JP6598770B2 - 炭化水素の重合 - Google Patents
炭化水素の重合 Download PDFInfo
- Publication number
- JP6598770B2 JP6598770B2 JP2016524464A JP2016524464A JP6598770B2 JP 6598770 B2 JP6598770 B2 JP 6598770B2 JP 2016524464 A JP2016524464 A JP 2016524464A JP 2016524464 A JP2016524464 A JP 2016524464A JP 6598770 B2 JP6598770 B2 JP 6598770B2
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- reaction vessel
- monomer
- hydrocarbon
- light
- reaction
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- 229930195733 hydrocarbon Natural products 0.000 title claims description 40
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 40
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 31
- 238000006116 polymerization reaction Methods 0.000 title claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 71
- 238000000034 method Methods 0.000 claims description 23
- 239000000178 monomer Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 8
- 238000010926 purge Methods 0.000 claims description 8
- 230000000379 polymerizing effect Effects 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 4
- 238000005401 electroluminescence Methods 0.000 claims description 4
- 150000002118 epoxides Chemical class 0.000 claims description 4
- 150000003951 lactams Chemical class 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000010526 radical polymerization reaction Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012967 coordination catalyst Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000008376 long-term health Effects 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/127—Sunlight; Visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/04—Acids; Metal salts or ammonium salts thereof
- C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0869—Feeding or evacuating the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/12—Processes employing electromagnetic waves
- B01J2219/1203—Incoherent waves
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN3272/MUM/2013 | 2013-10-18 | ||
| IN3272MU2013 IN2013MU03272A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2013-10-18 | 2014-10-16 | |
| PCT/IN2014/000655 WO2015075733A2 (en) | 2013-10-18 | 2014-10-16 | Polymerization of hydrocarbons |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016533419A JP2016533419A (ja) | 2016-10-27 |
| JP2016533419A5 JP2016533419A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2017-11-24 |
| JP6598770B2 true JP6598770B2 (ja) | 2019-10-30 |
Family
ID=53180343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016524464A Active JP6598770B2 (ja) | 2013-10-18 | 2014-10-16 | 炭化水素の重合 |
Country Status (6)
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201528379A (zh) * | 2013-12-20 | 2015-07-16 | Applied Materials Inc | 雙波長退火方法與設備 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2857322A (en) * | 1954-04-28 | 1958-10-21 | Chemstrand Corp | Photopolymerization of acrylonitrile |
| US3859189A (en) * | 1968-01-14 | 1975-01-07 | Central De Chimie Fizica | Polymerization of acrylonitrile using radiation in the presence of dimethylsulphoxide and a protein |
| NL162087C (nl) * | 1970-04-21 | 1980-04-15 | Ceskoslovenska Akademie Ved | Werkwijze voor het polymeriseren van monoalkenische monomeren op zichzelf of voor het copolymeriseren met andere onverzadigde verbindingen. |
| FR2200283B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1972-09-22 | 1979-01-26 | Toyo Soda Mfg Co Ltd | |
| US4325794A (en) * | 1980-06-02 | 1982-04-20 | Calgon Corporation | Combined visible light and thermally activated continuous polymerization process |
| US4517063A (en) * | 1984-02-13 | 1985-05-14 | The Standard Oil Company | Photochemical reactor and method for carrying out photochemical reactions therein |
| JP2692194B2 (ja) | 1988-11-14 | 1997-12-17 | 日本合成ゴム株式会社 | 水素化ブロック共重合体及びその組成物 |
| US5149895A (en) * | 1990-01-16 | 1992-09-22 | Mobil Oil Corporation | Vulcanizable liquid compositions |
| US5187236A (en) * | 1990-01-16 | 1993-02-16 | Mobil Oil Corporation | Solid block and random elastomeric copolymers |
| USH1786H (en) * | 1993-07-12 | 1999-02-02 | Shell Oil Company | Process for radiation cured conjugated diene-vinyl aromatic hydrocarbon block copolymers |
| WO2002055565A1 (fr) * | 2001-01-15 | 2002-07-18 | Kaneka Corporation | Procede et appareil pour produire une resine chloree de chlorure de vinyle |
| GB2396331A (en) * | 2002-12-20 | 2004-06-23 | Inca Digital Printers Ltd | Curing ink |
| US7524889B2 (en) * | 2006-07-06 | 2009-04-28 | Bisco, Inc. | Light emitting diode curable acrylates with reduced yellowing |
| CN102181001B (zh) * | 2011-03-11 | 2013-01-23 | 北京化工大学 | 一种可控/活性自由基聚合方法 |
| EP2778180B1 (en) * | 2011-11-07 | 2017-03-29 | Kaneka Corporation | Method for producing chlorinated vinyl chloride resin |
-
2014
- 2014-10-16 IN IN3272MU2013 patent/IN2013MU03272A/en unknown
- 2014-10-16 EP EP14863811.7A patent/EP3058000A4/en not_active Withdrawn
- 2014-10-16 CN CN201811130106.8A patent/CN109651535A/zh active Pending
- 2014-10-16 CN CN201480057162.7A patent/CN105658680A/zh active Pending
- 2014-10-16 JP JP2016524464A patent/JP6598770B2/ja active Active
- 2014-10-16 US US15/029,957 patent/US9969825B2/en active Active
- 2014-10-16 WO PCT/IN2014/000655 patent/WO2015075733A2/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015075733A2 (en) | 2015-05-28 |
| EP3058000A4 (en) | 2017-04-05 |
| CN109651535A (zh) | 2019-04-19 |
| WO2015075733A3 (en) | 2015-12-17 |
| EP3058000A2 (en) | 2016-08-24 |
| CN105658680A (zh) | 2016-06-08 |
| US20160244541A1 (en) | 2016-08-25 |
| US9969825B2 (en) | 2018-05-15 |
| IN2013MU03272A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2015-07-17 |
| JP2016533419A (ja) | 2016-10-27 |
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