JP4648916B2 - Liquid seasoning composition for cooking - Google Patents

Liquid seasoning composition for cooking Download PDF

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JP4648916B2
JP4648916B2 JP2007079748A JP2007079748A JP4648916B2 JP 4648916 B2 JP4648916 B2 JP 4648916B2 JP 2007079748 A JP2007079748 A JP 2007079748A JP 2007079748 A JP2007079748 A JP 2007079748A JP 4648916 B2 JP4648916 B2 JP 4648916B2
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JP2008237059A (en
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兼二 須藤
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Riken Vitamin Co Ltd
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本発明は、食材と調味組成物を加熱調理する際、焦げ付きを抑制する事を特徴とする加熱調理用の液体調味料を提供することを目的とする。   An object of this invention is to provide the liquid seasoning for heat cooking characterized by suppressing a burning when cooking food and a seasoning composition.

タレやソースなどの調味組成物は、食材をより美味しく食する為に種々の調味成分を配合し、焼き肉のタレ、焼き鳥のタレ、団子のタレなどのタレ類、ステ−キソ−ス、マ−ボ豆腐ソ−ス、エビチリソース、野菜炒め用ソ−スなど料理に合ったものに仕上げられている。これらの食材と調味組成物は、加熱調理する事により供されることが多いが、加熱による食材、調味組成物、調理器具に焦げが生じ、風味、見た目、食感が悪くなる事が問題であった。   Seasoning compositions such as sauces and sauces are blended with various seasoning ingredients to make the food more delicious, and sauces such as sauces for grilled meat, sauces for grilled chicken, sauces for dumplings, sticky sauce, marshes Botofu sauce, shrimp sauce, vegetable fried sauce, etc. These ingredients and seasoning compositions are often served by cooking, but the problem is that the ingredients, seasoning composition and cooking utensils are heated and the flavor, appearance and texture are poor. there were.

これらの対策として、風味成分を含有してなるO/W型乳化組成物であって、食用油脂を10〜50重量%含有し、HLBが各々7以上のグリセリン脂肪酸エステル、有機酸モノグリセリド、酵素分解レシチンまたはHLBが5以上のソルビタン脂肪酸エステルから選ばれる1種または2種以上を0.03〜0.3重量%含有してなり、粘度が1000〜7000センチポイズ/20℃であり、平均油滴粒子径が30μm以下のものである前記乳化組成物からなることを特徴とする炒め物用調味料が提案されている(特許文献1参照)。また、食用油が粉末調味料を含有することを特徴とする炒め物用調味料が提案されている(特許文献2参照)。さらに、醤油、味噌、ウスターソース、ケチャップなどの液状調味料をベースとし、増粘剤として、糊化開始温度が60℃以上で、かつ澱粉粒の膨潤を強く抑制している架橋度の高い澱粉のみを3〜7重量%添加し、加熱糊化させて得られるソースが提案されている(特許文献3参照)。しかし、前記したこれらの技術には、一長一短があり、これらの技術が必ずしも加熱時の焦げ抑制を満足させるものではない。
特開平10−113145号公報 特開2001−106号公報 特開2000−210059号公報
As these countermeasures, an O / W emulsion composition containing a flavor component, containing 10 to 50% by weight of edible fats and oils, HLB of 7 or more, glycerol fatty acid ester, organic acid monoglyceride, enzymatic degradation Lecithin or HLB contains 0.03 to 0.3 wt% of one or more sorbitan fatty acid esters selected from 5 or more, has a viscosity of 1000 to 7000 centipoise / 20 ° C, and average oil droplet particles A seasoning for fried foods characterized by comprising the above emulsion composition having a diameter of 30 μm or less has been proposed (see Patent Document 1). Further, a seasoning for fried foods characterized in that the edible oil contains a powder seasoning has been proposed (see Patent Document 2). Furthermore, based on liquid seasonings such as soy sauce, miso, Worcester sauce, and ketchup, as a thickener, only starch with a high degree of cross-linking that has a gelatinization start temperature of 60 ° C. or higher and strongly suppresses swelling of starch granules Has been proposed (see Patent Document 3). However, these technologies described above have advantages and disadvantages, and these technologies do not always satisfy the suppression of scorching during heating.
JP-A-10-113145 Japanese Patent Laid-Open No. 2001-106 JP 2000-210059 A

本発明は、加熱調理時の焦げ付きを抑制することを特徴とする、より優れた加熱調理用の液体調味料を提供する為になされたものである。   This invention is made in order to provide the more excellent liquid seasoning for heat cooking characterized by suppressing the burning at the time of heat cooking.

本発明者は、上記課題を解決するため鋭意検討した結果、油脂および乳化剤を含有する油脂加工澱粉と油脂を含む加熱調理用の液体調味組成物により、加熱調理時の焦げ抑制効果のある液体調味組成物が得られることを見出し、この知見に基づいてさらに検討を重ねて本発明を完成させるに至った。
即ち、本発明は以下の構成を有する。
油脂および乳化剤を含有する油脂加工澱粉と油脂を含み、油脂加工澱粉が糊化せず分散状態で存在することを特徴とする加熱調理用の液体調味組成物。
As a result of intensive studies to solve the above-mentioned problems, the present inventor has obtained a liquid seasoning having an effect of suppressing scorching during cooking by cooking with a liquid seasoning composition for cooking with oil and fat containing starch and fat containing an oil and fat and an emulsifier. It has been found that a composition can be obtained, and further studies have been made based on this finding to complete the present invention.
That is, the present invention has the following configuration.
A liquid seasoning composition for cooking by heating, comprising an oil and fat processed starch containing fats and oils and an emulsifier, wherein the oil processed starch is not gelatinized and exists in a dispersed state.

本発明の液体調味組成物を用いて食品を調製することにより、加熱調理時の焦げ抑制効果が得られる。   By preparing a food product using the liquid seasoning composition of the present invention, a scorch suppression effect during cooking can be obtained.

本発明は、油脂および乳化剤を含有する油脂加工澱粉と油脂を含み、油脂加工澱粉が糊化せず分散状態で存在することを特徴とする加熱調理用の液体調味組成物に関するものである。   [Technical Field] The present invention relates to a liquid seasoning composition for cooking by heating, comprising an oil and fat processed starch and an oil and fat containing an oil and fat and an emulsifier, wherein the oil and fat processed starch is not gelatinized and exists in a dispersed state.

本発明の加熱調理用の調味組成物には、油脂加工澱粉を含有する。前記油脂加工澱粉は、澱粉に油脂および乳化剤を添加し、均一に混合した後必要に応じて乾燥し、さらに加熱・熟成することにより得られる。
油脂加工澱粉に使用する原料澱粉としては、コーンスターチ、馬鈴薯澱粉、小麦澱粉、米澱粉、甘藷澱粉、タピオカ澱粉、緑豆澱粉、サゴ澱粉またはエンドウ豆澱粉、あるいはこれらの澱粉にエステル化処理(例えば、酢酸澱粉など。)、エーテル化処理(例えば、ヒドロキシプロピル澱粉など。)、架橋処理(例えば、リン酸架橋澱粉など。)、酸化処理(例えば、ジアルデヒド澱粉など。)、酸処理または湿熱処理等の処理を単一でまたは組み合わせて施した加工澱粉などが挙げられる。これら澱粉は単独でまたは二以上を組み合わせて使用することができる。
The seasoning composition for cooking according to the present invention contains fat and oil processed starch. The fat and oil-processed starch is obtained by adding fats and oils and an emulsifier to starch, mixing uniformly, drying as necessary, and further heating and aging.
The raw material starch used in the oil- and fat-processed starch includes corn starch, potato starch, wheat starch, rice starch, sweet potato starch, tapioca starch, mung bean starch, sago starch or pea starch, or esterification treatment (for example, acetic acid) Starch, etc.), etherification treatment (eg, hydroxypropyl starch, etc.), crosslinking treatment (eg, phosphoric acid crosslinked starch, etc.), oxidation treatment (eg, dialdehyde starch, etc.), acid treatment or wet heat treatment, etc. Examples include processed starch that has been processed in a single or combined manner. These starches can be used alone or in combination of two or more.

本発明において油脂加工澱粉に使われる油脂としては、食用可能な油脂であれば特に制限はなく、例えば大豆油、菜種油、綿実油、サフラワー油、ヒマワリ油、米糠油、コーン油、椰子油、パーム油、パーム核油、落花生油、オリーブ油、ハイオレイック菜種油、ハイオレイックサフラワー油、ハイオレイックコーン油またはハイオレイックヒマワリ油などの植物油脂や牛脂、ラード、魚油または乳脂等の動物油脂、さらにこれら動植物油脂を分別、水素添加またはエステル交換したものあるいは中鎖脂肪酸トリグリセリド(MCT)などが挙げられる。好ましくは大豆サラダ油、サフラワー油、ヒマワリ油またはコーンサラダ油などである。また、上記食用油脂の一部または全部の代替品として油分を多く含む穀紛、例えば生大豆粉などを用いてもよい。   In the present invention, fats and oils used in the oil and fat processed starch are not particularly limited as long as they are edible fats and oils, such as soybean oil, rapeseed oil, cottonseed oil, safflower oil, sunflower oil, rice bran oil, corn oil, coconut oil, palm Vegetable oils such as oil, palm kernel oil, peanut oil, olive oil, high oleic rapeseed oil, high oleic safflower oil, high oleic corn oil or high oleic sunflower oil, animal oils such as beef fat, lard, fish oil or milk fat, and more Examples include those obtained by fractionating, hydrogenating or transesterifying these animal and vegetable oils and fats, and medium-chain fatty acid triglycerides (MCT). Preferred are soybean salad oil, safflower oil, sunflower oil, corn salad oil, and the like. Moreover, you may use the grain flour which contains many oils, for example, raw soybean flour etc. as a part or all substitute of the said edible fats and oils.

本発明の油脂加工澱粉に使われる乳化剤としては、食品添加物である5種の乳化剤があげられる。すなわち、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、レシチンであり、これらの乳化剤は単独で、または2以上を組み合わせて使用することができる。
ここで、グリセリン脂肪酸エステルには、グリセリンと脂肪酸のエステルの外、グリセリン有機酸脂肪酸エステル、ポリグリセリン脂肪酸エステル、およびポリグリセリン縮合リシノレイン酸エステル等が含まれる。グリセリン有機酸脂肪酸エステルには、グリセリン酢酸脂肪酸エステル、グリセリン乳酸脂肪酸エステル、グリセリンクエン酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステルおよびグリセリンジアセチル酒石酸脂肪酸エステル等が含まれる。またレシチンには、分別レシチン、酵素分解レシチンおよび酵素処理レシチンなどが含まれる。
使用する乳化剤は、グリセリン脂肪酸エステルの中でも有機酸脂肪酸エステルが好ましく、より好ましくはグリセリンジアセチル酒石酸脂肪酸エステルである。
グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステルに使用される脂肪酸は、炭素数6〜22の飽和または不飽和脂肪酸を使用することができる。
Examples of the emulsifier used in the fat and oil processed starch of the present invention include five types of emulsifiers which are food additives. That is, they are glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, and lecithin, and these emulsifiers can be used alone or in combination of two or more.
Here, the glycerin fatty acid ester includes glycerin and fatty acid ester, glycerin organic acid fatty acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester and the like. Examples of the glycerin organic acid fatty acid ester include glycerin acetic acid fatty acid ester, glycerin lactic acid fatty acid ester, glycerin citrate fatty acid ester, glycerin succinic acid fatty acid ester, and glycerin diacetyl tartaric acid fatty acid ester. Lecithin includes fractionated lecithin, enzymatically decomposed lecithin, enzyme-treated lecithin, and the like.
Among the glycerin fatty acid esters, the emulsifier used is preferably an organic acid fatty acid ester, more preferably glycerin diacetyltartaric acid fatty acid ester.
As the fatty acid used in the glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, and propylene glycol fatty acid ester, a saturated or unsaturated fatty acid having 6 to 22 carbon atoms can be used.

澱粉に対する油脂および乳化剤の合計添加量は、約0.003〜10質量%、好ましくは約0.05〜5.0質量%、より好ましくは約0.1〜1.0質量%である。また油脂と乳化剤との添加割合(油脂/乳化剤)は、約1/99〜99/1(W/W)の範囲を示すことができ、好ましくは約60/40〜20/80(W/W)の範囲である。   The total amount of fat and oil and emulsifier added to starch is about 0.003 to 10% by mass, preferably about 0.05 to 5.0% by mass, and more preferably about 0.1 to 1.0% by mass. Moreover, the addition ratio (oil / fat / emulsifier) of fats and oils can show the range of about 1 / 99-99 / 1 (W / W), Preferably it is about 60 / 40-20 / 80 (W / W). ) is in the range of.

本発明で使用される油脂加工澱粉において、澱粉に油脂および乳化剤を添加する方法としては、例えば油脂または乳化剤をそれぞれ別々に澱粉に添加する方法、あるいは予め油脂および乳化剤を混合し、必要であれば加熱・溶融した油脂および乳化剤の混合物(以下、油脂組成物という。)を澱粉に添加する方法などが挙げられる。なかでも、加熱・溶融した油脂組成物を澱粉に添加する方法が好ましい。
例えば、油脂と乳化剤は、約1/99〜99/1(W/W;油脂/乳化剤)、好ましくは約60/40〜20/80(W/W;油脂/乳化剤)の割合で混合し、あるいは乳化剤が油脂に溶融するまで加熱(50〜90℃)し、油脂組成物が調製される。次いで、調製された油脂組成物は、澱粉に対し約0.003〜10質量%、好ましくは約0.05〜5.0質量%、より好ましくは約0.1〜1.0質量%となるよう添加されるのが好ましい。油脂組成物が添加された澱粉は、混合、乾燥される。
In the oil and fat processed starch used in the present invention, as a method of adding fat and emulsifier to starch, for example, a method of separately adding fat and emulsifier to starch respectively, or by mixing fat and emulsifier in advance, if necessary Examples include a method of adding a mixture of heated and melted oil and fat and an emulsifier (hereinafter referred to as an oil and fat composition) to starch. Especially, the method of adding the heated fat composition to starch is preferable.
For example, the fat and oil and the emulsifier are mixed at a ratio of about 1/99 to 99/1 (W / W; fat / emulsifier), preferably about 60/40 to 20/80 (W / W; fat / emulsifier), Or it heats (50-90 degreeC) until an emulsifier melt | dissolves in fats and oils, and an oil-fat composition is prepared. Subsequently, the prepared fat composition is about 0.003 to 10% by mass, preferably about 0.05 to 5.0% by mass, and more preferably about 0.1 to 1.0% by mass with respect to starch. It is preferable to be added. The starch to which the oil / fat composition is added is mixed and dried.

澱粉と油脂組成物とを混合および乾燥する方法は特に限定されないが、例えば平衡水分を保った澱粉、または水分約20〜40%に調湿した澱粉を流動層乾燥機中で流動状態とし、そこに該油脂組成物を噴霧し混合、乾燥する方法、水分約50%程度に調湿した澱粉のケーキに該油脂組成物を添加し、混合・分散させた後、例えば棚式通風乾燥機などを用いて乾燥し粉末を得る方法、水分約60〜70%に調湿したスラリー状の澱粉に該油脂組成物を添加・混合し、その後噴霧乾燥機あるいはドラムドライヤーなどを用いて乾燥し粉末を得る方法などが挙げられる。いずれにせよ、澱粉粒が破壊されない状態で澱粉の表面に該油脂組成物が吸着される方法であれば、どのような方法であっても良い。   The method for mixing and drying the starch and the fat composition is not particularly limited. For example, starch having an equilibrium moisture content or starch having a moisture content adjusted to about 20 to 40% is fluidized in a fluidized bed dryer. A method of spraying, mixing and drying the oil and fat composition, adding the oil and fat composition to a starch cake whose moisture has been adjusted to about 50%, mixing and dispersing, and then, for example, a shelf-type ventilation dryer A method for obtaining a powder by drying using a method, adding and mixing the oil and fat composition to a slurry starch adjusted to a moisture content of about 60 to 70%, and then drying the powder using a spray dryer or a drum dryer to obtain a powder. the method and the like. In any case, any method may be used as long as the oil and fat composition is adsorbed on the surface of the starch without destroying the starch granules.

該油脂組成物が吸着された澱粉は、次に加熱・熟成が行われる。熟成は乾燥工程をそのまま延長・継続してもよいが、高温で処理することにより比較的短時間で行うことができる。熟成は、通常例えば棚段式通風乾燥機を用いて、約30〜180℃、好ましくは約30〜140℃の温度範囲で行われる。熟成を約120℃以上で行う場合には、澱粉がデキストリン化しないよう注意が必要である。熟成に要する時間は、澱粉に対する油脂組成物の吸着量、熟成温度、熟成装置の熱効率等により異なるが、例えば水分約35質量%に調湿したコーンスターチに油脂組成物を約0.1%添加、混合し、室温で約20時間、乾燥した澱粉では、約60℃で約5時間程度、あるいは約140℃で約1時間程度などである。   The starch on which the oil / fat composition has been adsorbed is then heated and aged. Aging may be continued or extended as it is, but can be performed in a relatively short time by treating at a high temperature. The aging is usually performed in a temperature range of about 30 to 180 ° C., preferably about 30 to 140 ° C., for example, using a shelf-type ventilation dryer. When aging is performed at about 120 ° C. or higher, care must be taken so that starch does not become dextrin. The time required for aging varies depending on the adsorption amount of the fat composition to starch, the ripening temperature, the thermal efficiency of the ripening apparatus, etc., for example, adding about 0.1% of the fat composition to corn starch conditioned to a moisture of about 35% by mass, In the case of starch that has been mixed and dried at room temperature for about 20 hours and dried at about 60 ° C. for about 5 hours, or about 140 ° C. for about 1 hour.

加熱・熟成終了後、得られた加工澱粉は水分約8〜18%、好ましくは約10〜14%に調湿され、製品とされる。   After the completion of heating and aging, the obtained processed starch is conditioned to a moisture content of about 8 to 18%, preferably about 10 to 14%, to obtain a product.

本発明において加熱調理用の液体調味組成物に配合される油脂加工澱粉の量は、食材に対する液体調味組成物の添加量や、料理に適したたれの粘性に違いがあるため限定することはできないが、調味素材部分100部に対し好ましくは1〜30質量部であり、より好ましくは5〜15質量部である。1質量部より少ないと、液体調味組成物と食材を加熱調理する際、粘性を発現せず食材へのからみが悪くなり調味料として適当でなく、さらに焦げ抑制効果が弱く焦げの発生が顕著となる。逆に30質量部より多いと加熱調理時に食材に絡む調味料の粘性が強く食感が悪くなり料理の仕上がりが適当ではない。ここでいう調味素材部分とは、本加熱調理用の液体調味組成物の構成から油脂加工澱粉と油脂を除いた部分をいう。   In the present invention, the amount of the oil- and fat-processed starch blended in the liquid seasoning composition for cooking is not limited because there is a difference in the addition amount of the liquid seasoning composition to the food and the viscosity of the sauce suitable for cooking. However, Preferably it is 1-30 mass parts with respect to 100 parts of seasoning raw material parts, More preferably, it is 5-15 mass parts. If the amount is less than 1 part by mass, when cooking the liquid seasoning composition and ingredients, the viscosity does not develop and the entanglement of the ingredients worsens and is not suitable as a seasoning, and the charring suppression effect is weak and the occurrence of charring is significant. Become. On the other hand, if the amount is more than 30 parts by mass, the seasoning entangled with the ingredients during cooking is strong and the texture is poor, and the finish of the dish is not suitable. As used herein, the seasoning material portion refers to a portion obtained by removing the oil- and fat-processed starch and the oil and fat from the configuration of the liquid seasoning composition for cooking by heating.

本発明において加熱調理用の液体調味組成物に使われる油脂としては、食用可能な油脂であれば特に制限はなく、例えば大豆油、菜種油、綿実油、サフラワー油、ヒマワリ油、米糠油、コーン油、椰子油、パーム油、パーム核油、落花生油、オリーブ油、ハイオレイック菜種油、ハイオレイックサフラワー油、ハイオレイックコーン油またはハイオレイックヒマワリ油などの植物油脂や牛脂、ラード、魚油または乳脂等の動物油脂、さらにこれら動植物油脂を分別、水素添加またはエステル交換したものあるいは中鎖脂肪酸トリグリセリド(MCT)や油脂に香味を付与した香味油、ラー油などが挙げられる。好ましくは菜種油、大豆サラダ油、コーンサラダ油、ラー油、香味油、またはラードなどである。   The fats and oils used in the liquid seasoning composition for cooking in the present invention are not particularly limited as long as they are edible fats and oils, for example, soybean oil, rapeseed oil, cottonseed oil, safflower oil, sunflower oil, rice bran oil, corn oil , Plant oils such as coconut oil, palm oil, palm kernel oil, peanut oil, olive oil, high oleic rapeseed oil, high oleic safflower oil, high oleic corn oil or high oleic sunflower oil, lard, fish oil or milk fat, etc. Animal oils and fats, and those obtained by separation, hydrogenation or transesterification of these animal and vegetable oils, or medium-chain fatty acid triglycerides (MCT), flavor oils obtained by imparting flavor to oils and fats, and the like. Rapeseed oil, soybean salad oil, corn salad oil, chili oil, flavor oil or lard are preferred.

本発明において液体調味組成物に配合される油脂の量は、食材に対する液体調味組成物の添加量や、料理に適した油性感に違いがあるため限定することはできないが、調味素材部分100部に対し好ましくは1〜50質量部であり、より好ましくは5〜25質量部である。5質量部より少ないと、加熱調理時に焦げの発生が顕著になると同時に料理の仕上がりの油性感に乏しくなる。逆に50質量部より多いと料理の仕上がりが油っぽくなり過ぎて好ましくない。   In the present invention, the amount of fats and oils blended in the liquid seasoning composition cannot be limited because there is a difference in the amount of the liquid seasoning composition added to the food and the oily feeling suitable for cooking, but the seasoning material portion 100 parts Preferably it is 1-50 mass parts, More preferably, it is 5-25 mass parts. When the amount is less than 5 parts by mass, the occurrence of scoring becomes remarkable during cooking, and at the same time, the oily feeling of the finished dish becomes poor. On the contrary, if it is more than 50 parts by mass, the finish of the dish becomes too oily, which is not preferable.

本発明で使用される加熱調理用の液体調味組成物の構成は、料理の種類によって異なり特に制限はないが、醤油、味噌、食酢、酒、食塩、その他の無機塩類、砂糖、エキス類、香辛料、オイスターソース、豆板醤、甜面醤、トマトペースト、ケチャップ、液糖、味醂、油脂、有機酸、果汁、ねぎ・しょうが・にんにく等の野菜、化学調味料、増粘剤、酒精、色素、甘味料、静菌剤、酸化防止剤などの他、通常調味に使用される材料を配合したものである。
これら調味料組成物を用いた料理としては、焼肉、生姜焼き、ステーキ、蒲焼、照り焼、焼き鳥、肉団子、チンジャオロースー、野菜炒め、エビチリ、ホイコーロー、酢豚、マーボー豆腐などがあげられる。
The composition of the liquid seasoning composition for cooking used in the present invention varies depending on the type of dish and is not particularly limited, but soy sauce, miso, vinegar, sake, salt, other inorganic salts, sugar, extracts, spices , Oyster sauce, bean plate sauce, soup sauce, tomato paste, ketchup, liquid sugar, miso, fats and oils, organic acids, fruit juice, green onions, ginger, garlic and other vegetables, chemical seasoning, thickener, alcohol, pigment, sweetener In addition to bacteriostatic agents, antioxidants, and the like, materials that are usually used for seasoning are blended.
Examples of dishes using these seasoning compositions include yakiniku, ginger grilled, steak, grilled, teriyaki, yakitori, meat dumplings, chinjao roux, stir-fried vegetables, shrimp chilli, hoikoro, sour pork, marvo tofu and the like.

本発明で使用する油脂加工澱粉は、加熱調理用の液体調味組成物の温度が、油脂加工澱粉が糊化しない50℃以下、より好ましくは40℃以下で加えられる。ここで糊化しない状態とは、油脂加工澱粉の糊化により粘性を発生しない状態を意味する。
油脂加工澱粉を、油脂加工澱粉が糊化する温度以上で加熱調理用の液体調味組成物に添加すると、糊化して粘性が発生し食材にからめにくくなり液体調味組成物としては不適である。さらに本発明の目的である焦げ抑制効果がなくなり焦げの発生が顕著となる。
The fat and oil processed starch used in the present invention is added at a temperature of 50 ° C. or less, more preferably 40 ° C. or less, at which the temperature of the liquid seasoning composition for cooking is not gelatinized. Here, the state in which no gelatinization occurs means a state in which no viscosity is generated due to gelatinization of the fat and oil processed starch.
If the oil- and fat-processed starch is added to a liquid seasoning composition for cooking at a temperature higher than the temperature at which the oil-and-fat processed starch is gelatinized, it is gelatinized to generate viscosity, making it difficult to entangle with the food material, making it unsuitable as a liquid seasoning composition. Furthermore, the burn suppression effect which is the object of the present invention is lost, and the occurrence of burns becomes significant.

以下に本発明を実施例に基づいて、より具体的に説明するが、本発明はこれらに限定されるものではない。尚、実施例中の部は質量部を意味する。   Hereinafter, the present invention will be described more specifically based on examples, but the present invention is not limited thereto. In addition, the part in an Example means a mass part.

[リン酸架橋タピオカ澱粉の作製]
水180Lにトリメタリン酸ナトリウム2kgおよび炭酸ナトリウム3kgを溶解し、タピオカ澱粉100kgを懸濁させた後、さらに炭酸ナトリウムを加えpHを10.2に調整した。50℃で6時間攪拌下反応させた後、500Lの水を加えて希釈し、5質量%塩酸溶液でpH7.0に中和した。続いて、脱水、水洗および乾燥した後、リン酸架橋タピオカ澱粉100kgを得た。
[Preparation of phosphate cross-linked tapioca starch]
After dissolving 2 kg of sodium trimetaphosphate and 3 kg of sodium carbonate in 180 L of water and suspending 100 kg of tapioca starch, sodium carbonate was further added to adjust the pH to 10.2. After reacting with stirring at 50 ° C. for 6 hours, 500 L of water was added for dilution, and the mixture was neutralized to pH 7.0 with a 5 mass% hydrochloric acid solution. Subsequently, after dehydration, washing with water and drying, 100 kg of phosphoric acid crosslinked tapioca starch was obtained.

[油脂加工澱粉の作製1]
サフラワー油50質量%とグリセリンジアセチル酒石酸脂肪酸エステル(商品名:ポエムW−10;理研ビタミン社)50質量%からなる油脂組成物を60℃に加温・溶解した。水分12.5%に調湿したリン酸架橋タピオカ澱粉100質量部に対して前記油脂組成物0.5質量部を添加し、高速攪拌混合機(レーディゲミキサーFM130D;松坂技研社)で10分間混合した。得られた混合物をトレーに広げて機内温度60℃の棚段式通風乾燥機で水分約12.0%まで乾燥し、乾燥物を粉砕し、得られた粉末をポリ袋に詰めて60℃で2週間熟成し、油脂加工澱粉(油脂加工澱粉1)を得た。
[Preparation of oil and fat processed starch 1]
An oil and fat composition comprising 50% by mass of safflower oil and 50% by mass of glycerin diacetyltartaric acid fatty acid ester (trade name: Poem W-10; Riken Vitamin Co., Ltd.) was heated and dissolved at 60 ° C. 0.5 parts by mass of the oil and fat composition is added to 100 parts by mass of phosphate-crosslinked tapioca starch conditioned to a moisture content of 12.5%, and the mixture is mixed with a high-speed stirring mixer (Laedige Mixer FM130D; Matsuzaka Giken Co., Ltd.). Mixed for minutes. The obtained mixture is spread on a tray and dried to a moisture of about 12.0% with a shelf-type air dryer at an internal temperature of 60 ° C., the dried product is pulverized, and the obtained powder is packed in a plastic bag at 60 ° C. It was aged for 2 weeks to obtain an oil and fat processed starch (oil and fat processed starch 1).

[液体調味組成物の作製:焼肉]
焼肉用の液体調味組成物の配合を表1に示す。実施例、比較例では、表1の配合を10倍量した重量数(グラム)で液体調味組成物の作製を実施した。
[Preparation of liquid seasoning composition: Yakiniku]
Table 1 shows the composition of the liquid seasoning composition for yakiniku. In Examples and Comparative Examples, liquid seasoning compositions were prepared with the weight (grams) obtained by multiplying the formulation of Table 1 by 10 times.

Figure 0004648916
Figure 0004648916

[実施例1]
液体調味組成物の製造方法は、ステンレス製ジョッキを使用し、配合Aに記載の醤油、長ねぎみじん切り、りんご果汁、すりガーリック、コーンスターチをヘラで攪拌混合しながら85℃10分間加熱しコーンスターチを糊化した後、砂糖、食塩、グルタミン酸ナトリウム、黒胡椒末、レッドペッパー、キサンタンガム(エコーガムF:大日本住友製薬(株))をダマにならない様に加え、さらに果糖ブドウ糖液糖、カラメル、水を加え攪拌混合して均一にした。80℃5分間加熱殺菌を行い40℃まで冷却し酒精を加え調味素材部分を得た。その後、油脂加工澱粉1、菜種サラダ油を加え、ヘラで均一になるまで攪拌混合し、加熱調理用の液体調味組成物1250gを得た。
[実施例2]
実施例1の配合Aにおいて、油脂加工澱粉1の10部を15部に増量し同様の方法で液体調味組成物1300gを得た。
[実施例3]
実施例1の配合Aにおいて、油脂加工澱粉1の10部を5部に減量し同様の方法で液体調味組成物1200gを得た。
[Example 1]
The liquid seasoning composition is made using a stainless steel mug, and the soy sauce, long onion chopped, apple juice, ground garlic, and corn starch described in Formulation A are heated and mixed with a spatula at 85 ° C. for 10 minutes to paste the corn starch. After addition, sugar, salt, sodium glutamate, black pepper powder, red pepper, xanthan gum (Echo Gum F: Dainippon Sumitomo Pharma Co., Ltd.) are added so as not to become lumpy, and fructose glucose liquid sugar, caramel, and water are added. Stir and mix to make uniform. The mixture was sterilized by heating at 80 ° C. for 5 minutes, cooled to 40 ° C., and alcohol was added to obtain a seasoning material portion. Then, the fat and oil processed starch 1 and the rapeseed salad oil were added and stirred and mixed until uniform with a spatula to obtain 1250 g of a liquid seasoning composition for cooking.
[Example 2]
In the blend A of Example 1, 10 parts of the fat and oil processed starch 1 was increased to 15 parts, and 1300 g of a liquid seasoning composition was obtained by the same method.
[Example 3]
In the blend A of Example 1, 10 parts of the fat and oil processed starch 1 was reduced to 5 parts, and 1200 g of a liquid seasoning composition was obtained in the same manner.

[比較例1]
ステンレス製ジョッキを使用し、配合Aに記載の醤油、長ねぎみじん切り、りんご果汁、すりガーリック、コーンスターチをヘラで攪拌混合しながら85℃10分間加熱しコーンスターチを糊化した後、砂糖、食塩、グルタミン酸ナトリウム、黒胡椒末、レッドペッパー、キサンタンガム(エコーガムF:大日本住友製薬(株))、果糖ブドウ糖液糖、カラメル、水、油脂加工澱粉1、菜種サラダ油をダマにならない様に加え、攪拌混合して均一にした。80℃5分間加熱殺菌を行い40℃まで冷却し酒精を加え、加熱調理用の液体調味組成物1250gを得た。
[比較例2]
配合Bにおいて、実施例1と同様に調味素材部分を得た後に、油脂加工澱粉1を加え液体調味組成物1100gを得た。
[比較例3]
配合Cにおいて、実施例1と同様に調味素材部分を得た後に、菜種サラダ油を加え液体調味組成物1150gを得た。
上記実施例、比較例をまとめたものを表2に示す。
[Comparative Example 1]
Using a stainless steel mug, the soy sauce, long onion chopped, apple juice, ground garlic, and corn starch described in Formulation A were heated and mixed with a spatula at 85 ° C. for 10 minutes to gelatinize the corn starch, and then sugar, salt, and glutamic acid Add sodium, black pepper powder, red pepper, xanthan gum (Echo Gum F: Dainippon Sumitomo Pharma Co., Ltd.), fructose dextrose liquid sugar, caramel, water, oil-fat processed starch 1, and rapeseed salad oil so that they do not become lumpy and stir and mix. And even. The mixture was sterilized by heating at 80 ° C. for 5 minutes, cooled to 40 ° C., added with alcohol, and 1250 g of a liquid seasoning composition for cooking by heating was obtained.
[Comparative Example 2]
In Formulation B, after obtaining the seasoning raw material part like Example 1, the fat processed starch 1 was added and the liquid seasoning composition 1100g was obtained.
[Comparative Example 3]
In Formulation C, after obtaining a seasoning material portion in the same manner as in Example 1, rapeseed salad oil was added to obtain 1150 g of a liquid seasoning composition.
Table 2 summarizes the above Examples and Comparative Examples.

Figure 0004648916
Figure 0004648916

[調理法:焼肉]
牛スライス肉(厚さ2〜3ミリ)約500gに実施例1〜3、比較例1〜3の調味組成物をそれぞれ100g(対肉20%)からめ、10分間漬け込み処理を行った後に焼成用トレーに並べ、スチームコンベクションオーブン((株)マルゼン SSC−10DB)を使用し、庫内設定温度を220℃(熱風加熱)にして3分間加熱し調理を行った。
[Cooking method: Yakiniku]
About 500 g of beef sliced meat (thickness of 2 to 3 mm), each of the seasoning compositions of Examples 1 to 3 and Comparative Examples 1 to 3 was taken from 100 g (20% to meat), and after being soaked for 10 minutes, for baking Using a steam convection oven (Maruzen SSC-10DB Co., Ltd.) on the tray, cooking was carried out by heating for 3 minutes at 220 ° C. (hot air heating).

[評価:焼肉]
調味料組成物と素材のトレー上での焦げ具合について、専門パネル10名により下記評価基準と評点で評価を行った。
焦げの発生が抑制されている (3点)
どちらともいえない (2点)
焦げの発生が抑制されていない(1点)

また、10名の評点の平均値を以下の基準に従って記号化し、結果を表3に示した。
○:評点の平均値が2.5以上
△:評点の平均値が1.5以上、2.5未満
×:評点の平均値が1.5未満
[Evaluation: Yakiniku]
About the scoring condition on the tray of a seasoning composition and a raw material, it evaluated by the following evaluation criteria and a score by 10 expert panels.
Burning is suppressed (3 points)
I can say neither (2 points)
Burning is not suppressed (1 point)

In addition, the average value of the scores of 10 people was symbolized according to the following criteria, and the results are shown in Table 3.
○: Average score value is 2.5 or more Δ: Average score value is 1.5 or more and less than 2.5 ×: Average score value is less than 1.5

Figure 0004648916
Figure 0004648916

表3から本発明の加熱調理用の液体調味組成物は、加熱調理時にトレーへの食材、調味料の焦げ付きが抑制される事が確認された。比較例1では液体調味組成物を調整する際、油脂加工澱粉を加熱し糊化したため、焼肉のタレとしては粘性が強く食材に均一にからまず不適当である。また、調理加熱する事によりトレーとの接触面に激しい焦げが発生し、焦げ抑制効果は見られなかった。比較例2では、油脂加工澱粉が糊化し粘性が発現し調味組成物が肉にからむが加熱調理時に焦げを発生した。また比較例3では、適度な粘性を発現せず肉にからまず調味組成物として適切でないと同時に、加熱調理時に焦げが発生した。   From Table 3, it was confirmed that the liquid seasoning composition for cooking of the present invention suppresses the burning of ingredients and seasonings on the tray during cooking. In Comparative Example 1, when the liquid seasoning composition was adjusted, the oil- and fat-processed starch was heated and gelatinized, so that it is not suitable as a sauce for grilled meat because it is highly viscous and uniform to the food. In addition, when the food was cooked and heated, severe scorch occurred on the contact surface with the tray, and no scorch suppression effect was observed. In Comparative Example 2, the oil- and fat-processed starch was gelatinized to develop a viscosity, and the seasoning composition was entangled in the meat, but burnt occurred during cooking. Moreover, in Comparative Example 3, the appropriate viscosity was not exhibited and the meat was not suitable as a seasoning composition at the same time, and at the same time, scorching occurred during cooking.

[調味組成物の作製:チンジャオロースー]
チンジャオロースー用の調味組成物の配合を表4に示す。実施例、比較例では、表4の配合を10倍量にした重量数(グラム)で実施した。
[Preparation of seasoning composition: Tinjaolose]
Table 4 shows the composition of the seasoning composition for tinjaolose. In the Examples and Comparative Examples, the weights (grams) obtained by adding 10 times the amount shown in Table 4 were used.

Figure 0004648916
Figure 0004648916

[実施例4]
液体調味組成物の製造方法は、ステンレス製ジョッキを使用し、配合Dに記載の醤油、オイスターソース、すりジンジャー、すりガーリックをヘラで攪拌混合しながら85℃10分間加熱した後、水、カラメルを加えさらに砂糖、食塩、グルタミン酸ナトリウム、黒胡椒末をダマにならない様に加え、攪拌混合して均一にした。80℃5分間加熱殺菌を行い40℃まで冷却し酒精を加え調味素材部分を得た。その後、油脂加工澱粉1、菜種サラダ油を加え、ヘラで均一になるまで攪拌混合し、液体調味組成物1250gを得た。
[実施例5]
実施例4の配合Dにおいて、油脂15部を25部に増量し同様の方法で液体調味組成物1350gを得た。
[実施例6]
実施例4の配合Dにおいて、油脂15部を5部に減量し同様の方法で液体調味組成物1150gを得た。
[Example 4]
The liquid seasoning composition is produced using a stainless steel mug, and after heating the soy sauce, oyster sauce, ground ginger and ground garlic described in Formulation D with a spatula at 85 ° C. for 10 minutes, water and caramel are added. In addition, sugar, salt, sodium glutamate, and black pepper powder were added so as not to become lumps, and mixed by stirring to make uniform. The mixture was sterilized by heating at 80 ° C. for 5 minutes, cooled to 40 ° C., and alcohol was added to obtain a seasoning material portion. Then, the fats and oils processed starch 1 and rapeseed salad oil were added, and it stirred and mixed until it became uniform with the spatula, and obtained 1250 g of liquid seasoning compositions.
[Example 5]
In Formulation D of Example 4, 15 parts of fats and oils were increased to 25 parts, and 1350 g of a liquid seasoning composition was obtained in the same manner.
[Example 6]
In Formulation D of Example 4, 15 parts of fats and oils were reduced to 5 parts, and 1150 g of a liquid seasoning composition was obtained in the same manner.

[比較例4]
配合Eにおいて、実施例4と同様の方法で調味素材部を得た後、前記したリン酸架橋タピオカ澱粉の作製に記載のリン酸架橋タピオカ澱粉と菜種サラダ油を加え、攪拌混合し、液体調味組成物1250gを得た。
上記実施例、比較例をまとめたものを表5に示す。
[Comparative Example 4]
In Formulation E, after obtaining a seasoning raw material part by the same method as Example 4, add the phosphoric acid cross-linked tapioca starch and rapeseed salad oil described in the preparation of the phosphoric acid cross-linked tapioca starch, stir and mix, and liquid seasoning composition 1250 g of product was obtained.
Table 5 shows a summary of the above examples and comparative examples.

Figure 0004648916
Figure 0004648916

[調理法:チンジャオロースー]
ピーマン180g、ゆでた竹の子150g、牛モモ肉250gを千切りにし、千切りにした牛肉に実施例4〜6、比較例4の液体調味組成物それぞれ50gをからめて20分間漬け込む。油脂10gをしいたフライパンで牛肉に火がとおるまで牛肉・液体調味組成物を炒め、更に千切りのピーマン・ゆでた竹の子を加え、ピーマンに火がとおるまで炒め合わせ、チンジャオロースーを調理した。
[Cooking method: Chinja Orusu]
Pepper 180 g, boiled bamboo shoot 150 g, and beef leg meat 250 g are chopped, and each of the liquid seasoning compositions of Examples 4 to 6 and Comparative Example 4 is chopped into chopped beef and soaked for 20 minutes. Stir the beef and liquid seasoning composition in a frying pan with 10 g of oil and fat until the beef is on fire, add shredded peppers and boiled bamboo shoots, and stir-fry until the peppers are on fire to cook tinja roast.

調味料組成物と具材のフライパン上での焦げ具合について専門パネル10名により下記評価基準と評点で評価を行った。
焦げの発生が抑制されている (3点)
どちらともいえない (2点)
焦げの発生が抑制されていない(1点)

また、10名の評点の平均値を以下の基準に従って記号化し、結果を表6に示した。
○:評点の平均値が2.5以上
△:評点の平均値が1.5以上、2.5未満
×:評点の平均値が1.5未満
The scoring on the frying pan of the seasoning composition and ingredients was evaluated by the following 10 evaluation panels and scores by 10 expert panels.
Burning is suppressed (3 points)
I can say neither (2 points)
Burning is not suppressed (1 point)

In addition, the average value of the scores of 10 people was symbolized according to the following criteria, and the results are shown in Table 6.
○: Average score value is 2.5 or more Δ: Average score value is 1.5 or more and less than 2.5 ×: Average score value is less than 1.5

Figure 0004648916
Figure 0004648916

表6から本発明の加熱調理用の液体調味組成物は、加熱調理時にフライパンへの食材、調味料の焦げ付きが抑制される事が確認された。一方、比較例4では加熱調理時に焦げの発生が抑制されず好ましくなかった。   From Table 6, it was confirmed that the liquid seasoning composition for cooking of the present invention suppresses scorching of ingredients and seasonings on the frying pan during cooking. On the other hand, in Comparative Example 4, the occurrence of scorching during cooking was not suppressed, which was not preferable.

Claims (1)

油脂および乳化剤を含有する油脂加工澱粉と油脂を含み、油脂加工澱粉が糊化せず分散状態で存在することを特徴とする加熱調理用の液体調味組成物。   A liquid seasoning composition for cooking by heating, comprising an oil and fat processed starch containing fats and oils and an emulsifier, wherein the oil processed starch is not gelatinized and exists in a dispersed state.
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