JP6564440B2 - Hair treatment method - Google Patents
Hair treatment method Download PDFInfo
- Publication number
- JP6564440B2 JP6564440B2 JP2017203434A JP2017203434A JP6564440B2 JP 6564440 B2 JP6564440 B2 JP 6564440B2 JP 2017203434 A JP2017203434 A JP 2017203434A JP 2017203434 A JP2017203434 A JP 2017203434A JP 6564440 B2 JP6564440 B2 JP 6564440B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- treatment
- curl
- design
- aqueous composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000034 method Methods 0.000 title claims description 34
- 238000013461 design Methods 0.000 claims description 41
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- 108010076876 Keratins Proteins 0.000 claims description 33
- 238000010438 heat treatment Methods 0.000 claims description 31
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Landscapes
- Cosmetics (AREA)
Description
本発明は、毛髪に対してカールデザインまたはストレートデザインを形成する毛髪処理方法に関する。 The present invention relates to a hair treatment method for forming a curl design or a straight design for hair.
パーマネントウェーブ処理に代表される毛髪の還元処理を伴う毛髪変形処理では、還元処理の後に毛髪を酸化処理させて変形を定着させる。 In a hair deformation process involving a hair reduction process typified by a permanent wave process, the hair is oxidized after the reduction process to fix the deformation.
より具体的には、まず、チオグリコール酸等の還元剤を主成分とし、アルカリ剤を含有する第1剤により毛髪ケラチンのシスチン結合を切断する還元工程と、臭素酸塩等の酸化剤を主成分とする第2剤により再びシスチン結合に戻す酸化工程により毛髪にカールデザインまたはストレートデザインを形成する。 More specifically, first, a reducing step of cleaving the cystine bond of hair keratin with a first agent containing a reducing agent such as thioglycolic acid as a main component and an alkaline agent, and an oxidizing agent such as bromate are mainly used. A curl design or straight design is formed on the hair by an oxidation process that returns the cystine bond to the second agent as a component.
ここで、上記毛髪処理方法においては、アルカリ下においての還元処理、酸化処理を行うため、毛髪へのダメージが大きく、また、パーマネントウェーブ処理による効果が不十分であるという問題があった。 Here, in the said hair treatment method, since the reduction treatment and the oxidation treatment are performed under an alkali, there is a problem that the damage to the hair is large and the effect by the permanent wave treatment is insufficient.
そこで、これらの不都合を解消すべく、毛髪を加温処理する方法が提案されている。より具体的には、毛髪に還元剤を含有する第1剤を塗布して洗浄した後、通電により毛髪を加熱可能なロッドに巻き付け、ロッドを加熱して毛髪を加温し、ロッドを外した毛髪に酸化剤を含有する第2剤を塗布する方法が提案されている。そして、このような処理方法により、パーマネントウェーブ処理による毛髪の損傷が少なく、毛髪に強力なカールデザインを付与することができると記載されている(例えば、特許文献1参照)。 Therefore, in order to eliminate these disadvantages, a method of heating the hair has been proposed. More specifically, after the first agent containing a reducing agent is applied to the hair and washed, the hair is wound around a rod that can be heated by energization, the rod is heated to heat the hair, and the rod is removed. A method of applying a second agent containing an oxidizing agent to hair has been proposed. And it is described by such a processing method that there is little damage of the hair by a permanent wave process, and a strong curl design can be provided to hair (for example, refer patent document 1).
また、上記毛髪へのダメージを軽減すべく、一浴式のパーマネントウェーブ形成剤を使用した毛髪処理方法が提案されている。より具体的には、平均分子量が25,000〜35,000の加水分解ケラチンを含有する一浴式のパーマネントウェーブ形成剤を損傷した毛髪に塗布し、毛髪をロッドに巻き付けた後、所定時間、放置し、その後、ロッドを取り外して洗浄する方法が提案されている。そして、このような処理方法により、損傷毛に対してパーマネント処理を行う際に、当該パーマネントウェーブ処理による毛髪への更なるダメージを低減することができると記載されている(例えば、特許文献2参照)。 In order to reduce the damage to the hair, a hair treatment method using a one-bath type permanent wave forming agent has been proposed. More specifically, after applying a one-bath type permanent wave forming agent containing hydrolyzed keratin having an average molecular weight of 25,000 to 35,000 to damaged hair and winding the hair around a rod, a predetermined time, There has been proposed a method in which the rod is left and then removed and washed. And when performing a permanent process with respect to damaged hair by such a processing method, it is described that the further damage to the hair by the said permanent wave process can be reduced (for example, refer patent document 2). ).
しかし、上記特許文献1に記載の処理方法においては、還元処理された毛髪に対しての加温処理を行うため、当該加温処理に起因して毛髪が損傷するとともに、加温処理中における反応臭や毛髪処理後の残臭が発生するという問題があった。 However, in the treatment method described in Patent Document 1, since the heating treatment is performed on the hair subjected to the reduction treatment, the hair is damaged due to the heating treatment, and the reaction during the heating treatment is performed. There was a problem that odor and residual odor after hair treatment occurred.
また、上記特許文献2に記載の処理方法においては、損傷毛髪におけるダメージを低減することはできるものの、対象毛が損傷毛に限定されていた。健常毛髪の表面は疎水性が高く、平均分子量が25,000〜35,000の加水分解ケラチンの浸透が不十分になるため、十分な毛髪変形効果(カール形状の強さ)を得ることが困難であった。 Moreover, in the processing method of the said patent document 2, although the damage in damaged hair can be reduced, the target hair was limited to damaged hair. Since the surface of healthy hair is highly hydrophobic and the penetration of hydrolyzed keratin with an average molecular weight of 25,000-35,000 is insufficient, it is difficult to obtain a sufficient hair deformation effect (curl shape strength). Met.
そこで、本発明は、上記の問題に鑑みてなされたものであり、健常毛及び損傷毛のいずれの毛髪においても、毛髪処理に起因する毛髪の損傷及び不快臭の発生を抑制するとともに、十分な毛髪変形効果を得ることができる毛髪処理方法を提供することを目的とする。 Therefore, the present invention has been made in view of the above problems, and in both normal hair and damaged hair, while suppressing the occurrence of hair damage and unpleasant odor caused by hair treatment, it is sufficient. It aims at providing the hair processing method which can acquire a hair deformation effect.
上記目的を達成するために、本発明の毛髪処理方法は、加水分解ケラチンを含有する水性組成物を毛髪に塗布する第1工程と、水性組成物が塗布された毛髪にカールデザインを形成する第2工程と、カールデザインが形成された毛髪に対して、毛髪が濡れた状態で、40℃よりも高く、100℃未満の温度で加温処理を行う第3工程とを少なくとも備えることを特徴とする。 In order to achieve the above object, the hair treatment method of the present invention includes a first step of applying an aqueous composition containing hydrolyzed keratin to the hair, and a step of forming a curl design on the hair to which the aqueous composition is applied. Characterized in that it comprises at least a second step and a third step of performing a heating treatment at a temperature higher than 40 ° C. and lower than 100 ° C. while the hair is wet with respect to the hair on which the curl design is formed. To do.
本発明によれば、健常毛及び損傷毛のいずれの毛髪においても、毛髪処理に起因する毛髪の損傷を抑制することができるとともに、優れた毛髪変形の効果を得ることができる。また、毛髪処理に起因する不快臭の発生を抑制することができる。 ADVANTAGE OF THE INVENTION According to this invention, in any hair of healthy hair and damaged hair, while being able to suppress the damage of the hair resulting from hair processing, the effect of the outstanding hair deformation can be acquired. Moreover, generation | occurrence | production of the unpleasant odor resulting from hair processing can be suppressed.
以下に、本発明の好適な実施形態について説明する。なお、本発明は、以下の実施形態に限定されるものではなく、本発明の要旨を変更しない範囲において、適宜、変更して適用することができる。 Hereinafter, a preferred embodiment of the present invention will be described. In addition, this invention is not limited to the following embodiment, In the range which does not change the summary of this invention, it can change suitably and can apply.
本発明の毛髪処理方法は、加水分解ケラチンを含有する水性組成物を毛髪に塗布する第1工程と、水性組成物が塗布された毛髪にカールデザインを形成する第2工程と、カールデザインが形成された毛髪に対して、毛髪が濡れた状態で加温処理を行う第3工程とを備えており、上記従来の酸化処理、及び還元処理は行わない。 The hair treatment method of the present invention includes a first step of applying an aqueous composition containing hydrolyzed keratin to the hair, a second step of forming a curl design on the hair to which the aqueous composition is applied, and a curl design formed And a third step of performing a heating treatment in a state where the hair is wet, and the conventional oxidation treatment and reduction treatment are not performed.
(第1工程)
本発明の毛髪処理方法においては、毛髪に加水分解ケラチンを含有する水性組成物を塗布する。
(First step)
In the hair treatment method of the present invention, an aqueous composition containing hydrolyzed keratin is applied to the hair.
この加水分解ケラチンは、シスチンを多く含んでいるため、毛髪に非常になじみやすく、このような加水分解ケラチンを含有する水性組成物を塗布することにより、毛髪のダメージを低減させて、優れた毛髪変形の効果を得ることができる。 Since this hydrolyzed keratin contains a lot of cystine, it is very easy to adapt to hair. By applying an aqueous composition containing such hydrolyzed keratin, hair damage can be reduced and excellent hair can be obtained. A deformation effect can be obtained.
この加水分解ケラチンとしては、特に限定されず、通常、毛髪化粧料に用いられるものであればよい。 The hydrolyzed keratin is not particularly limited as long as it is usually used for hair cosmetics.
また、この加水分解ケラチンにおける平均分子量は特に限定されないが、加水分解ケラチンの平均分子量は10000以上であることが好ましい。これは、平均分子量が10000未満の場合、後述の「毛髪が濡れた状態での加温処理」を行う際に、毛髪内部へ浸透されるものの、分子サイズが小さいため、毛髪に対する定着が不十分となり、結果として、毛髪変形効果が十分に発揮されない場合があるためである。 The average molecular weight of the hydrolyzed keratin is not particularly limited, but the hydrolyzed keratin preferably has an average molecular weight of 10,000 or more. This is because when the average molecular weight is less than 10,000, it penetrates into the hair when performing the “heating treatment with the hair wet”, which will be described later, but the molecular size is small, so the fixation to the hair is insufficient. As a result, the hair deformation effect may not be sufficiently exhibited.
また、この加水分解ケラチンにおける化学修飾の有無は特に限定されないが、化学修飾がされていない加水分解ケラチンを使用することが好ましい。これは、カチオン化やシリル化等の化学修飾が施された加水分解ケラチンを用いた場合、後述の「毛髪が濡れた状態での加温処理」を行うことにより、仕上がり感(やわらかさ、すべりなど)が向上するものの、化学修飾に起因して、主要効果である毛髪変形効果が低下する場合があるためである。 The presence or absence of chemical modification in the hydrolyzed keratin is not particularly limited, but it is preferable to use hydrolyzed keratin that has not been chemically modified. When hydrolyzed keratin that has been chemically modified, such as cationization or silylation, is used, the finishing touch (softness, slipperiness) is achieved by performing the “heating treatment with wet hair” described later. This is because the hair deformation effect, which is the main effect, may be reduced due to chemical modification.
例えば、平均分子量35000の加水分解ケラチンを含む「プロティキュート Uアルファ」(一丸ファルコス社製)、平均分子量35000のヒドロキシプロピルトリモニウム加水分解ケラチン(カチオン化修飾)を含む「プロティキュート Cアルファ」(一丸ファルコス社製)、平均分子量10000の加水分解ケラチンを含む「プロモイス WK−GB」(成和化成社製)、平均分子量4000の加水分解ケラチンを含む「プロモイス WK−L」(成和化成社製)、平均分子量1000の加水分解ケラチンを含む「プロモイス WK−H」(成和化成社製)、平均分子量400の加水分解ケラチンを含む「プロモイス WK」(成和化成社製)、平均分子量1200の(ジヒドロキシメチルシリルプロポキシ)ヒドロキシプロピル加水分解ケラチン(シリル化修飾)を含む「プロモイス WK−HSIG」(成和化成社製)、平均分子量600のヒドロキシプロピルトリモニウム加水分解ケラチン(カチオン化修飾)を含む「プロモイス WK−Q」(成和化成社製)、平均分子量1000のヒドロキシプロピルトリモニウム加水分解ケラチン(カチオン化修飾)を含む「ケラタイドTK−C」(東洋羽毛工業社製)等の市販品を使用することができる。 For example, “Proticute U alpha” (produced by Ichimaru Falcos) containing hydrolyzed keratin having an average molecular weight of 35000, “Proticute C alpha” containing one hydrolyzed propylamine having an average molecular weight of 35,000 (cationized modification) (Ichimaru) "Promois WK-GB" (manufactured by Seiwa Kasei Co., Ltd.) containing hydrolyzed keratin with an average molecular weight of 10,000, and "Promois WK-L" (manufactured by Seiwa Kasei Co., Ltd.) containing hydrolyzed keratin with an average molecular weight of 4000 "Promois WK-H" (manufactured by Seiwa Kasei Co., Ltd.) containing hydrolyzed keratin having an average molecular weight of 1000, "Promois WK" (manufactured by Seiwa Kasei Co., Ltd.) containing hydrolyzed keratin having an average molecular weight of 400, Dihydroxymethylsilylpropoxy) hydroxypropyl "Promois WK-HSIG" containing keratin (silylation modification) (manufactured by Seiwa Kasei Co., Ltd.) and "Promois WK-Q" (Seiwa) containing hydroxypropyltrimonium hydrolyzed keratin (cationization modification) having an average molecular weight of 600 Commercially available products such as “Keratide TK-C” (manufactured by Toyo Feather Kogyo Co., Ltd.) containing hydroxypropyltrimonium hydrolyzed keratin (cationized modification) having an average molecular weight of 1000 can be used.
なお、本発明の水性組成物としては、例えば、水等の溶媒に上記加水分解ケラチンを分散させたものが使用できるが、毛髪のダメージ低減効果と変形効果を十分に発揮させるとの観点から、水性組成物の全体に対する加水分解ケラチンの配合量は、0.1〜20質量%が好ましい。 In addition, as the aqueous composition of the present invention, for example, a solution in which the hydrolyzed keratin is dispersed in a solvent such as water can be used, but from the viewpoint of sufficiently exhibiting the hair damage reduction effect and the deformation effect, As for the compounding quantity of the hydrolysis keratin with respect to the whole aqueous composition, 0.1-20 mass% is preferable.
(第2工程)
本発明の毛髪処理方法におけるカールデザインを形成する方法としては、美容技術として一般的に用いられる方法であれば特に限定されず、例えば、発熱体を用いる方法、ロッドと呼ばれる器具を用いる方法、及び加熱可能なロッドを用いる方法等が挙げられる。
(Second step)
The method for forming the curl design in the hair treatment method of the present invention is not particularly limited as long as it is a method generally used as a beauty technique. For example, a method using a heating element, a method using a tool called a rod, and Examples include a method using a heatable rod.
(第3工程)
本発明の毛髪処理方法においては、カールデザインが形成された毛髪に対して、毛髪が濡れた状態で加温処理を行うことにより、カールデザインを定着させる点に特徴がある。
(Third step)
The hair treatment method of the present invention is characterized in that the curl design is fixed by performing a heating treatment on the hair on which the curl design is formed while the hair is wet.
なお、ここで言う「毛髪が濡れた状態」とは、「第2工程におけるカールデザイン処理後の、水性組成物またはシャワー等による洗い流しにより濡れた状態にある毛髪を、乾燥させることなくそのままの状態で」、あるいは「第2工程におけるカールデザイン処理後の、水性組成物またはシャワー等による洗い流しにより濡れた状態にある毛髪に水分を浸漬させた状態で(即ち、毛髪が水分を保持した状態で)」という意味である。 As used herein, “the hair is in a wet state” means “the hair in a wet state after washing with an aqueous composition or shower after the curl design process in the second step, without being dried. Or "in a state where water is immersed in hair that has been wet by washing with an aqueous composition or shower after the curl design process in the second step (that is, in a state in which the hair retains moisture). ".
そして、この加熱工程においては、40℃よりも高く、100℃未満の温度で加熱を行う点に特徴がある。
This heating step is characterized in that heating is performed at a temperature higher than 40 ° C. and lower than 100 ° C.
これは、カールデザインを定着する際の処理温度が40℃以下の場合は、毛髪変形効果(カール形状の強さ)を得るために必要な温度が不十分になるため、所望のカールデザインが得られない場合があるためである。 This is because when the treatment temperature for fixing the curl design is 40 ° C. or lower, the temperature necessary for obtaining the hair deformation effect (the strength of the curl shape) becomes insufficient, and thus the desired curl design can be obtained. This is because it may not be possible.
また、カールデザインを定着する際の処理温度が100℃以上の場合は、カールデザインを確実に形成することはできるものの、高温処理に起因して、不快臭の発生や、毛髪内成分が熱ダメージを受けるため、良好な仕上がり感(良好な柔らかさ、良好なすべり感)が得られない場合があるためである。 In addition, when the treatment temperature when fixing the curl design is 100 ° C. or higher, the curl design can be reliably formed, but due to the high temperature treatment, unpleasant odor is generated and the hair components are thermally damaged. This is because a good finish (good softness, good slip) may not be obtained.
即ち、40℃よりも高く、100℃未満の温度で加温処理を行うことにより、健常毛及び損傷毛のいずれの毛髪においても、毛髪の損傷を抑制することができるとともに、優れた毛髪変形の効果を得ることが可能になる。更に、加温処理に起因する不快臭の発生を抑制することが可能になる。 That is, by performing the heating treatment at a temperature higher than 40 ° C. and lower than 100 ° C., hair damage can be suppressed in both normal hair and damaged hair, and excellent hair deformation can be achieved. An effect can be obtained. Furthermore, it is possible to suppress the generation of unpleasant odor due to the heating process.
なお、毛髪変形の効果、及び仕上がり感を向上させるとの観点から、加熱工程における温度は、50℃以上90℃以下が好ましい。 The temperature in the heating step is preferably 50 ° C. or higher and 90 ° C. or lower from the viewpoint of improving the effect of hair deformation and finishing feeling.
また、加温処理を行う処理時間は、3分以上45分以下が好ましい。これは、3分未満の場合は、加温時間不足に起因して毛髪変形効果が不十分になるという不都合が生じる場合があるためであり、45分よりも長い場合は、過剰な加温時間に起因して仕上がり感が低下するという不都合が生じる場合があるためである。 Further, the treatment time for the heating treatment is preferably 3 minutes or more and 45 minutes or less. This is because if it is less than 3 minutes, there may be a disadvantage that the hair deformation effect becomes insufficient due to insufficient heating time, and if it is longer than 45 minutes, excessive heating time is required. This is because there may be a disadvantage that the feeling of finish is lowered due to the above.
また、毛髪が濡れた状態で加温処理を行うのは、加温する際に毛髪が乾燥している場合、水性組成物中の加水分解ケラチンが毛髪内部へ効率よく浸透することができず、毛髪変形効果が不十分になり、所望のカールデザインが得られない場合があるためである。 In addition, when the hair is wet when the hair is wet, the hydrolyzed keratin in the aqueous composition cannot efficiently penetrate into the hair. This is because the hair deformation effect becomes insufficient and a desired curl design may not be obtained.
本工程の具体例としては、温水(40℃よりも高く、100℃未満)にカールデザインされた毛髪を浸漬して加温処理を行う場合や、カールデザインされた毛髪を保湿が可能なカバーで包み込んだ状態で加温処理を行う場合などが挙げられる。 Specific examples of this process include the case where a hair designed with curl is immersed in warm water (higher than 40 ° C. and less than 100 ° C.) for heating treatment, or a cover capable of moisturizing the curled hair. The case where a heating process is performed in the enveloped state is mentioned.
(その他の成分)
本発明の水性組成物において使用される溶媒(分散媒)は特に限定されず、水が使用されるが、必要に応じて、エタノール、イソプロパノール等の有機溶媒を、人体に接触しても無害な濃度で、水に含有させてもよい。
(Other ingredients)
The solvent (dispersion medium) used in the aqueous composition of the present invention is not particularly limited, and water is used. However, if necessary, an organic solvent such as ethanol or isopropanol is harmless even if it comes into contact with the human body. You may make it contain in water by density | concentration.
また、本発明の水性組成物には、本発明の効果を損なわない範囲で、pH調整成分(例えば、炭酸グアニジン、リン酸二水素ナトリウム、リン酸水素二ナトリウム、リン酸三ナトリウム、セスキ炭酸塩、アルギニン、炭酸水素ナトリウム、炭酸ナトリウム、モノエタノールアミン、トリエタノールアミン、アンモニア、2−アミノ−2−メチル−1−プロパノール、水酸化ナトリウム、クエン酸三カリウム、クエン酸三ナトリウム、リン酸水素二アンモニウム、酒石酸、クエン酸、乳酸、リン酸等)、油性成分(例えば、スフィンゴ脂質、セラミド類、コレステロール誘導体、フィトステロール誘導体、リン脂質、ラノリン、ラノリン脂肪酸誘導体、パーフルオロポリエーテル等)、植物油(例えば、オリーブ油、シア脂、マカデミアナッツ油等)、ロウ類(例えば、ホホバ種子油、カルナウバロウ、キャンデリラロウ、ミツロウ等)、炭化水素(例えば、流動パラフィン、軽質流動イソパラフィン、パラフィン、マイクロクリスタリンワックス、スクワラン、ワセリン、イソドデカン、イソヘキサデカン等)、高級脂肪酸(例えば、ミリスチン酸、オレイン酸、ステアリン酸、イソステアリン酸、分岐脂肪酸(C(炭素数)14−28)、ヒドロキシステアリン酸等)、アルコール類(例えば、セテアリルアルコール、セタノール、イソステアリルアルコール、オレイルアルコール、水添ナタネ油アルコール、コレステロール、シトステロール、1,3−ブチレングリコール、プロピレングリコール、ジプロピレングリコール、グリセリン、ジグリセリン、1,2−ペンタンジオール、1,2−ヘキサンジオール等)、糖及びその誘導体類(例えば、ブドウ糖、ショ糖、D−ソルビトール、マルトース、トレハロース、ポリオキシプロピレンメチルグルコシド、グリセリルグルコシド等)、エステル類(例えば、ミリスチン酸イソプロピル、パルミチン酸セチル、オレイン酸オクチルドデシル、トリイソステアリン酸グリセリル、コハク酸ジエトキシエチル、乳酸セチル、ラノリン脂肪酸オクチルドデシル等)、シリコーン類(例えば、ジメチルシリコーン、メチルフェニルシリコーン、環状ジメチルシリコーン、ポリエーテル変性シリコーン、アルキル変性シリコーン、アミノ変性シリコーン、ジメチコノール、PCAジメチコン等)、アミノ酸及びその誘導体類(例えば、グルタミン酸、アスパラギン酸、グリシン、セリン、メチオニン、トリメチルグリシン、ポリアスパラギン酸ナトリウム、ジラウロイルグルタミン酸リシンナトリウム、N−ラウロイル−L−リジン等)、PPT及びタンパク類(例えば、加水分解シルク、加水分解コムギ、加水分解ダイズ、加水分解コラーゲン、シリル化加水分解シルク、シリル化加水分解コムギ、カチオン化加水分解シルク、カチオン化加水分解コラーゲン、ケラチン等)、天然高分子及びその誘導体類(例えば、アルギン酸塩、マンナン、アラビアゴム、タマリンドガム、キトサン、カラギーナン、ムチン、セラック、ヒアルロン酸塩、カチオン化ヒアルロン酸、キサンタンガム、デキストリン、ヒドロキシエチルセルロース、カチオン化セルロース、グァーガム、カチオン化グァーガム、ハチミツ等)、合成高分子(例えば、アニオン性高分子、カチオン性高分子、非イオン性高分子、両性高分子、ポリエチレングリコール、ポリプロピレングリコール、ポリオキシプロピレンジグリセリルエーテル等)、アニオン性界面活性剤(例えば、アルキルエーテルカルボン酸塩、N−アシルグルタミン酸、N−アシルメチルタウリン塩、アルキルスルホコハク酸塩、アルキル硫酸塩、アルキルエーテル硫酸塩、ポリオキシエチレンアルキルエーテルリン酸、リン酸ジセチル等)、カチオン性界面活性剤(例えば、アルキルアミン塩、脂肪酸アミドアミン塩等)、両性界面活性剤(例えば、グリシン型両性界面活性剤、アミノプロピオン酸型両性界面活性剤、アミノ酢酸ベタイン型両性界面活性剤、スルホベタイン型両性界面活性剤等)、非イオン性界面活性剤(例えば、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、アルキルグルコシド、新油型モノステアリン酸グリセリル等)、染料(例えば、タール色素、天然色素等)、植物エキス類(例えば、カミツレエキス、コンフリーエキス、セージエキス、ローズマリーエキス、カキタンニン、チャ乾留液、銅クロロフィリンナトリウム等)、ビタミン類(例えば、L−アスコルビン酸、DL−α−トコフェロール、D−パンテノール、天然ビタミンE等)、紫外線吸収剤(例えば、パラアミノ安息香酸、サリチル酸オクチル、パラメトキシケイ皮酸2−エチルヘキシル、フェルラ酸等)、防腐剤(例えば、安息香酸、安息香酸ナトリウム、サリチル酸、デヒドロ酢酸、デヒドロ酢酸ナトリウム、パラベン、フェノキシエタノール、メチルイソチアゾリノン等)、酸化防止剤(例えば、ジブチルヒドロキシトルエン等)、金属封鎖剤(例えば、エデト酸塩、ポリリン酸ナトリウム、フィチン酸等)、その他無機化合物(例えば、酸化チタン、銀、白金、塩化鉄、酸化鉄等)、その他有機化合物(例えば、尿素、ヒドロキシエチル尿素、dl−ピロリドンカルボン酸ナトリウム、グルコン酸銅等)、溶剤(例えば、ベンジルアルコール等)、噴射剤(例えば、LPG(液化石油ガス)、DME(ジメチルエーテル)、窒素ガス、炭酸ガス等)、香料等の公知の化粧品各成分を配合することができる。 In addition, the aqueous composition of the present invention includes a pH adjusting component (for example, guanidine carbonate, sodium dihydrogen phosphate, disodium hydrogen phosphate, trisodium phosphate, sesquicarbonate within a range not impairing the effects of the present invention. Arginine, sodium bicarbonate, sodium carbonate, monoethanolamine, triethanolamine, ammonia, 2-amino-2-methyl-1-propanol, sodium hydroxide, tripotassium citrate, trisodium citrate, dihydrogen phosphate Ammonium, tartaric acid, citric acid, lactic acid, phosphoric acid, etc.), oily components (eg, sphingolipids, ceramides, cholesterol derivatives, phytosterol derivatives, phospholipids, lanolin, lanolin fatty acid derivatives, perfluoropolyether, etc.), vegetable oils (eg, , Olive oil, shea butter, macadamia nuts Etc.), waxes (eg jojoba seed oil, carnauba wax, candelilla wax, beeswax etc.), hydrocarbons (eg liquid paraffin, light liquid isoparaffin, paraffin, microcrystalline wax, squalane, petrolatum, isododecane, isohexadecane, etc.) Higher fatty acids (eg, myristic acid, oleic acid, stearic acid, isostearic acid, branched fatty acids (C (carbon number) 14-28), hydroxystearic acid, etc.), alcohols (eg, cetearyl alcohol, cetanol, isostearyl) Alcohol, oleyl alcohol, hydrogenated rapeseed oil alcohol, cholesterol, sitosterol, 1,3-butylene glycol, propylene glycol, dipropylene glycol, glycerin, diglycerin, 1,2-pentanedio , 1,2-hexanediol, etc.), sugars and derivatives thereof (eg, glucose, sucrose, D-sorbitol, maltose, trehalose, polyoxypropylene methyl glucoside, glyceryl glucoside, etc.), esters (eg, myristic acid) Isopropyl, cetyl palmitate, octyldodecyl oleate, glyceryl triisostearate, diethoxyethyl succinate, cetyl lactate, lanolin fatty acid octyldodecyl, etc.), silicones (eg, dimethyl silicone, methyl phenyl silicone, cyclic dimethyl silicone, polyether) Modified silicone, alkyl-modified silicone, amino-modified silicone, dimethiconol, PCA dimethicone, etc.), amino acids and derivatives thereof (for example, glutamic acid, aspartic acid, glycine, Serine, methionine, trimethylglycine, sodium polyaspartate, lysine sodium dilauroyl glutamate, N-lauroyl-L-lysine, etc., PPT and proteins (eg hydrolyzed silk, hydrolyzed wheat, hydrolyzed soybean, hydrolyzed collagen Silylated hydrolyzed silk, silylated hydrolyzed wheat, cationized hydrolyzed silk, cationized hydrolyzed collagen, keratin, etc.), natural polymers and derivatives thereof (eg, alginates, mannan, gum arabic, tamarind gum, Chitosan, carrageenan, mucin, shellac, hyaluronate, cationized hyaluronic acid, xanthan gum, dextrin, hydroxyethyl cellulose, cationized cellulose, guar gum, cationized guar gum, honey, etc.), synthetic high (For example, anionic polymer, cationic polymer, nonionic polymer, amphoteric polymer, polyethylene glycol, polypropylene glycol, polyoxypropylene diglyceryl ether, etc.), anionic surfactant (for example, alkyl ether carboxyl) Acid salt, N-acyl glutamic acid, N-acyl methyl taurate, alkyl sulfosuccinate, alkyl sulfate, alkyl ether sulfate, polyoxyethylene alkyl ether phosphate, dicetyl phosphate, etc.), cationic surfactant (for example, , Alkylamine salts, fatty acid amidoamine salts, etc.), amphoteric surfactants (for example, glycine type amphoteric surfactants, aminopropionic acid type amphoteric surfactants, aminoacetic acid betaine type amphoteric surfactants, sulfobetaine type amphoteric surfactants) Etc.), nonionic surface activity (Eg, polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene hydrogenated castor oil, alkyl glucoside, new oil type glyceryl monostearate, etc.), dye (eg, tar pigment, natural pigment, etc.), plant extract (For example, chamomile extract, comfrey extract, sage extract, rosemary extract, kakitannin, tea dry distillation liquid, copper chlorophyllin sodium), vitamins (for example, L-ascorbic acid, DL-α-tocopherol, D-pan Tenor, natural vitamin E, etc.), UV absorbers (eg, paraaminobenzoic acid, octyl salicylate, 2-methoxyhexyl paramethoxycinnamate, ferulic acid, etc.), preservatives (eg, benzoic acid, sodium benzoate, salicylic acid, dehydro Acetic acid Sodium roacetate, paraben, phenoxyethanol, methylisothiazolinone, etc.), antioxidants (eg, dibutylhydroxytoluene), sequestering agents (eg, edetate, sodium polyphosphate, phytic acid, etc.), other inorganic compounds ( For example, titanium oxide, silver, platinum, iron chloride, iron oxide, etc.), other organic compounds (eg, urea, hydroxyethylurea, sodium dl-pyrrolidonecarboxylate, copper gluconate, etc.), solvents (eg, benzyl alcohol, etc.) In addition, known cosmetic components such as a propellant (for example, LPG (liquefied petroleum gas), DME (dimethyl ether), nitrogen gas, carbon dioxide gas, etc.) and a fragrance can be blended.
本発明の水性組成物は、公知の方法により、液状、ミルク状、クリーム状、泡状(使用時形状)、霧状(使用時形状)等の剤形とすることができ、エアゾール形態とすることもできる。 The aqueous composition of the present invention can be made into a dosage form such as liquid, milk, cream, foam (in-use shape), mist (in-use shape), etc. by a known method, and is in an aerosol form. You can also.
なお、上記実施形態は以下のように変更しても良い。 In addition, you may change the said embodiment as follows.
上記実施形態における第1工程と第2工程は、その工程順を、適宜、入れ替えることが可能である。即ち、毛髪にカールデザインを形成した後、加水分解ケラチンを含有する水性組成物をカールデザインが形成された毛髪に塗布し、その後、水性組成物が塗布された毛髪を濡れた状態にして、上記加温処理を行ってもよい。このような工程順であっても、上述の実施形態と同様の効果を得ることができる。 The order of the first step and the second step in the above embodiment can be changed as appropriate. That is, after the curl design is formed on the hair, an aqueous composition containing hydrolyzed keratin is applied to the hair on which the curl design is formed, and then the hair on which the aqueous composition is applied is wetted, You may perform a heating process. Even in such a process order, the same effect as in the above-described embodiment can be obtained.
また、上記第3工程の後、毛髪を冷却処理してもよい。より具体的には、室温で放置する、ドライヤー等により冷風をあてる、毛髪を冷水に浸漬する等の処理を行う。 Moreover, you may cool the hair after the said 3rd process. More specifically, treatments such as leaving at room temperature, applying cool air with a dryer, and soaking hair in cold water are performed.
そして、このような冷却処理を行うことにより、毛髪の変形状態での定着効果が高まるため、カール形状の強さ及びカール形状の持続性を高めることができる。 And by performing such a cooling process, since the fixing effect in the deformation | transformation state of hair increases, the intensity | strength of a curl shape and the sustainability of a curl shape can be improved.
また、上記実施形態においては、カールデザインが形成された毛髪を対象としたが、本発明の毛髪処理方法は、くせ毛に対してストレートデザインを形成する場合にも適用することができる。例えば、加水分解ケラチンを含有する水性組成物を毛髪に塗布した後、水性組成物が塗布された毛髪にストレートデザインを形成する。次に、ストレートデザインが形成された毛髪に対して、該毛髪が濡れた状態で、40℃よりも高く、100℃未満の温度で加温処理を行うことができる。また、例えば、毛髪にストレートデザインを形成した後、加水分解ケラチンを含有する水性組成物をストレートデザインが形成された毛髪に塗布する。次に、水性組成物が塗布された毛髪に対して、該毛髪が濡れた状態で、40℃よりも高く、100℃未満の温度で加温処理を行うことができる。この場合も、上述の実施形態と同様の効果を得ることができる。 Moreover, in the said embodiment, although the hair by which the curl design was formed was made into object, the hair processing method of this invention is applicable also when forming a straight design with respect to a comb hair. For example, after applying an aqueous composition containing hydrolyzed keratin to hair, a straight design is formed on the hair to which the aqueous composition is applied. Next, the hair on which the straight design is formed can be heated at a temperature higher than 40 ° C. and lower than 100 ° C. while the hair is wet. For example, after forming a straight design on the hair, an aqueous composition containing hydrolyzed keratin is applied to the hair on which the straight design is formed. Next, the hair to which the aqueous composition is applied can be subjected to a heating treatment at a temperature higher than 40 ° C. and lower than 100 ° C. while the hair is wet. Also in this case, the same effect as the above-described embodiment can be obtained.
以下に、本発明を実施例に基づいて説明する。なお、本発明は、これらの実施例に限定されるものではなく、これらの実施例を本発明の趣旨に基づいて変形、変更することが可能であり、それらを発明の範囲から除外するものではない。 Hereinafter, the present invention will be described based on examples. In addition, this invention is not limited to these Examples, These Examples can be changed and changed based on the meaning of this invention, and they are not excluded from the scope of the invention. Absent.
(実施例1〜18及び比較例1〜3)
<毛髪変形用処理剤の製造>
水(イオン交換水)と各原料を配合して、表1〜表3に示す組成(質量%)を有する実施例1〜18及び比較例1〜3の毛髪変形用処理剤を製造した。
(Examples 1-18 and Comparative Examples 1-3)
<Manufacture of hair deformation treatment agent>
The hair deformation treatment agents of Examples 1 to 18 and Comparative Examples 1 to 3 having the composition (mass%) shown in Tables 1 to 3 were prepared by blending water (ion exchange water) and each raw material.
<サンプル用の毛髪の準備>
長さ25cmの直毛の毛髪からなる毛束(1g)を用い、化学的処理として市販のヘアカラーによる2回の染色処理を行い、さらに市販のパーマ液で、1回パーマネントウェーブ処理後、50℃に保ったポリオキシエチレンラウリル硫酸ナトリウム水溶液(5質量%)に一晩浸漬後、十分に水洗したものをサンプル毛髪とした。
<Preparation of sample hair>
Using a hair bundle (1 g) consisting of straight hair with a length of 25 cm, as a chemical treatment, dyeing was performed twice with a commercially available hair color, and further after a permanent wave treatment with a commercially available permanent solution, 50 The sample hair was immersed in a polyoxyethylene lauryl sodium sulfate aqueous solution (5% by mass) kept at 0 ° C. overnight and then sufficiently washed with water.
<実施例1〜18及び比較例1〜3における毛髪処理>
次に、準備した毛髪に対して、下記(A)〜(F)の処理を行った。
(A)まず、準備した毛髪の毛束を水で濡らした。
(B)次に、実施例1〜18及び比較例1〜3の加水分解ケラチンを含有する水性組成物を毛髪に塗布し、5分間、室温で放置した。
(C)次に、流水中で30秒間すすぎ、毛髪を濡れた状態にした。
(D)次に、毛髪をロッドに巻き付けた。
(E)次に、実施例1〜18及び比較例1〜3の各温度に設定した温水にロッドに巻きつけられた状態の毛髪を浸漬し、実施例1〜18及び比較例1〜3の各処理時間の間、加温処理を行った。
(F)そして、加温処理が終了した後、3分間、室温で放置する冷却工程を経て、ロッドを取り除き毛髪を水洗いした。
<Hair treatment in Examples 1-18 and Comparative Examples 1-3>
Next, the following treatments (A) to (F) were performed on the prepared hair.
(A) First, the prepared hair bundle was wetted with water.
(B) Next, aqueous compositions containing the hydrolyzed keratins of Examples 1-18 and Comparative Examples 1-3 were applied to the hair and allowed to stand at room temperature for 5 minutes.
(C) Next, the hair was rinsed in running water for 30 seconds to keep the hair wet.
(D) Next, the hair was wound around the rod.
(E) Next, the hair in the state wound around the rod was immersed in warm water set to each temperature of Examples 1-18 and Comparative Examples 1-3, and Examples 1-18 and Comparative Examples 1-3 Heating treatment was performed during each treatment time.
(F) Then, after the heating treatment was completed, the rod was removed and the hair was washed with water through a cooling step of leaving at room temperature for 3 minutes.
<評価基準>
次に、上記(A)〜(F)の処理を行った毛髪に対して、上記(E)の処理における処理温度や処理時間が、カールデザインの形成、臭い、及び毛髪処理の仕上がり感に及ぼす影響について、官能評価を行った。
<Evaluation criteria>
Next, with respect to the hair subjected to the treatments (A) to (F), the treatment temperature and treatment time in the treatment (E) affect the formation of the curl design, the odor, and the finished feeling of the hair treatment. Sensory evaluation was performed about the influence.
より具体的には、(1)カール形状の強さ、(2)カール形状の持続性、(3)やわらかさ、(4)すべり感、(5)褪色・変色、及び(6)臭いの6項目について、専門パネラー10名による評価を行った。各評価項目における評価基準を以下に示す。 More specifically, (1) strength of curl shape, (2) durability of curl shape, (3) softness, (4) slipperiness, (5) discoloration / discoloration, and (6) odor 6 The items were evaluated by 10 expert panelists. The evaluation criteria for each evaluation item are shown below.
(1)カール形状の強さ
毛髪処理の最終水洗直後の状態で、カール形状の強さを比較し、下記評価基準に従って評価した。
ウェーブ効率が非常に高く、非常にしっかりとカールデザインが形成されている:◎
ウェーブ効率が高く、しっかりとカールデザインが形成されている:○
ウェーブ効率が低く、ゆるやかにカールデザインが形成されている:△
ウェーブ効率が非常に低く、非常にゆるやかにカールデザインが形成されている:×
(1) Strength of curl shape Immediately after the final water washing of the hair treatment, the strength of the curl shape was compared and evaluated according to the following evaluation criteria.
The wave efficiency is very high and the curl design is formed very firmly: ◎
The wave efficiency is high and the curl design is firmly formed: ○
The wave efficiency is low and the curl design is gently formed:
The wave efficiency is very low and the curl design is formed very gently: ×
(2)カール形状の持続性
毛髪処理から2週間程度経過した場合と同程度の状態にするために、毛髪処理の最終水洗後に乾燥させた毛髪を、60℃の温水に20分間浸漬し、時間経過処理を行った。
(2) Persistence of curled shape In order to obtain a state similar to that when about two weeks have passed since hair treatment, the hair dried after the final water washing of hair treatment is immersed in warm water at 60 ° C. for 20 minutes, and time Progressive processing was performed.
また、毛髪処理の最終水洗直後の毛髪が濡れている状態におけるカール形状(処理直後のウェット時)と、上記時間経過処理後の濡れている状態におけるカール形状(時間経過処理後のウェット時)を比較し、下記評価基準に従って評価した。
毛髪処理直後と時間経過後の差がほとんどなく、持続性が非常に高い:◎
毛髪処理直後と時間経過後の差がややあるが、持続性が高い:○
毛髪処理直後と時間経過後の差があり、持続性が低い:△
毛髪処理直後と時間経過後の差がかなりあり、持続性が非常に低い:×
In addition, the curl shape when the hair is wet immediately after the final water washing of the hair treatment (when wet immediately after the treatment) and the curl shape when wet after the time lapse treatment (when wet after the time lapse treatment) Comparison was made and evaluated according to the following evaluation criteria.
There is almost no difference between after hair treatment and after time, and the sustainability is very high:
There is a slight difference between immediately after hair treatment and after the passage of time, but sustainability is high: ○
There is a difference between immediately after the hair treatment and after time, and the sustainability is low:
There is a considerable difference between immediately after hair treatment and after the passage of time, and the durability is very low: ×
(3)やわらかさ
毛髪処理の最終水洗後に乾燥させた毛束をほぐした時の手触りのやわらかさを、下記評価基準に従って評価した。
非常にやわらかい:◎
やわらかい:○
硬さがややある:△
硬さがある:×
(3) Softness The softness of the touch when the dried hair bundle was loosened after the final water washing of the hair treatment was evaluated according to the following evaluation criteria.
Very soft: ◎
Soft: ○
Somewhat hard: △
There is hardness: ×
(4)すべり感
毛髪処理の最終水洗後に乾燥させた毛束をほぐした時の指通り(すべり感)を、下記評価基準に従って評価した。
すべりが非常によい:◎
すべりがよい:○
すべりがやや悪い:△
すべりが悪い:×
(4) Feeling of slipping When the dried hair bundle was loosened after the final water washing of the hair treatment, the fingering (slipping feeling) was evaluated according to the following evaluation criteria.
Sliding is very good: ◎
Good sliding: ○
Slip is slightly bad: △
Slip is bad: ×
(5)褪色・変色
毛髪処理の最終水洗後に乾燥させた毛束の毛髪処理前の毛束と比較しての褪色及び変色を、下記評価基準に従って評価した。
褪色及び変色が非常に少ない:◎
褪色及び変色が少ない:○
褪色及び変色がやや多い:△
褪色及び変色が多い:×
(5) Discoloration / discoloration The discoloration and discoloration of the hair bundle dried after the final water washing of the hair treatment compared to the hair bundle before the hair treatment were evaluated according to the following evaluation criteria.
Very little discoloration and discoloration: ◎
Less fading and discoloration: ○
Slightly discolored and discolored: △
Many discoloration and discoloration: ×
(6)臭い
毛髪処理の最終水洗後に乾燥させた毛束の香気(臭い)を、下記評価基準に従って評価した。
不快臭が非常に少ない:◎
不快臭が少ない:○
不快臭がやや多い:△
不快臭が多い:×
(6) Odor The aroma (odor) of the hair bundle dried after the final water washing of the hair treatment was evaluated according to the following evaluation criteria.
Very little unpleasant odor: ◎
Less unpleasant odor: ○
Slightly unpleasant odor: △
Many unpleasant odors: ×
なお、上記(1)〜(6)の各評価において、「◎」は特に優れていると評価し、「○」は優れていると評価した。また、「△」と「×」は不十分であると評価した。以上の結果を表1〜表3に示す。 In each of the evaluations (1) to (6), “「 ”was evaluated as particularly excellent, and“ ◯ ”was evaluated as excellent. Further, “Δ” and “x” were evaluated as insufficient. The above results are shown in Tables 1 to 3.
表1〜表3に示すように、第3工程における「濡れた状態の毛髪に対する加温処理」の温度が40℃よりも高く、100℃未満である実施例1〜18においては、毛髪変形処理(カールデザイン形成)の効果(即ち、上記(1)〜(2)の各評価における効果)が十分に得られるとともに、良好な仕上がり感(即ち、上記(3)〜(4)の各評価における効果)を得ることができることが分かる。また、毛髪の損傷を抑制する効果(即ち、上記(3)〜(5)の評価における効果)が得られるとともに、加温処理に起因する不快臭発生の抑制効果(即ち、上記(6)の評価における効果)を得ることができることが分かる。 As shown in Tables 1 to 3, in Examples 1 to 18 in which the temperature of “warming treatment for wet hair” in the third step is higher than 40 ° C. and lower than 100 ° C., hair deformation treatment The effect of (curl design formation) (that is, the effect in each evaluation of the above (1) to (2)) is sufficiently obtained, and a good finish feeling (that is, in each evaluation of the above (3) to (4)) (Effect) can be obtained. In addition, the effect of suppressing hair damage (that is, the effect in the evaluation of the above (3) to (5)) is obtained, and the effect of suppressing the generation of unpleasant odor caused by the heating treatment (that is, the effect of (6) above). It can be seen that an effect in the evaluation can be obtained.
一方、処理温度が40℃以下である比較例1〜2においては、不快臭の発生は抑制できるものの、処理温度が低いため、毛髪変形処理の効果(即ち、上記(1)〜(2)の各評価における効果)が不十分であることが分かる。 On the other hand, in Comparative Examples 1 and 2 in which the treatment temperature is 40 ° C. or less, although the generation of unpleasant odor can be suppressed, the treatment temperature is low, so the effect of the hair deformation treatment (that is, the above (1) to (2) It can be seen that the effect in each evaluation is insufficient.
また、処理温度が100℃以上である比較例3においては、カールデザインを確実に形成することはできるものの、処理温度が高いため、高温処理に起因して、不快臭が発生するとともに、毛髪内成分が熱ダメージを受けるため、良好な仕上がり感(即ち、上記(3)〜(4)の各評価における効果)が得られないことが分かる。 In Comparative Example 3 in which the treatment temperature is 100 ° C. or higher, the curl design can be reliably formed. However, since the treatment temperature is high, an unpleasant odor is generated due to the high temperature treatment, It can be seen that because the components are damaged by heat, a good finish feeling (that is, the effects in the evaluations (3) to (4) above) cannot be obtained.
(実施例19〜28及び比較例4〜6)
<毛髪変形用処理剤の製造>
水(イオン交換水)と各原料を配合して、表4〜表5に示す組成(質量%)を有する実施例19〜28及び比較例4〜6の毛髪変形用処理剤を製造した。
(Examples 19 to 28 and Comparative Examples 4 to 6)
<Manufacture of hair deformation treatment agent>
Water (ion-exchanged water) and each raw material were blended to produce hair deformation treatment agents of Examples 19 to 28 and Comparative Examples 4 to 6 having the compositions (mass%) shown in Tables 4 to 5.
<サンプル用の毛髪の準備>
長さ30cmのくせ毛の毛髪からなる毛束(5g)を用い、化学的処理として市販のヘアカラーによる2回の染色処理を行い、さらに市販のパーマ液で、1回パーマネントウェーブ処理後、50℃に保ったポリオキシエチレンラウリル硫酸ナトリウム水溶液(5質量%)に一晩浸漬後、十分に水洗したものをサンプル毛髪とした。
<Preparation of sample hair>
Using a hair bundle (5 g) consisting of 30 cm long hair, chemically dyed twice with a commercially available hair color, and further with a commercially available permanent solution, once with permanent wave treatment, 50 ° C. Sample hair was immersed in a polyoxyethylene lauryl sodium sulfate aqueous solution (5% by mass) kept at 1 night and washed thoroughly with water.
<実施例19〜28及び比較例4〜6における毛髪処理>
次に、準備した毛髪に対して、下記(a)〜(f)の処理を行った。
(a)まず、準備した毛髪の毛束を水で濡らした。
(b)次に、実施例19〜28及び比較例4〜6の加水分解ケラチンを含有する水性組成物を毛髪に塗布し、5分間、室温で放置した。
(c)次に、流水中で30秒間すすぎ、毛髪を濡れた状態にした。
(d)次に、毛髪をガラス板に貼り付けてストレート形状に固定した。
(e)次に、実施例19〜28及び比較例4〜6の各温度に設定した温水にストレート形状に固定した状態の毛髪を浸漬し、実施例19〜28及び比較例4〜6の各処理時間の間、加温処理を行った。
(f)そして、加温処理が終了した後、3分間、室温で放置する冷却工程を経て、ガラス板から毛髪を取り除き水洗いした。
<Hair treatment in Examples 19 to 28 and Comparative Examples 4 to 6>
Next, the following treatments (a) to (f) were performed on the prepared hair.
(A) First, the prepared hair bundle was wetted with water.
(B) Next, aqueous compositions containing the hydrolyzed keratins of Examples 19 to 28 and Comparative Examples 4 to 6 were applied to the hair and allowed to stand at room temperature for 5 minutes.
(C) Next, the hair was rinsed in running water for 30 seconds to keep the hair wet.
(D) Next, the hair was affixed to a glass plate and fixed in a straight shape.
(E) Next, the hair of the state fixed to the straight shape in the warm water set to each temperature of Examples 19-28 and Comparative Examples 4-6 was immersed, and each of Examples 19-28 and Comparative Examples 4-6 was each immersed. Warming treatment was performed during the treatment time.
(F) Then, after the heating treatment was completed, the hair was removed from the glass plate and washed with water through a cooling step of leaving at room temperature for 3 minutes.
<評価基準>
次に、上記(a)〜(f)の処理を行った毛髪に対して、上記(e)の処理における処理温度や処理時間が、ストレートデザインの形成、臭い、及び毛髪処理の仕上がり感に及ぼす影響について、官能評価を行った。
<Evaluation criteria>
Next, with respect to the hair subjected to the treatments (a) to (f), the treatment temperature and treatment time in the treatment (e) affect the formation of the straight design, the odor, and the finish of the hair treatment. Sensory evaluation was performed about the influence.
より具体的には、上述の(3)やわらかさ、(5)褪色・変色、(6)臭いの3項目に加え、(7)ストレート形状の強さ、(8)ストレート形状の持続性、及び(9)ツヤ感について、専門パネラー10名による評価を行った。(7)ストレート形状の強さ、(8)ストレート形状の持続性、及び(9)ツヤ感の評価項目における評価基準を以下に示す。 More specifically, in addition to the above three items (3) softness, (5) discoloration / discoloration, (6) odor, (7) strength of straight shape, (8) durability of straight shape, and (9) The glossiness was evaluated by 10 expert panelists. The evaluation criteria in the evaluation items of (7) strength of straight shape, (8) persistence of straight shape, and (9) gloss feeling are shown below.
(7)ストレート形状の強さ
毛髪処理の最終水洗直後に乾燥させた毛束をほぐした時のストレート形状の強さ(くせの無さ)を毛髪処理前の状態と比較し、下記評価基準に従って評価した。
くせがほとんど無い:◎
くせがやや残っている:○
くせが残っている:△
くせが全くとれていない:×
(7) Strength of straight shape Compared with the state before hair treatment, the strength of straight shape (no wrinkles) when loosening the dried hair bundle immediately after the final water washing of hair treatment, and according to the following evaluation criteria evaluated.
There is almost no habit: ◎
A little habit remains: ○
The habit remains: △
There is no habit: x
(8)ストレート形状の持続性
毛髪処理から2週間程度経過した場合と同程度の状態にするために、毛髪処理の最終水洗後に乾燥させた毛髪を、60℃の温水に20分間浸漬し、時間経過処理を行った。
(8) Persistence of straight shape In order to obtain the same level as when about 2 weeks have passed since the hair treatment, the hair dried after the final water washing of the hair treatment is immersed in warm water at 60 ° C. for 20 minutes, and the time Progressive processing was performed.
また、毛髪処理の最終水洗後に乾燥させた毛束をほぐした時のストレート形状の強さ(処理直後のくせの無さ)と、上記時間経過処理後におけるストレート形状の強さ(時間経過処理後のくせの無さ)を比較し、下記評価基準に従って評価した。
毛髪処理直後と時間経過後の差がほとんどなく、持続性が非常に高い:◎
毛髪処理直後と時間経過後の差がややあるが、持続性が高い:○
毛髪処理直後と時間経過後の差があり、持続性が低い:△
毛髪処理直後と時間経過後の差がかなりあり、持続性が非常に低い:×
In addition, the strength of the straight shape when the dried hair bundle is loosened after the final water washing of the hair treatment (no wrinkles immediately after the treatment) and the strength of the straight shape after the time lapse treatment (after the time lapse treatment) Comparison was made and evaluated according to the following evaluation criteria.
There is almost no difference between after hair treatment and after time, and the sustainability is very high:
There is a slight difference between immediately after hair treatment and after the passage of time, but sustainability is high: ○
There is a difference between immediately after the hair treatment and after time, and the sustainability is low:
There is a considerable difference between immediately after hair treatment and after the passage of time, and the durability is very low: ×
(9)ツヤ感
毛髪処理の最終水洗直後に乾燥させた毛束をほぐした後、ツヤの有無を下記評価基準に従って評価した。
ツヤが非常にある:◎
ツヤがある:○
ツヤがややない:△
ツヤがない:×
(9) Glossiness After loosening the dried hair bundle immediately after the final water washing of the hair treatment, the presence or absence of gloss was evaluated according to the following evaluation criteria.
Very shiny: ◎
There is gloss: ○
Somewhat glossy: △
No gloss: ×
なお、上記(7)〜(9)の各評価において、「◎」は特に優れていると評価し、「○」は優れていると評価した。また、「△」と「×」は不十分であると評価した。以上の結果を表4〜表5に示す。 In addition, in each evaluation of said (7)-(9), "(double-circle)" evaluated that it was excellent especially and "(circle)" evaluated that it was excellent. Further, “Δ” and “x” were evaluated as insufficient. The above results are shown in Tables 4-5.
表4〜表5に示すように、第3工程における「濡れた状態の毛髪に対する加温処理」の温度が40℃よりも高く、100℃未満である実施例19〜28においては、毛髪変形処理(ストレートデザイン形成)の効果(即ち、上記(7)〜(8)の各評価における効果)が十分に得られるとともに、良好な仕上がり感(即ち、上記(3)、(9)の各評価における効果)を得ることができることが分かる。また、毛髪の損傷を抑制する効果(即ち、上記(3)、(5)、(9)の評価における効果)が得られるとともに、加温処理に起因する不快臭発生の抑制効果(即ち、上記(6)の評価における効果)を得ることができることが分かる。 As shown in Tables 4 to 5, in Examples 19 to 28 in which the temperature of the “heating treatment for wet hair” in the third step is higher than 40 ° C. and lower than 100 ° C., hair deformation treatment The effect of (straight design formation) (that is, the effect in each evaluation of the above (7) to (8)) is sufficiently obtained, and a good finish feeling (that is, in each evaluation of (3) and (9) above) (Effect) can be obtained. In addition, the effect of suppressing hair damage (that is, the effect in the evaluation of the above (3), (5), and (9)) is obtained, and the effect of suppressing the generation of unpleasant odor caused by the heating treatment (that is, the above) It can be seen that the effect in the evaluation of (6) can be obtained.
一方、処理温度が40℃以下である比較例4〜5においては、不快臭の発生は抑制できるものの、処理温度が低いため、毛髪変形処理の効果(即ち、上記(7)〜(8)の各評価における効果)が不十分であることが分かる。 On the other hand, in Comparative Examples 4 to 5 in which the treatment temperature is 40 ° C. or lower, although the generation of unpleasant odor can be suppressed, the treatment temperature is low, so the effects of the hair deformation treatment (that is, (7) to (8) above). It can be seen that the effect in each evaluation is insufficient.
また、処理温度が100℃以上である比較例6においては、ストレートデザインを確実に形成することはできるものの、処理温度が高いため、高温処理に起因して、不快臭が発生するとともに、毛髪内成分が熱ダメージを受けるため、良好な仕上がり感(即ち、上記(3)、(9)の各評価における効果)が得られないことが分かる。 Further, in Comparative Example 6 in which the treatment temperature is 100 ° C. or higher, although a straight design can be reliably formed, the treatment temperature is high. It can be seen that since the components are damaged by heat, good finish feeling (that is, effects in the evaluations of (3) and (9) above) cannot be obtained.
以上説明したように、本発明は、パーマネントウェーブ処理に代表される毛髪処理に、特に有用である。 As described above, the present invention is particularly useful for hair treatment typified by permanent wave treatment.
Claims (4)
前記水性組成物が塗布された毛髪にカールデザインまたはストレートデザインを形成する第2工程と、
前記カールデザインまたはストレートデザインが形成された毛髪に対して、該毛髪が水分を保持した状態で、40℃よりも高く、100℃未満の温度で加温処理を行う第3工程と
を少なくとも備えることを特徴とする毛髪処理方法。 A first step of applying an aqueous composition containing hydrolyzed keratin to the hair;
A second step of forming a curl design or a straight design on the hair coated with the aqueous composition;
And at least a third step of performing heating treatment at a temperature higher than 40 ° C. and lower than 100 ° C. with respect to the hair on which the curl design or straight design is formed. A hair treatment method characterized by the above.
加水分解ケラチンを含有する水性組成物を前記カールデザインまたはストレートデザインが形成された毛髪に塗布する第2工程と、
前記水性組成物が塗布された毛髪に対して、該毛髪が水分を保持した状態で、40℃よりも高く、100℃未満の温度で加温処理を行う第3工程と
を少なくとも備えることを特徴とする毛髪処理方法。 A first step of forming a curl or straight design on the hair;
A second step of applying an aqueous composition containing hydrolyzed keratin to the hair having the curl or straight design formed thereon;
And a third step of performing a heating treatment at a temperature higher than 40 ° C. and lower than 100 ° C. in a state where the hair retains moisture with respect to the hair coated with the aqueous composition. A hair treatment method.
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