JP6664646B2 - Lighting equipment and light collection method - Google Patents

Lighting equipment and light collection method Download PDF

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JP6664646B2
JP6664646B2 JP2015095503A JP2015095503A JP6664646B2 JP 6664646 B2 JP6664646 B2 JP 6664646B2 JP 2015095503 A JP2015095503 A JP 2015095503A JP 2015095503 A JP2015095503 A JP 2015095503A JP 6664646 B2 JP6664646 B2 JP 6664646B2
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高村明
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▲高▼村 明
▲高▼村 明
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Description

本発明は通常、照明器具として機能し、夜間商用電源等の喪失を導く様な非常時に短
時間の対策に必要な明るさを提供する照明、及びその集光方法に関する。
The present invention generally relates to a lighting device that functions as a lighting device and provides brightness necessary for a short-term countermeasure in an emergency such as loss of a commercial power supply at night, and a light collecting method thereof.

夜間に照明のない状態で畜光材の燐光を利用して避難経路や位置を示す表示用製品が従来から提案されている。また商用電源の喪失時に畜光材の燐光を利用して案内図等を光らせる標識製品が普及している。更に通常時は商用電源を用いて蓄電を行い、電源喪失などの非常時に蓄電した電力を照明に利用する器具が存在する。 2. Description of the Related Art A display product that indicates an evacuation route and a position by using phosphorescence of a luminous material without lighting at night has been conventionally proposed. Also, there is a widespread use of a marker product that illuminates a guide map or the like by using phosphorescence of a luminous material when a commercial power supply is lost. Further, there is a device that stores power using a commercial power supply in a normal time and uses the stored power in an emergency such as power loss for lighting.

特許文献1〜4では畜光の利用が提案されている。しかし、これらの発明は、省エネルギーが目的であり、周辺の照明をするに足る光度の確保を目的としていない。このため照明器具として機能するとともに、非常用照明に足る光量の提供は難しい。 Patent Documents 1 to 4 propose the use of light. However, these inventions aim at energy saving and do not aim at securing luminous intensity sufficient to illuminate the surroundings. For this reason, while functioning as a lighting fixture, it is difficult to provide an amount of light sufficient for emergency lighting.

蓄電池を利用した非常用電源による照明器具が特許文献5・6で提案されている。しかし、非常時に万一蓄電池や照明器具が故障して使用できなくなれば人命にかかわる危険を招く可能性があり、全てを、この様な器具に頼るわけにはゆかない。 Patent Literatures 5 and 6 propose lighting equipment using an emergency power supply using a storage battery. However, in the event of an emergency, if a storage battery or a lighting device fails and becomes unusable, there is a possibility of causing a danger to human life, and it is not possible to rely entirely on such a device.

特許3427797号広報Patent No. 3427797 public relations 特開2001−350143号広報JP 2001-350143 A 特開2010−040385号広報JP 2010-040385 public relations 特開平7−281032号広報Public information of JP-A-7-281032 特開2014−229467JP 2014-229467 A 特開2015−15191JP-A-2015-15191

畜光材を用い、太陽光から受光して畜光する方式の既存の器具では、畜光してから利用する時間帯まで経過した後では燐光の光度が低く、周囲を照らすに足るだけの光度は得られない。更に、これらの器具は通常の照明として機能しない為、別に照明器具を設備する必要がある。また一般照明器具から受光して蓄光する器具では、蓄光材の励起に必要な励起光照度が低く、その結果、蓄光による燐光は光度が低い。加えてこれら一般照明器具からの受光照度の低さにより、蓄光材が蓄光状態に至るまでには長時間を要する。 With existing instruments that use light-glowing materials and receive light from sunlight, the light intensity of phosphorescence is low after the time of use and after the time of use, and sufficient light intensity to illuminate the surroundings can be obtained. Absent. Furthermore, since these fixtures do not function as ordinary lighting, it is necessary to separately provide lighting fixtures. In a device that receives light from a general lighting device and stores light, the illuminance of the excitation light required for exciting the light storage material is low, and as a result, the phosphorescence due to the light storage has a low luminous intensity. In addition, due to the low illuminance received from these general lighting fixtures, it takes a long time for the phosphorescent material to reach the phosphorescent state.

これらの問題を解決するために、本発明では通常は照明器具として機能し、停電などの電源喪失時に短時間、暗闇でも手探りをしないで対策行動を可能にするだけの照明を提供できると共に、その後引き続き蓄光材の燐光により、その位置確認のための表示機能を有する照明器具の提供を目的とする。 In order to solve these problems, the present invention normally provides a lighting device that functions as a lighting device, and that can perform a countermeasure action without groping even in the dark for a short time when power is lost such as a power failure, and thereafter, It is another object of the present invention to provide a lighting fixture having a display function for confirming the position of the phosphorescent material by phosphorescence of the phosphorescent material.

前記課題を達成するために請求項1の発明は、光源と,この光を導く導光板とを揃えた照明器具であって、前記導光板の片面に凸状の突起部を設け、この突起部に対向して蓄光拡散反射シートを設け、この蓄光拡散反射シートは、前記凸状の突起部で集光する光を蓄光する蓄光機能層と、これを透過した光を反射する拡散反射層とを備える事を特徴とする照明器具である。
請求項2の発明は、光源と、この光源からの光を導く導光板と、この導光板の片面に設けた凸状の突起部と、この突起部に対向して設けられた蓄光機能層と、この蓄光機能層を透過した光を反射する拡散反射層とを備え、前記導光板からの光を前記突起部で前記蓄光機能層に集光させることを特徴とする集光方法である。
請求項3の発明は、導光板の片面に設けた凸状の突起部が、半球レンズ状であることを特徴とする請求項1記載の照明器具である
請求項4の発明は、蓄光機能層に用いられる蓄光材は、励起スペクトルが0.38〜0.49μmの範囲にある波長の光のエネルギー総量が励起スペクトル全体のエネルギー総量に対して20%以上となる畜光材を用いる事を特徴とする請求項1および3記載の照明器具である。
請求項5の発明は、蓄光機能層は、25cm角の平面形状の蓄光機能層の表面を700ルーメンの可視光で30秒間照明してから、これを止め、蓄光機能層の中心から垂直な線上の15cm離れた位置で2秒後の測定照度が40ルクス以上となる燐光発光能力を有する畜光機能層である事を特徴とする請求項1、および3,4記載の照明器具である
In order to achieve the above object, an invention according to claim 1 is a lighting apparatus in which a light source and a light guide plate for guiding the light are arranged, wherein a convex protrusion is provided on one surface of the light guide plate, and the protrusion is provided. A light-storing diffuse reflection sheet is provided in opposition to the light-storing diffuse reflection sheet, and the light-storing diffusion reflection sheet includes a light storage function layer that stores light condensed by the convex protrusions and a diffusion reflection layer that reflects light transmitted therethrough. It is a lighting fixture characterized by comprising.
The invention according to claim 2 includes a light source, a light guide plate for guiding light from the light source, a convex protrusion provided on one surface of the light guide plate, and a light storage function layer provided opposite to the protrusion. And a diffuse reflection layer for reflecting light transmitted through the light storage function layer, and condensing the light from the light guide plate to the light storage function layer at the protrusions.
The invention according to claim 3 is the lighting apparatus according to claim 1 , wherein the convex protrusion provided on one surface of the light guide plate has a hemispherical lens shape.
According to a fourth aspect of the present invention, in the phosphorescent material used in the phosphorescent functional layer, the total energy of light having a wavelength whose excitation spectrum is in the range of 0.38 to 0.49 μm is 20% or more of the total energy of the entire excitation spectrum. a luminaireMotomeko 1 and 3, wherein the use of畜光material becomes.
According to a fifth aspect of the present invention, the luminous function layer illuminates the surface of the luminous function layer having a planar shape of 25 cm square with visible light of 700 lumen for 30 seconds, then stops the luminous function layer on a line perpendicular to the center of the luminous function layer. 5. The lighting device according to claim 1, wherein the illuminating function layer has a phosphorescent light-emitting capability in which the measured illuminance after 2 seconds at a position 15 cm away from the device is 40 lux or more.

請求項1から5に記載の本発明の照明器具によれば、蓄光機能層における照度、つまり励起光照度が均一な照射に比べて集光箇所で大きくなる事により、蓄光機能層の燐光発光光度を大きくする事ができる。これにより本発明の照明器具は、通常時一般照明器具として使用しながら夜間非常時には緊急対策を可能にするに足る光度の燐光による照明を提供できる。 According to the luminaire of the present invention as set forth in claims 1 to 5, the illuminance in the luminous function layer, that is, the illuminance of the excitation light is larger at the converging point than in the case of uniform irradiation, so that the luminous intensity of the phosphorescent function layer is reduced. Can be bigger. As a result, the lighting fixture of the present invention can provide illumination with phosphorescence of sufficient luminosity to enable emergency countermeasures in case of emergency at night while being used as a general lighting fixture at normal times.

解決方法の詳述Detailed solution

本発明の照明器具に用いる蓄光材及び照明器具の構造に関して計測結果から得たところの本発明に必要な諸特性について記述する。測定結果によると励起光照度が大きい程燐光初期光度と総燐光光量は大きくなる事が判った。本発明の目的を達成する為には光源停止後の燐光初期光度と総燐光光量を大きくする事が必要であり、その為には畜光材への励起光照度を大きくする必要がある。これを実現する為に照明器具の畜光機能層に対する励起光照度を大きくする構造を検討し、更にこの器具に用いる畜光材の特性やその必要量の基準を規定する為に器具の燐光発光能力を評価する方法を定めた。 Various characteristics required for the present invention obtained from measurement results regarding the structure of the light storage material and the lighting device used for the lighting device of the present invention will be described. According to the measurement results, it was found that the initial phosphorescence and the total amount of phosphorescence increased as the excitation light illuminance increased. In order to achieve the object of the present invention, it is necessary to increase the initial luminous intensity of phosphorescence after stopping the light source and the total amount of phosphorescent light, and for that purpose, it is necessary to increase the illuminance of excitation light to the luminous material. In order to achieve this, we will study a structure to increase the illuminance of the excitation light for the luminous function layer of the luminaire, and evaluate the phosphorescence emission ability of the luminaire in order to specify the characteristics of the luminous material used in the luminaire and the criteria for the required amount. I decided how to do it.

畜光による燐光発光光度の経過時間による減衰の様子を、その減衰曲線から観測した。図3、図9のグラフの燐光発光光度と経過時間の関係において、励起光停止から2秒後の光度を本発明においては燐光初期光度と規定した。 The state of the decay of the phosphorescence intensity due to the illuminating light due to the elapsed time was observed from the decay curve. In the relationship between the phosphorescence emission luminous intensity and the elapsed time in the graphs of FIGS. 3 and 9, the luminous intensity two seconds after the excitation light was stopped was defined as the initial phosphorescence intensity in the present invention.

蓄光材の電子を励起する光の蓄光機能層表面における照度を本発明では励起光照度
とする。この照度とは標準分光視感効率に基いて観測光の測定データを数値処理した
値であり、それはこの数値処理を行う照度計から得られる測定値の事である。
In the present invention, the illuminance on the surface of the luminous function layer of light that excites electrons of the luminous material is referred to as illuminance of excitation light. The illuminance is a value obtained by numerically processing measurement data of observation light based on standard spectral luminous efficiency, and is a measurement value obtained from an illuminometer that performs this numerical processing.

図1の燐光初期光度と照射時間の関係において、励起光照度を固定した照射条件では、励起光照射時間はある特定時間以上増やしても燐光初期光度がそれ以上増加しない照射時間に到達する。この時の燐光初期光度を飽和燐光光度と称する。また図1のt−7、t−8の様にこの光度に達する時間を飽和燐光到達時間と称する。観測の結果、図1、2に示す様に(1)照射光による励起光照度を大きくする事で飽和燐光光度は増加する。また同時に(2)飽和燐光到達時間は短くなる事が確認できる。 In the relationship between the initial phosphorescence intensity and the irradiation time in FIG. 1, under the irradiation condition in which the excitation light illuminance is fixed, the irradiation time reaches the irradiation time in which the initial phosphorescence intensity does not increase any more even if the excitation light irradiation time is increased for a specific time or more. The initial phosphorescence at this time is referred to as saturated phosphorescence. The time to reach this luminous intensity, such as t-7 and t-8 in FIG. 1, is called the saturated phosphorescence arrival time. As a result of the observation, as shown in FIGS. 1 and 2, (1) the saturation phosphorescence is increased by increasing the illuminance of the excitation light by the irradiation light. At the same time, it can be confirmed that (2) the saturated phosphorescence arrival time is shortened.

蓄光材の燐光発光光度の減衰はふたつの減衰様式の異なる領域に分類される。ここで、図3、図9において励起光により蓄光した蓄光材の燐光発光光度は大きな光度から急激に減衰しながら短い時間に光度を落としてゆく領域と、安定した光度で長い時間に渡り同程度の光度を保ちながら徐々に暗くなる領域が現れる。境界領域を定める基準として励起光照度、励起光照射時間を様々な値に変化させた時、燐光発光光度の減衰曲線が変化する領域を第一領域、励起光照度、励起光照射時間を変化させても燐光発光光度の減衰曲線が変化しない領域を第二領域と定めた。図3において各領域の境界がその転換点である。
本発明では主として第一領域の燐光の発光を非常用の光源として用いる。この領域では燐光発光光度が大きく周囲を照らすに足る光度を数分に渡って提供でき、緊急の対応措置を可能とする事ができる。引き続き第二領域では第一領域よりも暗いけれど位置を確認できる程度の発光が長時間継続するので、その位置を示す標示機能を提供できる。
The decay of the phosphorescence of the phosphorescent material is classified into two regions having different attenuation modes. Here, in FIGS. 3 and 9, the phosphorescent luminous intensity of the phosphorescent material stored by the excitation light is approximately the same over a long period of time as the region where the luminous intensity rapidly decreases from a large luminous intensity and decreases in a short time. A region that gradually darkens appears while maintaining the luminous intensity of. When the excitation light illuminance and the excitation light irradiation time are changed to various values as a reference for determining the boundary area, the area where the decay curve of the phosphorescence emission luminosity changes is the first area, the excitation light illuminance, and the excitation light irradiation time are changed. The area where the decay curve of the phosphorescence did not change was defined as the second area. In FIG. 3, the boundary of each area is the turning point.
In the present invention, phosphorescent light emission in the first region is mainly used as an emergency light source. In this region, the phosphorescence luminous intensity is large, and the luminous intensity sufficient to illuminate the surroundings can be provided for several minutes, and emergency response measures can be made possible. Subsequently, in the second area, the light emission is darker than the first area but continues to be long enough to confirm the position, so that a marking function for indicating the position can be provided.

第一領域と第二領域の出現に関して、減衰機構からの検討を行い、その適切な利用方法を検討した。畜光による燐光発光光度は基本的に減衰曲線に従いその光度を減少させる。これは図13で示した式に従い図10の減衰曲線の減衰形式となるはずである。しかし、実際には図3、図9の様に第一領域と第二領域の境界において図13の式におけるk値が異なる値に入れ替わる。これは第一領域のk値で計算した燐光発光光度よりも第二領域では大きなk値に従う事が観測から確認された事による。この変換点において、k値の入れ替わりが発生しているとすると、これは一連の電子のエネルギー間での遷移機構全体の中の燐光を発光させるに至る過程における律速段階が交代している可能性がある。しかし、手元にESR等のデータがなく、電子の多重度に関する知見はないので正しい機構は判らない。但し、実際の観測現象では第一領域において励起光照度、または励起光照射時間の変化で燐光初期光度が変化する。またこの第一領域の継続する時間は上記条件の変化にかかわらず、ほぼ一定の時間である。第二領域では照射光照度、または励起光照射時間の変化があっても燐光光度の減衰曲線は常に同様の曲線に従う事が観測される。以上の事実のなかで、第一領域では励起光照度に関して、これを大きくすれば燐光発光光度が大きくなる。つまり、本発明の目的のためには励起光照度を大きくする事が必要である。   We examined the appearance of the first and second regions from the damping mechanism, and examined the appropriate usage. Phosphorescence luminous intensity due to animal light basically decreases its luminous intensity according to an attenuation curve. This should be the decay form of the decay curve of FIG. 10 according to the equation shown in FIG. However, in practice, the k value in the equation of FIG. 13 is changed to a different value at the boundary between the first area and the second area as shown in FIGS. This is because observation has confirmed that the second region follows a larger k value than the phosphorescence intensity calculated based on the k value of the first region. If a change in the k value occurs at this conversion point, it is possible that the rate-limiting step in the process of leading to phosphorescence in the entire transition mechanism between the energies of a series of electrons may be alternated. There is. However, there is no data such as ESR at hand and there is no knowledge about the multiplicity of electrons, so the correct mechanism cannot be understood. However, in the actual observation phenomenon, the phosphorescence initial luminous intensity changes due to a change in the excitation light illuminance or the excitation light irradiation time in the first region. Further, the duration of the first area is substantially constant regardless of the change of the above condition. In the second region, it is observed that the decay curve of the phosphorescence always follows the same curve even when the irradiation light illuminance or the excitation light irradiation time changes. Among the above facts, if the illuminance of the excitation light is increased in the first region, the luminous intensity of the phosphorescent light is increased. That is, for the purpose of the present invention, it is necessary to increase the illuminance of the excitation light.

本発明の照明器具の光源喪失時に一定以上の燐光光度を確保するために、この条件を満たす畜光機能層への励起光照度を大きくする照明器具の構造と、燐光発光光度を大きくする畜光材の選択を行った。       In order to ensure a certain level of phosphorescence when the light source of the lighting apparatus of the present invention is lost, the structure of the lighting apparatus that increases the excitation light illuminance to the light-storing functional layer that satisfies this condition, and the selection of the light-emitting material that increases the phosphorescence luminous intensity Was done.

畜光機能層への励起光照度を大きくするための器具を 図4、図11の導光板型照明器具構造とした。この構造では光源と蓄光材の距離を短く保ち、導光板内部に閉じ込めた光を導光板の半球レンズ状の突起部を介して図5の様に集光しながら板外へ取り出して蓄光拡散反射シートへ照射する。こうする事で励起光照度を大きくする構造とした。       An apparatus for increasing the illuminance of the excitation light to the light-irradiating functional layer has a light guide plate type illumination apparatus structure shown in FIGS. In this structure, the distance between the light source and the luminous material is kept short, and the light confined inside the light guide plate is taken out of the plate while being condensed through the hemispherical projection of the light guide plate as shown in FIG. Irradiate the sheet. By doing so, the structure was made to increase the illuminance of the excitation light.

蓄光拡散反射シートの蓄光機能層における畜光材粒子は受光した側へより多く発光する傾向があるので、シートの入射した側に大きく燐光発光する。これで燐光発光の効果をより多く利用できる。 The phosphor particles in the phosphorescent functional layer of the phosphorescent diffuse reflection sheet tend to emit more light to the light receiving side, and thus emit a large amount of phosphorescent light to the incident side of the sheet. Thus, the effect of phosphorescence can be more utilized.

図11の導光板型照明器具の構造において、畜光拡散反射シートは図の様に導光板下部に対向し接触させて配置する。蓄光拡散反射シートの構造は図7の構成からなり、励起光が入射する側から順次、蓄光材を含有した蓄光機能層、その次に高い反射率の拡散反射する粒子を含有した拡散反射層の二層構造からなる。この構造により畜光機能層を光が通過する時に蓄光材の電子を光が励起する。ここで吸収される光のエネルギーは光源からの光のごく一部でしかなく、励起光の大部分は拡散反射層で反射して白色光として照明に使われる。       In the structure of the light guide plate type lighting device of FIG. 11, the light diffusion / reflection sheet is disposed so as to face and contact the lower portion of the light guide plate as shown in the figure. The structure of the light-storing diffuse reflection sheet has the structure shown in FIG. 7, and sequentially includes a light-storing function layer containing a light-storing material and a diffuse reflection layer containing particles having a high reflectivity and diffuse reflection, sequentially from the side where excitation light is incident. It has a two-layer structure. With this structure, when the light passes through the light storage function layer, the light excites the electrons of the light storage material. The energy of the light absorbed here is only a small part of the light from the light source, and most of the excitation light is reflected by the diffuse reflection layer and used for illumination as white light.

畜光機能層で白色光のスペクトルから励起に有効な波長域の光を吸収させ、畜光材の電子を励起する。本発明の照明器具は通常時には一般照明器具として利用するので光源からの光は可視光領域の白色光であり、白色光の短波長側だけが畜光材の電子励起に有効に働く。       The light-absorbing function layer absorbs light in a wavelength range effective for excitation from the spectrum of white light, and excites electrons of the light-absorbing material. Since the lighting fixture of the present invention is normally used as a general lighting fixture, the light from the light source is white light in the visible light region, and only the short wavelength side of the white light effectively works for electronic excitation of the light-emitting material.

本発明では非常時に用いる照明として蓄光材の燐光を利用する。燐光の発光過程を図12に示したダイアグラムを使って説明すると、励起された電子のエネルギーは内部緩和、蛍光発光、一部は項間交差、燐光発光等を通して励起前の基底状態に戻るという過程を通る。本発明ではこのうちの燐光発光を非常用の照明に用いる。 In the present invention, phosphorescence of a phosphorescent material is used as illumination used in an emergency. The process of phosphorescence emission will be described with reference to the diagram shown in FIG. 12. Excited electron energy returns to the ground state before excitation through internal relaxation, fluorescence emission, part of intersystem crossing, phosphorescence emission, etc. Pass through. In the present invention, the phosphorescent light emission is used for emergency lighting.

図8、図12を比較してスペクトルの波長の長短とエネルギー準位間の差の大きさとの関係を見る。励起スペクトルと燐光発光スペクトルの波長の長短と、それに対応するエネルギー準位間の差の大小とは反比例する。図12の燐光発光のエネルギー準位差よりも励起のエネルギー準位差の方が大きい事がダイアグラムで示されている。これは図8の燐光発光スペクトルの波長よりも励起スペクトルの波長の方が短い事という事に対応する。
以上の関係より、燐光発光が目で見える為には、燐光発光スペクトルの波長領域が可視光の波長領域に含まれる必要がある。その結果、励起光のスペクトルの波長は一般に可視光の短波長領域から近紫外領域に属する。そして、光源からの白色光を吸収させて畜光材を励起するにはこの励起光スペクトルの一部が前期白色光のスペクトルの一部と重なりあう事が必要である。この重複する波長領域においてだけ、畜光材が光源からの光を吸収できる。図8で示した蓄光材の励起スペクトルを例にとると、この吸収の主波長は約350μm付近にあり、これは可視光領域よりも短い波長で、この領域の光を含まないLED照明の白色光では畜光材を励起できない。しかし、畜光材の結晶構造の乱れや電子のエネルギー準位間の遷移の微細構造などから、この主スペクトル線は分散して可視光領域までスペクトルの巾が広がる。この事により励起スペクトルは白色光の可視光領域と重複する領域が発生して白色光から光を吸収する事ができる。この励起スペクトルの広がり巾は畜光材固有の物性や製造過程の履歴に依存する。畜光材は、この重複領域の励起スペクトルのエネルギーが励起スペクトル全体のエネルギーに対して一定以上の比率となる事が必要である。こうする事で、大きな燐光発光を得る事ができる。
8 and 12, the relationship between the length of the wavelength of the spectrum and the magnitude of the difference between the energy levels will be examined. The length of the wavelengths of the excitation spectrum and the phosphorescence spectrum are inversely proportional to the magnitude of the difference between the corresponding energy levels. The diagram shows that the energy level difference of excitation is larger than the energy level difference of phosphorescence of FIG. This corresponds to the fact that the wavelength of the excitation spectrum is shorter than the wavelength of the phosphorescence emission spectrum of FIG.
From the above relationship, in order for phosphorescent light emission to be visible, the wavelength region of the phosphorescent light emission spectrum needs to be included in the wavelength region of visible light. As a result, the wavelength of the spectrum of the excitation light generally belongs to the short wavelength region to the near ultraviolet region of visible light. Then, in order to absorb the white light from the light source and excite the fluorescent material, it is necessary that a part of the excitation light spectrum overlaps with a part of the white light spectrum. Only in this overlapping wavelength region, the fluorescent material can absorb light from the light source. Taking the excitation spectrum of the phosphorescent material shown in FIG. 8 as an example, the dominant wavelength of this absorption is around 350 μm, which is shorter than the visible light region, and is the white color of the LED lighting that does not include light in this region. Light cannot excite the luminous material. However, due to the disorder of the crystal structure of the phosphor material and the fine structure of the transition between the energy levels of the electrons, the main spectral lines are dispersed and the spectrum width is extended to the visible light region. As a result, a region of the excitation spectrum overlapping with the visible light region of white light is generated, and light can be absorbed from the white light. The breadth of the excitation spectrum depends on the physical properties of the light-emitting material and the history of the manufacturing process. It is necessary for the light-emitting material that the energy of the excitation spectrum in this overlapping region be a certain ratio or more to the energy of the entire excitation spectrum. By doing so, large phosphorescence can be obtained.

励起光照度を大きくする事が燐光発光光度、総燐光光量を大きくするという現象は図12のダイアグラムに於いては、励起光照度を大きくする事により第一励起一重項にある電子数を増やすという事に相当する。これにより燐光発光光度を大きくし、総燐光光量も大きくする。この現象は励起光照度と励起光照射時間を増加してもそれ以上第一励起一重項にある電子数がそれ以上増えなくなるという状態である飽和状態まで現われる現象である。 The phenomenon that increasing the illuminance of the excitation light increases the luminous intensity of phosphorescence and the total amount of phosphorescence means that, in the diagram of FIG. 12, increasing the illuminance of the excitation light increases the number of electrons in the first excitation singlet. Equivalent to. As a result, the phosphorescent light intensity is increased, and the total phosphorescent light amount is also increased. This phenomenon is a phenomenon that appears even when the illuminance of the excitation light and the irradiation time of the excitation light are increased, until the number of electrons in the first excitation singlet no longer increases.

蓄光機能層が本発明の照明器具としての非常時における照明の能力を評価する方法と基準を定めた。蓄光能力の評価方法とは、25cm角の平面形状の蓄光機能層表面を700ルーメンの可視光で30秒間、光照射を行い、その後光照射を停止し、蓄光機能層の中心から垂直な線上の15cm離れた位置で2秒後の照度測定を行い、この測定値を蓄光能力の基準とした。また、蓄光能力の基準として測定照度が40ルクス以上を実用上有用な基準と定めた。40ルクスという基準値は、官能試験から得た数値、すなわち、目視観測により電源喪失時において対策活動を可能とする光の提供という状況を保持できると判断される照度であった。
畜光材の特性、発光層の面積、その面積あたりの畜光材重量、つまり器具に属する畜光材の総重量、励起光のスペクトル分布、光源の光度、畜光に要する励起時間などがこの測定照度に影響を与えるが、これら全ての要素の結果として得られる測定照度を蓄光能力の基準とした。こうする事で本発明の蓄光能力を確保する基準を設定できる。
The method and criteria for evaluating the ability of the phosphorescent functional layer to perform emergency lighting as the lighting fixture of the present invention have been established. The method for evaluating the light storage ability is as follows: the surface of the light storage function layer having a plane shape of 25 cm square is irradiated with visible light of 700 lumen for 30 seconds, then the light irradiation is stopped, and the light is stopped on a line perpendicular to the center of the light storage function layer. The illuminance after 2 seconds was measured at a position separated by 15 cm, and this measured value was used as a reference for the light storage ability. In addition, as a criterion of the light storage ability, a measured illuminance of 40 lux or more was determined as a practically useful criterion. The reference value of 40 lux was the value obtained from the sensory test, that is, the illuminance determined to be able to maintain the situation of providing light that enables countermeasure activities in the event of power loss by visual observation.
The characteristics of the light-emitting material, the area of the light-emitting layer, the weight of the light-emitting material per area, that is, the total weight of the light-emitting material belonging to the instrument, the spectral distribution of the excitation light, the luminous intensity of the light source, the excitation time required for the light emission, etc., affect the measured illuminance. Where the measured illuminance obtained as a result of all these factors was taken as the measure of the luminous capacity. By doing so, it is possible to set a criterion for ensuring the light storage ability of the present invention.

光源からの照射光の照射時間による燐光初期光度変化Phosphorescence initial luminous intensity change by irradiation time of light from light source 光源からの照射光の励起光照度による飽和燐光光度Saturated phosphorescence due to excitation light illuminance of irradiation light from light source 照射光による励起光照度を変えた時の燐光発光光度の時間変化Temporal change of phosphorescence luminous intensity when excitation light illuminance is changed by irradiation light 導光板型照明器具中の光路Light path in light guide plate type lighting equipment 導光板の半球レンズと畜光拡散反射シートへの集光Light guide plate hemispherical lens and light condensing on diffuse reflection sheet 蓄光拡散反射シート上における拡散反射Diffuse reflection on phosphorescent diffuse reflection sheet 蓄光拡散反射シートの構造Structure of phosphorescent diffuse reflection sheet 蓄光材の励起スペクトルと燐光発光スペクトルの例Example of excitation spectrum and phosphorescence spectrum of phosphorescent material 燐光発光光度の経過時間における領域区分Region division in elapsed time of phosphorescence intensity 様々なk値の計算による減衰曲線Decay curve by calculation of various k values 導光板型蓄光照明器具の構造Structure of light guide plate type phosphorescent lighting fixture 蓄光材の電子励起と緩和過程のダイアグラムDiagram of electronic excitation and relaxation process of phosphorescent material 減衰過程の微分方程式と解Differential equations and solutions for damping processes

図11は本発明の導光板型照明器具であり、図4は導光板照明器具中の光路を表し
ている。本発明の導光板型照明器具では、導光板側面に設置された光源からの光を図4のように導光板内部に導き板内で全反射を繰り返す事で導光板内部に光を閉じ込める。
ここで光源は蛍光灯、LED、発光管など任意の光源が利用できる。但し、非常用用途としては光源の寿命や動作の安定性、設置における占有空間の小ささからLEDが望ましい。次に、この光は導光板の片面に設けた半球レンズ状の凸状突起部を用いて導光板から板外へ集光しながら取り出して畜光拡散反射シート内で蓄光機能層を通過し拡散反射層で光の拡散反射が行われ、その拡散反射光は導光板を横切って進み、照明に用いられる。ここで導光板から光を取り出す方法は様々であるが、(1)導光板表面に板の内側に向かって傷や溝をいれてその部分で光を散乱させ外部に取り出す方法、(2)導光板の外側に突起部分を設けてそこから光を外部に取り出す方法、(3)導光板と同じ屈折率の有機樹脂に光拡散反射粒子を含有させ、この有機樹脂層を密着させて導光板から取り出した光をその拡散反射粒子で拡散反射させて外部に取り出す方法などが用いられる。本発明では(2)の外側の突起部を半球形状とする事で導光板から集光させながら光を取り出す照明器具を構成した。この構造で半球レンズ状突起部は凸レンズの役割を果たし図5の様に外部へ取り出す光を集光して蓄光拡散反射シート上に集光し、畜光機能層への励起光照度を大きくする構造としている。この様に取り出した光は蓄光拡散反射シートに侵入し、蓄光機能層に含有させた蓄光材粒子そして拡散反射層の拡散反射粒子により蓄光拡散反射を行う。又、この構造により畜光拡散反射シートから放出される光は、図6に示すように照明器具の外側を照明する事ができる。この構造により大きな照度の光を畜光機能層に届け、照射停止後に極めて明るい燐光を得ることが出来る。
なお、(1)の方法が本発明に対して適さない理由は導光板内部からの光採り出し部分の傷が、光の全てを蓄光拡散反射シートに向かわせるのではないので、蓄光の効率を最大にはできない事と、導光板において光源に近い部分で散乱が大きいため、光源付近で照明光は明るくなり、光源から離れるに従って暗くなるという照度の不均一を発生させ、蓄光拡散反射シート全体を有効に利用できない事による。
FIG. 11 shows a light guide plate type lighting device of the present invention, and FIG. 4 shows an optical path in the light guide plate lighting device. In the light guide plate type lighting device of the present invention, light from the light source installed on the side surface of the light guide plate is guided into the inside of the light guide plate as shown in FIG. 4, and the light is confined inside the light guide plate by repeating total reflection within the plate.
Here, as the light source, any light source such as a fluorescent lamp, an LED, and an arc tube can be used. However, for emergency use, LEDs are desirable because of the longevity of the light source, the stability of operation, and the small occupied space in installation. Next, this light is extracted from the light guide plate while being condensed out of the plate using a hemispherical lens-shaped convex portion provided on one side of the light guide plate, passes through the light storage function layer in the diffuse reflection sheet, and is diffusely reflected. The layer reflects light diffusely, and the diffuse reflected light travels across the light guide plate and is used for illumination. Here, there are various methods for extracting light from the light guide plate. (1) A method in which a scratch or a groove is formed on the surface of the light guide plate toward the inside of the plate to scatter light at that portion and extract the light to the outside, A method in which a projection is provided outside the light plate and light is extracted therefrom. (3) Light diffusion and reflection particles are contained in an organic resin having the same refractive index as that of the light guide plate, and the organic resin layer is brought into close contact with the light guide plate so that the light is diffused. A method of diffusing and reflecting the extracted light with the diffuse reflection particles and extracting the light to the outside is used. In the present invention, the illumination device for extracting light while condensing light from the light guide plate is configured by making the outer protrusion of (2) into a hemispherical shape. In this structure, the hemispherical lens-shaped projection serves as a convex lens, and as shown in FIG. 5, collects the light to be extracted to the outside and collects it on the light-storing diffuse reflection sheet, thereby increasing the illuminance of the excitation light to the storage light functional layer. I have. The light thus extracted enters the phosphorescent diffuse reflection sheet, and phosphorescent diffuse reflection is performed by the phosphorescent material particles contained in the phosphorescent functional layer and the diffuse reflection particles of the diffuse reflection layer. Further, light emitted from the light diffusion / reflection sheet according to this structure can illuminate the outside of the lighting device as shown in FIG. With this structure, light with high illuminance can be delivered to the light-emitting layer, and extremely bright phosphorescence can be obtained after stopping irradiation.
The reason that the method (1) is not suitable for the present invention is that the damage of the light extraction portion from the inside of the light guide plate does not cause all of the light to go to the light storage diffuse reflection sheet. Because it cannot be maximized and the light guide plate has large scattering near the light source, the illuminating light becomes bright near the light source, and the illuminance becomes uneven as the distance from the light source increases. It cannot be used effectively.

図7は、本発明に用いる畜光拡散反射シートの構造を表したものである。励起光の
入射してくる側から順に畜光機能層、次に拡散反射する粒子(炭酸マグネシウム、硫酸バリウムなどの様に拡散反射率の高い材料)を含有させた拡散反射層からなる2層で構成する。高反射完全拡散面を構成するために金属膜を用いた反射層を試みたが、金属は反射率が高いけれど、同時に鏡面反射となる。反射層へ導光板から取り出した光は反射層に対して浅い入射角度、すなわち反射層に対して、より平行に近い入射角度となり反射光は照明に必要である反射層とは垂直な方向へと進まないで、より水平方向に進み、その結果、照明器具としては暗い器具になる。金属表面を荒く加工する事で反射光の拡散を試みたが、その改良の効果は小さかった。この結果から、本発明では、拡散反射する粒子を有機樹脂に含有させた拡散反射層を必要な厚さにする方法に至った。
FIG. 7 shows the structure of the light diffusion and reflection sheet used in the present invention. Composed of two layers: a light-reflective layer, in order from the side where the excitation light is incident, and a diffuse-reflective layer containing diffusely-reflective particles (materials with high diffuse reflectance, such as magnesium carbonate and barium sulfate). I do. A reflective layer using a metal film has been tried to form a highly reflective perfect diffusion surface, but the metal has a high reflectance, but at the same time has a specular reflection. The light extracted from the light guide plate to the reflective layer has a shallow incident angle to the reflective layer, that is, an incident angle closer to parallel to the reflective layer, and the reflected light is directed in a direction perpendicular to the reflective layer required for illumination. Rather than proceed, it travels more horizontally, resulting in a darker lighting fixture. Attempts were made to diffuse the reflected light by roughening the metal surface, but the effect of the improvement was small. From these results, in the present invention, a method was achieved in which a diffuse reflection layer in which particles that diffusely reflect light were contained in an organic resin had a required thickness.

蓄光拡散反射シートの畜光機能層における畜光材は、蓄光材の励起スペクトルのうち波長が0.38〜0.55μmの範囲にある光のエネルギー総和量が少なくとも畜光材の励起スペクトル全体のエネルギー量の20%以上となる畜光材である事が好ましい。これは20%よりも低い数値ではLEDを光源とした白色光で効率良く励起できないためであり、それはすなわち蓄光材の一部でしか励起光を吸収できない事に起因する。これを解決するためには高価な蓄光材を大量に使用しなければならず合理的とは言えない。実際の励起スペクトルの波長に関するエネルギー分布から判断して、品質の変動なども考慮すると20%が適当である。なお、蓄光機能層は、ポリエステル、ナイロン、PET、ABS等様々な透明樹脂のフィルムやシート、板として形成しても良いし、また透明塗料に蓄光材を分散させ、塗料として塗布し形成しても良い。 The light-storage material in the light-storage function layer of the light-storing diffuse reflection sheet has at least the total energy of light having a wavelength in the range of 0.38 to 0.55 μm in the excitation spectrum of the light-storage material at least the energy amount of the entire excitation spectrum of the light storage material. It is preferable that the light emitting material is 20% or more. This is because, when the numerical value is lower than 20%, the excitation light cannot be efficiently excited by the white light using the LED as a light source, that is, only a part of the phosphorescent material can absorb the excitation light. In order to solve this, a large amount of expensive phosphorescent materials must be used, which is not rational. Judging from the energy distribution related to the wavelength of the actual excitation spectrum, 20% is appropriate in consideration of fluctuations in quality and the like. The phosphorescent functional layer may be formed as a film, sheet, or plate of various transparent resins such as polyester, nylon, PET, and ABS, or may be formed by dispersing a phosphorescent material in a transparent paint and applying it as a paint. Is also good.

本発明を具体化した蓄光照明器具を製作した。外寸は30×30cm厚さ15mmで
照明の開口部は25×25cmの平面形状である。光源としてLEDを用いた導光板型照明器具であり、導光板の片面に半球レンズ状の突起部を形成した。また蓄光拡散反射シートは図7の構造の2層構成シートであり、蓄光機能層にはイサム塗料製のアクリルウレタン樹脂塗料のハイアート#1000SPの塗料中に蓄光材として株式会社ネモト・ルミマテリアル製N夜光ルミノーバGLL-300Mを1.5g/cm2含有させた。拡散反射層として 東レ株式会社製ルミラーE6SR、#225を使用した。LEDの光源は光束量850ルーメン、通電照明時に照明器具から15cmの距離の照度は4300ルクス、光源消灯時から2秒後に68ルクス、30秒後に11ルクス、1分後に5ルクス、2分後に2.5ルクス、5分経過後2ルクスで、その後は長時間同じ状態が継続した。30分経過後も暗闇に照明器具の面が光を放ち、その位置が確認できる程で表示機能は果たした。
A phosphorescent lighting device embodying the present invention was manufactured. The outer dimensions are 30 × 30 cm, the thickness is 15 mm, and the opening of the illumination has a plane shape of 25 × 25 cm. This is a light guide plate type lighting device using an LED as a light source, and has a hemispherical lens-shaped protrusion formed on one surface of the light guide plate. The light-storing diffuse reflection sheet is a two-layer structure sheet having the structure shown in FIG. 7, and the light-storing function layer is a paint made of NEMOTO Lumi Materials Co., Ltd. as a light-storing material in a high-art # 1000SP acrylic urethane resin paint made of Isamu paint. 1.5 g / cm 2 of N Luminescent Luminova GLL-300M was contained. Lumirror E6SR, # 225 manufactured by Toray Industries, Inc. was used as the diffuse reflection layer. The LED light source has a luminous flux of 850 lumens, the illuminance at a distance of 15 cm from the lighting equipment during energization illumination is 4300 lux, 68 lux 2 seconds after the light source is turned off, 11 lux 30 seconds, 5 lux 1 minute, 2 lux 2 minutes later. 0.5 lux, 2 lux after 5 minutes, and the same condition continued for a long time thereafter. Even after 30 minutes had passed, the surface of the lighting fixture emitted light in the dark, and the display function was performed to the extent that its position could be confirmed.

本発明により通常は一般照明器具として使用できると共に夜間電源喪失時には短時間の非常対策照明として機能し、さらに引き続きその位置を示す表示機能を提供できる。これに加えて本発明では蓄光の励起時間が短い事から点灯、消灯を繰り返す間欠点灯で電力消費を低く抑える器具への応用が可能になる。これにより電力を削減でき、省エネルギーにも貢献できる。更に夜間に発生した地震で津波が襲う可能性を想定した避難路の路側に足元照明として配置し電源喪失時に安全な避難路の案内を支援する非常用照明器具としても使用できる。   According to the present invention, it can be normally used as a general lighting fixture, can function as a short-term emergency lighting at the time of power failure at night, and can further provide a display function for indicating its position. In addition to this, in the present invention, since the excitation time of the light storage is short, it is possible to apply the present invention to an appliance that suppresses power consumption by intermittent lighting in which lighting and extinguishing are repeated. This can reduce power consumption and contribute to energy conservation. Furthermore, it can be used as an emergency lighting device that is installed as a foot light on the road side of an evacuation route that assumes a possibility of a tsunami hit by an earthquake that occurs at night and that assists safe evacuation route guidance when power is lost.

1 導光板内部
2 畜光拡散反射シート
3 半球レンズ状突起部
4 畜光機能層
5 拡散反射層
7 高照度励起光の照射による燐光初期光度
8 7項よりも低い励起光照度による燐光初期光度
9 飽和到達点
10 励起スペクトル
11 燐光発光スペクトル
12 高励起光照度での燐光発光光度減衰
13 12項よりも低い励起光照度による燐光発光光度減衰
14 13項よりも低い励起光照度による燐光発光光度減衰
15 光源
1 Inside the light guide plate
2 Light reflection sheet
3 Hemispherical lenticular projection
4 Light function layer
5 Diffuse reflection layer 7 Phosphorescence initial luminosity by irradiation of high illuminance excitation light 8 Phosphorescence initial luminosity by excitation light illuminance lower than 7 9 Saturation reaching point 10 Excitation spectrum 11 Phosphorescence emission spectrum 12 Phosphorescence luminescence decay at high excitation light illuminance 13 12 Phosphorescence luminescence decay due to excitation light illuminance lower than 14 terms Phosphorescence luminescence decay due to excitation light illuminance lower than 13 terms

Claims (5)

光源と,この光を導く導光板とを揃えた照明器具であって、前記導光板の片面に凸状の突起部を設け、この突起部に対向して蓄光拡散反射シートを設け、この蓄光拡散反射シートは、前記凸状の突起部で集光する光を蓄光する蓄光機能層と、これを透過した光を反射する拡散反射層とを備える事を特徴とする照明器具。 A lighting device comprising a light source and a light guide plate for guiding the light, wherein a convex protrusion is provided on one surface of the light guide plate, and a light-storing diffuse reflection sheet is provided to face the protrusion, A lighting apparatus, wherein the reflection sheet includes a light storage function layer that stores light condensed by the convex protrusion, and a diffuse reflection layer that reflects light transmitted therethrough. 光源と、この光源からの光を導く導光板と、この導光板の片面に設けた凸状の突起部と、この突起部に対向して設けられた蓄光機能層と、この蓄光機能層を透過した光を反射する拡散反射層とを備え、前記導光板からの光を前記突起部で前記蓄光機能層に集光させることを特徴とする集光方法。 A light source, a light guide plate for guiding light from the light source, a convex protrusion provided on one side of the light guide plate, a light storage function layer provided opposite to the protrusion, and a light transmission function layer transmitted through the light storage function layer. A light-diffusing layer for reflecting the reflected light, and condensing the light from the light guide plate to the light-storing function layer at the protrusions. 導光板の片面に設けた凸状の突起部が、半球レンズ状であることを特徴とする請求項1記載の照明器具。 The lighting device according to claim 1 , wherein the convex protrusion provided on one surface of the light guide plate has a hemispherical lens shape . 蓄光機能層に用いられる蓄光材は、励起スペクトルが0.38〜0.49μmの範囲にある波長の光のエネルギー総量が励起スペクトル全体のエネルギー総量に対して20%以上となる畜光材を用いる事を特徴とする請求項1又は請求項3記載の照明器具。 As the phosphorescent material used for the phosphorescent functional layer, a phosphorescent material in which the total energy of light having a wavelength whose excitation spectrum is in the range of 0.38 to 0.49 μm is 20% or more of the total energy of the entire excitation spectrum is used. The lighting fixture according to claim 1 or 3, wherein: 蓄光機能層は、25cm角の平面形状の蓄光機能層の表面を700ルーメンの可視光で30秒間照明してから、これを止め、蓄光機能層の中心から垂直な線上の15cm離れた位置で2秒後の測定照度が40ルクス以上となる燐光発光能力を有する畜光機能層である事を特徴とする請求項1、3又は4記載の照明器具。 The luminous function layer illuminates the surface of the 25 cm square planar luminous function layer with 700 lumens of visible light for 30 seconds, then stops, and stops at a position 15 cm away from the center of the luminous function layer by a vertical line. The lighting device according to claim 1, 3 or 4, wherein the light emitting functional layer has a phosphorescent light emitting ability such that the measured illuminance after 40 seconds is 40 lux or more .
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