JP6618061B1 - Off-flavor inhibitor - Google Patents
Off-flavor inhibitor Download PDFInfo
- Publication number
- JP6618061B1 JP6618061B1 JP2019000937A JP2019000937A JP6618061B1 JP 6618061 B1 JP6618061 B1 JP 6618061B1 JP 2019000937 A JP2019000937 A JP 2019000937A JP 2019000937 A JP2019000937 A JP 2019000937A JP 6618061 B1 JP6618061 B1 JP 6618061B1
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- JP
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- Prior art keywords
- flavor
- added
- food
- isobutyl angelate
- mass
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L11/00—Pulses, i.e. fruits of leguminous plants, for production of food; Products from legumes; Preparation or treatment thereof
- A23L11/60—Drinks from legumes, e.g. lupine drinks
- A23L11/65—Soy drinks
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
- A23C9/156—Flavoured milk preparations ; Addition of fruits, vegetables, sugars, sugar alcohols or sweeteners
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- A—HUMAN NECESSITIES
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Abstract
【課題】飲食物が本来有する成分に影響を及ぼさずに、飲食物のオフフレーバーを抑制することができるオフフレーバー抑制剤を提供する。【解決手段】本発明に係るオフフレーバー抑制剤は、イソブチルアンゲレートを有効成分として含有し、大豆、牛乳、果実類、野菜類および植物油からなる群より選択される少なくとも1種の食材を含む飲食品が有するオフフレーバーを抑制する。【選択図】なし[Object] To provide an off-flavor inhibitor capable of suppressing the off-flavor of food and drink without affecting the components inherent in the food and drink. The off-flavor inhibitor according to the present invention contains isobutyl angelate as an active ingredient, and contains at least one foodstuff selected from the group consisting of soybean, milk, fruits, vegetables, and vegetable oils. Suppress the off-flavor of food and drink. [Selection diagram] None
Description
本発明は、オフフレーバー抑制剤、オフフレーバー低減飲食品、および飲食品のオフフレーバー抑制方法に関する。 The present invention relates to an off-flavor inhibitor, an off-flavor reducing food and drink, and a method for suppressing off-flavor of food and drink.
飲食品の中には、原材料に由来する独特の風味を有するもの、あるいは酸素、光、紫外線、温度などの影響により含まれる成分が経時的に変化して特異な風味を放つものがある。この飲食品の独特な風味および特異な風味とは、飲食品を口の中に入れて?み込むときに喉から鼻へ抜ける匂いを意味し、レトロネザール香と称される。オフフレーバーが発生した飲食品は、通常、健康面にはほとんど影響を及ぼさないものの、飲食品の品質やイメージに影響を及ぼす。 Some foods and drinks have a unique flavor derived from raw materials, and others have a unique flavor that changes over time due to the influence of oxygen, light, ultraviolet light, temperature, and the like. The unique and unique flavors of the food and drink mean the smell that goes from the throat to the nose when the food and drink is put in the mouth, and is called a retro nether scent. Foods and beverages with off-flavors usually have little effect on health, but affect the quality and image of food and beverages.
摂取する際にオフフレーバーが気になる飲食品としては、例えば豆乳が挙げられる。大豆を原料とする豆乳は、良質の植物性タンパク質を含んでおり、健康的な飲料である。しかし、豆乳は原料である大豆に由来する独特の青臭み(大豆臭)を有しており、摂取しにくいと感じる人も多い。 Examples of foods and beverages that are off-flavored when ingesting include soy milk. Soy milk made from soy is a healthy beverage that contains high-quality vegetable protein. However, soy milk has a unique blue odor (soybean odor) derived from soybean, which is a raw material, and many people feel that it is difficult to take.
そこで、豆乳が有する独特の青臭みを除去する方法として、特許文献1には、イオン交換樹脂または逆浸透膜を用いて、豆乳の青臭みを除去する方法が記載されている。しかし、このように物理的に成分を除去する方法では、豆乳に含まれる青臭み成分だけでなく、有用な成分など他の成分も除去される可能性がある。 Thus, as a method for removing the unique blue odor of soy milk, Patent Document 1 describes a method for removing the blue odor of soy milk using an ion exchange resin or a reverse osmosis membrane. However, in such a method of physically removing the components, not only the blue odor component contained in the soymilk but also other components such as useful components may be removed.
本発明の課題は、飲食物が本来有する成分に影響を及ぼさずに、飲食物のオフフレーバーを抑制することができるオフフレーバー抑制剤を提供することにある。 The subject of this invention is providing the off-flavor inhibitor which can suppress the off-flavor of food and drink, without affecting the ingredient which food and drink originally have.
本発明者は、上記課題を解決するべく鋭意検討を行った結果、以下の構成からなる解決手段を見出し、本発明を完成するに至った。
(1)イソブチルアンゲレートを有効成分として含有し、大豆、牛乳、果実類、野菜類および植物油からなる群より選択される少なくとも1種の食材を含む飲食品が有するオフフレーバーを抑制するためのオフフレーバー抑制剤。
(2)イソブチルアンゲレートが、ローマンカミツレ由来である上記(1)に記載のオフフレーバー抑制剤。
(3)大豆、牛乳、果実類、野菜類および植物油からなる群より選択される少なくとも1種の食材を含む飲食品と上記(1)または(2)に記載のオフフレーバー抑制剤とを含有し、オフフレーバー抑制剤が、イソブチルアンゲレートに換算して0.1〜2質量ppmの割合で含まれるオフフレーバー低減飲食品。
(4)大豆、牛乳、果実類、野菜類および植物油からなる群より選択される少なくとも1種の食材を含む飲食品に、イソブチルアンゲレートを0.1〜2質量ppmの割合で添加する飲食品のオフフレーバー抑制方法。
(5)イソブチルアンゲレートが、ローマンカミツレ由来である上記(4)に記載のオフフレーバー抑制方法。
As a result of intensive studies to solve the above-mentioned problems, the present inventor has found a means for solving the problems described below and has completed the present invention.
(1) To contain an isobutyl angelate as an active ingredient and to suppress off-flavor of a food or drink containing at least one food selected from the group consisting of soybean, milk, fruits, vegetables and vegetable oil Off-flavor inhibitor.
(2) The off-flavor inhibitor as described in (1) above, wherein the isobutyl angelate is derived from Roman chamomile.
(3) A food or drink containing at least one food selected from the group consisting of soybeans, milk, fruits, vegetables and vegetable oil, and the off-flavor inhibitor described in (1) or (2) above. The off-flavor reduced food / beverage product which contains an off-flavor inhibitor in the ratio of 0.1-2 mass ppm in terms of isobutyl angelate.
(4) Food and drink in which isobutyl angelate is added at a rate of 0.1 to 2 mass ppm to a food and drink containing at least one food selected from the group consisting of soybeans, milk, fruits, vegetables and vegetable oils For off-flavor control of products.
(5) The off-flavor suppression method according to (4), wherein the isobutyl angelate is derived from Roman chamomile.
本発明によれば、飲食物が本来有する成分に影響を及ぼさずに、飲食物のオフフレーバーを抑制することができるオフフレーバー抑制剤を提供することができる。さらに、本発明によれば、飲食物が本来有する成分に影響を及ぼさずにオフフレーバーが抑制されたオフフレーバー低減飲食品を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the off-flavor inhibitor which can suppress the off-flavor of food / beverage can be provided, without affecting the component which food / beverage originally has. Furthermore, according to this invention, the off-flavor reduced food-drinks by which the off-flavor was suppressed, without affecting the component which food and drink originally have can be provided.
本開示の一実施形態に係るオフフレーバー抑制剤は、イソブチルアンゲレートを有効成分として含有する。イソブチルアンゲレートはアンゲリカ酸エステルの1種であり、下記式(I)で示される構造を有する。 The off-flavor inhibitor according to an embodiment of the present disclosure contains isobutyl angelate as an active ingredient. Isobutyl angelate is one of angelic acid esters and has a structure represented by the following formula (I).
イソブチルアンゲレートは、化学合成によって得られたものであってもよく、天然物由来のものであってもよい。天然物由来の場合、ローマンカミツレ由来であることが好ましい。ローマンカミツレ(Anthemis nobilis)はキク科の多年生植物である。ローマンカミツレの精油および抽出物には、イソブチルアンゲレート、ブチルアンゲレート、イソプロピルアンゲレートなどが主成分として含まれる。 Isobutyl angelate may be obtained by chemical synthesis or derived from a natural product. When derived from a natural product, it is preferably derived from a Roman chamomile. Roman chamomile (Anthemis nobilis) is a perennial plant belonging to the family Asteraceae. The essential oil and extract of roman chamomile contain isobutyl angelate, butyl angelate, isopropyl angelate and the like as main components.
ローマンカミツレの精油は、ローマンカミツレを水蒸気蒸留、圧搾などに供することにより得られる。ローマンカミツレの部位は限定されず、花弁、葉、茎など全草を使用することができ、好ましくは花弁が使用される。 The essential oil of roman chamomile is obtained by subjecting the roman chamomile to steam distillation, pressing and the like. The site of the roman chamomile is not limited, and whole plants such as petals, leaves and stems can be used, and petals are preferably used.
ローマンカミツレの抽出物は、ローマンカミツレを水蒸気蒸留、還流抽出、常温ホモジナイズ抽出、超臨界流体抽出などに供することにより得られる。ローマンカミツレの部位は限定されず、精油と同様、全草を使用することができ、好ましくは花弁が使用される。還流抽出法のように溶媒を用いて抽出する場合、溶媒としては、例えば、アルコール類(メタノール、エタノールなどの低級アルコール、またはエチレングリコール、プロピレングリコール、1,3−ブチレングリコール、グリセリンなどの多価アルコール)、グリセリン脂肪酸エステル、アセトンなど比較的極性が高いケトン類、酢酸エチルなどのエステル類などの有機溶媒や、水などが挙げられる。 An extract of roman chamomile is obtained by subjecting roman chamomile to steam distillation, reflux extraction, room temperature homogenization extraction, supercritical fluid extraction, and the like. The site of the roman chamomile is not limited and, like the essential oil, whole grass can be used, and petals are preferably used. In the case of extraction using a solvent as in the reflux extraction method, examples of the solvent include alcohols (lower alcohols such as methanol and ethanol, or polyvalent such as ethylene glycol, propylene glycol, 1,3-butylene glycol, and glycerin). Alcohol), glycerol fatty acid ester, acetone having a relatively high polarity such as acetone, organic solvents such as esters such as ethyl acetate, water, and the like.
ローマンカミツレの精油および抽出物は、イソブチルアンゲレートを含有しているため、イソブチルアンゲレートとしてそのまま使用してもよい。あるいは、ローマンカミツレの精油および抽出物を精製して不純物を除去して使用してもよく、ローマンカミツレの精油および抽出物からイソブチルアンゲレートを単離して使用してもよい。 Since the essential oil and extract of Roman chamomile contain isobutyl angelate, they may be used as is as isobutyl angelate. Alternatively, the essential oil and extract of roman chamomile may be purified to remove impurities, and isobutyl angelate may be isolated and used from the essential oil and extract of roman chamomile.
一実施形態に係るオフフレーバー抑制剤には、本発明の効果を阻害しない範囲で、他の成分が含まれていてもよい。さらに、本開示の一実施形態に係るオフフレーバー抑制剤の形態は特に限定されず、例えば、液剤形態あるいは粉体形態にすることが可能である。 The off-flavor suppressing agent according to one embodiment may contain other components as long as the effects of the present invention are not impaired. Furthermore, the form of the off-flavor inhibitor according to an embodiment of the present disclosure is not particularly limited, and can be, for example, a liquid form or a powder form.
液剤形態として使用する場合、例えばイソブチルアンゲレートを、溶剤で希釈すればよい。希釈に使用される溶剤としては、例えば、水、エタノール、グリセリン、プロピレングリコール、トリアセチン、中鎖脂肪酸トリグリセリド、食用油脂、動植物油脂などが挙げられる。さらに、付加的成分または他の有効成分と組み合わせて合剤にすることができる。例えば、公知の各種天然香料、合成香料などと組み合わせて使用することもできる。 When used as a liquid form, for example, isobutyl angelate may be diluted with a solvent. Examples of the solvent used for dilution include water, ethanol, glycerin, propylene glycol, triacetin, medium chain fatty acid triglyceride, edible oil and fat, animal and vegetable oil and fat. Furthermore, it can be combined with additional ingredients or other active ingredients. For example, it can also be used in combination with various known natural and synthetic fragrances.
さらに、一実施形態に係るオフフレーバー抑制剤は、賦形剤(デキストリン、アラビアガム、乳糖など)や上記の溶剤を添加し、噴霧乾燥により粉末状あるいは顆粒状に、凍結乾燥または加熱乾燥により固形剤として使用することが可能であり、用途に応じて種々の剤形を採用することができる。 Further, the off-flavor suppressant according to one embodiment includes an excipient (dextrin, gum arabic, lactose, etc.) and the above-mentioned solvent, and is solidified by spray drying or powdered or granulated, and freeze-dried or heat-dried. It can be used as an agent, and various dosage forms can be employed depending on the application.
一実施形態に係るオフフレーバー抑制剤が対象とする飲食品は、大豆、牛乳、果実類、野菜類および植物油からなる群より選択される少なくとも1種の食材(以下、「特定の食材」と記載する場合がある)を含む飲食品である。特定の食材のうち、大豆は青臭い大豆臭を有し、牛乳は独特の牛乳臭を有している。そのため、大豆または牛乳を含む飲食品は、これらの食材に由来する独特の風味を有することがある。 The food or drink targeted by the off-flavor inhibitor according to one embodiment is at least one food selected from the group consisting of soybeans, milk, fruits, vegetables and vegetable oil (hereinafter referred to as “specific food”). Food and drinks including Of the specific ingredients, soy has a blue-smelling soy odor and milk has a unique milk odor. Therefore, food and drink containing soy or milk may have a unique flavor derived from these ingredients.
一方、果実類、野菜類および植物油は、酸素、光、紫外線、温度などの影響によって、例えば、含まれる成分が酸化されたり分解されたりして変質することがある。そのため、これらの食材を含む飲食品は、変質により生じる特異な風味を有することがある。 On the other hand, fruits, vegetables, and vegetable oils may be altered by the effects of oxygen, light, ultraviolet rays, temperature, etc., for example, by oxidizing or decomposing the contained components. Therefore, foods and drinks containing these ingredients may have a unique flavor caused by alteration.
果実類としては、例えば下記に示す果実が挙げられる。
柑橘類果実:レモン、オレンジ、グレープフルーツ、ライム、柚子、ミカン、カボス、すだち、シークワシャー、キンカンなど。
仁果類果実:リンゴ、梨、カリン、マルメロなど。
核果類果実:桃、梅、サクランボ、杏など。
ブドウ類:巨峰、マスカットなど。
熱帯果実:パイナップル、バナナ、マンゴー、パパイヤ、パッションフルーツなど。
ベリー類:苺、ブルーベリー、クランベリー、ラズベリーなど。
種実類:アーモンド、落花生、カシューナッツ、ヘーゼルナッツ、ピスタチオ、マカダミアナッツなど。
その他:メロン、スイカなど。
Examples of fruits include the fruits shown below.
Citrus fruits: lemon, orange, grapefruit, lime, eggplant, mandarin orange, kabosu, sudachi, shikwasha, kumquat, etc.
Pear fruit: apple, pear, karin, quince etc.
Nucleus fruit: peach, plum, cherry, apricot, etc.
Grapes: Kyoho, Muscat, etc.
Tropical fruits: pineapple, banana, mango, papaya, passion fruit, etc.
Berries: strawberry, blueberry, cranberry, raspberry, etc.
Seeds: almonds, peanuts, cashews, hazelnuts, pistachios, macadamia nuts, etc.
Other: Melon, watermelon, etc.
野菜類としては、例えば下記に示す野菜が挙げられる。
果菜類:ナス、トマト、ピーマン、かぼちゃ、きゅうり、唐辛子、トウモロコシ、グリーンピースなど。
葉菜類:キャベツ、メキャベツ、紫キャベツ、ケール、セロリ、ニラ、白菜、パセリ、ほうれん草、レタス、赤ジソ、ビート、アシタバ、チンゲンサイ、クレソン、小松菜など。
茎菜類:アスパラガス、たけのこ、ニンニク、ネギ、タマネギなど。
根菜類:大根、カブ、わさび、ゴボウ、生姜、ニンジン、レンコン、イモ類など。
花菜類:ブロッコリー、カリフラワーなど。
豆類:小豆、えんどう、そらまめ、大豆、緑豆など。
Examples of vegetables include the following vegetables.
Fruits and vegetables: eggplant, tomato, pepper, pumpkin, cucumber, chili, corn, green peas, etc.
Leafy vegetables: cabbage, me cabbage, purple cabbage, kale, celery, leek, Chinese cabbage, parsley, spinach, lettuce, red gizzard, beet, ashitaba, chingensai, watercress, komatsuna.
Stem vegetables: asparagus, bamboo shoots, garlic, leeks, onions, etc.
Root vegetables: radish, turnip, wasabi, burdock, ginger, carrot, lotus root, potatoes, etc.
Flower vegetables: broccoli, cauliflower, etc.
Beans: red beans, peas, broad beans, soybeans, mung beans, etc.
植物油としては、例えば、大豆油、サフラワー油、コーン油、菜種油、ヒマワリ油、落花生油、綿実油、オリーブ油、米油、パーム油などが挙げられる。 Examples of vegetable oils include soybean oil, safflower oil, corn oil, rapeseed oil, sunflower oil, peanut oil, cottonseed oil, olive oil, rice oil, palm oil, and the like.
特定の食材を含む飲食品としては、具体的には、豆乳、調製豆乳、大豆タンパク加工品、乳飲料、乳酸菌飲料、乳製品(例えば、ヨーグルト、チーズなど)、加工油脂(例えば、バター、マーガリン、ファットスプレッド、ショートニングなど)、果実ジュース、果実ミックスジュース、野菜ジュース、果実・野菜ミックスジュース、果汁入り飲料、菓子類(例えば、ソフトキャンディー、グミなど)大豆油など上記の植物油やこれらの植物油を含む飲食品(例えば、揚げ物など)などが挙げられる。 Specific examples of foods and drinks containing specific ingredients include soy milk, prepared soy milk, processed soy protein products, milk beverages, lactic acid bacteria beverages, dairy products (eg, yogurt, cheese, etc.), processed oils and fats (eg, butter, margarine). , Fat spread, shortening, etc.) Fruit juice, fruit mix juice, vegetable juice, fruit / vegetable mix juice, fruit juice drink, confectionery (eg, soft candy, gummy, etc.) Examples of foods and drinks to be included (for example, fried foods).
本開示の一実施形態に係るオフフレーバー抑制剤は、上述の特定の食材を含む飲食品に添加して使用される。オフフレーバー抑制剤の添加量は、飲食品中に含まれる特定の食材の種類や量に応じて適宜設定される。オフフレーバー抑制剤はイソブチルアンゲレートに換算して、飲食品中に通常0.1〜2質量ppm程度、好ましくは0.5〜1質量ppm程度の濃度となるように添加される。 The off-flavor inhibitor according to an embodiment of the present disclosure is used by being added to a food or drink containing the above-described specific food. The addition amount of an off-flavor inhibitor is appropriately set according to the type and amount of a specific food contained in the food or drink. The off-flavor inhibitor is added to the food or drink so that the concentration is usually about 0.1 to 2 ppm by mass, preferably about 0.5 to 1 ppm by mass, in terms of isobutyl angelate.
オフフレーバー抑制剤を添加するタイミングは特に限定されない。例えば、特定の食材を含む飲食品の製造工程中に添加してもよく、製造後に添加してもよく、オフフレーバーを感じるようになった後に添加してもよい。 The timing at which the off-flavor inhibitor is added is not particularly limited. For example, you may add during the manufacturing process of the food / beverage products containing a specific foodstuff, may add after manufacture, and may add after it comes to feel an off-flavor.
本開示の一実施形態に係るオフフレーバー抑制剤を、独特な風味や特異な風味であるオフフレーバーを有する飲食品に添加することによって、飲食物が本来有する成分に影響を及ぼさずにオフフレーバーが抑制されたオフフレーバー低減飲食品が得られる。本開示の一実施形態に係るオフフレーバー抑制剤は、例えば、食品産業分野などにおいて好適に使用される。 By adding the off-flavor inhibitor according to one embodiment of the present disclosure to a food or drink having an off-flavor that has a unique flavor or a unique flavor, the off-flavor can be obtained without affecting the ingredients that the food or drink originally has. Suppressed off-flavor reduced food or drink is obtained. The off-flavor suppressant according to an embodiment of the present disclosure is suitably used, for example, in the food industry field.
以下、実施例および比較例を挙げて本発明を具体的に説明するが、本発明はこれらの実施例に限定されるものではない。 EXAMPLES Hereinafter, although an Example and a comparative example are given and this invention is demonstrated concretely, this invention is not limited to these Examples.
(調製例1)
0.1gのイソブチルアンゲレートを、プロピレングリコールで希釈して、総量を100gとした。得られた溶液に含まれるイソブチルアンゲレートの濃度は1000質量ppmである。
(Preparation Example 1)
0.1 g of isobutyl angelate was diluted with propylene glycol to make a total amount of 100 g. The concentration of isobutyl angelate contained in the obtained solution is 1000 mass ppm.
(調製例2)
0.35gのローマンカミツレ精油を、プロピレングリコールで希釈して、総量を100gとした。使用したローマンカミツレ精油に含まれるアンゲリカ酸エステルは下記のとおりであり、ローマンカミツレ精油中に28.5質量%のイソブチルアンゲレートが含まれていた。得られた溶液に含まれるイソブチルアンゲレートの濃度は約997質量ppmである。
プロピルアンゲレート:2.9質量%
イソブチルアンゲレート:28.5質量%
2−メチル−2−ブチルアンゲレート:1.5質量%
ブチルアンゲレート:微量
tert−ブチルアンゲレート:微量
(Preparation Example 2)
0.35 g of Roman chamomile essential oil was diluted with propylene glycol to make a total amount of 100 g. The angelic acid ester contained in the used roman chamomile essential oil was as follows, and 28.5 mass% isobutyl angelate was contained in the roman chamomile essential oil. The concentration of isobutyl angelate contained in the obtained solution is about 997 mass ppm.
Propyl angelate: 2.9% by mass
Isobutyl angelate: 28.5% by mass
2-Methyl-2-butyl angelate: 1.5% by mass
Butyl angelate: Trace amount
tert-Butyl angelate: Trace amount
(実施例1:無調整豆乳)
市販の無調整豆乳(タンパク質を約9.1質量%、脂質を約7.3質量%、および炭水化物を約3.2質量%の割合で含む)に、調製例1で得られた溶液を0.1質量%の割合で添加した。無調整豆乳に添加されたイソブチルアンゲレートの濃度は1質量ppmであった。イソブチルアンゲレートが添加された無調整豆乳の風味について、下記の方法で評価した。結果を表1に示す。
(Example 1: Unadjusted soymilk)
The solution obtained in Preparation Example 1 was added to commercially available unadjusted soymilk (containing about 9.1% by mass of protein, about 7.3% by mass of lipid, and about 3.2% by mass of carbohydrate). .1% by mass was added. The concentration of isobutyl angelate added to unadjusted soymilk was 1 ppm by mass. The flavor of unadjusted soymilk to which isobutyl angelate was added was evaluated by the following method. The results are shown in Table 1.
7名のパネラーに(20代、30代、40代、50代および60代の男性各1名、ならびに20代および30代の女性各1名)、無調整豆乳(無添加品)を試飲してもらった。次いで、7名のパネラーに口内を十分に洗浄してもらい、イソブチルアンゲレートが添加された無調整豆乳(添加品)を試飲してもらった。無添加品と添加品とを比較して、無調整豆乳のオフフレーバー(大豆由来の青臭みおよびグリーン臭)が改善されているか否かを、下記の基準で評価してもらった。「青臭み」とは、例えば若い雑草などをすり潰した際に感じる強い草の臭気であり、「グリーン臭」とは、緑色野菜を食した際に感じる青臭みほど強くない(青臭みよりは爽やかな)臭気である。7名のパネラーの合計点が10点以上の場合、オフフレーバーが改善されていると評価した。
2点:オフフレーバーを感じない、あるいは明らかにオフフレーバーが改善されている場合。
1点:若干オフフレーバーを感じるものの、無添加品よりは改善されている場合。
0点:オフフレーバーが改善されておらず、無添加品と差がない場合。
7 panelists (1 male each in their 20s, 30s, 40s, 50s and 60s, and 1 female each in their 20s and 30s) tasting unadjusted soymilk (no additives) I got it. Next, seven panelists thoroughly cleaned their mouths and sampled unadjusted soymilk (added product) to which isobutyl angelate was added. By comparing the additive-free product with the additive-free product, whether or not the off-flavor of unadjusted soymilk (soybean-derived blue odor and green odor) was improved was evaluated according to the following criteria. “Blue odor” is a strong grass odor that is felt when mashing young weeds, for example. “Green odor” is not as strong as the blue odor that is felt when eating green vegetables (fresher than blue odor) It ’s an odor. When the total score of 7 panelists was 10 or more, it was evaluated that the off-flavor was improved.
2 points: When off-flavor is not felt or when off-flavor is clearly improved.
1 point: A slight off-flavor is felt, but it is improved over the additive-free product.
0 point: When the off-flavor is not improved and there is no difference from the additive-free product.
(実施例2:無調整豆乳)
実施例1で用いた無調整豆乳に、調製例2で得られた溶液を0.1質量%の割合で添加した。無調整豆乳に添加されたイソブチルアンゲレートの濃度は約0.997質量ppmであった。無調整豆乳(無添加品)とイソブチルアンゲレートが添加された無調整豆乳(添加品)とを比較して、実施例1と同様の方法で評価した。結果を表1に示す。
(Example 2: Unadjusted soymilk)
To the unadjusted soymilk used in Example 1, the solution obtained in Preparation Example 2 was added at a ratio of 0.1% by mass. The concentration of isobutyl angelate added to unadjusted soymilk was about 0.997 ppm by mass. Non-adjusted soymilk (additive-free product) and non-adjusted soymilk (added product) to which isobutyl angelate was added were compared and evaluated in the same manner as in Example 1. The results are shown in Table 1.
(実施例3:調整豆乳)
市販の調整豆乳に、調製例1で得られた溶液を0.1質量%の割合で添加した。調整豆乳には、原料として無調整豆乳、砂糖、米油、食塩、乳酸カルシウム、乳化剤、糊料および香料が含まれていた。調整豆乳に添加されたイソブチルアンゲレートの濃度は1質量ppmであった。イソブチルアンゲレートが添加された調整豆乳の風味について、下記の方法で評価した。結果を表1に示す。
(Example 3: adjusted soy milk)
The solution obtained in Preparation Example 1 was added to commercially available prepared soymilk at a ratio of 0.1% by mass. The adjusted soymilk contained unadjusted soymilk, sugar, rice oil, salt, calcium lactate, emulsifier, paste and flavor as raw materials. The concentration of isobutyl angelate added to the conditioned soymilk was 1 ppm by mass. The flavor of the adjusted soymilk to which isobutyl angelate was added was evaluated by the following method. The results are shown in Table 1.
上記7名のパネラーに、調整豆乳(無添加品)を試飲してもらった。次いで、7名のパネラーに口内を十分に洗浄してもらい、イソブチルアンゲレートが添加された調整豆乳(添加品)を試飲してもらった。無添加品と添加品とを比較して、調整豆乳のオフフレーバー(香料で若干マスキングされているものの、後味として残る大豆由来のグリーン臭および豆臭)が改善されているか否かを、上述の実施例1と同様の基準で評価してもらった。7名のパネラーの合計点が10点以上の場合、オフフレーバーが改善されていると評価した。 The above seven panelists sampled the adjusted soymilk (additive-free product). Next, seven panelists thoroughly cleaned their mouths and sampled the adjusted soymilk (added product) to which isobutyl angelate was added. By comparing the additive-free product with the additive product, whether or not the off-flavor of the adjusted soymilk (green odor and bean odor derived from soybean that remains as a aftertaste, although slightly masked with a fragrance) has been improved as described above. The evaluation was made based on the same criteria as in Example 1. When the total score of 7 panelists was 10 or more, it was evaluated that the off-flavor was improved.
(実施例4:調整豆乳)
実施例2で用いた調整豆乳に、調製例2で得られた溶液を0.1質量%の割合で添加した。調整豆乳に添加されたイソブチルアンゲレートの濃度は約0.997質量ppmであった。調整豆乳(無添加品)とイソブチルアンゲレートが添加された調整豆乳(添加品)とを比較して、実施例3と同様の方法で評価した。結果を表1に示す。
(Example 4: adjusted soy milk)
To the prepared soymilk used in Example 2, the solution obtained in Preparation Example 2 was added at a ratio of 0.1% by mass. The concentration of isobutyl angelate added to the conditioned soymilk was about 0.997 mass ppm. The adjusted soymilk (additive-free product) and the adjusted soymilk (added product) to which isobutyl angelate was added were compared and evaluated in the same manner as in Example 3. The results are shown in Table 1.
(実施例5:大豆油)
市販の大豆油に、調製例1で得られた溶液を0.1質量%の割合で添加した。大豆油に添加されたイソブチルアンゲレートの濃度は1質量ppmであった。イソブチルアンゲレートが添加された大豆油の風味について、下記の方法で評価した。結果を表1に示す。
(Example 5: Soybean oil)
To the commercially available soybean oil, the solution obtained in Preparation Example 1 was added at a ratio of 0.1% by mass. The concentration of isobutyl angelate added to soybean oil was 1 ppm by mass. The flavor of soybean oil to which isobutyl angelate was added was evaluated by the following method. The results are shown in Table 1.
上記7名のパネラーに、大豆油(無添加品)を試飲してもらった。次いで、7名のパネラーに口内を十分に洗浄してもらい、イソブチルアンゲレートが添加された大豆油(添加品)を試飲してもらった。無添加品と添加品とを比較して、大豆油のオフフレーバー(植物油特有の青臭みおよびグリーン臭)が改善されているか否かを、上述の実施例1と同様の基準で評価してもらった。7名のパネラーの合計点が10点以上の場合、オフフレーバーが改善されていると評価した。 The above seven panelists sampled soybean oil (no additives). Next, seven panelists thoroughly washed their mouths and sampled soybean oil (added product) to which isobutyl angelate was added. By comparing the additive-free product with the additive product, whether or not the off-flavor of soybean oil (green odor and green odor peculiar to vegetable oil) has been improved is evaluated based on the same criteria as in Example 1 above. It was. When the total score of 7 panelists was 10 or more, it was evaluated that the off-flavor was improved.
(実施例6:大豆油)
実施例5で用いた大豆油に、調製例2で得られた溶液を0.1質量%の割合で添加した。大豆油に添加されたイソブチルアンゲレートの濃度は約0.997質量ppmであった。大豆油(無添加品)とイソブチルアンゲレートが添加された大豆油(添加品)とを比較して、実施例5と同様の方法で評価した。結果を表1に示す。
(Example 6: soybean oil)
The solution obtained in Preparation Example 2 was added to the soybean oil used in Example 5 at a ratio of 0.1% by mass. The concentration of isobutyl angelate added to soybean oil was about 0.997 ppm by mass. Soybean oil (additive-free product) was compared with soybean oil (added product) to which isobutyl angelate was added, and evaluated in the same manner as in Example 5. The results are shown in Table 1.
(実施例7:綿実油)
実施例5で用いた大豆油の代わりに市販の綿実油を用いた以外は、実施例5と同様の手順で綿実油のオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。結果を表1に示す。
(Example 7: Cottonseed oil)
The above seven panelists evaluated whether or not the off-flavor of cottonseed oil was improved in the same procedure as in Example 5 except that a commercially available cottonseed oil was used instead of the soybean oil used in Example 5. received. The results are shown in Table 1.
(実施例8:綿実油)
実施例6で用いた大豆油の代わりに市販の綿実油を用いた以外は、実施例6と同様の手順で綿実油のオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。結果を表1に示す。
(Example 8: Cottonseed oil)
The above seven panelists evaluated whether or not the off-flavor of cottonseed oil was improved in the same procedure as in Example 6 except that a commercially available cottonseed oil was used instead of the soybean oil used in Example 6. received. The results are shown in Table 1.
(実施例9:菜種油)
実施例5で用いた大豆油の代わりに市販の菜種油を用いた以外は、実施例5と同様の手順で菜種油のオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。結果を表1に示す。
(Example 9: rapeseed oil)
Except for using commercially available rapeseed oil in place of the soybean oil used in Example 5, whether or not the rapeseed oil off-flavor was improved by the same procedure as in Example 5 was evaluated by the above seven panelists. received. The results are shown in Table 1.
(実施例10:菜種油)
実施例6で用いた大豆油の代わりに市販の菜種油を用いた以外は、実施例6と同様の手順で菜種油のオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。結果を表1に示す。
(Example 10: rapeseed oil)
Except for using commercially available rapeseed oil in place of the soybean oil used in Example 6, the above seven panelists evaluated whether the rapeseed oil off-flavor had been improved in the same procedure as in Example 6. received. The results are shown in Table 1.
(実施例11:ヒマワリ油)
実施例5で用いた大豆油の代わりに市販のヒマワリ油を用いた以外は、実施例5と同様の手順でヒマワリ油のオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。結果を表1に示す。
(Example 11: sunflower oil)
The above seven panelists evaluated whether or not the sunflower oil off-flavor was improved in the same procedure as in Example 5 except that a commercially available sunflower oil was used instead of the soybean oil used in Example 5. I was asked to. The results are shown in Table 1.
(実施例12:ヒマワリ油)
実施例6で用いた大豆油の代わりに市販のヒマワリ油を用いた以外は、実施例6と同様の手順でヒマワリ油のオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。結果を表1に示す。
(Example 12: sunflower oil)
The above seven panelists evaluated whether or not the sunflower oil off-flavor was improved in the same procedure as in Example 6 except that a commercially available sunflower oil was used instead of the soybean oil used in Example 6. I was asked to. The results are shown in Table 1.
(実施例13:菜種白絞油)
実施例5で用いた大豆油の代わりに市販の菜種白絞油を用いた以外は、実施例5と同様の手順で菜種白絞油のオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。結果を表1に示す。
(Example 13: Rapeseed white squeezed oil)
Whether or not the off-flavor of rapeseed white squeezed oil was improved in the same procedure as in Example 5 except that a commercially available rapeseed white squeezed oil was used instead of the soybean oil used in Example 5, Was evaluated by the panelists. The results are shown in Table 1.
(実施例14:菜種白絞油)
実施例6で用いた大豆油の代わりに市販の菜種白絞油を用いた以外は、実施例6と同様の手順で菜種白絞油のオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。結果を表1に示す。
(Example 14: Rapeseed white oil)
Whether or not the off-flavor of rapeseed white squeezed oil was improved in the same procedure as in Example 6 except that a commercially available rapeseed white squeezed oil was used instead of the soybean oil used in Example 6, the above seven Was evaluated by the panelists. The results are shown in Table 1.
(実施例15:マーガリン)
市販のマーガリン(コーン油を70質量%含み、油脂を合計で80質量%以上含む)に、調製例1で得られた溶液を0.1質量%の割合で添加した。マーガリンには、原料としてコーン油、食用精製加工油脂、ホエーパウダー、食塩、乳化剤、香料および着色料が含まれていた。マーガリンに添加されたイソブチルアンゲレートの濃度は1質量ppmであった。イソブチルアンゲレートが添加されたマーガリンの風味について、下記の方法で評価した。結果を表1に示す。
(Example 15: Margarine)
The solution obtained in Preparation Example 1 was added at a ratio of 0.1% by mass to commercially available margarine (containing 70% by mass of corn oil and 80% by mass or more of fats and oils in total). Margarine contained corn oil, edible refined processed fats and oils, whey powder, salt, emulsifier, flavoring and coloring as raw materials. The concentration of isobutyl angelate added to margarine was 1 mass ppm. The flavor of margarine to which isobutyl angelate was added was evaluated by the following method. The results are shown in Table 1.
上記7名のパネラーに、マーガリン(無添加品)を試食してもらった。次いで、7名のパネラーに口内を十分に洗浄してもらい、イソブチルアンゲレートが添加されたマーガリン(添加品)を試食してもらった。無添加品と添加品とを比較して、マーガリンのオフフレーバー(植物油特有の青臭み、グリーン臭、ならびに植物油および香料の金属的酸化臭)が改善されているか否かを、上述の実施例1と同様の基準で評価してもらった。7名のパネラーの合計点が10点以上の場合、オフフレーバーが改善されていると評価した。 The above seven panelists tried margarine (without additives). Next, 7 panelists thoroughly cleaned their mouths and tried margarine (added product) to which isobutyl angelate was added. Whether or not margarine off-flavor (vegetable oil-specific blue odor, green odor and metallic oxidation odor of vegetable oil and fragrance) is improved by comparing the additive-free product with the additive-free product is described in Example 1 above. And evaluated on the same criteria. When the total score of 7 panelists was 10 or more, it was evaluated that the off-flavor was improved.
(実施例16:マーガリン)
実施例15で用いたマーガリンに、調製例2で得られた溶液を0.1質量%の割合で添加した。マーガリンに添加されたイソブチルアンゲレートの濃度は約0.997質量ppmであった。マーガリン(無添加品)とイソブチルアンゲレートが添加されたマーガリン(添加品)とを比較して、実施例15と同様の方法で評価した。結果を表1に示す。
(Example 16: Margarine)
To the margarine used in Example 15, the solution obtained in Preparation Example 2 was added at a ratio of 0.1% by mass. The concentration of isobutyl angelate added to margarine was about 0.997 ppm by mass. Margarine (additive-free product) and margarine (added product) to which isobutyl angelate was added were compared and evaluated in the same manner as in Example 15. The results are shown in Table 1.
(実施例17:マーガリン)
実施例15で用いたマーガリンの代わりに別の市販のマーガリン(油脂を合計で80質量%含む)を用いた以外は、実施例15と同様の手順でマーガリンのオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。このマーガリンには、原料として食用精製加工油脂、大豆油、パーム油、脱脂粉乳、乳化剤および香料が含まれていた。結果を表1に示す。
(Example 17: Margarine)
Whether margarine off-flavor was improved in the same procedure as in Example 15 except that another commercially available margarine (containing a total of 80% by mass of fats and oils) was used instead of the margarine used in Example 15. Was evaluated by the above seven panelists. This margarine contained edible refined processed fats and oils, soybean oil, palm oil, skim milk powder, emulsifiers and fragrances as raw materials. The results are shown in Table 1.
(実施例18:マーガリン)
実施例16で用いたマーガリンの代わりに実施例17で用いたマーガリンを用いた以外は、実施例16と同様の手順でマーガリンのオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。結果を表1に示す。
(Example 18: Margarine)
Except for using the margarine used in Example 17 instead of the margarine used in Example 16, whether or not the margarine off-flavor was improved by the same procedure as in Example 16 was evaluated to the above seven panelists. We had you evaluate. The results are shown in Table 1.
(実施例19:ファットスプレッド)
実施例15で用いたマーガリンの代わりに市販のファットスプレッド(油脂を合計で65質量%含む)を用いた以外は、実施例15と同様の手順でファットスプレッドのオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。このファットスプレッドには、原料として菜種油、コーン油、食用精製加工油脂、食塩、ホエーパウダー、乳化剤、香料および着色料が含まれていた。マーガリンとファットスプレッドとの違いは油脂の含有量であり、マーガリンの油脂含有量は80質量%以上であり、ファットスプレッドの油脂含有量は80質量%未満である。結果を表1に示す。
(Example 19: Fat spread)
Whether or not the fat spread off-flavor is improved in the same procedure as in Example 15 except that a commercially available fat spread (containing 65% by mass of fats and oils) is used instead of the margarine used in Example 15. Was evaluated by the above seven panelists. This fat spread contained rapeseed oil, corn oil, edible refined processed oil, salt, whey powder, emulsifier, flavoring and coloring as raw materials. The difference between margarine and fat spread is the fat content, the fat content of margarine is 80% by mass or more, and the fat content of fat spread is less than 80% by mass. The results are shown in Table 1.
(実施例20:ファットスプレッド)
実施例16で用いたマーガリンの代わりに実施例19で用いたファットスプレッドを用いた以外は、実施例16と同様の手順でファットスプレッドのオフフレーバーが改善されているか否かを、上記7名のパネラーに評価してもらった。結果を表1に示す。
(Example 20: Fat spread)
Whether or not the fat spread off-flavor was improved in the same procedure as in Example 16 except that the fat spread used in Example 19 was used instead of the margarine used in Example 16, the above seven persons The panelist evaluated it. The results are shown in Table 1.
(実施例21:牛乳を含むコーヒー飲料(乳飲料))
牛乳を含むコーヒー飲料(乳飲料)について、オフフレーバーが改善されているか否かを検証するために、試験用の乳飲料を次のように調製した。661.6gのコーヒー抽出物(固形分濃度17.2質量%)、450gの牛乳、103gのグラニュー糖、3gの重曹、2gのカゼインナトリウム、および2gの乳化剤を混合して、十分に撹拌した。次いで、得られた混合物にイオン交換水を加えて、全量を2000mLにした。次いで、調製例1で得られた溶液を0.1質量%の割合で添加して缶容器に200mLずつ詰め、123℃で20分間殺菌処理を行って試験用の乳飲料を得た。
(Example 21: Coffee drink containing milk (milk drink))
In order to verify whether or not the off-flavor is improved for a coffee beverage (milk beverage) containing milk, a test milk beverage was prepared as follows. 661.6 g of coffee extract (solid content 17.2% by weight), 450 g of milk, 103 g of granulated sugar, 3 g of sodium bicarbonate, 2 g of sodium caseinate, and 2 g of emulsifier were mixed and stirred thoroughly. Subsequently, ion exchange water was added to the resulting mixture to make the total volume 2000 mL. Next, the solution obtained in Preparation Example 1 was added at a ratio of 0.1% by mass, and 200 mL each was packed in a can, and sterilized at 123 ° C. for 20 minutes to obtain a test milk beverage.
試験用の乳飲料に添加されたイソブチルアンゲレートの濃度は1質量ppmであった。イソブチルアンゲレートが添加された試験用の乳飲料の風味について、下記の方法で評価した。結果を表1に示す。 The concentration of isobutyl angelate added to the test milk beverage was 1 ppm by mass. The flavor of the test milk beverage to which isobutyl angelate was added was evaluated by the following method. The results are shown in Table 1.
上記7名のパネラーに、イソブチルアンゲレート添加しなかった以外は同様の手順で調製した乳飲料(無添加品)を試飲してもらった。次いで、7名のパネラーに口内を十分に洗浄してもらい、イソブチルアンゲレートが添加された試験用の乳飲料(添加品)を試飲してもらった。無添加品と添加品とを比較して、試験用の乳飲料のオフフレーバー(乳由来の生臭みおよびケモノ臭)が改善されているか否かを、上述の実施例1と同様の基準で評価してもらった。7名のパネラーの合計点が10点以上の場合、オフフレーバーが改善されていると評価した。 The seven panelists were asked to sample milk beverages (additive-free products) prepared in the same manner except that isobutyl angelate was not added. Next, seven panelists thoroughly cleaned their mouths and sampled a test milk beverage (added product) to which isobutyl angelate was added. By comparing the additive-free product with the additive product, whether or not the off-flavor (milk-derived odor and furry odor) of the test milk beverage is improved is evaluated based on the same criteria as in Example 1 above. I was asked to. When the total score of 7 panelists was 10 or more, it was evaluated that the off-flavor was improved.
(実施例22:牛乳を含むコーヒー飲料(乳飲料))
調製例1で得られた溶液の代わりに、調製例2で得られた溶液を0.1質量%の割合で添加した以外は、実施例21と同様の手順で試験用の乳飲料を得た。得られた試験用の乳飲料に添加されたイソブチルアンゲレートの濃度は約0.997質量ppmであった。イソブチルアンゲレートを含まない乳飲料(無添加品)とイソブチルアンゲレートが添加された試験用の乳飲料(添加品)とを比較して、実施例21と同様の方法で評価した。結果を表1に示す。
(Example 22: Coffee drink containing milk (milk drink))
A milk drink for testing was obtained in the same procedure as in Example 21, except that the solution obtained in Preparation Example 2 was added at a ratio of 0.1% by mass instead of the solution obtained in Preparation Example 1. . The concentration of isobutyl angelate added to the test milk beverage obtained was about 0.997 ppm by mass. A milk beverage not containing isobutyl angelate (additive-free product) was compared with a test milk beverage (added product) added with isobutyl angelate, and evaluated in the same manner as in Example 21. The results are shown in Table 1.
(実施例23:野菜ジュース)
市販の野菜ミックスジュースに、調製例1で得られた溶液を0.1質量%の割合で添加した。野菜ミックスジュースには、原料としてトマト、ニンジン、メキャベツ、ケール、ピーマン、ビート、ホウレン草、ブロッコリー、アシタバ、チンゲンサイ、小松菜、カボチャ、パセリ、クレソン、アスパラガス、セロリ、ショウガ、トウモロコシ、ゴボウ、グリーンピース、紫イモ、キャベツ、レタス、タマネギ、ダイコン、紫キャベツ、赤シソ、カリフラワー、ナス、白菜、およびレモンが含まれていた。野菜ミックスジュースに添加されたイソブチルアンゲレートの濃度は1質量ppmであった。イソブチルアンゲレートが添加された野菜ミックスジュースの風味について、下記の方法で評価した。結果を表1に示す。
(Example 23: Vegetable juice)
The solution obtained in Preparation Example 1 was added to a commercially available vegetable mix juice at a ratio of 0.1% by mass. Vegetable mix juice includes tomato, carrot, cabbage, kale, pepper, beet, spinach, broccoli, ashitaba, chingensai, komatsuna, pumpkin, parsley, watercress, asparagus, celery, ginger, corn, burdock, green peas, Purple potato, cabbage, lettuce, onion, radish, purple cabbage, red perilla, cauliflower, eggplant, Chinese cabbage, and lemon were included. The concentration of isobutyl angelate added to the vegetable mix juice was 1 ppm by mass. The flavor of the vegetable mixed juice to which isobutyl angelate was added was evaluated by the following method. The results are shown in Table 1.
上記7名のパネラーに、野菜ミックスジュース(無添加品)を試飲してもらった。次いで、7名のパネラーに口内を十分に洗浄してもらい、イソブチルアンゲレートが添加された野菜ミックスジュース(添加品)を試飲してもらった。無添加品と添加品とを比較して、野菜ミックスジュースのオフフレーバー(野菜独特のむれた風味、青臭みおよびグリーン臭)が改善されているか否かを、上述の実施例1と同様の基準で評価してもらった。7名のパネラーの合計点が10点以上の場合、オフフレーバーが改善されていると評価した。 The above seven panelists had a sample of mixed vegetable juice (without additives). Next, 7 panelists thoroughly cleaned their mouths and sampled the mixed vegetable juice (added product) to which isobutyl angelate was added. Whether the additive-free product is compared with the additive product or not, whether the off-flavor (vegetable peculiar flavor, blue odor and green odor unique to the vegetable) is improved is the same standard as in Example 1 above. We had you evaluate in. When the total score of 7 panelists was 10 or more, it was evaluated that the off-flavor was improved.
(実施例24:野菜ミックスジュース)
実施例23で用いた野菜ミックスジュースに、調製例2で得られた溶液を0.1質量%の割合で添加した。野菜ミックスジュースに添加されたイソブチルアンゲレートの濃度は約0.997質量ppmであった。野菜ミックスジュース(無添加品)とイソブチルアンゲレートが添加された野菜ミックスジュース(添加品)とを比較して、実施例23と同様の方法で評価した。結果を表1に示す。
(Example 24: Vegetable mix juice)
The solution obtained in Preparation Example 2 was added to the vegetable mix juice used in Example 23 at a ratio of 0.1% by mass. The concentration of isobutyl angelate added to the vegetable mix juice was about 0.997 ppm by mass. The vegetable mix juice (additive product) and the vegetable mix juice (addition product) to which isobutyl angelate was added were compared and evaluated in the same manner as in Example 23. The results are shown in Table 1.
(実施例25:オレンジジュース)
市販のオレンジジュース(濃縮還元)に、調製例1で得られた溶液を0.05質量%の割合で添加した。オレンジジュースには、原料として濃縮オレンジジュースおよび香料が使用されていた。
オレンジジュースに添加されたイソブチルアンゲレートの濃度は0.5質量ppmであった。イソブチルアンゲレートが添加されたオレンジジュースの風味について、下記の方法で評価した。結果を表1に示す。
(Example 25: Orange juice)
To the commercially available orange juice (concentrated and reduced), the solution obtained in Preparation Example 1 was added at a ratio of 0.05% by mass. In orange juice, concentrated orange juice and flavor were used as raw materials.
The concentration of isobutyl angelate added to the orange juice was 0.5 mass ppm. The flavor of orange juice to which isobutyl angelate was added was evaluated by the following method. The results are shown in Table 1.
上記7名のパネラーに、オレンジジュース(無添加品)を試飲してもらった。次いで、7名のパネラーに口内を十分に洗浄してもらい、イソブチルアンゲレートが添加されたオレンジジュース(添加品)を試飲してもらった。無添加品と添加品とを比較して、オレンジジュースのオフフレーバー(加熱殺菌による独特のむれた風味、金属的な風味)が改善されているか否かを、上述の実施例1と同様の基準で評価してもらった。7名のパネラーの合計点が10点以上の場合、オフフレーバーが改善されていると評価した。 The above seven panelists sampled orange juice (no additives). Next, seven panelists thoroughly cleaned their mouths and sampled orange juice (added product) to which isobutyl angelate was added. The same criteria as in Example 1 above are used to compare whether or not the off-flavor of orange juice (a unique unpleasant flavor by heat sterilization, a metallic flavor) is improved by comparing the additive-free product with the additive-free product. We had you evaluate in. When the total score of 7 panelists was 10 or more, it was evaluated that the off-flavor was improved.
(実施例26:オレンジジュース)
実施例25で用いたオレンジジュースに、調製例2で得られた溶液を0.05質量%の割合で添加した。オレンジジュースに添加されたイソブチルアンゲレートの濃度は約0.4985質量ppmであった。オレンジジュース(無添加品)とイソブチルアンゲレートが添加されたオレンジジュース(添加品)とを比較して、実施例25と同様の方法で評価した。結果を表1に示す。
(Example 26: Orange juice)
The solution obtained in Preparation Example 2 was added to the orange juice used in Example 25 at a ratio of 0.05% by mass. The concentration of isobutyl angelate added to the orange juice was about 0.4985 ppm by mass. The orange juice (additive product) and the orange juice (added product) to which isobutyl angelate was added were compared and evaluated in the same manner as in Example 25. The results are shown in Table 1.
(実施例27:レモンジュース)
市販のレモンジュースに、調製例1で得られた溶液を0.1質量%の割合で添加した。レモンジュースには、原料としてぶどう糖果糖液糖、砂糖、レモン果汁、酸味料、香料が使用されていた。
レモンジュースに添加されたイソブチルアンゲレートの濃度は0.1質量ppmであった。イソブチルアンゲレートが添加されたレモンジュースの風味について、下記の方法で評価した。結果を表1に示す。
(Example 27: Lemon juice)
To the commercially available lemon juice, the solution obtained in Preparation Example 1 was added at a ratio of 0.1% by mass. Lemon juice used glucose fructose liquid sugar, sugar, lemon juice, acidulant, and flavor as raw materials.
The concentration of isobutyl angelate added to lemon juice was 0.1 mass ppm. The flavor of lemon juice to which isobutyl angelate was added was evaluated by the following method. The results are shown in Table 1.
上記7名のパネラーに、レモンジュース(無添加品)を試飲してもらった。次いで、7名のパネラーに口内を十分に洗浄してもらい、イソブチルアンゲレートが添加されたレモンジュース(添加品)を試飲してもらった。無添加品と添加品とを比較して、レモンジュースのオフフレーバー(加熱殺菌による独特のむれた風味、カビ臭を想起させる風味、金属的な風味)が改善されているか否かを、上述の実施例1と同様の基準で評価してもらった。7名のパネラーの合計点が10点以上の場合、オフフレーバーが改善されていると評価した。 The seven panelists sampled lemon juice (no additives). Next, seven panelists thoroughly cleaned their mouths and sampled lemon juice (added product) to which isobutyl angelate was added. Compared with the additive-free product and the additive product, whether or not the lemon juice off-flavor (a unique unpleasant flavor by heat sterilization, a flavor reminiscent of a mold smell, a metallic flavor) The evaluation was made based on the same criteria as in Example 1. When the total score of 7 panelists was 10 or more, it was evaluated that the off-flavor was improved.
(実施例28:レモンジュース)
実施例27で用いたレモンジュースに、調製例2で得られた溶液を0.1質量%の割合で添加した。レモンジュースに添加されたイソブチルアンゲレートの濃度は約0.997質量ppmであった。レモンジュース(無添加品)とイソブチルアンゲレートが添加されたレモンジュース(添加品)とを比較して、実施例27と同様の方法で評価した。結果を表1に示す。
(Example 28: Lemon juice)
To the lemon juice used in Example 27, the solution obtained in Preparation Example 2 was added at a ratio of 0.1% by mass. The concentration of isobutyl angelate added to lemon juice was about 0.997 ppm by mass. Lemon juice (non-added product) and lemon juice (added product) to which isobutyl angelate was added were compared and evaluated in the same manner as in Example 27. The results are shown in Table 1.
表1に示すように、実施例1〜28に示すいずれの飲食品も、イソブチルアンゲレートを添加すると、添加しない場合と比べてオフフレーバーが抑制されていることがわかる。 As shown in Table 1, it can be seen that in any of the foods and beverages shown in Examples 1 to 28, when isobutyl angelate is added, the off-flavor is suppressed as compared with the case where it is not added.
Claims (5)
オフフレーバーがレトロネザール香に関するオフフレーバーである、オフフレーバー抑制方法。 Off of food and beverages in which isobutyl angelate is added at a rate of 0.1 to 2 ppm by mass to foods and beverages containing at least one food selected from the group consisting of soybeans, milk, fruits, vegetables and vegetable oils A flavor suppression method,
An off-flavor suppression method , wherein the off-flavor is an off-flavor related to retro nether scent .
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