JP6764979B2 - Oil composition for stir-fry cooking - Google Patents

Oil composition for stir-fry cooking Download PDF

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JP6764979B2
JP6764979B2 JP2019114493A JP2019114493A JP6764979B2 JP 6764979 B2 JP6764979 B2 JP 6764979B2 JP 2019114493 A JP2019114493 A JP 2019114493A JP 2019114493 A JP2019114493 A JP 2019114493A JP 6764979 B2 JP6764979 B2 JP 6764979B2
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弥生 金子
弥生 金子
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Showa Sangyo Co Ltd
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Description

本発明は、米飯や麺類などの澱粉系食材を炒め調理する際に用いる油脂組成物に関する。特に本発明は、澱粉系食材を炒め調理する際に用いられ、炒め調理をしやすくするとともに、炒め調理された食品の食感や美味しさを向上させることのできる油脂組成物に関する。 The present invention relates to an oil / fat composition used for stir-frying and cooking starch-based ingredients such as cooked rice and noodles. In particular, the present invention relates to an oil / fat composition which is used when stir-frying a starch-based food material and can facilitate stir-fry cooking and improve the texture and deliciousness of the stir-fried food.

一般に米飯や麺類などの澱粉系食材は、調理直後の結着性はそれほど強くないものの、時間の経過とともに、澱粉によって互いが結着したり、食材同士がべとつきやすくなる。これは、糊化された澱粉の粘着性によって、食材が互いに付着してしまうことが原因である。 In general, starch-based foodstuffs such as cooked rice and noodles do not have a strong binding property immediately after cooking, but over time, the starches tend to bind each other and the foodstuffs tend to become sticky. This is because the stickiness of the gelatinized starch causes the foodstuffs to adhere to each other.

従来、麺類などの澱粉系食材の付着を抑制し、ほぐれ性を改善するために、いくつかの技術が提案されている。例えば、食用油脂を用いて麺類の付着を抑制することが提案されているが、単に食用油脂を添加しただけでは、均一に食用油脂を付着させることが難しく、むらができてしまう場合がある。 Conventionally, some techniques have been proposed in order to suppress the adhesion of starch-based foodstuffs such as noodles and improve the looseness. For example, it has been proposed to use edible oils and fats to suppress the adhesion of noodles, but it is difficult to uniformly attach the edible oils and fats simply by adding the edible oils and fats, and unevenness may occur.

そこで、麺類への食用油脂の付着性を高めるために、食用油脂に乳化剤を添加した組成物を麺類のほぐれ性向上剤として使用することが提案されている。例えば、特許文献1〜3には、特定のポリグリセリン脂肪酸エステルを用いることが記載されており、特許文献4には、ジグリセリン脂肪酸エステルを用いることが記載されている。また、特許文献5には、ポリグリセリン脂肪酸エステルとポリオキシエチレンソルビタン脂肪酸エステルを併用することが記載されている。 Therefore, in order to enhance the adhesion of edible fats and oils to noodles, it has been proposed to use a composition in which an emulsifier is added to edible fats and oils as an agent for improving the looseness of noodles. For example, Patent Documents 1 to 3 describe that a specific polyglycerin fatty acid ester is used, and Patent Document 4 describes that a diglycerin fatty acid ester is used. Further, Patent Document 5 describes that a polyglycerin fatty acid ester and a polyoxyethylene sorbitan fatty acid ester are used in combination.

また、炒め調理などの調理時に用いる油脂組成物にレシチンを用いることも提案されている。例えば、特許文献6〜8には、食用油脂にレシチンを配合することによって調理用の油脂組成物を調製することが記載されている。 It has also been proposed to use lecithin in oil and fat compositions used during cooking such as stir-fry. For example, Patent Documents 6 to 8 describe that a cooking oil / fat composition is prepared by adding lecithin to an edible oil / fat.

さらに、炒め調理などの調理時に用いる油脂組成物に乳化剤を用いることも提案されている。例えば、特許文献9には、グリセリンのオレイン酸エステルを食用油脂に配合した炒め物用の油脂組成物が記載されている。 Further, it has been proposed to use an emulsifier in an oil / fat composition used during cooking such as stir-fry cooking. For example, Patent Document 9 describes an oil / fat composition for stir-fried foods in which an oleic acid ester of glycerin is blended with an edible oil / fat.

特開平07−039332号公報Japanese Patent Application Laid-Open No. 07-039332 特開平07−298847号公報Japanese Patent Application Laid-Open No. 07-298847 特開平11−221033号公報JP-A-11-22103 特開平09−037728号公報JP-A-09-037728 特開2006−006132号公報Japanese Unexamined Patent Publication No. 2006-006132 特開平8−89186号公報Japanese Patent Application Laid-Open No. 8-89186 特開2009−039021号公報Japanese Unexamined Patent Publication No. 2009-039021 特開2012−249621号公報Japanese Unexamined Patent Publication No. 2012-249621 特開2007−105035号公報JP-A-2007-105035

従来、澱粉系食材を炒め調理する際の技術課題として、フライパンや中華鍋などの調理
器具への付着防止が重視され、種々の提案がなされてきた。例えば、炒め調理の際に用いられる油脂(炒め油)については、上述したように、レシチンや乳化剤を配合することによって調理器具への剥離性を向上させることが提案されてきた(特許文献6〜9)。
Conventionally, as a technical issue when stir-frying starch-based ingredients, prevention of adhesion to cooking utensils such as frying pans and woks has been emphasized, and various proposals have been made. For example, as for fats and oils (stir-fry oil) used in stir-fry cooking, it has been proposed to improve the peelability to cooking utensils by blending lecithin and an emulsifier as described above (Patent Documents 6 to 6). 9).

また近年は、調理器具や調理設備、さらには調理手法の観点から、炒め調理する際の食材と調理器具との付着防止技術の改良が進んでおり、炒め油にあまり依存せずに食材と調理器具の付着防止を図ることも可能になっている。 In recent years, from the viewpoint of cooking utensils, cooking equipment, and cooking methods, improvements have been made in the technology for preventing the adhesion between ingredients and cooking utensils during stir-fry cooking, and cooking with ingredients without much dependence on stir-fry oil. It is also possible to prevent the attachment of equipment.

このような状況の中、炒め調理時に用いられる油脂(炒め油)に求められるニーズが変化してきており、従来重視されてきた調理器具への澱粉系食材の付着防止だけでなく、炒め調理した食材へ付加価値を与えられるような炒め調理用油脂が求められている。例えば、炒め調理時に用いることによって、調理器具への澱粉系食材の付着防止を図ることはもちろん、炒め飯であればパラパラ感、麺類であればつるみ感などを食材に付与するなど、炒め調理後の食品の美味しさをも向上させるような油脂組成物が求められている。 Under these circumstances, the needs for fats and oils (stir-fry oil) used during stir-fry cooking are changing, and not only the prevention of adhesion of starch-based ingredients to cooking utensils, which has been emphasized in the past, but also the stir-fry food ingredients. There is a demand for oils and fats for stir-fry that can add value to the food. For example, by using it during stir-fry cooking, it is possible to prevent the adhesion of starch-based foodstuffs to cooking utensils, and to give the foodstuffs a fluffy feeling for stir-fried rice and a smooth feeling for noodles. There is a demand for oil and fat compositions that also improve the deliciousness of foods.

上述したように、炒め調理用の油脂組成物としては、従来、レシチンを配合することが知られているが、レシチンを配合した油脂組成物を用いて炒め調理を行うと味や臭いに影響が生じてしまい、また、炒め調理時の熱によって着色(加熱着色)が生じてしまうという問題があった。すなわち、従来用いられてきたレシチンを配合した油脂組成物では、炒め調理時の調理器具と食材との剥離性を向上させることはできるものの、調理後の食品の価値を損なってしまうことがあった。 As described above, it is conventionally known that lecithin is blended as an oil / fat composition for stir-fry cooking, but when stir-fry cooking is performed using an oil / fat composition containing lecithin, the taste and odor are affected. In addition, there is a problem that coloring (heat coloring) occurs due to heat during stir-fry cooking. That is, the oil and fat composition containing lecithin, which has been conventionally used, can improve the peelability between the cooking utensil and the food material during stir-fry cooking, but may impair the value of the food after cooking. ..

このような状況に鑑み、本発明の課題は、特に澱粉系食材を炒め調理した後の食品の価値を高められる、炒め調理に利用するための油脂組成物を提供することである。 In view of such a situation, an object of the present invention is to provide an oil / fat composition for use in stir-fry cooking, which can enhance the value of the food after stir-fry and cook the starch-based food material.

本発明者らが上記課題について鋭意検討したところ、HLBが4.7〜8である乳化剤を食用油脂に配合した油脂組成物を用いることによって、澱粉系食材を美味しく炒め調理した食品が得られることを見出し、本発明を完成させるに至った。 As a result of diligent studies on the above-mentioned problems, the present inventors have found that by using an oil / fat composition in which an emulsifier having an HLB of 4.7 to 8 is mixed with an edible oil / fat, a food product obtained by frying and cooking a starch-based ingredient deliciously can be obtained. The present invention has been completed.

本発明は、これに限定されるものではないが、以下の態様を包含する。
(1) HLBが4.7〜8の乳化剤(a)と食用油脂を含有する、澱粉系食材の炒め調理用の油脂組成物。
(2) HLBが2.5以下の乳化剤(b)をさらに含有する、(1)に記載の油脂組成物。
(3) 澱粉系食材が、米飯または麺類である、(1)または(2)に記載の油脂組成物。
(4) 前記乳化剤(a)および(b)の合計の配合量が、食用油脂に対して0.3〜20重量%である、(2)に記載の油脂組成物。
(5) (a)と(b)の重量比が、90:10〜10:90である、(2)に記載の油脂組成物。
(6) 前記乳化剤(a)が、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、有機酸脂肪酸エステルから選ばれる1以上を含む、(1)〜(5)のいずれかに記載の油脂組成物。
(7) 前記乳化剤(a)が、クエン酸モノオレイン酸エステル、ジグリセリン脂肪酸エステルから選ばれる1以上を含む、(1)〜(6)のいずれかに記載の油脂組成物。
(8) 前記乳化剤(b)が、ポリグリセリン縮合リシノレイン酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる1以上を含む、(2)に記載の油脂組成物。
(9) 炒め調理時の炒め油として用いられる、(1)〜(8)のいずれかに記載の油脂
組成物。
(10) 炒め調理時に他の炒め油と併せて用いられる、(1)〜(8)のいずれかに記載の油脂組成物。
(11) 澱粉系食材に予め付着させてから炒め調理に用いられる、(1)〜(8)のいずれかに記載の油脂組成物。
(12) 澱粉系食材を炒め調理した食品を再加熱する際に、食品に付着させて用いられる、(1)〜(8)のいずれかに記載の油脂組成物。
(13) (1)〜(8)のいずれかに記載の油脂組成物を添加して澱粉系食材を炒め調理することを含む、澱粉系食材の調理方法。
(14) (13)の方法によって調理して得られる食品。
The present invention includes, but is not limited to, the following aspects.
(1) An oil / fat composition for stir-frying cooking of starch-based foodstuffs, which contains an emulsifier (a) having an HLB of 4.7 to 8 and an edible oil / fat.
(2) The oil / fat composition according to (1), which further contains an emulsifier (b) having an HLB of 2.5 or less.
(3) The oil / fat composition according to (1) or (2), wherein the starch-based foodstuff is cooked rice or noodles.
(4) The oil / fat composition according to (2), wherein the total amount of the emulsifiers (a) and (b) is 0.3 to 20% by weight based on the edible oil / fat.
(5) The oil / fat composition according to (2), wherein the weight ratio of (a) and (b) is 90:10 to 10:90.
(6) The fat or oil composition according to any one of (1) to (5), wherein the emulsifier (a) contains one or more selected from polyglycerin fatty acid ester, sorbitan fatty acid ester, and organic acid fatty acid ester.
(7) The oil / fat composition according to any one of (1) to (6), wherein the emulsifier (a) contains one or more selected from a citric acid monooleic acid ester and a diglycerin fatty acid ester.
(8) The oil / fat composition according to (2), wherein the emulsifier (b) contains one or more selected from polyglycerin condensed ricinoleic acid ester, sorbitan fatty acid ester, and sucrose fatty acid ester.
(9) The oil / fat composition according to any one of (1) to (8), which is used as a stir-fry oil during stir-fry cooking.
(10) The oil / fat composition according to any one of (1) to (8), which is used in combination with other stir-fry oils during stir-fry cooking.
(11) The oil / fat composition according to any one of (1) to (8), which is used for stir-fry cooking after being previously attached to a starch-based food material.
(12) The oil / fat composition according to any one of (1) to (8), which is used by adhering to food when reheating a food prepared by frying starch-based ingredients.
(13) A method for cooking a starch-based ingredient, which comprises adding the oil-and-fat composition according to any one of (1) to (8) and stir-frying the starch-based ingredient.
(14) Food obtained by cooking by the method of (13).

本発明によれば、炒め調理時の澱粉系食材と調理器具との付着性を抑制できるだけでなく、食材を美味しく炒め調理することができる。本発明の油脂組成物によれば、例えば、炒め飯(チャーハン)であれば米飯のパラパラ感が出るように炒め調理することが容易になり、焼きそばやパスタなどの麺類であれば、炒め調理後にも麺のつるみ感を出すことが容易になる。特に、本発明の油脂組成物を炒め調理時に用いると、油脂、調味料、熱などが効率的に澱粉系食材に行き渡ることから、澱粉系食材と調理器具の付着性を抑制できることはもちろん、炒め調理によって美味しい食品を得ることが容易になる。 According to the present invention, not only can the adhesion between the starch-based foodstuff and the cooking utensil during stir-fry cooking be suppressed, but also the foodstuff can be stir-fried and cooked deliciously. According to the oil and fat composition of the present invention, for example, stir-fried rice (charhan) can be easily stir-fried so as to give a crisp feeling of cooked rice, and noodles such as fried noodles and pasta can be cooked after stir-fry. It is easy to make the noodles feel smooth. In particular, when the oil / fat composition of the present invention is used during stir-fry cooking, the oil / fat, seasonings, heat, etc. are efficiently distributed to the starch-based foodstuff, so that the adhesion between the starch-based foodstuff and the cooking utensil can be suppressed, and the stir-fry is of course possible. Cooking makes it easier to obtain delicious food.

本発明は、HLBが4.7〜8である乳化剤(a)を食用油脂に配合した、澱粉系食材の炒め調理に利用するための油脂組成物に関する。 The present invention relates to an oil / fat composition for use in stir-fry cooking of starch-based foodstuffs, in which an emulsifier (a) having an HLB of 4.7 to 8 is blended with an edible oil / fat.

本発明の油脂組成物は、澱粉系食材を炒め調理するものに用いられる。例えば、澱粉系食材を炒め調理する際に、本発明の油脂組成物を炒め油として用いることができる。別の態様では、澱粉系食材を炒め調理する際に、本発明の油脂組成物を他の炒め油と併せて用いることができる。また別の態様では、本発明の油脂組成物を澱粉系食材に予め付着させておき、それを炒め調理に供することもできる。 The oil and fat composition of the present invention is used for stir-frying and cooking starch-based ingredients. For example, the oil and fat composition of the present invention can be used as a stir-fry oil when stir-frying and cooking starch-based foodstuffs. In another aspect, the oil and fat composition of the present invention can be used in combination with other stir-fry oils when the starch-based foodstuffs are stir-fried and cooked. In another aspect, the oil and fat composition of the present invention may be attached to a starch-based food material in advance, and the composition may be fried and cooked.

さらに本発明の油脂組成物は、澱粉系食材を炒め調理した食品を再加熱する際に用いられる。これにより、澱粉系食材を炒め調理した食品に、例えば米飯の場合はパラパラ感、麺類の場合は麺のつるみ感といった良好な品質を付与することができる。例えば、澱粉系食材を炒め調理した食品に本発明の油脂組成物を予め付着させておき、喫食時に電子レンジ等での再加熱に供することで、良好な品質を付与することができる。別の態様では、澱粉系食材を炒め調理した食品を電子レンジ等で再加熱する前に、本発明の油脂組成物を付着させることで、良好な品質を付与することができる。 Further, the oil and fat composition of the present invention is used when reheating a food prepared by frying a starch-based ingredient. As a result, it is possible to impart good quality such as a fluffy feeling in the case of cooked rice and a smooth feeling of noodles in the case of noodles to the food prepared by frying starch-based ingredients. For example, good quality can be imparted by adhering the oil and fat composition of the present invention to a food prepared by frying a starch-based food material in advance and subjecting it to reheating in a microwave oven or the like at the time of eating. In another aspect, good quality can be imparted by adhering the oil and fat composition of the present invention before reheating the food prepared by frying starch-based ingredients in a microwave oven or the like.

本発明において澱粉系食材とは、澱粉を主体とする食材のことであり、例えば、麺類、米飯、いも類などを挙げることができる。本発明において麺類とは、小麦粉、そば粉、米粉などの穀粉と水などを原料として含み、これらの原料を混捏し、製麺されたものや、緑豆や馬鈴薯等の澱粉を原料にして麺状に調製されたものをいう。具体的には、例えば、パスタ、うどん、きしめん、ひやむぎ、そうめん、そば、中華麺、米麺(ビーフン、フォー等)、春雨などを挙げることができる。また、本発明における麺類は、例えば、茹で麺あるいは蒸し麺の形態で使用されるものであってよく、茹で麺あるいは蒸し麺としては、チルド麺(低温流通麺)、冷凍流通麺あるいは常温流通麺(LL麺)などであってよい。 In the present invention, the starch-based foodstuff is a foodstuff mainly composed of starch, and examples thereof include noodles, cooked rice, and potatoes. In the present invention, noodles contain grain flour such as wheat flour, buckwheat flour, rice flour and the like as raw materials, and noodles made by kneading these raw materials, or noodles made from starch such as green beans and horse bells. It means the one prepared in. Specific examples include pasta, udon, kishimen, hiyamugi, somen, buckwheat noodles, Chinese noodles, rice noodles (rice noodles, pho, etc.), vermicelli, and the like. Further, the noodles in the present invention may be used in the form of boiled noodles or steamed noodles, and the boiled noodles or steamed noodles include chilled noodles (low temperature distribution noodles), frozen distribution noodles or normal temperature distribution noodles. (LL noodles) and the like.

本発明の油脂組成物に用いる油脂は、食用であれば特に限定されるものではなく、植物由来であるか、動物由来であるか、また、合成品であるかも問わない。例えば、大豆油、菜種油、キャノーラ油、コーン油、ひまわり油、紅花油、とうもろこし油、綿実油、ゴマ
油、シソ油、亜麻仁油、落花生油、オリーブ油、ブドウ種子油、マカデミアナッツ油、ヘーゼルナッツ油、カボチャ種子油、クルミ油、椿油、茶実油、エゴマ油、ボラージ油、米糠油、小麦胚芽油、パーム油、パーム核油、ヤシ油、カカオ脂、牛脂、豚脂、鶏脂、乳脂、魚油、アザラシ脂、藻類油などを単独または組み合わせて使用することができる。また、水素添加油脂、グリセリンと脂肪酸のエステル化油、エステル交換油、分別油脂なども適宜使用することができる。さらに、遺伝子組換えの技術を用いて品種改良した植物から抽出したものであってもよい。中でも常温で液状を呈する食用油脂とするのが使い勝手の点から好ましい。
The fats and oils used in the fats and oils composition of the present invention are not particularly limited as long as they are edible, and may be derived from plants, animals, or synthetic products. For example, soybean oil, rapeseed oil, canola oil, corn oil, sunflower oil, red flower oil, corn oil, cottonseed oil, sesame oil, perilla oil, flaxseed oil, peanut oil, olive oil, grape seed oil, macadamia nut oil, hazelnut oil, pumpkin seed oil. , Walnut oil, camellia oil, tea seed oil, sesame oil, borage oil, rice bran oil, wheat germ oil, palm oil, palm kernel oil, coconut oil, cacao fat, beef fat, pork fat, chicken fat, milk fat, fish oil, pearl oyster fat , Corn oil, etc. can be used alone or in combination. Further, hydrogenated fats and oils, esterified oils of glycerin and fatty acids, transesterified oils, fractionated fats and oils and the like can also be appropriately used. Further, it may be extracted from a plant whose variety has been improved by using a gene recombination technique. Of these, edible oils and fats that are liquid at room temperature are preferable from the viewpoint of usability.

本発明に係る油脂組成物には、HLBが4.7〜8である乳化剤(a)が配合される。本発明において乳化剤のHLBとは、Hydrophilic Lipophilic Balanceの略語であり、0(親油基のみの場合)〜20(親水基のみの場合)の数値を有する。Griffin法による場
合は、HLB=20×〔1−(エステルのケン化価/原料脂肪酸の中和価)〕によってHLBを算出することができる。乳化剤のHLBが8を超えると、乳化剤が油脂に溶解しにくくなり、白濁してしまう場合がある。一方、乳化剤のHLBが4.7未満であると、澱粉系食材を炒め調理した際に調理しにくく、また、調理後の澱粉系食材がべとつきやすくなる。HLBが4.7〜8である乳化剤(a)については、ある態様において、HLBが5.5以上であってもよく、別の好ましい態様においてHLBを6.0以上としてもよい。
The oil / fat composition according to the present invention contains an emulsifier (a) having an HLB of 4.7 to 8. In the present invention, the emulsifier HLB is an abbreviation for Hydrophilic Lipophilic Balance, and has a numerical value of 0 (in the case of only a lipophilic group) to 20 (in the case of only a hydrophilic group). In the case of the Griffin method, the HLB can be calculated by HLB = 20 × [1- (the saponification value of the ester / the neutralization value of the raw material fatty acid)]. If the HLB of the emulsifier exceeds 8, the emulsifier becomes difficult to dissolve in fats and oils and may become cloudy. On the other hand, if the HLB of the emulsifier is less than 4.7, it is difficult to cook the starch-based food when it is fried and cooked, and the starch-based food after cooking becomes sticky. For the emulsifier (a) having an HLB of 4.7 to 8, in one embodiment the HLB may be 5.5 or higher, and in another preferred embodiment the HLB may be 6.0 or higher.

HLBが4.7〜8である乳化剤(a)の配合量は特に制限されないが、例えば、食用油脂100重量%に対して合計で0.1〜20重量%の乳化剤を配合することが好ましく、0.5〜15重量%がより好ましく、1.0〜12重量%がさらに好ましく、1.5〜10重量%としてもよい。 The amount of the emulsifier (a) having an HLB of 4.7 to 8 is not particularly limited, but for example, it is preferable to add 0.1 to 20% by weight of the emulsifier in total with respect to 100% by weight of the edible fat. It is more preferably 0.5 to 15% by weight, further preferably 1.0 to 12% by weight, and may be 1.5 to 10% by weight.

HLBが4.7〜8である乳化剤(a)としては、これに限定されるものではないが、例えば、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、有機酸脂肪酸エステルから選ばれる1以上を使用することができる。中でも、ポリグリセリン脂肪酸エステル、有機酸脂肪酸エステルから選ばれる1以上が好ましい。有機酸脂肪酸エステルの中でも、有機酸としてはクエン酸が好ましく、脂肪酸としてはオレイン酸が好ましく、特にクエン酸モノオレイン酸エステル(クエン酸モノオレイン酸グリセリン)が好ましい。またポリグリセリン脂肪酸エステルとしては、ジグリセリン脂肪酸エステルが好ましく、ジグリセリンモノ脂肪酸エステルがより好ましく、脂肪酸エステルの脂肪酸としてはオレイン酸が特に好ましい。 The emulsifier (a) having an HLB of 4.7 to 8 is not limited to this, and for example, one or more selected from polyglycerin fatty acid ester, sorbitan fatty acid ester, and organic acid fatty acid ester may be used. Can be done. Among them, one or more selected from polyglycerin fatty acid ester and organic acid fatty acid ester is preferable. Among the organic acid fatty acid esters, citric acid is preferable as the organic acid, oleic acid is preferable as the fatty acid, and citric acid monooleic acid ester (glycerin citrate monooleate) is particularly preferable. Further, as the polyglycerin fatty acid ester, a diglycerin fatty acid ester is preferable, a diglycerin monofatty acid ester is more preferable, and oleic acid is particularly preferable as a fatty acid of the fatty acid ester.

なお、ポリグリセリン脂肪酸エステルとは、ポリグリセリンと脂肪酸とのエステル化生成物であり、一般にエステル化反応などの方法で製造することができる。ポリグリセリンは、例えば、グリセリンまたはグリシドールあるいはエピクロルヒドリンなどを加熱し、重縮合反応させて得ることができる。本発明で用いられるポリグリセリンとしては平均重合度が約2〜10程度のものを使用してもよく、例えば、具体的にはジグリセリン(平均重合度2)、トリグリセリン(平均重合度3)、テトラグリセリン(平均重合度4)、ヘキサグリセリン(平均重合度6)、オクタグリセリン(平均重合度8)またはデカグリセリン(平均重合度10)などが挙げられ、好ましくはジグリセリン、トリグリセリンまたはテトラグリセリン、より好ましくはジグリセリンが挙げられる。上記脂肪酸としては、食用可能な動植物油脂を起源とする脂肪酸であれば特に制限はなく、例えば炭素数6〜24の直鎖の飽和または不飽和脂肪酸、好ましくは炭素数8〜18の直鎖の飽和または不飽和脂肪酸、より好ましくは炭素数18の直鎖の不飽和脂肪酸が挙げられる。例えば、具体的にはオレイン酸、リノール酸およびリノレン酸の群から選ばれる一種または二種以上の脂肪酸が挙げられる。 The polyglycerin fatty acid ester is an esterification product of polyglycerin and a fatty acid, and can generally be produced by a method such as an esterification reaction. Polyglycerin can be obtained, for example, by heating glycerin, glycidol, epichlorohydrin, or the like and causing a polycondensation reaction. As the polyglycerin used in the present invention, one having an average degree of polymerization of about 2 to 10 may be used. Specifically, for example, diglycerin (average degree of polymerization 2) and triglycerin (average degree of polymerization 3). , Tetraglycerin (average degree of polymerization 4), hexaglycerin (average degree of polymerization 6), octaglycerin (average degree of polymerization 8) or decaglycerin (average degree of polymerization 10), and preferably diglycerin, triglycerin or tetra. Glycerin, more preferably diglycerin. The fatty acid is not particularly limited as long as it is a fatty acid derived from edible animal and vegetable fats and oils, and is, for example, a linear saturated or unsaturated fatty acid having 6 to 24 carbon atoms, preferably a linear fatty acid having 8 to 18 carbon atoms. Saturated or unsaturated fatty acids, more preferably linear unsaturated fatty acids with 18 carbon atoms. For example, specific examples thereof include one or more fatty acids selected from the group of oleic acid, linoleic acid and linolenic acid.

本発明の好ましい態様において、HLBが4.7〜8である乳化剤(a)とともにHLBが2.5以下の乳化剤(b)を使用する。併用する乳化剤(b)のHLBの下限は特にないが、HLBが0.1以上としてもよく、後述する実施例において示すようにHLBが0.5程度の乳化剤を用いても本発明の効果は十分に発揮される。HLBが4.7〜8である乳化剤(a)と併用する乳化剤(b)は、HLBが2.5以下であるが、ある態様においてHLBが1.9以下とすることもでき、別の態様においてはHLBを1.5以下とすることもできる。 In a preferred embodiment of the present invention, an emulsifier (b) having an HLB of 2.5 or less is used together with an emulsifier (a) having an HLB of 4.7 to 8. The lower limit of the HLB of the emulsifier (b) to be used in combination is not particularly limited, but the HLB may be 0.1 or more, and the effect of the present invention may be obtained even if an emulsifier having an HLB of about 0.5 is used as shown in Examples described later. It is fully demonstrated. The emulsifier (b) used in combination with the emulsifier (a) having an HLB of 4.7 to 8 has an HLB of 2.5 or less, but in one embodiment the HLB can be 1.9 or less, and in another embodiment. In, the HLB can be set to 1.5 or less.

HLBが2.5以下の乳化剤(b)としては、これに限定されるものではないが、例えば、ポリグリセリン縮合リシノレイン酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる1以上が好ましく、ポリグリセリン縮合リシノレイン酸エステル、ショ糖脂肪酸エステルから選ばれる1以上が特に好ましい。 The emulsifier (b) having an HLB of 2.5 or less is not limited to this, but for example, one or more selected from polyglycerin condensed ricinoleic acid ester, sorbitan fatty acid ester, and sucrose fatty acid ester is preferable, and poly. One or more selected from glycerin condensed ricinoleic acid ester and sucrose fatty acid ester is particularly preferable.

HLBが4.7〜8である乳化剤(a)とHLBが2.5以下である乳化剤(b)の両方を併用する場合、両者の併用比率は特に制限されないが、例えば、(a)と(b)の重量比を90:10〜10:90とすることができ、好ましくは85:15〜15:85であり、70:30〜30:70としてもよい。また、本発明においては、HLBが4.7〜8である乳化剤(a)とHLBが2.5以下である乳化剤(b)の合計量は、例えば、油脂100重量%に対して合計で0.3〜20重量%の乳化剤を配合することが好ましく、1〜15重量%がより好ましく、1.5〜12重量%がさらに好ましく、2〜10重量%としてもよい。 When both the emulsifier (a) having an HLB of 4.7 to 8 and the emulsifier (b) having an HLB of 2.5 or less are used in combination, the combined ratio of the two is not particularly limited, but for example, (a) and ( The weight ratio of b) can be 90:10 to 10:90, preferably 85: 15 to 15:85, and may be 70:30 to 30:70. Further, in the present invention, the total amount of the emulsifier (a) having an HLB of 4.7 to 8 and the emulsifier (b) having an HLB of 2.5 or less is, for example, 0 in total with respect to 100% by weight of fats and oils. It is preferable to add 3 to 20% by weight of the emulsifier, more preferably 1 to 15% by weight, further preferably 1.5 to 12% by weight, and may be 2 to 10% by weight.

本発明に係る油脂組成物は、一般的な方法によって適宜製造することができる。これに限定されるものではないが、例えば、HLBが4.7〜8である乳化剤(a)を食用油脂に添加し、又はHLBが4.7〜8である乳化剤(a)とHLBが2.5以下である乳化剤(b)を食用油脂に添加し、撹拌することによって、本発明に係る油脂組成物を製造することができる。また、好ましい態様において、食用油脂を加熱し、例えば、約20〜100℃、より好ましくは約40〜95℃、さらに好ましくは50〜90℃において、乳化剤と混合することによって、本発明に係る油脂組成物を容易に調製することができる。また、混合および攪拌は、加圧、減圧、常圧下で実施することが可能であり、ある態様では、常圧下で混合が行われる。 The oil and fat composition according to the present invention can be appropriately produced by a general method. For example, but not limited to this, an emulsifier (a) having an HLB of 4.7 to 8 is added to an edible oil or fat, or an emulsifier (a) having an HLB of 4.7 to 8 and an HLB of 2 are added. The oil / fat composition according to the present invention can be produced by adding the emulsifier (b) having a thickness of .5 or less to an edible oil / fat and stirring the mixture. Further, in a preferred embodiment, the fat or oil according to the present invention is obtained by heating the edible fat or oil and mixing it with an emulsifier at, for example, about 20 to 100 ° C., more preferably about 40 to 95 ° C., still more preferably 50 to 90 ° C. The composition can be easily prepared. Further, mixing and stirring can be performed under pressure, reduced pressure, and normal pressure, and in some embodiments, mixing is performed under normal pressure.

本発明に係る油脂組成物を製造する装置は、特に限定されないが、例えば、攪拌機、加熱用のジャケットなどを備えた加温可能な攪拌槽、邪魔板等を備えた通常の攪拌・混合装置を用いることができる。回転数、攪拌時間などの撹拌条件は、原材料が均一に混合されれば、特に制限されない。攪拌機における攪拌翼の形状は特に制限されないが、例えば、プロペラ型、かい十字型、ファンタービン型、ディスクタービン型またはいかり型などとすることができる。 The device for producing the oil / fat composition according to the present invention is not particularly limited, and for example, a normal stirring / mixing device provided with a stirrer, a heatable stirring tank equipped with a jacket for heating, a baffle plate, or the like. Can be used. Stirring conditions such as rotation speed and stirring time are not particularly limited as long as the raw materials are uniformly mixed. The shape of the stirring blade in the stirrer is not particularly limited, and may be, for example, a propeller type, a cross-shaped cross, a fan turbine type, a disc turbine type, or an anchor type.

本発明の油脂組成物を用いて澱粉系食材を炒め調理する場合、本発明の油脂組成物を澱粉系食材に付着させることが必要である。一つの態様においては、本発明の油脂組成物をフライパンや中華鍋などの調理器具に入れてから澱粉系食材を投入して炒め調理することができ、また別の態様においては、本発明の油脂組成物を澱粉系食材に付着させてから調理器具で炒め調理することもできる。 When a starch-based foodstuff is fried and cooked using the fat-and-fat composition of the present invention, it is necessary to attach the fat-and-fat composition of the present invention to the starch-based foodstuff. In one embodiment, the fat and oil composition of the present invention can be placed in a cooking utensil such as a frying pan or a wok, and then a starch-based ingredient can be added and fried and cooked. In another embodiment, the fat and oil of the present invention can be cooked. It is also possible to attach the composition to a starch-based ingredient and then stir-fry it in a cooking utensil.

本発明において油脂組成物の使用量は特に制限されないが、澱粉系食材の種類、炒め調理する際の食材の量などを勘案して適宜設定することができる。一つの態様において、澱粉系食材に対して、0.1〜5重量%、好ましくは0.5〜4重量%、より好ましくは1〜3重量%の量で使用してもよい。 In the present invention, the amount of the fat and oil composition used is not particularly limited, but it can be appropriately set in consideration of the type of starch-based foodstuff, the amount of foodstuff for stir-fry cooking, and the like. In one embodiment, it may be used in an amount of 0.1 to 5% by weight, preferably 0.5 to 4% by weight, more preferably 1 to 3% by weight, based on the starch-based foodstuff.

一つの態様において、本発明は澱粉系食材を炒め調理する際の調理性を向上させる方法であり、具体的には、澱粉系食材と調理器具の付着を抑制することができる。また別の態様において本発明は、澱粉系食材を炒め調理して得られる食品の付着性を小さくする方法であり、具体的には、例えば、米飯であれば炒め調理後の米飯のパラパラ感を向上させることができ、麺類であれば炒め調理後の麺線の接着を抑制し、麺線のつるみ感を向上させることができる。また、クレープやお好み焼きなどを製造する場合、本発明の油脂組成物を調理器具に塗布してから生地を焼いて調理することも可能である。 In one embodiment, the present invention is a method for improving the cookability when stir-frying a starch-based food material, and specifically, it is possible to suppress adhesion between the starch-based food material and a cooking utensil. In another aspect, the present invention is a method for reducing the adhesiveness of foods obtained by stir-frying and cooking noodle-based foods. Specifically, for example, in the case of rice, the feeling of stir-fried rice is felt. It can be improved, and in the case of noodles, the adhesion of the noodle strings after stir-fry cooking can be suppressed, and the smoothness of the noodle strings can be improved. Further, when producing crepes, okonomiyaki, etc., it is also possible to apply the oil and fat composition of the present invention to a cooking utensil and then bake the dough for cooking.

また本発明の油脂組成物は、炒め調理後の澱粉系食品を再加熱する際に、澱粉系食品に付着させることで、炒め調理時に使用した場合と同様の効果を発揮することができる。即ち、炒め調理後の澱粉系食品に本発明の油脂組成物を予め付着させておき、喫食時に電子レンジ等での再加熱に供すること、別の態様では、炒め調理後の澱粉系食品を電子レンジ等で再加熱する前に、本発明の油脂組成物を付着させること、により、例えば、米飯であれば炒め調理後の米飯のパラパラ感を向上させることができ、麺類であれば炒め調理後の麺線の接着を抑制し、麺線のつるみ感を向上させることができる。 Further, the fat and oil composition of the present invention can exhibit the same effect as when used during stir-fry cooking by adhering to the starch-based food when reheating the starch-based food after stir-fry cooking. That is, the oil and fat composition of the present invention is attached in advance to the noodle-based food after roasting and cooking, and the noodle-based food is subjected to reheating in a microwave oven or the like at the time of eating. By adhering the oil and fat composition of the present invention before reheating in a microwave oven or the like, for example, it is possible to improve the fluffy feeling of rice after fried cooking for rice, and after fried cooking for noodles. It is possible to suppress the adhesion of the noodle strings and improve the smoothness of the noodle strings.

さらに本発明の油脂組成物は、好ましい態様においてレシチン非含有である。レシチンは、加熱によって独特の色や風味を食材に付与してしまう場合があるところ、レシチン非含有の油脂組成物とすることによって、食材の色や風味を損なうことなく、澱粉系食材を炒め調理した食品を提供することができる。 Further, the fat and oil composition of the present invention is lecithin-free in a preferred embodiment. Lecithin may give a unique color and flavor to foodstuffs by heating, but by using a lecithin-free oil and fat composition, starch-based foodstuffs are roasted and cooked without impairing the color and flavor of the foodstuffs. Lecithin can be provided.

なお、本発明の油脂組成物は、澱粉系食材を炒め調理する場合に特に好適なものであるが、野菜や肉、魚などの澱粉系食材以外の食材を炒め調理する場合にも好適に使用できるものである。 The oil and fat composition of the present invention is particularly suitable for stir-frying and cooking starch-based ingredients, but is also preferably used for stir-frying and cooking ingredients other than starch-based ingredients such as vegetables, meat and fish. It can be done.

以下、本発明を実施例に基づいてさらに詳細に説明するが、本発明はこれらの実施例に限定されるものではない。なお、特に記載しない限り、本明細書において濃度などは重量基準であり、数値範囲はその端点を含むものとして記載される。 Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited to these examples. Unless otherwise specified, the concentration and the like are based on weight in the present specification, and the numerical range is described as including the end points thereof.

乳化剤
以下の実験例においては、下記の乳化剤を使用した。なお、各乳化剤のHLBはカタログ記載の数値である。
・モノオレイン酸ジグリセリン(HLB:7.4、理研ビタミン、ポエムDO100V)
・クエン酸モノオレイン酸グリセリン(HLB:6.0、理研ビタミン、ポエムK-37V)
・シュガーエステル(オレイン酸エステル)(HLB:1、三菱化学フーズ、O-170)
・ヘキサグリセリン縮合リシノレート(HLB:0.5、理研ビタミン、ポエムPR300)
・テトラグリセリン縮合リシノレート(HLB:1.0、理研ビタミン、ポエムPR100)
試験1:炒め飯
食用菜種油(キャノーラ油、昭和産業)に対して各種乳化剤を添加し、加温可能な容器において撹拌しながら60℃に加温し、均一な油脂組成物を得た。使用した乳化剤の種類と量を以下の表に示す。表における各種乳化剤の量は、食用菜種油に対する重量%である。
Emulsifier In the following experimental examples, the following emulsifier was used. The HLB of each emulsifier is a numerical value described in the catalog.
・ Diglycerin monooleate (HLB: 7.4, RIKEN Vitamin, Poem DO100V)
・ Glycerin monooleate citrate (HLB: 6.0, RIKEN Vitamin, Poem K-37V)
・ Sugar ester (oleic acid ester) (HLB: 1, Mitsubishi Chemical Foods, O-170)
・ Hexaglycerin condensed ricinolate (HLB: 0.5, RIKEN Vitamin, Poem PR300)
・ Tetraglycerin condensed ricinolate (HLB: 1.0, RIKEN Vitamin, Poem PR100)
Test 1: Various emulsifiers were added to fried rice edible rapeseed oil (canola oil, Showa Sangyo) and heated to 60 ° C. with stirring in a heatable container to obtain a uniform oil and fat composition. The types and amounts of emulsifiers used are shown in the table below. The amount of various emulsifiers in the table is% by weight based on edible rapeseed oil.

千葉県産コシヒカリに対して水を加え(加水145%)、炊飯器を用いて米飯を調製した。ステンレス製フライパンに油脂組成物10gを入れ、電磁調理器で加熱し、150℃になったところで、50〜60℃に保温した米飯500gを投入し、2分間炒め調理して炒め飯(具なし、味付けなしのチャーハン)を製造した。炒め調理時の米飯のほぐれ状態(ほぐれ性)を4段階で評価した。 Water was added to Koshihikari produced in Chiba prefecture (145% water added), and cooked rice was prepared using a rice cooker. Put 10 g of oil and fat composition in a stainless frying pan, heat it with an electromagnetic cooker, and when it reaches 150 ° C, add 500 g of cooked rice kept at 50-60 ° C and stir-fry for 2 minutes to stir-fry rice (without ingredients, Unseasoned fried rice) was manufactured. The unraveled state (unraveling property) of cooked rice during stir-fry cooking was evaluated on a 4-point scale.

また、炒めた米飯について、調理直後、および、真空冷却後1時間経過した段階で、パラパラ感と食感(口当たり)をそれぞれ4段階で評価した。評価基準は以下のとおりである。
[炒め調理時の米飯のほぐれ状態]
◎:炒め時のほぐれが良好で、固まりがなく、全体がパラパラしている。
○:炒め時に固まりなくほぐれる。
△:炒め時の固まりは無いが、ご飯同士の粘着性は高い。
×:炒め時にご飯がもったりし、ほぐれが悪い。
[炒め飯のパラパラ感]
◎:非常に良好である。
○:良好である。
△:やや劣る。
×:パラパラしていない。
[食感(口当たり)]
◎:米飯の表面が滑らかで口当たりが非常に良い。
○:米飯の表面が滑らかで口当たりが良い。
△:米飯の表面に滑らかさが無く、口当たりが劣る。
×:米飯の表面がパサパサしており、口当たりが悪い。
In addition, the stir-fried cooked rice was evaluated for its crunchy texture and texture (mouthfeel) on a 4-point scale immediately after cooking and 1 hour after vacuum cooling. The evaluation criteria are as follows.
[Unraveled state of cooked rice during stir-fry]
◎: Good loosening during stir-fry, no lumps, and the whole is fluffy.
◯: It loosens without solidification when stir-fried.
Δ: There is no lump when frying, but the rice is highly sticky to each other.
×: Rice is stuffy when stir-fried, and it does not loosen easily.
[Sautéed rice]
⊚: Very good.
◯: Good.
Δ: Slightly inferior.
×: Not fluttering.
[Texture (mouthfeel)]
◎: The surface of cooked rice is smooth and the taste is very good.
◯: The surface of cooked rice is smooth and has a pleasant taste.
Δ: The surface of cooked rice is not smooth and the mouthfeel is inferior.
×: The surface of cooked rice is dry and has a bad taste.

Figure 0006764979
Figure 0006764979

Figure 0006764979
Figure 0006764979

上記の表から明らかなように、HLBが4.7〜8である乳化剤を食用油脂に配合した油脂組成物を炒め油として使用すると、炒め調理時の米飯のほぐれ性が良好であり、また、調理直後および冷却保存後の炒め飯のパラパラ感や食感も優れたものであった。 As is clear from the above table, when an oil / fat composition in which an emulsifier having an HLB of 4.7 to 8 is mixed with an edible oil / fat is used as a stir-fry oil, the unraveling property of cooked rice during stir-fry cooking is good, and also. The texture and texture of the stir-fried rice immediately after cooking and after cooling storage were also excellent.

一方、HLBが低い乳化剤のみを食用油脂に配合した油脂組成物を用いた場合(試験1
−6、試験1−7)、炒め調理時の米飯のほぐれ性、調理直後および冷却保存後の炒め飯のパラパラ感や食感のいずれも、良好な結果は得られなかった。
On the other hand, when an oil / fat composition in which only an emulsifier having a low HLB is mixed with an edible oil / fat is used (Test 1).
-6, Test 1-7), the looseness of cooked rice during stir-fry cooking, and the crunchy texture and texture of stir-fried cooked rice immediately after cooking and after cooling storage did not give good results.

しかしながら、HLBが低い乳化剤であっても、HLBが4.7〜8である乳化剤と併用した場合(試験1−8〜試験1−13)、炒め調理時の米飯のほぐれ性、調理直後および冷却保存後の炒め飯のパラパラ感や食感のいずれも、良好な結果が得られた。HLBの異なる乳化剤を併用した場合に特に優れた効果が得られる理由の詳細は明らかでないが、HLBの大きく異なる乳化剤を併用することによって、澱粉系食材と調理器具という性状の異なる対象のいずれに対しても油脂組成物が迅速になじむことができるため優れた効果が奏されたものと推測される。 However, even if the emulsifier has a low HLB, when used in combination with an emulsifier having an HLB of 4.7 to 8 (Tests 1-8 to 1-13), the cooked rice is loosened during stir-fry, immediately after cooking, and cooled. Good results were obtained in both the texture and texture of the stir-fried rice after storage. Although the details of the reason why a particularly excellent effect can be obtained when emulsifiers with different HLBs are used in combination are not clear, the combined use of emulsifiers with significantly different HLBs can be used for both starch-based foodstuffs and cooking utensils with different properties. However, it is presumed that an excellent effect was achieved because the fat and oil composition can be quickly adapted.

試験2:炒め飯(その2)
試験1と同様にして米飯を調製した。テフロン(登録商標)コーティングされたフライパンに炒め油としてサラダ油(乳化剤無添加)5gを入れ、電磁調理器で加熱し、150℃になったところで、50〜60℃に保温した米飯500gを投入し、1分間炒めたところで、下表の油脂組成物10gを鍋肌より添加し、さらに1分間炒めて炒め飯(具なし、味付けなし)を製造した。ここで、油脂組成物の調製、および、炒めた米飯の評価は、試験1と同様にして行った。
Test 2: Stir-fried rice (2)
Cooked rice was prepared in the same manner as in Test 1. Put 5 g of salad oil (without adding emulsifier) as stir-fry oil in a frying pan coated with Teflon (registered trademark), heat it with an electromagnetic cooker, and when it reaches 150 ° C, add 500 g of cooked rice kept at 50-60 ° C. After stir-frying for 1 minute, 10 g of the oil and fat composition shown in the table below was added from the pan skin and stir-fried for another 1 minute to produce fried rice (without ingredients, without seasoning). Here, the preparation of the fat and oil composition and the evaluation of the fried cooked rice were carried out in the same manner as in Test 1.

Figure 0006764979
Figure 0006764979

試験3:炒め飯(その3)
試験1と同様にして米飯を調製し、この米飯に油脂組成物を2重量%添加して20℃の環境下で2時間保管した。
Test 3: Stir-fried rice (3)
Cooked rice was prepared in the same manner as in Test 1, 2% by weight of the oil and fat composition was added to the cooked rice, and the cooked rice was stored in an environment of 20 ° C. for 2 hours.

テフロン(登録商標)コーティングされたフライパンに炒め油としてサラダ油(乳化剤無添加)5gを入れ、電磁調理器で加熱し、150℃になったところで、予め油脂組成物を添加しておいた冷飯500gを投入し、2分間炒めて炒め飯(具なし、味付けなし)を製造した。ここで、油脂組成物の調製、および、炒めた米飯の評価は、試験1と同様にして行った。 Put 5 g of salad oil (without emulsifier added) as stir-fry oil in a frying pan coated with Teflon (registered trademark), heat it with an electromagnetic cooker, and when it reaches 150 ° C, add 500 g of cold rice to which the oil and fat composition has been added in advance. It was added and fried for 2 minutes to produce fried rice (without ingredients, without seasoning). Here, the preparation of the fat and oil composition and the evaluation of the fried cooked rice were carried out in the same manner as in Test 1.

Figure 0006764979
Figure 0006764979

試験4:炒め飯(その4、ケチャップライス)
試験1と同様にして米飯を調製した。ステンレス製フライパンに油脂組成物10gを入れ、電磁調理器で加熱して150℃になったところで、50〜60℃に保温した米飯500gを投入して1分間炒め、塩5g、ケチャップ25gを加え、さらに1分炒めた。ここで、油脂組成物の調製、および、炒めた米飯の評価は、試験1と同様にして行った。
Test 4: Stir-fried rice (4, ketchup price)
Cooked rice was prepared in the same manner as in Test 1. Put 10 g of the oil and fat composition in a stainless steel frying pan, heat it with an electromagnetic cooker to reach 150 ° C, add 500 g of cooked rice kept at 50-60 ° C, fry for 1 minute, add 5 g of salt and 25 g of ketchup. Fry for another 1 minute. Here, the preparation of the fat and oil composition and the evaluation of the fried cooked rice were carried out in the same manner as in Test 1.

Figure 0006764979
Figure 0006764979

試験5:炒め飯(その5)
ステンレス製フライパンに炒め油としてサラダ油10gを入れ、電磁調理器で加熱して150℃になったところで、みじん切りにしたタマネギ(1玉分)を入れて軽く炒め、次いで、輪切りにしたウインナー(2本分)と細かく切ったキャベツ(1/8玉分)を入れて、全体に火が通るまで炒めた。塩・コショウを少々添加した後、50〜60℃に保温した米飯500gを投入し、次いで油脂組成物10gを米飯全体に振り掛けるように添加した。全体を均等に混ぜながら1分間炒めた後、ウスターソースを大さじ1杯添加し、さらに1分間炒めて炒め飯を製造した。なお、本試験において米飯および油脂組成物は試験1と同様にして調製したが、油脂組成物は、食用菜種油に対してモノオレイン酸ジグリセリン(HLB:7.4)2重量%、クエン酸モノオレイン酸グリセリン(HLB:6.0)3重量%、ヘキサグリセリン縮合リシノレート(HLB:0.5)3重量%を配合したものを使用した。
Test 5: Stir-fried rice (No. 5)
Put 10g of salad oil as stir-fry oil in a stainless steel frying pan, heat it with an electromagnetic cooker and when it reaches 150 ℃, add chopped onion (1 ball) and fry lightly, then sliced wieners (2 pieces) (Min) and finely chopped cabbage (1/8 ball) were added and fried until the whole was cooked. After adding a little salt and pepper, 500 g of cooked rice kept at 50 to 60 ° C. was added, and then 10 g of the oil and fat composition was added so as to sprinkle the whole cooked rice. After stir-frying for 1 minute while mixing the whole evenly, 1 tablespoon of Worcestershire sauce was added and stir-fried for another 1 minute to produce fried rice. In this test, the rice and fat composition were prepared in the same manner as in Test 1, but the fat composition was diglycerin monooleate (HLB: 7.4) 2% by weight and monocitrate with respect to edible rapeseed oil. A mixture of 3% by weight of glycerin oleate (HLB: 6.0) and 3% by weight of hexaglycerin condensed ricinolate (HLB: 0.5) was used.

この炒め飯は、皿に盛り付ける際に、米飯のパラパラ感を感じるほど良好な状態に仕上がった。また、喫食したところ、非常に良好なパラパラ感があり、おいしく食すことができた。 This stir-fried rice was finished in a good condition so that you could feel the fluffy feeling of the cooked rice when serving it on a plate. Also, when I ate it, I had a very good feeling of para-para, and I was able to eat it deliciously.

試験6:炒め飯(その6)
試験1と同様にして米飯を調製した。テフロン(登録商標)コーティングされたフライパンに、炒め油としてサラダ油10gを入れ、電磁調理器で加熱して150℃になったところで、みじん切りにしたタマネギ(1玉分)を入れて軽く炒めた。次いで、50〜60℃に保温した米飯500gを投入して2分間炒め、塩・コショウで味を調え、火を止めて炒め飯を調理した。
Test 6: Stir-fried rice (6)
Cooked rice was prepared in the same manner as in Test 1. In a frying pan coated with Teflon (registered trademark), 10 g of salad oil was added as frying oil, and when the temperature reached 150 ° C., chopped onions (1 ball) were added and lightly fryed. Next, 500 g of cooked rice kept at 50 to 60 ° C. was added and fried for 2 minutes, the taste was adjusted with salt and pepper, the heat was turned off, and the fried rice was cooked.

炒め飯をステンレスバットに移して粗熱を取ったのち、全体を2等分した。片方に油脂組成物(試験3−1と同じ)5gを添加して全体に軽く混ぜ合わせ、プラスチック製容器に盛り付けて蓋をして20℃の環境下で4時間保管した(試験6−1)。もう一方は、油脂組成物を添加せずにそのままプラスチック製容器に盛り付けて蓋をして20℃の環境下で4時間保管した(試験6−2)。 The fried rice was transferred to a stainless steel vat to remove the rough heat, and then the whole was divided into two equal parts. Add 5 g of the fat and oil composition (same as Test 3-1) to one side, mix lightly, serve in a plastic container, cover and store in an environment of 20 ° C. for 4 hours (Test 6-1). .. The other was placed in a plastic container as it was without adding the fat and oil composition, covered, and stored in an environment of 20 ° C. for 4 hours (Test 6-2).

試験6−1の炒め飯は、電子レンジで再加熱を行ってから喫食した。一方、試験6−2の炒め飯は、油脂組成物(試験3−1と同じ)5gを全体に振り掛けるように添加してか
ら電子レンジで再加熱して喫食した。
The stir-fried rice of Test 6-1 was reheated in a microwave oven before being eaten. On the other hand, the stir-fried rice of Test 6-2 was eaten by adding 5 g of the fat and oil composition (same as Test 3-1) so as to sprinkle it on the whole and then reheating it in a microwave oven.

試験6−1、試験6−2の炒め飯は、いずれも、電子レンジで再加熱後、米飯のパラパラ感を感じる状態に仕上がっていた。また、喫食したところ、いずれも非常に良好なパラパラ感があり、おいしく食すことができた。 Both of the stir-fried rice in Test 6-1 and Test 6-2 were finished in a state in which the cooked rice felt a fluffy feeling after being reheated in a microwave oven. In addition, when I ate it, all of them had a very good feeling of para-para, and I was able to eat deliciously.

試験7:焼きそば
下表に示す処方に基づいて、試験1と同様にして油脂組成物を調製した。表における各種乳化剤の量は、食用菜種油に対する重量%である。
Test 7: Yakisoba An oil and fat composition was prepared in the same manner as in Test 1 based on the formulation shown in the table below. The amount of various emulsifiers in the table is% by weight based on edible rapeseed oil.

ステンレス製フライパンに油脂組成物3gを入れ、電磁調理器で加熱し、150℃になったところで、中華ゆで麺150g(冷蔵)を投入し、2分間炒めて焼きそば(具なし、味付けなし)を製造した。炒め調理時の麺線のほぐれ状態を4段階で評価した。 Put 3g of oil and fat composition in a stainless steel frying pan, heat it with an electromagnetic cooker, and when it reaches 150 ℃, add 150g of Chinese boiled noodles (refrigerated) and fry for 2 minutes to make fried noodles (without ingredients, without seasoning). did. The unraveled state of the noodle strings during stir-fry cooking was evaluated on a 4-point scale.

また、炒めた麺類について、調理直後、および、真空冷却後1時間経過した段階で、食感(つるみ感)を4段階で官能評価した。評価基準は以下のとおりである。
[炒め調理時の麺線のほぐれ状態]
◎:麺の塊が早く良くほぐれる。
○:麺の塊が良くほぐれる。
△:麺の塊が一応ほぐれるが、麺線同士の付着はみられる。
×:麺の塊が菜箸にからみほぐれにくい。
[食感(つるみ感)]
◎:非常に良好である。
○:良好である。
△:やや劣る。
×:つるみ感なし。
In addition, the texture (smoothness) of the fried noodles was sensory-evaluated on a 4-point scale immediately after cooking and 1 hour after vacuum cooling. The evaluation criteria are as follows.
[Unraveled state of noodle strings during stir-fry]
◎: The noodle mass loosens quickly and well.
◯: The noodle mass is well loosened.
Δ: The lumps of noodles are loosened for the time being, but the noodle strings are attached to each other.
×: Noodle lumps are not easily loosened by the chopsticks.
[Texture (smoothness)]
⊚: Very good.
◯: Good.
Δ: Slightly inferior.
×: No feeling of slack.

Figure 0006764979
Figure 0006764979

表から明らかなように、本発明によれば、炒め調理時に麺線をほぐれやすくすることができ、また、調理直後および冷却保存後のいずれにおいても食感(つるみ感)が良好であった。特に、HLBが4.7〜8の乳化剤とHLBが2.5以下の乳化剤を併用することによって、炒め調理時の麺線のほぐれやすさ、調理直後および冷却保存後の食感(つるみ感)がいずれも大きく向上した。 As is clear from the table, according to the present invention, the noodle strings can be easily loosened during stir-fry cooking, and the texture (smoothness) is good both immediately after cooking and after cooling storage. In particular, by using an emulsifier with an HLB of 4.7 to 8 and an emulsifier with an HLB of 2.5 or less in combination, the noodle strings are easily loosened during stir-fry cooking, and the texture immediately after cooking and after cooling storage (smoothness). However, both have improved significantly.

試験8:パスタ
ステンレス製フライパンに、炒め油としてオリーブ油3gを入れ、電磁調理器で加熱し、150℃になったところで、予め茹でて真空冷却しておいたロングパスタ200gを投入し、次いで、油脂組成物2gをロングパスタに振り掛けるように添加し、2分間炒めた。油脂組成物の調製は試験1、麺類の評価は試験7と同様にして行った。
Test 8: Pasta Put 3 g of olive oil as stir-fry oil in a stainless steel frying pan, heat it with an electromagnetic cooker, and when it reaches 150 ° C, add 200 g of pre-boiled and vacuum-cooled long pasta, and then add fat. 2 g of the composition was sprinkled on the long pasta and fried for 2 minutes. The oil and fat composition was prepared in the same manner as in Test 1, and the noodles were evaluated in the same manner as in Test 7.

Figure 0006764979
Figure 0006764979

試験9:パスタ(その2)
ステンレス製のフライパンに炒め油としてサラダ油10gを入れ、電磁調理器で加熱して150℃になったところで、食べやすい大きさに裂いた舞茸(100g)、細切りにしたピーマン(1個分)とタマネギ(1/2玉分)を入れて炒め、塩・コショウで軽く味付けをした。次いで、予め茹でて真空冷却を掛けたロングパスタ200gを投入し、油脂組成物(試験7−8と同じ)2gをロングパスタに振り掛けるようにして添加し、約1分間軽く炒め合わせてパスタを調理した。
Test 9: Pasta (Part 2)
Put 10g of salad oil as stir-fry oil in a stainless steel frying pan, heat it with an electromagnetic cooker and when it reaches 150 ℃, split it into pieces that are easy to eat (100g) and chopped peppers (1 piece). Add onion (1/2 ball), fry and lightly season with salt and pepper. Next, add 200 g of pre-boiled and vacuum-cooled long pasta, add 2 g of the fat and oil composition (same as in Test 7-8) by sprinkling on the long pasta, and stir-fry lightly for about 1 minute to make the pasta. Cooked.

調理後の麺線の状態は非常に滑らかな状態であった。また、喫食したところ、パスタに非常に良好なつるみ感があり、おいしく食すことができた。 The state of the noodle strings after cooking was very smooth. Also, when I ate it, the pasta had a very good smooth feeling, and I was able to eat it deliciously.

Claims (11)

HLBが4.7〜8の乳化剤(a)、HLBが2.5以下の乳化剤(b)および食用油脂を含有する、炊飯済の米飯を炒め調理するための油脂組成物であって、
乳化剤(a)および(b)の合計の配合量が、食用油脂に対して1.5〜20重量%である、調理後の米飯のパラパラ感を向上させるための油脂組成物(ただし、W/O型乳化組成物である場合を除く)
An oil / fat composition for stir-frying cooked cooked rice, which contains an emulsifier (a) having an HLB of 4.7 to 8, an emulsifier (b) having an HLB of 2.5 or less, and an edible oil / fat.
The total amount of the emulsifiers (a) and (b) is 1.5 to 20% by weight based on the edible oil / fat, and the oil / fat composition for improving the fluffy feeling of cooked rice after cooking (however, W / (Except when it is an O-type emulsifying composition) .
(a)および(b)の合計の配合量が、食用油脂に対して4.5重量%以上である、請求項1に記載の油脂組成物。 The fat or oil composition according to claim 1, wherein the total amount of the fats and oils (a) and (b) is 4.5% by weight or more based on the edible fats and oils. (a)と(b)の重量比が、90:10〜10:90である、請求項1または2に記載の油脂組成物。 The oil / fat composition according to claim 1 or 2, wherein the weight ratio of (a) and (b) is 90:10 to 10:90. (a)と(b)の重量比が、70:30〜30:70である、請求項1〜3のいずれかに記載の油脂組成物。The oil / fat composition according to any one of claims 1 to 3, wherein the weight ratio of (a) and (b) is 70:30 to 30:70. 前記乳化剤(a)が、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、有機酸脂肪酸エステルから選ばれる1以上を含む、請求項1〜のいずれかに記載の油脂組成物。 The oil and fat composition according to any one of claims 1 to 4 , wherein the emulsifier (a) contains one or more selected from polyglycerin fatty acid ester, sorbitan fatty acid ester, and organic acid fatty acid ester. 前記乳化剤(a)が、クエン酸モノオレイン酸エステル、ジグリセリン脂肪酸エステルから選ばれる1以上を含む、請求項1〜のいずれかに記載の油脂組成物。 The oil and fat composition according to any one of claims 1 to 5 , wherein the emulsifier (a) contains one or more selected from a citric acid monooleic acid ester and a diglycerin fatty acid ester. 前記乳化剤(b)が、ポリグリセリン縮合リシノレイン酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる1以上を含む、請求項1〜のいずれかに記載の油脂組成物。 The oil or fat composition according to any one of claims 1 to 6 , wherein the emulsifier (b) contains one or more selected from polyglycerin condensed ricinoleic acid ester, sorbitan fatty acid ester, and sucrose fatty acid ester. 米飯に対して0.1〜5重量%の量で使用される、請求項1〜のいずれかに記載の油脂組成物。 The oil / fat composition according to any one of claims 1 to 7 , which is used in an amount of 0.1 to 5% by weight based on cooked rice. 請求項1〜のいずれかに記載の油脂組成物を添加して炊飯済の米飯を炒め調理して、炒め調理後の米飯のパラパラ感を向上させることを含む、米飯の調理方法。 A method for cooking cooked rice, which comprises adding the oil / fat composition according to any one of claims 1 to 8 and stir-frying cooked cooked rice to improve the fluffy feeling of cooked rice after the stir-fry cooking. 請求項1〜のいずれかに記載の油脂組成物を、下記:
(1)前記油脂組成物を、炒め油として炒め調理を行う調理器具に付着させる;
(2)前記油脂組成物を、米飯に予め付着させてから炒め調理に供する;
(3)前記油脂組成物を、炒め調理中の米飯に直接的又は間接的に付着させる;
(4)前記油脂組成物を、米飯を炒め調理した食品を再加熱する際に食品に付着させる;
のいずれか1以上の態様で用いることを含む、炊飯済の米飯の調理方法。
The oil and fat composition according to any one of claims 1 to 8 is as follows:
(1) The fat and oil composition is attached to a cooking utensil to be stir-fried as stir-fry oil;
(2) The oil / fat composition is attached to cooked rice in advance and then subjected to stir-fry cooking;
(3) The fat and oil composition is directly or indirectly attached to cooked rice being fried and cooked;
(4) The fat and oil composition is attached to the food when the food cooked by frying cooked rice is reheated;
A method for cooking cooked rice, which comprises using it in any one or more aspects of the above.
前記油脂組成物が、米飯に対して0.1〜5重量%の量で使用される、請求項または10に記載の方法。 The method according to claim 9 or 10 , wherein the fat and oil composition is used in an amount of 0.1 to 5% by weight based on cooked rice.
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