JP6779714B2 - Moisture transfer inhibitor for medium-sized bean paste foods - Google Patents

Moisture transfer inhibitor for medium-sized bean paste foods Download PDF

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JP6779714B2
JP6779714B2 JP2016170541A JP2016170541A JP6779714B2 JP 6779714 B2 JP6779714 B2 JP 6779714B2 JP 2016170541 A JP2016170541 A JP 2016170541A JP 2016170541 A JP2016170541 A JP 2016170541A JP 6779714 B2 JP6779714 B2 JP 6779714B2
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fatty acid
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water transfer
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藤井 淳
淳 藤井
隆一 吉川
隆一 吉川
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Riken Vitamin Co Ltd
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Description

本発明は、包餡食品の中種に用いる水分移行抑制剤に関する。 The present invention relates to a water transfer inhibitor used for middle species of bean paste foods.

従来、餃子や春巻き等、各種食品素材を含む中種を、澱粉質を主原料とする外皮で包んでなる包餡食品においては、中種と外皮との水分含有量の差に起因する水分移行(即ち、保存中や調理中に比較的水分含有量の多い中種から水分が流出し、比較的水分含有量の少ない外皮に浸み込むこと)が問題となっている。水分移行が生じると、外皮がふやけて本来の軽い食感が損なわれる、外皮の厚みが増したり、べたついたりして歯切れが悪くなる等の弊害が生じる。特に、包餡食品を冷凍保存した後に加熱した場合、中種から多量の水分が外皮に移行して該包餡食品の品質を著しく損なうことがあり、改善が求められていた。 Conventionally, in wrapping foods in which medium-sized foods including various food materials such as dumplings and spring rolls are wrapped with an outer skin made mainly of starch, water transfer due to the difference in water content between the medium-sized seeds and the outer skin. (That is, water flows out from the medium seeds having a relatively high water content during storage or cooking and infiltrates into the outer skin having a relatively low water content). When water transfer occurs, the exodermis becomes soggy and the original light texture is impaired, the exodermis becomes thicker, and the exodermis becomes sticky, resulting in poor crispness. In particular, when the bean paste food is stored frozen and then heated, a large amount of water from the middle seeds may migrate to the outer skin and significantly impair the quality of the bean paste food, and improvement has been sought.

水分移行を抑制する方法としては、例えば、発酵セルロースを含有することを特徴とする、水分含量の異なる食品間の水分移行抑制剤(特許文献1)、主要構成脂肪酸がベヘン酸であるポリグリセリン脂肪酸エステルを油相中0.5〜35質量%含有することを特徴とする中種用油脂組成物(特許文献2)等を用いる方法が提案されている。 Examples of the method for suppressing water transfer include a water transfer inhibitor between foods having different water contents (Patent Document 1), which is characterized by containing fermented cellulose, and a polyglycerin fatty acid in which the main constituent fatty acid is behenic acid. A method using a medium-sized oil / fat composition (Patent Document 2) or the like, which comprises 0.5 to 35% by mass of an ester in the oil phase, has been proposed.

しかし、これらの方法によっても包餡食品の中種から外皮への水分移行を十分に抑制することは難しく、実用上満足し得るものとは言えない。そこで、より優れた水分移行抑制効果を得られる方法が求められていた。 However, even with these methods, it is difficult to sufficiently suppress the transfer of water from the middle species of the bean paste food to the exodermis, and it cannot be said that it is practically satisfactory. Therefore, there has been a demand for a method capable of obtaining a more excellent effect of suppressing water transfer.

特開2012−029682号公報Japanese Unexamined Patent Publication No. 2012-029682 特開2010−081868号公報Japanese Unexamined Patent Publication No. 2010-081868

本発明は、餃子や春巻き等の包餡食品において、中種から外皮への水分移行を抑制することのできる包餡食品の中種用水分移行抑制剤を提供することを課題とする。 An object of the present invention is to provide a water transfer inhibitor for medium seeds of bean paste foods capable of suppressing water transfer from medium seeds to outer skin in dumpling foods such as dumplings and spring rolls.

本発明者らは、上記課題に対して鋭意検討を行った結果、包餡食品の中種に特定の油脂加工澱粉とソルビタン脂肪酸エステルを添加することにより、中種から外皮への水分移行が抑制されることを見出し、この知見に基づいて本発明を成すに至った。 As a result of diligent studies on the above-mentioned problems, the present inventors suppressed the transfer of water from the middle seed to the outer skin by adding a specific modified starch and sorbitan fatty acid ester to the middle seed of the bean paste food. Based on this finding, the present invention has been made.

即ち、本発明は、下記(1)〜(3)からなっている。
(1)(a)モノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを含む油脂加工澱粉と、(b)ソルビタン脂肪酸エステルとを含有することを特徴とする包餡食品の中種用水分移行抑制剤。
(2)上記(1)に記載の包餡食品の中種用水分移行抑制剤を含有する中種を内包する包餡食品。
(3)上記(1)に記載の包餡食品の中種用水分移行抑制剤を中種に添加することを特徴とする包餡食品の水分移行抑制方法。
That is, the present invention comprises the following (1) to (3).
(1) Inhibition of water transfer for middle-class foods of packaged foods, which comprises (a) oil-processed starch containing monoglycerin fatty acid ester and / or glycerin organic acid fatty acid ester, and (b) sorbitan fatty acid ester. Agent.
(2) A bean paste food containing a medium seed containing the water transfer inhibitor for the middle seed of the bean paste food according to (1) above.
(3) A method for suppressing water transfer of a bean paste food, which comprises adding the water transfer inhibitor for medium seeds of the bean paste food according to (1) above to the middle seeds.

本発明の包餡食品の中種用水分移行抑制剤は、包餡食品の中種に添加して使用することにより、該中種から外皮への水分移行を抑制することができる。
本発明の包餡食品の中種用水分移行抑制剤を中種に添加して製造した包餡食品は、中種から外皮への水分移行が抑制されており、これを冷凍保存した後に加熱した場合であっても、外皮本来の軽くクリスピーな食感やソフトな食感、歯切れのよさを維持することができる。
The water transfer inhibitor for medium seeds of the bean paste food of the present invention can be used by adding it to the medium seeds of the bean paste food to suppress the water transfer from the middle seeds to the outer skin.
The bean paste food produced by adding the water transfer inhibitor for medium seeds of the bean paste food of the present invention to the middle seeds has suppressed water transfer from the middle seeds to the outer skin, and this is frozen and stored and then heated. Even in some cases, the original light and crispy texture, soft texture, and crispness of the outer skin can be maintained.

本発明において包餡食品とは、各種食品素材を含む中種を、澱粉質を主原料とする外皮で包み、これを加熱調理して得られる食品をいう。なお、包餡食品は、中種が外皮によって完全に覆われていることを必須とするものではなく、少なくとも調理中に中種が漏れ出さない程度に内包されていれば、部分的に外皮から中種が露出していてもよい。 In the present invention, the bean paste food refers to a food obtained by wrapping a medium species containing various food materials with an exodermis containing starch as a main raw material and cooking the exodermis. In addition, it is not essential that the bean paste food is completely covered with the exodermis, and if it is contained at least to the extent that the middle seeds do not leak during cooking, it is partially covered from the exodermis. The middle species may be exposed.

上記中種に用いられる食品素材としては、例えば、豚肉、牛肉、鶏肉等の肉類、キャベツ、白菜、ジャガイモ、ニンジン、玉ねぎ、長ねぎ、にら、たけのこ等の野菜類、シイタケ、マイタケ、キクラゲ等のきのこ類、魚肉、エビ、イカ、貝柱等の魚介類等が挙げられる。中種は、これら食品素材を生のまま混合したものであってもよく、予め茹でる、炒める等の加熱調理を行ったものであってもよい。また、必要に応じて食塩、醤油等の調味料、つなぎやとろみ付けのための小麦粉、片栗粉等を加えてもよい。 Examples of food materials used for the above-mentioned medium species include meats such as pork, beef, and chicken, vegetables such as cabbage, white vegetables, potatoes, carrots, onions, green onions, nira, and mushrooms, shiitake mushrooms, maitake mushrooms, and wood ear mushrooms. Examples include mushrooms, fish meat, shrimp, squid, and seafood such as shellfish. The medium seed may be a mixture of these food materials as they are, or may be cooked in advance by boiling, frying, or the like. In addition, if necessary, seasonings such as salt and soy sauce, wheat flour for binder and thickening, potato starch and the like may be added.

上記外皮は、澱粉質を主原料とし、中種を包むことのできるものであれば特に制限はなく、例えば、小麦粉、そば粉、米粉等の穀粉類を主原料とする麺生地やパン生地を外皮として用いることができる。また、中種の表面にパン粉や小麦粉、片栗粉等をまぶして衣付けすることにより得られる食品においては、該衣が外皮となる。 The husk is not particularly limited as long as it is made of starch as a main raw material and can wrap medium seeds. For example, noodle dough or bread dough made mainly of flour such as wheat flour, buckwheat flour, and rice flour is used as the husk. Can be used as. Further, in the food obtained by sprinkling bread crumbs, wheat flour, potato starch or the like on the surface of the middle seeds and battering, the batter becomes the exodermis.

上記加熱調理の方法に特に制限はなく、焼く、揚げる、蒸す、茹でる等いずれであってもよいが、特に中種から外皮への水分移行が問題となりやすい焼き料理、揚げ料理又は蒸し料理に使用することにより、本発明の効果を十分に発揮することができる。 The above cooking method is not particularly limited and may be any of baking, frying, steaming, boiling, etc., but is particularly used for grilled dishes, fried dishes or steamed dishes in which the transfer of water from the middle seeds to the outer skin tends to be a problem. By doing so, the effect of the present invention can be fully exerted.

包餡食品の具体的な例としては、餃子、おやき、ミートパイ、春巻き、ピロシキ、カレーパン、メンチカツ、から揚げ、チキンナゲット、白身魚フライ、コロッケ、中華まん、シュウマイ、水餃子、ワンタン等の惣菜食品が挙げられる。 Specific examples of bean paste foods include side dish foods such as dumplings, oyaki, meat pie, spring rolls, piroshki, curry bread, menchi cutlet, fried chicken, chicken nuggets, fried white fish, croquettes, Chinese steamed buns, shumai, water dumplings, and wantan. Can be mentioned.

本発明の包餡食品の中種用水分移行抑制剤(以下「本発明の水分移行抑制剤」ともいう)は、このような包餡食品の中種に添加して使用することにより、該中種から外皮への水分移行を抑制するものであって、(a)モノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを含む油脂加工澱粉と、(b)ソルビタン脂肪酸エステルとを含有することを特徴とする。 The water transfer inhibitor for medium seeds of the packaged food of the present invention (hereinafter, also referred to as "moisture transfer inhibitor of the present invention") can be added to the medium species of such packaged foods and used. It suppresses the transfer of water from the seed to the rind, and is characterized by containing (a) a fat-processed starch containing a monoglycerin fatty acid ester and / or a glycerin organic acid fatty acid ester, and (b) a sorbitan fatty acid ester. And.

本発明で用いられる(a)モノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを含む油脂加工澱粉(以下「本発明に係る油脂加工澱粉」ともいう)は、澱粉にモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを吸着させ、これを加熱して熟成したものである。 The oil-processed starch containing (a) monoglycerin fatty acid ester and / or glycerin organic acid fatty acid ester used in the present invention (hereinafter, also referred to as “oil-processed starch according to the present invention”) is a starch in which monoglycerin fatty acid ester and / or It is a product obtained by adsorbing a glycerin organic acid fatty acid ester and heating it for aging.

本発明に係る油脂加工澱粉の原料となる澱粉としては、タピオカ澱粉、コーンスターチ、馬鈴薯澱粉、小麦澱粉、米澱粉、甘藷澱粉、緑豆澱粉、サゴ澱粉、エンドウ豆澱粉、あるいはこれらの澱粉に、架橋処理を施した加工澱粉(例えば、リン酸架橋澱粉等)、アセチル化処理を施した加工澱粉、エステル化処理を施した加工澱粉(例えば、酢酸澱粉等)、エーテル化処理を施した加工澱粉(例えば、ヒドロキシプロピル澱粉等)、酸化処理を施した加工澱粉(例えば、ジアルデヒド澱粉等)、酸処理を施した加工澱粉、湿熱処理を施した加工澱粉、さらに架橋、アセチル化、エステル化、エーテル化等の処理を2以上組み合わせて施した加工澱粉等が挙げられる。これらの中でも、リン酸架橋タピオカ澱粉が好ましい。これら澱粉は、1種類のみを単独で用いてもよく、2種類以上を組み合わせて用いてもよい。 As the starch used as a raw material for the oil-processed starch according to the present invention, tapioca starch, corn starch, horse belly starch, wheat starch, rice starch, sweet potato starch, green bean starch, sago starch, pea starch, or these starches are cross-linked. Processed starch (eg, phosphoric acid crosslinked starch, etc.), acetylated processed starch, esterified processed starch (eg, acetate starch, etc.), etherified processed starch (eg, eg, etherified starch). , Hydroxypropyl starch, etc.), oxidized processed starch (eg, dialdehyde starch, etc.), acid treated processed starch, moist heat treated processed starch, further cross-linking, acetylation, esterification, etherification. Examples thereof include processed starch obtained by combining two or more of the above treatments. Of these, phosphate-crosslinked tapioca starch is preferred. Only one type of these starches may be used alone, or two or more types may be used in combination.

本発明に係る油脂加工澱粉に含まれるモノグリセリン脂肪酸エステルは、グリセリンと脂肪酸とのエステルであり、エステル化反応、エステル交換反応等自体公知の方法で製造される。該エステルは、モノエステル体(モノグリセリド)、ジエステル体(ジグリセリド)のいずれであってもよく、あるいはそれらの混合物であってもよい。 The monoglycerin fatty acid ester contained in the oil-processed starch according to the present invention is an ester of glycerin and a fatty acid, and is produced by a method known per se, such as an esterification reaction and a transesterification reaction. The ester may be either a monoester compound (monoglyceride), a diester compound (diglyceride), or a mixture thereof.

モノグリセリン脂肪酸エステルを構成する脂肪酸としては、食用可能な動植物油脂を起源とする脂肪酸であれば特に制限はなく、例えば、炭素数6〜24の直鎖状の飽和又は不飽和脂肪酸(例えば、カプロン酸、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、リグノセリン酸、オレイン酸、エライジン酸、リノール酸、リノレン酸、エルカ酸等)が挙げられる。これらの中でも、炭素数16〜18の直鎖状の飽和又は不飽和脂肪酸(例えば、パルミチン酸、ステアリン酸、オレイン酸、リノール酸、リノレン酸等)が好ましい。これら脂肪酸は、1種類のみを単独で用いてもよく、2種類以上を組み合わせて用いてもよい。 The fatty acid constituting the monoglycerin fatty acid ester is not particularly limited as long as it is a fatty acid derived from edible animal and vegetable fats and oils, and is, for example, a linear saturated or unsaturated fatty acid having 6 to 24 carbon atoms (for example, capron). Acids, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, lignoseric acid, oleic acid, elaidic acid, linoleic acid, linolenic acid, erucic acid, etc.). Among these, linear saturated or unsaturated fatty acids having 16 to 18 carbon atoms (for example, palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, etc.) are preferable. Only one type of these fatty acids may be used alone, or two or more types may be used in combination.

モノグリセリン脂肪酸エステルとしては、ポエムOL−200V(商品名;モノグリセリンオレイン酸エステル;理研ビタミン社製)、エマルジーOL−100H(商品名;モノグリセリンオレイン酸エステル;理研ビタミン社製)等が商業的に販売されており、本発明ではこれらを用いることができる。 Commercially available monoglycerin fatty acid esters include Poem OL-200V (trade name; monoglycerin oleic acid ester; manufactured by RIKEN Vitamin) and Emargy OL-100H (trade name; monoglycerin oleic acid ester; manufactured by RIKEN Vitamin). They are sold in the present invention, and these can be used in the present invention.

本発明に係る油脂加工澱粉に含まれるグリセリン有機酸脂肪酸エステルは、グリセリン、有機酸及び脂肪酸のエステルであり、モノグリセリンモノ脂肪酸エステルと有機酸(又は有機酸の酸無水物)との反応、又はグリセリンと有機酸と脂肪酸との反応により製造される。グリセリン有機酸脂肪酸エステルの種類としては、例えば、グリセリン酢酸脂肪酸エステル、グリセリン乳酸脂肪酸エステル、グリセリンクエン酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステル、グリセリンジアセチル酒石酸脂肪酸エステル等が挙げられる。これらの中でも、グリセリンジアセチル酒石酸脂肪酸エステルが好ましい。これらグリセリン有機酸脂肪酸エステルは、1種類のみを単独で用いてもよく、2種類以上を組み合わせて用いてもよい。 The glycerin organic acid fatty acid ester contained in the oil-processed starch according to the present invention is an ester of glycerin, an organic acid and a fatty acid, and is a reaction between the monoglycerin monofatty acid ester and an organic acid (or an acid anhydride of the organic acid), or It is produced by the reaction of glycerin, organic acids and fatty acids. Examples of the type of glycerin organic acid fatty acid ester include glycerin acetic acid fatty acid ester, glycerin lactic acid fatty acid ester, glycerin cinic acid fatty acid ester, glycerin succinic acid fatty acid ester, and glycerin diacetyl tartrate fatty acid ester. Among these, glycerin diacetyl tartrate fatty acid ester is preferable. Only one type of these glycerin organic acid fatty acid esters may be used alone, or two or more types may be used in combination.

グリセリン有機酸脂肪酸エステルを構成する脂肪酸としては、食用可能な動植物油脂を起源とする脂肪酸であれば特に制限はなく、例えば、炭素数6〜24の直鎖状の飽和又は不飽和脂肪酸(例えば、カプロン酸、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、リグノセリン酸、オレイン酸、エライジン酸、リノール酸、リノレン酸、エルカ酸等)が挙げられる。これらの中でも、好ましくは炭素数16〜18の直鎖状の飽和又は不飽和脂肪酸(例えば、パルミチン酸、ステアリン酸、オレイン酸、リノール酸、リノレン酸等)が好ましい。これら脂肪酸は、1種類のみを単独で用いてもよく、2種類以上を組み合わせて用いてもよい。 The fatty acid constituting the glycerin organic acid fatty acid ester is not particularly limited as long as it is a fatty acid derived from edible animal and vegetable fats and oils, and is, for example, a linear saturated or unsaturated fatty acid having 6 to 24 carbon atoms (for example, Caproic acid, capric acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, bechenic acid, lignoseric acid, oleic acid, elaidic acid, linoleic acid, linolenic acid, erucic acid, etc.). Among these, linear saturated or unsaturated fatty acids having 16 to 18 carbon atoms (for example, palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, etc.) are preferable. Only one type of these fatty acids may be used alone, or two or more types may be used in combination.

グリセリン有機酸脂肪酸エステルとしては、ポエムW−10(商品名;理研ビタミン社製、グリセリンジアセチル酒石酸脂肪酸エステル)、ポエムB−10(商品名;理研ビタミン社製、グリセリンコハク酸脂肪酸エステル)、ポエムK−30(商品名;理研ビタミン社製、グリセリンクエン酸脂肪酸エステル)等が商業的に販売されており、本発明ではこれらを用いることができる。 Examples of the glycerin organic acid fatty acid ester include Poem W-10 (trade name; glycerin diacetyl tartrate fatty acid ester manufactured by RIKEN Vitamin), Poem B-10 (trade name; glycerin succinic acid fatty acid ester manufactured by RIKEN Vitamin), and Poem K. -30 (trade name; manufactured by Riken Vitamin Co., Ltd., glycerin acid fatty acid ester) and the like are commercially available, and these can be used in the present invention.

澱粉に対するモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルの添加量は、澱粉100質量部に対して、例えば、0.0012〜8質量部、好ましくは0.02〜2質量部、より好ましくは0.04〜0.8質量部である。 The amount of the monoglycerin fatty acid ester and / or the glycerin organic acid fatty acid ester added to the starch is, for example, 0.0012 to 8 parts by mass, preferably 0.02 to 2 parts by mass, more preferably 0.02 to 2 parts by mass with respect to 100 parts by mass of the starch. It is 0.04 to 0.8 parts by mass.

澱粉にモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを吸着させる方法は、澱粉粒が破壊されない状態で澱粉の表面にモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを均一に吸着させる方法であれば特に制限はなく、例えば、澱粉にモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを添加し、公知の混合装置等を用いて均一に混合すればよい。混合装置としては、例えば、リボンミキサー、ナウターミキサー、ヘンシェルミキサー、レーディゲミキサー、V型混合機等を用いることができる。 The method of adsorbing the monoglycerin fatty acid ester and / or the glycerin organic acid fatty acid ester on the starch is a method of uniformly adsorbing the monoglycerin fatty acid ester and / or the glycerin organic acid fatty acid ester on the surface of the starch without destroying the starch granules. If there is no particular limitation, for example, a monoglycerin fatty acid ester and / or a glycerin organic acid fatty acid ester may be added to the starch and mixed uniformly using a known mixing device or the like. As the mixing device, for example, a ribbon mixer, a Nauter mixer, a Henschel mixer, a Reedige mixer, a V-type mixer and the like can be used.

モノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを吸着させた澱粉は、その後乾燥して粉末化することが好ましい。乾燥及び粉末化する方法としては、例えば、水分含有量50質量%程度に調湿した澱粉のケーキにモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを添加して吸着させた後、棚段式通風乾燥機等を用いて乾燥し、粉末化する方法、水分含有量60〜70質量%に調湿したスラリー状の澱粉にモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを添加して吸着させた後、噴霧乾燥機又はドラムドライヤー等を用いて乾燥し、粉末化する方法等を実施することができる。
また、吸着と乾燥及び粉末化処理を同時に行ってもよく、そのような方法としては、例えば、平衡水分を保った澱粉若しくは水分含有量を20〜40質量%に調整した澱粉を流動層乾燥機中で流動状態とし、そこにモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを噴霧して該澱粉に吸着させながら、乾燥及び粉末化する方法を実施することができる。
It is preferable that the starch on which the monoglycerin fatty acid ester and / or the glycerin organic acid fatty acid ester is adsorbed is then dried and pulverized. As a method of drying and pulverizing, for example, a monoglycerin fatty acid ester and / or a glycerin organic acid fatty acid ester is added to a cake of starch whose humidity is adjusted to about 50% by mass and adsorbed, and then a shelf type is used. A method of drying and pulverizing using a ventilation dryer or the like. Monoglycerin fatty acid ester and / or glycerin organic acid fatty acid ester is added to a slurry-like starch adjusted to a water content of 60 to 70% by mass and adsorbed. After that, a method of drying and pulverizing using a spray dryer, a drum dryer, or the like can be carried out.
Further, adsorption, drying and pulverization may be carried out at the same time. As such a method, for example, starch having equilibrium moisture or starch having a moisture content adjusted to 20 to 40% by mass is used in a fluidized layer dryer. A method can be carried out in which a monoglycerin fatty acid ester and / or a glycerin organic acid fatty acid ester is sprayed into a fluid state and dried and powdered while being adsorbed on the starch.

モノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを吸着させた澱粉は、さらに一定時間加熱して熟成される。なお、上記乾燥処理が加熱を伴う場合は、該乾燥処理をそのまま延長・継続して熟成してもよい。熟成温度は、例えば、棚段式通風乾燥機を用いて熟成する場合、30〜180℃、好ましくは30〜140℃である。熟成温度が高い方が短時間で熟成することができるが、120℃以上で熟成する場合には、澱粉がデキストリン化しないよう注意が必要である。熟成に要する時間は、澱粉に対するモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルの吸着量、熟成温度、熟成装置の熱効率等により異なるが、例えば、水分含有量35質量%に調湿したコーンスターチにモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを0.25質量部添加して混合し、室温で20時間乾燥した澱粉では、60℃で5時間程度、あるいは140℃で1時間程度である。なお、所望によりさらに数日〜数週間に亘って熟成を行ってもよい。 The starch on which the monoglycerin fatty acid ester and / or the glycerin organic acid fatty acid ester is adsorbed is further heated for a certain period of time to be aged. When the drying treatment involves heating, the drying treatment may be extended and continuously aged as it is. The aging temperature is, for example, 30 to 180 ° C., preferably 30 to 140 ° C. when aging using a shelf-type ventilation dryer. The higher the aging temperature, the shorter the aging time, but when aging at 120 ° C or higher, care must be taken to prevent the starch from becoming dextrin. The time required for aging varies depending on the amount of monoglycerin fatty acid ester and / or glycerin organic acid fatty acid ester adsorbed on starch, aging temperature, thermal efficiency of the aging apparatus, etc., but for example, for corn starch adjusted to a water content of 35% by mass. For starch in which 0.25 parts by mass of monoglycerin fatty acid ester and / or glycerin organic acid fatty acid ester is added and mixed and dried at room temperature for 20 hours, it is about 5 hours at 60 ° C. or about 1 hour at 140 ° C. If desired, aging may be carried out for several days to several weeks.

熟成終了後、得られた油脂加工澱粉は、水分含有量8〜18質量%、好ましくは10〜14質量%に調湿することが望ましい。 After completion of aging, it is desirable that the obtained modified starch is adjusted to a water content of 8 to 18% by mass, preferably 10 to 14% by mass.

なお、上記澱粉にモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸エステルを吸着させる際、モノグリセリン脂肪酸エステル及び/又はグリセリン有機酸エステルに対して油脂を配合してもよい。即ち、予めモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステル並びに油脂を混合し、必要であれば加熱・溶融して調製した油脂組成物を澱粉に添加して吸着させることができる。このようにすることで、モノグリセリン脂肪酸エステル及び/又はグリセリン有機酸エステルに適度な流動性が付与され、澱粉に対して均一に吸着させやすくなる。 When adsorbing the monoglycerin fatty acid ester and / or the glycerin organic acid ester on the starch, the fat and oil may be mixed with the monoglycerin fatty acid ester and / or the glycerin organic acid ester. That is, a fat or oil composition prepared by mixing a monoglycerin fatty acid ester and / or a glycerin organic acid fatty acid ester and a fat or oil in advance and heating and melting the fat or oil, if necessary, can be added to the starch for adsorption. By doing so, appropriate fluidity is imparted to the monoglycerin fatty acid ester and / or the glycerin organic acid ester, and it becomes easy to uniformly adsorb them to starch.

油脂としては、食用可能な油脂であれば特に制限はなく、例えば、サフラワー油、大豆油、菜種油、綿実油、ヒマワリ油、米糠油、コーン油、椰子油、パーム油、パーム核油、カポック油、落花生油、オリーブ油、ハイオレイック菜種油、ハイオレイックサフラワー油、ハイオレイックコーン油及びハイオレイックヒマワリ油等の植物油脂、牛脂、ラード、魚油及び乳脂等の動物油脂、さらにこれら動植物油脂を分別、水素添加又はエステル交換したもの、並びに中鎖脂肪酸トリグリセリド(MCT)等が挙げられる他、プロピレングリコールジ脂肪酸エステルもこれらに含まれる。これらの中でも、サフラワー油、大豆油、ヒマワリ油又はコーン油が好ましい。また、上記油脂の一部又は全部の代替品として油分を多く含む穀粉、例えば、生大豆粉等を用いてもよい。 The fats and oils are not particularly limited as long as they are edible fats and oils. For example, safflower oil, soybean oil, rapeseed oil, cotton seed oil, sunflower oil, rice bran oil, corn oil, coconut oil, palm oil, palm kernel oil, and capoc oil. , Vegetable oils such as peanut oil, olive oil, high oleic rapeseed oil, high oleic safflower oil, high oleic corn oil and high oleic sunflower oil, animal fats and oils such as beef fat, lard, fish oil and milk fat, and these animal and vegetable fats and oils are separated. , Hydrogenated or ester-exchanged, medium chain fatty acid triglyceride (MCT) and the like, and propylene glycol difatty acid ester is also included in these. Among these, safflower oil, soybean oil, sunflower oil or corn oil are preferable. Further, as a substitute for a part or all of the above fats and oils, a flour containing a large amount of oil, for example, raw soybean flour may be used.

上記油脂組成物中のモノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルと油脂との割合(モノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステル:油脂)としては、1:99〜99:1(質量比)の範囲を示すことができ、好ましくは40:60〜80:20(質量比)の範囲である。 The ratio of the monoglycerin fatty acid ester and / or the glycerin organic acid fatty acid ester to the fat and oil (monoglycerin fatty acid ester and / or the glycerin organic acid fatty acid ester: fat and oil) in the fat and oil composition is 1: 99 to 99: 1 ( The range of (mass ratio) can be shown, preferably in the range of 40:60 to 80:20 (mass ratio).

澱粉に対する上記油脂組成物の添加量は、澱粉100質量部に対して0.003〜10質量部、好ましくは0.05〜5.0質量部、より好ましくは0.1〜1.0質量部である。 The amount of the fat and oil composition added to the starch is 0.003 to 10 parts by mass, preferably 0.05 to 5.0 parts by mass, and more preferably 0.1 to 1.0 part by mass with respect to 100 parts by mass of the starch. Is.

この他、本発明に係る油脂加工澱粉は、本発明の目的を阻害しない範囲で、他の任意の成分を含んでいてもよい。そのような成分としては、例えば、モノグリセリン脂肪酸エステル及びグリセリン有機酸脂肪酸エステル以外の食品用乳化剤、酸化防止剤等が挙げられる。
モノグリセリン脂肪酸エステル及びグリセリン有機酸脂肪酸エステル以外の食品用乳化剤としては、例えば、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、レシチン等が挙げられる。ここで、レシチンには、分別レシチン、酵素分解レシチン、酵素処理レシチン等が含まれる。
酸化防止剤としては、例えば、トコフェロール、アスコルビン酸パルミチン酸エステル、茶抽出物等が挙げられる。
In addition, the modified starch according to the present invention may contain any other component as long as the object of the present invention is not impaired. Examples of such a component include food emulsifiers and antioxidants other than monoglycerin fatty acid ester and glycerin organic acid fatty acid ester.
Examples of food emulsifiers other than monoglycerin fatty acid ester and glycerin organic acid fatty acid ester include polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, and lecithin. Here, lecithin includes fractionated lecithin, enzymatically decomposed lecithin, enzyme-treated lecithin and the like.
Examples of the antioxidant include tocopherol, ascorbic acid palmitic acid ester, tea extract and the like.

なお、本発明に係る油脂加工澱粉としては、モノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを含む油脂加工澱粉として市販されているものを用いてもよい。例えば、モノグリセリン脂肪酸エステルを含む油脂加工澱粉としては、日食バッタースターチ#200(商品名;日本食品化工社製)、日食ねりこみ澱粉IPYF(商品名;日本食品化工社製)等が商業的に販売されており、本発明ではこれらを用いることができる。 As the modified starch according to the present invention, a commercially available modified starch containing a monoglycerin fatty acid ester and / or a glycerin organic acid fatty acid ester may be used. For example, as oil-processed starch containing monoglycerin fatty acid ester, eclipse batter starch # 200 (trade name; manufactured by Nihon Shokuhin Kako Co., Ltd.), eclipse eclipse starch IPYF (trade name; manufactured by Nihon Shokuhin Kako Co., Ltd.), etc. are commercially available. These are used in the present invention.

本発明の水分移行抑制剤中の本発明に係る油脂加工澱粉の含有量に特に制限はないが、該水分移行抑制剤100質量%、好ましくは50〜99.9質量%、より好ましくは65〜99.8質量%である。 The content of the modified starch according to the present invention in the water transfer inhibitor of the present invention is not particularly limited, but the water transfer inhibitor is 100% by mass, preferably 50 to 99.9% by mass, more preferably 65 to 65. It is 99.8% by mass.

本発明で用いられる(b)ソルビタン脂肪酸エステルとは、ソルビタン又はソルビトールと脂肪酸のエステルであり、エステル化反応、エステル交換反応等自体公知の方法により製造される。該エステルは、モノエステル体、ジエステル体、トリエステル体等のいずれであってもよく、あるいはそれらの混合物であってもよい。 The (b) sorbitan fatty acid ester used in the present invention is an ester of sorbitan or sorbitol and a fatty acid, and is produced by a method known per se such as an esterification reaction and a transesterification reaction. The ester may be any of a monoester, a diester, a triester, etc., or a mixture thereof.

ソルビタン脂肪酸エステルを構成する脂肪酸としては、食用可能な動植物油脂を起源とする脂肪酸であれば特に制限はなく、例えば、炭素数6〜24の直鎖状の飽和又は不飽和脂肪酸(例えば、カプロン酸、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、リグノセリン酸、オレイン酸、エライジン酸、リノール酸、リノレン酸、エルカ酸等)が挙げられる。これらの中でも、炭素数18〜22の直鎖状の飽和又は不飽和脂肪酸(例えば、ステアリン酸、ベヘン酸、オレイン酸等)が好ましく、とりわけオレイン酸が好ましい。これら脂肪酸は、1種類のみを単独で用いてもよく、2種類以上を組み合わせて用いてもよい。 The fatty acid constituting the sorbitan fatty acid ester is not particularly limited as long as it is a fatty acid derived from edible animal and vegetable fats and oils, and is, for example, a linear saturated or unsaturated fatty acid having 6 to 24 carbon atoms (for example, caprylic acid). , Caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, lignoseric acid, oleic acid, elaidic acid, linoleic acid, linolenic acid, erucic acid, etc.). Among these, linear saturated or unsaturated fatty acids having 18 to 22 carbon atoms (for example, stearic acid, behenic acid, oleic acid, etc.) are preferable, and oleic acid is particularly preferable. Only one type of these fatty acids may be used alone, or two or more types may be used in combination.

ソルビタン脂肪酸エステルとしては、ポエムS−65V(商品名;ソルビタントリステアリン酸エステル;理研ビタミン社製)、ポエムS−60V(商品名;ソルビタンモノステアリン酸エステル;理研ビタミン社製)、ポエムO−80V(商品名;ソルビタンモノオレイン酸エステル;理研ビタミン社製)等が商業的に販売されており、本発明ではこれらを用いることができる。 Examples of the sorbitan fatty acid ester include Poem S-65V (trade name; sorbitan tristearic acid ester; manufactured by RIKEN Vitamin), Poem S-60V (trade name; sorbitan monostearic acid ester; manufactured by RIKEN Vitamin), and Poem O-80V. (Product name; sorbitan monooleic acid ester; manufactured by RIKEN Vitamin Co., Ltd.) and the like are commercially available, and these can be used in the present invention.

本発明の水分移行抑制剤中のソルビタン脂肪酸エステルの含有量に特に制限はないが、該水分移行抑制剤100質量%中、好ましくは0.01〜30質量%、より好ましくは0.1〜25質量%である。 The content of the sorbitan fatty acid ester in the water transfer inhibitor of the present invention is not particularly limited, but is preferably 0.01 to 30% by mass, more preferably 0.1 to 25% of 100% by mass of the water transfer inhibitor. It is mass%.

また、本発明の水分移行抑制剤は、上記本発明に係る油脂加工澱粉、ソルビタン脂肪酸エステルに加え、本発明の目的を阻害しない範囲で、他の任意の成分を含んでいてもよい。そのような成分としては、例えば、ソルビタン脂肪酸エステル以外の食品用乳化剤、増粘安定剤、糖類、調味料、風味原料、香辛料、蛋白質(大豆タンパク、卵白粉末等)、粉質改良剤(炭酸Ca、第三リン酸Ca、微粒二酸化ケイ素等)、pH調整剤等が挙げられる。
ソルビタン脂肪酸エステル以外の食品用乳化剤としては、例えば、モノグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、レシチン等が挙げられる。ここで、レシチンには、分別レシチン、酵素分解レシチン、酵素処理レシチン等が含まれる。
増粘粘安定剤としては、キサンタンガム、グア−ガム、タラガム、タマリンドシードガム、カラギーナン、サイリウムシードガム、ジェランガム、プルラン等が挙げられる。
In addition to the modified starch and sorbitan fatty acid ester according to the present invention, the water transfer inhibitor of the present invention may contain any other components as long as the object of the present invention is not impaired. Examples of such components include food emulsifiers other than sorbitan fatty acid esters, thickening stabilizers, sugars, seasonings, flavor raw materials, spices, proteins (soy protein, egg white powder, etc.), and powder quality improvers (Ca carbonate). , Tertiary phosphate Ca, fine silicon dioxide, etc.), pH adjuster, etc.
Examples of food emulsifiers other than sorbitan fatty acid ester include monoglycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, propylene glycol fatty acid ester, lecithin and the like. Here, lecithin includes fractionated lecithin, enzymatically decomposed lecithin, enzyme-treated lecithin and the like.
Examples of the thickening and viscous stabilizer include xanthan gum, guar gum, tara gum, tamarind seed gum, carrageenan, psyllium seed gum, gellan gum, pullulan and the like.

本発明の水分移行抑制剤の製造方法に特に制限はなく、例えば、本発明に係る油脂加工澱粉とソルビタン脂肪酸エステルに、所望により他の任意の成分を加えて均一に混合すればよい。混合には、例えば、リボンミキサー、ナウターミキサー、ヘンシェルミキサー、レーディゲミキサー、V型混合機等の公知の混合装置を用いることができる。なお、ソルビタン脂肪酸エステルは、予め60℃以上に加熱・溶融してから混合してもよい。 The method for producing the water transfer inhibitor of the present invention is not particularly limited, and for example, any other component may be added to the modified starch and sorbitan fatty acid ester according to the present invention and uniformly mixed. For mixing, for example, a known mixing device such as a ribbon mixer, a Nauter mixer, a Henschel mixer, a Laedige mixer, or a V-type mixer can be used. The sorbitan fatty acid ester may be mixed after being heated and melted at 60 ° C. or higher in advance.

本発明の水分移行抑制剤を使用して包餡食品の中種を製造する方法に特に制限はなく、包餡食品の中種を製造する際の任意の工程において、原材料に本発明の水分移行抑制剤を添加すればよい。具体的には、中種の原材料に対して本発明の水分移行抑制剤を粉末のまま添加して混合する方法、あるいは予め本発明の水分移行抑制剤を調味液等に溶解し、タンブリング処理や浸漬処理等により該調味液等を中種になじませて添加する方法等を実施することができる。また、本発明の水分移行抑制剤を添加した中種を使用して包餡食品を製造する方法にも特に制限はなく、常法に従って製造することができる。 There is no particular limitation on the method for producing the medium seeds of the bean paste food using the water transfer inhibitor of the present invention, and the water transfer of the present invention to the raw material in any step when producing the medium seeds of the bean paste food. An inhibitor may be added. Specifically, a method of adding the moisture transfer inhibitor of the present invention as a powder to a medium-sized raw material and mixing it, or a method of dissolving the moisture transfer inhibitor of the present invention in a seasoning liquid or the like in advance and tumbling treatment or the like. It is possible to carry out a method or the like in which the seasoning liquid or the like is blended with the medium seeds and added by a dipping treatment or the like. Further, there is no particular limitation on the method for producing the bean paste food using the medium seed to which the water transfer inhibitor of the present invention is added, and the food can be produced according to a conventional method.

本発明の水分移行抑制剤の包餡食品の中種に対する添加量は、包餡食品の種類や中種の配合、中種や外皮の水分含有量等により異なるが、該中種100質量部中、好ましくは0.05〜5質量部、より好ましくは0.1〜1質量部である。 The amount of the water transfer inhibitor added to the medium type of the bean paste food varies depending on the type of the bean paste food, the composition of the medium type, the water content of the medium type and the outer skin, etc., but in 100 parts by mass of the medium type. , It is preferably 0.05 to 5 parts by mass, and more preferably 0.1 to 1 part by mass.

本発明の水分移行抑制剤を中種に添加して製造した包餡食品は、保存中や調理中における中種からの水分の流出が少なくなり、外皮への水分移行が抑制されるため、外皮が水を吸ってべたつく、外皮がふやけて軟化する、水を吸って厚みを増した外皮が加熱されることにより硬化するといった弊害が生じにくい。従って、例えば、該包餡食品を冷凍保存した後に加熱した場合であっても、外皮本来の軽くクリスピーな食感やソフトな食感、歯切れのよさを維持することができる。
また、中種から外皮への水分移行が生じると、中種が水分を失ってパサついたり、収縮して硬くなったりすることがあるが、本発明の水分移行抑制剤を添加した場合、中種が多くの水分を保持できるため、柔らかく、ジューシーなものとなる。
このように、本発明の水分移行抑制剤を中種に添加することにより、包餡食品の総合的な食味の改良が期待できる。
The packaged food produced by adding the water transfer inhibitor of the present invention to the middle seeds reduces the outflow of water from the middle seeds during storage and cooking, and suppresses the water transfer to the exodermis. Is less likely to cause adverse effects such as stickiness by absorbing water, softening of the exodermis by absorbing water, and hardening by heating the exodermis that has increased in thickness by absorbing water. Therefore, for example, even when the bean paste food is frozen and stored and then heated, the original light and crispy texture, soft texture, and crispness of the exodermis can be maintained.
In addition, when water transfer from the middle seed to the outer skin occurs, the middle seed may lose water and become dry or shrink and become hard. However, when the water transfer inhibitor of the present invention is added, the middle seed is medium. The seeds can retain a lot of water, making them soft and juicy.
As described above, by adding the water transfer inhibitor of the present invention to the middle seeds, it is expected that the overall taste of the bean paste food will be improved.

以下、実施例をもって本発明を具体的に説明するが、本発明はこれらに限定されるものではない。 Hereinafter, the present invention will be specifically described with reference to Examples, but the present invention is not limited thereto.

[油脂加工澱粉の製造]
<製造例1>
モノグリセリン脂肪酸エステル(商品名:ポエムOL−200V;理研ビタミン社製)及びサフラワー油を質量比1:1で混合し、60℃に加熱・溶融して油脂組成物を得た。水分含有量約50質量%に調湿したリン酸架橋タピオカ澱粉(商品名:ネオビスT−100;日本食品化工社製)100質量部に対して上記油脂組成物0.5質量部を添加し、高速攪拌混合機(型式:レーディゲミキサーFM130D;松坂技研社製)で10分間混合した。得られた混合物をトレーに広げて機内温度約60℃の棚段式通風乾燥機で水分含有量約12.0質量%まで乾燥し、乾燥物を粉砕して粉末化した。得られた粉末をポリエチレン製の袋に詰めて約60℃で2週間熟成し、油脂加工澱粉1を得た。
[Manufacturing of modified starch]
<Manufacturing example 1>
Monoglycerin fatty acid ester (trade name: Poem OL-200V; manufactured by RIKEN Vitamin Co., Ltd.) and safflower oil were mixed at a mass ratio of 1: 1 and heated and melted at 60 ° C. to obtain an oil and fat composition. 0.5 parts by mass of the above fat and oil composition was added to 100 parts by mass of phosphoric acid-crosslinked tapioca starch (trade name: Neobis T-100; manufactured by Nihon Shokuhin Kako Co., Ltd.) adjusted to a water content of about 50% by mass. The mixture was mixed for 10 minutes with a high-speed stirring mixer (model: Ladyge mixer FM130D; manufactured by Matsuzaka Giken Co., Ltd.). The obtained mixture was spread on a tray and dried in a shelf-type ventilation dryer having an internal temperature of about 60 ° C. to a water content of about 12.0% by mass, and the dried product was crushed and pulverized. The obtained powder was packed in a polyethylene bag and aged at about 60 ° C. for 2 weeks to obtain a modified starch 1.

<製造例2>
モノグリセリン脂肪酸エステルをグリセリンコハク酸脂肪酸エステル(商品名:ポエムB−10;理研ビタミン社製)に替えた以外は上記製造例1と同様に操作し、油脂加工澱粉2を得た。
<Manufacturing example 2>
The operation was carried out in the same manner as in Production Example 1 above except that the monoglycerin fatty acid ester was replaced with a glycerin succinic acid fatty acid ester (trade name: Poem B-10; manufactured by RIKEN Vitamin Co., Ltd.) to obtain a modified starch 2.

<製造例3>
モノグリセリン脂肪酸エステルをグリセリンジアセチル酒石酸脂肪酸エステル(商品名:ポエムW−10;理研ビタミン社製)に替えた以外は上記製造例1と同様に操作し、油脂加工澱粉3を得た。
<Manufacturing example 3>
The operation was carried out in the same manner as in Production Example 1 above except that the monoglycerin fatty acid ester was replaced with a glycerin diacetyl tartrate fatty acid ester (trade name: Poem W-10; manufactured by RIKEN Vitamin) to obtain a modified starch 3.

<製造例4>
モノグリセリン脂肪酸エステルの半量をグリセリンジアセチル酒石酸脂肪酸エステル(商品名:ポエムW−10;理研ビタミン社製)に替えた以外は上記製造例1と同様に操作し、油脂加工澱粉4を得た。
<Manufacturing example 4>
A modified starch 4 was obtained in the same manner as in Production Example 1 above, except that half of the monoglycerin fatty acid ester was replaced with a glycerin diacetyl tartrate fatty acid ester (trade name: Poem W-10; manufactured by RIKEN Vitamin).

<製造例5>
モノグリセリン脂肪酸エステル及びサフラワー油を含む油脂組成物をサフラワー油に替えた以外は上記製造例1と同様に操作し、油脂加工澱粉5を得た。
<Manufacturing example 5>
The operation was carried out in the same manner as in Production Example 1 above except that the fat and oil composition containing the monoglycerin fatty acid ester and safflower oil was replaced with safflower oil to obtain a fat and oil modified starch 5.

[水分移行抑制剤の調製]
(1)原材料
1)油脂加工澱粉1〜5
2)リン酸架橋タピオカ澱粉(商品名:ネオビスT−100;日本食品化工社製)
3)ソルビタンステアリン酸エステル(商品名:ポエムS−65V;理研ビタミン社製)
4)ソルビタンオレイン酸エステル(商品名:ポエムO−80V;理研ビタミン社製)
5)ジグリセリンオレイン酸エステル(商品名:ポエムDO−100V;理研ビタミン社製)
[Preparation of water transfer inhibitor]
(1) Raw materials 1) Oil-processed starch 1-5
2) Phosphate cross-linked tapioca starch (trade name: Neobis T-100; manufactured by Nihon Shokuhin Kako Co., Ltd.)
3) Sorbitan stearic acid ester (trade name: Poem S-65V; manufactured by RIKEN Vitamin Co., Ltd.)
4) Sorbitan oleate (trade name: Poem O-80V; manufactured by RIKEN Vitamin Co., Ltd.)
5) Diglycerin oleate (trade name: Poem DO-100V; manufactured by RIKEN Vitamin Co., Ltd.)

(2)水分移行抑制剤の配合
上記原材料を用いて調製した水分移行抑制剤1〜10の配合組成を表1に示した。これらの内、水分移行抑制剤1〜5は本発明の実施例であり、水分移行抑制剤6〜10はこれらに対する比較例である。なお、各水分移行抑制剤は、原材料の合計が200gとなる分量で調製した。
(2) Formulation of Moisture Transfer Inhibitors Table 1 shows the composition of the moisture transfer inhibitors 1 to 10 prepared using the above raw materials. Of these, the water transfer inhibitors 1 to 5 are examples of the present invention, and the water transfer inhibitors 6 to 10 are comparative examples. Each water transfer inhibitor was prepared in an amount such that the total amount of the raw materials was 200 g.

Figure 0006779714
Figure 0006779714

(3)水分移行抑制剤の調製方法
表1に示した配合割合に従って原材料を所定量ずつフードプロセッサー(型式:MK−K48P;パナソニック社製)に投入し、該フードプロセッサーで2分間混合して、水分移行抑制剤1〜8を得た。なお、水分移行抑制剤9及び10は、油脂加工澱粉又はソルビタン脂肪酸エステルのみをそのまま水分移行抑制剤として使用する比較例のため、上記混合処理は行っていない。
(3) Preparation method of water transfer inhibitor A predetermined amount of the raw material is added to a food processor (model: MK-K48P; manufactured by Panasonic Corporation) according to the blending ratio shown in Table 1, and the mixture is mixed in the food processor for 2 minutes. Moisture transfer inhibitors 1 to 8 were obtained. Since the water transfer inhibitors 9 and 10 are comparative examples in which only the modified starch or sorbitan fatty acid ester is used as it is as the water transfer inhibitor, the above mixing treatment is not performed.

[餃子による評価]
(1)餃子の製造方法
1)鶏ムネ肉360g、豚ウデ肉360g、豚脂780gをまとめて挽き目6mmでチョッピングし、挽き肉1500gを得た。
2)キャベツ3000g、玉ねぎ480g、長ねぎ240g、にら180gをみじん切りし、みじん切り野菜3900gを得た。
3)粒状大豆たん白(商品名:フジニックエース100;不二製油社製)6gに水を12g加え、水戻し粒状大豆たん白18gを得た。
4)挽き肉100g、食塩2.4g、黒コショウ2.4g、グルタミン酸ナトリウム1.2g及び水分移行抑制剤1〜10のいずれか1.2gを卓上ミキサー(型式:KSM150WH;エフ・エム・アイ社製)に投入し、該ミキサーで2分間混合した。
5)上記4)で得た混合物に、みじん切り野菜260g、醤油12g、水戻し粒状大豆たん白18g、菜種油4gを加え、さらに該ミキサーで1分間混合して餃子の中種1〜10を得た。
6)得られた餃子の中種1〜10を、1個あたり12gずつ市販の餃子の皮(商品名:餃子の皮;モランボン社製)に包み、餃子1〜10を各12個得た。
7)対照として、水分移行抑制剤を添加しない以外は同様にして、餃子11を得た。
8)得られた餃子1〜11を、急速凍結庫(庫内温度約−35℃)で30分凍結した後、袋に入れて−20℃で7日間冷凍保存した。
[Evaluation by dumplings]
(1) Method for producing dumplings 1) 360 g of chicken breast meat, 360 g of pork meat, and 780 g of lard were collectively chopped with a minced meat of 6 mm to obtain 1500 g of minced meat.
2) 3000 g of cabbage, 480 g of onion, 240 g of long onion and 180 g of leek were chopped to obtain 3900 g of chopped vegetables.
3) 12 g of water was added to 6 g of granular soybean protein (trade name: Fujinic Ace 100; manufactured by Fuji Oil Co., Ltd.) to obtain 18 g of water-rehydrated granular soybean protein.
4) 100 g of minced meat, 2.4 g of salt, 2.4 g of black pepper, 1.2 g of monosodium glutamate, and 1.2 g of any of the water transfer inhibitors 1 to 10 are mixed with a desktop mixer (model: KSM150WH; manufactured by FMI). ), And mixed with the mixer for 2 minutes.
5) To the mixture obtained in 4) above, 260 g of chopped vegetables, 12 g of soy sauce, 18 g of water-rehydrated granular soybean protein, and 4 g of rapeseed oil were added and further mixed for 1 minute with the mixer to obtain medium-sized dumplings 1-10. ..
6) 12 g of each of the obtained gyoza seeds 1 to 10 was wrapped in commercially available gyoza skin (trade name: gyoza skin; manufactured by Moranborg Co., Ltd.) to obtain 12 gyoza 1 to 10 each.
7) As a control, dumplings 11 were obtained in the same manner except that a water transfer inhibitor was not added.
8) The obtained dumplings 1 to 11 were frozen in a quick freezer (inside temperature of about −35 ° C.) for 30 minutes, placed in a bag, and stored frozen at −20 ° C. for 7 days.

(2)歯切れのよさの評価
冷凍保存後、餃子1〜11をそれぞれフライパンに12個並べて水80gを入れ、IHヒーター(型式:KIH−1400/R;小泉成器社製)を使用して中火で6.5分加熱し、焼成した。焼成後、各餃子の皮の歯切れのよさについて官能評価を行った。評価は表2に示す評価基準に従って10名のパネラーで行い、結果は10名の評点の平均値を下記の基準に従って記号化した。結果を表3に示す。
〔基準〕
◎:極めて良好 平均値4.0以上
○:良好 平均値3.0以上、4.0未満
△:やや悪い 平均値2.0以上、3.0未満
×:悪い 平均値2.0未満
(2) Evaluation of crispness After freezing and storing, 12 dumplings 1 to 11 are placed in a frying pan, 80 g of water is added, and an IH heater (model: KIH-1400 / R; manufactured by Koizumi Seiki Co., Ltd.) is used. It was heated on fire for 6.5 minutes and baked. After firing, a sensory evaluation was performed on the crispness of the skin of each dumpling. The evaluation was performed by 10 panelists according to the evaluation criteria shown in Table 2, and the results were symbolized by the average value of the scores of 10 persons according to the following criteria. The results are shown in Table 3.
[Criteria]
⊚: Very good average value 4.0 or more ○: Good average value 3.0 or more and less than 4.0 Δ: Slightly bad average value 2.0 or more and less than 3.0 ×: Bad average value less than 2.0

Figure 0006779714
Figure 0006779714

Figure 0006779714
Figure 0006779714

表3の結果から明らかなように、本発明の実施例である水分移行抑制剤1〜5を中種に添加した餃子1〜5は、いずれも皮の歯切れが良好であった。一方、比較例の餃子6〜10は、水分移行抑制剤無添加の餃子11と同等か、それよりも劣る結果となった。 As is clear from the results in Table 3, all of the dumplings 1 to 5 to which the water transfer inhibitors 1 to 5 added to the middle seeds, which are the examples of the present invention, had good crispness of the skin. On the other hand, the dumplings 6 to 10 of the comparative example were equal to or inferior to the dumplings 11 to which the water transfer inhibitor was not added.

(3)餃子の重量測定
中種から皮への水分移行の程度をより定量的に測定するため、上記官能評価において評価の良好であった餃子5及び対照の餃子11について、焼成後における中種と皮の重量を測定し、成型時の各重量(中種:12g、皮:5.7g)と比較した。結果を表4に示す。
(3) Weight measurement of dumplings In order to more quantitatively measure the degree of water transfer from the middle seeds to the skin, the middle seeds of the dumplings 5 and the control dumplings 11, which were evaluated well in the above sensory evaluation, after firing. And the weight of the skin was measured and compared with each weight at the time of molding (medium seed: 12 g, skin: 5.7 g). The results are shown in Table 4.

Figure 0006779714
Figure 0006779714

表4に示したとおり、餃子5は焼成後と成型時における中種及び皮の重量の差が餃子11よりも小さかった。この結果は、餃子11に比べて餃子5は中種からの水分の流出が少なく、皮への水分移行が抑制されていたことを意味する。 As shown in Table 4, the difference in weight between the middle seeds and the skin of the dumplings 5 after firing and during molding was smaller than that of the dumplings 11. This result means that the gyoza 5 had less water outflow from the middle species than the gyoza 11, and the water transfer to the skin was suppressed.

[メンチカツによる評価]
(1)メンチカツの製造方法
1)牛トリミング肉(赤身75%)140g、鳥ムネ肉260gをまとめて挽き目3mmでチョッピングし、挽き肉400gを得た。
2)粒状大豆たん白22.5g(商品名:フジニックエース100;不二製油社製)に水64.5g、ドミグラスソース12g、ウスターソース3g、醤油2.5g、たん白加水分解物(商品名:HAP−GL;理研ビタミン社製)1.5gを加え、水戻し粒状大豆たん白106gを得た。
3)バッターミックス(商品名:U869 2次用バッターミックス;理研ビタミン社製)100gに水400gを加え、ジューサーミキサー(型式:MX−152S;松下電器産業社製)で5分間混合し、バッター液を得た。
4)粉末状大豆たん白(商品名:ニューフジプロ−SEH;不二製油社製)1.25g、水5g、大豆油15.5gを卓上ミキサー(型式:KSM150WH;エフ・エム・アイ社製)に投入し、該ミキサーで30秒間混合した。
5)上記4)で得た混合物に、挽き肉200g、食塩1g、グルタミン酸ナトリウム1g、白コショウ0.75g、ナツメグ0.25g及び水分移行抑制剤5を1.5g加え、さらに該ミキサーで2分間混合した。
6)上記5)で得た混合物に、ダイスカット生玉ねぎ150g、水戻し粒状大豆たん白106g、ドライパン粉8.25gを加え、さらに該ミキサーで1分間混合した。
7)上記6)で得た混合物に、加工でん粉(商品名:日食MT−01;日本食品化工社製)5gを加え、さらに該ミキサーで30秒間混合してメンチカツの中種を得た。
8)得られたメンチカツの中種を、1個あたり40gずつ小判型に成型し、表面にバッター液及び生パン粉を均一に付着させ、メンチカツ1を得た。
9)対照として、水分移行抑制剤を添加しない以外は同様にして、メンチカツ2を得た。
10)得られたメンチカツ1及び2を、急速凍結庫(庫内温度約−35℃)で30分凍結した後、袋に入れて−20℃で7日間冷凍保存した。
[Evaluation by Menchi-katsu]
(1) Method for producing Menchi-katsu 1) 140 g of beef trimmed meat (75% lean meat) and 260 g of chicken breast meat were collectively chopped with a minced meat of 3 mm to obtain 400 g of minced meat.
2) Granular soy protein 22.5 g (trade name: Fuji Nick Ace 100; manufactured by Fuji Oil Co., Ltd.), water 64.5 g, domigrass sauce 12 g, Worcester sauce 3 g, soy sauce 2.5 g, protein hydrolyzate (trade name) : HAP-GL; manufactured by RIKEN Vitamin Co., Ltd.) 1.5 g was added to obtain 106 g of water-rehydrated granular soybean protein.
3) Add 400 g of water to 100 g of batter mix (trade name: U869 secondary batter mix; manufactured by Riken Vitamin Co., Ltd.), mix with a juicer mixer (model: MX-152S; manufactured by Matsushita Electric Industrial Co., Ltd.) for 5 minutes, and batter liquid. Got
4) Powdered soy protein (trade name: New Fujipro-SEH; manufactured by Fuji Oil Co., Ltd.) 1.25 g, 5 g of water, and 15.5 g of soybean oil are mixed with a desktop mixer (model: KSM150WH; manufactured by FMI). And mixed with the mixer for 30 seconds.
5) To the mixture obtained in 4) above, add 200 g of minced meat, 1 g of salt, 1 g of monosodium glutamate, 0.75 g of white pepper, 0.25 g of nutmeg and 1.5 g of water transfer inhibitor 5, and further mix for 2 minutes with the mixer. did.
6) To the mixture obtained in 5) above, 150 g of dice-cut raw onions, 106 g of water-rehydrated granular soybean protein, and 8.25 g of dry bread crumbs were added, and the mixture was further mixed for 1 minute with the mixer.
7) To the mixture obtained in 6) above, 5 g of modified starch (trade name: Nissho MT-01; manufactured by Nihon Shokuhin Kako Co., Ltd.) was added, and the mixture was further mixed for 30 seconds with the mixer to obtain a middle seed of Menchi-katsu.
8) The obtained middle seeds of Menchi-katsu were molded into an oval shape by 40 g each, and the batter liquid and raw bread crumbs were uniformly adhered to the surface to obtain Menchi-katsu 1.
9) As a control, Menchi-katsu 2 was obtained in the same manner except that a water transfer inhibitor was not added.
10) The obtained Menchi-katsu 1 and 2 were frozen in a quick freezer (inside temperature of about −35 ° C.) for 30 minutes, placed in a bag, and stored frozen at −20 ° C. for 7 days.

(2)歯切れのよさの評価
冷凍保存後、メンチカツ1及び2を170℃で7分30秒間油ちょうし、さらにホットショーケース(型式:YN−500;ヨシキン社製)で3時間加湿保温した。加湿保温後、各メンチカツの衣の歯切れのよさについて官能評価を行った。評価は表5に示す評価基準に従って10名のパネラーで行い、結果は10名の評点の平均値を下記の基準に従って記号化した。結果を表6に示す。
〔基準〕
◎:極めて良好 平均値4.0以上
○:良好 平均値3.0以上、4.0未満
△:やや悪い 平均値2.0以上、3.0未満
×:悪い 平均値2.0未満
(2) Evaluation of crispness After freezing and storing, Menchi-katsu 1 and 2 were oiled at 170 ° C. for 7 minutes and 30 seconds, and further humidified and kept warm in a hot showcase (model: YN-500; manufactured by Yoshikin Co., Ltd.) for 3 hours. After humidification and heat retention, a sensory evaluation was performed on the crispness of the batter of each Menchi-katsu. The evaluation was performed by 10 panelists according to the evaluation criteria shown in Table 5, and the results were symbolized by the average value of the scores of 10 persons according to the following criteria. The results are shown in Table 6.
[Criteria]
⊚: Very good average value 4.0 or more ○: Good average value 3.0 or more and less than 4.0 Δ: Slightly bad average value 2.0 or more and less than 3.0 ×: Bad average value less than 2.0

Figure 0006779714
Figure 0006779714

Figure 0006779714
Figure 0006779714

表6の結果から明らかなように、本発明の実施例である水分移行抑制剤5を中種に添加したメンチカツ1は、水分移行抑制剤無添加のメンチカツ2に比べて衣の歯切れが良好であった。 As is clear from the results in Table 6, the Menchi-katsu 1 to which the water transfer inhibitor 5 added to the medium seeds, which is an example of the present invention, has better crispness of the batter than the Menchi-katsu 2 to which the water transfer inhibitor is not added. there were.

Claims (2)

(a)モノグリセリン脂肪酸エステル及び/又はグリセリン有機酸脂肪酸エステルを含む油脂加工澱粉と、(b)ソルビタン脂肪酸エステルとを含有することを特徴とする包餡食品の中種用水分移行抑制剤。 A water transfer inhibitor for medium species of packaged foods, which comprises (a) oil-processed starch containing a monoglycerin fatty acid ester and / or a glycerin organic acid fatty acid ester, and (b) a sorbitan fatty acid ester. 請求項1に記載の包餡食品の中種用水分移行抑制剤を中種に添加することを特徴とする包餡食品の水分移行抑制方法。 A method for suppressing water transfer of a bean paste food, which comprises adding the water transfer inhibitor for medium seeds of the bean paste food according to claim 1 to the middle seed.
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