応じて適宜の厚さに設定し得る。   And the pressure-sensitive adhesive tape 10 of the present invention, by dispersing the fiber pieces 32 in the base material layer 20 and the pressure-sensitive adhesive layer 30 described above, suppressing the elongation in the longitudinal direction of the pressure-sensitive adhesive tape 10 while maintaining the hand cutting property, As an example, an adhesive tape having a total thickness of 120 to 600 μm, which has improved tensile strength and air permeability. In addition, total thickness is not limited to this, It can set to appropriate thickness according to a use etc.

また,本発明の第2実施形態として,例えば,図2に示すように,一方の面を平滑面21とし,他方の面に粘着テープの長手方向と直交する方向の多数の凹溝23が形成された凹凸面22としたポリオレフィン樹脂フィルムを基材層20とし,この基材層20の両面に,粘着剤層30,30’を設け,前記基材層20及び前記粘着剤層30,30’の粘着剤中に繊維片32が分散された,通気性及び手切れ性を有する両面粘着テープ10’とすることができる。   Further, as a second embodiment of the present invention, for example, as shown in FIG. 2, one surface is a smooth surface 21, and the other surface is formed with a number of concave grooves 23 in a direction perpendicular to the longitudinal direction of the adhesive tape. The polyolefin resin film having the uneven surface 22 is used as a base material layer 20, and adhesive layers 30 and 30 ′ are provided on both surfaces of the base material layer 20, and the base material layer 20 and the adhesive layers 30 and 30 ′ are provided. A double-sided pressure-sensitive adhesive tape 10 ′ having air permeability and hand cutting properties in which the fiber pieces 32 are dispersed in the pressure-sensitive adhesive can be obtained.

さらに,本発明の第3実施形態として,図3に示すように,両面を粘着テープの長手方向と直交する方向の多数の凹溝23,23’が形成された凹凸面22,22’としたポリオレフィン樹脂フィルムを基材層20とし,この基材層20の両面に,粘着剤層30,30’を設け,前記基材層20及び前記粘着剤層30,30’の粘着剤中に繊維片32が分散された,通気性及び手切れ性を有する両面粘着テープ10’とすることもできる。   Further, as a third embodiment of the present invention, as shown in FIG. 3, the both surfaces are uneven surfaces 22 and 22 ′ in which a large number of concave grooves 23 and 23 ′ in the direction orthogonal to the longitudinal direction of the adhesive tape are formed. A polyolefin resin film is used as a base material layer 20, and adhesive layers 30 and 30 ′ are provided on both surfaces of the base material layer 20, and fiber pieces are contained in the adhesive material of the base material layer 20 and the adhesive layers 30 and 30 ′. A double-sided pressure-sensitive adhesive tape 10 'having air permeability and hand cutting properties in which 32 is dispersed can also be obtained.

〔基材層〕
本発明の粘着テープ10及び両面粘着テープ10’で基材層20として使用するフィルムは,未延伸のポリオレフィン樹脂のフィルムであり,これは公知のポリオレフィン樹脂を使用して製造することかできる。
[Base material layer]
The film used as the base material layer 20 in the pressure-sensitive adhesive tape 10 and the double-sided pressure-sensitive adhesive tape 10 ′ of the present invention is an unstretched polyolefin resin film, which can be manufactured using a known polyolefin resin.

このようなポリオレフィン樹脂としては,例えばポリエチレン樹脂,ポリプロピレン樹脂,エチレンとプロピレンとの共重合体樹脂,エチレン及び/又はプロピレンと他の一種または二種以上のα−オレフィンとの共重合体樹脂などを例示することができる。   Examples of such polyolefin resins include polyethylene resins, polypropylene resins, copolymer resins of ethylene and propylene, copolymer resins of ethylene and / or propylene and one or more other α-olefins. It can be illustrated.

このうちのα−オレフィンとしては,例えばブテン−1,ペンテン−1,ヘキセン−1,ヘプテン−1,オクテン−1,ノネン−1,4−メチルペンテン−1,デセン−1等を挙げることができる。   Examples of the α-olefin include butene-1, pentene-1, hexene-1, heptene-1, octene-1, nonene-1, 4-methylpentene-1, and decene-1. .

好ましいポリオレフィン樹脂の例としては,ポリエチレン樹脂を挙げることができる。   Examples of preferred polyolefin resins include polyethylene resins.

ポリオレフィン樹脂の分子量は,フィルムに成形し得る範囲であれば特に制限されないが,樹脂の流れ性を表す尺度であるメルトインデックスで表すと,一般に0.2〜20g/10分の範囲,好ましくは1〜10g/10分(いずれも荷重2.16kg,温度190℃)の範囲である。   The molecular weight of the polyolefin resin is not particularly limited as long as it can be formed into a film, but it is generally in the range of 0.2 to 20 g / 10 min, preferably 1 in terms of melt index, which is a measure representing the resin flowability. -10 g / 10 min (both are 2.16 kg, temperature is 190 ° C.).

本発明の粘着テープ10及び両面粘着テープ10’の基材層20となる前述のポリオレフィン樹脂のシートの厚さは,一例として40〜400μmの範囲であるが,この厚さに限定されず,用途等に応じて適宜の厚さに設定し得る。   The thickness of the polyolefin resin sheet used as the base layer 20 of the pressure-sensitive adhesive tape 10 and the double-sided pressure-sensitive adhesive tape 10 ′ of the present invention is, for example, in the range of 40 to 400 μm, but is not limited to this thickness. It can be set to an appropriate thickness depending on the like.

このポリオレフィン樹脂シートは,一方の面を平滑面21とし,他方の面を凹凸面22としており,この凹凸面22に,粘着テープ10の長手方向に対し直交方向を成す凹溝23が多数形成されている。   In this polyolefin resin sheet, one surface is a smooth surface 21 and the other surface is a concavo-convex surface 22, and a number of concave grooves 23 that are orthogonal to the longitudinal direction of the adhesive tape 10 are formed on the concavo-convex surface 22. ing.

また,両面粘着テープ10’の場合,前記ポリオレフィン樹脂シートの両面を凹凸面22,22’とし,この凹凸面22,22’に,粘着テープ10の長手方向に対し直交方向を成す凹溝23が多数形成されているものとしても良い。   In the case of the double-sided pressure-sensitive adhesive tape 10 ′, both surfaces of the polyolefin resin sheet are uneven surfaces 22, 22 ′, and the uneven surfaces 23, 22 ′ have concave grooves 23 that are perpendicular to the longitudinal direction of the adhesive tape 10. Many may be formed.

この凹溝23は,粘着テープ10を手で切断する際に基材層20に破断が生じる位置となるもので,このような手による切断を可能と成すものであれば,その断面形状は,図示したようなV字状の他,矩形状,(半)円形状等,如何なる形状であっても良く,その深さも,特に限定されるものではないが,前述したシート厚40〜400μmのポリオレフィン樹脂のシートを基材層20として使用する場合,深さは,30μm未満では手切れ性が損なわれることから,30〜300μm,好ましくは40〜120μmの凹溝23を形成し,凹溝23の形成部分における肉厚を,10〜100μmとすることが好ましい。   The groove 23 is a position where the base material layer 20 is broken when the adhesive tape 10 is cut by hand. If the groove 23 can be cut by hand, its cross-sectional shape is In addition to the V shape shown in the figure, the shape may be any shape such as a rectangular shape or a (semi) circular shape, and the depth thereof is not particularly limited, but the above-described polyolefin having a sheet thickness of 40 to 400 μm When the resin sheet is used as the base material layer 20, the depth is less than 30 μm, and the hand cutting property is impaired. Therefore, the concave groove 23 of 30 to 300 μm, preferably 40 to 120 μm is formed. It is preferable that the thickness of the formed portion is 10 to 100 μm.

この凹溝23の間隔は,0.5mm未満では粘着テープ10の長手方向に強度が不足し,5mmを超えると本来の手切れ性が不十分となる可能性があることから,一例として0.5〜5mm,好ましくは0.6〜1.4mm間隔に設定することができる。但し,これよりも広く,又は狭く形成しても良い。   If the interval between the concave grooves 23 is less than 0.5 mm, the strength in the longitudinal direction of the adhesive tape 10 is insufficient, and if it exceeds 5 mm, the original hand cutting property may be insufficient. The interval can be set to 5 to 5 mm, preferably 0.6 to 1.4 mm. However, it may be formed wider or narrower than this.

前述したポリオレフィン樹脂を原料として,一方の面を平滑面21,他方の面を凹凸面22としたポリオレフィン樹脂シートを製造する方法の一例を,図7に示す。   FIG. 7 shows an example of a method for producing a polyolefin resin sheet using the above-described polyolefin resin as a raw material and having one surface as a smooth surface 21 and the other surface as an uneven surface 22.

図7に示す例では,予め繊維片32と混練したポリオレフィン樹脂を溶融して押出機50の押出ダイ51よりフィルム状に押出した後,押し出されたフィルムが未だ完全に室温まで冷却されていない状態でエンボスロール61とゴムロール62間を通過させることにより,ゴムロール62との接触側に平滑面21,エンボスロール61との接触側にエンボスロール61の表面に設けた凸条61aに対応する形状の凹溝23を形成している。   In the example shown in FIG. 7, after the polyolefin resin previously kneaded with the fiber pieces 32 is melted and extruded into a film shape from the extrusion die 51 of the extruder 50, the extruded film is not yet completely cooled to room temperature. By passing between the embossing roll 61 and the rubber roll 62, the concave surface having a shape corresponding to the convex surface 61a provided on the surface of the embossing roll 61 on the smooth surface 21 on the contact side with the rubber roll 62 and on the surface side with the embossing roll 61 is provided. A groove 23 is formed.

なお,基材層20の両面に凹凸面22,22’を形成する場合は,例えば,前記ゴムロール62の代わりにエンボスロール61’を用意し,前記エンボスロール61とエンボスロール61’間を通過させることにより,両面に凹溝23,23’を形成することができる。   In the case where the concave and convex surfaces 22 and 22 ′ are formed on both surfaces of the base material layer 20, for example, an embossing roll 61 ′ is prepared instead of the rubber roll 62, and the embossing roll 61 and the embossing roll 61 ′ are passed through. Thus, the concave grooves 23 and 23 'can be formed on both sides.

粘着剤との馴染みを良好なものとして層間剥離が生じることを防止するために,ポリオレフィン樹脂フィルムに形成した凹凸面22には,図7に示すように,放電電極64と,平滑な表面を有する処理ロール65間を通過させる際にコロナ放電処理を行うものとしても良い。   The uneven surface 22 formed on the polyolefin resin film has a discharge electrode 64 and a smooth surface, as shown in FIG. 7, in order to prevent the delamination from occurring due to good conformity with the adhesive. Corona discharge treatment may be performed when passing between the treatment rolls 65.

このようにコロナ放電処理を行うことで,凹凸面22と後述する粘着剤31との親和性(凹凸面に対する接着剤の投錨性,凹凸面のぬれ性)を向上させることができ,粘着テープ10を被着物より剥離する際に層間剥離が生じて粘着剤が被着物の表面上に残る,所謂「糊残り」の発生を防止することができる。   By performing the corona discharge treatment in this manner, it is possible to improve the affinity between the uneven surface 22 and the pressure-sensitive adhesive 31 described later (adhesiveness of the adhesive to the uneven surface, wettability of the uneven surface). It is possible to prevent the occurrence of so-called “glue residue”, in which delamination occurs when the film is peeled off from the adherend and the pressure-sensitive adhesive remains on the surface of the adherend.

なお,前述したように凹凸面22に対するコロナ放電処理は,粘着剤層30との馴染みを良好とする上で好ましいが,本発明の粘着テープ10においてこのコロナ放電処理は必須ではなく,必要に応じて処理を行うものすれば良い。   As described above, the corona discharge treatment for the concavo-convex surface 22 is preferable in order to improve the familiarity with the pressure-sensitive adhesive layer 30, but this corona discharge treatment is not essential in the pressure-sensitive adhesive tape 10 of the present invention. What is necessary is just to process.

基材層20のダイン数(濡れ指数)は,平滑面21に対し凹凸面22の方が大きくなっていることが好ましく,好ましいダイン数(濡れ指数)は一例として平滑面21で30Dyn/cm以下,凹凸面22で35Dyn/cm以上であり,平滑面21の濡れ指数が30Dyn/cmより大きいと,粘着テープ10をロール状に巻き取った際に平滑面21と粘着剤層30が必要以上に強固に接着してしまう,所謂「ブロッキング現象」の発生によって,粘着テープ10を展開することが困難となる。   The dying number (wetting index) of the base material layer 20 is preferably larger on the concavo-convex surface 22 than on the smooth surface 21, and the preferable dyne number (wetting index) is, for example, 30 Dyn / cm or less on the smooth surface 21. When the uneven surface 22 is 35 Dyn / cm or more and the wetting index of the smooth surface 21 is greater than 30 Dyn / cm, the smooth surface 21 and the adhesive layer 30 are more than necessary when the adhesive tape 10 is wound into a roll. Due to the occurrence of a so-called “blocking phenomenon” that results in strong adhesion, it becomes difficult to deploy the adhesive tape 10.

一方,凹凸面22のぬれ指数が35Dyn/cm未満であると,凹凸面22に対する粘着剤31の接着力が不足して,前述した「糊残り」等が生じる原因となる。   On the other hand, if the wetting index of the concavo-convex surface 22 is less than 35 Dyn / cm, the adhesive force of the pressure-sensitive adhesive 31 to the concavo-convex surface 22 is insufficient, which causes the aforementioned “glue residue” or the like.

なお,凹凸面22に対する粘着剤層30の親和性を高めるための方法としては,前述したコロナ放電処理の他に,プライマーを塗布する方法もある。   As a method for increasing the affinity of the pressure-sensitive adhesive layer 30 with respect to the uneven surface 22, there is a method of applying a primer in addition to the above-described corona discharge treatment.

このようなプライマーの塗布による親和性の向上も良く知られた方法であり,プライマーとしては既知の各種のもの,例えばニトリルゴム等のゴム系のプライマー,アクリル樹脂系のプライマーなどを使用することができる。   The improvement of affinity by the application of such a primer is also a well-known method, and it is possible to use various known primers, for example, a rubber-based primer such as nitrile rubber, an acrylic resin-based primer, etc. it can.

なお,前述したコロナ放電処理と同様,本発明ではプライマーの塗布も必須ではなく,必要に応じて適宜行うことができ,また,前述したコロナ放電処理に代え,又はコロナ放電処理と併用してプライマー塗布を行っても良い。   As in the case of the corona discharge treatment described above, in the present invention, primer application is not essential, and can be appropriately performed as necessary. In addition, the primer is used instead of the corona discharge treatment described above or in combination with the corona discharge treatment. Application may be performed.

また,本発明の基材層20には,繊維片32が添加されるが,繊維片32の一次分散は,マスターバッチでポリオレフィン樹脂と混練を得て,押出機ホッパーへと供給される。用いられる繊維片32は,ポリオレフィン樹脂の熱溶融温度200℃域を超えていなければならず,この観点からは,ポリエステル系(Tg220℃),ナイロン(Tg220℃),アクリル系(熱硬化),で最も好ましいのは熱溶融とは無縁なレーヨンが好ましいが,防水性の観点からは,ポリプロピレン系,ポリエステル系が好ましい。   Moreover, the fiber piece 32 is added to the base material layer 20 of the present invention, and the primary dispersion of the fiber piece 32 is kneaded with the polyolefin resin in a master batch and supplied to the extruder hopper. The fiber pieces 32 to be used must exceed the heat melting temperature of 200 ° C. of the polyolefin resin. From this viewpoint, polyester (Tg 220 ° C.), nylon (Tg 220 ° C.), acrylic (thermosetting), Most preferred is rayon which is unrelated to heat melting, but from the viewpoint of waterproofness, polypropylene and polyester are preferred.

繊維片32の分散した基材層20は,未延伸のポリオレフィン樹脂のフィルムであり,これは公知のポリオレフィン樹脂を使用して製造することができる。   The base material layer 20 in which the fiber pieces 32 are dispersed is an unstretched polyolefin resin film, which can be manufactured using a known polyolefin resin.

〔粘着剤層〕
以上のように構成されたポリオレフィン樹脂のフィルムから成る基材層20の凹凸面22に,また,両面粘着テープとする場合には基材層20の両面に,繊維片32が分散された粘着剤層30が形成される。
(Adhesive layer)
A pressure-sensitive adhesive in which fiber pieces 32 are dispersed on the uneven surface 22 of the base material layer 20 made of a polyolefin resin film configured as described above, or on both surfaces of the base material layer 20 in the case of a double-sided pressure-sensitive adhesive tape. Layer 30 is formed.

粘着剤
粘着剤層30を構成する粘着剤としては,既知の各種の粘着剤を使用可能であり,一例としてアクリル系粘着剤,ビニルエーテル系粘着剤,シリコーン系粘着剤,ゴム系粘着剤等を挙げることができる。
Adhesive Various known adhesives can be used as the adhesive constituting the adhesive layer 30, and examples thereof include acrylic adhesives, vinyl ether adhesives, silicone adhesives, rubber adhesives, and the like. be able to.

使用する粘着剤の形態も特に制限されず,溶液型粘着剤,エマルジョン型粘着剤,ホットメルト型粘着剤等のいずれの型のものを使用しても良い。   The form of the pressure-sensitive adhesive to be used is not particularly limited, and any type such as a solution-type pressure-sensitive adhesive, an emulsion-type pressure-sensitive adhesive, and a hot-melt type pressure-sensitive adhesive may be used.

粘着剤層の積層方法
前述した粘着剤層30の形成は,例えば,図1に示す本発明の第1実施形態のように,予め繊維を分散させておいた粘着剤を,前述した基材層20の凹凸面22に塗布することにより,あるいは工程紙上に塗布した後,前記基材層20の凹凸面22に転写することにより形成する。
Method of Laminating Adhesive Layer The above-described adhesive layer 30 is formed by, for example, using the above-mentioned base material layer with an adhesive in which fibers are dispersed in advance as in the first embodiment of the present invention shown in FIG. It is formed by applying to the concave / convex surface 22 of the base material layer 20 by coating on the concave / convex surface 22 of the substrate 20, or after coating on the process paper.

この粘着剤層30は,図1に示すように繊維片32が分散された粘着剤を1層塗工することにより形成した単層の粘着剤層30によって形成するものとしても良いが,好ましくは,図4及び図5に示すように繊維片32の分散量が異なる複数種類の粘着剤を2層以上塗工して,粘着剤層30の厚み方向における繊維片32の分散量に勾配を持たせるものとしても良い。   The pressure-sensitive adhesive layer 30 may be formed of a single-layer pressure-sensitive adhesive layer 30 formed by applying one layer of pressure-sensitive adhesive in which fiber pieces 32 are dispersed as shown in FIG. 4 and FIG. 5, two or more types of adhesives having different dispersion amounts of the fiber pieces 32 are applied, and the dispersion amount of the fiber pieces 32 in the thickness direction of the adhesive layer 30 has a gradient. It can also be used.

前述した繊維片32は,これを基材層20及び粘着剤層30中に分散させることにより,通気性を有し,さらに,基材層20及び粘着剤層30が補強されて伸びが低減すると共に引張強さの向上を得ることができる一方で,粘着剤層30に前述した疑似架橋を生じさせ,被着物の表面に対する追従性及び接着力を低下させる原因となり得る。   The fiber pieces 32 described above have air permeability by being dispersed in the base material layer 20 and the pressure-sensitive adhesive layer 30, and the base material layer 20 and the pressure-sensitive adhesive layer 30 are further reinforced to reduce elongation. At the same time, an improvement in tensile strength can be obtained, while the pressure-sensitive adhesive layer 30 is caused to undergo the above-described pseudo-crosslinking, which can cause a decrease in followability and adhesion force to the surface of the adherend.

そこで,図4に示すように粘着剤層30のうち,基材層20側(紙面上側)を相対的に繊維片32の含有量が多い粘着剤を積層して形成した粘着剤層(図示の例では繊維片含有粘着剤層301)とする一方,被着物と接着する側(紙面下側)を繊維片32の添加量が少ない粘着剤を積層して形成した粘着剤層(図示の例では繊維片少量含有粘着剤層302)とした,複層構造の粘着剤層を形成するものとしても良い。   Therefore, as shown in FIG. 4, the pressure-sensitive adhesive layer 30 is formed by laminating a pressure-sensitive adhesive having a relatively large content of fiber pieces 32 on the base material layer 20 side (the upper side of the paper) (shown in the figure). In the example, the fiber piece-containing pressure-sensitive adhesive layer 301) is used, while the pressure-sensitive adhesive layer (in the illustrated example) is formed by laminating a pressure-sensitive adhesive with a small amount of fiber pieces 32 on the side to be adhered to the adherend (the lower side of the paper) A pressure-sensitive adhesive layer 302) containing a small amount of fiber pieces may be used to form a multi-layered pressure-sensitive adhesive layer.

また,図5に示すように,基材層と粘着剤層間の層間剥離を防止するために,粘着剤層30の厚み方向中央部に繊維片32の分散量が相対的に多い粘着剤を積層して形成した粘着剤層(図示の例では繊維片含有粘着剤層301)を設ける一方,これを中心としてその外側に繊維片の分散量が少ない粘着剤を塗布,積層して形成した粘着剤層(図示の例では第1の繊維片少量含有粘着剤層302a,第2の繊維片少量含有粘着剤層302b)を形成した三層構造の粘着剤層30を形成し,被着物との接着性を向上させるのみならず,基材層20との接着性を向上させるものとしても良い。   Further, as shown in FIG. 5, in order to prevent delamination between the base material layer and the pressure-sensitive adhesive layer, a pressure-sensitive adhesive having a relatively large dispersion amount of the fiber pieces 32 is laminated on the central portion in the thickness direction of the pressure-sensitive adhesive layer 30. The pressure-sensitive adhesive layer (fiber piece-containing pressure-sensitive adhesive layer 301 in the example shown in the figure) is provided, and a pressure-sensitive adhesive formed by applying and laminating a pressure-sensitive adhesive with a small amount of fiber pieces to the outside. The adhesive layer 30 having a three-layer structure in which the layers (in the illustrated example, the first fiber piece-containing pressure-sensitive adhesive layer 302a and the second fiber piece-containing pressure-sensitive adhesive layer 302b) are formed is formed and adhered to the adherend It is good also as what improves not only the property but adhesiveness with the base material layer 20. FIG.

なお,上述した複層構造の粘着剤層は,本発明の両面粘着テープ10’にも適用できる。なお,基材層20の両面に積層された粘着剤層30,30’のうち一方のみを上述の複層構造としても良く,双方を上述の複層構造としても良い(図示せず)。   In addition, the adhesive layer having the multilayer structure described above can also be applied to the double-sided adhesive tape 10 'of the present invention. Note that only one of the pressure-sensitive adhesive layers 30 and 30 ′ laminated on both surfaces of the base material layer 20 may have the above-described multilayer structure, or both may have the above-described multilayer structure (not shown).

このようにして得られた粘着テープ10は,既知の粘着テープと同様,図8に示すように例えば25m,50mといった所定の長さを巻き取って形成したロールの状態で提供される。   The adhesive tape 10 thus obtained is provided in the form of a roll formed by winding a predetermined length such as 25 m or 50 m as shown in FIG.

ロール状に巻き取った状態で粘着テープを提供する場合,粘着剤としてゴム系粘着剤を使用する場合又は,粘着剤の塗布量が多い場合等には,粘着テープ10の展開性を向上させるために,基材層20の平滑面21に既知の剥離剤を塗布する等しても良い。   In order to improve the developability of the pressure-sensitive adhesive tape 10 when the pressure-sensitive adhesive tape is provided in a rolled state, when a rubber-based pressure-sensitive adhesive is used as the pressure-sensitive adhesive, or when the amount of pressure-sensitive adhesive applied is large. In addition, a known release agent may be applied to the smooth surface 21 of the base material layer 20.

また,本発明は,図2又は図3に示すように,基材層20の両面に粘着剤層30を積層することで両面粘着テープ10’とすることができる。   Moreover, as shown in FIG. 2 or FIG. 3, the present invention can be a double-sided pressure-sensitive adhesive tape 10 ′ by laminating an adhesive layer 30 on both surfaces of a base material layer 20.

例えば,図2に示す,基材層20の平滑面21及び凹凸面22の両面に粘着剤層30を積層した第2実施形態の両面粘着テープ10’については,例として,以下の方法により製造することができる。   For example, the double-sided pressure-sensitive adhesive tape 10 ′ of the second embodiment in which the pressure-sensitive adhesive layer 30 is laminated on both the smooth surface 21 and the uneven surface 22 of the base material layer 20 shown in FIG. 2 is manufactured by the following method as an example. can do.

剥離シートに,予め繊維片32を分散させておいた粘着剤を,キスロールコーター,グラビアコーター,ナイフコーター,リバースロールコーター等により,塗布し,乾燥する。   The pressure-sensitive adhesive in which the fiber pieces 32 are dispersed in advance is applied to the release sheet with a kiss roll coater, gravure coater, knife coater, reverse roll coater, and the like, and dried.

これに,前述の図7を参照して説明した方法で製造した,繊維片32が分散された基材層20を積層し,巻き込んでいく。   The base material layer 20 in which the fiber pieces 32 are dispersed is manufactured by the method described with reference to FIG.

さらに,これを巻き戻しながら,前記基材層20上に,前記予め繊維片32を分散させておいた粘着剤をキスロールコーター,グラビアコーター,ナイフコーター,リバースロールコーター等により塗布し,乾燥後に巻き上げる。   Further, while rewinding, the adhesive in which the fiber pieces 32 are dispersed in advance is applied onto the base material layer 20 by a kiss roll coater, gravure coater, knife coater, reverse roll coater, etc. Roll up.

本発明の両面粘着テープ10’は,片面または両面が前記剥離シートで覆われ,巻き上げられたテープもしくはシート形状で提供される。   The double-sided pressure-sensitive adhesive tape 10 ′ of the present invention is provided in the form of a tape or sheet rolled up by covering one side or both sides with the release sheet.

前記剥離シートとしては,紙に樹脂をアンカーコートしたもの,ポリエチレン,ポリプロピレン等よりなる剥離性の高い樹脂シート等よりなり,所望により表面にシリコーン系材料等の剥離剤を塗布したものが使用される。   The release sheet is made of a paper-anchored resin, a resin sheet made of polyethylene, polypropylene, or the like having a high release property, and if desired, a surface coated with a release agent such as a silicone material. .

〔繊維片〕
基材層20及び粘着剤層30中に分散される前述の繊維片32としては,例えば,アクリル,ポリエチレン,ポリプロピレン,ポリエチレンテレフタレート,6−ナイロン,6,6−ナイロン,ポリパラフェニレンテレフタルアミド,ポリアクリルニトリル,PMMA(ポリメタクリル酸メチル),ビニロン,レーヨン,麻,絹,毛等の繊維を挙げることができる。
[Fiber pieces]
Examples of the fiber pieces 32 dispersed in the base material layer 20 and the pressure-sensitive adhesive layer 30 include, for example, acrylic, polyethylene, polypropylene, polyethylene terephthalate, 6-nylon, 6,6-nylon, polyparaphenylene terephthalamide, poly Examples thereof include fibers such as acrylonitrile, PMMA (polymethyl methacrylate), vinylon, rayon, hemp, silk, and hair.

この繊維片32は,綿又は麻,羊毛等の短繊維の単体又は,これら短繊維又は絹又は化学繊維等の長繊維の断片等から成るモノフィラメントであっても良く,又は,モノフィラメントを撚り合わせて得たマルチフィラメント(糸)の断片であっても良い。   The fiber pieces 32 may be monofilaments made of short fibers such as cotton or hemp or wool, or short filaments or fragments of long fibers such as silk or chemical fibers, or twisted monofilaments. It may be a fragment of the obtained multifilament (yarn).

これらのうち特にレーヨン,ナイロン,ポリエチレン,ポリプロピレン,ポリエチレンテレフタレートに代表されるポリエステル系や,アクリル系の繊維片の使用は,基材層20とするポリオレフィン樹脂フィルムとの接着性,耐熱性,耐溶剤性等の観点から好ましい。   Of these, polyester fiber typified by rayon, nylon, polyethylene, polypropylene, and polyethylene terephthalate, and the use of acrylic fiber fragments, adhesion to the polyolefin resin film as the base material layer 20, heat resistance, and solvent resistance. From the viewpoint of properties and the like.

これらの原料から成る繊維片32は,単一の原料から成る繊維片32のみを単独で使用してもよいが,異なる原料で製造された複数種類の繊維片32を2種類以上混ぜて使用するものとしても良い。   As the fiber pieces 32 made of these raw materials, only the fiber pieces 32 made of a single raw material may be used alone, but two or more types of fiber pieces 32 made of different raw materials are mixed and used. It is good as a thing.

また,繊維片32は,着色したものを使用することもでき,あるいは予め着色しておいた原料を使用して製造した繊維片32を使用することもできる。   Further, the fiber piece 32 may be a colored one, or may be a fiber piece 32 produced using a previously colored raw material.

粘着剤層30への繊維片32の添加量は,得られる粘着テープ10の,粘着力,靱性,手切れ性・手触り(柔らかさ)等の観点から,粘着テープの粘着剤固形分100重量部に対し,0.5〜10重量部とすることが好ましく,より好ましくは1〜5重量部である。   The amount of the fiber pieces 32 added to the pressure-sensitive adhesive layer 30 is 100 parts by weight of the pressure-sensitive adhesive solid content of the pressure-sensitive adhesive tape from the viewpoint of the pressure-sensitive adhesive strength, toughness, hand cutting property, and touch (softness) of the pressure-sensitive adhesive tape 10 to be obtained. The amount is preferably 0.5 to 10 parts by weight, more preferably 1 to 5 parts by weight.

また,基材層20における繊維片の添加量としては,前記基材層固形分100重量部に対し,0.2〜10重量部,好ましくは,0.5〜3重量部である。   Further, the amount of the fiber pieces added to the base material layer 20 is 0.2 to 10 parts by weight, preferably 0.5 to 3 parts by weight with respect to 100 parts by weight of the solid content of the base material layer.

なお,本発明で繊維片32として使用する材質としては,粘着剤として後述のアクリル系のものを使用する場合,アクリル系のものの使用が好ましく,また,アクリル系の繊維片の使用は耐熱性,耐水性の点でも好ましい。   In addition, as a material used as the fiber piece 32 in this invention, when using the acrylic type mentioned later as an adhesive, use of an acrylic type is preferable, and use of an acrylic type fiber piece is heat resistant, Also preferred from the viewpoint of water resistance.

また,耐水性の点ではポリエステル系のものの使用も好ましく,また,耐熱性の点ではレーヨン繊維も好適に使用できる。   In addition, the use of a polyester-based material is preferable in terms of water resistance, and rayon fibers can also be suitably used in terms of heat resistance.

また,通気性の観点から,繊維片32として,繊維内部が中空となっている(断面に孔が存在する構造を有する)中空繊維片を使用することが好ましい。   From the viewpoint of air permeability, it is preferable to use a hollow fiber piece in which the inside of the fiber is hollow (having a structure in which a hole exists in the cross section) as the fiber piece 32.

本発明で使用される中空繊維片は,単糸繊維が中空を有するものであれば特に限定されず,繊維の表面に多数の微細孔を有した多孔性の中空繊維片でもよく,また,表面に多数の微細孔を有しない非多孔性の中空繊維片であってもよい。   The hollow fiber piece used in the present invention is not particularly limited as long as the single fiber has a hollow shape, and may be a porous hollow fiber piece having a large number of micropores on the surface of the fiber. It may be a non-porous hollow fiber piece having a large number of micropores.

本発明に使用される中空繊維片としては,例えば,麻,綿等の天然繊維の他,ポリエステル,ナイロン,アクリル,塩化ビニル等の合成繊維の内部を中空にしたものが好適である。   As the hollow fiber piece used in the present invention, for example, natural fibers such as hemp and cotton, and synthetic fibers such as polyester, nylon, acrylic and vinyl chloride that are hollow are suitable.

なお,中空繊維片の単糸の断面形状については,中空断面であれば特に限定されず,丸,三角,四角が例示される。   In addition, about the cross-sectional shape of the single yarn of a hollow fiber piece, if it is a hollow cross section, it will not specifically limit, A round, a triangle, and a square are illustrated.

また,本発明の粘着テープ10は,図6に示すように,基材層及び粘着剤層に含有された繊維片32を,粘着テープ10の長手方向に沿って層状に分散させても良い。   In the pressure-sensitive adhesive tape 10 of the present invention, the fiber pieces 32 contained in the base material layer and the pressure-sensitive adhesive layer may be dispersed in layers along the longitudinal direction of the pressure-sensitive adhesive tape 10 as shown in FIG.

この場合,テープの厚み方向よりも長手方向への通気性が向上し,例えば,貼着時に抱き込んだエアーを,テープの厚み方向の他,長手方向に効率良く逃がす(排出する)ことができる。   In this case, the air permeability in the longitudinal direction is improved compared to the thickness direction of the tape, and for example, the air entrapped at the time of sticking can be efficiently released (discharged) in the longitudinal direction in addition to the thickness direction of the tape. .

10 粘着テープ(10’ 両面粘着テープ)
20 基材層(ポリオレフィン樹脂シート)
21 平滑面
22,22’ 凹凸面
23,23’ 凹溝
30,30’ 粘着剤層
301 繊維片含有粘着剤層
302 繊維片少量含有粘着剤層
302a 第1の繊維片少量含有粘着剤層
302b 第2の繊維片少量含有粘着剤層
31 粘着剤
32 繊維片
40 巻き芯
50 押出機
51 押出ダイ
61,61’ エンボスロール
61a 凸条
62 ゴムロール
64 放電電極
65 処理ロール
100 粘着テープ
120 基材層
121 平滑面
122 凹凸面
123 凹溝
130 粘着剤層
131 粘着剤
135 不織布又は割布
136 ポリエステル系樹脂
140 巻き芯
150 工程紙
10 Adhesive tape (10 'double-sided adhesive tape)
20 Base material layer (polyolefin resin sheet)
21 Smooth surface 22, 22 'Concavity and convexity surface 23, 23' Concave groove 30, 30 'Adhesive layer 301 Fiber piece containing adhesive layer 302 Small amount of fiber piece containing adhesive layer 302a First small amount of fiber piece containing adhesive layer 302b No. 1 2 small amount of fiber-containing pressure-sensitive adhesive layer 31 pressure-sensitive adhesive 32 fiber piece 40 winding core 50 extruder 51 extrusion die 61, 61 ′ embossing roll 61a ridge 62 rubber roll 64 discharge electrode 65 treatment roll 100 pressure-sensitive adhesive tape 120 base material layer 121 smooth Surface 122 Concavity and convexity surface 123 Concave groove 130 Adhesive layer 131 Adhesive 135 Non-woven fabric or split cloth 136 Polyester resin 140 Core 150 150 Process paper

Claims (19)

片面に粘着テープの長手方向と直交する方向に複数本の凹溝が所定間隔で形成された凹凸面を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層と,
前記基材層の前記凹凸面上に形成された粘着剤層を備え,
前記基材層及び前記粘着剤層に,繊維片が分散され,通気性を有していることを特徴とする粘着テープ。
A base layer made of an unstretched polyolefin resin film having a concavo-convex surface in which a plurality of concave grooves are formed at predetermined intervals in a direction orthogonal to the longitudinal direction of the adhesive tape on one side;
Comprising an adhesive layer formed on the uneven surface of the base material layer,
A pressure-sensitive adhesive tape, wherein fiber pieces are dispersed in the base material layer and the pressure-sensitive adhesive layer and have air permeability.
前記粘着剤層が前記基材層の両面に形成され,
前記基材層及び前記粘着剤層に繊維片が分散され,通気性を有していることを特徴とする請求項1記載の粘着テープ。
The pressure-sensitive adhesive layer is formed on both surfaces of the base material layer;
The pressure-sensitive adhesive tape according to claim 1, wherein fiber pieces are dispersed in the base material layer and the pressure-sensitive adhesive layer and have air permeability.
前記基材層が,両面に前記凹凸面を有することを特徴とする請求項2記載の粘着テープ。   The pressure-sensitive adhesive tape according to claim 2, wherein the base material layer has the uneven surface on both sides. 前記粘着剤層が,粘着剤の固形分100重量部に対し,前記繊維片を0.5〜10重量部含有することを特徴とする請求項1〜3いずれか1項記載の粘着テープ。   The said adhesive layer contains 0.5-10 weight part of said fiber pieces with respect to 100 weight part of solid content of an adhesive, The adhesive tape of any one of Claims 1-3 characterized by the above-mentioned. 前記繊維片の繊維径が,0.05〜100デニールであることを特徴とする請求項1〜4いずれか1項記載の粘着テープ。   The pressure-sensitive adhesive tape according to claim 1, wherein the fiber piece has a fiber diameter of 0.05 to 100 denier. 前記繊維片の長さが1〜10mmであることを特徴とする請求項1〜5いずれか1項記載の粘着テープ。   The pressure-sensitive adhesive tape according to any one of claims 1 to 5, wherein the fiber piece has a length of 1 to 10 mm. 前記基材層が,前記基材層固形分100重量部に対し,前記繊維片を0.2〜10重量部含有することを特徴とする請求項1〜6いずれか1項記載の粘着テープ。   The pressure-sensitive adhesive tape according to claim 1, wherein the base material layer contains 0.2 to 10 parts by weight of the fiber piece with respect to 100 parts by weight of the solid content of the base material layer. 粘着テープの長手方向の伸びが30%以下である請求項1〜7いずれか1項記載の粘着テープ。   The adhesive tape according to any one of claims 1 to 7, wherein an elongation in the longitudinal direction of the adhesive tape is 30% or less. 粘着テープの長手方向の引張強さが100(N/50mm幅)以上であることを特徴とする請求項1〜8いずれか1項記載の粘着テープ。   The pressure-sensitive adhesive tape according to any one of claims 1 to 8, wherein the pressure-sensitive adhesive tape has a tensile strength in the longitudinal direction of 100 (N / 50 mm width) or more. 前記粘着剤層が,被着物に対する貼着側において前記繊維片の分散量が減少する構成であることを特徴とする請求項1〜9いずれか1項記載の粘着テープ。   The pressure-sensitive adhesive tape according to any one of claims 1 to 9, wherein the pressure-sensitive adhesive layer has a configuration in which a dispersion amount of the fiber pieces is reduced on a sticking side to an adherend. 前記粘着剤層が,基材層との貼着側において前記繊維片の分散量が減少する構成であることを特徴とする請求項10記載の粘着テープ。   The pressure-sensitive adhesive tape according to claim 10, wherein the pressure-sensitive adhesive layer has a configuration in which a dispersion amount of the fiber pieces is reduced on a bonding side with the base material layer. 前記繊維片が,PET,オレフィン系樹脂,レーヨン,ビニロン,ナイロンの群から選択されたいずれかの材質から成り,該繊維片の一種を,又は二種以上を混合したものを,前記粘着剤層に分散させたことを特徴とする請求項1〜11いずれか1項記載の粘着テープ。   The above-mentioned pressure-sensitive adhesive layer is made of any material selected from the group consisting of PET, olefin-based resin, rayon, vinylon, and nylon, and one or a mixture of two or more of the fiber pieces. The pressure-sensitive adhesive tape according to any one of claims 1 to 11, wherein the pressure-sensitive adhesive tape is dispersed. 前記繊維片が中空繊維片であることを特徴とする請求項1〜12いずれか1項記載の粘着テープ。   The pressure-sensitive adhesive tape according to claim 1, wherein the fiber piece is a hollow fiber piece. 前記繊維片が,粘着テープの長手方向に沿って層状に分散されたことを特徴とする請求項1〜13いずれか1項記載の粘着テープ。   The pressure-sensitive adhesive tape according to claim 1, wherein the fiber pieces are dispersed in layers along the longitudinal direction of the pressure-sensitive adhesive tape. 片面に粘着テープの長手方向と直交する方向に複数本の凹溝が所定間隔で形成された凹凸面を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層の前記凹凸面に,粘着剤を積層して粘着剤層を形成する共に,前記基材層及び前記粘着剤層に,繊維片を分散させたことを特徴とする粘着テープの製造方法。   Adhesive is laminated on the concavo-convex surface of a base layer made of an unstretched polyolefin resin film having a concavo-convex surface in which a plurality of concave grooves are formed at predetermined intervals in a direction orthogonal to the longitudinal direction of the adhesive tape on one side. Thus, a pressure-sensitive adhesive layer is formed, and fiber pieces are dispersed in the base material layer and the pressure-sensitive adhesive layer. 前記基材層の両面に,粘着剤を積層して粘着剤層を形成すると共に,前記基材層及び前記粘着剤層に,繊維片を分散させたことを特徴とする請求項15記載の粘着テープの製造方法。   The pressure-sensitive adhesive according to claim 15, wherein a pressure-sensitive adhesive is laminated on both surfaces of the base material layer to form a pressure-sensitive adhesive layer, and fiber pieces are dispersed in the base material layer and the pressure-sensitive adhesive layer. Tape manufacturing method. 前記基材層が,両面に粘着テープの長手方向と直交する方向に複数本の凹溝が所定間隔で形成された凹凸面を有する未延伸のポリオレフィン樹脂製フィルムから成ることを特徴とする請求項16記載の粘着テープの製造方法。   The base material layer is made of an unstretched polyolefin resin film having a concavo-convex surface in which a plurality of concave grooves are formed at predetermined intervals in a direction orthogonal to the longitudinal direction of the adhesive tape on both surfaces. The manufacturing method of the adhesive tape of 16. 前記繊維片の分散量を変化させた複数種類の粘着剤を多層に積層して,被着物との接着面側で前記繊維片の分散量が減少する前記粘着剤層を形成したことを特徴とする請求項15〜17いずれか1項記載の粘着テープの製造方法。   A plurality of types of pressure-sensitive adhesives in which the dispersion amount of the fiber pieces is changed are laminated in multiple layers to form the pressure-sensitive adhesive layer in which the dispersion amount of the fiber pieces decreases on the adhesion surface side with the adherend. The manufacturing method of the adhesive tape of any one of Claims 15-17 to do. 前記繊維片の分散量を変化させた複数種類の粘着剤を多層に積層して,前記基材層の前記凹凸面との接着面側で前記繊維片の分散量が減少する前記粘着剤層を形成したことを特徴とする請求項15〜18いずれか1項記載の粘着テープの製造方法。   The pressure-sensitive adhesive layer in which a plurality of types of pressure-sensitive adhesives in which the dispersion amount of the fiber pieces is changed is laminated in multiple layers, and the dispersion amount of the fiber pieces decreases on the adhesive surface side of the base material layer with the uneven surface. The method for producing a pressure-sensitive adhesive tape according to any one of claims 15 to 18, wherein the pressure-sensitive adhesive tape is formed.
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