JP6548874B2 - Method and system for cleaning contaminated soil - Google Patents

Method and system for cleaning contaminated soil Download PDF

Info

Publication number
JP6548874B2
JP6548874B2 JP2014171112A JP2014171112A JP6548874B2 JP 6548874 B2 JP6548874 B2 JP 6548874B2 JP 2014171112 A JP2014171112 A JP 2014171112A JP 2014171112 A JP2014171112 A JP 2014171112A JP 6548874 B2 JP6548874 B2 JP 6548874B2
Authority
JP
Japan
Prior art keywords
slurry
pump
pipe
piping
soil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2014171112A
Other languages
Japanese (ja)
Other versions
JP2016043332A (en
Inventor
学 武石
学 武石
一弥 木川田
一弥 木川田
佐藤 博
博 佐藤
忠弘 河原
忠弘 河原
川崎 一弘
一弘 川崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokyo Electric Power Co Inc
Hazama Ando Corp
Original Assignee
Tokyo Electric Power Co Inc
Hazama Ando Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo Electric Power Co Inc, Hazama Ando Corp filed Critical Tokyo Electric Power Co Inc
Priority to JP2014171112A priority Critical patent/JP6548874B2/en
Publication of JP2016043332A publication Critical patent/JP2016043332A/en
Application granted granted Critical
Publication of JP6548874B2 publication Critical patent/JP6548874B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Processing Of Solid Wastes (AREA)

Description

本発明は、放射性物質、重金属等の有害物質に汚染された汚染土壌の洗浄方法及びシステムに関する。   The present invention relates to a method and system for cleaning contaminated soil contaminated with harmful substances such as radioactive substances and heavy metals.

放射性物質、重金属等の有害物質に汚染された土壌において、有害物質は土粒子の内部にまでは侵入し難いため、主に土粒子の表面付近に付着したり吸着したりしている。よって、有害物質に汚染された土壌の汚染濃度をその構成要素の土粒子の粒子径別に比較した場合、比表面積の大きい細粒分ほど高濃度となり、比表面積の小さい粗粒分ほど低濃度になる。そこで、汚染土壌を洗浄する場合、通常は、元の土壌に水を加えて解砕し(すなわち、当初の土壌に含まれている細粒分の塊を解し、粗粒分に付着している細粒分を剥離させて、土粒子をバラバラにし)た上で、分級により粗粒分のみを取り出すという方法を取る。なお、粗粒分を取り出した後の濁水には元の土壌の細粒分が含まれており、汚染濃度が高いため、濁水処理設備で細粒分を汚泥として回収し、脱水の上、高濃度汚染物として処分し、細粒分除去後の処理水は洗浄に再利用する。かかる方法では、解砕設備としてウォータージェット装置、ドラムウォッシャー等、分級設備として水平バケット式分級機、スパイラル式分級機、サイクロン式分級機等、濁水処理設備として凝集沈殿設備等がよく用いられる。この種の汚染土壌の洗浄方法に関連する技術が例えば特許文献1などにより提案されている。
また、この方法で取り出された粗粒分は、通常、汚染濃度が目標値以下となり、洗浄済み土となるところ、元の汚染土壌の濃度や有害物質の種類によっては、目標値以下の濃度にならないことがある。このような場合、当該汚染土壌は洗浄に適さない土壌であるとして洗浄対象から外されることが多い。しかし、その一方で何とか汚染除去効果を上げて目標値以下の濃度に下げる試みも行われている。この場合、粗粒分のみになった濃度が目標値以下にならないのであるから、濃度をより低下させるために、有害物質を多く付着、吸着している粗粒分の表面を削り取ることになる。粗粒分の表面を削り取るには、例えば商品名でハリケーンと呼ばれる特殊磨砕機、キャビテーションジェット等の装置が使用されており、また、表面切削を促進するための薬剤を併用することも行われている。
In the soil contaminated with harmful substances such as radioactive substances and heavy metals, the harmful substances are difficult to intrude into the inside of the soil particles, so they are mainly attached and adsorbed near the surface of the soil particles. Therefore, when the contamination concentration of the soil contaminated with harmful substances is compared according to the particle size of the soil particles of the component, the larger the fine particle with a large specific surface area, the higher the concentration, and the smaller the coarse particle with a small specific surface area Become. Therefore, when washing the contaminated soil, usually, water is added to the original soil to crush it (ie, the clumps of fine particles contained in the original soil are broken up and attached to the coarse particles) The fine particles are peeled off, and the soil particles are broken up, and then only the coarse particles are taken out by classification. The turbid water after taking out the coarse particles contains fine particles of the original soil, and the contamination concentration is high. Therefore, the fine particles are recovered as sludge in the turbid water treatment facility and dewatered to a high level. Dispose of as a concentration contaminant and reuse the treated water after fine particle removal for cleaning. In such a method, a water jet apparatus, a drum washer, etc. as a crushing equipment, a horizontal bucket type classifier as a classification equipment, a spiral type classifier, a cyclone type classifier, etc., and a coagulation sedimentation equipment as a turbid water treatment equipment are often used. The technique related to the cleaning method of this kind of contaminated soil is proposed by patent document 1 etc., for example.
In addition, the coarse particle fraction extracted by this method usually has a contamination concentration below the target value and becomes cleaned soil, but depending on the concentration of the original contaminated soil or the type of harmful substance, the concentration does not exceed the target value. There is nothing to do. In such a case, the contaminated soil is often excluded from being cleaned as soil that is not suitable for cleaning. However, on the other hand, attempts have been made to increase the decontamination effect somehow and to lower the concentration below the target value. In this case, since the concentration of the coarse particles only does not fall below the target value, the surface of the coarse particles adhering to and adsorbed with a large amount of harmful substances is scraped in order to lower the concentration. In order to scrape off the surface of coarse particles, for example, a device such as a special grinder called hurricane by the trade name, cavitation jet, etc. is used, and it is also carried out to use an agent for promoting surface cutting in combination. There is.

ところが、このような従来の汚染土壌の洗浄方法では、これに用いる土壌洗浄プラントが、基本的な構成だけでも、解砕設備、分級設備、濁水処理設備と大掛かりな設備が必要であり、これに加えて、粗粒分の表面切削関連の設備まで備えるとなると、極めて大規模なプラントになってしまい、イニシャルコスト、ランニングコストが共に増加して、実用性に乏しいものになる。   However, with such conventional methods for cleaning contaminated soil, even if the soil cleaning plant used for this is only the basic configuration, crushing equipment, classification equipment, turbid water treatment equipment and large-scale equipment are necessary, In addition, if equipment for surface cutting related to coarse particles is provided, the plant becomes a very large scale, and both initial costs and running costs increase, resulting in poor practicability.

そこで、本願発明者らは、先の出願(特許文献2)により、従来のように特殊磨砕機や薬剤等、粗粒分の表面切削関連の機器、機材を使用することなく、汎用的で安価な機器、機材のみを用いた極めて簡単な設備で、粗粒分の表面切削を可能とし、洗浄効果を高めることができ、洗浄プラントの小規模化及び洗浄コストの低減に寄与することのできる汚染土壌の洗浄方法及びシステムを提案した。
この洗浄方法は、有害物質で汚染された土壌と水とを混ぜたスラリーを容器に入れて、容器内のスラリーをポンプにより吸引し、ポンプから輸送配管を経由して搬送し、容器内に戻すことにより、容器内のスラリーを容器、ポンプ、輸送配管の間で循環させ、スラリーの循環をポンプの連続運転により繰り返し、一定時間循環させた後のスラリーから分級により土壌の粗粒分を取り出し、有害物質の濃度が元の土壌に比べて低濃度になった粗粒分を得るようにしたもので、かかる洗浄方法により、所期の目的を実現することができる。
また、この洗浄システムは、有害物質で汚染された土壌と水とを混ぜたスラリーを入れるための容器と、容器内のスラリーを吸引し送り出すためのポンプと、一端がポンプに接続されて、他端はそこから放出されたスラリーが容器内に戻るように配置され、ポンプから送り出されたスラリーを搬送するための輸送配管とを備え、容器内に入れたスラリーを、ポンプの連続運転により、容器、ポンプ、輸送配管の間で繰り返し循環させるようにしたもので、かかる洗浄システムにより、所期の目的を実現することができる。
Therefore, the inventors of the present application, according to the prior application (Patent Document 2), are versatile and inexpensive without using surface grinding related devices and equipment such as special grinders and medicines as in the prior art. Contamination that can make surface cutting of coarse particles possible, enhance cleaning effects, and contribute to the reduction of the scale of cleaning plants and reduction of cleaning costs with extremely simple equipment using only large equipment and equipment A soil cleaning method and system was proposed.
In this cleaning method, a slurry obtained by mixing soil and water contaminated with harmful substances is placed in a container, the slurry in the container is sucked by a pump, conveyed from a pump through a transportation pipe, and returned to the container. Thus, the slurry in the container is circulated between the container, the pump, and the transport piping, circulation of the slurry is repeated by continuous operation of the pump, and coarse particles of soil are taken out by classification from the slurry after being circulated for a fixed time. The purpose of the present invention is to achieve the intended purpose by obtaining the coarse particle fraction in which the concentration of harmful substances is lower than that of the original soil.
In addition, this cleaning system includes a container for containing the slurry mixed with soil and water contaminated with harmful substances, a pump for sucking and discharging the slurry in the container, and one end connected to the pump, The end is disposed so that the slurry discharged therefrom is returned to the container, and the transport piping for conveying the slurry discharged from the pump is provided, and the slurry contained in the container is continuously pumped by the pump. And the pump and the transport piping, and the intended purpose can be realized by such a cleaning system.

特開2005−28290公報JP, 2005-28290, A 特願2013−37057Japanese Patent Application No. 2013-37057

本願発明者らは、上記特許文献2の汚染土壌の洗浄方法及びシステムを用いて、放射性物質などの有害物質に汚染された汚染土壌の洗浄を行った結果、所期の効果が得られたことを確認したが、他面で、この洗浄方法及びシステムでは、土粒子を循環して洗浄処理するために、次のような課題があることが分かった。
(1)この洗浄方法及びシステムでは、土粒子を循環して洗浄処理するため、水を入れ、土を入れ、一定時間混ぜて取り出すというバッチ式の処理を採らざるを得ず、このため、処理時間に一定の時間を要し、処理時間の短縮化が難しい。また、バッチ処理のため、一回毎の処理能力には限界があり、装置全体を大型化しない限り、処理能力の拡大、向上は難しい。
(2)この洗浄方法及びシステムでは、土粒子を循環して洗浄処理するため、土粒子を磨砕するためには、一定の洗浄時間(15分程度)が必要であり、この一定の洗浄時間を確保するために、水槽、循環用の配管などスラリーを循環するための設備が必要で、設備のさらなる小規模化、簡略化、及び設備の小規模化、簡略化によるコストの低減は困難である。
The inventors of the present invention used the cleaning method and system of the contaminated soil of the above-mentioned patent document 2, and as a result of cleaning the contaminated soil contaminated with harmful substances such as radioactive substances, expected effects were obtained. On the other hand, in this cleaning method and system, it was found that there are the following problems for circulating and cleaning the soil particles.
(1) In this cleaning method and system, since soil particles are circulated and washed, it is necessary to adopt a batch type treatment in which water is added, soil is added, mixed for a certain period of time, and taken out. It takes a certain amount of time and it is difficult to shorten the processing time. In addition, because of batch processing, there is a limit to the processing capacity of each operation, and it is difficult to expand and improve the processing capacity unless the entire apparatus is upsized.
(2) In this cleaning method and system, since soil particles are circulated and washed, a certain cleaning time (about 15 minutes) is necessary to grind the soil particles, and this constant cleaning time In order to ensure water quality, it is necessary to have facilities for circulating the slurry, such as a water tank and piping for circulation, and it is difficult to reduce the cost by further downsizing the facilities, simplifying the facilities, and downsizing the facilities and simplification. is there.

本発明は、上記従来の課題を解決するものであり、上記汚染土壌の洗浄方法及びシステムにおいて、土粒子の磨砕効果を高めて洗浄処理時間を短縮すること、さらに、スラリー循環させることなく、一度の配管通過で洗浄処理を完了させ、連続処理を行なえること、設備のさらなる小規模化、簡略化を図り、コストの低減に資することなど、を目的とする。   The present invention solves the above-mentioned conventional problems, and in the cleaning method and system of the above-mentioned contaminated soil, enhancing the grinding effect of the soil particles and shortening the cleaning processing time, and further, without circulating the slurry. The purpose is to complete the cleaning process by passing the pipe once and perform the continuous process, to further reduce the size of the equipment, to simplify, and to reduce the cost.

上記目的を達成するために、本発明の汚染土壌の洗浄方法(1)は、
放射性物質で汚染された土壌と水とを混ぜたスラリーをポンプで吸引し、配管に通して撹拌混合させながら流動させることにより、放射性物質で汚染された土壌を洗浄する汚染土壌の洗浄方法であって、
前記ポンプに砂分まで吸引搬送可能なポンプを採用し、
前記配管を全体として略L字形に形成し、垂直方向に向けて立ち上げられる垂直方向の配管と水平方向に向けて延ばされる水平方向の配管とにより構成し、前記配管の一部又は全部に、スラリーを前記配管内で分割分散可能にかつ前記配管の内面に繰り返し衝突可能に、前記配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は前記配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーをスラリー中の土粒子の磨砕に必要な磨砕時間を確保した長さに設け、
前記ポンプの連続運転によりスラリーを前記ポンプ、前記スタティックミキサー付きの前記配管に通してスラリー中の土粒子を磨砕する、
ことを要旨とする。
上記目的を達成するために、本発明の汚染土壌の洗浄方法(2)は、
放射性物質で汚染された土壌と水とを混ぜたスラリーを容器に入れて、前記容器内のスラリーをポンプにより吸引し、スラリーを配管に通して前記容器内に送還することにより、前記容器内のスラリーを前記容器、前記ポンプ、前記配管の間で循環し、前記スラリーの循環を繰り返すことにより、放射性物質で汚染された土壌を洗浄する汚染土壌の洗浄方法であって、
前記ポンプに砂分まで吸引搬送可能なポンプを採用し、
前記配管を全体として略逆U字形又は略逆J字形に形成し、前記配管の一部又は全部に、スラリーを前記配管内で分割分散可能にかつ前記配管の内面に繰り返し衝突可能に、前記配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は前記配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーを設け、
前記ポンプの連続運転により、前記容器内に入れたスラリーを前記容器、前記ポンプ、前記スタティックミキサー付きの配管の間で繰り返し循環させ、スラリー中の土粒子を磨砕する、
ことを要旨とする。
In order to achieve the above object, the method (1) for cleaning contaminated soil of the present invention is
A method for cleaning contaminated soil in which radioactive substance-contaminated soil is cleaned by aspirating slurry mixed with radioactive substance-contaminated soil and water through a pipe and flowing it while stirring and mixing. ,
A pump capable of suction and transfer to the sand is adopted as the pump,
The pipe as a whole is formed into a substantially L shape, and is constituted by a vertical pipe which is vertically raised and a horizontal pipe which is horizontally extended, and a part or all of the pipe, The inner surface of the pipe is formed into a curved shape or an uneven shape that changes the flow of the slurry so that the slurry can be divided and dispersed in the pipe and repeatedly collides with the inner surface of the pipe, or the pipe can be flowed with the slurry Provide a static mixer consisting of bending, or a combination of these, to a length that changes the grinding time required for grinding the soil particles in the slurry .
The continuous operation of the pump passes the slurry through the pump and the pipe with the static mixer to grind particles in the slurry.
It shall be the gist.
In order to achieve the above object, the method (2) for cleaning contaminated soil of the present invention is
The slurry mixed with the soil contaminated with radioactive material and water is placed in a container, the slurry in the container is sucked by a pump, and the slurry is sent through piping to the container to return the inside of the container. A method for cleaning contaminated soil, wherein the slurry is circulated between the container, the pump, and the piping, and the soil contaminated with radioactive material is cleaned by repeating circulation of the slurry.
A pump capable of suction and transfer to the sand is adopted as the pump,
The piping as a whole is formed in a substantially inverted U-shape or a substantially inverted J-shape, and the slurry can be divided and dispersed in the piping to a part or all of the piping and the piping can be repeatedly collided with the inner surface of the piping A static mixer is provided, which is formed in a curved shape or uneven shape that changes the flow of the slurry, or by bending the pipe into a waveform that changes the flow of the slurry, or a combination thereof.
By continuous operation of the pump, the slurry contained in the vessel is repeatedly circulated among the vessel, the pump, and the piping with the static mixer to grind the soil particles in the slurry.
Make it a gist.

上記目的を達成するために、本発明の汚染土壌の洗浄システム(1)は、
放射性物質で汚染された土壌と水とを混ぜたスラリーを吸引し送り出すためのポンプと、
前記ポンプにより吸引し送り出されたスラリーを撹拌混合して流動させるための配管と、
を備え、
前記ポンプは砂分まで吸引搬送可能なポンプとし、
前記配管は全体が略L字形に形成されて、垂直方向に向けて立ち上げられる垂直方向の配管と水平方向に向けて延ばされる水平方向の配管とからなり、前記配管の一部又は全部に、スラリーを前記配管内で分割分散可能にかつ前記配管の内面に繰り返し衝突可能に、前記配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は前記配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーがスラリー中の土粒子の磨砕に必要な磨砕時間を確保した長さにして設けられ
前記ポンプの連続運転によりスラリーを前記ポンプ、前記スタティックミキサー付きの前記配管に通してスラリー中の土粒子を磨砕する、
ことを要旨とする。
上記目的を達成するために、本発明の汚染土壌の洗浄システム(2)は、
放射性物質で汚染された土壌と水とを混ぜたスラリーを入れるための容器と、
前記容器内のスラリーを吸引し送り出すためのポンプと、
前記ポンプにより吸引し送り出されたスラリーを通過させ、前記容器に送還する配管と、
を備え、
前記ポンプは砂分まで吸引搬送可能なポンプとし、
前記配管は全体が略逆U字形又は略逆J字形に形成されて、前記配管の一部又は全部に、スラリーを前記配管内で分割分散可能にかつ前記配管の内面に繰り返し衝突可能に、前記配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は前記配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーが設けられ
前記ポンプの連続運転により、前記容器内に入れたスラリーを前記容器、前記ポンプ、前記スタティックミキサー付きの配管の間で繰り返し循環させ、スラリー中の土粒子を磨砕する、
ことを要旨とする。
In order to achieve the above object, the contaminated soil cleaning system (1) of the present invention is
A pump for suctioning and delivering a slurry mixed with soil and water contaminated with radioactive material;
Piping for stirring, mixing and flowing the slurry sucked and sent out by the pump;
Equipped with
The pump is a pump capable of suction and transfer to the sand,
The piping is generally formed in a substantially L-shape, and includes a vertical piping that is vertically raised and a horizontal piping that is horizontally extended, and a part or all of the piping, The inner surface of the pipe is formed into a curved shape or an uneven shape that changes the flow of the slurry so that the slurry can be divided and dispersed in the pipe and repeatedly collides with the inner surface of the pipe, or the pipe can be flowed with the slurry A static mixer, which is bent in a wave form or a combination of these, is provided with a length that secures the grinding time required for grinding the soil particles in the slurry ,
The continuous operation of the pump passes the slurry through the pump and the pipe with the static mixer to grind particles in the slurry.
It shall be the gist.
In order to achieve the above object, the contaminated soil cleaning system (2) of the present invention is
A container for containing a slurry of soil and water contaminated with radioactive material;
A pump for suctioning and delivering the slurry in the container;
Piping for passing the slurry sucked and sent out by the pump and sending it back to the container;
Equipped with
The pump is a pump capable of suction and transfer to the sand,
The whole of the pipe is formed in a substantially inverted U-shape or a substantially inverted J-shape so that the slurry can be divided and dispersed in part or all of the pipe and can repeatedly collide with the inner surface of the pipe. There is provided a static mixer in which the inner surface of the pipe is formed into a curved shape or an uneven shape which changes the flow of slurry, or the pipe is bent into a waveform which changes the flow of slurry or a combination thereof.
By continuous operation of the pump, the slurry contained in the vessel is repeatedly circulated among the vessel, the pump, and the piping with the static mixer to grind the soil particles in the slurry.
Make it a gist.

本発明の汚染土壌の洗浄方法(1)によれば、ポンプに砂分まで吸引搬送可能なポンプを採用し、配管を全体として略L字形に形成し、垂直方向に向けて立ち上げられる垂直方向の配管と水平方向に向けて延ばされる水平方向の配管とにより構成し、配管の一部又は全部に、スラリーを配管内で分割分散可能にかつ配管の内面に繰り返し衝突可能に、配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーをスラリー中の土粒子の磨砕に必要な磨砕時間を確保した長さに設け、ポンプの連続運転によりスラリーをポンプ、スタティックミキサー付きの配管に通してスラリー中の土粒子を磨砕するので、搬送用の(上記のようなスタティックミキサーを有しない)配管を用いた場合に比べて、土粒子の磨砕効果を高めて、洗浄処理時間を短縮することができる。また、この場合、配管を全体として略L字形に形成し、垂直方向の配管と水平方向の配管とにより構成したこと、配管の一部又は全部に、スタティックミキサーをスラリー中の土粒子の磨砕に必要な磨砕時間を確保した長さに形成したことで、スラリーを一度の配管通過で洗浄できるようにしスラリーを循環させるための設備を不要とし、全体として設備のさらなる小規模化、簡略化を図り、コストの低減に資することができる。
本発明の汚染土壌の洗浄方法(2)によれば、ポンプに砂分まで吸引搬送可能なポンプを採用し、配管を全体として略逆U字形又は略逆J字形に形成し、配管の一部又は全部に、スラリーを配管内で分割分散可能にかつ配管の内面に繰り返し衝突可能に、配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーを設け、ポンプの連続運転により、容器内に入れたスラリーを容器、ポンプ、スタティックミキサー付きの配管の間で繰り返し循環させ、スラリー中の土粒子を磨砕するので、搬送用の(上記のようなスタティックミキサーを有しない)配管を用いた場合に比べて、土粒子の磨砕効果を高めて、洗浄処理時間を短縮することができる。
また、この洗浄方法(2)は、本願発明者らによる先の出願(特願2013−37057)の洗浄方法を一部改良したもので、容器内に入れたスラリーを、ポンプの連続運転により、容器、ポンプ、配管の間で繰り返し循環させ、一定時間循環させた後のスラリーから分級により土壌の粗粒分を取り出し、有害物質の濃度が元の土壌に比べて低濃度になった粗粒分を得るようにした点では共通しているので、先の出願の洗浄方法及びシステムと同様に、汚染土壌の洗浄において、従来のように特殊磨砕機や薬剤等、粗粒分の表面切削関連の機器、機材を使用することなく、汎用的で安価な機器、機材のみを用いた極めて簡単な設備で、粗粒分の表面切削を可能とし、洗浄効果を高めることができ、洗浄プラントの小規模化及び洗浄コストの低減に寄与することができる。
According to the method (1) for cleaning contaminated soil of the present invention, a pump capable of suctioning and transporting to sand is adopted as the pump, and the piping as a whole is formed into a substantially L shape and can be raised vertically. The inner surface of the pipe can be divided and dispersed in the pipe in a part or all of the pipe, and the inner surface of the pipe can be repeatedly collided with the inner surface of the pipe. A static mixer consisting of curved surface shape or uneven shape that changes the flow of slurry, or bending piping to change the flow of slurry, or a combination of these is used to grind earth particles in the slurry It provided the length secured between a grinding time necessary, pump a slurry by continuous operation of the pump, since the ground soil particles in the slurry through a pipe with a static mixer, For feeding (no static mixer as described above) in comparison with the case of using a pipe, to enhance the grinding effect of the soil particles, it is possible to shorten the cleaning time. Also, in this case, the piping as a whole is formed in a substantially L-shape, and is constituted by the piping in the vertical direction and the piping in the horizontal direction. by forming a length secured between a grinding time required to further scale of the as slurry can be cleaned in one pipe passage is unnecessary equipment for circulating the slurry as a whole facility, It is possible to simplify and contribute to cost reduction.
According to the method (2) for cleaning contaminated soil of the present invention, a pump capable of sucking and transporting sand to the pump is adopted, and the pipe as a whole is formed in a substantially inverted U-shape or a substantially inverted J-shape. Alternatively, the slurry can be divided and dispersed in the pipe and repeatedly collided with the inner surface of the pipe, the inner surface of the pipe is formed into a curved shape or uneven shape that changes the flow of the slurry, or the pipe is the slurry flow Add a static mixer that bends or combines them into a corrugated shape, and by continuous operation of the pump, the slurry placed in the container is circulated repeatedly between the container, the pump, and the piping with the static mixer. since grinding the soil particles in, for transporting (without a static mixer as described above) in comparison with the case of using a pipe, to enhance the grinding effect of the soil particles They are possible to shorten the cleaning time.
In addition, this cleaning method (2) is a modification of the cleaning method of the previous application (Japanese Patent Application No. 2013-37057) by the present inventors (Japanese Patent Application No. 2013-37057). The coarse particles in the soil are removed from the slurry by classification after being circulated repeatedly between the container, pump, and piping, and circulated for a fixed time, and the concentration of harmful substances is lower than in the original soil. As in the cleaning method and system of the previous application, in the cleaning of contaminated soil, it is related to surface cutting related to coarse particles such as special grinders and medicines as in the prior art. It is possible to cut the surface of coarse particles with extremely simple equipment using only general-purpose and inexpensive equipment and equipment without using equipment and equipment, and it is possible to enhance the cleaning effect, and the scale of the cleaning plant is small. And cleaning costs It can contribute to.

本発明の汚染土壌の洗浄システム(1)によれば、ポンプは砂分まで吸引搬送可能なポンプとし、配管は全体が略L字形に形成されて、垂直方向に向けて立ち上げられる垂直方向の配管と水平方向に向けて延ばされる水平方向の配管とからなり、配管の一部又は全部に、スラリーを配管内で分割分散可能にかつ配管の内面に繰り返し衝突可能に、配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーがスラリー中の土粒子の磨砕に必要な磨砕時間を確保した長さにして設けられポンプの連続運転によりスラリーをポンプ、スタティックミキサー付きの配管に通してスラリー中の土粒子を磨砕するので、搬送用の(上記のようなスタティックミキサーを有しない)配管を用いた場合に比べて、土粒子の磨砕効果を高めて洗浄処理時間を短縮することができる。また、この場合、配管を全体として略L字形に形成し、垂直方向の配管と水平方向の配管とにより構成したこと、配管の一部又は全部に、スタティックミキサーをスラリー中の土粒子の磨砕に必要な磨砕時間を確保した長さに形成したことで、スラリーを一度の配管通過で洗浄できるようにしてスラリーを循環させるための設備を不要とし、全体として設備のさらなる小規模化、簡略化を図り、コストの低減に資することができる。
本発明の汚染土壌の洗浄システム(2)によれば、ポンプは砂分まで吸引搬送可能なポンプとし、配管は全体が略逆U字形又は略逆J字形に形成されて、配管の一部又は全部に、スラリーを配管内で分割分散可能にかつ配管の内面に繰り返し衝突可能に、配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサー設けられポンプの連続運転により、容器内に入れたスラリーを容器、ポンプ、スタティックミキサー付きの配管の間で繰り返し循環させ、スラリー中の土粒子を磨砕するので、搬送用の(上記のようなスタティックミキサーを有しない)配管を用いた場合に比べて、土粒子の磨砕効果を高めて洗浄処理時間を短縮することができる。
また、この洗浄システム(2)は、本願発明者らによる先の出願(特願2013−37057)の洗浄システムを一部改良したもので、容器内に入れたスラリーを、ポンプの連続運転により、容器、ポンプ、配管の間で繰り返し循環させ、一定時間循環させた後のスラリーから分級により土壌の粗粒分を取り出し、有害物質の濃度が元の土壌に比べて低濃度になった粗粒分を得るようにした点では共通しているので、先の出願の洗浄方法及びシステムと同様に、汚染土壌の洗浄において、従来のように特殊磨砕機や薬剤等、粗粒分の表面切削関連の機器、機材を使用することなく、汎用的で安価な機器、機材のみを用いた極めて簡単な設備で、粗粒分の表面切削を可能とし、洗浄効果を高めることができ、洗浄プラントの小規模化及び洗浄コストの低減に寄与することができる。
According to the contaminated soil cleaning system (1) of the present invention, the pump is a pump capable of sucking and transporting sand, and the piping is generally formed in a substantially L shape and can be raised vertically. It consists of piping and horizontal piping extended horizontally , and the slurry can be divided and dispersed in part or all of the piping within the piping and can repeatedly collide with the inner surface of the piping. A static mixer consisting of curved surface shape or uneven shape that changes the flow, or bending the pipe into a waveform that changes the flow of the slurry, or a combination of these is necessary for grinding the soil particles in the slurry provided the length secured between grinding time, the slurry pump, to ground the soil particles in the slurry through a pipe with a static mixer by continuous operation of the pump , As compared with the case of using a pipe (not having a static mixer such as described above) for conveying, to shorten the cleaning time to enhance the grinding effect of the soil particles. In this case, it formed into a substantially L-shape as a whole piping that is constituted by a vertical pipe and a horizontal direction of the pipe, a part or the whole of the pipe, ground static mixers of the soil particles in the slurry The length of the grinding time required for the installation is enough to make it possible to wash the slurry by passing it through a single pipe , eliminating the need for equipment for circulating the slurry, further downsizing the equipment as a whole , simplification To contribute to cost reduction.
According to the contaminated soil cleaning system (2) of the present invention, the pump is a pump capable of sucking and transporting sand, and the piping is generally formed in a substantially inverted U-shape or a substantially inverted J-shape, In all, the slurry can be divided and dispersed in the pipe and can be repeatedly collided with the inner surface of the pipe, the inner surface of the pipe is formed into a curved shape or uneven shape that changes the flow of the slurry, or the pipe is made into the slurry flow bending the waveform to give a change, or a static mixer comprising a combination of these is provided by continuous operation of the pump, the slurry was placed in a container vessel, a pump, is repeatedly circulated between the pipe with a static mixer, the slurry since grinding the soil particles in, for transporting (without a static mixer as described above) in comparison with the case of using a pipe, high attrition effect of soil particles The cleaning time can be shortened Te.
Further, this cleaning system (2) is a modification of the cleaning system of the prior application (Japanese Patent Application No. 2013-37057) by the present inventors (Japanese Patent Application No. 2013-37057). The coarse particles in the soil are removed from the slurry by classification after being circulated repeatedly between the container, pump, and piping, and circulated for a fixed time, and the concentration of harmful substances is lower than in the original soil. As in the cleaning method and system of the previous application, in the cleaning of contaminated soil, it is related to surface cutting related to coarse particles such as special grinders and medicines as in the prior art. It is possible to cut the surface of coarse particles with extremely simple equipment using only general-purpose and inexpensive equipment and equipment without using equipment and equipment, and it is possible to enhance the cleaning effect, and the scale of the cleaning plant is small. And washing It can contribute to a reduction of the bets.

本発明の第1の実施の形態における汚染土壌の洗浄方法及びシステムを示す図The figure which shows the cleaning method and system of contaminated soil in a 1st embodiment of the present invention. 本発明の第2の実施の形態における汚染土壌の洗浄方法及びシステムを示す図The figure which shows the cleaning method and system of the contaminated soil in 2nd Embodiment of this invention. 同方法及びシステムの要部を拡大して示す図The figure which expands and shows the principal part of the method and system

以下、この発明を実施するための形態について図を用いて説明する。
図1に本発明の第1の実施の形態による汚染土壌の洗浄方法及びシステムを併せて示している。
図1に示すように、この洗浄方法では、放射性物質、重金属等の有害物質で汚染された土壌(以下、単に汚染土壌という。)と水とを混ぜたスラリーを、ポンプ12により吸引し、スラリーを撹拌混合して流動させるためのスタティックミキサー14を有する配管13に通して磨砕する。
そして、この洗浄方法は洗浄システムにより実現される。この洗浄システムは、汚染土壌と水とを混ぜたスラリーを吸引し送り出すためのポンプ12と、ポンプ12により吸引し送り出されたスラリーを撹拌混合して流動させるためのスタティックミキサー14を有する配管13とにより構成される。
この場合、ポンプ12は砂分まで吸引搬送可能なポンプで、水中に設置して使用する場合は水中ポンプ、それ以外では吸引ポンプが採用される。なお、ここでは、水中ポンプ(サンドポンプ)を採用している。
また、配管13は汚染土壌と水とを混ぜたスラリーを循環搬送させるのに適した材質、径、長さを有するもので、この配管13は、特に、配管の一部又は全部がスタティックミキサー14になっている。このスタティックミキサー14は、スラリーの流れに変化を付けて積極的に撹拌混合可能に、管の内面に曲面形状若しくは凹凸形状が形成されて、又は管が波形に曲げられて、又はこれらの組み合わせにより構成される。この場合、配管13は全体が略L字形に形成されて、垂直方向に向けて立ち上げられる垂直方向の配管131と、水平方向に向けて延ばされる水平方向の配管132とからなり、水平方向の配管132のうち中間部分の広範囲に亘って、土粒子の磨砕に必要な磨砕時間を確保した長さを有するスタティックミキサー14が設けられる。このスタティックミキサー14は管の内面が曲面形状、ここでは螺旋状の羽根が付けられて、スラリーを螺旋状の各羽根を通過する毎に分割分散し、また、螺旋状の羽根の案内により、管内面の各部に衝突を繰り返しながら流動させるなど、管内で積極的に撹拌混合する構造になっている。なお、この場合、螺旋状の各羽根をねじれの方向を部分的に反対に変えてもよく、また、螺旋状の羽根はそれぞれが異なる大きさ、形状でもよく、このようにすることで、スラリーの流れにさらに変化を付けることができる。
この洗浄システムはかかる構成を備え、スラリーを、ポンプ12により、スタティックミキサー14を有する配管13に連続的に通して磨砕するようになっている。
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
FIG. 1 also shows the method and system for cleaning contaminated soil according to the first embodiment of the present invention.
As shown in FIG. 1, in this cleaning method, a slurry of a mixture of soil contaminated with radioactive substances, harmful substances such as heavy metals (hereinafter simply referred to as contaminated soil) and water is sucked by a pump 12 and the slurry is used. The mixture is ground through a pipe 13 having a static mixer 14 for stirring, mixing and flowing.
And this cleaning method is realized by the cleaning system. This cleaning system includes a pump 12 for suctioning and feeding a slurry obtained by mixing contaminated soil and water, and a pipe 13 having a static mixer 14 for stirring, mixing and flowing the slurry sucked and fed by the pump 12. It consists of
In this case, the pump 12 is a pump capable of suction and transfer to the sand, and a submersible pump is used when installed in water and used, and a suction pump is used otherwise. Here, a submersible pump (sand pump) is adopted.
The pipe 13 has a material, diameter, and length suitable for circulating and conveying a slurry in which contaminated soil and water are mixed, and in particular, part or all of the pipe 13 is a static mixer 14. It has become. This static mixer 14 changes the flow of the slurry to allow active agitation and mixing, the inner surface of the pipe has a curved or uneven shape, or the pipe is corrugated, or a combination thereof. Configured In this case, the pipe 13 is formed in a substantially L-shape as a whole, and includes a vertical pipe 131 which is raised in the vertical direction and a horizontal pipe 132 which is extended in the horizontal direction. A static mixer 14 having a length that secures the grinding time required to grind the soil particles is provided over a wide range of the middle portion of the pipe 132. In this static mixer 14, the inner surface of the tube has a curved shape, in which a spiral blade is attached, and the slurry is divided and dispersed as it passes each spiral blade, and the guide of the spiral blade leads to The structure is such that stirring and mixing are performed positively in the pipe, such as flowing while repeatedly colliding with each part of the surface. In this case, the direction of twist may be partially reversed in each spiral blade, and the spiral blades may have different sizes and shapes, and in this way slurry Can make further changes in the flow of
The cleaning system comprises such an arrangement, wherein the slurry is continuously pumped by means of a pump 12 through a line 13 having a static mixer 14.

図1に示すように、この洗浄方法及びシステムにおいては、汚染土壌と水とを混ぜたスラリーの吸引先でスラリーをポンプ12により吸引し、このスラリーをスタティックミキサー14付きの配管13に通して磨砕し、この配管13の終端で放出して次の工程へ送る。また、ポンプ12の連続運転により、スラリーをスタティックミキサー14付きの配管に連続的に通していく。このようにしてスラリー中の粗粒分を配管13に通すことで、この通過の際に、特に、スタティックミキサー14では、スラリーを、動力を必要とすることなしに、螺旋状の各羽根を通過する毎に分割分散し、また、螺旋状の羽根の案内により管内面の各部へ衝突を繰り返し、さらに、このような管内での積極的な撹拌混合による粗粒分同士の擦れ合い等の作用により、激しくミキシングされ、単に搬送用の(スタティックミキサーを有しない)配管の場合に比べて、著しく短い一定の洗浄処理時間で、粗粒分表面付近の高濃度に汚染された層が切削され、また、土壌の解砕が進み、細粒分の塊が解され、粗粒分に強固に付着していた細粒分が剥離されていく。
そして、このスタティックミキサー14付きの配管13を通過させた後の次の工程で、スラリーから分級により土壌の粗粒分を取り出し、有害物質の濃度が元の土壌に比べて低濃度になった粗粒分を得る。
As shown in FIG. 1, in this cleaning method and system, the slurry is sucked by the pump 12 at the suction destination of the slurry in which the contaminated soil and water are mixed, and this slurry is passed through the pipe 13 with the static mixer 14 and polished. It is crushed and discharged at the end of this pipe 13 and sent to the next step. In addition, the continuous operation of the pump 12 continuously passes the slurry through the pipe with the static mixer 14. In this way, by passing the coarse particles in the slurry through the pipe 13, particularly in the static mixer 14, the slurry passes through each spiral blade without requiring power at this passage. Each time it is divided and dispersed, collision with each part of the inner surface of the tube is repeated by the guidance of a spiral blade, and furthermore, the action such as rubbing of coarse particles by such active stirring and mixing in the tube The heavily contaminated layer near the coarse particle surface is cut off at a very short constant cleaning time, compared to the case of heavily mixed and simply conveying (without static mixer) piping Crushing of the soil proceeds, the lumps of fine grains are broken up, and the fine grains that were firmly attached to the coarse grains are peeled off.
Then, in the next step after passing through the pipe 13 with the static mixer 14, the coarse particles in the soil are taken out of the slurry by classification, and the concentration of harmful substances is lower than in the original soil. Get the grain.

以上説明したように、この汚染土壌の洗浄方法及びシステムによれば、スラリーを、ポンプ12により吸引し、スタティックミキサー14を有する配管13に通して磨砕するので、搬送用の(スタティックミキサーを有しない)配管を用いた場合に比べて、土粒子の磨砕効果を高めて、洗浄処理時間を著しく短縮することができ、この洗浄処理時間の短縮により、汚染土壌の洗浄処理量を増大させることができる。また、この場合、土粒子の磨砕に必要な磨砕時間を確保した長さのスタティックミキサー14を有する配管13を採用し、ポンプ12の連続運転によりスラリーをスタティックミキサー14を有する配管13に連続的に通して磨砕することで、スラリーを循環させることなく一度の配管通過で、洗浄処理を完了することができ、この連続処理により汚染土壌の洗浄処理時間を大幅に短縮することができる。また、このようにすることで水槽や循環用の配管などスラリーを循環させるための設備を不要とし、設備のさらなる小規模化、簡略化を図り、コストの低減に資することができる。   As described above, according to the method and system for cleaning contaminated soil, the slurry is sucked by the pump 12 and is passed through the pipe 13 having the static mixer 14 for grinding, so that it can be used for transportation (static mixer (6) Compared to the case where piping is used, the grinding effect of soil particles can be enhanced and the washing treatment time can be significantly shortened, and the washing treatment time can be shortened to increase the washing treatment amount of contaminated soil. Can. Also, in this case, the pipe 13 having the static mixer 14 of such a length as to secure the grinding time necessary for grinding the soil particles is adopted, and the slurry is continuously supplied to the pipe 13 having the static mixer 14 by the continuous operation of the pump 12 By grinding through in a straight line, the washing process can be completed in one pipe passage without circulating the slurry, and the continuous treatment can greatly reduce the washing process time of the contaminated soil. Moreover, the installation for circulating a slurry, such as a water tank and piping for circulation, becomes unnecessary by doing in this way, the scale-reduction and simplification of an installation can be achieved, and it can contribute to the cost reduction.

図2、図3に本発明の第2の実施の形態による汚染土壌の洗浄方法及びシステムを併せて示している。
図2に示すように、この洗浄方法では、汚染土壌と水とを混ぜたスラリーを容器(水槽)21に入れて、この容器21内のスラリーをポンプ22により吸引し、スラリーを撹拌混合して流動させるためのスタティックミキサー24を有する配管23に通して磨砕し、容器21内に送還することにより、容器21内のスラリーを容器21、スタティックミキサー24を有する配管23の間で磨砕循環し、このスラリーの磨砕循環をポンプ22の連続運転により繰り返す。
そして、この洗浄方法は洗浄システムにより実現される。図3に示すように、この洗浄システムは、汚染土壌と水とを混ぜたスラリーを入れるための容器(水槽)21と、容器21内のスラリーを吸引し送り出すためのポンプ22と、スラリーを撹拌混合して流動させるためのスタティックミキサー24を有し、ポンプ22により吸引し送り出されたスラリーを通過させ、容器21に送還する配管23とにより構成される。
この場合、容器21は、汚染土壌と水とを混ぜた所定量のスラリーを循環させるのに適した材質、大きさ及び形状を有するものであればよい。ここでは、容器21の周面の下部側がテーパ状に形成されて、容器21の底部中央付近に設置するポンプ22の吸引口側に向けて傾斜が付けられており、容器21内に沈降した粗粒分をポンプ22付近に集めやすくしてある。なお、この容器21の傾斜は必須ではなく、無くてもかまわない。
ポンプ22は砂分まで吸引搬送可能なポンプで、容器21内の水中に設置する場合は水中ポンプが採用され、容器21の外部に設置する場合は吸引ポンプでよい。なお、ここでは、ポンプ22に水中ポンプ(サンドポンプ)を採用している。このポンプ22は容器21の底部中央付近に設置される。
配管23は汚染土壌と水とを混ぜたスラリーを循環搬送させるのに適した材質、径、長さを有するもので、この配管23は、特に、配管の一部又は全部がスタティックミキサー24になっている。このスタティックミキサー24は、スラリーの流れに変化を付けて積極的に撹拌混合可能に、管の内面に曲面形状若しくは凹凸形状が形成されて、又は配管それ自体が波形に曲げられて、又はこれらの組み合わせにより構成される。この場合、配管23は全体が略逆U字形又は略逆J字形に形成され、中央の直状の配管部分にスタティックミキサー24が設けられる。このスタティックミキサー24は管の内面が曲面形状、ここでは螺旋状の羽根が付けられて、スラリーを螺旋状の各羽根を通過する毎に分割分散し、また、螺旋状の羽根の案内により、管内面の各部に衝突を繰り返しながら流動させるなど、管内で積極的に撹拌混合する構造になっている。なお、この場合、螺旋状の各羽根をねじれの方向を部分的に反対に変えてもよく、また、螺旋状の羽根はそれぞれが異なる大きさ、形状でもよく、このようにすることで、スラリーの流れにさらに変化を付けることができる。
この洗浄システムはかかる構成を備え、容器21内に入れたスラリーを、ポンプ22の連続運転により、容器21、ポンプ22、スタティックミキサー24を有する配管23の間で繰り返し磨砕循環するようになっている。
FIGS. 2 and 3 also show a method and system for cleaning contaminated soil according to a second embodiment of the present invention.
As shown in FIG. 2, in this cleaning method, a slurry obtained by mixing contaminated soil and water is placed in a container (water tank) 21, the slurry in the container 21 is sucked by a pump 22, and the slurry is stirred and mixed. The slurry in the vessel 21 is milled and circulated between the vessel 21 and the pipe 23 having the static mixer 24 by grinding it through the pipe 23 having the static mixer 24 for fluidization and feeding back into the vessel 21. The grinding circulation of the slurry is repeated by continuous operation of the pump 22.
And this cleaning method is realized by the cleaning system. As shown in FIG. 3, this cleaning system comprises a container (water tank) 21 for containing a slurry in which contaminated soil and water are mixed, a pump 22 for sucking and delivering the slurry in the container 21, and agitating the slurry It has the static mixer 24 for mixing and making it flow, and it is comprised by the piping 23 which passes through the slurry drawn and sent out by the pump 22, and sends it back to the container 21.
In this case, the container 21 may be of any material, size, and shape suitable for circulating a predetermined amount of slurry in which contaminated soil and water are mixed. Here, the lower side of the circumferential surface of the container 21 is formed in a tapered shape, and is inclined toward the suction port side of the pump 22 installed near the center of the bottom of the container 21 The particles are easily collected near the pump 22. Note that the inclination of the container 21 is not essential, and may not be.
The pump 22 is a pump capable of suction and transfer to the sand, and a submersible pump may be employed when installed in water in the container 21, and a suction pump may be used when installed outside the container 21. Here, a submersible pump (sand pump) is adopted as the pump 22. The pump 22 is installed near the center of the bottom of the container 21.
The pipe 23 is made of a material, diameter, and length suitable for circulating and conveying a slurry in which contaminated soil and water are mixed, and in particular, part or all of the pipe becomes the static mixer 24. ing. The static mixer 24 changes the flow of the slurry to actively stir and mix, a curved surface or uneven shape is formed on the inner surface of the pipe, or the pipe itself is bent into a corrugated shape, or Composed of a combination. In this case, the piping 23 is generally formed in a substantially inverted U-shape or a substantially inverted J-shape, and the static mixer 24 is provided in the central straight piping portion. In this static mixer 24, the inner surface of the tube has a curved shape, in which a spiral blade is added, and the slurry is divided and dispersed as it passes each spiral blade, and the guide of the spiral blade leads to The structure is such that stirring and mixing are performed positively in the pipe, such as flowing while repeatedly colliding with each part of the surface. In this case, the direction of twist may be partially reversed in each spiral blade, and the spiral blades may have different sizes and shapes, and in this way slurry Can make further changes in the flow of
This cleaning system has such a configuration, and the slurry contained in the container 21 is repeatedly ground and circulated between the container 21, the pump 22, and the piping 23 having the static mixer 24 by continuous operation of the pump 22. There is.

図2に示すように、この洗浄方法及びシステムにおいては、まず、汚染土壌と水とを混ぜたスラリーaを容器21に入れ、続いて、容器21内のスラリーaをポンプ22により吸引し、ポンプ22からスタティックミキサー24付きの配管23に通し、容器21内でこの配管23の終端から放出して元に戻すことにより、容器21内のスラリーaを容器21、ポンプ22、スタティックミキサー24付きの配管23の間で循環させ、このスラリーaの循環をポンプ22の連続運転により繰り返す。
この場合、容器21に所定量の水を注入し、ポンプ22を運転して水を循環させながら順次汚染土壌を投入すればよい。なお、汚染土壌中にポンプ22を通過できないような大径の礫や大きな異物が多く混入されている場合は、これらの礫や異物をスクリーン等を使って除去しておく。このように容器21に投入された汚染土壌はポンプ22による水の循環作用により即時に水とともに撹拌されてスラリーaとなる。容器21に所定量の汚染土壌の投入が終了したら、そのままポンプ22の運転を続け、スラリーaを容器21、ポンプ22、スタティックミキサー24付きの配管23の間で繰り返し循環させる。このスラリーaの循環の間、スラリーa中の粗粒分bが、図示のように容器21下部に沈降するが、サンドポンプ等、砂分まで吸引搬送できるポンプ22を使用することで、この沈降した粗粒分bを何ら問題なく循環させることができる。また、容器21の周面の下部側がテーパ状でポンプ22側へ傾斜が付けられているので、容器21内で沈降した粗粒分bがポンプ22付近に集まりやすくなり、粗粒分bも円滑に循環させることができる。このようにしてスラリーa中の粗粒分bが、ポンプ22やスタティックミキサー24付きの配管23を何度も通過し、この通過の際に、ポンプ22の羽根等による強い撹拌、ポンプ22内部やスタティックミキサー24付きの配管23の壁面への衝突、特に、スタティックミキサー24では、スラリーは、動力を必要とすることなしに、螺旋状の各羽根を通過する毎に分割分散し、螺旋状の羽根の案内により管内面の各部へ衝突を繰り返し、さらに、このような管内での積極的な撹拌混合による粗粒分b同士の擦れ合い等の作用により、激しくミキシングされ、搬送用の(スタティックミキサーを有しない)配管の場合に比べて、著しく短い一定の洗浄処理時間で、粗粒分b表面付近の高濃度に汚染された層が切削され、また、土壌の解砕が進み、細粒分の塊が解され、粗粒分に強固に付着していた細粒分が剥離されていく。
そして、一定時間循環させた後のスラリーaから分級により土壌の粗粒分bを取り出し、有害物質の濃度が元の土壌に比べて低濃度になった粗粒分bを得る。
As shown in FIG. 2, in this cleaning method and system, first, a slurry a, which is a mixture of contaminated soil and water, is placed in a container 21, and then the slurry a in the container 21 is aspirated by a pump 22, The slurry a in the container 21 is discharged from the end of the pipe 23 in the vessel 21 and returned to the original inside through the pipe 23 with the static mixer 24 from 22 and the pipe with the pump 21 and the static mixer 24 is returned. The circulation of the slurry a is repeated by continuous operation of the pump 22.
In this case, a predetermined amount of water may be injected into the container 21 and the contaminated soil may be sequentially introduced while operating the pump 22 to circulate water. In the case where a large diameter soot or a large foreign substance which can not pass through the pump 22 is mixed in the contaminated soil, the soot or the foreign substance is removed using a screen or the like. The contaminated soil thus introduced into the container 21 is immediately stirred together with water by the circulating action of water by the pump 22 to form a slurry a. When the feeding of the predetermined amount of contaminated soil to the container 21 is completed, the operation of the pump 22 is continued, and the slurry a is repeatedly circulated among the container 21, the pump 22, and the piping 23 with the static mixer 24. During circulation of the slurry a, the coarse particle fraction b in the slurry a settles in the lower part of the container 21 as shown in the figure, but this sedimentation can be achieved by using a pump 22 which can suction and convey the sand, such as a sand pump. The coarse particle fraction b can be circulated without any problem. In addition, since the lower side of the peripheral surface of the container 21 is tapered and inclined toward the pump 22, the coarse particle fraction b precipitated in the container 21 is easily collected near the pump 22, and the coarse particle fraction b is also smooth. Can be circulated. In this manner, the coarse particle fraction b in the slurry a passes through the pump 22 and the pipe 23 with the static mixer 24 many times, and during this passage, strong agitation by the blades of the pump 22, etc. The collision of the pipe 23 with the static mixer 24 with the wall, in particular, in the static mixer 24, the slurry splits and disperses as it passes through the spiral blades without requiring power, and the spiral blades The collision of each part of the inner surface of the tube is repeated by the guidance of the guide, and the mixture is vigorously mixed by the action such as rubbing of the coarse particles b by such appreciable stirring and mixing in the tube. The heavily polluted layer near the surface of the coarse particle b is cut with a considerably shorter constant cleaning time than in the case of the piping which does not have it, and the crushing of the soil Seen, mass fine fraction is understood, fine fraction which has been firmly attached to the coarse fraction is gradually peeled.
Then, the coarse particle fraction b of the soil is extracted from the slurry a which has been circulated for a certain period of time by classification to obtain a coarse particle fraction b in which the concentration of harmful substances is lower than that of the original soil.

以上説明したように、この汚染土壌の洗浄方法及びシステムによれば、容器21に入れたスラリーをポンプ22により吸引し、このスラリーを、スラリーを撹拌混合して流動させるためのスタティックミキサー24を有する配管23に通して磨砕し、容器21内に送還することにより、容器21内のスラリーを容器21、ポンプ22、スタティックミキサー24を有する配管23の間で磨砕循環し、スラリーの磨砕循環をポンプ22の連続運転により繰り返すようにしたので、搬送用の(スタティックミキサーを有しない)配管を用いた場合に比べて、土粒子の磨砕効果を高めて、洗浄処理時間を著しく短縮することができ、この洗浄処理時間の短縮により、汚染土壌の洗浄処理量を増大させることができる。
また、この洗浄方法及びシステムは、本願発明者らによる先の出願(特願2013−37057)の洗浄方法及びシステムを一部改良したもので、容器内に入れたスラリーを、ポンプの連続運転により、容器、ポンプ、配管の間で繰り返し循環させ、一定時間循環させた後のスラリーから分級により土壌の粗粒分を取り出し、有害物質の濃度が元の土壌に比べて低濃度になった粗粒分を得るようにした点では共通しているので、先の出願の洗浄方法及びシステムと同様に、汚染土壌の洗浄において、従来のように特殊磨砕機や薬剤等、粗粒分の表面切削関連の機器、機材を使用することなく、汎用的で安価な機器、機材のみを用いた極めて簡単な設備で、粗粒分の表面切削を可能とし、洗浄効果を高めることができ、洗浄プラントの小規模化及び洗浄コストの低減に寄与することができる利点を有することは勿論である。
As described above, according to the method and system for cleaning contaminated soil, the slurry contained in the container 21 is sucked by the pump 22 and the static mixer 24 for stirring and mixing the slurry and causing the slurry to flow is provided. The slurry in the container 21 is ground and circulated between the container 21, the pump 22 and the piping 23 having the static mixer 24 by grinding through the piping 23 and feeding back into the container 21, and the grinding circulation of the slurry is performed. Since it was made to repeat by continuous operation of pump 22, compared with the case where piping for conveyance (without a static mixer) is used, the grinding effect of soil particles is heightened and the washing processing time is shortened remarkably. The reduction of the cleaning time can increase the cleaning throughput of the contaminated soil.
In addition, this cleaning method and system is a modification of the cleaning method and system of the previous application (Japanese Patent Application No. 2013-37057) by the present inventors (Japanese Patent Application No. 2013-37057). , The container, the pump, and the piping are repeatedly circulated, and the coarse particles of the soil are taken out from the slurry by classification after being circulated for a fixed time, and the concentration of harmful substances is reduced compared to the original soil As it is common in terms of obtaining a portion, as in the cleaning method and system of the previous application, in the cleaning of contaminated soil, the surface cutting related to coarse particles such as special grinders and drugs as in the prior art is related It is possible to cut the surface of coarse particles with extremely simple equipment using only general-purpose and inexpensive equipment and equipment, without using equipment and equipment, and it is possible to enhance the cleaning effect, and the size of the cleaning plant is small. Scaling To have the advantage of being able to contribute to a reduction in the fine cleaning cost is a matter of course.

なお、この実施の形態では、スタティックミキサーは、管の内面に曲面形状として、螺旋状の羽根が付けられて、スラリーを螺旋状の各羽根を通過する毎に分割分散し、また、螺旋状の羽根の案内により、管内面の各部に衝突を繰り返しながら流動させるなど、管内で積極的に撹拌混合する構造にしたが、配管の内面に凹凸形状として、突状片や突起が形成されて、配管に通すスラリーを分割分散して流動させる作用、スラリーの流れる方向を変えて、又はスラリーを回転させて(さらに反転させてもよく)、配管内部での衝突を繰り返す作用を有する構造にしてもよい。この場合、突状片や突起はそれぞれが同じ大きさ、形状でもよく、異なる大きさ、形状でもよい。また、配管それ自体がさらに波形(ジグザグ状)に曲げられてもよい。このようにしても上記実施の形態と同様の作用効果を得ることができる。   In this embodiment, in the static mixer, a spiral blade is attached as a curved surface shape to the inner surface of the tube, and the slurry is divided and dispersed each time it passes through each spiral blade, and the spiral mixer is also used. The structure is such that stirring and mixing is performed actively in the pipe, such as flowing while repeatedly colliding with each part of the inner surface by guidance of the blades, but projecting pieces and protrusions are formed on the inner surface of the pipe as uneven shapes. The slurry may be divided and dispersed to flow, the flow direction of the slurry may be changed, or the slurry may be rotated (it may be reversed) to have a structure having an effect of repeating the collision inside the pipe. . In this case, the protruding pieces and the protrusions may have the same size and shape, or may have different sizes and shapes. Also, the piping itself may be further bent in a wavy shape (zigzag shape). Even with this configuration, the same effects as those of the above embodiment can be obtained.

また、この実施の形態では、この発明の汚染土壌の洗浄方法及びシステムにより汚染土壌を直接洗浄する場合について説明したが、この洗浄方法及びシステムは汚染土壌を切削機械により切削した後の土砂粗粒分に付着している切削粉の除去のための洗浄に用いることもできる。特に、放射能汚染土壌の場合は、切削後の粗粒分からの切削粉の除去の程度が除去率に大きく影響するため、簡単な設備で効率的に切削粉の除去ができる本案の方法及びシステムは極めて有効である。   In this embodiment, although the case where the contaminated soil is directly cleaned by the method and system for cleaning contaminated soil according to the present invention has been described, this cleaning method and system are coarse particles of soil after cutting the contaminated soil with a cutting machine It can also be used for cleaning for removal of cutting powder adhering to the minute. In particular, in the case of radioactively contaminated soil, since the degree of removal of cutting powder from the coarse particles after cutting greatly affects the removal rate, the method and system of the present invention capable of efficiently removing cutting powder with a simple facility Is extremely effective.

12 ポンプ
13 輸送配管
131 垂直方向の配管
132 水平方向の配管
14 スタティックミキサー
21 容器
22 ポンプ
23 輸送配管
24 スタティックミキサー
a スラリー
b 粗粒分
12 pump 13 transport piping 131 vertical piping 132 horizontal piping 14 static mixer 21 vessel 22 pump 23 transport piping 24 static mixer a slurry b coarse particle fraction

Claims (4)

放射性物質で汚染された土壌と水とを混ぜたスラリーをポンプで吸引し、配管に通して撹拌混合させながら流動させることにより、放射性物質で汚染された土壌を洗浄する汚染土壌の洗浄方法であって、
前記ポンプに砂分まで吸引搬送可能なポンプを採用し、
前記配管を全体として略L字形に形成し、垂直方向に向けて立ち上げられる垂直方向の配管と水平方向に向けて延ばされる水平方向の配管とにより構成し、前記配管の一部又は全部に、スラリーを前記配管内で分割分散可能にかつ前記配管の内面に繰り返し衝突可能に、前記配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は前記配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーをスラリー中の土粒子の磨砕に必要な磨砕時間を確保した長さに設け、
前記ポンプの連続運転によりスラリーを前記ポンプ、前記スタティックミキサー付きの前記配管に通してスラリー中の土粒子を磨砕する、
ことを特徴とする汚染土壌の洗浄方法。
A method for cleaning contaminated soil in which radioactive substance-contaminated soil is cleaned by aspirating slurry mixed with radioactive substance-contaminated soil and water through a pipe and flowing it while stirring and mixing. ,
A pump capable of suction and transfer to the sand is adopted as the pump,
The pipe as a whole is formed into a substantially L shape, and is constituted by a vertical pipe which is vertically raised and a horizontal pipe which is horizontally extended, and a part or all of the pipe, The inner surface of the pipe is formed into a curved shape or an uneven shape that changes the flow of the slurry so that the slurry can be divided and dispersed in the pipe and repeatedly collides with the inner surface of the pipe, or the pipe can be flowed with the slurry Provide a static mixer consisting of bending, or a combination of these, to a length that changes the grinding time required for grinding the soil particles in the slurry .
The continuous operation of the pump passes the slurry through the pump and the pipe with the static mixer to grind particles in the slurry.
A method of cleaning contaminated soil characterized by
放射性物質で汚染された土壌と水とを混ぜたスラリーを容器に入れて、前記容器内のスラリーをポンプにより吸引し、スラリーを配管に通して前記容器内に送還することにより、前記容器内のスラリーを前記容器、前記ポンプ、前記配管の間で循環し、前記スラリーの循環を繰り返すことにより、放射性物質で汚染された土壌を洗浄する汚染土壌の洗浄方法であって、
前記ポンプに砂分まで吸引搬送可能なポンプを採用し、
前記配管を全体として略逆U字形又は略逆J字形に形成し、前記配管の一部又は全部に、スラリーを前記配管内で分割分散可能にかつ前記配管の内面に繰り返し衝突可能に、前記配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は前記配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーを設け
前記ポンプの連続運転により、前記容器内に入れたスラリーを前記容器、前記ポンプ、前記スタティックミキサー付きの配管の間で繰り返し循環させ、スラリー中の土粒子を磨砕する、
ことを特徴とする汚染土壌の洗浄方法。
The slurry mixed with the soil contaminated with radioactive material and water is placed in a container, the slurry in the container is sucked by a pump, and the slurry is sent through piping to the container to return the inside of the container. A method for cleaning contaminated soil, wherein the slurry is circulated between the container, the pump, and the piping, and the soil contaminated with radioactive material is cleaned by repeating circulation of the slurry.
A pump capable of suction and transfer to the sand is adopted as the pump,
The piping as a whole is formed in a substantially inverted U-shape or a substantially inverted J-shape, and the slurry can be divided and dispersed in the piping to a part or all of the piping and the piping can be repeatedly collided with the inner surface of the piping A static mixer is provided , which is formed in a curved shape or uneven shape that changes the flow of the slurry, or by bending the pipe into a waveform that changes the flow of the slurry, or a combination thereof .
By continuous operation of the pump, the slurry contained in the vessel is repeatedly circulated among the vessel, the pump, and the piping with the static mixer to grind the soil particles in the slurry.
A method of cleaning contaminated soil characterized by
放射性物質で汚染された土壌と水とを混ぜたスラリーを吸引し送り出すためのポンプと、
前記ポンプにより吸引し送り出されたスラリーを撹拌混合して流動させるための配管と、
を備え、
前記ポンプは砂分まで吸引搬送可能なポンプとし、
前記配管は全体が略L字形に形成されて、垂直方向に向けて立ち上げられる垂直方向の配管と水平方向に向けて延ばされる水平方向の配管とからなり、前記配管の一部又は全部に、スラリーを前記配管内で分割分散可能にかつ前記配管の内面に繰り返し衝突可能に、前記配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は前記配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーがスラリー中の土粒子の磨砕に必要な磨砕時間を確保した長さにして設けられ
前記ポンプの連続運転によりスラリーを前記ポンプ、前記スタティックミキサー付きの前記配管に通してスラリー中の土粒子を磨砕する、
ことを特徴とする汚染土壌の洗浄システム
A pump for suctioning and delivering a slurry mixed with soil and water contaminated with radioactive material;
Piping for stirring, mixing and flowing the slurry sucked and sent out by the pump;
Equipped with
The pump is a pump capable of suction and transfer to the sand,
The piping is generally formed in a substantially L-shape, and includes a vertical piping that is vertically raised and a horizontal piping that is horizontally extended, and a part or all of the piping, The inner surface of the pipe is formed into a curved shape or an uneven shape that changes the flow of the slurry so that the slurry can be divided and dispersed in the pipe and repeatedly collides with the inner surface of the pipe, or the pipe can be flowed with the slurry a bend in the waveform to give a change, or provided to a length to ensure inter that grinding time required for grinding the soil particles of the static mixer in the slurry formed by combining these,
The continuous operation of the pump passes the slurry through the pump and the pipe with the static mixer to grind particles in the slurry.
Cleaning system for contaminated soil characterized by that.
放射性物質で汚染された土壌と水とを混ぜたスラリーを入れるための容器と、
前記容器内のスラリーを吸引し送り出すためのポンプと、
前記ポンプにより吸引し送り出されたスラリーを通過させ、前記容器に送還する配管と、
を備え、
前記ポンプは砂分まで吸引搬送可能なポンプとし、
前記配管は全体が略逆U字形又は略逆J字形に形成されて、前記配管の一部又は全部に、スラリーを前記配管内で分割分散可能にかつ前記配管の内面に繰り返し衝突可能に、前記配管の内面をスラリーの流れに変化を付ける曲面形状若しくは凹凸形状に形成して、又は前記配管をスラリーの流れに変化を付ける波形に曲げて、又はこれらを組み合わせてなるスタティックミキサーが設けられ
前記ポンプの連続運転により、前記容器内に入れたスラリーを前記容器、前記ポンプ、前記スタティックミキサー付きの配管の間で繰り返し循環させ、スラリー中の土粒子を磨砕する、
ことを特徴とする汚染土壌の洗浄システム。

A container for containing a slurry of soil and water contaminated with radioactive material ;
A pump for suctioning and delivering the slurry in the container ;
Piping for passing the slurry sucked and sent out by the pump and sending it back to the container ;
Equipped with
The pump is a pump capable of suction and transfer to the sand,
The whole of the pipe is formed in a substantially inverted U-shape or a substantially inverted J-shape so that the slurry can be divided and dispersed in part or all of the pipe and can repeatedly collide with the inner surface of the pipe. There is provided a static mixer in which the inner surface of the pipe is formed into a curved shape or an uneven shape which changes the flow of slurry, or the pipe is bent into a waveform which changes the flow of slurry or a combination thereof.
By continuous operation of the pump, the slurry contained in the vessel is repeatedly circulated among the vessel, the pump, and the piping with the static mixer to grind the soil particles in the slurry.
Cleaning system for contaminated soil characterized by that.

JP2014171112A 2014-08-26 2014-08-26 Method and system for cleaning contaminated soil Active JP6548874B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2014171112A JP6548874B2 (en) 2014-08-26 2014-08-26 Method and system for cleaning contaminated soil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2014171112A JP6548874B2 (en) 2014-08-26 2014-08-26 Method and system for cleaning contaminated soil

Publications (2)

Publication Number Publication Date
JP2016043332A JP2016043332A (en) 2016-04-04
JP6548874B2 true JP6548874B2 (en) 2019-07-24

Family

ID=55634450

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2014171112A Active JP6548874B2 (en) 2014-08-26 2014-08-26 Method and system for cleaning contaminated soil

Country Status (1)

Country Link
JP (1) JP6548874B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7075310B2 (en) * 2018-08-10 2022-05-25 五洋建設株式会社 Landfill method for waste disposal site
KR102635364B1 (en) * 2023-07-12 2024-02-08 국방과학연구소 Mobile Chemical Reactant Neutralization Device and Its Operating Method

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4112276B2 (en) * 2002-05-20 2008-07-02 大阪瓦斯株式会社 Washing and collecting method of fine soil particles in muddy water
JP4583771B2 (en) * 2003-02-10 2010-11-17 日鉄環境エンジニアリング株式会社 Method for removing non-volatile pollutants in soil
JP4372067B2 (en) * 2005-09-01 2009-11-25 忠広 藤井 Contaminated soil continuous cleaning method
KR101287486B1 (en) * 2005-12-07 2013-07-19 미쯔이 죠센 가부시키가이샤 Apparatus for removing of unburned carbon from fly ash and relevant removing method
JP4847497B2 (en) * 2008-07-30 2011-12-28 株式会社奥村組 Purification method for contaminated soil
WO2013186873A1 (en) * 2012-06-13 2013-12-19 学校法人日本大学 Contaminated soil treatment system
JP5155487B1 (en) * 2012-07-23 2013-03-06 あおみ建設株式会社 Classification method of contaminated soil
JP2014070997A (en) * 2012-09-28 2014-04-21 Ihi Corp Soil continuous processing system

Also Published As

Publication number Publication date
JP2016043332A (en) 2016-04-04

Similar Documents

Publication Publication Date Title
KR101396416B1 (en) The washing apparatus of oils and heavy metals contaminated soils using thermal stress crushing, the remediation system of oils and heavy metals contaminated soils comprising thereof, and remediation method of oils and heavy metals contaminated soils comprising thereof
JP2013164379A (en) Processor for radiation-contaminated soil
JP6548874B2 (en) Method and system for cleaning contaminated soil
GB2530663A (en) Reuse of by-products from metallurgical processes
JP2007050347A (en) Crushing polishing apparatus and treating method of contaminated soil using it
TWI651131B (en) Grinder with agitating function
KR101723908B1 (en) Decontamination method of radioactivity contaminated material and method of radioactive waste disposal
KR101797591B1 (en) Cleaning Apparatus and Cleaning Method of Recycling Fine Aggregate
US9192968B2 (en) Process and system for treating particulate solids
JP2012106158A (en) Contaminated soil washing tank
JP3823849B2 (en) Oil-contaminated soil cleaning equipment
JP2011115713A (en) Machine and method for cleaning of medium
JP7142513B2 (en) METHOD AND DEVICE FOR PROMOTING VOLUME REDUCTION BY CONTINUOUS WASHING OF CONTAMINATED SAND
JP6096526B2 (en) Polishing machine, contaminant removal system using the same, and contaminant removal method
JP2014137311A (en) Ultrasonic cleaning device and ultrasonic cleaning method
JP6199154B2 (en) Radioactive substance removal equipment
JP6434201B2 (en) Method and system for cleaning contaminated soil
JP2014070997A (en) Soil continuous processing system
KR20090003015A (en) Glassware clushing system
CN211436080U (en) Dispersible oil suspending agent production device
JP5270048B1 (en) Soil decontamination equipment
US9266117B2 (en) Process and system for treating particulate solids
KR101169378B1 (en) Apparatus for crushing sludge of anaerobic digester and apparatus for reducing sludge having the anaerobic digester
JP6275443B2 (en) Separation apparatus and separation method for plant waste in radioactively contaminated soil
JP6783908B1 (en) Heavy metal fixing agent injection device into fly ash kneader

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20170529

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20180625

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20180703

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20180824

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20181023

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20181211

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20190528

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20190626

R150 Certificate of patent or registration of utility model

Ref document number: 6548874

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250