JP2019040837A - Sealed battery - Google Patents

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JP2019040837A
JP2019040837A JP2017164235A JP2017164235A JP2019040837A JP 2019040837 A JP2019040837 A JP 2019040837A JP 2017164235 A JP2017164235 A JP 2017164235A JP 2017164235 A JP2017164235 A JP 2017164235A JP 2019040837 A JP2019040837 A JP 2019040837A
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current collector
positive electrode
leg
electrode current
terminal
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JP6769412B2 (en
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松浦 智浩
Tomohiro Matsuura
智浩 松浦
幸男 播磨
Yukio Harima
幸男 播磨
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Toyota Motor Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

To provide a sealed battery in which a collector terminal can be favorably welded to an electrode body and an effect on the electrode body in welding is suppressed.SOLUTION: A positive electrode collector terminal 11 includes a pedestal 22, a plurality of legs 23A-23D, and plate members 24A, 24B. The plate member 24A is configured to be provided to the leg 23B, extend toward the leg 23A adjacent to the outside of the leg 23B and restrict the movement of the leg 23A in a direction of the electrode body while allowing the movement of the leg 23A in a direction of the leg 23B. The plate member 24B is configured to be provided to the leg 23C, extend toward the leg 23D adjacent to the outside of the leg 23C and restrict the movement of the leg 23D in a direction of the electrode body while allowing the movement of the leg 23D in a direction of the leg 23C.SELECTED DRAWING: Figure 3

Description

本開示は、密閉型電池に関し、特に、密閉型電池内に設けられる集電端子の構成に関する。   The present disclosure relates to a sealed battery, and more particularly, to a configuration of a current collecting terminal provided in the sealed battery.

特開2007−299536号公報(特許文献1)は、密閉型の角形非水電解質二次電池を開示する。この密閉型電池は、シート状の電極板の電極活物質が塗布されていない未塗布部が積層した状態の端縁部を有する電極体と、電極体の端縁部に溶接される集電端子とを備える。集電端子には複数のスリットが形成されており、電極体の端縁部における集電体がこれらのスリットに挿入された状態で、集電体(電極体)と集電端子とが溶接されている(特許文献1参照)。   Japanese Patent Laying-Open No. 2007-299536 (Patent Document 1) discloses a sealed prismatic non-aqueous electrolyte secondary battery. The sealed battery includes an electrode body having an edge portion in a state where uncoated portions to which an electrode active material of a sheet-like electrode plate is not applied are laminated, and a current collecting terminal welded to the edge portion of the electrode body With. The current collector terminal has a plurality of slits, and the current collector (electrode body) and the current collector terminal are welded with the current collector at the edge of the electrode body being inserted into these slits. (See Patent Document 1).

特開2007−299536号公報JP 2007-299536 A

電極体の集電体がスリットに挿入された状態で集電体と集電端子とが溶接(一般的にはレーザ溶接)される場合には、集電体がスリットにしっかりと挟み込まれるように集電端子に外力(挟力)を加えて集電端子を変形させた状態で、集電体と集電端子との溶接が行なわれる。   When the current collector of the electrode body is inserted into the slit and the current collector and the current collector terminal are welded (generally laser welding), the current collector should be firmly sandwiched between the slits. The current collector and the current collector terminal are welded in a state in which the current collector terminal is deformed by applying an external force (clamping force) to the current collector terminal.

しかしながら、集電端子を変形させた場合に、スリットを形成している脚部が捩れることによりスリットに隙間が残ると、溶接の際にその隙間からレーザ光が抜けたり、溶接に伴ない生じた金属片が電極体側に飛散したりして、電極体に影響を与えるおそれがある。   However, when the current collector terminal is deformed, if a gap remains in the slit due to twisting of the leg portion forming the slit, laser light may come off from the gap during welding or may occur with welding. Otherwise, the metal pieces may be scattered on the electrode body side and affect the electrode body.

本開示は、かかる問題を解決するためになされたものであり、その目的は、集電端子を電極体に良好に溶接可能であるとともに、溶接の際の電極体への影響が抑制された密閉型電池を提供することである。   The present disclosure has been made in order to solve such a problem, and an object of the present disclosure is to make it possible to satisfactorily weld the current collecting terminal to the electrode body and to suppress the influence on the electrode body during welding. Type battery.

本開示の密閉型電池は、電極体と、集電端子とを備える。電極体は、積層された複数の極板を含んで構成され、複数の極板の積層方向に沿う側面に集電体が形成されている。集電端子は、集電体に溶接されている。集電端子は、台座部と、複数の脚部と、部材とを含む。複数の脚部は、台座部から互いに間隔をあけて電極体の上記側面に沿って延びている。集電体は、複数の脚部の間に挟み込まれて複数の脚部に溶接されている。そして、上記部材は、複数の脚部のうちの一の脚部に設けられるとともに一の脚部からその外側に隣接する他の脚部に向けて延び、他の脚部の上記一の脚部の方向への移動を許容しつつ、他の脚部の電極体の方向への移動を規制するように構成される。   The sealed battery according to the present disclosure includes an electrode body and a current collecting terminal. The electrode body includes a plurality of stacked electrode plates, and a current collector is formed on a side surface along the stacking direction of the plurality of electrode plates. The current collector terminal is welded to the current collector. The current collecting terminal includes a pedestal, a plurality of legs, and a member. The plurality of leg portions extend along the side surface of the electrode body at intervals from the pedestal portion. The current collector is sandwiched between the plurality of legs and welded to the plurality of legs. The member is provided on one leg portion of the plurality of leg portions and extends from the one leg portion toward another leg portion adjacent to the outside thereof, and the one leg portion of the other leg portion. The movement of the other leg portion in the direction of the electrode body is restricted while allowing the movement in the direction of.

本開示の密閉型電池においては、上記のような部材が集電端子に設けられるので、電極体の集電体を複数の脚部の間に挟み込む際に脚部の捩れが抑制される。これにより、複数の脚部の間に集電体を隙間なくしっかりと挟み込むことができるので、良好な溶接が行なわれるとともに、溶接の際に隙間からレーザ光が抜けたり、溶接に伴ない生じた金属片が電極体側に飛散したりするのを抑制することができる。このように、本開示の密閉型電池によれば、集電端子を電極体に良好に溶接可能であり、かつ、溶接の際の電極体への影響を抑制することができる。   In the sealed battery according to the present disclosure, the members as described above are provided in the current collecting terminal, so that twisting of the leg portion is suppressed when the current collector of the electrode body is sandwiched between the plurality of leg portions. As a result, the current collector can be firmly sandwiched between the plurality of legs without any gaps, so that good welding is performed, and laser light is emitted from the gaps during welding, which is caused by welding. It can suppress that a metal piece scatters to the electrode body side. Thus, according to the sealed battery of the present disclosure, the current collecting terminal can be well welded to the electrode body, and the influence on the electrode body during welding can be suppressed.

本開示の実施の形態に従う密閉型電池の断面図である。1 is a cross-sectional view of a sealed battery according to an embodiment of the present disclosure. 電極体に取付けられた正極集電端子をX方向に視た場合の平面図である。It is a top view at the time of seeing the positive electrode current collection terminal attached to the electrode body to a X direction. 正極集電端子を−X方向から(電極体側から)視た場合の正極集電端子の平面図である。It is a top view of a positive electrode current collection terminal at the time of seeing a positive electrode current collection terminal from the -X direction (from the electrode body side). 図3中のIV-IVに沿った断面図である。FIG. 4 is a cross-sectional view taken along IV-IV in FIG. 3. 脚部に外力(挟力)を加えて脚部間のスリットを閉じる際の様子を模式的に示した断面図である。It is sectional drawing which showed typically the mode at the time of applying the external force (clamping force) to a leg part and closing the slit between leg parts. 脚部に外力(挟力)を加えて脚部間のスリットを閉じる際の様子を模式的に示した断面図である。It is sectional drawing which showed typically the mode at the time of applying the external force (clamping force) to a leg part and closing the slit between leg parts. 脚部に外力(挟力)を加えて脚部間のスリットを閉じる際の様子を模式的に示した断面図である。It is sectional drawing which showed typically the mode at the time of applying the external force (clamping force) to a leg part and closing the slit between leg parts. 密閉型電池の製造工程を示すフローチャートである。It is a flowchart which shows the manufacturing process of a sealed battery. 正極シートの平面図である。It is a top view of a positive electrode sheet. 負極シートの平面図である。It is a top view of a negative electrode sheet. 電極体の斜視図である。It is a perspective view of an electrode body. 電極体の斜視図である。It is a perspective view of an electrode body. 集電体予備成形工程S2において正極集電体が成形される様子を模式的に示した図である。It is the figure which showed typically a mode that the positive electrode electrical power collector was shape | molded in current collector preforming process S2. 集電体予備成形工程S2において正極集電体が成形される様子を模式的に示した図である。It is the figure which showed typically a mode that the positive electrode electrical power collector was shape | molded in current collector preforming process S2. 正極集電端子が整形される前の平面図である。It is a top view before a positive electrode current collection terminal is shape | molded. 正極集電端子にプレート部材が取付けられた様子を示した図である。It is the figure which showed a mode that the plate member was attached to the positive electrode current collection terminal. 収容ケースの蓋に、正極外部端子及び負極外部端子、並びに正極集電端子及び負極集電端子が組付けられた様子を示した図である。It is the figure which showed a mode that the positive electrode external terminal and the negative electrode external terminal, the positive electrode current collection terminal, and the negative electrode current collection terminal were assembled | attached to the cover of the storage case. 収容ケースの蓋並びに正極集電端子及び負極集電端子が電極体に組付けられた様子を示した図である。It is the figure which showed a mode that the cover of the storage case, the positive electrode current collection terminal, and the negative electrode current collection terminal were assembled | attached to the electrode body. 正極集電端子が電極体に組付けられる様子を示した図である。It is the figure which showed a mode that the positive electrode current collection terminal was assembled | attached to an electrode body. 正極集電端子の脚部に正極集電体が溶接される様子を示す斜視図である。It is a perspective view which shows a mode that a positive electrode collector is welded to the leg part of a positive electrode current collection terminal. 正極集電端子の脚部に正極集電体が溶接される様子を示す断面図である。It is sectional drawing which shows a mode that a positive electrode collector is welded to the leg part of a positive electrode current collection terminal. 正極集電端子の脚部に正極集電体が溶接される様子を示す断面図である。It is sectional drawing which shows a mode that a positive electrode collector is welded to the leg part of a positive electrode current collection terminal. 正極集電端子の脚部に正極集電体が溶接される様子を示す断面図である。It is sectional drawing which shows a mode that a positive electrode collector is welded to the leg part of a positive electrode current collection terminal. 比較例における正極集電端子を電極体側から視た場合の正極集電端子の平面図である。It is a top view of the positive electrode current collection terminal at the time of seeing the positive electrode current collection terminal in a comparative example from the electrode body side. 比較例における正極集電端子をY方向に視た場合の平面図である。It is a top view at the time of seeing the positive electrode current collection terminal in a comparative example in the Y direction. 比較例における、集電端子加圧工程時の正極集電端子の脚部を模式的に示した断面図である。It is sectional drawing which showed typically the leg part of the positive electrode current collection terminal at the time of the current collection terminal pressurization process in a comparative example. 比較例における、集電端子加圧工程時の正極集電端子の脚部を模式的に示した断面図である。It is sectional drawing which showed typically the leg part of the positive electrode current collection terminal at the time of the current collection terminal pressurization process in a comparative example. 比較例において正極集電端子の脚部に正極集電体が溶接される様子を示した断面図である。It is sectional drawing which showed a mode that the positive electrode electrical power collector was welded to the leg part of the positive electrode current collection terminal in a comparative example. 本開示の実施の形態に従う密閉型電池と比較例の密閉型電池とにおいて、集電端子と集電体との溶接の評価結果を示した図である。It is the figure which showed the evaluation result of welding with a current collection terminal and a collector in the sealed battery according to embodiment of this indication, and the sealed battery of a comparative example. 実施の形態の変形例1における正極集電端子を−X方向から(電極体側から)視た場合の正極集電端子の平面図である。It is a top view of the positive electrode current collection terminal at the time of seeing the positive electrode current collection terminal in the modification 1 of embodiment from the -X direction (from the electrode body side). 図30中のXXXI-XXXIに沿った断面図である。It is sectional drawing in alignment with XXXI-XXXI in FIG. 実施の形態の変形例2における正極集電端子を−X方向から(電極体側から)視た場合の正極集電端子の平面図である。It is a top view of a positive electrode current collection terminal at the time of seeing the positive electrode current collection terminal in modification 2 of an embodiment from the -X direction (from the electrode body side). 図32中のXXXIII-XXXIIIに沿った断面図である。FIG. 33 is a cross-sectional view taken along XXXIII-XXXIII in FIG. 32. 実施の形態の変形例3における正極集電端子を−X方向から(電極体側から)視た場合の正極集電端子の平面図である。It is a top view of the positive electrode current collection terminal at the time of seeing the positive electrode current collection terminal in modification 3 of an embodiment from the -X direction (from the electrode body side). 変形例3において、電極体に取付けられた正極集電端子をX方向に視た場合の平面図である。In the modification 3, it is a top view at the time of seeing the positive electrode current collection terminal attached to the electrode body to a X direction.

以下、本開示の実施の形態について、図面を参照しながら詳細に説明する。なお、図中同一又は相当部分には同一符号を付してその説明は繰り返さない。   Hereinafter, embodiments of the present disclosure will be described in detail with reference to the drawings. In the drawings, the same or corresponding portions are denoted by the same reference numerals and description thereof will not be repeated.

<密閉型電池の全体構成>
図1は、本開示の実施の形態に従う密閉型電池1の断面図である。図1を参照して、密閉型電池1は、収容ケース2と、電極体3と、電解液6と、正極外部端子9と、負極外部端子10と、正極集電端子11と、負極集電端子12とを備える。電極体3の側面4には、正極集電体7が形成されており、電極体3の側面5には、負極集電体8が形成されている。電極体3、正極集電端子11及び負極集電端子12は、収容ケース2に収容され、収容ケース2内には、電解液6が注入されている。
<Overall configuration of sealed battery>
FIG. 1 is a cross-sectional view of a sealed battery 1 according to an embodiment of the present disclosure. With reference to FIG. 1, the sealed battery 1 includes a housing case 2, an electrode body 3, an electrolytic solution 6, a positive electrode external terminal 9, a negative electrode external terminal 10, a positive electrode current collector terminal 11, and a negative electrode current collector. And a terminal 12. A positive electrode current collector 7 is formed on the side surface 4 of the electrode body 3, and a negative electrode current collector 8 is formed on the side surface 5 of the electrode body 3. The electrode body 3, the positive electrode current collector terminal 11, and the negative electrode current collector terminal 12 are housed in the housing case 2, and the electrolytic solution 6 is injected into the housing case 2.

収容ケース2は、ケース本体20と、蓋21とを含む。ケース本体20には、上方に向けて開口する開口部が形成されている。蓋21は、ケース本体20の開口部を閉塞するように配置されており、蓋21はケース本体20に溶接されている。蓋21の上面には、正極外部端子9及び負極外部端子10が配置されている。   The housing case 2 includes a case body 20 and a lid 21. The case body 20 has an opening that opens upward. The lid 21 is disposed so as to close the opening of the case body 20, and the lid 21 is welded to the case body 20. A positive electrode external terminal 9 and a negative electrode external terminal 10 are disposed on the upper surface of the lid 21.

電極体3は、複数の正極シートと、複数のセパレータと、複数の負極シートとを含んで構成される(各々については図示せず)。電極体3は、セパレータを挟んで正極シートと負極シートとが交互に順次積層されることで形成されている。   The electrode body 3 includes a plurality of positive electrode sheets, a plurality of separators, and a plurality of negative electrode sheets (each not shown). The electrode body 3 is formed by alternately laminating positive electrode sheets and negative electrode sheets with a separator interposed therebetween.

正極集電体7は、各正極シートの端部が積層されることで形成されており、電極体3の正極を構成する。負極集電体8は、各負極シートの端部が積層されることで形成されており、電極体3の負極を構成する。   The positive electrode current collector 7 is formed by stacking the end portions of the respective positive electrode sheets, and constitutes the positive electrode of the electrode body 3. The negative electrode current collector 8 is formed by laminating end portions of the respective negative electrode sheets, and constitutes the negative electrode of the electrode body 3.

正極集電端子11は、台座部22と、脚部23と、プレート部材24とを含む。台座部22は、電極体3の上面(電極体3の−Y方向)に配置されており、蓋21に形成された孔を通じて正極外部端子9と電気的に接続される。脚部23は、台座部22に接続されており、電極体3の側面4に沿ってY方向に延びるように設けられる。そして、脚部23は、正極集電体7に溶接されている。なお、図1では示されていないが、脚部23は、互いに間隔(スリット)をあけて側面4に沿って延びる複数の脚部によって構成されている。   The positive electrode current collecting terminal 11 includes a pedestal part 22, a leg part 23, and a plate member 24. The pedestal portion 22 is disposed on the upper surface of the electrode body 3 (the −Y direction of the electrode body 3), and is electrically connected to the positive electrode external terminal 9 through a hole formed in the lid 21. The leg portion 23 is connected to the pedestal portion 22 and is provided so as to extend in the Y direction along the side surface 4 of the electrode body 3. The leg portion 23 is welded to the positive electrode current collector 7. Although not shown in FIG. 1, the leg portion 23 is composed of a plurality of leg portions that extend along the side surface 4 at intervals (slits).

プレート部材24は、脚部23の電極体3に対向する面であって、脚部23と正極集電体7との接続部よりも上方(台座部22側)に設けられる。このプレート部材24は、脚部23と正極集電体7とを接続(溶接)するにあたって脚部23のスリットに正極集電体7を挟み込む際に、脚部23を構成する複数の脚部の配列乱れを抑制するための部材である。プレート部材24の配置及び構成については、後ほど詳しく説明する。   The plate member 24 is a surface facing the electrode body 3 of the leg portion 23, and is provided above (on the pedestal portion 22 side) the connection portion between the leg portion 23 and the positive electrode current collector 7. The plate member 24 has a plurality of leg portions constituting the leg portion 23 when the positive electrode current collector 7 is sandwiched between slits of the leg portion 23 when the leg portion 23 and the positive electrode current collector 7 are connected (welded). It is a member for suppressing arrangement disorder. The arrangement and configuration of the plate member 24 will be described in detail later.

負極集電端子12は、台座部25と、脚部26と、プレート部材27とを含む。台座部25も、電極体3の上面(電極体3の−Y方向)に配置されており、蓋21に形成された孔を通じて負極外部端子10と電気的に接続される。脚部26は、台座部25に接続されており、電極体3の側面5に沿ってY方向に延びるように設けられる。そして、脚部26は、負極集電体8に溶接されている。なお、図1では示されていないが、脚部26も、互いに間隔(スリット)をあけて側面5に沿って延びる複数の脚部によって構成されている。   The negative electrode current collecting terminal 12 includes a pedestal portion 25, a leg portion 26, and a plate member 27. The pedestal 25 is also disposed on the upper surface of the electrode body 3 (the −Y direction of the electrode body 3), and is electrically connected to the negative electrode external terminal 10 through a hole formed in the lid 21. The leg portion 26 is connected to the pedestal portion 25 and is provided so as to extend in the Y direction along the side surface 5 of the electrode body 3. The leg portion 26 is welded to the negative electrode current collector 8. Although not shown in FIG. 1, the leg portion 26 is also composed of a plurality of leg portions extending along the side surface 5 with a space (slit) therebetween.

プレート部材27は、脚部26の電極体3に対向する面であって、脚部26と負極集電体8との接続部よりも上方(台座部25側)に設けられる。このプレート部材27は、脚部26と負極集電体8とを接続(溶接)するにあたって脚部26のスリットに負極集電体8を挟み込む際に、脚部26を構成する複数の脚部の配列乱れを抑制するための部材である。   The plate member 27 is a surface of the leg portion 26 facing the electrode body 3, and is provided above the connection portion between the leg portion 26 and the negative electrode current collector 8 (on the pedestal portion 25 side). The plate member 27 has a plurality of leg portions constituting the leg portion 26 when the negative electrode current collector 8 is sandwiched between slits of the leg portion 26 when the leg portion 26 and the negative electrode current collector 8 are connected (welded). It is a member for suppressing arrangement disorder.

<集電端子の構成>
図2は、電極体3に取付けられた正極集電端子11をX方向に視た場合の平面図である。また、図3は、正極集電端子11を−X方向から(電極体3側から)視た場合の正極集電端子11の平面図であり、図4は、図3中のIV-IVに沿った断面図である。なお、負極集電端子12の構成も、正極集電端子11と同様であり、以下では、正極集電端子11について代表的に説明される。
<Configuration of current collector terminal>
FIG. 2 is a plan view when the positive electrode current collecting terminal 11 attached to the electrode body 3 is viewed in the X direction. 3 is a plan view of the positive electrode current collector terminal 11 when the positive electrode current collector terminal 11 is viewed from the −X direction (from the electrode body 3 side), and FIG. 4 is a cross-sectional view taken along IV-IV in FIG. FIG. In addition, the structure of the negative electrode current collection terminal 12 is the same as that of the positive electrode current collection terminal 11, and the positive electrode current collection terminal 11 is typically demonstrated below.

図2から図4を参照して、正極集電端子11の脚部23は、4本の脚部23A〜23Dによって構成される。なお、脚部の本数は、4本に限定されるものではなく、これより多くても少なくてもよい。脚部23A〜23Dの間には、隙間(スリット)が設けられている。正極集電体7は、スリットに合わせて寄り集められ、スリットに挿入されている。そして、スリットの幅を狭めるように脚部23A〜23Dの両側から外力(狭力)を加えながら、スリットに挿入された正極集電体7にレーザ光を照射することによって、溶接部28において脚部23A〜23Dが正極集電体7と溶接される(図2)。   2 to 4, the leg portion 23 of the positive electrode current collecting terminal 11 is constituted by four leg portions 23A to 23D. Note that the number of leg portions is not limited to four, and may be more or less. A gap (slit) is provided between the leg portions 23A to 23D. The positive electrode current collector 7 is gathered close to the slit and inserted into the slit. Then, while applying an external force (narrow force) from both sides of the leg portions 23A to 23D so as to narrow the width of the slit, the positive electrode current collector 7 inserted into the slit is irradiated with laser light, whereby the leg is welded at the welded portion 28. The parts 23A to 23D are welded to the positive electrode current collector 7 (FIG. 2).

プレート部材24は、プレート部材24A,24Bによって構成される。プレート部材24A,24Bは、脚部23の裏面側(電極体3側)において、電極体3の正極集電体7よりも上方(台座部22に近い側)に設けられる。プレート部材24A,24Bは、接合部29によってそれぞれ脚部23B,23Cに接合されている。そして、プレート部材24Aは、脚部23Bからその外側に隣接する脚部23Aに向けて延び、かつ、脚部23Aにかかるように形成されている。プレート部材24Bは、脚部23Cからその外側に隣接する脚部23Dに向けて延び、かつ、脚部23Dにかかるように形成されている。   The plate member 24 is composed of plate members 24A and 24B. The plate members 24A and 24B are provided above the positive electrode current collector 7 of the electrode body 3 (on the side closer to the pedestal section 22) on the back surface side (electrode body 3 side) of the leg portion 23. The plate members 24A and 24B are joined to the leg portions 23B and 23C by the joining portion 29, respectively. Then, the plate member 24A extends from the leg portion 23B toward the leg portion 23A adjacent to the outside thereof, and is formed so as to cover the leg portion 23A. The plate member 24B extends from the leg portion 23C toward the leg portion 23D adjacent to the outside thereof, and is formed so as to cover the leg portion 23D.

このようなプレート部材24が設けられることにより、脚部23A〜23Dと正極集電体7との溶接に際して脚部23A〜23D間のスリットに正極集電体7を挟み込んで脚部23A〜23Dの両側から外力(狭力)を加えた場合に、脚部23A〜23Dの配列の乱れが抑制される。これにより、脚部23A〜23Dの間に正極集電体7が隙間なくしっかりと挟み込まれるので、溶接部28において良好な溶接が行なわれるとともに、溶接の際に隙間からレーザ光が抜けたり、溶接に伴ない生じた金属片が電極体3側に飛散したりするのを抑制することができる。   By providing such a plate member 24, when welding the leg portions 23A to 23D and the positive electrode current collector 7, the positive electrode current collector 7 is sandwiched between slits between the leg portions 23A to 23D and the leg portions 23A to 23D are inserted. When an external force (narrow force) is applied from both sides, the disorder of the arrangement of the leg portions 23A to 23D is suppressed. As a result, the positive electrode current collector 7 is firmly sandwiched between the leg portions 23A to 23D without a gap, so that a good welding is performed in the welded portion 28, and laser light is emitted from the gap during welding or welding. It can suppress that the metal piece which arose with scattering to the electrode body 3 side.

図5から図7は、脚部23A〜23Dに外力(挟力)を加えて脚部23A〜23D間のスリットを閉じる際の様子を模式的に示した断面図である。図5は、スリットが閉じられる前の脚部23A〜23Dの配置を示す。図6は、脚部23A〜23Dに挟力を加えることによって、脚部23A,23B間のスリット及び脚部23C,23D間のスリットが閉じた場合の脚部23A〜23Dの配置を示す。図7は、さらに挟力を加えることによって、脚部23B,23C間のスリットも閉じた場合の脚部23A〜23Dの配置を示す。なお、実際には、脚部23A〜23D間には、正極集電体7が挟み込まれているので、図6,7に示されるようにスリットが完全に閉じることはない。   5 to 7 are cross-sectional views schematically showing a state in which an external force (clamping force) is applied to the leg portions 23A to 23D to close the slit between the leg portions 23A to 23D. FIG. 5 shows the arrangement of the legs 23A-23D before the slit is closed. FIG. 6 shows the arrangement of the legs 23A to 23D when the slits between the legs 23A and 23B and the slits between the legs 23C and 23D are closed by applying a clamping force to the legs 23A to 23D. FIG. 7 shows the arrangement of the leg portions 23A to 23D when the slit between the leg portions 23B and 23C is also closed by further applying a clamping force. Actually, since the positive electrode current collector 7 is sandwiched between the leg portions 23A to 23D, the slit is not completely closed as shown in FIGS.

図6に示されるように、スリットを閉じるように脚部23A,23DにZ方向の外力(挟力)を加えることによって脚部23A,23DをZ方向に移動(変形)させると、脚部23A,23Dの根元が台座部22(図示せず)に接続されていることにより、脚部23A,23Dには、矢印で示されるようなねじりモーメントが発生する。しかしながら、この実施の形態に従う密閉型電池1では、プレート部材24A,24Bがストッパーとなって脚部23A,23Dの捩れが抑制される。その結果、図7に示されるように、脚部23A,23Dからそれぞれ荷重を受ける脚部23B,23Cの捩れも抑制される。   As shown in FIG. 6, when the leg portions 23A and 23D are moved (deformed) in the Z direction by applying an external force (clamping force) in the Z direction to the leg portions 23A and 23D so as to close the slit, the leg portion 23A , 23D are connected to the pedestal 22 (not shown), a torsional moment as indicated by an arrow is generated in the legs 23A, 23D. However, in sealed battery 1 according to the present embodiment, plate members 24A and 24B serve as stoppers to suppress twisting of leg portions 23A and 23D. As a result, as shown in FIG. 7, the torsion of the leg portions 23B and 23C that receive loads from the leg portions 23A and 23D, respectively, is also suppressed.

このように、脚部23A(23D)の脚部23B(23C)の方向への移動を許容しつつ、脚部23A(23D)の電極体3の方向への移動を規制するプレート部材24A(24B)が設けられることにより、正極集電体7を寄り集めて脚部23A〜23Dの間のスリットに挟み込む際に、脚部23A〜23Dの捩れが抑制され、脚部23A〜23Dの配列の乱れが抑制される。   In this way, the plate member 24A (24B) that restricts the movement of the leg 23A (23D) in the direction of the electrode body 3 while allowing the movement of the leg 23A (23D) in the direction of the leg 23B (23C). ), The twisting of the leg portions 23A to 23D is suppressed and the arrangement of the leg portions 23A to 23D is disturbed when the positive electrode current collector 7 is gathered and sandwiched between the slits between the leg portions 23A to 23D. Is suppressed.

<密閉型電池の製造方法>
図8は、密閉型電池1の製造工程を示すフローチャートである。図8を参照して、密閉型電池1の製造工程は、電極体成形工程S1と、集電体予備成形工程S2と、集電端子成形工程S3と、プレート板取付工程S4と、蓋成形工程S5と、蓋・電極体組付工程S6と、集電端子加圧工程S7と、集電端子溶接工程S8と、収容工程S9と、蓋溶接工程S10と、注入工程S11と、封止工程S12とを含む。
<Method for producing sealed battery>
FIG. 8 is a flowchart showing the manufacturing process of the sealed battery 1. Referring to FIG. 8, the manufacturing process of sealed battery 1 includes an electrode body forming step S1, a current collector pre-forming step S2, a current collecting terminal forming step S3, a plate plate attaching step S4, and a lid forming step. S5, lid / electrode assembly process S6, collector terminal pressurizing process S7, collector terminal welding process S8, housing process S9, lid welding process S10, injection process S11, and sealing process S12 Including.

電極体成形工程S1では、複数の正極シート及び負極シートが作製され、絶縁体のセパレータを挟んで正極シートと負極シートとが交互に順次積層されることで電極体3が形成される。   In the electrode body forming step S1, a plurality of positive electrode sheets and negative electrode sheets are produced, and the electrode bodies 3 are formed by alternately laminating positive electrode sheets and negative electrode sheets sequentially with an insulator separator interposed therebetween.

図9は、正極シートの平面図である。図9を参照して、正極シート30は、アルミ合金箔シートの表裏面に塗布される矩形状の活物質合剤層31と、アルミ合金箔シートの一辺に設けられる未塗布部が所定の寸法にカットされた未塗工箔部32とを含む。未塗工箔部32は、正極シート30において活物質合剤層31が形成されていない部分であり、アルミ合金箔シートが活物質合剤層31から露出した部分である。この未塗工箔部32は、正極シート30、負極シート33及びセパレータが積層されて電極体3が形成されたときに正極集電体7となる。   FIG. 9 is a plan view of the positive electrode sheet. Referring to FIG. 9, the positive electrode sheet 30 has a rectangular active material mixture layer 31 applied to the front and back surfaces of the aluminum alloy foil sheet, and a non-applied portion provided on one side of the aluminum alloy foil sheet has a predetermined size. And the uncoated foil part 32 cut into two pieces. The uncoated foil portion 32 is a portion where the active material mixture layer 31 is not formed in the positive electrode sheet 30, and is a portion where the aluminum alloy foil sheet is exposed from the active material mixture layer 31. The uncoated foil part 32 becomes the positive electrode current collector 7 when the electrode body 3 is formed by laminating the positive electrode sheet 30, the negative electrode sheet 33 and the separator.

図10は、負極シートの平面図である。図10を参照して、負極シート33は、銅箔シートの表裏面に塗布される矩形状の活物質合剤層34と、銅箔シートの一辺に設けられる未塗布部が所定の寸法にカットされた未塗工箔部35とを含む。未塗工箔部35は、負極シート33において活物質合剤層34が形成されていない部分であり、銅箔シートが活物質合剤層34から露出した部分である。この未塗工箔部35は、正極シート30、負極シート33及びセパレータが積層されて電極体3が形成されたときに負極集電体8となる。   FIG. 10 is a plan view of the negative electrode sheet. Referring to FIG. 10, the negative electrode sheet 33 has a rectangular active material mixture layer 34 applied to the front and back surfaces of the copper foil sheet, and an uncoated portion provided on one side of the copper foil sheet is cut to a predetermined size. Uncoated foil portion 35. The uncoated foil portion 35 is a portion where the active material mixture layer 34 is not formed in the negative electrode sheet 33, and is a portion where the copper foil sheet is exposed from the active material mixture layer 34. The uncoated foil portion 35 becomes the negative electrode current collector 8 when the positive electrode sheet 30, the negative electrode sheet 33 and the separator are laminated to form the electrode body 3.

図11は、電極体3の斜視図である。図11を参照して、電極体3は、多孔質絶縁層を含むセパレータ(図示せず)を挟んで、正極シート30(図9)と負極シート33(図10)とを交互に順次積層することによって形成される。このとき、複数の正極シート30は、図示されるように各正極シート30の未塗工箔部32が揃うように積層され、積層された未塗工箔部32によって正極集電体7が構成される。   FIG. 11 is a perspective view of the electrode body 3. Referring to FIG. 11, in electrode body 3, positive electrode sheets 30 (FIG. 9) and negative electrode sheets 33 (FIG. 10) are alternately and sequentially stacked with a separator (not shown) including a porous insulating layer interposed therebetween. Formed by. At this time, the plurality of positive electrode sheets 30 are laminated so that the uncoated foil portions 32 of the respective positive electrode sheets 30 are aligned as illustrated, and the positive electrode current collector 7 is configured by the laminated uncoated foil portions 32. Is done.

なお、図示されていないが、複数の負極シート33は、正極シート30の未塗工箔部32と反対側において各負極シート33の未塗工箔部35が揃うように積層され、積層された未塗工箔部35によって負極集電体8が構成される。   Although not shown in the drawing, the plurality of negative electrode sheets 33 are laminated so that the uncoated foil portions 35 of the respective negative electrode sheets 33 are aligned on the side opposite to the uncoated foil portions 32 of the positive electrode sheet 30. The uncoated foil portion 35 constitutes the negative electrode current collector 8.

再び図8を参照して、集電体予備成形工程S2では、正極集電端子11の脚部23A〜23D間のスリットに正極集電体7を挿入可能なように正極集電体7が成形される。この実施の形態では、図12に示されるように、正極集電端子11のスリット数(3つ)に合わせて、正極集電体7は3つの集合体に成形されている。なお、図示されていないが、負極側においても、負極集電端子12の脚部間のスリットに負極集電体8を挿入可能なように負極集電体8が成形される。   Referring again to FIG. 8, in current collector pre-forming step S <b> 2, positive electrode current collector 7 is formed so that positive electrode current collector 7 can be inserted into the slit between legs 23 </ b> A to 23 </ b> D of positive electrode current collector terminal 11. Is done. In this embodiment, as shown in FIG. 12, the positive electrode current collector 7 is formed into three aggregates according to the number of slits (three) of the positive electrode current collector terminal 11. Although not shown, the negative electrode current collector 8 is formed on the negative electrode side so that the negative electrode current collector 8 can be inserted into the slit between the legs of the negative electrode current collector terminal 12.

図13及び図14は、集電体予備成形工程S2において正極集電体7が成形される様子を模式的に示した図である。図13及び図14を参照して、正極集電体7の成形は、集箔治具50,51を用いて行なわれる。集箔治具50,51は、先端部が凸形状をしており、集箔治具50,51を正極集電体7に向けて移動させた後、集箔治具50,51で正極集電体7を挟み込むことによって、正極集電体7の成形(癖付け)が行なわれる。   FIGS. 13 and 14 are diagrams schematically showing how the positive electrode current collector 7 is formed in the current collector pre-forming step S2. With reference to FIG. 13 and FIG. 14, the positive electrode current collector 7 is formed using the foil collecting jigs 50 and 51. The foil collection jigs 50 and 51 have convex ends, and after the foil collection jigs 50 and 51 are moved toward the positive electrode current collector 7, the positive electrode collection is performed by the foil collection jigs 50 and 51. The positive electrode current collector 7 is molded (brazed) by sandwiching the electric body 7 therebetween.

再び図8を参照して、集電端子成形工程S3では、正極集電端子11及び負極集電端子12が作製される。   Referring to FIG. 8 again, in current collector terminal forming step S3, positive electrode current collector terminal 11 and negative electrode current collector terminal 12 are manufactured.

図15は、正極集電端子11が整形される前の平面図である。図15を参照して、正極集電端子11は、アルミ製であり、アルミ板を所定の型で打ち抜くことによって、正極集電端子11の原板が成形される。この原板には、台座部22と、台座部22から延びる脚部23A〜23Dとが設けられており、図の点線において90度に折り曲げることによって正極集電端子11が成形される。なお、図示されていないが、負極集電端子12は、銅製であり、銅板を所定の型で打ち抜くことによって負極集電端子12の原板が成形され、正極集電端子11と同様に折り曲げることによって負極集電端子12が成形される。   FIG. 15 is a plan view before the positive electrode current collector terminal 11 is shaped. Referring to FIG. 15, positive electrode current collector terminal 11 is made of aluminum, and an original plate of positive electrode current collector terminal 11 is formed by punching an aluminum plate with a predetermined mold. The original plate is provided with a pedestal portion 22 and leg portions 23A to 23D extending from the pedestal portion 22, and the positive electrode current collecting terminal 11 is formed by being bent at 90 degrees along the dotted line in the figure. Although not shown, the negative electrode current collector terminal 12 is made of copper, and the negative electrode current collector terminal 12 is formed by punching a copper plate with a predetermined mold, and is bent in the same manner as the positive electrode current collector terminal 11. A negative electrode current collecting terminal 12 is formed.

再び図8を参照して、プレート板取付工程S4では、正極集電端子11にプレート部材24が取付けられ、負極集電端子12にプレート部材27が取付けられる。   Referring to FIG. 8 again, in the plate plate attaching step S4, the plate member 24 is attached to the positive electrode current collecting terminal 11, and the plate member 27 is attached to the negative electrode current collecting terminal 12.

図16は、正極集電端子11にプレート部材24が取付けられた様子を示した図である。図16を参照して、台座部22は、複数の脚部23A〜23Dに対して90度に折り曲げられている(この図では、紙面手前側に折り曲げられている。)。そして、台座部22が折り曲げられた側の脚部23A〜23Dの面に、プレート部材24(24A,24B)が取付けられる。   FIG. 16 is a diagram illustrating a state where the plate member 24 is attached to the positive electrode current collecting terminal 11. Referring to FIG. 16, pedestal portion 22 is bent at 90 degrees with respect to a plurality of leg portions 23 </ b> A to 23 </ b> D (in this drawing, bent toward the front side of the sheet). And the plate member 24 (24A, 24B) is attached to the surface of leg part 23A-23D by the side where the base part 22 was bent.

プレート部材24(24A,24B)は、正極集電端子11が電極体3に組付けられた場合に、電極体3の正極集電体7よりも上方(台座部22側)に位置するように正極集電端子11に取付けられる。具体的には、プレート部材24Aは、脚部23Bからその外側に隣接する脚部23Aに向けて延び、かつ脚部23Aにかかるように、接合部29によって脚部23Bに取付けられる。プレート部材24Bは、脚部23Cからその外側に隣接する脚部23Dに向けて延び、かつ脚部23Dにかかるように、接合部29によって脚部23Cに取付けられる。なお、負極集電端子12についても、同様にしてプレート部材27が取付けられる。   The plate member 24 (24A, 24B) is positioned above (on the pedestal portion 22 side) the positive electrode current collector 7 of the electrode body 3 when the positive electrode current collector terminal 11 is assembled to the electrode body 3. Attached to the positive electrode current collector terminal 11. Specifically, the plate member 24A extends from the leg portion 23B toward the leg portion 23A adjacent to the outside thereof, and is attached to the leg portion 23B by the joint portion 29 so as to be applied to the leg portion 23A. The plate member 24B extends from the leg portion 23C toward the leg portion 23D adjacent to the outside thereof, and is attached to the leg portion 23C by the joint portion 29 so as to be applied to the leg portion 23D. The plate member 27 is similarly attached to the negative electrode current collecting terminal 12.

再び図8を参照して、蓋成形工程S5では、収容ケース2の蓋21に、正極外部端子9、負極外部端子10、正極集電端子11、及び負極集電端子12が組付けられる。   Referring again to FIG. 8, in lid forming step S <b> 5, positive electrode external terminal 9, negative electrode external terminal 10, positive electrode current collector terminal 11, and negative electrode current collector terminal 12 are assembled to lid 21 of housing case 2.

図17は、収容ケース2の蓋21に、正極外部端子9及び負極外部端子10、並びに正極集電端子11及び負極集電端子12が組付けられた様子を示した図である。図17を参照して、蓋21の上面の一方端に正極外部端子9が組付けられ、蓋21の上面の他方端に負極外部端子10が組付けられる。   FIG. 17 is a diagram illustrating a state in which the positive electrode external terminal 9 and the negative electrode external terminal 10, and the positive electrode current collector terminal 11 and the negative electrode current collector terminal 12 are assembled to the lid 21 of the housing case 2. Referring to FIG. 17, positive external terminal 9 is assembled to one end of the upper surface of lid 21, and negative external terminal 10 is assembled to the other end of the upper surface of lid 21.

そして、正極外部端子9の下方において、蓋21の下面に正極集電端子11が組付けられ、蓋21に形成される穴を通じて正極外部端子9と正極集電端子11の台座部22とが電気的に接続される。同様に、負極外部端子10の下方において、蓋21の下面に負極集電端子12が組付けられ、蓋21に形成される穴を通じて負極外部端子10と負極集電端子12の台座部25とが電気的に接続される。   Then, below the positive external terminal 9, the positive current collector terminal 11 is assembled to the lower surface of the lid 21, and the positive external terminal 9 and the pedestal portion 22 of the positive current collector terminal 11 are electrically connected through a hole formed in the lid 21. Connected. Similarly, below the negative electrode external terminal 10, the negative electrode current collector terminal 12 is assembled to the lower surface of the lid 21, and the negative electrode external terminal 10 and the base portion 25 of the negative electrode current collector terminal 12 are connected through a hole formed in the lid 21. Electrically connected.

再び図8を参照して、蓋・電極体組付工程S6では、蓋成形工程S5で組付けられた蓋21、正極外部端子9、負極外部端子10、正極集電端子11、及び負極集電端子12が、電極体3に組付けられる。   Referring to FIG. 8 again, in the lid / electrode assembly assembling step S6, the lid 21, the positive external terminal 9, the negative external terminal 10, the positive current collecting terminal 11, and the negative current collecting assembled in the lid forming step S5. The terminal 12 is assembled to the electrode body 3.

図18は、収容ケース2の蓋21並びに正極集電端子11及び負極集電端子12が電極体3に組付けられた様子を示した図である。図19は、正極集電端子11が電極体3に組付けられる様子を示した図である。   FIG. 18 is a diagram illustrating a state in which the lid 21 of the housing case 2, the positive electrode current collector terminal 11, and the negative electrode current collector terminal 12 are assembled to the electrode body 3. FIG. 19 is a view showing a state in which the positive electrode current collecting terminal 11 is assembled to the electrode body 3.

図18及び図19を参照して、蓋21並びに正極集電端子11及び負極集電端子12が電極体3の上方から電極体3に組付けられる。このとき、正極集電端子11の脚部23のスリットに正極集電体7が挿入されるように、正極集電端子11が電極体3に組付けられる。なお、図示していないが、負極側についても、負極集電端子12の脚部26のスリットに負極集電体8が挿入されるように、負極集電端子12が電極体3に組付けられる。   With reference to FIGS. 18 and 19, the lid 21, the positive electrode current collector terminal 11, and the negative electrode current collector terminal 12 are assembled to the electrode body 3 from above the electrode body 3. At this time, the positive electrode current collector terminal 11 is assembled to the electrode body 3 so that the positive electrode current collector 7 is inserted into the slit of the leg portion 23 of the positive electrode current collector terminal 11. Although not shown, the negative electrode current collector terminal 12 is assembled to the electrode body 3 so that the negative electrode current collector 8 is inserted into the slit of the leg portion 26 of the negative electrode current collector terminal 12 also on the negative electrode side. .

再び図8を参照して、集電端子加圧工程S7では、正極集電端子11の脚部23が両側面から加圧され、脚部23と正極集電体7との隙間が狭められる。同様に、負極集電端子12の脚部26も両側面から加圧され、脚部26と負極集電体8との隙間が狭められる。   Referring to FIG. 8 again, in the current collecting terminal pressurizing step S7, the leg portion 23 of the positive electrode current collecting terminal 11 is pressurized from both side surfaces, and the gap between the leg portion 23 and the positive electrode current collector 7 is narrowed. Similarly, the leg part 26 of the negative electrode current collector terminal 12 is also pressurized from both side surfaces, and the gap between the leg part 26 and the negative electrode current collector 8 is narrowed.

集電端子溶接工程S8では、正極集電端子11の脚部23と正極集電体7とが溶接され、負極集電端子12の脚部26と負極集電体8とが溶接される。   In the current collector terminal welding step S8, the leg portion 23 of the positive electrode current collector terminal 11 and the positive electrode current collector 7 are welded, and the leg portion 26 of the negative electrode current collector terminal 12 and the negative electrode current collector 8 are welded.

図20は、正極集電端子11の脚部23に正極集電体7が溶接される様子を示す斜視図である。図21から図23は、正極集電端子11の脚部23に正極集電体7が溶接される様子を示す断面図である。   FIG. 20 is a perspective view showing a state in which the positive electrode current collector 7 is welded to the leg portion 23 of the positive electrode current collector terminal 11. 21 to 23 are cross-sectional views showing a state in which the positive electrode current collector 7 is welded to the leg portion 23 of the positive electrode current collector terminal 11.

図20から図23を参照して、正極集電体7の先端部は、脚部23A〜23D間のスリットから突出している。集電端子加圧工程S7において脚部23A〜23Dを両側面から加圧した状態で、正極集電体7の先端部にレーザ光LBを照射することによって、正極集電体7が脚部23A〜23Dに溶接される。   Referring to FIGS. 20 to 23, the tip of positive electrode current collector 7 protrudes from a slit between leg portions 23A to 23D. By irradiating the tip of the positive electrode current collector 7 with the laser beam LB in a state where the leg parts 23A to 23D are pressurized from both sides in the current collecting terminal pressurizing step S7, the positive electrode current collector 7 becomes the leg part 23A. Welded to ~ 23D.

この実施の形態では、脚部23A〜23Dにプレート部材24(24A,24B)が設けられることにより、集電端子加圧工程S7における脚部23A〜23Dへの加圧の際に脚部の捩れが抑制され、脚部23A〜23Dの配列の乱れが抑制されている。これにより、集電端子加圧工程S7において、脚部23A〜23Dの間に正極集電体7を隙間なくしっかりと挟み込むことができており、溶接部28において脚部23A〜23Dを正極集電体7と良好に溶接できている。   In this embodiment, the plate members 24 (24A, 24B) are provided on the leg portions 23A to 23D, so that the leg portions are twisted when the legs 23A to 23D are pressed in the collector terminal pressurizing step S7. Is suppressed, and the disorder of the arrangement of the leg portions 23A to 23D is suppressed. Thereby, in current collection terminal pressurization process S7, the positive electrode current collector 7 can be firmly sandwiched between the leg portions 23A to 23D without a gap, and the leg portions 23A to 23D are connected to the positive electrode current collector in the welded portion 28. The body 7 is welded well.

再び図8を参照して、収容工程S9では、電極体3、並びに電極体3に組付けられた蓋21、正極集電端子11及び負極集電端子12が、収容ケース2のケース本体20に収容される。蓋21は、ケース本体20の開口部を閉塞するように配置される。   Referring again to FIG. 8, in the housing step S <b> 9, the electrode body 3, the lid 21 assembled to the electrode body 3, the positive electrode current collecting terminal 11, and the negative electrode current collecting terminal 12 are attached to the case body 20 of the housing case 2. Be contained. The lid 21 is disposed so as to close the opening of the case body 20.

蓋溶接工程S10では、蓋21の外周縁部とケース本体20の開口縁部とが溶接される。注入工程S11では、蓋21の図示しない注入口から収容ケース2内に電解液6が注入される。そして、封止工程S12において、上記の注入口が封止部材で閉塞される。これにより、図1に示した密閉型電池1が完成する。   In the lid welding step S10, the outer peripheral edge portion of the lid 21 and the opening edge portion of the case body 20 are welded. In the injection step S11, the electrolytic solution 6 is injected into the housing case 2 from an injection port (not shown) of the lid 21. And in sealing process S12, said inlet is obstruct | occluded with the sealing member. Thereby, the sealed battery 1 shown in FIG. 1 is completed.

<比較例の説明>
以下では、正極集電端子11及び負極集電端子12にそれぞれプレート部材24,27が設けられていない比較例について簡単に説明する。
<Description of Comparative Example>
Hereinafter, a comparative example in which the plate members 24 and 27 are not provided on the positive electrode current collector terminal 11 and the negative electrode current collector terminal 12 will be briefly described.

図24は、比較例における正極集電端子を電極体側から視た場合の正極集電端子の平面図である。図25は、比較例における正極集電端子をY方向に視た場合の平面図である。図24及び図25を参照して、比較例における正極集電端子には、実施の形態におけるプレート部材24が設けられていない。そして、集電端子加圧工程において、正極集電端子の脚部を両側面から加圧すると、外側の脚部23A,23Dが荷重方向に変形する。   FIG. 24 is a plan view of the positive electrode current collector terminal when the positive electrode current collector terminal in the comparative example is viewed from the electrode body side. FIG. 25 is a plan view of the positive electrode current collector terminal in the comparative example when viewed in the Y direction. Referring to FIGS. 24 and 25, the positive electrode current collecting terminal in the comparative example is not provided with the plate member 24 in the embodiment. In the current collecting terminal pressurizing step, when the leg portion of the positive current collecting terminal is pressurized from both side surfaces, the outer leg portions 23A and 23D are deformed in the load direction.

図26及び図27は、比較例における、集電端子加圧工程時の正極集電端子の脚部を模式的に示した断面図である。図26は、脚部23A〜23Dに挟力を加えることによって、脚部23A,23B間のスリット及び脚部23C,23D間のスリットが閉じた場合の脚部23A〜23Dの配置を示す。図27は、さらに挟力を加えることによって、脚部23B,23C間のスリットも閉じた場合の脚部23A〜23Dの配置を示す。なお、実際には、脚部23A〜23D間には、正極集電体が挟み込まれているので、図26,27に示されるようにスリットが完全に閉じることはない。   26 and 27 are cross-sectional views schematically showing the leg portion of the positive electrode current collector terminal during the current collector terminal pressurizing step in the comparative example. FIG. 26 shows the arrangement of the leg portions 23A to 23D when the slits between the leg portions 23A and 23B and the slits between the leg portions 23C and 23D are closed by applying a clamping force to the leg portions 23A to 23D. FIG. 27 shows the arrangement of the leg portions 23A to 23D when the slit between the leg portions 23B and 23C is also closed by further applying a clamping force. In practice, since the positive electrode current collector is sandwiched between the leg portions 23A to 23D, the slit is not completely closed as shown in FIGS.

図26及び図27とともに図25も参照して、比較例における正極集電端子には、本開示の実施の形態におけるプレート部材24が設けられていないので、集電端子加圧工程において脚部23A〜23DにZ方向の外力(挟力)を加えると、スリットの根元を基点に(図25)脚部23A,23Dが捩れ、脚部23A,23Dのスリット側(脚部23Aの脚部23Bと隣接する側、及び脚部23Dの脚部23Cと隣接する側)がX方向(電極体の方向)に変形する。   Referring to FIG. 25 as well as FIG. 26 and FIG. 27, the positive electrode current collector terminal in the comparative example is not provided with the plate member 24 in the embodiment of the present disclosure. When an external force (clamping force) in the Z direction is applied to .about.23D, the legs 23A and 23D are twisted from the base of the slit (FIG. 25), and the slits of the legs 23A and 23D (the legs 23B of the legs 23A and the legs 23B) The adjacent side and the side adjacent to the leg portion 23C of the leg portion 23D) are deformed in the X direction (the direction of the electrode body).

そして、脚部23B,23C間のスリットも閉じる程度に脚部23A〜23Dにさらに外力(挟力)が加えられると(図27)、脚部23B,23C間のスリットの根元がY方向に変形し、その結果、脚部23B,23Cが−X方向(脚部23A,23Dと反対方向)に変形する。   Then, when an external force (clamping force) is further applied to the legs 23A to 23D to such an extent that the slit between the legs 23B and 23C is also closed (FIG. 27), the base of the slit between the legs 23B and 23C is deformed in the Y direction. As a result, the leg portions 23B and 23C are deformed in the −X direction (the direction opposite to the leg portions 23A and 23D).

このように、比較例では、集電端子加圧工程において脚部23A〜23Dを両側面から加圧すると、外側の脚部23A,23Dは捩れ、内側の脚部23B,23Cも変形する。このため、集電端子加圧工程において脚部23A〜23Dの配列が乱れ、脚部23A〜23Dと正極集電体7との間に隙間が残ってしまう。この状態で集電端子溶接工程において脚部23A〜23Dと正極集電体との溶接が行なわれると、隙間からレーザ光が抜けたり、溶接に伴ない生じた金属片が電極体側に飛散したりするおそれがある。   Thus, in the comparative example, when the leg portions 23A to 23D are pressed from both sides in the current collecting terminal pressurizing step, the outer leg portions 23A and 23D are twisted and the inner leg portions 23B and 23C are also deformed. For this reason, the arrangement of the leg portions 23 </ b> A to 23 </ b> D is disturbed in the current collecting terminal pressurizing step, and a gap remains between the leg portions 23 </ b> A to 23 </ b> D and the positive electrode current collector 7. In this state, when the leg portions 23A to 23D are welded to the positive electrode current collector in the current collector terminal welding process, laser light is emitted from the gap, or metal pieces generated by welding are scattered to the electrode body side. There is a risk.

図28は、比較例において正極集電端子の脚部23に正極集電体7が溶接される様子を示した断面図である。図28を参照して、脚部23A〜23D間のスリットから突出した正極集電体7の先端部にレーザ光LBを照射することによって、正極集電体7が脚部23A〜23Dに溶接される。   FIG. 28 is a cross-sectional view showing how the positive electrode current collector 7 is welded to the leg portion 23 of the positive electrode current collector terminal in the comparative example. Referring to FIG. 28, the positive electrode current collector 7 is welded to the leg portions 23A to 23D by irradiating the front end portion of the positive electrode current collector 7 protruding from the slit between the leg portions 23A to 23D with the laser beam LB. The

比較例では、脚部23A〜23Dの配列に乱れが生じているため、脚部23A〜23Dと正極集電体7との間に隙間が生じているおそれがある。そうすると、その隙間からレーザ光LBが抜けたり、図示されるように、溶接に伴ない生じた金属片が電極体側(集電体側)に飛散したりする可能性がある。   In the comparative example, since the arrangement of the leg portions 23 </ b> A to 23 </ b> D is disturbed, there may be a gap between the leg portions 23 </ b> A to 23 </ b> D and the positive electrode current collector 7. Then, there is a possibility that the laser beam LB may be lost from the gap, or, as shown in the figure, metal pieces generated by welding may be scattered on the electrode body side (current collector side).

これに対して、この実施の形態に従う密閉型電池1では、図2から図7に示したように、脚部23A(23D)の脚部23B(23C)の方向への移動を許容しつつ、脚部23A(23D)の電極体3の方向への移動を規制するプレート部材24A(24B)が設けられる。これにより、集電端子加圧工程S7において、脚部23A〜23D間のスリットに正極集電体7を挟み込んだ場合に、図5から図7に示したように、脚部23A〜23Dの配列の乱れが抑制され、脚部23A〜23D間に正極集電体7を隙間なくしっかりと挟み込むことができる。その結果、良好な溶接が行なわれるとともに、溶接の際に隙間からレーザ光LBが抜けたり、溶接に伴ない生じた金属片が電極体3側に飛散したりするのを抑制することができる。   On the other hand, in the sealed battery 1 according to this embodiment, as shown in FIGS. 2 to 7, while allowing the movement of the leg 23A (23D) in the direction of the leg 23B (23C), A plate member 24A (24B) that restricts the movement of the leg 23A (23D) in the direction of the electrode body 3 is provided. Thereby, in the current collector terminal pressurizing step S7, when the positive electrode current collector 7 is sandwiched between the slits between the leg portions 23A to 23D, the arrangement of the leg portions 23A to 23D as shown in FIGS. Is prevented, and the positive electrode current collector 7 can be firmly sandwiched between the leg portions 23A to 23D without any gap. As a result, good welding can be performed, and laser beam LB can be prevented from being released from the gap during welding, and metal pieces generated due to welding can be prevented from scattering to the electrode body 3 side.

図29は、本開示の実施の形態に従う密閉型電池1と、上記の比較例の密閉型電池とにおいて、集電端子と集電体との溶接の評価結果を示した図である。溶接の評価においては、溶接箇所を分解し、レーザ光抜けによるセパレータの損傷ダメージを確認するとともに、溶融物の飛散の有無を確認した。セパレータの損傷ダメージについては、熱による透明化部がセパレータに生じていないかを拡大鏡で確認した。溶融物の飛散については、集電端子の裏側の飛散物の有無を拡大鏡で確認した。評価については、セパレータの損傷ダメージがなく、かつ、溶融物の飛散もなかったものを良品(評価OK)とした。   FIG. 29 is a diagram illustrating an evaluation result of welding between the current collector terminal and the current collector in the sealed battery 1 according to the embodiment of the present disclosure and the sealed battery of the comparative example. In the evaluation of welding, the welded portion was disassembled, the separator was damaged and damaged by the laser beam loss, and the presence or absence of the melt was confirmed. About the damage damage of a separator, it confirmed with the magnifier whether the transparent part by heat had arisen in the separator. About the scattering of the molten material, the presence or absence of the scattered material on the back side of the current collecting terminal was confirmed with a magnifying glass. About evaluation, what did not have the damage damage of a separator and was not scattered of a melt was made good (evaluation OK).

図29を参照して、比較例の密閉型電池については、10サンプル中のうちの5サンプルにおいて、セパレータの損傷ダメージ及び溶融物の飛散の少なくともいずれかが確認された。集電端子加圧工程において集電端子の脚部の配列乱れが生じたために、隙間からのレーザ光抜けや、溶接に伴ない生じた金属片の飛散が生じたものである。   Referring to FIG. 29, regarding the sealed battery of the comparative example, at least one of damage damage to the separator and scattering of the melt was confirmed in 5 samples out of 10 samples. In the current collecting terminal pressurizing step, the arrangement disorder of the leg portions of the current collecting terminal occurred, so that the laser light was lost from the gap and the metal pieces generated due to welding were scattered.

一方、本開示の実施の形態に従う密閉型電池1については、10サンプル全て良品であった。密閉型電池1では、正極集電端子11及び負極集電端子12にそれぞれプレート部材24,27が設けられているので、集電端子加圧工程において集電端子の脚部の配列乱れが抑制される。その結果、隙間からのレーザ光抜けが抑制され、セパレータの損傷や、溶接に伴なう溶融物の電池内部への飛散が抑制されている。   On the other hand, for sealed battery 1 according to the embodiment of the present disclosure, all 10 samples were non-defective products. In the sealed battery 1, since the plate members 24 and 27 are provided on the positive electrode current collector terminal 11 and the negative electrode current collector terminal 12, respectively, the disorder of the arrangement of the legs of the current collector terminal is suppressed in the current collector terminal pressurizing step. The As a result, the laser beam is prevented from coming out from the gap, and the damage to the separator and the scattering of the melt accompanying the welding into the battery are suppressed.

以上のように、本開示の実施の形態によれば、正極集電端子11及び負極集電端子12を電極体3(正極集電体7及び負極集電体8)に良好に溶接可能であり、かつ、溶接の際の電極体3への影響を抑制することができる。   As described above, according to the embodiment of the present disclosure, the positive electrode current collector terminal 11 and the negative electrode current collector terminal 12 can be well welded to the electrode body 3 (the positive electrode current collector 7 and the negative electrode current collector 8). And the influence on the electrode body 3 in the case of welding can be suppressed.

[変形例1]
図30は、実施の形態の変形例1における正極集電端子を−X方向から(電極体3側から)視た場合の正極集電端子の平面図であり、図31は、図30中のXXXI-XXXIに沿った断面図である。なお、負極集電端子の構成も、正極集電端子と同様であり、以下では、正極集電端子について代表的に説明される。
[Modification 1]
30 is a plan view of the positive electrode current collector terminal when the positive electrode current collector terminal in Modification 1 of the embodiment is viewed from the −X direction (from the electrode body 3 side). FIG. 31 is a plan view of FIG. It is sectional drawing along XXXI-XXXI. In addition, the structure of a negative electrode current collection terminal is the same as that of a positive electrode current collection terminal, and below, a positive electrode current collection terminal is demonstrated typically.

図30及び図31を参照して、この変形例1では、正極集電端子11Aは、図3及び図4に示した上記の実施の形態における正極集電端子11において、プレート部材24(24A,24B)に代えてプレート部材40(40A,40B)を含む。   With reference to FIGS. 30 and 31, in Modification 1, the positive electrode current collecting terminal 11 </ b> A is the same as the plate member 24 (24 </ b> A, 24 </ b> A, 24B) includes a plate member 40 (40A, 40B).

プレート部材40Aは、脚部23Aにかかる部分において段差部41Aが形成されている点でプレート部材24Aと異なる。段差部41Aは、脚部23Aと隙間を有するように形成されている。プレート部材40Bも、脚部23Dにかかる部分において段差部41Bが形成されている点でプレート部材24Bと異なる。段差部41Bは、脚部23Dと隙間を有するように形成されている。   The plate member 40A is different from the plate member 24A in that a stepped portion 41A is formed at a portion of the leg portion 23A. The step portion 41A is formed to have a gap with the leg portion 23A. The plate member 40B is also different from the plate member 24B in that a stepped portion 41B is formed in a portion related to the leg portion 23D. The step portion 41B is formed to have a gap with the leg portion 23D.

段差部41Aと脚部23Aとの隙間、及び段差部41Bと脚部23Dとの隙間については、たとえば、集電端子加圧工程S7における脚部23A〜23Dへの加圧の際の、脚部23A,23Dの捩れの許容範囲に基づいて決定することができる。   Regarding the gap between the stepped portion 41A and the leg portion 23A and the gap between the stepped portion 41B and the leg portion 23D, for example, the leg portion at the time of pressurizing the leg portions 23A to 23D in the collector terminal pressurizing step S7 It can be determined based on the allowable range of twist of 23A and 23D.

このような段差部41A,41Bが形成されることにより、集電端子加圧工程S7における脚部23A〜23Dへの加圧の初期段階において、脚部23A(23D)がプレート部材40A(40B)と接触しない。これにより、脚部23A(23D)とプレート部材40A(40B)との間に摩擦が発生せず、脚部23A〜23Dへの負荷及び脚部23A〜23Dの変形が軽減される。   By forming such stepped portions 41A and 41B, the leg portion 23A (23D) becomes the plate member 40A (40B) at the initial stage of pressurization to the leg portions 23A to 23D in the collector terminal pressurizing step S7. Do not contact with. Thereby, friction does not generate | occur | produce between leg part 23A (23D) and plate member 40A (40B), and the load to leg part 23A-23D and a deformation | transformation of leg part 23A-23D are reduced.

[変形例2]
図32は、実施の形態の変形例2における正極集電端子を−X方向から(電極体3側から)視た場合の正極集電端子の平面図であり、図33は、図32中のXXXIII-XXXIIIに沿った断面図である。なお、負極集電端子の構成も、正極集電端子と同様であり、以下では、正極集電端子について代表的に説明される。
[Modification 2]
32 is a plan view of the positive electrode current collector terminal when the positive electrode current collector terminal in Modification 2 of the embodiment is viewed from the −X direction (from the electrode body 3 side). FIG. 33 is a plan view of FIG. It is sectional drawing along XXXIII-XXXIII. In addition, the structure of a negative electrode current collection terminal is the same as that of a positive electrode current collection terminal, and below, a positive electrode current collection terminal is demonstrated typically.

図32及び図33を参照して、この変形例2では、正極集電端子11Bは、図3及び図4に示した上記の実施の形態における正極集電端子11において、プレート部材24A,24Bに代えてそれぞれプレート状部位45A,45Bを含む。   Referring to FIGS. 32 and 33, in Modification 2, positive electrode current collecting terminal 11B is connected to plate members 24A and 24B in positive electrode current collecting terminal 11 in the above-described embodiment shown in FIGS. Instead, plate-like portions 45A and 45B are included.

プレート状部位45A,45Bは、図3及び図4に示した正極集電端子11のプレート部材24A,24Bが取付けられている部分において、それぞれ脚部23B,23Cと一体的に形成されている。   The plate-like portions 45A and 45B are integrally formed with the leg portions 23B and 23C, respectively, in the portion where the plate members 24A and 24B of the positive electrode current collecting terminal 11 shown in FIGS. 3 and 4 are attached.

そして、プレート状部位45Aは、脚部23Bからその外側に隣接する脚部23Aに向けて延び、かつ脚部23Aにかかるように形成されている。プレート状部位45Bは、脚部23Cからその外側に隣接する脚部23Dに向けて延び、かつ脚部23Dにかかるように形成されている。   The plate-like portion 45A is formed so as to extend from the leg portion 23B toward the leg portion 23A adjacent to the outside of the leg portion 23B and to cover the leg portion 23A. The plate-like portion 45B extends from the leg portion 23C toward the leg portion 23D adjacent to the outside thereof and is formed so as to cover the leg portion 23D.

なお、特に図示しないが、上記の変形例1のように、プレート状部位45Aの脚部23Aにかかる部分において、脚部23Aと隙間を有するように段差部を設け、プレート状部位45Bの脚部23Dにかかる部分において、脚部23Dと隙間を有するように段差部を設けてもよい。   Although not particularly illustrated, a step portion is provided in the portion of the plate-like portion 45A on the leg portion 23A so as to have a gap with the leg portion 23A as in the first modification, and the leg portion of the plate-like portion 45B is provided. In the portion related to 23D, a step portion may be provided so as to have a gap with the leg portion 23D.

[変形例3]
図34は、実施の形態の変形例3における正極集電端子を−X方向から(電極体3側から)視た場合の正極集電端子の平面図である。図35は、この変形例3において、電極体3に取付けられた正極集電端子をX方向に視た場合の平面図である。
[Modification 3]
FIG. 34 is a plan view of the positive electrode current collector terminal when the positive electrode current collector terminal in Modification 3 of the embodiment is viewed from the −X direction (from the electrode body 3 side). FIG. 35 is a plan view of the modification 3 in which the positive electrode current collecting terminal attached to the electrode body 3 is viewed in the X direction.

図34及び図35を参照して、上記の実施の形態では、図2及び図3に示したように、プレート部材24A,24Bは、電極体3の正極集電体7よりも上方(台座部22に近い側)に設けられるものとしたが、図示されるように、プレート部材24A,24Bは、電極体3の正極集電体7よりも下方(台座部22から遠い側)に設けられてもよい。   34 and 35, in the above-described embodiment, as shown in FIGS. 2 and 3, the plate members 24A and 24B are located above the positive electrode current collector 7 of the electrode body 3 (the pedestal portion). The plate members 24A and 24B are provided below the positive electrode current collector 7 of the electrode body 3 (on the side far from the pedestal portion 22) as shown in the figure. Also good.

今回開示された実施の形態は、すべての点で例示であって制限的なものではないと考えられるべきである。本発明の範囲は、上記した実施の形態の説明ではなくて特許請求の範囲によって示され、特許請求の範囲と均等の意味及び範囲内でのすべての変更が含まれることが意図される。   The embodiment disclosed this time should be considered as illustrative in all points and not restrictive. The scope of the present invention is shown not by the above description of the embodiment but by the scope of claims, and is intended to include all modifications within the meaning and scope equivalent to the scope of claims.

1 密閉型電池、2 収容ケース、3 電極体、4,5 端面、6 電解液、7 正極集電体、8 負極集電体、9 正極外部端子、10 負極外部端子、11,11A,11B 正極集電端子、12 負極集電端子、20 ケース本体、21 蓋、22,25 台座部、23,23A〜23D,26 脚部、24,24A,24B,27,40A,40B プレート部材、28 溶接部、29 接合部、30 正極シート、31,34 活物質合剤層、32,35 未塗工箔部、33 負極シート、41A,41B 段差部、45A,45B プレート状部位、50,51 集箔治具。   DESCRIPTION OF SYMBOLS 1 Sealed battery, 2 Containment case, 3 Electrode body, 4, 5 End surface, 6 Electrolyte, 7 Positive electrode collector, 8 Negative electrode collector, 9 Positive external terminal, 10 Negative external terminal, 11, 11A, 11B Positive electrode Current collecting terminal, 12 Negative current collecting terminal, 20 Case body, 21 Lid, 22, 25 Base part, 23, 23A to 23D, 26 Leg part, 24, 24A, 24B, 27, 40A, 40B Plate member, 28 Welded part , 29 Joint part, 30 Positive electrode sheet, 31, 34 Active material mixture layer, 32, 35 Uncoated foil part, 33 Negative electrode sheet, 41A, 41B Step part, 45A, 45B Plate-like part, 50, 51 Ingredients.

Claims (1)

積層された複数の極板を含んで構成され、前記複数の極板の積層方向に沿う側面に集電体が形成された電極体と、
前記集電体に溶接された集電端子とを備え、
前記集電端子は、
台座部と、
前記台座部から互いに間隔をあけて前記側面に沿って延びる複数の脚部とを含み、
前記集電体は、前記複数の脚部の間に挟み込まれて前記複数の脚部に溶接されており、
前記集電端子は、さらに、
前記複数の脚部のうちの一の脚部に設けられるとともに前記一の脚部から前記一の脚部の外側に隣接する他の脚部に向けて延び、前記他の脚部の前記一の脚部の方向への移動を許容しつつ前記他の脚部の前記電極体の方向への移動を規制するように構成された部材を含む、密閉型電池。
An electrode body that includes a plurality of stacked electrode plates, and a current collector is formed on a side surface along the stacking direction of the plurality of electrode plates;
A current collector terminal welded to the current collector,
The current collecting terminal is
A pedestal,
A plurality of legs extending along the side surface at a distance from the pedestal,
The current collector is sandwiched between the plurality of legs and welded to the plurality of legs.
The current collecting terminal further includes:
The one of the plurality of legs is provided on one leg and extends from the one leg toward another leg adjacent to the outside of the one leg. A sealed battery including a member configured to regulate movement of the other leg in the direction of the electrode body while allowing movement in the direction of the leg.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013084546A (en) * 2011-09-28 2013-05-09 Toyota Industries Corp Power storage device and vehicle
JP2013196959A (en) * 2012-03-21 2013-09-30 Toyota Industries Corp Power storage device, secondary battery and vehicle
JP2015141891A (en) * 2014-01-28 2015-08-03 三星エスディアイ株式会社Samsung SDI Co.,Ltd. secondary battery
JP2018125068A (en) * 2017-01-30 2018-08-09 トヨタ自動車株式会社 Manufacturing method of secondary battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013084546A (en) * 2011-09-28 2013-05-09 Toyota Industries Corp Power storage device and vehicle
JP2013196959A (en) * 2012-03-21 2013-09-30 Toyota Industries Corp Power storage device, secondary battery and vehicle
JP2015141891A (en) * 2014-01-28 2015-08-03 三星エスディアイ株式会社Samsung SDI Co.,Ltd. secondary battery
JP2018125068A (en) * 2017-01-30 2018-08-09 トヨタ自動車株式会社 Manufacturing method of secondary battery

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