JP6745579B2 - Oil composition for stir-fry cooking - Google Patents

Oil composition for stir-fry cooking Download PDF

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JP6745579B2
JP6745579B2 JP2014242109A JP2014242109A JP6745579B2 JP 6745579 B2 JP6745579 B2 JP 6745579B2 JP 2014242109 A JP2014242109 A JP 2014242109A JP 2014242109 A JP2014242109 A JP 2014242109A JP 6745579 B2 JP6745579 B2 JP 6745579B2
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fat composition
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弥生 金子
弥生 金子
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Showa Sangyo Co Ltd
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Description

本発明は、米飯や麺類などの澱粉系食材を炒め調理する際に用いる油脂組成物に関する。特に本発明は、澱粉系食材を炒め調理する際に用いられ、炒め調理をしやすくするとともに、炒め調理された食品の食感や美味しさを向上させることのできる油脂組成物に関する。 TECHNICAL FIELD The present invention relates to an oil and fat composition used when frying and cooking starch-based foodstuffs such as cooked rice and noodles. In particular, the present invention relates to an oil and fat composition which is used when stir-frying a starch-based food material, which makes it easy to stir-fried and can improve the texture and taste of the stir-fried food.

一般に米飯や麺類などの澱粉系食材は、調理直後の結着性はそれほど強くないものの、時間の経過とともに、澱粉によって互いが結着したり、食材同士がべとつきやすくなる。これは、糊化された澱粉の粘着性によって、食材が互いに付着してしまうことが原因である。 Generally, starch-based food materials such as cooked rice and noodles are not so strongly bound immediately after being cooked, but with the passage of time, the starch-based food materials become bound to each other or the food materials tend to become sticky. This is due to the stickiness of the gelatinized starch causing the food materials to stick to each other.

従来、麺類などの澱粉系食材の付着を抑制し、ほぐれ性を改善するために、いくつかの技術が提案されている。例えば、食用油脂を用いて麺類の付着を抑制することが提案されているが、単に食用油脂を添加しただけでは、均一に食用油脂を付着させることが難しく、むらができてしまう場合がある。 Conventionally, several techniques have been proposed in order to suppress the adhesion of starch-based food materials such as noodles and improve the loosening property. For example, it has been proposed to suppress the attachment of noodles by using edible oil and fat, but it is difficult to uniformly attach the edible oil and fat, and unevenness may be caused by simply adding the edible oil and fat.

そこで、麺類への食用油脂の付着性を高めるために、食用油脂に乳化剤を添加した組成物を麺類のほぐれ性向上剤として使用することが提案されている。例えば、特許文献1〜3には、特定のポリグリセリン脂肪酸エステルを用いることが記載されており、特許文献4には、ジグリセリン脂肪酸エステルを用いることが記載されている。また、特許文献5には、ポリグリセリン脂肪酸エステルとポリオキシエチレンソルビタン脂肪酸エステルを併用することが記載されている。 Therefore, in order to improve the adhesion of the edible oil/fat to the noodles, it has been proposed to use a composition obtained by adding an emulsifier to the edible oil/fat as a raveling improver for noodles. For example, Patent Documents 1 to 3 describe using a specific polyglycerin fatty acid ester, and Patent Document 4 describes using a diglycerin fatty acid ester. Further, Patent Document 5 describes that polyglycerin fatty acid ester and polyoxyethylene sorbitan fatty acid ester are used in combination.

また、炒め調理などの調理時に用いる油脂組成物にレシチンを用いることも提案されている。例えば、特許文献6〜8には、食用油脂にレシチンを配合することによって調理用の油脂組成物を調製することが記載されている。 It has also been proposed to use lecithin in an oil and fat composition used during cooking such as stir-fry cooking. For example, Patent Documents 6 to 8 describe that an oil and fat composition for cooking is prepared by blending edible oil and fat with lecithin.

さらに、炒め調理などの調理時に用いる油脂組成物に乳化剤を用いることも提案されている。例えば、特許文献9には、グリセリンのオレイン酸エステルを食用油脂に配合した炒め物用の油脂組成物が記載されている。 Further, it has been proposed to use an emulsifier in an oil and fat composition used for cooking such as stir-fried cooking. For example, Patent Document 9 describes an oil and fat composition for stir-fried foods in which oleic acid ester of glycerin is mixed with edible oil and fat.

特開平07−039332号公報Japanese Patent Laid-Open No. 07-039332 特開平07−298847号公報JP-A-07-298847 特開平11−221033号公報JP, 11-221033, A 特開平09−037728号公報Japanese Patent Laid-Open No. 09-037728 特開2006−006132号公報JP, 2006-006132, A 特開平8−89186号公報JP-A-8-89186 特開2009−039021号公報JP, 2009-039021, A 特開2012−249621号公報JP2012-249621A 特開2007−105035号公報JP, 2007-105035, A

従来、澱粉系食材を炒め調理する際の技術課題として、フライパンや中華鍋などの調理器具への付着防止が重視され、種々の提案がなされてきた。例えば、炒め調理の際に用いられる油脂(炒め油)については、上述したように、レシチンや乳化剤を配合することによって調理器具への剥離性を向上させることが提案されてきた(特許文献6〜9)。 BACKGROUND ART Conventionally, various technical proposals have been made with a focus on prevention of adhesion to cooking utensils such as frying pans and woks as a technical problem when frying starch-based foods. For example, regarding oils and fats (frying oil) used during stir-fry cooking, it has been proposed to improve the peelability to cooking utensils by blending lecithin and an emulsifier as described above (Patent Documents 6 to 6). 9).

また近年は、調理器具や調理設備、さらには調理手法の観点から、炒め調理する際の食材と調理器具との付着防止技術の改良が進んでおり、炒め油にあまり依存せずに食材と調理器具の付着防止を図ることも可能になっている。 In recent years, from the viewpoint of cooking utensils, cooking equipment, and cooking techniques, the technology for preventing the food from sticking to the cooking utensils during frying has been improved, and the cooking ingredients and cooking u It is also possible to prevent attachment of equipment.

このような状況の中、炒め調理時に用いられる油脂(炒め油)に求められるニーズが変化してきており、従来重視されてきた調理器具への澱粉系食材の付着防止だけでなく、炒め調理した食材へ付加価値を与えられるような炒め調理用油脂が求められている。例えば、炒め調理時に用いることによって、調理器具への澱粉系食材の付着防止を図ることはもちろん、炒め飯であればパラパラ感、麺類であればつるみ感などを食材に付与するなど、炒め調理後の食品の美味しさをも向上させるような油脂組成物が求められている。 Under these circumstances, the needs for oils and fats used in stir-fried cooking (stir-fried oil) are changing, and not only is the prevention of starch-based food materials from sticking to cooking utensils, which has been emphasized in the past, the foods that are stir-fried. There is a need for stir-frying oils and fats that can add value to For example, by using it during stir cooking, it is possible to prevent starch-based food materials from sticking to the cooking utensils, and to give the food a fluffy texture for stir-fried rice and a slushy texture for noodles. There is a need for an oil and fat composition that improves the taste of the food.

上述したように、炒め調理用の油脂組成物としては、従来、レシチンを配合することが知られているが、レシチンを配合した油脂組成物を用いて炒め調理を行うと味や臭いに影響が生じてしまい、また、炒め調理時の熱によって着色(加熱着色)が生じてしまうという問題があった。すなわち、従来用いられてきたレシチンを配合した油脂組成物では、炒め調理時の調理器具と食材との剥離性を向上させることはできるものの、調理後の食品の価値を損なってしまうことがあった。 As described above, as an oil and fat composition for stir-fry cooking, it is conventionally known to mix lecithin, but when the oil and fat composition containing lecithin is used for stir-fry cooking, the taste and odor are affected. In addition, there is a problem that coloring occurs (heating coloring) due to heat during stir cooking. That is, in the oil composition containing lecithin that has been conventionally used, although it is possible to improve the peelability between the cooking utensil and the food material at the time of stir cooking, the value of the food after cooking may be impaired. ..

このような状況に鑑み、本発明の課題は、特に澱粉系食材を炒め調理した後の食品の価値を高められる、炒め調理に利用するための油脂組成物を提供することである。 In view of such a situation, an object of the present invention is to provide an oil and fat composition for use in stir cooking, which can enhance the value of foods after stir cooking a starch-based foodstuff.

本発明者らが上記課題について鋭意検討したところ、HLBが4.7〜8である乳化剤を食用油脂に配合した油脂組成物を用いることによって、澱粉系食材を美味しく炒め調理した食品が得られることを見出し、本発明を完成させるに至った。 When the present inventors have diligently studied the above-mentioned problems, it is possible to obtain a food in which a starch-based food material is deliciously fried and cooked by using an oil and fat composition in which an edible oil and fat has an emulsifier having an HLB of 4.7 to 8. The present invention has been completed and the present invention has been completed.

本発明は、これに限定されるものではないが、以下の態様を包含する。
(1) HLBが4.7〜8の乳化剤(a)と食用油脂を含有する、澱粉系食材の炒め調理用の油脂組成物。
(2) HLBが2.5以下の乳化剤(b)をさらに含有する、(1)に記載の油脂組成物。
(3) 澱粉系食材が、米飯または麺類である、(1)または(2)に記載の油脂組成物。
(4) 前記乳化剤(a)および(b)の合計の配合量が、食用油脂に対して0.3〜20重量%である、(2)に記載の油脂組成物。
(5) (a)と(b)の重量比が、90:10〜10:90である、(2)に記載の油脂組成物。
(6) 前記乳化剤(a)が、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、有機酸脂肪酸エステルから選ばれる1以上を含む、(1)〜(5)のいずれかに記載の油脂組成物。
(7) 前記乳化剤(a)が、クエン酸モノオレイン酸エステル、ジグリセリン脂肪酸エステルから選ばれる1以上を含む、(1)〜(6)のいずれかに記載の油脂組成物。
(8) 前記乳化剤(b)が、ポリグリセリン縮合リシノレイン酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる1以上を含む、(2)に記載の油脂組成物。
(9) 炒め調理時の炒め油として用いられる、(1)〜(8)のいずれかに記載の油脂組成物。
(10) 炒め調理時に他の炒め油と併せて用いられる、(1)〜(8)のいずれかに記載の油脂組成物。
(11) 澱粉系食材に予め付着させてから炒め調理に用いられる、(1)〜(8)のいずれかに記載の油脂組成物。
(12) 澱粉系食材を炒め調理した食品を再加熱する際に、食品に付着させて用いられる、(1)〜(8)のいずれかに記載の油脂組成物。
(13) (1)〜(8)のいずれかに記載の油脂組成物を添加して澱粉系食材を炒め調理することを含む、澱粉系食材の調理方法。
(14) (13)の方法によって調理して得られる食品。
The present invention includes, but is not limited to, the following aspects.
(1) An oil and fat composition for stir-frying a starch-based food material, which comprises an emulsifier (a) having an HLB of 4.7 to 8 and an edible oil and fat.
(2) The oil and fat composition according to (1), further containing an emulsifier (b) having an HLB of 2.5 or less.
(3) The oil and fat composition according to (1) or (2), wherein the starch-based food material is cooked rice or noodles.
(4) The oil/fat composition according to (2), wherein the total content of the emulsifiers (a) and (b) is 0.3 to 20% by weight based on the edible oil and fat.
(5) The oil/fat composition according to (2), wherein the weight ratio of (a) and (b) is 90:10 to 10:90.
(6) The oil and fat composition according to any one of (1) to (5), wherein the emulsifier (a) contains one or more selected from polyglycerin fatty acid ester, sorbitan fatty acid ester, and organic acid fatty acid ester.
(7) The oil and fat composition according to any one of (1) to (6), wherein the emulsifier (a) contains one or more selected from citric acid monooleate and diglycerin fatty acid ester.
(8) The oil and fat composition according to (2), wherein the emulsifier (b) contains one or more selected from polyglycerin condensed ricinoleic acid ester, sorbitan fatty acid ester and sucrose fatty acid ester.
(9) The oil/fat composition according to any one of (1) to (8), which is used as a stir-fry oil during stir-fry cooking.
(10) The oil and fat composition according to any one of (1) to (8), which is used in combination with other stir-fry oil during stir-fry cooking.
(11) The oil/fat composition according to any one of (1) to (8), which is used for frying after being preliminarily attached to a starch-based food material.
(12) The oil and fat composition according to any one of (1) to (8), which is used by adhering to a food when reheating a food prepared by frying a starch-based food.
(13) A method for cooking a starch-based food material, which comprises adding the oil composition according to any one of (1) to (8) and stir-frying the starch-based food material.
(14) A food obtained by cooking by the method of (13).

本発明によれば、炒め調理時の澱粉系食材と調理器具との付着性を抑制できるだけでなく、食材を美味しく炒め調理することができる。本発明の油脂組成物によれば、例えば、炒め飯(チャーハン)であれば米飯のパラパラ感が出るように炒め調理することが容易になり、焼きそばやパスタなどの麺類であれば、炒め調理後にも麺のつるみ感を出すことが容易になる。特に、本発明の油脂組成物を炒め調理時に用いると、油脂、調味料、熱などが効率的に澱粉系食材に行き渡ることから、澱粉系食材と調理器具の付着性を抑制できることはもちろん、炒め調理によって美味しい食品を得ることが容易になる。 ADVANTAGE OF THE INVENTION According to this invention, not only the adhesiveness of a starch-type foodstuff and a cooking utensil at the time of a fried cooking can be suppressed, but also a fried food can be deliciously fried and cooked. According to the oil/fat composition of the present invention, for example, fried rice (fried rice) can be easily fried and cooked so that the rice has a fluffy texture, and noodles such as yakisoba and pasta can be cooked after fried cooking. It also makes it easier to give the noodles a tightness. In particular, when the oil/fat composition of the present invention is used during frying and cooking, oils, seasonings, heat, etc. are efficiently spread to the starch-based foodstuffs, and thus the adhesion of the starch-based foodstuffs and the cooking utensils can be suppressed, as well as the frying. Cooking makes it easy to obtain delicious food.

本発明は、HLBが4.7〜8である乳化剤(a)を食用油脂に配合した、澱粉系食材の炒め調理に利用するための油脂組成物に関する。 The present invention relates to an oil/fat composition for use in frying cooking of a starch-based food, which comprises an edible oil/fat containing an emulsifier (a) having an HLB of 4.7 to 8.

本発明の油脂組成物は、澱粉系食材を炒め調理するものに用いられる。例えば、澱粉系食材を炒め調理する際に、本発明の油脂組成物を炒め油として用いることができる。別の態様では、澱粉系食材を炒め調理する際に、本発明の油脂組成物を他の炒め油と併せて用いることができる。また別の態様では、本発明の油脂組成物を澱粉系食材に予め付着させておき、それを炒め調理に供することもできる。 The oil/fat composition of the present invention is used for frying and cooking a starch-based food material. For example, when the starch-based food material is cooked by frying, the oil/fat composition of the present invention can be used as a frying oil. In another embodiment, the oil/fat composition of the present invention can be used in combination with another frying oil when the starch-based food material is cooked by frying. In another embodiment, the oil/fat composition of the present invention may be attached to a starch-based food material in advance, and then it may be subjected to stir-fry cooking.

さらに本発明の油脂組成物は、澱粉系食材を炒め調理した食品を再加熱する際に用いられる。これにより、澱粉系食材を炒め調理した食品に、例えば米飯の場合はパラパラ感、麺類の場合は麺のつるみ感といった良好な品質を付与することができる。例えば、澱粉系食材を炒め調理した食品に本発明の油脂組成物を予め付着させておき、喫食時に電子レンジ等での再加熱に供することで、良好な品質を付与することができる。別の態様では、澱粉系食材を炒め調理した食品を電子レンジ等で再加熱する前に、本発明の油脂組成物を付着させることで、良好な品質を付与することができる。 Furthermore, the oil/fat composition of the present invention is used when reheating a food prepared by frying a starch-based food material. As a result, it is possible to impart good quality to the food prepared by stir-frying the starch-based food material, for example, in the case of cooked rice, the feeling of fluffiness, and in the case of noodles, the taste of noodles. For example, good quality can be imparted by preliminarily adhering the oil composition of the present invention to a food prepared by frying a starch-based food material and subjecting it to reheating in a microwave oven or the like at the time of eating. In another aspect, good quality can be imparted by adhering the oil/fat composition of the present invention before reheating a food prepared by frying a starch-based food material in a microwave oven or the like.

本発明において澱粉系食材とは、澱粉を主体とする食材のことであり、例えば、麺類、米飯、いも類などを挙げることができる。本発明において麺類とは、小麦粉、そば粉、米粉などの穀粉と水などを原料として含み、これらの原料を混捏し、製麺されたものや、緑豆や馬鈴薯等の澱粉を原料にして麺状に調製されたものをいう。具体的には、例えば、パスタ、うどん、きしめん、ひやむぎ、そうめん、そば、中華麺、米麺(ビーフン、フォー等)、春雨などを挙げることができる。また、本発明における麺類は、例えば、茹で麺あるいは蒸し麺の形態で使用されるものであってよく、茹で麺あるいは蒸し麺としては、チルド麺(低温流通麺)、冷凍流通麺あるいは常温流通麺(LL麺)などであってよい。 In the present invention, the starch-based food material is a food material mainly composed of starch, and examples thereof include noodles, cooked rice, potatoes and the like. In the present invention, noodles include wheat flour, buckwheat flour, cereal flour such as rice flour and water as raw materials, kneading these raw materials, noodles made, noodles made from starch such as mung beans and potatoes as raw materials The one prepared in the above. Specific examples thereof include pasta, udon, kishimen, hiyamugi, somen, soba, Chinese noodles, rice noodles (beef noodles, pho, etc.), vermicelli and the like. Further, the noodles in the present invention may be, for example, those used in the form of boiled noodles or steamed noodles, and as boiled noodles or steamed noodles, chilled noodles (low-temperature distribution noodles), frozen distribution noodles or room-temperature distribution noodles may be used. (LL noodle) or the like.

本発明の油脂組成物に用いる油脂は、食用であれば特に限定されるものではなく、植物由来であるか、動物由来であるか、また、合成品であるかも問わない。例えば、大豆油、菜種油、キャノーラ油、コーン油、ひまわり油、紅花油、とうもろこし油、綿実油、ゴマ油、シソ油、亜麻仁油、落花生油、オリーブ油、ブドウ種子油、マカデミアナッツ油、ヘーゼルナッツ油、カボチャ種子油、クルミ油、椿油、茶実油、エゴマ油、ボラージ油、米糠油、小麦胚芽油、パーム油、パーム核油、ヤシ油、カカオ脂、牛脂、豚脂、鶏脂、乳脂、魚油、アザラシ脂、藻類油などを単独または組み合わせて使用することができる。また、水素添加油脂、グリセリンと脂肪酸のエステル化油、エステル交換油、分別油脂なども適宜使用することができる。さらに、遺伝子組換えの技術を用いて品種改良した植物から抽出したものであってもよい。中でも常温で液状を呈する食用油脂とするのが使い勝手の点から好ましい。 The oil/fat used in the oil/fat composition of the present invention is not particularly limited as long as it is edible, and it may be plant-derived, animal-derived, or synthetic. For example, soybean oil, rapeseed oil, canola oil, corn oil, sunflower oil, safflower oil, corn oil, cottonseed oil, sesame oil, perilla oil, linseed oil, peanut oil, olive oil, grape seed oil, macadamia nut oil, hazelnut oil, pumpkin seed oil. , Walnut oil, camellia oil, teaseed oil, perilla oil, borage oil, rice bran oil, wheat germ oil, palm oil, palm kernel oil, coconut oil, cocoa butter, beef tallow, lard, chicken fat, milk fat, fish oil, seal fat , Algal oil and the like can be used alone or in combination. Further, hydrogenated oils and fats, esterified oils of glycerin and fatty acids, transesterified oils, fractionated oils and fats and the like can also be used appropriately. Furthermore, it may be extracted from a plant whose breed has been improved by using a gene recombination technique. Among them, edible oils and fats that are liquid at room temperature are preferable from the viewpoint of ease of use.

本発明に係る油脂組成物には、HLBが4.7〜8である乳化剤(a)が配合される。本発明において乳化剤のHLBとは、Hydrophilic Lipophilic Balanceの略語であり、0(親油基のみの場合)〜20(親水基のみの場合)の数値を有する。Griffin法による場合は、HLB=20×〔1−(エステルのケン化価/原料脂肪酸の中和価)〕によってHLBを算出することができる。乳化剤のHLBが8を超えると、乳化剤が油脂に溶解しにくくなり、白濁してしまう場合がある。一方、乳化剤のHLBが4.7未満であると、澱粉系食材を炒め調理した際に調理しにくく、また、調理後の澱粉系食材がべとつきやすくなる。HLBが4.7〜8である乳化剤(a)については、ある態様において、HLBが5.5以上であってもよく、別の好ましい態様においてHLBを6.0以上としてもよい。 The oil/fat composition according to the present invention contains an emulsifier (a) having an HLB of 4.7 to 8. In the present invention, the emulsifier HLB is an abbreviation for Hydrophilic Lipophilic Balance and has a numerical value of 0 (in the case of only lipophilic group) to 20 (in the case of only hydrophilic group). In the case of the Griffin method, HLB can be calculated by HLB=20×[1-(saponification value of ester/neutralization value of raw material fatty acid)]. When the HLB of the emulsifier exceeds 8, the emulsifier becomes difficult to dissolve in the oil and fat, and may become cloudy. On the other hand, when the HLB of the emulsifier is less than 4.7, it is difficult to cook the starch-based food when it is fried and cooked, and the starch-based food after cooking becomes sticky. Regarding the emulsifier (a) having an HLB of 4.7 to 8, in one embodiment, the HLB may be 5.5 or more, and in another preferred embodiment, the HLB may be 6.0 or more.

HLBが4.7〜8である乳化剤(a)の配合量は特に制限されないが、例えば、食用油脂100重量%に対して合計で0.1〜20重量%の乳化剤を配合することが好ましく、0.5〜15重量%がより好ましく、1.0〜12重量%がさらに好ましく、1.5〜10重量%としてもよい。 The amount of the emulsifier (a) having HLB of 4.7 to 8 is not particularly limited, but for example, it is preferable to add 0.1 to 20% by weight of the emulsifier to 100% by weight of edible oil and fat, It is more preferably 0.5 to 15% by weight, further preferably 1.0 to 12% by weight, and may be 1.5 to 10% by weight.

HLBが4.7〜8である乳化剤(a)としては、これに限定されるものではないが、例えば、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、有機酸脂肪酸エステルから選ばれる1以上を使用することができる。中でも、ポリグリセリン脂肪酸エステル、有機酸脂肪酸エステルから選ばれる1以上が好ましい。有機酸脂肪酸エステルの中でも、有機酸としてはクエン酸が好ましく、脂肪酸としてはオレイン酸が好ましく、特にクエン酸モノオレイン酸エステル(クエン酸モノオレイン酸グリセリン)が好ましい。またポリグリセリン脂肪酸エステルとしては、ジグリセリン脂肪酸エステルが好ましく、ジグリセリンモノ脂肪酸エステルがより好ましく、脂肪酸エステルの脂肪酸としてはオレイン酸が特に好ましい。 The emulsifier (a) having an HLB of 4.7 to 8 includes, but is not limited to, one or more selected from polyglycerin fatty acid ester, sorbitan fatty acid ester, and organic acid fatty acid ester. You can Among them, one or more selected from polyglycerin fatty acid ester and organic acid fatty acid ester is preferable. Among the organic acid fatty acid esters, citric acid is preferred as the organic acid, oleic acid is preferred as the fatty acid, and citric acid monooleate (citrate monooleate glycerin) is particularly preferred. The polyglycerin fatty acid ester is preferably a diglycerin fatty acid ester, more preferably a diglycerin monofatty acid ester, and the fatty acid ester fatty acid is particularly preferably oleic acid.

なお、ポリグリセリン脂肪酸エステルとは、ポリグリセリンと脂肪酸とのエステル化生成物であり、一般にエステル化反応などの方法で製造することができる。ポリグリセリンは、例えば、グリセリンまたはグリシドールあるいはエピクロルヒドリンなどを加熱し、重縮合反応させて得ることができる。本発明で用いられるポリグリセリンとしては平均重合度が約2〜10程度のものを使用してもよく、例えば、具体的にはジグリセリン(平均重合度2)、トリグリセリン(平均重合度3)、テトラグリセリン(平均重合度4)、ヘキサグリセリン(平均重合度6)、オクタグリセリン(平均重合度8)またはデカグリセリン(平均重合度10)などが挙げられ、好ましくはジグリセリン、トリグリセリンまたはテトラグリセリン、より好ましくはジグリセリンが挙げられる。上記脂肪酸としては、食用可能な動植物油脂を起源とする脂肪酸であれば特に制限はなく、例えば炭素数6〜24の直鎖の飽和または不飽和脂肪酸、好ましくは炭素数8〜18の直鎖の飽和または不飽和脂肪酸、より好ましくは炭素数18の直鎖の不飽和脂肪酸が挙げられる。例えば、具体的にはオレイン酸、リノール酸およびリノレン酸の群から選ばれる一種または二種以上の脂肪酸が挙げられる。 The polyglycerin fatty acid ester is an esterification product of polyglycerin and a fatty acid, and can generally be produced by a method such as an esterification reaction. Polyglycerin can be obtained, for example, by heating glycerin, glycidol, epichlorohydrin, or the like to cause polycondensation reaction. As the polyglycerin used in the present invention, those having an average degree of polymerization of about 2 to 10 may be used, and specifically, for example, diglycerin (average degree of polymerization 2) and triglycerin (average degree of polymerization 3). , Tetraglycerin (average degree of polymerization 4), hexaglycerin (average degree of polymerization 6), octaglycerin (average degree of polymerization 8), decaglycerin (average degree of polymerization 10) and the like, preferably diglycerin, triglycerin or tetra Glycerin, more preferably diglycerin is mentioned. The fatty acid is not particularly limited as long as it is a fatty acid originating from edible animal and vegetable oils and fats, for example, a straight chain saturated or unsaturated fatty acid having 6 to 24 carbon atoms, preferably a straight chain having 8 to 18 carbon atoms. Examples thereof include saturated or unsaturated fatty acids, and more preferably linear unsaturated fatty acids having 18 carbon atoms. Specific examples thereof include one or more fatty acids selected from the group consisting of oleic acid, linoleic acid and linolenic acid.

本発明の好ましい態様において、HLBが4.7〜8である乳化剤(a)とともにHLBが2.5以下の乳化剤(b)を使用する。併用する乳化剤(b)のHLBの下限は特にないが、HLBが0.1以上としてもよく、後述する実施例において示すようにHLBが0.5程度の乳化剤を用いても本発明の効果は十分に発揮される。HLBが4.7〜8である乳化剤(a)と併用する乳化剤(b)は、HLBが2.5以下であるが、ある態様においてHLBが1.9以下とすることもでき、別の態様においてはHLBを1.5以下とすることもできる。 In a preferred embodiment of the present invention, an emulsifier (b) having an HLB of 2.5 or less is used together with an emulsifier (a) having an HLB of 4.7 to 8. The lower limit of the HLB of the emulsifier (b) used in combination is not particularly limited, but the HLB may be 0.1 or more, and even if an emulsifier having an HLB of about 0.5 is used, the effect of the present invention will not be obtained. It is fully demonstrated. The emulsifier (b) used in combination with the emulsifier (a) having an HLB of 4.7 to 8 has an HLB of 2.5 or less, but in one embodiment, the HLB can be 1.9 or less. In the above, HLB can be 1.5 or less.

HLBが2.5以下の乳化剤(b)としては、これに限定されるものではないが、例えば、ポリグリセリン縮合リシノレイン酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる1以上が好ましく、ポリグリセリン縮合リシノレイン酸エステル、ショ糖脂肪酸エステルから選ばれる1以上が特に好ましい。 The emulsifier (b) having an HLB of 2.5 or less is not limited to this. For example, one or more selected from polyglycerin condensed ricinoleic acid ester, sorbitan fatty acid ester and sucrose fatty acid ester is preferable, and One or more selected from glycerin condensed ricinoleic acid ester and sucrose fatty acid ester is particularly preferable.

HLBが4.7〜8である乳化剤(a)とHLBが2.5以下である乳化剤(b)の両方を併用する場合、両者の併用比率は特に制限されないが、例えば、(a)と(b)の重量比を90:10〜10:90とすることができ、好ましくは85:15〜15:85であり、70:30〜30:70としてもよい。また、本発明においては、HLBが4.7〜8である乳化剤(a)とHLBが2.5以下である乳化剤(b)の合計量は、例えば、油脂100重量%に対して合計で0.3〜20重量%の乳化剤を配合することが好ましく、1〜15重量%がより好ましく、1.5〜12重量%がさらに好ましく、2〜10重量%としてもよい。 When both the emulsifier (a) having an HLB of 4.7 to 8 and the emulsifier (b) having an HLB of 2.5 or less are used in combination, the combined ratio of the two is not particularly limited, but, for example, (a) and ( The weight ratio of b) may be 90:10 to 10:90, preferably 85:15 to 15:85, and may be 70:30 to 30:70. Further, in the present invention, the total amount of the emulsifier (a) having an HLB of 4.7 to 8 and the emulsifier (b) having an HLB of 2.5 or less is, for example, 0 in total with respect to 100% by weight of the fat and oil. It is preferable to add 0.3 to 20% by weight of an emulsifier, more preferably 1 to 15% by weight, further preferably 1.5 to 12% by weight, and even 2 to 10% by weight.

本発明に係る油脂組成物は、一般的な方法によって適宜製造することができる。これに限定されるものではないが、例えば、HLBが4.7〜8である乳化剤(a)を食用油脂に添加し、又はHLBが4.7〜8である乳化剤(a)とHLBが2.5以下である乳化剤(b)を食用油脂に添加し、撹拌することによって、本発明に係る油脂組成物を製造することができる。また、好ましい態様において、食用油脂を加熱し、例えば、約20〜100℃、より好ましくは約40〜95℃、さらに好ましくは50〜90℃において、乳化剤と混合することによって、本発明に係る油脂組成物を容易に調製することができる。また、混合および攪拌は、加圧、減圧、常圧下で実施することが可能であり、ある態様では、常圧下で混合が行われる。 The oil/fat composition according to the present invention can be appropriately produced by a general method. Although not limited thereto, for example, an emulsifier (a) having an HLB of 4.7 to 8 is added to an edible oil or fat, or an emulsifier (a) having an HLB of 4.7 to 8 and an HLB of 2 are added. The oil/fat composition according to the present invention can be produced by adding the emulsifier (b) of 0.5 or less to edible oil/fat and stirring the mixture. Further, in a preferred embodiment, the edible oil or fat according to the present invention is heated by mixing with an emulsifier at, for example, about 20 to 100°C, more preferably about 40 to 95°C, further preferably 50 to 90°C. The composition can be easily prepared. Further, the mixing and stirring can be carried out under pressure, reduced pressure or normal pressure, and in one embodiment, the mixing is carried out under normal pressure.

本発明に係る油脂組成物を製造する装置は、特に限定されないが、例えば、攪拌機、加熱用のジャケットなどを備えた加温可能な攪拌槽、邪魔板等を備えた通常の攪拌・混合装置を用いることができる。回転数、攪拌時間などの撹拌条件は、原材料が均一に混合されれば、特に制限されない。攪拌機における攪拌翼の形状は特に制限されないが、例えば、プロペラ型、かい十字型、ファンタービン型、ディスクタービン型またはいかり型などとすることができる。 The apparatus for producing the oil/fat composition according to the present invention is not particularly limited, but for example, a stirring machine, a stirring tank that can be heated with a jacket for heating, a normal stirring/mixing apparatus with a baffle plate, etc. Can be used. The stirring conditions such as the rotation speed and stirring time are not particularly limited as long as the raw materials are uniformly mixed. The shape of the stirring blade in the stirrer is not particularly limited, but may be, for example, a propeller type, a cross shape, a fan turbine type, a disk turbine type, or an anchor type.

本発明の油脂組成物を用いて澱粉系食材を炒め調理する場合、本発明の油脂組成物を澱粉系食材に付着させることが必要である。一つの態様においては、本発明の油脂組成物をフライパンや中華鍋などの調理器具に入れてから澱粉系食材を投入して炒め調理することができ、また別の態様においては、本発明の油脂組成物を澱粉系食材に付着させてから調理器具で炒め調理することもできる。 When the starch-based food material is stir-fried with the oil-fat composition of the present invention, it is necessary to attach the oil-fat composition of the present invention to the starch-based food material. In one embodiment, the fat composition of the present invention can be put in a cooking utensil such as a frying pan or a wok and then the starch-based food material can be added to stir-fry, and in another aspect, the oil fat of the present invention can be used. It is also possible to attach the composition to the starch-based food material and then stir and cook with a cooking utensil.

本発明において油脂組成物の使用量は特に制限されないが、澱粉系食材の種類、炒め調理する際の食材の量などを勘案して適宜設定することができる。一つの態様において、澱粉系食材に対して、0.1〜5重量%、好ましくは0.5〜4重量%、より好ましくは1〜3重量%の量で使用してもよい。 In the present invention, the amount of the oil/fat composition used is not particularly limited, but can be appropriately set in consideration of the type of the starch-based food material, the amount of the food material when the fried food is cooked, and the like. In one embodiment, it may be used in an amount of 0.1 to 5% by weight, preferably 0.5 to 4% by weight, more preferably 1 to 3% by weight, based on the starch-based food material.

一つの態様において、本発明は澱粉系食材を炒め調理する際の調理性を向上させる方法であり、具体的には、澱粉系食材と調理器具の付着を抑制することができる。また別の態様において本発明は、澱粉系食材を炒め調理して得られる食品の付着性を小さくする方法であり、具体的には、例えば、米飯であれば炒め調理後の米飯のパラパラ感を向上させることができ、麺類であれば炒め調理後の麺線の接着を抑制し、麺線のつるみ感を向上させることができる。また、クレープやお好み焼きなどを製造する場合、本発明の油脂組成物を調理器具に塗布してから生地を焼いて調理することも可能である。 In one aspect, the present invention is a method for improving the cookability when a starch-based food material is fried and cooked, and specifically, it is possible to suppress the adhesion between the starch-based food material and the cooking utensil. In yet another aspect, the present invention is a method for reducing the adhesiveness of a food product obtained by frying a starch-based food material, and specifically, for example, in the case of cooked rice, it creates a fluffy feeling of cooked rice after frying and cooking. In the case of noodles, the noodle strings can be prevented from adhering to each other after being cooked and the squeezing feeling of the noodle strings can be improved. Further, when producing a crepe, an okonomiyaki, etc., it is possible to apply the oil and fat composition of the present invention to a cooking utensil and then bake the dough to cook it.

また本発明の油脂組成物は、炒め調理後の澱粉系食品を再加熱する際に、澱粉系食品に付着させることで、炒め調理時に使用した場合と同様の効果を発揮することができる。即ち、炒め調理後の澱粉系食品に本発明の油脂組成物を予め付着させておき、喫食時に電子レンジ等での再加熱に供すること、別の態様では、炒め調理後の澱粉系食品を電子レンジ等で再加熱する前に、本発明の油脂組成物を付着させること、により、例えば、米飯であれば炒め調理後の米飯のパラパラ感を向上させることができ、麺類であれば炒め調理後の麺線の接着を抑制し、麺線のつるみ感を向上させることができる。 In addition, the oil and fat composition of the present invention can exhibit the same effect as when used during stir cooking, by adhering it to the starch-based food when reheating the starch-based food after cooking. That is, the oil-and-fat composition of the present invention is attached in advance to the starch-based food after stir-fried cooking, and subjected to reheating in a microwave oven or the like at the time of eating. In another embodiment, the starch-based food after stir-fried cooking is electronically heated. Before reheating in a microwave oven or the like, by adhering the oil composition of the present invention, for example, if rice is cooked, it is possible to improve the fluffiness of cooked rice, and if noodles are cooked after cooking. It is possible to suppress the adhesion of the noodle strings and improve the squeezing feeling of the noodle strings.

さらに本発明の油脂組成物は、好ましい態様においてレシチン非含有である。レシチンは、加熱によって独特の色や風味を食材に付与してしまう場合があるところ、レシチン非含有の油脂組成物とすることによって、食材の色や風味を損なうことなく、澱粉系食材を炒め調理した食品を提供することができる。 Furthermore, the oil/fat composition of the present invention does not contain lecithin in a preferred embodiment. Lecithin may give a unique color or flavor to foods by heating, but by using an oil and fat composition that does not contain lecithin, the starch-based foods are fried without sacrificing the color or flavor of the foods. Food can be provided.

なお、本発明の油脂組成物は、澱粉系食材を炒め調理する場合に特に好適なものであるが、野菜や肉、魚などの澱粉系食材以外の食材を炒め調理する場合にも好適に使用できるものである。 The oil composition of the present invention is particularly suitable for stir-fry cooking of starch-based foodstuffs, but is also suitable for use when stir-frying foodstuffs other than starch-based foodstuffs such as vegetables, meat and fish. It is possible.

以下、本発明を実施例に基づいてさらに詳細に説明するが、本発明はこれらの実施例に限定されるものではない。なお、特に記載しない限り、本明細書において濃度などは重量基準であり、数値範囲はその端点を含むものとして記載される。 Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited to these examples. In addition, unless otherwise stated, the concentration and the like in the present specification are based on weight, and the numerical range is described as including the endpoints thereof.

乳化剤
以下の実験例においては、下記の乳化剤を使用した。なお、各乳化剤のHLBはカタログ記載の数値である。
・モノオレイン酸ジグリセリン(HLB:7.4、理研ビタミン、ポエムDO100V)
・クエン酸モノオレイン酸グリセリン(HLB:6.0、理研ビタミン、ポエムK-37V)
・シュガーエステル(オレイン酸エステル)(HLB:1、三菱化学フーズ、O-170)
・ヘキサグリセリン縮合リシノレート(HLB:0.5、理研ビタミン、ポエムPR300)
・テトラグリセリン縮合リシノレート(HLB:1.0、理研ビタミン、ポエムPR100)
試験1:炒め飯
食用菜種油(キャノーラ油、昭和産業)に対して各種乳化剤を添加し、加温可能な容器において撹拌しながら60℃に加温し、均一な油脂組成物を得た。使用した乳化剤の種類と量を以下の表に示す。表における各種乳化剤の量は、食用菜種油に対する重量%である。
Emulsifiers The following emulsifiers were used in the following experimental examples. The HLB of each emulsifier is a numerical value described in the catalog.
・Diglycerin monooleate (HLB:7.4, RIKEN vitamin, Poem DO100V)
・Glycerin monooleate citrate (HLB: 6.0, RIKEN vitamin, Poem K-37V)
・Sugar ester (oleate) (HLB: 1, Mitsubishi Chemical Foods, O-170)
・Hexaglycerin condensed ricinoleate (HLB: 0.5, RIKEN vitamin, Poem PR300)
・Tetraglycerin condensed ricinoleate (HLB: 1.0, RIKEN vitamin, Poem PR100)
Test 1: Stir-fried rice Various emulsifiers were added to edible rapeseed oil (Canola oil, Showa Sangyo Co., Ltd.) and heated to 60° C. with stirring in a heatable container to obtain a uniform oil and fat composition. The types and amounts of emulsifiers used are shown in the table below. The amounts of various emulsifiers in the table are% by weight with respect to edible rapeseed oil.

千葉県産コシヒカリに対して水を加え(加水145%)、炊飯器を用いて米飯を調製した。ステンレス製フライパンに油脂組成物10gを入れ、電磁調理器で加熱し、150℃になったところで、50〜60℃に保温した米飯500gを投入し、2分間炒め調理して炒め飯(具なし、味付けなしのチャーハン)を製造した。炒め調理時の米飯のほぐれ状態(ほぐれ性)を4段階で評価した。 Water was added to Koshihikari produced in Chiba prefecture (water 145%), and cooked rice was prepared using a rice cooker. Put 10 g of the oil and fat composition in a stainless steel frying pan, heat with an electromagnetic cooker, and when it reaches 150° C., add 500 g of cooked rice kept at 50-60° C., cook for 2 minutes, and cook with fried rice (no ingredients, Non-flavored fried rice) was produced. The unraveling state (unraveling property) of cooked rice during stir-fry cooking was evaluated in four levels.

また、炒めた米飯について、調理直後、および、真空冷却後1時間経過した段階で、パラパラ感と食感(口当たり)をそれぞれ4段階で評価した。評価基準は以下のとおりである。
[炒め調理時の米飯のほぐれ状態]
◎:炒め時のほぐれが良好で、固まりがなく、全体がパラパラしている。
○:炒め時に固まりなくほぐれる。
△:炒め時の固まりは無いが、ご飯同士の粘着性は高い。
×:炒め時にご飯がもったりし、ほぐれが悪い。
[炒め飯のパラパラ感]
◎:非常に良好である。
○:良好である。
△:やや劣る。
×:パラパラしていない。
[食感(口当たり)]
◎:米飯の表面が滑らかで口当たりが非常に良い。
○:米飯の表面が滑らかで口当たりが良い。
△:米飯の表面に滑らかさが無く、口当たりが劣る。
×:米飯の表面がパサパサしており、口当たりが悪い。
In addition, the stir-fried rice was evaluated immediately after cooking, and at the stage when 1 hour had passed after vacuum cooling, the texture and texture (mouth feel) were evaluated in 4 grades. The evaluation criteria are as follows.
[Release of cooked rice during stir-fry cooking]
⊚: Good unraveling when stir-fried, no lumps, and whole pieces.
◯: When stir-fried, it loosens without solidifying.
Δ: There is no lump at the time of frying, but the stickiness between the rice is high.
X: Rice is stiff when stir-frying, and unraveling is bad.
[Fried rice taste]
A: Very good.
◯: Good.
Δ: Slightly inferior
×: Not flipping.
[Food texture]
⊚: The surface of cooked rice is smooth and the texture is very good.
◯: The surface of cooked rice is smooth and has a pleasant texture.
Δ: The surface of cooked rice is not smooth and the mouthfeel is poor.
X: The surface of cooked rice is dry and has a bad mouthfeel.

Figure 0006745579
Figure 0006745579

Figure 0006745579
Figure 0006745579

上記の表から明らかなように、HLBが4.7〜8である乳化剤を食用油脂に配合した油脂組成物を炒め油として使用すると、炒め調理時の米飯のほぐれ性が良好であり、また、調理直後および冷却保存後の炒め飯のパラパラ感や食感も優れたものであった。 As is apparent from the above table, when an oil and fat composition obtained by mixing an edible oil and fat with an emulsifier having HLB of 4.7 to 8 is used as a stir-frying oil, the looseness of cooked rice during stir-fry cooking is good, and Immediately after cooking and after cold storage, the stir-fried rice also had an excellent texture and texture.

一方、HLBが低い乳化剤のみを食用油脂に配合した油脂組成物を用いた場合(試験1−6、試験1−7)、炒め調理時の米飯のほぐれ性、調理直後および冷却保存後の炒め飯のパラパラ感や食感のいずれも、良好な結果は得られなかった。 On the other hand, when using an oil/fat composition in which only an emulsifier having a low HLB is mixed with an edible oil/fat (Test 1-6, Test 1-7), the looseness of cooked rice during stir-fried cooking, the stir-fried rice immediately after cooking and after cold storage. Good results were not obtained with regard to the fluffy texture and the texture.

しかしながら、HLBが低い乳化剤であっても、HLBが4.7〜8である乳化剤と併用した場合(試験1−8〜試験1−13)、炒め調理時の米飯のほぐれ性、調理直後および冷却保存後の炒め飯のパラパラ感や食感のいずれも、良好な結果が得られた。HLBの異なる乳化剤を併用した場合に特に優れた効果が得られる理由の詳細は明らかでないが、HLBの大きく異なる乳化剤を併用することによって、澱粉系食材と調理器具という性状の異なる対象のいずれに対しても油脂組成物が迅速になじむことができるため優れた効果が奏されたものと推測される。 However, even if the emulsifier has a low HLB, when it is used in combination with an emulsifier having an HLB of 4.7 to 8 (Test 1-8 to Test 1-13), the looseness of cooked rice during stir cooking, immediately after cooking and cooling. Good results were obtained with regard to the texture and texture of the fried rice after storage. The details of the reason why a particularly excellent effect is obtained when the emulsifiers having different HLBs are used are not clear. However, by using the emulsifiers having greatly different HLBs, it is possible to obtain starch-based foods and cookware having different properties. However, it is presumed that the oil and fat composition had a good effect because the oil and fat composition could quickly adapt to it.

試験2:炒め飯(その2)
試験1と同様にして米飯を調製した。テフロン(登録商標)コーティングされたフライパンに炒め油としてサラダ油(乳化剤無添加)5gを入れ、電磁調理器で加熱し、150℃になったところで、50〜60℃に保温した米飯500gを投入し、1分間炒めたところで、下表の油脂組成物10gを鍋肌より添加し、さらに1分間炒めて炒め飯(具なし、味付けなし)を製造した。ここで、油脂組成物の調製、および、炒めた米飯の評価は、試験1と同様にして行った。
Test 2: Fried rice (Part 2)
Cooked rice was prepared in the same manner as in Test 1. 5 g of salad oil (without adding emulsifier) was added as a stir-fry oil to a Teflon (registered trademark)-coated frying pan, heated with an electromagnetic cooker, and when it reached 150°C, 500 g of cooked rice kept at 50-60°C was added, When fried for 1 minute, 10 g of the oil and fat composition shown in the table below was added from the skin of the pan, and fried for 1 minute to prepare fried rice (no ingredients, no seasoning). Here, the preparation of the oil and fat composition and the evaluation of the cooked cooked rice were performed in the same manner as in Test 1.

Figure 0006745579
Figure 0006745579

試験3:炒め飯(その3)
試験1と同様にして米飯を調製し、この米飯に油脂組成物を2重量%添加して20℃の環境下で2時間保管した。
Test 3: Fried rice (3)
Cooked rice was prepared in the same manner as in Test 1, and 2% by weight of the oil/fat composition was added to this cooked rice and stored under an environment of 20° C. for 2 hours.

テフロン(登録商標)コーティングされたフライパンに炒め油としてサラダ油(乳化剤無添加)5gを入れ、電磁調理器で加熱し、150℃になったところで、予め油脂組成物を添加しておいた冷飯500gを投入し、2分間炒めて炒め飯(具なし、味付けなし)を製造した。ここで、油脂組成物の調製、および、炒めた米飯の評価は、試験1と同様にして行った。 In a Teflon (registered trademark)-coated frying pan, 5 g of salad oil (without adding an emulsifier) was added as a stir-frying oil, heated with an electromagnetic cooker, and when it reached 150°C, 500 g of cold rice to which an oil and fat composition had been added in advance. It was put in and stir-fried for 2 minutes to produce stir-fried rice (without ingredients and without seasoning). Here, the preparation of the oil and fat composition and the evaluation of the cooked cooked rice were performed in the same manner as in Test 1.

Figure 0006745579
Figure 0006745579

試験4:炒め飯(その4、ケチャップライス)
試験1と同様にして米飯を調製した。ステンレス製フライパンに油脂組成物10gを入れ、電磁調理器で加熱して150℃になったところで、50〜60℃に保温した米飯500gを投入して1分間炒め、塩5g、ケチャップ25gを加え、さらに1分炒めた。ここで、油脂組成物の調製、および、炒めた米飯の評価は、試験1と同様にして行った。
Test 4: Stir-fried rice (4, ketchup rice)
Cooked rice was prepared in the same manner as in Test 1. Put 10 g of the oil and fat composition in a frying pan made of stainless steel, and when heated to 150° C. with an electromagnetic cooker, add 500 g of cooked rice kept at 50 to 60° C. and stir for 1 minute, add 5 g of salt and 25 g of ketchup, Stir for another minute. Here, the preparation of the oil and fat composition and the evaluation of the cooked cooked rice were performed in the same manner as in Test 1.

Figure 0006745579
Figure 0006745579

試験5:炒め飯(その5)
ステンレス製フライパンに炒め油としてサラダ油10gを入れ、電磁調理器で加熱して150℃になったところで、みじん切りにしたタマネギ(1玉分)を入れて軽く炒め、次いで、輪切りにしたウインナー(2本分)と細かく切ったキャベツ(1/8玉分)を入れて、全体に火が通るまで炒めた。塩・コショウを少々添加した後、50〜60℃に保温した米飯500gを投入し、次いで油脂組成物10gを米飯全体に振り掛けるように添加した。全体を均等に混ぜながら1分間炒めた後、ウスターソースを大さじ1杯添加し、さらに1分間炒めて炒め飯を製造した。なお、本試験において米飯および油脂組成物は試験1と同様にして調製したが、油脂組成物は、食用菜種油に対してモノオレイン酸ジグリセリン(HLB:7.4)2重量%、クエン酸モノオレイン酸グリセリン(HLB:6.0)3重量%、ヘキサグリセリン縮合リシノレート(HLB:0.5)3重量%を配合したものを使用した。
Test 5: Fried rice (5)
Put 10 g of salad oil as a stir-fry oil in a stainless steel frying pan, heat it with an electromagnetic cooker to 150° C., add chopped onion (1 piece) and fry it lightly, and then slice it into wieners (2 pieces) Min) and finely chopped cabbage (1/8 balls) were added and fried until the whole was cooked. After adding a small amount of salt and pepper, 500 g of cooked rice kept at 50-60° C. was added, and then 10 g of the oil and fat composition was added so as to sprinkle the whole cooked rice. After stir-frying for 1 minute while uniformly mixing the whole, 1 tablespoon of Worcester sauce was added, and further stir-fried for 1 minute to produce stir-fried rice. In this test, cooked rice and oil/fat composition were prepared in the same manner as in Test 1. However, the oil/fat composition was 2% by weight of diglycerin monooleate (HLB:7.4), monocitrate monohydrate with respect to edible rapeseed oil. A mixture containing 3% by weight of glyceryl oleate (HLB:6.0) and 3% by weight of hexaglycerin condensed ricinoleate (HLB:0.5) was used.

この炒め飯は、皿に盛り付ける際に、米飯のパラパラ感を感じるほど良好な状態に仕上がった。また、喫食したところ、非常に良好なパラパラ感があり、おいしく食すことができた。 This stir-fried rice was finished in a good condition so that when it was served on a plate, it felt as if it were rice. Also, when I ate it, I had a very good sense of flapping and I was able to eat deliciously.

試験6:炒め飯(その6)
試験1と同様にして米飯を調製した。テフロン(登録商標)コーティングされたフライパンに、炒め油としてサラダ油10gを入れ、電磁調理器で加熱して150℃になったところで、みじん切りにしたタマネギ(1玉分)を入れて軽く炒めた。次いで、50〜60℃に保温した米飯500gを投入して2分間炒め、塩・コショウで味を調え、火を止めて炒め飯を調理した。
Test 6: Fried rice (6)
Cooked rice was prepared in the same manner as in Test 1. In a frying pan coated with Teflon (registered trademark), 10 g of salad oil was added as a stir-frying oil, and when heated to 150° C. in an electromagnetic cooker, chopped onion (one ball) was added and lightly stir-fried. Next, 500 g of cooked rice kept at 50 to 60° C. was added and fried for 2 minutes, the taste was adjusted with salt and pepper, and the heat was turned off to cook the fried rice.

炒め飯をステンレスバットに移して粗熱を取ったのち、全体を2等分した。片方に油脂組成物(試験3−1と同じ)5gを添加して全体に軽く混ぜ合わせ、プラスチック製容器に盛り付けて蓋をして20℃の環境下で4時間保管した(試験6−1)。もう一方は、油脂組成物を添加せずにそのままプラスチック製容器に盛り付けて蓋をして20℃の環境下で4時間保管した(試験6−2)。 The stir-fried rice was transferred to a stainless steel vat to remove rough heat, and then the whole was divided into two equal parts. 5 g of the oil/fat composition (same as in Test 3-1) was added to one side, lightly mixed into the whole, put on a plastic container, covered with a lid, and stored in an environment of 20° C. for 4 hours (Test 6-1). .. The other was placed in a plastic container as it was without adding the oil and fat composition, covered with a lid, and stored in an environment of 20° C. for 4 hours (Test 6-2).

試験6−1の炒め飯は、電子レンジで再加熱を行ってから喫食した。一方、試験6−2の炒め飯は、油脂組成物(試験3−1と同じ)5gを全体に振り掛けるように添加してから電子レンジで再加熱して喫食した。 The fried rice of Test 6-1 was eaten after being reheated in a microwave oven. On the other hand, in the fried rice of Test 6-2, 5 g of the oil/fat composition (the same as in Test 3-1) was added so as to be sprinkled on the whole, and then reheated in a microwave oven to eat.

試験6−1、試験6−2の炒め飯は、いずれも、電子レンジで再加熱後、米飯のパラパラ感を感じる状態に仕上がっていた。また、喫食したところ、いずれも非常に良好なパラパラ感があり、おいしく食すことができた。 The stir-fried rices of Test 6-1 and Test 6-2 were all finished in a state in which the rice was felt to the touch after being reheated in a microwave oven. In addition, when eating, they all had a very good feeling of flapping and were able to eat deliciously.

試験7:焼きそば
下表に示す処方に基づいて、試験1と同様にして油脂組成物を調製した。表における各種乳化剤の量は、食用菜種油に対する重量%である。
Test 7: Yakisoba An oil and fat composition was prepared in the same manner as in Test 1 based on the formulation shown in the table below. The amounts of various emulsifiers in the table are% by weight with respect to edible rapeseed oil.

ステンレス製フライパンに油脂組成物3gを入れ、電磁調理器で加熱し、150℃になったところで、中華ゆで麺150g(冷蔵)を投入し、2分間炒めて焼きそば(具なし、味付けなし)を製造した。炒め調理時の麺線のほぐれ状態を4段階で評価した。 Put 3 g of oil composition in a stainless steel frying pan, heat with an electromagnetic cooker, and when it reaches 150°C, add 150 g of Chinese boiled noodles (refrigerated) and stir for 2 minutes to make yakisoba (no ingredients, no seasoning) did. The unraveled state of the noodle strings during fried cooking was evaluated on a 4-point scale.

また、炒めた麺類について、調理直後、および、真空冷却後1時間経過した段階で、食感(つるみ感)を4段階で官能評価した。評価基準は以下のとおりである。
[炒め調理時の麺線のほぐれ状態]
◎:麺の塊が早く良くほぐれる。
○:麺の塊が良くほぐれる。
△:麺の塊が一応ほぐれるが、麺線同士の付着はみられる。
×:麺の塊が菜箸にからみほぐれにくい。
[食感(つるみ感)]
◎:非常に良好である。
○:良好である。
△:やや劣る。
×:つるみ感なし。
In addition, the stir-fried noodles were subjected to a sensory evaluation on a 4-grade scale immediately after cooking and at the stage when 1 hour had passed after vacuum cooling. The evaluation criteria are as follows.
[Unraveled noodle strings during stir-fry cooking]
⊚: The lumps of noodles are quickly loosened well.
○: The noodle mass is loosened well.
Δ: The noodle masses are loosened for the time being, but the adhesion between the noodle strings is observed.
X: The mass of noodles is difficult to be entangled with the chopsticks.
[Food texture]
A: Very good.
◯: Good.
Δ: Slightly inferior
X: No slackness.

Figure 0006745579
Figure 0006745579

表から明らかなように、本発明によれば、炒め調理時に麺線をほぐれやすくすることができ、また、調理直後および冷却保存後のいずれにおいても食感(つるみ感)が良好であった。特に、HLBが4.7〜8の乳化剤とHLBが2.5以下の乳化剤を併用することによって、炒め調理時の麺線のほぐれやすさ、調理直後および冷却保存後の食感(つるみ感)がいずれも大きく向上した。 As is clear from the table, according to the present invention, the noodle strings can be easily unraveled during stir cooking, and the texture (smoothness) was good both immediately after cooking and after cold storage. In particular, by using an emulsifier having an HLB of 4.7 to 8 and an emulsifier having an HLB of 2.5 or less, the noodle strings are easily disentangled during stir cooking, and the texture (smoothness) immediately after cooking and after cold storage. However, both are greatly improved.

試験8:パスタ
ステンレス製フライパンに、炒め油としてオリーブ油3gを入れ、電磁調理器で加熱し、150℃になったところで、予め茹でて真空冷却しておいたロングパスタ200gを投入し、次いで、油脂組成物2gをロングパスタに振り掛けるように添加し、2分間炒めた。油脂組成物の調製は試験1、麺類の評価は試験7と同様にして行った。
Test 8: Put 3 g of olive oil as a stir-frying oil in a frying pan made of stainless steel pasta , heat with an electromagnetic cooker, and when the temperature reached 150° C., add 200 g of long pasta that had been boiled and vacuum-cooled in advance, and then oil and fat. 2 g of the composition was sprinkled on long pasta and fried for 2 minutes. The oil and fat composition was prepared in the same manner as in Test 1, and the noodles were evaluated in the same manner as in Test 7.

Figure 0006745579
Figure 0006745579

試験9:パスタ(その2)
ステンレス製のフライパンに炒め油としてサラダ油10gを入れ、電磁調理器で加熱して150℃になったところで、食べやすい大きさに裂いた舞茸(100g)、細切りにしたピーマン(1個分)とタマネギ(1/2玉分)を入れて炒め、塩・コショウで軽く味付けをした。次いで、予め茹でて真空冷却を掛けたロングパスタ200gを投入し、油脂組成物(試験7−8と同じ)2gをロングパスタに振り掛けるようにして添加し、約1分間軽く炒め合わせてパスタを調理した。
Test 9: Pasta (2)
Put 10 g of salad oil as a stir-fry oil in a stainless steel frying pan, heat it with an electromagnetic cooker to 150° C., and maitake mushrooms (100 g) that were torn to a size that was easy to eat, and chopped peppers (1 piece) Add the onion (1/2 ball), fry and season lightly with salt and pepper. Then, add 200 g of long pasta that has been boiled and vacuum-cooled in advance, add 2 g of the oil and fat composition (same as in Test 7-8) so as to sprinkle on the long pasta, and stir lightly for about 1 minute to make the pasta. Cooked

調理後の麺線の状態は非常に滑らかな状態であった。また、喫食したところ、パスタに非常に良好なつるみ感があり、おいしく食すことができた。 The noodle strings after cooking were in a very smooth state. Also, when I ate it, the pasta had a very good succulent feeling and I was able to eat it deliciously.

Claims (7)

HLBが4.7〜8の乳化剤(a)、HLBが2.5以下の乳化剤(b)および食用油脂を含有する、麺類の炒め調理用の油脂組成物であって、
乳化剤(a)および(b)の合計の配合量が、食用油脂に対して1.5〜20重量%である、麺線同士の付着を抑制するための油脂組成物。
An oil and fat composition for stir-frying noodles, comprising an emulsifier (a) having an HLB of 4.7 to 8, an emulsifier (b) having an HLB of 2.5 or less, and an edible oil and fat,
An oil and fat composition for suppressing adhesion between noodle strings, wherein the total amount of the emulsifiers (a) and (b) is 1.5 to 20% by weight based on the edible oil and fat.
(a)および(b)の合計の配合量が、食用油脂に対して4.5重量%以上である、請求項1に記載の油脂組成物。 The oil/fat composition according to claim 1, wherein the total amount of (a) and (b) compounded is 4.5% by weight or more based on the edible oil/fat. (a)と(b)の重量比が、90:10〜10:90である、請求項1または2に記載の油脂組成物。 The oil/fat composition according to claim 1 or 2, wherein the weight ratio of (a) and (b) is 90:10 to 10:90. 前記乳化剤(a)が、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、有機酸脂肪酸エステルから選ばれる1以上を含む、請求項1〜3のいずれかに記載の油脂組成物。 The oil and fat composition according to any one of claims 1 to 3, wherein the emulsifier (a) contains one or more selected from polyglycerin fatty acid ester, sorbitan fatty acid ester, and organic acid fatty acid ester. 前記乳化剤(a)が、クエン酸モノオレイン酸エステル、ジグリセリン脂肪酸エステルから選ばれる1以上を含む、請求項1〜4のいずれかに記載の油脂組成物。 The oil and fat composition according to any one of claims 1 to 4, wherein the emulsifier (a) contains one or more selected from citric acid monooleate and diglycerin fatty acid ester. 前記乳化剤(b)が、ポリグリセリン縮合リシノレイン酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる1以上を含む、請求項1〜5のいずれかに記載の油脂組成物。 The oil/fat composition according to any one of claims 1 to 5, wherein the emulsifier (b) contains one or more selected from polyglycerin condensed ricinoleic acid ester, sorbitan fatty acid ester, and sucrose fatty acid ester. 請求項1〜6のいずれかに記載の油脂組成物を添加して麺類を炒め調理して、麺線同士の付着を抑制することを含み、油脂組成物の使用量が麺類に対して0.1〜5重量%である、麺類の調理方法。 The method includes adding the oil and fat composition according to any one of claims 1 to 6 and frying and cooking the noodles to suppress the adhesion of the noodle strings to each other . A method for cooking noodles, which is 1 to 5% by weight.
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