JP6769412B2 - Sealed battery - Google Patents

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JP6769412B2
JP6769412B2 JP2017164235A JP2017164235A JP6769412B2 JP 6769412 B2 JP6769412 B2 JP 6769412B2 JP 2017164235 A JP2017164235 A JP 2017164235A JP 2017164235 A JP2017164235 A JP 2017164235A JP 6769412 B2 JP6769412 B2 JP 6769412B2
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positive electrode
current collector
electrode current
legs
terminal
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JP2019040837A (en
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松浦 智浩
智浩 松浦
幸男 播磨
幸男 播磨
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Toyota Motor Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Description

本開示は、密閉型電池に関し、特に、密閉型電池内に設けられる集電端子の構成に関する。 The present disclosure relates to a closed-type battery, and more particularly to a configuration of a current collecting terminal provided in the closed-type battery.

特開2007−299536号公報(特許文献1)は、密閉型の角形非水電解質二次電池を開示する。この密閉型電池は、シート状の電極板の電極活物質が塗布されていない未塗布部が積層した状態の端縁部を有する電極体と、電極体の端縁部に溶接される集電端子とを備える。集電端子には複数のスリットが形成されており、電極体の端縁部における集電体がこれらのスリットに挿入された状態で、集電体(電極体)と集電端子とが溶接されている(特許文献1参照)。 Japanese Unexamined Patent Publication No. 2007-299536 (Patent Document 1) discloses a sealed square non-aqueous electrolyte secondary battery. This sealed battery has an electrode body having an edge portion in which uncoated portions of a sheet-shaped electrode plate not coated with the electrode active material are laminated, and a current collecting terminal welded to the edge portion of the electrode body. And. A plurality of slits are formed in the current collector terminal, and the current collector (electrode body) and the current collector terminal are welded together with the current collector at the edge of the electrode body inserted into these slits. (See Patent Document 1).

特開2007−299536号公報JP-A-2007-299536

電極体の集電体がスリットに挿入された状態で集電体と集電端子とが溶接(一般的にはレーザ溶接)される場合には、集電体がスリットにしっかりと挟み込まれるように集電端子に外力(挟力)を加えて集電端子を変形させた状態で、集電体と集電端子との溶接が行なわれる。 When the current collector and the current collector terminal are welded (generally laser welding) with the current collector of the electrode body inserted in the slit, the current collector should be firmly sandwiched in the slit. Welding is performed between the current collector and the current collector terminal in a state where the current collector terminal is deformed by applying an external force (pinching force) to the current collector terminal.

しかしながら、集電端子を変形させた場合に、スリットを形成している脚部が捩れることによりスリットに隙間が残ると、溶接の際にその隙間からレーザ光が抜けたり、溶接に伴ない生じた金属片が電極体側に飛散したりして、電極体に影響を与えるおそれがある。 However, when the current collecting terminal is deformed, if a gap remains in the slit due to twisting of the leg forming the slit, laser light may escape from the gap during welding, or it may occur during welding. The metal pieces may scatter toward the electrode body and affect the electrode body.

本開示は、かかる問題を解決するためになされたものであり、その目的は、集電端子を電極体に良好に溶接可能であるとともに、溶接の際の電極体への影響が抑制された密閉型電池を提供することである。 The present disclosure has been made to solve such a problem, and an object thereof is to seal the current collecting terminal to the electrode body in a good manner and to suppress the influence on the electrode body at the time of welding. It is to provide a mold battery.

本開示の密閉型電池は、電極体と、集電端子とを備える。電極体は、積層された複数の極板を含んで構成され、複数の極板の積層方向に沿う側面に集電体が形成されている。集電端子は、集電体に溶接されている。集電端子は、台座部と、複数の脚部と、部材とを含む。複数の脚部は、台座部から互いに間隔をあけて電極体の上記側面に沿って延びている。集電体は、複数の脚部の間に挟み込まれて複数の脚部に溶接されている。そして、上記部材は、複数の脚部のうちの一の脚部に設けられるとともに一の脚部からその外側に隣接する他の脚部に向けて延び、他の脚部の上記一の脚部の方向への移動を許容しつつ、他の脚部の電極体の方向への移動を規制するように構成される。 The sealed battery of the present disclosure includes an electrode body and a current collecting terminal. The electrode body is configured to include a plurality of laminated electrode plates, and a current collector is formed on a side surface of the plurality of electrode plates along the stacking direction. The current collector terminal is welded to the current collector. The current collecting terminal includes a pedestal portion, a plurality of legs portions, and a member. The plurality of legs extend from the pedestal portion along the side surface of the electrode body at intervals from each other. The current collector is sandwiched between the plurality of legs and welded to the plurality of legs. Then, the member is provided on one leg of the plurality of legs and extends from one leg toward the other leg adjacent to the outside thereof, and the one leg of the other leg. It is configured to regulate the movement of other legs in the direction of the electrode body while allowing the movement in the direction of.

本開示の密閉型電池においては、上記のような部材が集電端子に設けられるので、電極体の集電体を複数の脚部の間に挟み込む際に脚部の捩れが抑制される。これにより、複数の脚部の間に集電体を隙間なくしっかりと挟み込むことができるので、良好な溶接が行なわれるとともに、溶接の際に隙間からレーザ光が抜けたり、溶接に伴ない生じた金属片が電極体側に飛散したりするのを抑制することができる。このように、本開示の密閉型電池によれば、集電端子を電極体に良好に溶接可能であり、かつ、溶接の際の電極体への影響を抑制することができる。 In the sealed battery of the present disclosure, since the above-mentioned member is provided at the current collector terminal, twisting of the leg portion is suppressed when the current collector of the electrode body is sandwiched between the plurality of legs. As a result, the current collector can be firmly sandwiched between the plurality of legs without any gaps, so that good welding can be performed, and laser light can escape from the gaps during welding, which occurs during welding. It is possible to prevent the metal pieces from scattering toward the electrode body side. As described above, according to the sealed battery of the present disclosure, the current collecting terminal can be satisfactorily welded to the electrode body, and the influence on the electrode body at the time of welding can be suppressed.

本開示の実施の形態に従う密閉型電池の断面図である。It is sectional drawing of the closed type battery according to embodiment of this disclosure. 電極体に取付けられた正極集電端子をX方向に視た場合の平面図である。It is a top view when the positive electrode current collector terminal attached to the electrode body is seen in the X direction. 正極集電端子を−X方向から(電極体側から)視た場合の正極集電端子の平面図である。It is a top view of the positive electrode current collecting terminal when the positive electrode current collecting terminal is viewed from the −X direction (from the electrode body side). 図3中のIV-IVに沿った断面図である。It is sectional drawing along IV-IV in FIG. 脚部に外力(挟力)を加えて脚部間のスリットを閉じる際の様子を模式的に示した断面図である。It is sectional drawing which shows typically the state when the slit between the legs is closed by applying an external force (pinching force) to a leg. 脚部に外力(挟力)を加えて脚部間のスリットを閉じる際の様子を模式的に示した断面図である。It is sectional drawing which shows typically the state when the slit between the legs is closed by applying an external force (pinching force) to a leg. 脚部に外力(挟力)を加えて脚部間のスリットを閉じる際の様子を模式的に示した断面図である。It is sectional drawing which shows typically the state when the slit between the legs is closed by applying an external force (pinching force) to a leg. 密閉型電池の製造工程を示すフローチャートである。It is a flowchart which shows the manufacturing process of a closed type battery. 正極シートの平面図である。It is a top view of the positive electrode sheet. 負極シートの平面図である。It is a top view of the negative electrode sheet. 電極体の斜視図である。It is a perspective view of the electrode body. 電極体の斜視図である。It is a perspective view of the electrode body. 集電体予備成形工程S2において正極集電体が成形される様子を模式的に示した図である。It is a figure which showed typically the mode that the positive electrode current collector is molded in the current collector pre-molding step S2. 集電体予備成形工程S2において正極集電体が成形される様子を模式的に示した図である。It is a figure which showed typically the mode that the positive electrode current collector is molded in the current collector pre-molding step S2. 正極集電端子が整形される前の平面図である。It is a top view before the positive electrode current collector terminal is shaped. 正極集電端子にプレート部材が取付けられた様子を示した図である。It is a figure which showed the state which the plate member was attached to the positive electrode current collector terminal. 収容ケースの蓋に、正極外部端子及び負極外部端子、並びに正極集電端子及び負極集電端子が組付けられた様子を示した図である。It is a figure which showed the state which the positive electrode external terminal and the negative electrode external terminal, and the positive electrode current collecting terminal and the negative electrode current collecting terminal were assembled to the lid of the accommodating case. 収容ケースの蓋並びに正極集電端子及び負極集電端子が電極体に組付けられた様子を示した図である。It is a figure which showed the state which the lid of the accommodating case, the positive electrode current collecting terminal and the negative electrode current collecting terminal were assembled to an electrode body. 正極集電端子が電極体に組付けられる様子を示した図である。It is a figure which showed how the positive electrode current collecting terminal is assembled to an electrode body. 正極集電端子の脚部に正極集電体が溶接される様子を示す斜視図である。It is a perspective view which shows the state that the positive electrode current collector is welded to the leg part of the positive electrode current collector terminal. 正極集電端子の脚部に正極集電体が溶接される様子を示す断面図である。It is sectional drawing which shows the state that the positive electrode current collector is welded to the leg part of the positive electrode current collector terminal. 正極集電端子の脚部に正極集電体が溶接される様子を示す断面図である。It is sectional drawing which shows the state that the positive electrode current collector is welded to the leg part of the positive electrode current collector terminal. 正極集電端子の脚部に正極集電体が溶接される様子を示す断面図である。It is sectional drawing which shows the state that the positive electrode current collector is welded to the leg part of the positive electrode current collector terminal. 比較例における正極集電端子を電極体側から視た場合の正極集電端子の平面図である。It is a top view of the positive electrode current collecting terminal when the positive electrode current collecting terminal in the comparative example is seen from the electrode body side. 比較例における正極集電端子をY方向に視た場合の平面図である。It is a top view when the positive electrode current collector terminal in the comparative example is seen in the Y direction. 比較例における、集電端子加圧工程時の正極集電端子の脚部を模式的に示した断面図である。It is sectional drawing which shows typically the leg part of the positive electrode current collector terminal at the time of the current collector terminal pressurization process in the comparative example. 比較例における、集電端子加圧工程時の正極集電端子の脚部を模式的に示した断面図である。It is sectional drawing which shows typically the leg part of the positive electrode current collector terminal at the time of the current collector terminal pressurization process in the comparative example. 比較例において正極集電端子の脚部に正極集電体が溶接される様子を示した断面図である。It is sectional drawing which showed the state that the positive electrode current collector is welded to the leg part of the positive electrode current collector terminal in the comparative example. 本開示の実施の形態に従う密閉型電池と比較例の密閉型電池とにおいて、集電端子と集電体との溶接の評価結果を示した図である。It is a figure which showed the evaluation result of the welding of the current collector terminal and the current collector in the closed type battery which follows the embodiment of this disclosure, and the closed type battery of a comparative example. 実施の形態の変形例1における正極集電端子を−X方向から(電極体側から)視た場合の正極集電端子の平面図である。FIG. 5 is a plan view of the positive electrode current collecting terminal when the positive electrode current collecting terminal in the first modification of the embodiment is viewed from the −X direction (from the electrode body side). 図30中のXXXI-XXXIに沿った断面図である。It is sectional drawing which follows XXXI-XXXI in FIG. 実施の形態の変形例2における正極集電端子を−X方向から(電極体側から)視た場合の正極集電端子の平面図である。FIG. 5 is a plan view of the positive electrode current collecting terminal when the positive electrode current collecting terminal in the second modification of the embodiment is viewed from the −X direction (from the electrode body side). 図32中のXXXIII-XXXIIIに沿った断面図である。It is sectional drawing which follows XXXIII-XXXIII in FIG. 実施の形態の変形例3における正極集電端子を−X方向から(電極体側から)視た場合の正極集電端子の平面図である。FIG. 5 is a plan view of the positive electrode current collecting terminal when the positive electrode current collecting terminal in the modified example 3 of the embodiment is viewed from the −X direction (from the electrode body side). 変形例3において、電極体に取付けられた正極集電端子をX方向に視た場合の平面図である。FIG. 3 is a plan view of the positive electrode current collecting terminal attached to the electrode body in the third modification when viewed in the X direction.

以下、本開示の実施の形態について、図面を参照しながら詳細に説明する。なお、図中同一又は相当部分には同一符号を付してその説明は繰り返さない。 Hereinafter, embodiments of the present disclosure will be described in detail with reference to the drawings. The same or corresponding parts in the drawings are designated by the same reference numerals, and the description thereof will not be repeated.

<密閉型電池の全体構成>
図1は、本開示の実施の形態に従う密閉型電池1の断面図である。図1を参照して、密閉型電池1は、収容ケース2と、電極体3と、電解液6と、正極外部端子9と、負極外部端子10と、正極集電端子11と、負極集電端子12とを備える。電極体3の側面4には、正極集電体7が形成されており、電極体3の側面5には、負極集電体8が形成されている。電極体3、正極集電端子11及び負極集電端子12は、収容ケース2に収容され、収容ケース2内には、電解液6が注入されている。
<Overall configuration of sealed battery>
FIG. 1 is a cross-sectional view of a sealed battery 1 according to an embodiment of the present disclosure. With reference to FIG. 1, the sealed battery 1 includes a housing case 2, an electrode body 3, an electrolytic solution 6, a positive electrode external terminal 9, a negative electrode external terminal 10, a positive electrode current collecting terminal 11, and a negative electrode current collector. It is provided with a terminal 12. A positive electrode current collector 7 is formed on the side surface 4 of the electrode body 3, and a negative electrode current collector 8 is formed on the side surface 5 of the electrode body 3. The electrode body 3, the positive electrode current collecting terminal 11, and the negative electrode current collecting terminal 12 are housed in a storage case 2, and the electrolytic solution 6 is injected into the storage case 2.

収容ケース2は、ケース本体20と、蓋21とを含む。ケース本体20には、上方に向けて開口する開口部が形成されている。蓋21は、ケース本体20の開口部を閉塞するように配置されており、蓋21はケース本体20に溶接されている。蓋21の上面には、正極外部端子9及び負極外部端子10が配置されている。 The storage case 2 includes a case body 20 and a lid 21. The case body 20 is formed with an opening that opens upward. The lid 21 is arranged so as to close the opening of the case body 20, and the lid 21 is welded to the case body 20. A positive electrode external terminal 9 and a negative electrode external terminal 10 are arranged on the upper surface of the lid 21.

電極体3は、複数の正極シートと、複数のセパレータと、複数の負極シートとを含んで構成される(各々については図示せず)。電極体3は、セパレータを挟んで正極シートと負極シートとが交互に順次積層されることで形成されている。 The electrode body 3 includes a plurality of positive electrode sheets, a plurality of separators, and a plurality of negative electrode sheets (each of which is not shown). The electrode body 3 is formed by alternately laminating positive electrode sheets and negative electrode sheets with a separator interposed therebetween.

正極集電体7は、各正極シートの端部が積層されることで形成されており、電極体3の正極を構成する。負極集電体8は、各負極シートの端部が積層されることで形成されており、電極体3の負極を構成する。 The positive electrode current collector 7 is formed by laminating the ends of the positive electrode sheets, and constitutes the positive electrode of the electrode body 3. The negative electrode current collector 8 is formed by laminating the ends of the negative electrode sheets, and constitutes the negative electrode of the electrode body 3.

正極集電端子11は、台座部22と、脚部23と、プレート部材24とを含む。台座部22は、電極体3の上面(電極体3の−Y方向)に配置されており、蓋21に形成された孔を通じて正極外部端子9と電気的に接続される。脚部23は、台座部22に接続されており、電極体3の側面4に沿ってY方向に延びるように設けられる。そして、脚部23は、正極集電体7に溶接されている。なお、図1では示されていないが、脚部23は、互いに間隔(スリット)をあけて側面4に沿って延びる複数の脚部によって構成されている。 The positive electrode current collecting terminal 11 includes a pedestal portion 22, a leg portion 23, and a plate member 24. The pedestal portion 22 is arranged on the upper surface of the electrode body 3 (in the −Y direction of the electrode body 3), and is electrically connected to the positive electrode external terminal 9 through a hole formed in the lid 21. The leg portion 23 is connected to the pedestal portion 22 and is provided so as to extend in the Y direction along the side surface 4 of the electrode body 3. The legs 23 are welded to the positive electrode current collector 7. Although not shown in FIG. 1, the leg portion 23 is composed of a plurality of leg portions extending along the side surface 4 at intervals (slits) from each other.

プレート部材24は、脚部23の電極体3に対向する面であって、脚部23と正極集電体7との接続部よりも上方(台座部22側)に設けられる。このプレート部材24は、脚部23と正極集電体7とを接続(溶接)するにあたって脚部23のスリットに正極集電体7を挟み込む際に、脚部23を構成する複数の脚部の配列乱れを抑制するための部材である。プレート部材24の配置及び構成については、後ほど詳しく説明する。 The plate member 24 is a surface of the leg portion 23 facing the electrode body 3, and is provided above the connecting portion between the leg portion 23 and the positive electrode current collector 7 (on the pedestal portion 22 side). When the positive electrode current collector 7 is sandwiched between the slits of the leg portion 23 when the leg portion 23 and the positive electrode current collector 7 are connected (welded), the plate member 24 is formed by a plurality of leg portions constituting the leg portion 23. It is a member for suppressing arrangement disorder. The arrangement and configuration of the plate member 24 will be described in detail later.

負極集電端子12は、台座部25と、脚部26と、プレート部材27とを含む。台座部25も、電極体3の上面(電極体3の−Y方向)に配置されており、蓋21に形成された孔を通じて負極外部端子10と電気的に接続される。脚部26は、台座部25に接続されており、電極体3の側面5に沿ってY方向に延びるように設けられる。そして、脚部26は、負極集電体8に溶接されている。なお、図1では示されていないが、脚部26も、互いに間隔(スリット)をあけて側面5に沿って延びる複数の脚部によって構成されている。 The negative electrode current collecting terminal 12 includes a pedestal portion 25, a leg portion 26, and a plate member 27. The pedestal portion 25 is also arranged on the upper surface of the electrode body 3 (in the −Y direction of the electrode body 3), and is electrically connected to the negative electrode external terminal 10 through a hole formed in the lid 21. The leg portion 26 is connected to the pedestal portion 25 and is provided so as to extend in the Y direction along the side surface 5 of the electrode body 3. The leg portion 26 is welded to the negative electrode current collector 8. Although not shown in FIG. 1, the leg portion 26 is also composed of a plurality of leg portions extending along the side surface 5 at intervals (slits) from each other.

プレート部材27は、脚部26の電極体3に対向する面であって、脚部26と負極集電体8との接続部よりも上方(台座部25側)に設けられる。このプレート部材27は、脚部26と負極集電体8とを接続(溶接)するにあたって脚部26のスリットに負極集電体8を挟み込む際に、脚部26を構成する複数の脚部の配列乱れを抑制するための部材である。 The plate member 27 is a surface of the leg portion 26 facing the electrode body 3, and is provided above the connecting portion between the leg portion 26 and the negative electrode current collector 8 (on the pedestal portion 25 side). When the negative electrode current collector 8 is sandwiched between the slits of the leg portion 26 when the leg portion 26 and the negative electrode current collector 8 are connected (welded), the plate member 27 is formed by a plurality of leg portions constituting the leg portion 26. It is a member for suppressing arrangement disorder.

<集電端子の構成>
図2は、電極体3に取付けられた正極集電端子11をX方向に視た場合の平面図である。また、図3は、正極集電端子11を−X方向から(電極体3側から)視た場合の正極集電端子11の平面図であり、図4は、図3中のIV-IVに沿った断面図である。なお、負極集電端子12の構成も、正極集電端子11と同様であり、以下では、正極集電端子11について代表的に説明される。
<Current collector terminal configuration>
FIG. 2 is a plan view of the positive electrode current collecting terminal 11 attached to the electrode body 3 when viewed in the X direction. Further, FIG. 3 is a plan view of the positive electrode current collecting terminal 11 when the positive electrode current collecting terminal 11 is viewed from the −X direction (from the electrode body 3 side), and FIG. 4 shows IV-IV in FIG. It is a cross-sectional view along. The configuration of the negative electrode current collecting terminal 12 is the same as that of the positive electrode current collecting terminal 11, and the positive electrode current collecting terminal 11 will be typically described below.

図2から図4を参照して、正極集電端子11の脚部23は、4本の脚部23A〜23Dによって構成される。なお、脚部の本数は、4本に限定されるものではなく、これより多くても少なくてもよい。脚部23A〜23Dの間には、隙間(スリット)が設けられている。正極集電体7は、スリットに合わせて寄り集められ、スリットに挿入されている。そして、スリットの幅を狭めるように脚部23A〜23Dの両側から外力(狭力)を加えながら、スリットに挿入された正極集電体7にレーザ光を照射することによって、溶接部28において脚部23A〜23Dが正極集電体7と溶接される(図2)。 With reference to FIGS. 2 to 4, the leg 23 of the positive electrode current collecting terminal 11 is composed of four legs 23A to 23D. The number of legs is not limited to four, and may be more or less than this. A gap (slit) is provided between the legs 23A to 23D. The positive electrode current collector 7 is gathered together with the slit and inserted into the slit. Then, while applying external force (narrow force) from both sides of the legs 23A to 23D so as to narrow the width of the slit, the positive electrode current collector 7 inserted in the slit is irradiated with the laser beam, so that the leg is formed at the welded portion 28. The portions 23A to 23D are welded to the positive electrode current collector 7 (FIG. 2).

プレート部材24は、プレート部材24A,24Bによって構成される。プレート部材24A,24Bは、脚部23の裏面側(電極体3側)において、電極体3の正極集電体7よりも上方(台座部22に近い側)に設けられる。プレート部材24A,24Bは、接合部29によってそれぞれ脚部23B,23Cに接合されている。そして、プレート部材24Aは、脚部23Bからその外側に隣接する脚部23Aに向けて延び、かつ、脚部23Aにかかるように形成されている。プレート部材24Bは、脚部23Cからその外側に隣接する脚部23Dに向けて延び、かつ、脚部23Dにかかるように形成されている。 The plate member 24 is composed of plate members 24A and 24B. The plate members 24A and 24B are provided on the back surface side (electrode body 3 side) of the leg portion 23, above the positive electrode current collector 7 of the electrode body 3 (side close to the pedestal portion 22). The plate members 24A and 24B are joined to the legs 23B and 23C by the joints 29, respectively. The plate member 24A is formed so as to extend from the leg portion 23B toward the leg portion 23A adjacent to the outside thereof and to hang on the leg portion 23A. The plate member 24B is formed so as to extend from the leg portion 23C toward the leg portion 23D adjacent to the outside thereof and to extend over the leg portion 23D.

このようなプレート部材24が設けられることにより、脚部23A〜23Dと正極集電体7との溶接に際して脚部23A〜23D間のスリットに正極集電体7を挟み込んで脚部23A〜23Dの両側から外力(狭力)を加えた場合に、脚部23A〜23Dの配列の乱れが抑制される。これにより、脚部23A〜23Dの間に正極集電体7が隙間なくしっかりと挟み込まれるので、溶接部28において良好な溶接が行なわれるとともに、溶接の際に隙間からレーザ光が抜けたり、溶接に伴ない生じた金属片が電極体3側に飛散したりするのを抑制することができる。 By providing such a plate member 24, the positive electrode current collector 7 is sandwiched in the slit between the legs 23A to 23D when welding the leg portions 23A to 23D and the positive electrode current collector 7, and the leg portions 23A to 23D are provided. When an external force (narrow force) is applied from both sides, the disorder of the arrangement of the legs 23A to 23D is suppressed. As a result, the positive electrode current collector 7 is firmly sandwiched between the legs 23A to 23D without any gaps, so that good welding is performed at the welded portion 28, and laser light escapes from the gaps during welding or welding. It is possible to prevent the metal pieces generated in the process from scattering toward the electrode body 3.

図5から図7は、脚部23A〜23Dに外力(挟力)を加えて脚部23A〜23D間のスリットを閉じる際の様子を模式的に示した断面図である。図5は、スリットが閉じられる前の脚部23A〜23Dの配置を示す。図6は、脚部23A〜23Dに挟力を加えることによって、脚部23A,23B間のスリット及び脚部23C,23D間のスリットが閉じた場合の脚部23A〜23Dの配置を示す。図7は、さらに挟力を加えることによって、脚部23B,23C間のスリットも閉じた場合の脚部23A〜23Dの配置を示す。なお、実際には、脚部23A〜23D間には、正極集電体7が挟み込まれているので、図6,7に示されるようにスリットが完全に閉じることはない。 5 to 7 are cross-sectional views schematically showing a state when an external force (pinching force) is applied to the legs 23A to 23D to close the slit between the legs 23A to 23D. FIG. 5 shows the arrangement of the legs 23A to 23D before the slit is closed. FIG. 6 shows the arrangement of the legs 23A to 23D when the slits between the legs 23A and 23B and the slits between the legs 23C and 23D are closed by applying a pinching force to the legs 23A to 23D. FIG. 7 shows the arrangement of the legs 23A to 23D when the slit between the legs 23B and 23C is also closed by further applying a pinching force. In reality, since the positive electrode current collector 7 is sandwiched between the legs 23A to 23D, the slits are not completely closed as shown in FIGS. 6 and 7.

図6に示されるように、スリットを閉じるように脚部23A,23DにZ方向の外力(挟力)を加えることによって脚部23A,23DをZ方向に移動(変形)させると、脚部23A,23Dの根元が台座部22(図示せず)に接続されていることにより、脚部23A,23Dには、矢印で示されるようなねじりモーメントが発生する。しかしながら、この実施の形態に従う密閉型電池1では、プレート部材24A,24Bがストッパーとなって脚部23A,23Dの捩れが抑制される。その結果、図7に示されるように、脚部23A,23Dからそれぞれ荷重を受ける脚部23B,23Cの捩れも抑制される。 As shown in FIG. 6, when the legs 23A and 23D are moved (deformed) in the Z direction by applying an external force (pinching force) in the Z direction to the legs 23A and 23D so as to close the slit, the legs 23A Since the roots of the legs 23A and 23D are connected to the pedestal portion 22 (not shown), a twisting moment as shown by an arrow is generated in the leg portions 23A and 23D. However, in the sealed battery 1 according to this embodiment, the plate members 24A and 24B serve as stoppers to suppress the twisting of the legs 23A and 23D. As a result, as shown in FIG. 7, twisting of the legs 23B and 23C, which receive loads from the legs 23A and 23D, respectively, is also suppressed.

このように、脚部23A(23D)の脚部23B(23C)の方向への移動を許容しつつ、脚部23A(23D)の電極体3の方向への移動を規制するプレート部材24A(24B)が設けられることにより、正極集電体7を寄り集めて脚部23A〜23Dの間のスリットに挟み込む際に、脚部23A〜23Dの捩れが抑制され、脚部23A〜23Dの配列の乱れが抑制される。 In this way, the plate member 24A (24B) restricts the movement of the leg 23A (23D) in the direction of the electrode body 3 while allowing the leg 23A (23D) to move in the direction of the leg 23B (23C). ) Is provided, so that when the positive electrode current collectors 7 are gathered together and sandwiched in the slit between the legs 23A to 23D, the twisting of the legs 23A to 23D is suppressed and the arrangement of the legs 23A to 23D is disturbed. Is suppressed.

<密閉型電池の製造方法>
図8は、密閉型電池1の製造工程を示すフローチャートである。図8を参照して、密閉型電池1の製造工程は、電極体成形工程S1と、集電体予備成形工程S2と、集電端子成形工程S3と、プレート板取付工程S4と、蓋成形工程S5と、蓋・電極体組付工程S6と、集電端子加圧工程S7と、集電端子溶接工程S8と、収容工程S9と、蓋溶接工程S10と、注入工程S11と、封止工程S12とを含む。
<Manufacturing method of sealed battery>
FIG. 8 is a flowchart showing a manufacturing process of the sealed battery 1. With reference to FIG. 8, the manufacturing process of the sealed battery 1 includes an electrode body molding step S1, a current collector preforming step S2, a current collecting terminal molding step S3, a plate plate mounting step S4, and a lid molding step. S5, lid / electrode body assembly step S6, current collecting terminal pressurizing step S7, current collecting terminal welding step S8, accommodating step S9, lid welding step S10, injection step S11, and sealing step S12. And include.

電極体成形工程S1では、複数の正極シート及び負極シートが作製され、絶縁体のセパレータを挟んで正極シートと負極シートとが交互に順次積層されることで電極体3が形成される。 In the electrode body forming step S1, a plurality of positive electrode sheets and negative electrode sheets are produced, and the positive electrode body 3 is formed by alternately laminating the positive electrode sheets and the negative electrode sheets with the insulator separator interposed therebetween.

図9は、正極シートの平面図である。図9を参照して、正極シート30は、アルミ合金箔シートの表裏面に塗布される矩形状の活物質合剤層31と、アルミ合金箔シートの一辺に設けられる未塗布部が所定の寸法にカットされた未塗工箔部32とを含む。未塗工箔部32は、正極シート30において活物質合剤層31が形成されていない部分であり、アルミ合金箔シートが活物質合剤層31から露出した部分である。この未塗工箔部32は、正極シート30、負極シート33及びセパレータが積層されて電極体3が形成されたときに正極集電体7となる。 FIG. 9 is a plan view of the positive electrode sheet. With reference to FIG. 9, in the positive electrode sheet 30, the rectangular active material mixture layer 31 coated on the front and back surfaces of the aluminum alloy foil sheet and the uncoated portion provided on one side of the aluminum alloy foil sheet have predetermined dimensions. Includes the uncoated foil portion 32 cut into. The uncoated foil portion 32 is a portion of the positive electrode sheet 30 where the active material mixture layer 31 is not formed, and is a portion where the aluminum alloy foil sheet is exposed from the active material mixture layer 31. The uncoated foil portion 32 becomes a positive electrode current collector 7 when the positive electrode sheet 30, the negative electrode sheet 33 and the separator are laminated to form the electrode body 3.

図10は、負極シートの平面図である。図10を参照して、負極シート33は、銅箔シートの表裏面に塗布される矩形状の活物質合剤層34と、銅箔シートの一辺に設けられる未塗布部が所定の寸法にカットされた未塗工箔部35とを含む。未塗工箔部35は、負極シート33において活物質合剤層34が形成されていない部分であり、銅箔シートが活物質合剤層34から露出した部分である。この未塗工箔部35は、正極シート30、負極シート33及びセパレータが積層されて電極体3が形成されたときに負極集電体8となる。 FIG. 10 is a plan view of the negative electrode sheet. With reference to FIG. 10, in the negative electrode sheet 33, the rectangular active material mixture layer 34 coated on the front and back surfaces of the copper foil sheet and the uncoated portion provided on one side of the copper foil sheet are cut to predetermined dimensions. Includes the unpainted foil portion 35 and the like. The uncoated foil portion 35 is a portion of the negative electrode sheet 33 where the active material mixture layer 34 is not formed, and is a portion where the copper foil sheet is exposed from the active material mixture layer 34. The uncoated foil portion 35 becomes the negative electrode current collector 8 when the positive electrode sheet 30, the negative electrode sheet 33 and the separator are laminated to form the electrode body 3.

図11は、電極体3の斜視図である。図11を参照して、電極体3は、多孔質絶縁層を含むセパレータ(図示せず)を挟んで、正極シート30(図9)と負極シート33(図10)とを交互に順次積層することによって形成される。このとき、複数の正極シート30は、図示されるように各正極シート30の未塗工箔部32が揃うように積層され、積層された未塗工箔部32によって正極集電体7が構成される。 FIG. 11 is a perspective view of the electrode body 3. With reference to FIG. 11, in the electrode body 3, the positive electrode sheet 30 (FIG. 9) and the negative electrode sheet 33 (FIG. 10) are alternately and sequentially laminated with a separator (not shown) containing a porous insulating layer interposed therebetween. Formed by At this time, as shown in the figure, the plurality of positive electrode sheets 30 are laminated so that the uncoated foil portions 32 of each positive electrode sheet 30 are aligned, and the laminated uncoated foil portions 32 form the positive electrode current collector 7. Will be done.

なお、図示されていないが、複数の負極シート33は、正極シート30の未塗工箔部32と反対側において各負極シート33の未塗工箔部35が揃うように積層され、積層された未塗工箔部35によって負極集電体8が構成される。 Although not shown, the plurality of negative electrode sheets 33 are laminated and laminated so that the uncoated foil portions 35 of each negative electrode sheet 33 are aligned on the side opposite to the uncoated foil portion 32 of the positive electrode sheet 30. The negative electrode current collector 8 is formed by the uncoated foil portion 35.

再び図8を参照して、集電体予備成形工程S2では、正極集電端子11の脚部23A〜23D間のスリットに正極集電体7を挿入可能なように正極集電体7が成形される。この実施の形態では、図12に示されるように、正極集電端子11のスリット数(3つ)に合わせて、正極集電体7は3つの集合体に成形されている。なお、図示されていないが、負極側においても、負極集電端子12の脚部間のスリットに負極集電体8を挿入可能なように負極集電体8が成形される。 With reference to FIG. 8 again, in the current collector preforming step S2, the positive electrode current collector 7 is formed so that the positive electrode current collector 7 can be inserted into the slit between the legs 23A to 23D of the positive electrode current collector terminal 11. Will be done. In this embodiment, as shown in FIG. 12, the positive electrode current collector 7 is formed into three aggregates according to the number of slits (three) of the positive electrode current collector terminal 11. Although not shown, the negative electrode current collector 8 is also formed on the negative electrode side so that the negative electrode current collector 8 can be inserted into the slit between the legs of the negative electrode current collector terminal 12.

図13及び図14は、集電体予備成形工程S2において正極集電体7が成形される様子を模式的に示した図である。図13及び図14を参照して、正極集電体7の成形は、集箔治具50,51を用いて行なわれる。集箔治具50,51は、先端部が凸形状をしており、集箔治具50,51を正極集電体7に向けて移動させた後、集箔治具50,51で正極集電体7を挟み込むことによって、正極集電体7の成形(癖付け)が行なわれる。 13 and 14 are diagrams schematically showing how the positive electrode current collector 7 is molded in the current collector preforming step S2. With reference to FIGS. 13 and 14, the positive electrode current collector 7 is formed by using the foil collecting jigs 50 and 51. The foil collecting jigs 50 and 51 have a convex shape at the tip, and after moving the foil collecting jigs 50 and 51 toward the positive electrode current collector 7, the foil collecting jigs 50 and 51 collect the positive electrodes. By sandwiching the electric body 7, the positive electrode current collector 7 is formed (habited).

再び図8を参照して、集電端子成形工程S3では、正極集電端子11及び負極集電端子12が作製される。 With reference to FIG. 8 again, in the current collecting terminal forming step S3, the positive electrode current collecting terminal 11 and the negative electrode current collecting terminal 12 are manufactured.

図15は、正極集電端子11が整形される前の平面図である。図15を参照して、正極集電端子11は、アルミ製であり、アルミ板を所定の型で打ち抜くことによって、正極集電端子11の原板が成形される。この原板には、台座部22と、台座部22から延びる脚部23A〜23Dとが設けられており、図の点線において90度に折り曲げることによって正極集電端子11が成形される。なお、図示されていないが、負極集電端子12は、銅製であり、銅板を所定の型で打ち抜くことによって負極集電端子12の原板が成形され、正極集電端子11と同様に折り曲げることによって負極集電端子12が成形される。 FIG. 15 is a plan view of the positive electrode current collecting terminal 11 before being shaped. With reference to FIG. 15, the positive electrode current collecting terminal 11 is made of aluminum, and the original plate of the positive electrode current collecting terminal 11 is formed by punching an aluminum plate with a predetermined mold. The original plate is provided with a pedestal portion 22 and legs 23A to 23D extending from the pedestal portion 22, and the positive electrode current collecting terminal 11 is formed by bending the original plate at 90 degrees along the dotted line in the figure. Although not shown, the negative electrode current collecting terminal 12 is made of copper, and the original plate of the negative electrode current collecting terminal 12 is formed by punching a copper plate with a predetermined mold, and the original plate is bent in the same manner as the positive electrode current collecting terminal 11. The negative electrode current collecting terminal 12 is formed.

再び図8を参照して、プレート板取付工程S4では、正極集電端子11にプレート部材24が取付けられ、負極集電端子12にプレート部材27が取付けられる。 With reference to FIG. 8 again, in the plate plate attaching step S4, the plate member 24 is attached to the positive electrode current collecting terminal 11 and the plate member 27 is attached to the negative electrode current collecting terminal 12.

図16は、正極集電端子11にプレート部材24が取付けられた様子を示した図である。図16を参照して、台座部22は、複数の脚部23A〜23Dに対して90度に折り曲げられている(この図では、紙面手前側に折り曲げられている。)。そして、台座部22が折り曲げられた側の脚部23A〜23Dの面に、プレート部材24(24A,24B)が取付けられる。 FIG. 16 is a diagram showing a state in which the plate member 24 is attached to the positive electrode current collecting terminal 11. With reference to FIG. 16, the pedestal portion 22 is bent 90 degrees with respect to the plurality of leg portions 23A to 23D (in this figure, it is bent toward the front side of the paper surface). Then, the plate members 24 (24A, 24B) are attached to the surfaces of the legs 23A to 23D on the side where the pedestal portion 22 is bent.

プレート部材24(24A,24B)は、正極集電端子11が電極体3に組付けられた場合に、電極体3の正極集電体7よりも上方(台座部22側)に位置するように正極集電端子11に取付けられる。具体的には、プレート部材24Aは、脚部23Bからその外側に隣接する脚部23Aに向けて延び、かつ脚部23Aにかかるように、接合部29によって脚部23Bに取付けられる。プレート部材24Bは、脚部23Cからその外側に隣接する脚部23Dに向けて延び、かつ脚部23Dにかかるように、接合部29によって脚部23Cに取付けられる。なお、負極集電端子12についても、同様にしてプレート部材27が取付けられる。 The plate members 24 (24A, 24B) are located above the positive electrode current collector 7 (pedestal portion 22 side) of the electrode body 3 when the positive electrode current collector terminal 11 is assembled to the electrode body 3. It is attached to the positive electrode current collecting terminal 11. Specifically, the plate member 24A is attached to the leg portion 23B by the joint portion 29 so as to extend from the leg portion 23B toward the leg portion 23A adjacent to the outside thereof and to cover the leg portion 23A. The plate member 24B is attached to the leg portion 23C by the joint portion 29 so as to extend from the leg portion 23C toward the leg portion 23D adjacent to the outside thereof and to cover the leg portion 23D. The plate member 27 is also attached to the negative electrode current collector terminal 12 in the same manner.

再び図8を参照して、蓋成形工程S5では、収容ケース2の蓋21に、正極外部端子9、負極外部端子10、正極集電端子11、及び負極集電端子12が組付けられる。 With reference to FIG. 8 again, in the lid forming step S5, the positive electrode external terminal 9, the negative electrode external terminal 10, the positive electrode current collecting terminal 11, and the negative electrode current collecting terminal 12 are assembled to the lid 21 of the housing case 2.

図17は、収容ケース2の蓋21に、正極外部端子9及び負極外部端子10、並びに正極集電端子11及び負極集電端子12が組付けられた様子を示した図である。図17を参照して、蓋21の上面の一方端に正極外部端子9が組付けられ、蓋21の上面の他方端に負極外部端子10が組付けられる。 FIG. 17 is a diagram showing a state in which the positive electrode external terminal 9 and the negative electrode external terminal 10, and the positive electrode current collecting terminal 11 and the negative electrode current collecting terminal 12 are assembled to the lid 21 of the housing case 2. With reference to FIG. 17, the positive electrode external terminal 9 is assembled to one end of the upper surface of the lid 21, and the negative electrode external terminal 10 is assembled to the other end of the upper surface of the lid 21.

そして、正極外部端子9の下方において、蓋21の下面に正極集電端子11が組付けられ、蓋21に形成される穴を通じて正極外部端子9と正極集電端子11の台座部22とが電気的に接続される。同様に、負極外部端子10の下方において、蓋21の下面に負極集電端子12が組付けられ、蓋21に形成される穴を通じて負極外部端子10と負極集電端子12の台座部25とが電気的に接続される。 Then, below the positive electrode external terminal 9, the positive electrode current collecting terminal 11 is assembled on the lower surface of the lid 21, and the positive electrode external terminal 9 and the pedestal portion 22 of the positive electrode current collecting terminal 11 are electrically connected through a hole formed in the lid 21. Is connected. Similarly, below the negative electrode external terminal 10, the negative electrode current collecting terminal 12 is assembled on the lower surface of the lid 21, and the negative electrode external terminal 10 and the pedestal portion 25 of the negative electrode current collecting terminal 12 are connected through a hole formed in the lid 21. It is electrically connected.

再び図8を参照して、蓋・電極体組付工程S6では、蓋成形工程S5で組付けられた蓋21、正極外部端子9、負極外部端子10、正極集電端子11、及び負極集電端子12が、電極体3に組付けられる。 With reference to FIG. 8 again, in the lid / electrode body assembling step S6, the lid 21, the positive electrode external terminal 9, the negative electrode external terminal 10, the positive electrode current collecting terminal 11, and the negative electrode current collecting as assembled in the lid molding step S5. The terminal 12 is assembled to the electrode body 3.

図18は、収容ケース2の蓋21並びに正極集電端子11及び負極集電端子12が電極体3に組付けられた様子を示した図である。図19は、正極集電端子11が電極体3に組付けられる様子を示した図である。 FIG. 18 is a diagram showing a state in which the lid 21, the positive electrode current collecting terminal 11, and the negative electrode current collecting terminal 12 of the accommodating case 2 are assembled to the electrode body 3. FIG. 19 is a diagram showing how the positive electrode current collecting terminal 11 is assembled to the electrode body 3.

図18及び図19を参照して、蓋21並びに正極集電端子11及び負極集電端子12が電極体3の上方から電極体3に組付けられる。このとき、正極集電端子11の脚部23のスリットに正極集電体7が挿入されるように、正極集電端子11が電極体3に組付けられる。なお、図示していないが、負極側についても、負極集電端子12の脚部26のスリットに負極集電体8が挿入されるように、負極集電端子12が電極体3に組付けられる。 With reference to FIGS. 18 and 19, the lid 21, the positive electrode current collecting terminal 11 and the negative electrode current collecting terminal 12 are assembled to the electrode body 3 from above the electrode body 3. At this time, the positive electrode current collector terminal 11 is assembled to the electrode body 3 so that the positive electrode current collector 7 is inserted into the slit of the leg 23 of the positive electrode current collector terminal 11. Although not shown, the negative electrode current collector terminal 12 is also assembled to the electrode body 3 on the negative electrode side so that the negative electrode current collector 8 is inserted into the slit of the leg 26 of the negative electrode current collector terminal 12. ..

再び図8を参照して、集電端子加圧工程S7では、正極集電端子11の脚部23が両側面から加圧され、脚部23と正極集電体7との隙間が狭められる。同様に、負極集電端子12の脚部26も両側面から加圧され、脚部26と負極集電体8との隙間が狭められる。 With reference to FIG. 8 again, in the current collecting terminal pressurizing step S7, the legs 23 of the positive electrode current collecting terminal 11 are pressurized from both side surfaces, and the gap between the legs 23 and the positive electrode current collector 7 is narrowed. Similarly, the legs 26 of the negative electrode current collector terminal 12 are also pressurized from both side surfaces, and the gap between the legs 26 and the negative electrode current collector 8 is narrowed.

集電端子溶接工程S8では、正極集電端子11の脚部23と正極集電体7とが溶接され、負極集電端子12の脚部26と負極集電体8とが溶接される。 In the current collecting terminal welding step S8, the leg portion 23 of the positive electrode current collecting terminal 11 and the positive electrode current collector 7 are welded, and the leg portion 26 of the negative electrode current collecting terminal 12 and the negative electrode current collector 8 are welded.

図20は、正極集電端子11の脚部23に正極集電体7が溶接される様子を示す斜視図である。図21から図23は、正極集電端子11の脚部23に正極集電体7が溶接される様子を示す断面図である。 FIG. 20 is a perspective view showing how the positive electrode current collector 7 is welded to the legs 23 of the positive electrode current collector terminal 11. 21 to 23 are cross-sectional views showing how the positive electrode current collector 7 is welded to the legs 23 of the positive electrode current collector terminal 11.

図20から図23を参照して、正極集電体7の先端部は、脚部23A〜23D間のスリットから突出している。集電端子加圧工程S7において脚部23A〜23Dを両側面から加圧した状態で、正極集電体7の先端部にレーザ光LBを照射することによって、正極集電体7が脚部23A〜23Dに溶接される。 With reference to FIGS. 20 to 23, the tip of the positive electrode current collector 7 projects from the slit between the legs 23A to 23D. In the current collector terminal pressurizing step S7, the positive electrode current collector 7 is subjected to the leg 23A by irradiating the tip of the positive electrode current collector 7 with the laser beam LB while the legs 23A to 23D are pressurized from both sides. Welded to ~ 23D.

この実施の形態では、脚部23A〜23Dにプレート部材24(24A,24B)が設けられることにより、集電端子加圧工程S7における脚部23A〜23Dへの加圧の際に脚部の捩れが抑制され、脚部23A〜23Dの配列の乱れが抑制されている。これにより、集電端子加圧工程S7において、脚部23A〜23Dの間に正極集電体7を隙間なくしっかりと挟み込むことができており、溶接部28において脚部23A〜23Dを正極集電体7と良好に溶接できている。 In this embodiment, since the plate members 24 (24A, 24B) are provided on the legs 23A to 23D, the legs are twisted when the legs 23A to 23D are pressurized in the current collecting terminal pressurizing step S7. Is suppressed, and the disorder of the arrangement of the legs 23A to 23D is suppressed. As a result, in the current collecting terminal pressurizing step S7, the positive electrode current collector 7 can be firmly sandwiched between the legs 23A to 23D without any gap, and the legs 23A to 23D are collected by the positive electrode in the welded portion 28. It is well welded to the body 7.

再び図8を参照して、収容工程S9では、電極体3、並びに電極体3に組付けられた蓋21、正極集電端子11及び負極集電端子12が、収容ケース2のケース本体20に収容される。蓋21は、ケース本体20の開口部を閉塞するように配置される。 With reference to FIG. 8 again, in the accommodating step S9, the electrode body 3, the lid 21, the positive electrode current collecting terminal 11 and the negative electrode current collecting terminal 12 assembled to the electrode body 3 are attached to the case body 20 of the accommodating case 2. Be housed. The lid 21 is arranged so as to close the opening of the case body 20.

蓋溶接工程S10では、蓋21の外周縁部とケース本体20の開口縁部とが溶接される。注入工程S11では、蓋21の図示しない注入口から収容ケース2内に電解液6が注入される。そして、封止工程S12において、上記の注入口が封止部材で閉塞される。これにより、図1に示した密閉型電池1が完成する。 In the lid welding step S10, the outer peripheral edge of the lid 21 and the opening edge of the case body 20 are welded. In the injection step S11, the electrolytic solution 6 is injected into the storage case 2 from an injection port (not shown) of the lid 21. Then, in the sealing step S12, the injection port is closed by the sealing member. As a result, the sealed battery 1 shown in FIG. 1 is completed.

<比較例の説明>
以下では、正極集電端子11及び負極集電端子12にそれぞれプレート部材24,27が設けられていない比較例について簡単に説明する。
<Explanation of comparative example>
Hereinafter, a comparative example in which the plate members 24 and 27 are not provided on the positive electrode current collecting terminal 11 and the negative electrode current collecting terminal 12, respectively, will be briefly described.

図24は、比較例における正極集電端子を電極体側から視た場合の正極集電端子の平面図である。図25は、比較例における正極集電端子をY方向に視た場合の平面図である。図24及び図25を参照して、比較例における正極集電端子には、実施の形態におけるプレート部材24が設けられていない。そして、集電端子加圧工程において、正極集電端子の脚部を両側面から加圧すると、外側の脚部23A,23Dが荷重方向に変形する。 FIG. 24 is a plan view of the positive electrode current collecting terminal when the positive electrode current collecting terminal in the comparative example is viewed from the electrode body side. FIG. 25 is a plan view of the positive electrode current collecting terminal in the comparative example when viewed in the Y direction. With reference to FIGS. 24 and 25, the positive electrode current collector terminal in the comparative example is not provided with the plate member 24 according to the embodiment. Then, in the current collecting terminal pressurizing step, when the legs of the positive electrode current collecting terminal are pressurized from both side surfaces, the outer legs 23A and 23D are deformed in the load direction.

図26及び図27は、比較例における、集電端子加圧工程時の正極集電端子の脚部を模式的に示した断面図である。図26は、脚部23A〜23Dに挟力を加えることによって、脚部23A,23B間のスリット及び脚部23C,23D間のスリットが閉じた場合の脚部23A〜23Dの配置を示す。図27は、さらに挟力を加えることによって、脚部23B,23C間のスリットも閉じた場合の脚部23A〜23Dの配置を示す。なお、実際には、脚部23A〜23D間には、正極集電体が挟み込まれているので、図26,27に示されるようにスリットが完全に閉じることはない。 26 and 27 are cross-sectional views schematically showing the legs of the positive electrode current collector terminal during the current collector terminal pressurization step in the comparative example. FIG. 26 shows the arrangement of the legs 23A to 23D when the slits between the legs 23A and 23B and the slits between the legs 23C and 23D are closed by applying a pinching force to the legs 23A to 23D. FIG. 27 shows the arrangement of the legs 23A to 23D when the slit between the legs 23B and 23C is also closed by further applying a pinching force. In reality, since the positive electrode current collector is sandwiched between the legs 23A to 23D, the slits are not completely closed as shown in FIGS. 26 and 27.

図26及び図27とともに図25も参照して、比較例における正極集電端子には、本開示の実施の形態におけるプレート部材24が設けられていないので、集電端子加圧工程において脚部23A〜23DにZ方向の外力(挟力)を加えると、スリットの根元を基点に(図25)脚部23A,23Dが捩れ、脚部23A,23Dのスリット側(脚部23Aの脚部23Bと隣接する側、及び脚部23Dの脚部23Cと隣接する側)がX方向(電極体の方向)に変形する。 With reference to FIGS. 26 and 27 as well as FIG. 25, the positive electrode current collecting terminal in the comparative example is not provided with the plate member 24 according to the embodiment of the present disclosure. When an external force (pinching force) in the Z direction is applied to ~ 23D, the legs 23A and 23D are twisted from the base of the slit (FIG. 25), and the legs 23A and 23D are twisted on the slit side (the legs 23B of the legs 23A). The adjacent side and the side of the leg 23D adjacent to the leg 23C) are deformed in the X direction (direction of the electrode body).

そして、脚部23B,23C間のスリットも閉じる程度に脚部23A〜23Dにさらに外力(挟力)が加えられると(図27)、脚部23B,23C間のスリットの根元がY方向に変形し、その結果、脚部23B,23Cが−X方向(脚部23A,23Dと反対方向)に変形する。 When an external force (pinching force) is further applied to the legs 23A to 23D to the extent that the slit between the legs 23B and 23C is also closed (FIG. 27), the base of the slit between the legs 23B and 23C is deformed in the Y direction. As a result, the legs 23B and 23C are deformed in the −X direction (the direction opposite to the legs 23A and 23D).

このように、比較例では、集電端子加圧工程において脚部23A〜23Dを両側面から加圧すると、外側の脚部23A,23Dは捩れ、内側の脚部23B,23Cも変形する。このため、集電端子加圧工程において脚部23A〜23Dの配列が乱れ、脚部23A〜23Dと正極集電体7との間に隙間が残ってしまう。この状態で集電端子溶接工程において脚部23A〜23Dと正極集電体との溶接が行なわれると、隙間からレーザ光が抜けたり、溶接に伴ない生じた金属片が電極体側に飛散したりするおそれがある。 As described above, in the comparative example, when the legs 23A to 23D are pressurized from both side surfaces in the current collecting terminal pressurizing step, the outer legs 23A and 23D are twisted and the inner legs 23B and 23C are also deformed. Therefore, the arrangement of the legs 23A to 23D is disturbed in the current collecting terminal pressurizing step, and a gap remains between the legs 23A to 23D and the positive electrode current collector 7. If the legs 23A to 23D are welded to the positive electrode current collector in the current collector terminal welding process in this state, the laser beam may escape from the gap or the metal pieces generated by the welding may be scattered toward the electrode body. There is a risk of

図28は、比較例において正極集電端子の脚部23に正極集電体7が溶接される様子を示した断面図である。図28を参照して、脚部23A〜23D間のスリットから突出した正極集電体7の先端部にレーザ光LBを照射することによって、正極集電体7が脚部23A〜23Dに溶接される。 FIG. 28 is a cross-sectional view showing how the positive electrode current collector 7 is welded to the legs 23 of the positive electrode current collector terminal in the comparative example. With reference to FIG. 28, the positive electrode current collector 7 is welded to the legs 23A to 23D by irradiating the tip of the positive electrode current collector 7 protruding from the slit between the legs 23A to 23D with the laser beam LB. To.

比較例では、脚部23A〜23Dの配列に乱れが生じているため、脚部23A〜23Dと正極集電体7との間に隙間が生じているおそれがある。そうすると、その隙間からレーザ光LBが抜けたり、図示されるように、溶接に伴ない生じた金属片が電極体側(集電体側)に飛散したりする可能性がある。 In the comparative example, since the arrangement of the legs 23A to 23D is disturbed, there is a possibility that a gap is formed between the legs 23A to 23D and the positive electrode current collector 7. Then, the laser beam LB may escape from the gap, or as shown in the figure, metal pieces generated by welding may be scattered toward the electrode body side (current collector side).

これに対して、この実施の形態に従う密閉型電池1では、図2から図7に示したように、脚部23A(23D)の脚部23B(23C)の方向への移動を許容しつつ、脚部23A(23D)の電極体3の方向への移動を規制するプレート部材24A(24B)が設けられる。これにより、集電端子加圧工程S7において、脚部23A〜23D間のスリットに正極集電体7を挟み込んだ場合に、図5から図7に示したように、脚部23A〜23Dの配列の乱れが抑制され、脚部23A〜23D間に正極集電体7を隙間なくしっかりと挟み込むことができる。その結果、良好な溶接が行なわれるとともに、溶接の際に隙間からレーザ光LBが抜けたり、溶接に伴ない生じた金属片が電極体3側に飛散したりするのを抑制することができる。 On the other hand, in the sealed battery 1 according to this embodiment, as shown in FIGS. 2 to 7, the legs 23A (23D) are allowed to move in the direction of the legs 23B (23C) while being allowed to move. A plate member 24A (24B) for restricting the movement of the leg portion 23A (23D) in the direction of the electrode body 3 is provided. As a result, in the current collector terminal pressurizing step S7, when the positive electrode current collector 7 is sandwiched between the slits between the legs 23A to 23D, the legs 23A to 23D are arranged as shown in FIGS. 5 to 7. The disturbance of the current collector 7 is suppressed, and the positive electrode current collector 7 can be firmly sandwiched between the legs 23A to 23D without any gap. As a result, good welding can be performed, and it is possible to prevent the laser beam LB from coming out from the gap during welding and the metal pieces generated by welding from being scattered toward the electrode body 3.

図29は、本開示の実施の形態に従う密閉型電池1と、上記の比較例の密閉型電池とにおいて、集電端子と集電体との溶接の評価結果を示した図である。溶接の評価においては、溶接箇所を分解し、レーザ光抜けによるセパレータの損傷ダメージを確認するとともに、溶融物の飛散の有無を確認した。セパレータの損傷ダメージについては、熱による透明化部がセパレータに生じていないかを拡大鏡で確認した。溶融物の飛散については、集電端子の裏側の飛散物の有無を拡大鏡で確認した。評価については、セパレータの損傷ダメージがなく、かつ、溶融物の飛散もなかったものを良品(評価OK)とした。 FIG. 29 is a diagram showing the evaluation results of welding between the current collector terminal and the current collector in the sealed battery 1 according to the embodiment of the present disclosure and the sealed battery of the above comparative example. In the evaluation of welding, the welded part was disassembled, damage to the separator due to laser light leakage was confirmed, and the presence or absence of scattered melt was confirmed. Damage to the separator Regarding damage, it was confirmed with a magnifying glass whether or not a transparent part due to heat was generated on the separator. Regarding the scattering of the melt, the presence or absence of the scattering on the back side of the current collector terminal was confirmed with a magnifying glass. Regarding the evaluation, those with no damage to the separator and no scattering of melt were regarded as good products (evaluation OK).

図29を参照して、比較例の密閉型電池については、10サンプル中のうちの5サンプルにおいて、セパレータの損傷ダメージ及び溶融物の飛散の少なくともいずれかが確認された。集電端子加圧工程において集電端子の脚部の配列乱れが生じたために、隙間からのレーザ光抜けや、溶接に伴ない生じた金属片の飛散が生じたものである。 With reference to FIG. 29, for the sealed battery of the comparative example, at least one of damage to the separator and scattering of melt was confirmed in 5 out of 10 samples. In the current collecting terminal pressurizing step, the arrangement of the legs of the current collecting terminal was disturbed, so that the laser light escaped from the gap and the metal pieces generated by welding were scattered.

一方、本開示の実施の形態に従う密閉型電池1については、10サンプル全て良品であった。密閉型電池1では、正極集電端子11及び負極集電端子12にそれぞれプレート部材24,27が設けられているので、集電端子加圧工程において集電端子の脚部の配列乱れが抑制される。その結果、隙間からのレーザ光抜けが抑制され、セパレータの損傷や、溶接に伴なう溶融物の電池内部への飛散が抑制されている。 On the other hand, all 10 samples of the sealed battery 1 according to the embodiment of the present disclosure were good products. In the sealed battery 1, since the plate members 24 and 27 are provided on the positive electrode current collecting terminal 11 and the negative electrode current collecting terminal 12, respectively, the arrangement disorder of the legs of the current collecting terminal is suppressed in the current collecting terminal pressurizing step. To. As a result, the laser light escape from the gap is suppressed, the damage of the separator and the scattering of the molten material due to welding into the battery are suppressed.

以上のように、本開示の実施の形態によれば、正極集電端子11及び負極集電端子12を電極体3(正極集電体7及び負極集電体8)に良好に溶接可能であり、かつ、溶接の際の電極体3への影響を抑制することができる。 As described above, according to the embodiment of the present disclosure, the positive electrode current collector terminal 11 and the negative electrode current collector terminal 12 can be satisfactorily welded to the electrode body 3 (positive electrode current collector 7 and negative electrode current collector 8). Moreover, the influence on the electrode body 3 at the time of welding can be suppressed.

[変形例1]
図30は、実施の形態の変形例1における正極集電端子を−X方向から(電極体3側から)視た場合の正極集電端子の平面図であり、図31は、図30中のXXXI-XXXIに沿った断面図である。なお、負極集電端子の構成も、正極集電端子と同様であり、以下では、正極集電端子について代表的に説明される。
[Modification 1]
FIG. 30 is a plan view of the positive electrode current collecting terminal when the positive electrode current collecting terminal in the first modification of the embodiment is viewed from the −X direction (from the electrode body 3 side), and FIG. 31 is a plan view of the positive electrode current collecting terminal in FIG. It is sectional drawing along XXXI-XXXI. The configuration of the negative electrode current collecting terminal is also the same as that of the positive electrode current collecting terminal, and the positive electrode current collecting terminal will be typically described below.

図30及び図31を参照して、この変形例1では、正極集電端子11Aは、図3及び図4に示した上記の実施の形態における正極集電端子11において、プレート部材24(24A,24B)に代えてプレート部材40(40A,40B)を含む。 With reference to FIGS. 30 and 31, in this modification 1, the positive electrode current collector terminal 11A is the plate member 24 (24A, in the positive electrode current collector terminal 11 in the above embodiment shown in FIGS. 3 and 4). 24B) is replaced with the plate member 40 (40A, 40B).

プレート部材40Aは、脚部23Aにかかる部分において段差部41Aが形成されている点でプレート部材24Aと異なる。段差部41Aは、脚部23Aと隙間を有するように形成されている。プレート部材40Bも、脚部23Dにかかる部分において段差部41Bが形成されている点でプレート部材24Bと異なる。段差部41Bは、脚部23Dと隙間を有するように形成されている。 The plate member 40A is different from the plate member 24A in that a step portion 41A is formed at a portion extending over the leg portion 23A. The step portion 41A is formed so as to have a gap with the leg portion 23A. The plate member 40B is also different from the plate member 24B in that a step portion 41B is formed at a portion extending over the leg portion 23D. The step portion 41B is formed so as to have a gap with the leg portion 23D.

段差部41Aと脚部23Aとの隙間、及び段差部41Bと脚部23Dとの隙間については、たとえば、集電端子加圧工程S7における脚部23A〜23Dへの加圧の際の、脚部23A,23Dの捩れの許容範囲に基づいて決定することができる。 Regarding the gap between the step portion 41A and the leg portion 23A and the gap between the step portion 41B and the leg portion 23D, for example, the leg portion when pressurizing the leg portions 23A to 23D in the current collecting terminal pressurizing step S7. It can be determined based on the twist tolerance of 23A and 23D.

このような段差部41A,41Bが形成されることにより、集電端子加圧工程S7における脚部23A〜23Dへの加圧の初期段階において、脚部23A(23D)がプレート部材40A(40B)と接触しない。これにより、脚部23A(23D)とプレート部材40A(40B)との間に摩擦が発生せず、脚部23A〜23Dへの負荷及び脚部23A〜23Dの変形が軽減される。 By forming such step portions 41A and 41B, the leg portions 23A (23D) become the plate member 40A (40B) in the initial stage of pressurizing the leg portions 23A to 23D in the current collecting terminal pressurizing step S7. Do not contact with. As a result, friction does not occur between the leg portions 23A (23D) and the plate member 40A (40B), and the load on the leg portions 23A to 23D and the deformation of the leg portions 23A to 23D are reduced.

[変形例2]
図32は、実施の形態の変形例2における正極集電端子を−X方向から(電極体3側から)視た場合の正極集電端子の平面図であり、図33は、図32中のXXXIII-XXXIIIに沿った断面図である。なお、負極集電端子の構成も、正極集電端子と同様であり、以下では、正極集電端子について代表的に説明される。
[Modification 2]
FIG. 32 is a plan view of the positive electrode current collecting terminal when the positive electrode current collecting terminal in the second modification of the embodiment is viewed from the −X direction (from the electrode body 3 side), and FIG. 33 is a plan view of the positive electrode current collecting terminal in FIG. 32. It is sectional drawing along XXXIII-XXXIII. The configuration of the negative electrode current collecting terminal is also the same as that of the positive electrode current collecting terminal, and the positive electrode current collecting terminal will be typically described below.

図32及び図33を参照して、この変形例2では、正極集電端子11Bは、図3及び図4に示した上記の実施の形態における正極集電端子11において、プレート部材24A,24Bに代えてそれぞれプレート状部位45A,45Bを含む。 With reference to FIGS. 32 and 33, in the second modification, the positive electrode current collector terminal 11B is attached to the plate members 24A and 24B in the positive electrode current collector terminal 11 according to the above embodiment shown in FIGS. 3 and 4. Instead, the plate-shaped portions 45A and 45B are included, respectively.

プレート状部位45A,45Bは、図3及び図4に示した正極集電端子11のプレート部材24A,24Bが取付けられている部分において、それぞれ脚部23B,23Cと一体的に形成されている。 The plate-shaped portions 45A and 45B are integrally formed with the leg portions 23B and 23C at the portions where the plate members 24A and 24B of the positive electrode current collecting terminals 11 shown in FIGS. 3 and 4 are attached.

そして、プレート状部位45Aは、脚部23Bからその外側に隣接する脚部23Aに向けて延び、かつ脚部23Aにかかるように形成されている。プレート状部位45Bは、脚部23Cからその外側に隣接する脚部23Dに向けて延び、かつ脚部23Dにかかるように形成されている。 The plate-shaped portion 45A is formed so as to extend from the leg portion 23B toward the leg portion 23A adjacent to the outside thereof and to extend over the leg portion 23A. The plate-shaped portion 45B is formed so as to extend from the leg portion 23C toward the leg portion 23D adjacent to the outside thereof and to extend over the leg portion 23D.

なお、特に図示しないが、上記の変形例1のように、プレート状部位45Aの脚部23Aにかかる部分において、脚部23Aと隙間を有するように段差部を設け、プレート状部位45Bの脚部23Dにかかる部分において、脚部23Dと隙間を有するように段差部を設けてもよい。 Although not particularly shown, in the portion of the plate-shaped portion 45A that covers the leg portion 23A, a step portion is provided so as to have a gap with the leg portion 23A, and the leg portion of the plate-shaped portion 45B is provided as in the above modification 1. A step portion may be provided so as to have a gap with the leg portion 23D in the portion relating to the 23D.

[変形例3]
図34は、実施の形態の変形例3における正極集電端子を−X方向から(電極体3側から)視た場合の正極集電端子の平面図である。図35は、この変形例3において、電極体3に取付けられた正極集電端子をX方向に視た場合の平面図である。
[Modification 3]
FIG. 34 is a plan view of the positive electrode current collecting terminal when the positive electrode current collecting terminal in the modified example 3 of the embodiment is viewed from the −X direction (from the electrode body 3 side). FIG. 35 is a plan view of the positive electrode current collecting terminal attached to the electrode body 3 in the modified example 3 when viewed in the X direction.

図34及び図35を参照して、上記の実施の形態では、図2及び図3に示したように、プレート部材24A,24Bは、電極体3の正極集電体7よりも上方(台座部22に近い側)に設けられるものとしたが、図示されるように、プレート部材24A,24Bは、電極体3の正極集電体7よりも下方(台座部22から遠い側)に設けられてもよい。 With reference to FIGS. 34 and 35, in the above embodiment, as shown in FIGS. 2 and 3, the plate members 24A and 24B are above the positive electrode current collector 7 of the electrode body 3 (pedestal portion). Although it was supposed to be provided on the side closer to 22), as shown in the figure, the plate members 24A and 24B are provided below the positive electrode current collector 7 of the electrode body 3 (the side far from the pedestal portion 22). May be good.

今回開示された実施の形態は、すべての点で例示であって制限的なものではないと考えられるべきである。本発明の範囲は、上記した実施の形態の説明ではなくて特許請求の範囲によって示され、特許請求の範囲と均等の意味及び範囲内でのすべての変更が含まれることが意図される。 The embodiments disclosed this time should be considered as exemplary in all respects and not restrictive. The scope of the present invention is shown by the scope of claims rather than the description of the embodiment described above, and is intended to include all modifications within the meaning and scope equivalent to the scope of claims.

1 密閉型電池、2 収容ケース、3 電極体、4,5 端面、6 電解液、7 正極集電体、8 負極集電体、9 正極外部端子、10 負極外部端子、11,11A,11B 正極集電端子、12 負極集電端子、20 ケース本体、21 蓋、22,25 台座部、23,23A〜23D,26 脚部、24,24A,24B,27,40A,40B プレート部材、28 溶接部、29 接合部、30 正極シート、31,34 活物質合剤層、32,35 未塗工箔部、33 負極シート、41A,41B 段差部、45A,45B プレート状部位、50,51 集箔治具。 1 Sealed battery, 2 Storage case, 3 Electrode body, 4, 5 End face, 6 Electrode solution, 7 Positive electrode current collector, 8 Negative electrode current collector, 9 Positive electrode external terminal, 10 Negative electrode external terminal, 11, 11A, 11B Positive electrode Current collection terminal, 12 negative electrode current collection terminal, 20 case body, 21 lid, 22,25 pedestal, 23,23A to 23D, 26 legs, 24,24A, 24B, 27,40A, 40B plate member, 28 welds , 29 Joint part, 30 Positive electrode sheet, 31,34 Active material mixture layer, 32,35 Uncoated foil part, 33 Negative electrode sheet, 41A, 41B Step part, 45A, 45B Plate-shaped part, 50,51 Foil collection cure Ingredients.

Claims (1)

積層された複数の極板を含んで構成され、前記複数の極板の積層方向に沿う側面に集電体が形成された電極体と、
前記集電体に溶接された集電端子とを備え、
前記集電端子は、
台座部と、
前記台座部から互いに間隔をあけて前記側面に沿って延びる複数の脚部とを含み、
前記集電体は、前記複数の脚部の間に挟み込まれて前記複数の脚部に溶接されており、
前記集電端子は、さらに、
前記複数の脚部のうちの内側の一の脚部に設けられるとともに前記一の脚部から前記一の脚部の外側に隣接する他の脚部に向けて延び、前記他の脚部の前記一の脚部の方向への移動を許容しつつ前記他の脚部の前記電極体の方向への移動を規制するように構成された部材を含む、密閉型電池。
An electrode body composed of a plurality of laminated electrode plates and having a current collector formed on a side surface of the plurality of electrode plates along the stacking direction.
A current collector terminal welded to the current collector is provided.
The current collector terminal
With the pedestal
Including a plurality of legs extending along the side surface from the pedestal portion at intervals from each other.
The current collector is sandwiched between the plurality of legs and welded to the plurality of legs.
The current collector terminal further
It is provided on one inner leg of the plurality of legs and extends from the one leg toward the other leg adjacent to the outside of the one leg, and the other leg of the other leg. A sealed battery comprising a member configured to allow movement in the direction of one leg while restricting movement of the other leg in the direction of the electrode body.
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