JP6682181B2 - W / O / W type emulsion seasoning - Google Patents

W / O / W type emulsion seasoning Download PDF

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JP6682181B2
JP6682181B2 JP2014225663A JP2014225663A JP6682181B2 JP 6682181 B2 JP6682181 B2 JP 6682181B2 JP 2014225663 A JP2014225663 A JP 2014225663A JP 2014225663 A JP2014225663 A JP 2014225663A JP 6682181 B2 JP6682181 B2 JP 6682181B2
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竹内 秀和
秀和 竹内
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Description

本発明は、W/O/W型乳化調味料に関する。   The present invention relates to a W / O / W type emulsion seasoning.

マヨネーズ等の乳化調味料は、野菜、果物、肉、魚、卵、豆腐、ご飯、パン等の色々な食材と混合させて使用される。このうち、野菜と乳化調味料とを混合して調製されるサラダ類では、製造直後から様々な変化が生じるが、なかでも、野菜からの離水は、外観を損ない、野菜の食感が悪くなり、かつ、旨み成分の流出が生じる等の問題を生じさせる。   Emulsified seasonings such as mayonnaise are used by mixing with various food ingredients such as vegetables, fruits, meat, fish, eggs, tofu, rice and bread. Of these, in salads prepared by mixing vegetables and emulsified seasonings, various changes occur immediately after production, but above all, water separation from vegetables impairs the appearance and deteriorates the texture of vegetables. In addition, it causes problems such as outflow of the umami component.

かかる問題は、家庭又は飲食店で調製されるサラダ類及び市販のサラダ類のいずれでも生じるものであるが、中でも、市販のサラダ類は通常、製造後、流通工程を経て消費者に喫食されるまでに数時間〜数十時間を要する。したがって、市販のサラダ類では、野菜からの離水によって、外観が損なわれ、水分の流出により食感が悪くなったり、旨み成分の流出により風味が大きく低下したりする等の問題が生じる傾向がある。   Such a problem occurs in both salads prepared at home or in restaurants and commercially available salads. Among them, commercially available salads are usually eaten by consumers through a distribution process after production. It takes several hours to several tens of hours. Therefore, commercially available salads tend to cause problems such as appearance deterioration due to water separation from vegetables, deterioration of texture due to outflow of moisture, and significant deterioration in flavor due to outflow of umami components. .

野菜からの離水を抑制する方法として、例えば、特許文献1には、エステル化度が30%を超え、40%以下で、リシノール酸縮合度が5以上、8以下であるポリグリセリン脂肪酸エステルを含有し、製造後24時間経過時の粘度が27万mPa・s以上、40万mPa・s以下である複合乳化ドレッシング類が記載されている。また、特許文献2には、食用油脂、乳化剤、増粘材および食塩を含有するW/O/W型の乳化調味料であって、粘度が50〜500Pa・sであり、前記食用油脂の含有量が10〜70質量%であり、前記食塩の含有量が1〜6質量%であり、前記乳化調味料を構成するW/O/W型乳化粒子の平均粒子径が4〜20μmであり、かつ、特定の条件で測定した離水率が、30%以下であるW/O/W型乳化調味料が記載されている。   As a method for suppressing water separation from vegetables, for example, Patent Document 1 contains a polyglycerin fatty acid ester having an esterification degree of more than 30% and 40% or less and a ricinoleic acid condensation degree of 5 or more and 8 or less. However, composite emulsion dressings having a viscosity of 270,000 mPa · s or more and 400,000 mPa · s or less after 24 hours from the production are described. Further, Patent Document 2 discloses a W / O / W type emulsified seasoning containing an edible oil / fat, an emulsifier, a thickener, and a salt, having a viscosity of 50 to 500 Pa · s, and containing the edible oil / fat. The amount is 10 to 70 mass%, the content of the salt is 1 to 6 mass%, the average particle size of the W / O / W type emulsified particles constituting the emulsified seasoning is 4 to 20 μm, Moreover, the W / O / W type emulsified seasoning in which the water separation rate measured under specific conditions is 30% or less is described.

上記のように「W/O/W型」という特別な乳化形態をとることによって野菜からの離水を抑制する方法が知られているが、特殊な乳化形態であるためか、当該乳化調味料の外観がいわゆるマヨネーズとは異なる外観であり、マヨネーズらしいツヤ及びジューシーな外観ではなく、ラード様の肌荒れした外観になってしまうという問題があった。   As described above, a method of suppressing water separation from vegetables by taking a special emulsified form of "W / O / W type" is known, but because of the special emulsified form, the emulsified seasoning The appearance is different from that of so-called mayonnaise, and there is a problem in that it has a lard-like rough appearance rather than a glossy and juicy appearance like mayonnaise.

特開2012−044987号公報JP 2012-044987 A WO2013/061653号公報WO2013 / 061653

そこで、本発明は、マヨネーズらしいツヤ及びジューシーな外観を有し、且つ食材と混合したときに、食材からの離水を効果的に抑制することができるW/O/W型乳化調味料を提供する。   Therefore, the present invention provides a W / O / W type emulsified seasoning which has a glossy and juicy appearance like mayonnaise and can effectively suppress water separation from the food when mixed with the food. .

本願発明者は、上記課題を解決すべく鋭意研究を重ねた結果、意外にも、所定の要件を具備するW/O/W型の乳化調味料が、マヨネーズらしいツヤ及びジューシーな外観を有し、且つ食材と混合した時に食材からの離水を効果的に抑制できることを見出し、本発明を完成するに至った。   As a result of earnest studies to solve the above problems, the inventor of the present application has surprisingly found that a W / O / W type emulsified seasoning having predetermined requirements has a glossy and juicy appearance like mayonnaise. Moreover, they have found that the water separation from the food material can be effectively suppressed when mixed with the food material, and have completed the present invention.

すなわち、本発明は、
(1)内水相(W1)、ポリグリセリン縮合リシノレイン酸エステルを含有する油相(O)、外水相(W2)からなるW/O/W型乳化調味料であって、
食用油脂を前記乳化調味料全体に対して20%以上35%未満含有し、
外水相(W2)に、卵白、卵黄、糖質及びガム質類を含有し、前記卵白含有量が前記乳化調味料全体に対して生換算で1%以上10%以下であり、
外水相(W2)における固形分が、外水相(W2)に対して20%以上40%以下であり、
前記外水相(W2)における卵白と卵黄との含有比率が、生換算で1:1〜1:10であり、
前記乳化調味料の粘度が50Pa・s以上500Pa・s以下である、
W/O/W型乳化調味料、
(2)(1)に記載の乳化調味料と、野菜および果物もしくはいずれか一方とを含む、サラダ、
である。
That is, the present invention is
(1) A W / O / W type emulsified seasoning comprising an inner water phase (W1), an oil phase (O) containing a polyglycerin condensed ricinoleic acid ester, and an outer water phase (W2),
Contains 20% or more and less than 35% of edible oil / fat with respect to the entire emulsified seasoning,
The outer water phase (W2) contains egg white, egg yolk, carbohydrates and gums, and the egg white content is 1% or more and 10% or less in terms of raw conversion with respect to the whole emulsified seasoning,
The solid content in the external water phase (W2) is 20% or more and 40% or less with respect to the external water phase (W2),
The content ratio of egg white and egg yolk in the external water phase (W2) is 1: 1 to 1:10 in raw conversion,
The viscosity of the emulsified seasoning is 50 Pa · s or more and 500 Pa · s or less,
W / O / W type emulsified seasoning,
(2) A salad comprising the emulsified seasoning according to (1) and vegetables and / or fruits,
Is.

本発明によれば、マヨネーズらしいツヤ及びジューシーな外観を有し、且つ食材と混合した時に、食材から離水を効果的に抑制することができるW/O/W型乳化調味料を提供できる。これにより、お客さまの求める機能を保有しながらも従来のマヨネーズに近しい外観を有する乳化調味料を提供できる。   According to the present invention, it is possible to provide a W / O / W type emulsified seasoning which has a glossy and juicy appearance like mayonnaise and can effectively suppress water separation from the food when mixed with the food. As a result, it is possible to provide an emulsified seasoning that has the appearance similar to that of conventional mayonnaise while having the functions required by customers.

図1は本発明のW/O/W型乳化調味料の乳化状態の模式図である。FIG. 1 is a schematic diagram of an emulsified state of the W / O / W type emulsified seasoning of the present invention.

以下、本発明を詳細に説明する。なお、本発明において、格別に断らない限り、「%」は「質量%」を意味する。   Hereinafter, the present invention will be described in detail. In the present invention, "%" means "mass%" unless otherwise specified.

<本発明の特徴>
本発明のW/O/W型乳化調味料は、
内水相(W1)、ポリグリセリン縮合リシノレイン酸エステルを含有する油相(O)、外水相(W2)からなるW/O/W型乳化調味料であって、
食用油脂を前記乳化調味料全体に対して20%以上35%未満含有し、
外水相(W2)に、卵白、卵黄、糖質及びガム質類を含有し、前記卵白含有量が前記乳化調味料全体に対して生換算で1%以上10%以下であり、
外水相(W2)における固形分が、外水相(W2)に対して20%以上40%以下であり、
前記外水相(W2)における卵白と卵黄との含有比率が、生換算で1:1〜1:10であり、
前記乳化調味料の粘度が50Pa・s以上500Pa・s以下である、
W/O/W型乳化調味料、
である。
<Characteristics of the present invention>
The W / O / W type emulsified seasoning of the present invention is
A W / O / W type emulsified seasoning comprising an inner water phase (W1), an oil phase (O) containing a polyglycerin condensed ricinoleic acid ester, and an outer water phase (W2),
Contains 20% or more and less than 35% of edible oil / fat with respect to the entire emulsified seasoning,
The outer water phase (W2) contains egg white, egg yolk, carbohydrates and gums, and the egg white content is 1% or more and 10% or less in terms of raw conversion with respect to the whole emulsified seasoning,
The solid content in the external water phase (W2) is 20% or more and 40% or less with respect to the external water phase (W2),
The content ratio of egg white and egg yolk in the external water phase (W2) is 1: 1 to 1:10 in raw conversion,
The viscosity of the emulsified seasoning is 50 Pa · s or more and 500 Pa · s or less,
W / O / W type emulsified seasoning,
Is.

<W/O/W型乳化調味料>
本発明のW/O/W型乳化調味料は、内水相(W1)、ポリグリセリン縮合リシノレイン酸エステルを含有する油相(O)、外水相(W2)からなるW/O/W型乳化調味料であり、W/O/W型乳化調味料は主に、内水相と、この内水相を内包する油相と、この油相を内包する外水相とを含むものである。
<W / O / W type emulsified seasoning>
The W / O / W type emulsified seasoning of the present invention is a W / O / W type composed of an inner water phase (W1), an oil phase (O) containing a polyglycerin condensed ricinoleic acid ester, and an outer water phase (W2). The W / O / W type emulsion seasoning, which is an emulsified seasoning, mainly contains an inner water phase, an oil phase enclosing the inner water phase, and an outer water phase enclosing the oil phase.

<粘度>
本発明のW/O/W型乳化調味料の粘度は、マヨネーズらしい外観となるように一般的なマヨネーズと同様の粘度に調製する。具体的には、50Pa・s以上500Pa・s以下である。
ここで、本発明のW/O/W型乳化調味料の粘度は、品温25℃のものをBH型粘度計にて、ローターNo.6、回転数2rpmの条件で測定した1分後の示度により算出した値である。
<Viscosity>
The viscosity of the W / O / W type emulsified seasoning of the present invention is adjusted to be the same as that of a general mayonnaise so that the appearance looks like mayonnaise. Specifically, it is 50 Pa · s or more and 500 Pa · s or less.
Here, the viscosity of the W / O / W type emulsified seasoning of the present invention was measured at a product temperature of 25 ° C. with a BH type viscometer under the conditions of rotor No. 6 and rotation speed 2 rpm. It is a value calculated by reading.

<油相の成分>
油相(O)は、食用油脂及びポリグリセリン縮合リシノレイン酸エステルを含むことができる。
<Oil phase components>
The oil phase (O) may include edible oil and fat and polyglycerin condensed ricinoleic acid ester.

<食用油脂>
油脂(食用油脂)は、本発明のW/O/W型乳化調味料の油相(O)を主に構成する。本発明のW/O/W型乳化調味料では、食用油脂の含有量が20%以上35%未満である。
食用油脂の含有量が前記範囲であることによって、マヨネーズらしいツヤ及びジューシーな外観が得られる。
特に、食用油脂の含有量が20%未満の場合は、マヨネーズらしいツヤ及びジューシーな外観が得られない。
<Edible fats and oils>
The oil and fat (edible oil and fat) mainly constitutes the oil phase (O) of the W / O / W type emulsified seasoning of the present invention. In the W / O / W type emulsion seasoning of the present invention, the content of edible oil / fat is 20% or more and less than 35%.
When the content of the edible oil / fat is within the above range, a glossy and juicy appearance like mayonnaise can be obtained.
In particular, when the content of edible oil / fat is less than 20%, the glossy and juicy appearance of mayonnaise cannot be obtained.

食用油脂としては、例えば、食用植物油脂(例えば、菜種油、大豆油、紅花油、ひまわり油、コーン油、オリーブ油、グレープシード油、ごま油、綿実油、シソの実油、アマニ油)、魚油、肝油、さらにはエステル交換した油脂やジグリセライドを主に含む油脂が挙げられ、これらを単独でまたは2種以上を組み合わせて使用することができる。   Examples of edible oils and fats include edible vegetable oils and fats (for example, rapeseed oil, soybean oil, safflower oil, sunflower oil, corn oil, olive oil, grape seed oil, sesame oil, cottonseed oil, perilla seed oil, linseed oil), fish oil, liver oil, Further, examples thereof include transesterified oils and fats and oils and fats mainly containing diglyceride, and these can be used alone or in combination of two or more kinds.

<ポリグリセリン縮合リシノレイン酸エステル(PGPR)>
本発明のW/O/W型乳化調味料には、ポリグリセリン縮合リシノレイン酸エステル(以下「PGPR」とする。)を用いる。PGPRは、本発明のW/O/W型乳化調味料において乳化剤として機能し、食用油脂と共に油相(O)を形成する。PGPRとしては、食用として供されるものであれば、特に限定するものではない。本発明のW/O/W型乳化調味料において、PGPRは上述の卵黄及び後述の他の乳化剤と併用することができる。なお、PGPRは油相に添加することが好ましい。
<Polyglycerin condensed ricinoleic acid ester (PGPR)>
Polyglycerin condensed ricinoleic acid ester (hereinafter referred to as "PGPR") is used for the W / O / W type emulsion seasoning of the present invention. PGPR functions as an emulsifier in the W / O / W type emulsified seasoning of the present invention and forms an oil phase (O) together with edible fats and oils. The PGPR is not particularly limited as long as it can be used for food . In the W / O / W type emulsion seasoning of the present invention, PGPR can be used in combination with the above-mentioned egg yolk and other emulsifiers described later. It should be noted that PGPR is preferably added to the oil phase.

<PGPRの含有量>
本発明で用いるPGPRの含有量は、W/O/W型乳化調味料の乳化を安定化させる目的で、W/O/W型乳化調味料に対して0.1%以上5%以下がよく、0.5%以上3%以下がさらによい。
<Content of PGPR>
The content of PGPR used in the present invention is preferably 0.1% or more and 5% or less with respect to the W / O / W type emulsified seasoning for the purpose of stabilizing the emulsification of the W / O / W type emulsified seasoning. , 0.5% or more and 3% or less is more preferable.

さらに、本実施形態に係る乳化調味料では、上述のPGPRのほかに、他の乳化剤を使用してもよい。他の乳化剤としては、例えば、卵黄レシチン、乳タンパク、大豆タンパク、モノグリセリド、モノグリセリド誘導体、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、植物レシチンが挙げられ、これらを単独でまたは2種以上を組み合わせて使用することができる。   Furthermore, in the emulsified seasoning according to the present embodiment, other emulsifiers may be used in addition to the above-mentioned PGPR. Examples of other emulsifiers include egg yolk lecithin, milk protein, soybean protein, monoglyceride, monoglyceride derivative, sucrose fatty acid ester, sorbitan fatty acid ester, glycerin fatty acid ester, propylene glycol fatty acid ester, stearoyl lactate calcium, and plant lecithin. These can be used alone or in combination of two or more.

<外水相の成分>
外水相(W2)は、外水相中の固形分が20%以上40%以下であり、卵白をW/O/W型乳化調味料に対して生換算で1%以上10%以下含有し、卵黄、糖質及びガム質類を含有する。これにより、W/O/W型乳化調味料のマヨネーズらしいツヤ及びジューシーな外観を得ることができる。
<Outer water phase components>
The external water phase (W2) has a solid content in the external water phase of 20% or more and 40% or less, and contains egg white in an amount of 1% or more and 10% or less of the W / O / W type emulsified seasoning in raw conversion. , Egg yolk, sugar and gums. This makes it possible to obtain a glossy and juicy appearance of the W / O / W type emulsified seasoning, which is typical of mayonnaise.

<外水相中の固形分(%)>
本発明のW/O/W型乳化調味料の外水相の固形分は、外水相(W2)に対して20%以上40%以下であり、25%以上35%以下がよい。外水相中の固形分を前記範囲とすることで、W/O/W型乳化調味料をマヨネーズらしいツヤ及びジューシーな外観とすることができる。
なお、外水相中の固形分とは、水分を除いた残りの成分をいう。
<Solid content (%) in external water phase>
The solid content of the external water phase of the W / O / W type emulsion seasoning of the present invention is 20% or more and 40% or less, and preferably 25% or more and 35% or less, based on the external water phase (W2). By setting the solid content in the outer water phase within the above range, the W / O / W type emulsified seasoning can have a glossy and juicy appearance like mayonnaise.
The solid content in the external water phase refers to the remaining components excluding water.

<卵白とその含有量>
本発明のW/O/W型乳化調味料の外水相(W2)には、卵白をW/O/W型乳化調味料全体に対して生換算で1%以上10%以下含有する。前記範囲の卵白を含有し、下記に詳述する卵黄、糖質及びガム質類と合わせて含有することで、W/O/W型乳化調味料をマヨネーズらしいツヤ及びジューシーな外観とすることができる。
本発明のW/O/W型乳化調味料の外水相(W2)中の卵白の含有量が、前記範囲より少ないと、マヨネーズらしいツヤ及びジューシーな外観が得られず、前記範囲より多くても、マヨネーズらしいツヤ及びジューシーな外観が得られない。
<Egg white and its content>
The outer water phase (W2) of the W / O / W type emulsified seasoning of the present invention contains egg white in an amount of 1% or more and 10% or less based on the total amount of the W / O / W type emulsified seasoning. By containing the egg white in the above range and the egg yolk, the sugar and the gums which will be described in detail below, the W / O / W type emulsified seasoning can have a glossy and juicy appearance like mayonnaise. it can.
When the content of egg white in the outer aqueous phase (W2) of the W / O / W type emulsified seasoning of the present invention is less than the above range, glossy and juicy appearance typical of mayonnaise cannot be obtained, and more than the above range. However, the gloss and juicy appearance of mayonnaise cannot be obtained.

<卵黄>
本発明のW/O/W型乳化調味料の外水相(W2)には、卵黄を含有する。外水相に卵黄を含有させ、卵白、糖質及びガム質類と併せて用いることにより、W/O/W型乳化調味料をマヨネーズらしいツヤ及びジューシーな外観とすることができる。
卵黄としては、例えば、生卵黄をはじめ、当該生卵黄に殺菌処理、冷凍処理、スプレードライ又はフリーズドライ等の乾燥処理、ホスフォリパーゼA1、ホスフォリパーゼA2、ホスフォリパーゼC、ホスフォリパーゼD又はプロテアーゼ等による酵素処理、酵母又はグルコースオキシダーゼ等による脱糖処理、超臨界二酸化炭素処理等の脱コレステロール処理、食塩又は糖質等の混合処理等の1種または2種以上の処理を施したもの等が挙げられる。
<Yolk>
The outer aqueous phase (W2) of the W / O / W type emulsion seasoning of the present invention contains egg yolk. By adding egg yolk to the outer water phase and using it in combination with egg white, sugar and gums, the W / O / W type emulsified seasoning can have a mayonnaise-like luster and juicy appearance.
Examples of the egg yolk include raw egg yolk, sterilization treatment, freezing treatment, drying treatment such as spray drying or freeze drying of the raw egg yolk, phospholipase A1, phospholipase A2, phospholipase C, phospholipase D Or, one or more kinds of treatments such as enzyme treatment with protease, etc., desugarization treatment with yeast or glucose oxidase, decholesterolization treatment such as supercritical carbon dioxide treatment, mixed treatment with salt or sugar etc. Etc.

<卵黄の含有量>
本発明のW/O/W型乳化調味料の外水相(W2)に含有する卵黄は、W/O/W型乳化調味料全体に対して生換算で1%以上20%以下がよく、さらに5%以上15%以下がよい。卵黄の含有量が前記範囲であることにより、W/O/W型乳化調味料をマヨネーズらしいツヤ及びジューシーな外観とすることができる。
<Egg yolk content>
The egg yolk contained in the outer aqueous phase (W2) of the W / O / W type emulsified seasoning of the present invention is preferably 1% or more and 20% or less in terms of raw weight with respect to the whole W / O / W type emulsified seasoning, Further, 5% or more and 15% or less is preferable. When the content of egg yolk is within the above range, the W / O / W type emulsified seasoning can have a glossy and juicy appearance like mayonnaise.

<卵白と卵黄との含有比率>
本発明のW/O/W型乳化調味料の外水相には、上記の通り卵白1%以上10%以下と卵黄を含有するが、外水相における卵白と卵黄の含有比率は、生換算で1:1〜1:10の割合で含有し、1:1〜1:7の比率であるとよい。
卵白と卵黄との含有比率が前記範囲より卵白が多いと、マヨネーズらしいツヤ及びジューシーな外観が得られず、一方、前記範囲より卵黄が多いと、マヨネーズらしいツヤ及びジューシーな外観が得られない。
<Content ratio of egg white and egg yolk>
The outer water phase of the W / O / W type emulsified seasoning of the present invention contains 1% or more and 10% or less of egg white and egg yolk as described above. The content ratio of egg white and egg yolk in the outer water phase is the raw conversion. It is good to contain it in a ratio of 1: 1 to 1:10, and a ratio of 1: 1 to 1: 7.
When the content ratio of egg white and egg yolk is more than the above range, the gloss and juicy appearance like mayonnaise cannot be obtained, while when the yolk is more than the above range, the gloss and juicy appearance like mayonnaise cannot be obtained.

<糖質>
本発明のW/O/W型乳化調味料の外水相(W2)には、糖質を含有する。外水相(W2)に糖質を含有させ、卵白、卵黄、ガム質を併せて含有させることで、W/O/W型乳化調味料をマヨネーズらしいツヤ及びジューシーな外観とすることができる。
本発明のW/O/W型乳化調味料に用いる糖質とは、炭水化物から食物繊維を除いたものである。つまり、具体的な糖質の種類としては、ぶどう糖、果糖等の単糖類、砂糖、乳糖、麦芽糖等の二糖類、オリゴ糖、澱粉等の多糖類、還元澱粉糖化物、キシリトール、マルチトール等の糖アルコール類などであり、特に、砂糖等の二糖類と澱粉とを併用するのがよい。また、糖質には、後述のガム質は含まない。
<Carbohydrate>
The external water phase (W2) of the W / O / W type emulsion seasoning of the present invention contains a sugar. When the outer water phase (W2) contains a sugar, and also contains an egg white, an egg yolk and a gum, the W / O / W type emulsified seasoning can have a mayonnaise-like luster and a juicy appearance.
The sugar used in the W / O / W type emulsified seasoning of the present invention is a carbohydrate obtained by removing dietary fiber. That is, as specific sugar types, glucose, fructose and other monosaccharides, sugar, lactose, maltose and other disaccharides, oligosaccharides, starch and other polysaccharides, reduced starch saccharified products, xylitol, maltitol, etc. Such as sugar alcohols, it is particularly preferable to use a disaccharide such as sugar and starch together. Further, the sugar does not include the below-mentioned gum.

<澱粉>
本発明のW/O/W型乳化調味料で用いる糖質のうち、澱粉としては、例えば、馬鈴薯澱粉、コーンスターチ、タピオカ澱粉、小麦澱粉、米澱粉、これらの澱粉をアルファ化、架橋等の処理を施した加工澱粉、又はこれらの澱粉に湿熱処理を施した湿熱処理澱粉が挙げられる。
湿熱処理澱粉としては、「湿熱処理澱粉」として市販されているものであれば特に限定するものではないが、例えば、澱粉を加熱しても糊化しない程度の水分を含む澱粉粒子を、密閉容器中で相対湿度100%の条件下で約100〜125℃に加熱して得る方法、あるいは第1段階で澱粉を容器中に入れ密閉・減圧し、第2段階で生蒸気を容器内に導入し、加湿加熱するシステムである減圧加圧加熱法等で製造されたものを用いるとよい。
また、加工澱粉としては、食品衛生法で含有物に指定された化学的処理を施された澱粉であって食用として供されるものであれば特に限定するものではない。例えば、アセチル化アジピン酸架橋澱粉、アセチル化リン酸架橋澱粉、アセチル化酸化澱粉、オクテニルコハク酸澱粉ナトリウム、酢酸澱粉、酸化澱粉、ヒドロキシプロピル化リン酸架橋澱粉、ヒドロキシプロピル澱粉、リン酸化澱粉、リン酸架橋澱粉、リン酸モノエステル化リン酸架橋澱粉等が挙げられ、これらの1種又は2種以上を用いるとよい。
なかでも、マヨネーズらしいツヤ及びジューシーな外観を得る観点で、アセチル化アジピン酸架橋デンプン、ヒドロキシプロピル化リン酸架橋デンプンを使用することが好ましい。
<Starch>
Among the sugars used in the W / O / W type emulsified seasoning of the present invention, starch includes, for example, potato starch, cornstarch, tapioca starch, wheat starch, rice starch, and treatments such as pregelatinization and cross-linking of these starches. Examples of the processed starch that has been subjected to heat treatment, or a heat-moisture-treated starch obtained by subjecting these starches to heat-moisture treatment.
The heat-moisture treated starch is not particularly limited as long as it is commercially available as "heat-moisture treated starch". For example, starch particles containing water in an amount that does not gelatinize even when the starch is heated are sealed in a closed container. In which the temperature is about 100 to 125 ° C. under the condition of relative humidity of 100%, or in the first step, the starch is placed in a container, sealed and decompressed, and in the second step, live steam is introduced into the container. It is preferable to use the one manufactured by the depressurization / pressure heating method, which is a system for heating by humidification.
In addition, the processed starch is not particularly limited as long as it is a starch that has been subjected to a chemical treatment specified by the food hygiene law as a chemical and is to be used for food. For example, acetylated adipic acid crosslinked starch, acetylated phosphoric acid crosslinked starch, acetylated oxidized starch, sodium octenyl succinate starch, acetic acid starch, oxidized starch, hydroxypropylated phosphoric acid crosslinked starch, hydroxypropyl starch, phosphorylated starch, phosphoric acid Examples thereof include crosslinked starch and phosphoric acid monoesterified phosphoric acid crosslinked starch, and it is preferable to use one or more of these.
Among them, acetylated adipic acid crosslinked starch and hydroxypropylated phosphoric acid crosslinked starch are preferably used from the viewpoint of obtaining a mayonnaise-like luster and a juicy appearance.

<糖質の含有量>
本発明のW/O/W型乳化調味料の外水相(W2)に含有する糖質は、外水相(W2)の固形分が20%以上40%以下となるように適宜調整して配合すればよい。
例えば、外水相(W2)に対して5%以上20%以下がよく、さらに5%以上15%以下がよい。糖質の含有量が前記範囲であることにより、W/O/W型乳化調味料をマヨネーズらしいツヤ及びジューシーな外観とすることができる。
<Sugar content>
The sugar contained in the outer water phase (W2) of the W / O / W type emulsified seasoning of the present invention is appropriately adjusted so that the solid content of the outer water phase (W2) is 20% or more and 40% or less. It may be blended.
For example, it is preferably 5% or more and 20% or less, and more preferably 5% or more and 15% or less with respect to the external water phase (W2). When the sugar content is in the above range, the W / O / W type emulsified seasoning can have a glossy and juicy appearance like mayonnaise.

<ガム質>
本発明の乳化調味料の外水相には、ガム質を含有する。外水相にガム質を含有させ、上記卵白、卵黄、糖質と併せて用いることにより、W/O/W型乳化調味料をマヨネーズらしいツヤ及びジューシーな外観とすることができる。
使用するガム質としては、例えば、キサンタンガム、ジェランガム、ローカストビーンガム、タラガム、グアガム、アラビアガム、タマリンドガム、サイリュームシードガム等が挙げられる。
<Gum quality>
The external water phase of the emulsified seasoning of the present invention contains a gum substance. By adding a gum substance to the external water phase and using it in combination with the above-mentioned egg white, egg yolk and sugar, the W / O / W type emulsified seasoning can have a glossy and juicy appearance like mayonnaise.
Examples of gums used include xanthan gum, gellan gum, locust bean gum, tara gum, guar gum, gum arabic, tamarind gum, silium seed gum and the like.

<ガム質の含有量>
本発明の乳化調味料中のガム質の含有量は、マヨネーズらしいツヤ及びジューシーな外観とする観点から0.05%以上3%以下がよく、さらに0.3%以上3%以下がよい。
<Gum content>
The content of gum in the emulsified seasoning of the present invention is preferably 0.05% or more and 3% or less, and more preferably 0.3% or more and 3% or less, from the viewpoint of giving a mayonnaise-like luster and a juicy appearance.

<他の成分>
本発明のW/O/W型乳化調味料は水相成分として、一般的にマヨネーズに配合される原料であれば特に限定されることなく、用いることができる。例えば、水、食酢(醸造酢)、食塩、アミノ酸等の調味料、はちみつ、香辛料抽出物、たん白加水分解物、着色料および着香料を含むことができ、これらを単独でまたは2種以上を組み合わせて使用することができる。
<Other components>
The W / O / W type emulsified seasoning of the present invention can be used as the water phase component without any particular limitation, as long as it is a raw material generally mixed with mayonnaise. For example, water, vinegar (brewed vinegar), salt, seasonings such as amino acids, honey, spice extract, protein hydrolyzate, coloring and flavoring agents may be included, either alone or in combination of two or more. It can be used in combination.

<内水相の成分>
内水相(W1)は、食塩濃度及び糖質濃度を外水相(W2)と同程度に調整すれば、特に限定されないが、例えば、卵白、卵黄、糖質、ガム質、水、食酢(醸造酢)、食塩、アミノ酸等の調味料、はちみつ、香辛料抽出物、たん白加水分解物、着色料及び着香料等を含んでいてもよい。
<Internal water phase components>
The inner water phase (W1) is not particularly limited as long as the salt concentration and the sugar concentration are adjusted to the same level as the outer water phase (W2), but for example, egg white, egg yolk, sugar, gum, water, vinegar ( (Brewed vinegar), salt, seasonings such as amino acids, honey, spice extract, protein hydrolyzate, colorant, flavoring agent and the like may be contained.

<製造方法>
本発明のW/O/W型乳化調味料は以下の工程により得ることができる。
なお、乳化は、ホモミキサーやコロイドミル等の一般的な乳化装置を用いて行うことができる。また、外水相形成用混合液には、上述した卵白、卵黄、糖質及びガム質を含有する。具体的には、次の(i)(ii)の工程により製造することができる。
(i)内水相形成用混合液が、食用油脂及びPGPRを含有する油相(O)に分散したW/O型乳化物を形成する工程、
(ii)外水相形成用混合液に、得られたW/O型乳化物を混合する工程
<Manufacturing method>
The W / O / W type emulsion seasoning of the present invention can be obtained by the following steps.
The emulsification can be performed using a general emulsifying device such as a homomixer or a colloid mill. The mixed liquid for forming the outer aqueous phase contains the above-mentioned egg white, egg yolk, sugar and gum. Specifically, it can be manufactured by the following steps (i) and (ii).
(I) a step of forming a W / O type emulsion in which the mixed solution for forming an inner aqueous phase is dispersed in an oil phase (O) containing edible oil and fat and PGPR,
(Ii) A step of mixing the obtained W / O type emulsion with the mixed liquid for forming the outer aqueous phase

<W/O/W型乳化調味料の乳化状態>
第1の製造方法により得られるW/O/W型乳化調味料は、図1に示す乳化状態となる。つまり、図1に示す通り、本発明のW/O/W型乳化調味料は、内水相(W1)を内包する油相(O)、その油相(O)を内包する外水相(W2)から成る、乳化状態となっている。
<Emulsified state of W / O / W type emulsified seasoning>
The W / O / W type emulsified seasoning obtained by the first production method is in the emulsified state shown in FIG. That is, as shown in FIG. 1, the W / O / W type emulsified seasoning of the present invention comprises an oil phase (O) containing an inner water phase (W1) and an outer water phase (O) containing the oil phase (O). W2), which is in an emulsified state.

<サラダ>
本発明のサラダは、上記詳述した本発明のW/O/W型乳化調味料と食材とを含む。すなわち、本発明のサラダは、本発明のW/O/W型乳化調味料が配合されていることにより、食材からの離水を抑える効果を奏し、且つ食材と和えた後も本発明のW/O/W型乳化調味料及びサラダは、マヨネーズらしいツヤ及びジューシーな外観を維持することができる。本発明のサラダに含まれる食材は例えば、離水を生じ易い食材である。例えば、本発明に係るサラダは、本発明のW/O/W型乳化調味料と、野菜および果物もしくはいずれか一方とを含むものであることができる。
離水を生じ易い食材としては、例えば、きゅうり、玉ねぎ、にんじん、レタス、セロリ、キャベツ、コーン、大根、ごぼう、ブロッコリー、カリフラワー、トマト等の野菜、りんご、パイナップル、ぶどう、いちご、キウイ、もも、梨、メロン、すいか、グレープフルーツ、アボガド、マンゴー等の果実、マカロニ、スパゲティ、春雨、ビーフン、ペンネ、アジア麺等の麺類が挙げられる。
また、これらの食材を用いた本発明のサラダとしては、例えば、野菜サラダ、ポテトサラダ、パスタサラダ、タマゴサラダ、フルーツサラダ、マカロニサラダ、コールスローサラダ、大根サラダ、ごぼうサラダ等が挙げられる。
本発明のサラダは、通常、食材と本発明のW/O/W型乳化調味料とを和えて製する。本発明のサラダにおける本発明の乳化調味料の好ましい含有量は10〜90%である。
<Salad>
The salad of the present invention contains the W / O / W type emulsified seasoning of the present invention described above in detail and a food material. That is, the salad of the present invention, by incorporating the W / O / W type emulsified seasoning of the present invention, has an effect of suppressing water separation from the food material, and has W / O of the present invention even after being mixed with the food material. The O / W type emulsified seasoning and salad can maintain the gloss and juicy appearance of mayonnaise. The food material contained in the salad of the present invention is, for example, a food material that easily causes water separation. For example, the salad according to the present invention can contain the W / O / W type emulsified seasoning of the present invention and vegetables and / or fruits.
Examples of foods that easily produce syneresis include vegetables such as cucumbers, onions, carrots, lettuce, celery, cabbage, corn, radish, burdock, broccoli, cauliflower, tomatoes, apples, pineapples, grapes, strawberries, kiwis, peaches, Examples thereof include fruits such as pears, melons, watermelons, grapefruits, avocados and mangoes, and noodles such as macaroni, spaghetti, vermicelli, rice noodles, penne and Asian noodles.
In addition, examples of the salad of the present invention using these ingredients include vegetable salad, potato salad, pasta salad, egg salad, fruit salad, macaroni salad, coleslaw salad, radish salad, burdock salad and the like.
The salad of the present invention is usually produced by mixing the food material and the W / O / W type emulsified seasoning of the present invention. The content of the emulsified seasoning of the present invention in the salad of the present invention is preferably 10 to 90%.

[実施例1]
<W/O/W型乳化調味料の調製>
下記表1の配合にて、W/O/W型乳化調味料を調製した。
すなわち、下記表1の内水相(W1)を形成する各成分を混合した。ホモミキサー(特殊機化工業製、T.K.オートホモミキサーMA)を用いて、ポリグリセリン縮合リシノレイン酸エステルを添加した食用油脂に内水相形成用混合液を注加し、攪拌混合して予備乳化を行い、得られた混合物をコロイドミルにかけて精乳化することによりW/O型乳化物を調製した。
次に、外水相形成用混合液を調製し、ホモミキサー等の攪拌装置を用いて、外水相形成用混合液に、上記W/O型乳化物を注加攪拌して予備乳化して、更にコロイドミルを用いて精乳化することによりW/O/W型乳化調味料を得た。
なお、粘度は250Pa・sであった。
[Example 1]
<Preparation of W / O / W type emulsified seasoning>
A W / O / W type emulsified seasoning was prepared according to the formulation shown in Table 1 below.
That is, the respective components forming the inner aqueous phase (W1) shown in Table 1 below were mixed. Using a homomixer (TK Auto Homomixer MA manufactured by Tokushu Kika Kogyo Co., Ltd.), the mixed solution for forming the inner aqueous phase was added to the edible oil / fat to which polyglycerin condensed ricinoleic acid ester was added, and the mixture was stirred and mixed Preliminary emulsification was performed, and the resulting mixture was subjected to a colloid mill for fine emulsification to prepare a W / O type emulsion.
Next, an external water phase forming mixed solution is prepared, and the above W / O type emulsion is added to the external water phase forming mixed solution by using a stirring device such as a homomixer, followed by pre-emulsification. A W / O / W type emulsified seasoning was obtained by further emulsifying using a colloid mill.
The viscosity was 250 Pa · s.

[比較例1〜6]
下記表1の配合に変更した以外は、実施例1に準じてW/O/W型乳化調味料を調製した。次いで、実施例1の方法に準じて、得られたW/O/W型乳化調味料を用いてサラダを調製した。
[Comparative Examples 1 to 6]
A W / O / W type emulsified seasoning was prepared according to Example 1 except that the formulation was changed to that shown in Table 1 below. Then, according to the method of Example 1, a salad was prepared using the obtained W / O / W type emulsified seasoning.

[試験例1]
実施例1及び比較例1〜6のW/O/W型乳化調味料の外観評価、これらの乳化調味料を用いたサラダの外観評価及び離水評価を以下の評価方法及び評価基準に従って行った。
[Test Example 1]
The appearance evaluation of the W / O / W type emulsified seasonings of Example 1 and Comparative Examples 1 to 6, the appearance evaluation of the salad using these emulsified seasonings, and the water separation evaluation were performed according to the following evaluation methods and evaluation criteria.

<W/O/W型乳化調味料の外観評価方法>
以下の要領で調製した基準調味料と、各W/O/W型乳化調味料とを各10gずつ平皿に出し、外観評価を行った。
<Appearance evaluation method of W / O / W type emulsion seasoning>
10 g each of the standard seasoning prepared in the following manner and each W / O / W type emulsified seasoning were placed on a flat plate and evaluated for appearance.

<基準マヨネーズタイプ調味料の調製>
基準マヨネーズタイプ調味料は、生卵黄100g、食酢(酸度4%)90g、清水35g、食塩10g、キサンタンガム2がおよびグルタミン酸ナトリウム3gをミキサー(例えば、ホバート社製、卓上ホバートミキサー)で均一とし水相を調製した後、攪拌しながら食用植物油脂760gを注加して粗乳化物を調製し、次いで、この粗乳化物を、コロイドミルを用いて3560rpmで連続的に精乳化して調製される。この基準マヨネーズタイプ調味料は、公知のマヨネーズの製造方法(例えば、特開2006−187277号、特開2009−61号公報参照)に準じて調製されたものである。
<Preparation of standard mayonnaise type seasoning>
The standard mayonnaise type seasoning is prepared by uniformly mixing 100 g of raw egg yolk, 90 g of vinegar (acidity 4%), 35 g of fresh water, 10 g of salt, xanthan gum 2 and 3 g of sodium glutamate with a mixer (for example, Hobart's tabletop Hobart mixer) and water phase. Then, 760 g of edible vegetable oils and fats are added with stirring to prepare a crude emulsion, and then the crude emulsion is continuously refined at 3560 rpm using a colloid mill. This reference mayonnaise type seasoning is prepared according to a known mayonnaise production method (see, for example, JP-A 2006-187277 and JP-A 2009-61).

<W/O/W型乳化調味料の外観評価基準>
A:基準マヨネーズタイプ調味料とほぼ同様に、ツヤがありジューシーな外観である。
B:基準マヨネーズタイプ調味料と比較して、若干ツヤがないが、マヨネーズと呼べる程度である。
C:基準マヨネーズタイプ調味料と比較して、ツヤが無くマヨネーズらしさがない。
<Appearance evaluation standard of W / O / W type emulsified seasoning>
A: It has a glossy and juicy appearance almost like the standard mayonnaise type seasoning.
B: Compared with the standard mayonnaise type seasoning, it is slightly glossy, but can be called mayonnaise.
C: Compared with the standard mayonnaise type seasoning, there is no luster and no mayonnaise-likeness.

<サラダの離水評価方法>
実施例1及び比較例1〜5のW/O/W型乳化調味料並びに基準マヨネーズタイプ調味料を使用して、以下の配合でコールスローサラダを製した。
具体的には、キャベツ(3mm千切り)40g、レタス(30mm)40g、ニンジン(1mm×1mm)5g、玉ねぎ(1mmスライス)8g、およびコーン4.5gと、各W/O/W型乳化調味料又は基準マヨネーズタイプ調味料タイプ調味料60gと清水30gとを混合して、コールスローサラダを製し、サラダをプラスチック容器に入れ、蓋をして冷蔵庫で72時間静置した。
得られたサラダの離水の程度を基準マヨネーズタイプ調味料を用いたサラダを対照にして、下記の評価基準で評価した。
<Evaluation method for water separation of salad>
Using the W / O / W type emulsified seasoning of Example 1 and Comparative Examples 1 to 5 and the standard mayonnaise type seasoning, a coleslaw salad was prepared with the following formulation.
Specifically, cabbage (3 mm shredded) 40 g, lettuce (30 mm) 40 g, carrot (1 mm x 1 mm) 5 g, onion (1 mm slice) 8 g, and corn 4.5 g, and each W / O / W type emulsified seasoning Alternatively, 60 g of the standard mayonnaise type seasoning type seasoning and 30 g of fresh water were mixed to prepare a coleslaw salad, the salad was placed in a plastic container, the lid was put on, and the mixture was allowed to stand in a refrigerator for 72 hours.
The degree of water separation of the obtained salad was evaluated according to the following evaluation criteria, with a salad using a standard mayonnaise type seasoning as a control.

<サラダの離水評価>
A:容器を傾けても離水がなかった。
B:基準マヨネーズタイプ調味料のサラダと比較して、離水量は少なったが、容器を傾けると離水が生じていた。
C:基準マヨネーズタイプ調味料のサラダと同程度の離水があった。
<Evaluation of water separation of salad>
A: There was no water separation even when the container was tilted.
B: The amount of water separation was small as compared with the standard mayonnaise type seasoning salad, but water separation occurred when the container was tilted.
C: Water was released to the same extent as the standard mayonnaise type seasoning salad.

<サラダの外観評価方法>
各W/O/W型乳化調味料を用いたサラダの外観評価直前に、基準マヨネーズタイプ調味料を用いたサラダを再度調製し、当該基準サラダを対照に、下記の評価基準で外観を評価した。
尚、評価直前に調製した基準サラダは、離水評価時のサラダと同様の調製方法である。
<How to evaluate the appearance of salad>
Immediately before the appearance evaluation of the salad using each W / O / W type emulsified seasoning, a salad using the reference mayonnaise type seasoning was prepared again, and the appearance was evaluated according to the following evaluation criteria with the reference salad as a control. .
The standard salad prepared immediately before the evaluation has the same preparation method as the salad used in the evaluation of water separation.

<サラダの外観評価基準>
A:基準マヨネーズタイプ調味料を用いたサラダとほぼ同様に、ツヤがありジューシーな外観である
B:基準マヨネーズタイプ調味料を用いたサラダと比較して、若干ツヤがある・ジューシーな外観である
C:基準マヨネーズタイプ調味料を用いたサラダと比較して、ツヤが無くマヨネーズらしさがない。
<Appearance evaluation criteria for salads>
A: It has a glossy and juicy appearance, which is almost the same as the salad using the standard mayonnaise type seasoning. B: It has a slightly glossy and juicy appearance compared to the salad using the standard mayonnaise type seasoning. C: Compared to the salad using the standard mayonnaise type seasoning, it has no gloss and does not have the mayonnaise-like character.

Figure 0006682181
Figure 0006682181

表1の結果より、実施例1のW/O/W型乳化調味料の外観は、基準マヨネーズタイプ調味料とほぼ同様に、ツヤがあり、ジューシーな外観であった。また、実施例1の調味料を用いたサラダの離水評価及び外観評価の結果も良好であった。一方、比較例1〜6のW/O/W型乳化調味料の外観は、基準マヨネーズタイプ調味料と異なり、ジューシーさがなくマヨネーズらしくないか、及び/又はサラダの外観のいずれかが悪かった。 From the results in Table 1, the appearance of the W / O / W type emulsified seasoning of Example 1 was glossy and juicy, almost the same as the reference mayonnaise type seasoning. In addition, the results of the water separation evaluation and the appearance evaluation of the salad using the seasoning of Example 1 were also good. On the other hand, the appearance of the W / O / W type emulsified seasonings of Comparative Examples 1 to 6 was different from the standard mayonnaise type seasoning and was not juicy and did not look like mayonnaise, and / or the appearance of the salad was poor. .

[実施例2]
下記配合表1の配合に変更した以外は、実施例1に準じてW/O/W型乳化調味料を調製した。得られたW/O/W型乳化調味料の粘度は150Pa・sであった。
次いで、実施例1に準じて調製したW/O/W型乳化調味料を用いたサラダを調製した。
[Example 2]
A W / O / W type emulsified seasoning was prepared according to Example 1 except that the composition was changed to the composition shown in Table 1 below. The viscosity of the obtained W / O / W type emulsion seasoning was 150 Pa · s.
Then, a salad using the W / O / W type emulsified seasoning prepared according to Example 1 was prepared.

[配合表1]
(内水相W1)食酢(酸度4%) 10%
食塩 1%
砂糖 5%
清水 15.5%
(油相O) 食用植物油脂 20%
PGPR(エステル化度33%) 1.4%
(外水相W2)食酢(酸度4% 水分95%) 10%
食塩 1%
砂糖 3%
澱粉 0.4%
卵黄(固形分50% 水分50%) 12%
卵白(固形分10% 水分90%) 10%
キサンタンガム 0.3%
清水 10.4%
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
合計 100%
[Recipe 1]
(Inner water phase W1) Vinegar (acidity 4%) 10%
1% salt
5% sugar
Shimizu 15.5%
(Oil phase O) Edible vegetable oil 20%
PGPR (esterification degree 33%) 1.4%
(Outer water phase W2) Vinegar (acidity 4%, water content 95%) 10%
1% salt
3% sugar
0.4% starch
Egg yolk (solid content 50%, water content 50%) 12%
Egg white (solid content 10%, water content 90%) 10%
Xanthan gum 0.3%
Shimizu 10.4%
-----------------
100% in total

得られたW/O/W型乳化調味料及びサラダを試験例1の評価方法及び評価基準に基づいて、評価した。
実施例2のW/O/W型乳化調味料の外観は、基準マヨネーズタイプ調味料とほぼ同様に、ツヤがあり、ジューシーな外観であった。また、実施例2の調味料を用いたサラダの離水評価及び外観評価の結果は、若干劣っていたが離水及び外観も問題ない程度であった。
The obtained W / O / W type emulsified seasoning and salad were evaluated based on the evaluation method and evaluation criteria of Test Example 1.
The appearance of the W / O / W type emulsion seasoning of Example 2 was glossy and juicy, almost the same as the standard mayonnaise type seasoning. In addition, the results of the water separation evaluation and the appearance evaluation of the salad using the seasoning of Example 2 were slightly inferior, but the water separation and the appearance were not problematic.

[実施例3
記配合表2の配合に変更した以外は、実施例1に準じて、W/O/W型乳化調味料を調
製した。
次いで、実施例1に準じて調製したW/O/W型乳化調味料を用いたサラダを調製した。
[Example 3 ]
Except for changing the formulation of lower Symbol recipe 2, in accordance with Example 1 to prepare a W / O / W type emulsified seasoning.
Then, a salad using the W / O / W type emulsified seasoning prepared according to Example 1 was prepared.

[配合表2]
(内水相W1)食酢(酸度4%) 10%
食塩 1%
砂糖 5%
清水 15.5%
(油相O) 食用植物油脂 27%
PGPR(エステル化度33%) 1.4%
(外水相W2)食酢(酸度4% 水分95%) 10%
食塩 1%
砂糖 3%
澱粉 0.4%
卵黄(固形分50% 水分50%) 16%
卵白(固形分10% 水分90%) 1.5%
キサンタンガム 0.3%
清水 7.9%
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
合計 100%
[Recipe 2]
(Inner water phase W1) Vinegar (acidity 4%) 10%
1% salt
5% sugar
Shimizu 15.5%
(Oil phase O) Edible vegetable oil / fat 27%
PGPR (esterification degree 33%) 1.4%
(Outer water phase W2) Vinegar (acidity 4%, water content 95%) 10%
1% salt
3% sugar
0.4% starch
Egg yolk (solid content 50%, water content 50%) 16%
Egg white (solid content 10%, water content 90%) 1.5%
Xanthan gum 0.3%
Shimizu 7.9%
-----------------
100% in total

得られたW/O/W型乳化調味料及びサラダを試験例1の評価方法及び評価基準に基づいて、評価した。
実施例3のW/O/W型乳化調味料の外観は、基準マヨネーズタイプ調味料とほぼ同様に、ツヤがあり、ジューシーな外観であった。また、実施例3の調味料を用いたサラダの離水評価及び外観評価の結果も良好であった。
The obtained W / O / W type emulsified seasoning and salad were evaluated based on the evaluation method and evaluation criteria of Test Example 1.
The appearance of the W / O / W type emulsion seasoning of Example 3 was glossy and juicy, almost the same as the standard mayonnaise type seasoning. Moreover, the results of the water separation evaluation and the appearance evaluation of the salad using the seasoning of Example 3 were also good.

[実施例4]
下記配合表3の配合に変更した以外は、実施例1に準じて、W/O/W型乳化調味料を調製した。
次いで、実施例1に準じて調製したW/O/W型乳化調味料を用いたサラダを調製した。
[Example 4]
A W / O / W type emulsified seasoning was prepared according to Example 1 except that the composition was changed to the composition shown in Table 3 below.
Then, a salad using the W / O / W type emulsified seasoning prepared according to Example 1 was prepared.

[配合表3]
(内水相W1)食酢(酸度4%) 10%
食塩 1%
砂糖 5%
清水 15.5%
(油相O) 食用植物油脂 30%
PGPR(エステル化度33%) 1.4%
(外水相) 食酢(酸度4% 水分95%) 10%
食塩 1%
砂糖 1%
澱粉 0.3%
卵黄(固形分50% 水分50%) 8.4%
卵白(固形分10% 水分90%) 6%
キサンタンガム 0.3%
清水 10.1%
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
合計 100%
[Recipe 3]
(Inner water phase W1) Vinegar (acidity 4%) 10%
1% salt
5% sugar
Shimizu 15.5%
(Oil phase O) Edible vegetable oil 30%
PGPR (esterification degree 33%) 1.4%
(Outer water phase) Vinegar (acidity 4%, water content 95%) 10%
1% salt
1% sugar
Starch 0.3%
Egg yolk (solid content 50%, water content 50%) 8.4%
Egg white (solid content 10%, water content 90%) 6%
Xanthan gum 0.3%
Shimizu 10.1%
-----------------
100% in total

得られたW/O/W型乳化調味料及びサラダを試験例1の評価方法及び評価基準に基づいて、評価した。
実施例4のW/O/W型乳化調味料の外観は、基準マヨネーズタイプ調味料と比較して離水量は少なかったが、容器を傾けると若干離水が確認された。また、実施例4の調味料を用いたサラダの離水評価及び外観評価は、若干劣っていたが離水及び外観も問題ない程度であった。
The obtained W / O / W type emulsified seasoning and salad were evaluated based on the evaluation method and evaluation criteria of Test Example 1.
Regarding the appearance of the W / O / W type emulsified seasoning of Example 4, the amount of water separation was smaller than that of the standard mayonnaise type seasoning, but some water separation was confirmed when the container was tilted. Further, the water separation and appearance evaluation of the salad using the seasoning of Example 4 were slightly inferior, but the water separation and appearance were also satisfactory.

[実施例5] フルーツサラダ
実施例1のW/O/W型乳化調味料を使用して、以下の配合でフルーツサラダを製した。具体的には、上白糖20g、寒天90g、シロップ漬け缶詰みかん30g、シロップ漬け缶詰パインアップル30g、りんご15gおよびキウイフルーツ15gと実施例1のW/O/W型乳化調味料45gを混合してフルーツサラダを製し、プラスチック容器に入れ、蓋をして冷蔵庫で一晩静置した。その後、サラダの外観および風味について評価したところ、離水は見られず、サラダの調製直後と比べて外観および風味に変化は見られなかった。
[Example 5] Fruit salad Using the W / O / W emulsified seasoning of Example 1, a fruit salad was prepared with the following formulation. Specifically, 20 g of white sucrose, 90 g of agar, 30 g of canned oranges in syrup, 30 g of canned pineapple in syrup, 15 g of apple, 15 g of kiwi fruit and 45 g of the W / O / W emulsified seasoning of Example 1 were mixed. A fruit salad was prepared, placed in a plastic container, covered, and allowed to stand overnight in the refrigerator. After that, when the appearance and flavor of the salad were evaluated, no syneresis was observed, and no change was observed in the appearance and flavor compared to immediately after the preparation of the salad.

[実施例6] 春雨サラダ
実施例1のW/O/W型乳化調味料を使用して、以下の配合で春雨サラダを製した。具体的には、水に浸漬し、沸騰水中で10分間加熱した春雨150gと、きゅうりの輪切り15g、ニンジンの千切り15g、スライスした玉ねぎ15g、短冊切りしたレタス15g、紫キャベツの千切り6g、上白糖1.5g、食塩1gと実施例1のW/O/W型乳化調味料70gを混合して春雨サラダを製し、プラスチック容器に入れ、蓋をして冷蔵庫で一晩静置した。その後、サラダの外観および風味について評価したところ、離水は見られず、サラダの調製直後と比べて外観および風味に変化は見られなかった。
[Example 6] Vermicelli salad Using the W / O / W type emulsified seasoning of Example 1, vermicelli salad was prepared with the following formulation. Specifically, 150 g of vermicelli soaked in water and heated in boiling water for 10 minutes, 15 g of cucumber slices, 15 g of carrots, 15 g of sliced onions, 15 g of sliced onions, 15 g of striped lettuce, 6 g of purple cabbage, 6 g of fine white sugar. 1.5 g, 1 g of salt and 70 g of the W / O / W emulsified seasoning of Example 1 were mixed to prepare vermicelli salad, which was placed in a plastic container, covered with a lid, and allowed to stand overnight in a refrigerator. After that, when the appearance and flavor of the salad were evaluated, no syneresis was observed, and no change was observed in the appearance and flavor compared to immediately after the preparation of the salad.

[実施例7] マカロニサラダ
実施例2のW/O/W型乳化調味料を使用して、以下の配合で春雨サラダを製した。具体的には、沸騰水中で9分間加熱したマカロニ120gと、きゅうりの輪切り15g、ニンジンの千切り15g、スライスした玉ねぎ15g、コーン15g、キャベツの千切り15g、短冊切りしたレタス15g、上白糖2g、食塩2gと実施例2のW/O/W型乳化調味料30gを混合してマカロニサラダを製し、プラスチック容器に入れ、蓋をして冷蔵庫で一晩静置した。その後、サラダの外観および風味について評価したところ、離水は見られず、サラダの調製直後と比べて外観および風味に変化は見られなかった。
[Example 7] Macaroni salad Using the W / O / W emulsified seasoning of Example 2, vermicelli salad was prepared with the following formulation. Specifically, 120 g of macaroni heated in boiling water for 9 minutes, 15 g of cucumber slices, 15 g of carrots, 15 g of sliced onions, 15 g of sliced onions, corn 15 g, shredded cabbage 15 g, cut lettuce 15 g, white sucrose 2 g, salt 2 g and 30 g of the W / O / W type emulsified seasoning of Example 2 were mixed to produce a macaroni salad, which was placed in a plastic container, covered with a lid, and allowed to stand in a refrigerator overnight. After that, when the appearance and flavor of the salad were evaluated, no syneresis was observed, and no change was observed in the appearance and flavor compared to immediately after the preparation of the salad.

[実施例8] ポテトサラダ
実施例2のW/O/W型乳化調味料を使用して、以下の配合でポテトサラダを製した。具体的には、じゃがいも120g、きゅうりの輪切り15g、ニンジンの千切り15g、スライスした玉ねぎ15g、コーン15g、キャベツの千切り15g、短冊切りしたレタス15g、上白糖2g、食塩2gと実施例2のW/O/W型乳化調味料30gを混合してポテトサラダを製し、プラスチック容器に入れ、蓋をして冷蔵庫で一晩静置した。その後、サラダの外観および風味について評価したところ、離水は見られず、サラダの調製直後と比べて外観および風味に変化は見られなかった。
Example 8 Potato Salad Using the W / O / W type emulsified seasoning of Example 2, a potato salad was prepared with the following formulation. Specifically, 120 g of potato, 15 g of sliced cucumber, 15 g of carrot, 15 g of sliced onion, 15 g of sliced onion, 15 g of corn, 15 g of shredded cabbage, 15 g of stripped lettuce, 2 g of white sucrose, 2 g of salt and W / of Example 2. 30 g of the O / W type emulsified seasoning was mixed to prepare a potato salad, which was placed in a plastic container, covered with a lid, and allowed to stand in a refrigerator overnight. After that, when the appearance and flavor of the salad were evaluated, no syneresis was observed, and no change was observed in the appearance and flavor compared to immediately after the preparation of the salad.

[実施例9] ごぼうサラダ
実施例1のW/O/W型乳化調味料を使用して、以下の配合でごぼうサラダを製した。具体的には、加熱調味したごぼう150g、ゆでたニンジンの千切り15g、いちょう切りしてゆでたレンコン15g、湯戻ししたひじき5g、湯戻ししたきくらげの千切り5g、こんにゃくの千切り5g、上白糖5g、食塩1.5gと実施例2のW/O/W型乳化調味料30gを混合してごぼうサラダを製し、プラスチック容器に入れ、蓋をして冷蔵庫で二晩静置した。その後、サラダの外観および風味について評価したところ、離水は見られず、サラダの調製直後と比べて外観および風味に変化は見られなかった。
[Example 9] Burdock salad Using the W / O / W emulsified seasoning of Example 1, a burdock salad was prepared with the following formulation. Specifically, 150 g of burdock cooked with heat, 15 g shredded boiled carrot, 15 g of grated chopped lotus root, 5 g of boiled hijiki, 5 g of shredded kelp jelly, 5 g of konjac, 5 g of white sucrose, 1.5 g of salt and 30 g of the W / O / W emulsified seasoning of Example 2 were mixed to prepare a burdock salad, which was placed in a plastic container, covered with a lid, and left to stand in a refrigerator for two nights. After that, when the appearance and flavor of the salad were evaluated, no syneresis was observed, and no change was observed in the appearance and flavor compared to immediately after the preparation of the salad.

[実施例10] かに風味サラダ
実施例1のW/O/W型乳化調味料を使用して、以下の配合でかに風味サラダを製した。具体的には、かに風味かまぼこ150g、キャベツの千切り150g、レタスの角切り120g、きゅうりの輪切り50g、上白糖2g、食塩2gと実施例2のW/O/W型乳化調味料120gを混合してかに風味サラダを製し、プラスチック容器に入れ、蓋をして冷蔵庫で二晩静置した。その後、サラダの外観および風味について評価したところ、離水は見られず、サラダの調製直後と比べて外観および風味に変化は見られなかった。
[Example 10] Crab flavor salad Using the W / O / W emulsified seasoning of Example 1, a crab flavor salad was prepared with the following formulation. Specifically, 150 g crab-flavored kamaboko, 150 g shredded cabbage, 120 g chopped lettuce, 50 g cucumber slices, 2 g white sucrose, 2 g salt and 120 g of the W / O / W emulsified seasoning of Example 2. Then, a crab-flavored salad was prepared, placed in a plastic container, covered with a lid, and allowed to stand in a refrigerator for two nights. After that, when the appearance and flavor of the salad were evaluated, no syneresis was observed, and no change was observed in the appearance and flavor compared to immediately after the preparation of the salad.

Claims (2)

内水相(W1)、ポリグリセリン縮合リシノレイン酸エステルを含有する油相(O)、
外水相(W2)からなるW/O/W型乳化調味料であって、
食用油脂を前記乳化調味料全体に対して20%以上35%未満含有し、
外水相(W2)に、卵白、卵黄、糖質及びガム質類を含有し、前記卵白含有量が前記乳化調味料全体に対して生換算で1%以上10%以下であり、
外水相(W2)における固形分が、外水相(W2)に対して20%以上40%以下であり、
前記外水相(W2)における卵白と卵黄との含有比率が、生換算で1:1〜1:10であり、
前記ポリグリセリン縮合リシノレイン酸エステルのエステル化度が33%であり、
前記乳化調味料の粘度が50Pa・s以上500Pa・s以下である、
W/O/W型乳化調味料(W2に分岐デキストリンを、前記乳化調味料全体に対して0.05%以上含むものを除く。)。
An inner water phase (W1), an oil phase (O) containing a polyglycerin condensed ricinoleic acid ester,
A W / O / W type emulsified seasoning consisting of an external water phase (W2),
Contains 20% or more and less than 35% of edible oil / fat with respect to the entire emulsified seasoning,
The outer water phase (W2) contains egg white, egg yolk, carbohydrates and gums, and the egg white content is 1% or more and 10% or less in terms of raw conversion with respect to the whole emulsified seasoning,
The solid content in the external water phase (W2) is 20% or more and 40% or less with respect to the external water phase (W2),
The content ratio of egg white and egg yolk in the external water phase (W2) is 1: 1 to 1:10 in raw conversion,
The degree of esterification of the polyglycerin condensed ricinoleic acid ester is 33%,
The viscosity of the emulsified seasoning is 50 Pa · s or more and 500 Pa · s or less,
W / O / W type emulsified seasoning ( excluding those containing branched dextrin in W 2 in an amount of 0.05% or more based on the entire emulsified seasoning).
請求項1に記載の乳化調味料と、野菜および果物もしくはいずれか一方とを含む、サラダ。   A salad comprising the emulsified seasoning according to claim 1 and vegetables and / or fruits.
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