JP6541295B2 - Hair shaping agent and method of styling hair using the hair shaping agent - Google Patents
Hair shaping agent and method of styling hair using the hair shaping agent Download PDFInfo
- Publication number
- JP6541295B2 JP6541295B2 JP2013129922A JP2013129922A JP6541295B2 JP 6541295 B2 JP6541295 B2 JP 6541295B2 JP 2013129922 A JP2013129922 A JP 2013129922A JP 2013129922 A JP2013129922 A JP 2013129922A JP 6541295 B2 JP6541295 B2 JP 6541295B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- shellac
- agent
- forming
- forming agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000007493 shaping process Methods 0.000 title claims description 23
- 238000000034 method Methods 0.000 title claims description 13
- 229920001800 Shellac Polymers 0.000 claims description 77
- 239000004208 shellac Substances 0.000 claims description 77
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims description 77
- 229940113147 shellac Drugs 0.000 claims description 77
- 235000013874 shellac Nutrition 0.000 claims description 77
- 239000003795 chemical substances by application Substances 0.000 claims description 76
- 229920001187 thermosetting polymer Polymers 0.000 claims description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 238000010438 heat treatment Methods 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 4
- 230000003699 hair surface Effects 0.000 claims description 4
- 238000005452 bending Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 229920005989 resin Polymers 0.000 description 32
- 239000011347 resin Substances 0.000 description 32
- 239000003822 epoxy resin Substances 0.000 description 20
- 229920000647 polyepoxide Polymers 0.000 description 20
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 150000002576 ketones Chemical class 0.000 description 6
- 239000000025 natural resin Substances 0.000 description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 102000011782 Keratins Human genes 0.000 description 3
- 108010076876 Keratins Proteins 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000037308 hair color Effects 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 230000036760 body temperature Effects 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 230000003700 hair damage Effects 0.000 description 2
- 239000000118 hair dye Substances 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 241000186660 Lactobacillus Species 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000021474 generally recognized As safe (food) Nutrition 0.000 description 1
- 235000021473 generally recognized as safe (food ingredients) Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000003648 hair appearance Effects 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229940039696 lactobacillus Drugs 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000012261 resinous substance Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Hair Curling (AREA)
Description
本発明は、毛髪の成形に用いる毛髪成形剤に関する。 The present invention relates to a hair-forming agent used to form hair.
従来、縮毛矯正剤としては、還元剤（第１剤）及び酸化剤（第２剤）を使用し、毛髪の組成を化学的に変化させる方法があり、近年では、ホルムアルデヒドを含む熱硬化性樹脂のコーティングによる縮毛矯正が提案されている。 Conventionally, as a hair straightener, there is a method of chemically changing the composition of the hair using a reducing agent (first agent) and an oxidizing agent (second agent), and in recent years, a thermosetting resin containing formaldehyde Hair straightening by resin coating has been proposed.
また、従来の天然樹脂セラックを配合した毛髪用化粧料は、セラックの光沢性を利用したつや出し剤や、一時的な接着性を利用した整髪料が提案されている（例えば、特許文献１及び特許文献２参照）。 In addition, as a cosmetic for hair containing a conventional natural resin shellac, a polishing agent utilizing the glossiness of shellac and a hair styling agent utilizing temporary adhesiveness are proposed (for example, Patent Document 1 and Patent Document 1) Reference 2).
従来の毛髪の表面部分を熱変性させる縮毛矯正剤は、毛髪そのものの構造を化学的に変化させることから、切れ毛、枝毛の原因となり、毛髪へのダメージが大きかった。 Conventional hair straighteners which thermally denature the surface portion of the hair chemically change the structure of the hair itself, causing broken hair and split hair, resulting in significant damage to the hair.
また、従来の熱硬化性樹脂を使用した縮毛矯正剤は、縮毛矯正の施術の際に、人体に有害なホルムアルデヒドが飛散されることがあり、人体に用いるには好ましいものではなかった。 In addition, the hair straightening agent using the conventional thermosetting resin sometimes scatters formaldehyde harmful to the human body at the time of the hair straightening treatment, and it was not preferable for the human body.
また、天然樹脂セラックを用いた毛髪用化粧料として、つや出し剤や整髪料は提案されていたものの、セラックの熱硬化性を利用した毛髪成形剤は存在していなかった。 Moreover, although a glossing agent and a hair setting agent have been proposed as hair cosmetics using natural resin shellac, there is no hair forming agent using the thermosetting property of shellac.
本発明は、上記問題点を解消するものであり、毛髪の周囲に熱硬化性樹脂の皮膜を形成して安全にくせ毛の矯正及び毛髪のスタイリングを行うとともに、毛髪の損傷・カラーリングの退色を抑制することが可能な、熱硬化性樹脂を使用した毛髪成形剤並びに前記毛髪成形剤を用いたくせ毛の矯正及び毛髪のスタイリングの施術方法を提供することを目的とする。 The present invention solves the above problems, and forms a thermosetting resin film around the hair to make it possible to safely cure false hair and styling the hair, as well as damage to the hair and discoloration of the coloring. It is an object of the present invention to provide a hair-forming agent using a thermosetting resin that can be suppressed, and a method for correcting combed hair and styling hair using the hair-forming agent.
本発明は、セラックと、アルコール、フェノール、エーテル又はアルカリから選ばれた前記セラックの溶媒と、増粘剤とを含み、還元剤を含まない毛髪成形剤であって、前記毛髪成形剤は、それぞれの毛髪の表面に塗布され、毛髪の凹凸に含浸して凹部を埋めるとともに、前記セラックを毛髪の周囲に配置させ、毛髪の形状を仮形成したあと、又は形状固定しながら、毛髪を摂氏43度以上250度未満で加熱することにより毛髪に前記セラックによる三次元網目構造の硬化性の皮膜を均一に形成する方法において用いられる毛髪成形剤である。 The present invention includes a shellac, alcohol, phenol, and the shellac in solvent selected from ether or an alkali, a thickener, a hair shaping agent containing no reducing agent, the hair shaping agent, respectively The hair is applied to the surface of the hair to impregnate the unevenness of the hair to fill in the recesses, and the shellac is placed around the hair to temporarily form the shape of the hair or fix the shape, while holding the hair at 43 degrees Celsius a hair shaping agent used in the method of uniformly forming a curable film of the three-dimensional network structure by the shellac in the hair by heating at less than 250 degrees.
本発明によれば、前記毛髪成形剤がそれぞれの毛髪の表面に塗布され、硬化されることにより、セラックの皮膜が毛髪を取り囲み、毛髪を成形及び支持する。 According to the present invention, the hair-forming agent is applied to the surface of each hair and cured so that the shellac coat surrounds the hair and shapes and supports the hair.
また、好ましくは、前記アルコールとしてエタノールを含む。 In addition, preferably, ethanol is contained as the alcohol.
また、本発明は、セラックと、アルコール、フェノール、エーテル又はアルカリから選ばれた前記セラックの溶媒と、増粘剤とを含み、還元剤を含まない毛髪成形剤を用い、毛髪単体の表面に前記セラックの皮膜を形成する毛髪のスタイリングの施術方法であって、前記毛髪成形剤をそれぞれの毛髪の表面に塗布する工程と、前記毛髪成形剤を塗布した毛髪に所定方向に張力を与え、又は湾曲させる工程と、前記毛髪成形剤を塗布された毛髪表面を三次元網目構造の皮膜を均一に形成するため摂氏43度以上250度未満で加熱装置により加熱することにより毛髪に前記セラックの熱硬化した皮膜を形成する工程を有する毛髪のスタイリングの施術方法である。 The present invention also shellac and alcohol, phenol, wherein said shellac solvent selected from ethers or alkali, and a thickening agent, using a hair shaping agent which contains no reducing agent, wherein the hair single surface A method of styling hair to form a shellac film, comprising the steps of: applying the hair shaping agent to the surface of each hair; tensioning the hair on which the hair shaping agent is applied in a predetermined direction; Heat curing of the shellac on the hair by heating with a heating device at a temperature of 43 ° C. or more and less than 250 ° C. to uniformly form a film of a three-dimensional network structure on the hair surface coated with the hair forming agent It is a treatment method of the styling of the hair which has the process of forming a film.
本発明によれば、毛髪の周囲に熱硬化性樹脂の皮膜を形成して安全にくせ毛の矯正及び毛髪のスタイリングを行うとともに、毛髪の損傷・カラーリングの退色を抑制することが可能であって、特に、それぞれの毛髪表面に所定の形状を保つ熱硬化性樹脂層を形成することにより、より長時間の形状維持が可能な、熱硬化性樹脂を使用した毛髪成形剤並びに前記毛髪成形剤を用いたくせ毛の矯正及び毛髪のスタイリングの施術方法を提供することができる。 According to the present invention, it is possible to form a film of thermosetting resin around the hair to safely make it possible to straighten hair and perform styling of the hair, and to prevent hair damage and coloring deterioration Particularly, by forming a thermosetting resin layer maintaining a predetermined shape on each hair surface, it is possible to maintain the shape for a longer time, and a hair forming agent using the thermosetting resin and the hair forming agent It is possible to provide a method for the treatment of straight hair and styling of the hair used.
以下、本発明の実施の形態を詳細に説明する。 Hereinafter, embodiments of the present invention will be described in detail.
本発明に係る毛髪成形剤は、熱硬化性樹脂と、アルコール、ケトン、フェノール、エーテル又はアルカリから選ばれた溶媒とを含む混合物であり液状をなしている。 The hair-forming agent according to the present invention is a mixture containing a thermosetting resin and a solvent selected from alcohol, ketone, phenol, ether or alkali, and is in a liquid state.
熱硬化性樹脂としては、天然樹脂であるセラックや、ホルマリンを使用することなく合成されるエポキシ樹脂等を使用することができる。 As the thermosetting resin, shellac which is a natural resin, an epoxy resin synthesized without using formalin, or the like can be used.
熱硬化性樹脂のうち、セラックは、現在、唯一知られている天然樹脂である。セラックは、インドから東南アジアおよび台湾にかけて分布する、半翅目のラックカイガラムシが分泌する樹脂状物質を原料とし、これを精製して得られる動物性天然樹脂である。無色又は淡黄から黄褐色、透明から半透明のもろい片状または粉末状物質で、推定構造はシェロリン酸、アロイリチン酸及びその誘導体並びに各種有機酸からなる。セラックは、熱硬化性、皮膜特性、電気絶縁性、耐油性、耐溶剤性などのさまざまな性質を有している。また、日本食品衛生法に基づき食品添加物として登録されており（白セラック）、米国食品医薬局（FDA）のGRAS物質（安全性の確認された物質）として認定されているように、人体に無害であることが確認されている。 Among thermosetting resins, shellac is currently the only known natural resin. Shellac is an animal natural resin obtained by purifying a resinous substance secreted by Lactobacillus in the order of Semi-Lembs, which is distributed from India to Southeast Asia and Taiwan, and purifying it. It is a colorless or pale yellow to yellowish brown, transparent to translucent, brittle flake-like or powdery substance, and its presumed structure consists of celerynic acid, aleuritinic acid and its derivatives and various organic acids. Shellac has various properties such as thermosetting, film properties, electrical insulation, oil resistance and solvent resistance. In addition, it is registered as a food additive under the Japan Food Sanitation Law (White Shellac), and as a GRAS substance (a substance whose safety has been confirmed) of the US Food and Drug Administration (FDA), it is It is confirmed to be harmless.
本発明で使用されるセラックは、従来から公知であるいかなるセラックでもよい。例えば、精製セラック、脱色セラック、白セラック等を選択して使用することができる。特に、毛髪色に影響を与えない無色透明な脱色セラックの微粉末が好ましい。セラックは、本発明に係る毛髪成形剤中、０.００１〜２０質量％、好ましくは０.０１〜１０質量％配合する。セラックが０.００１質量％未満であれば、本発明に係る毛髪成形剤を毛髪に使用した際に、毛髪に形成されるセラック皮膜が少なく、毛髪を成形することができない。他方、セラックが２０質量％を超える量であれば、毛髪に形成されるセラック皮膜が多すぎ、毛髪の自然な風合いを保つことができない。 The shellac used in the present invention may be any shellac known in the art. For example, purified shellac, decolorized shellac, white shellac, etc. can be selected and used. In particular, fine powder of colorless and transparent decolorized shellac which does not affect the hair color is preferable. The shellac is blended in an amount of 0.001 to 20% by mass, preferably 0.01 to 10% by mass, in the hair shaping agent according to the present invention. When the shellac is less than 0.001% by mass, when the hair shaping agent according to the present invention is used for hair, the shellac film formed on the hair is small, and the hair can not be molded. On the other hand, if the amount of shellac is more than 20% by mass, the amount of shellac film formed on the hair is too large to maintain the natural texture of the hair.
本発明に係る毛髪成形剤が塗布された毛髪は、セラックの有する皮膜特性及び熱硬化性のため、毛髪に熱を加えることにより、熱硬化したセラックの三次元網目構造の皮膜が形成される。 The hair to which the hair forming agent according to the present invention is applied has a film property and thermosetting property of shellac, so that heat is applied to the hair to form a film of a three-dimensional network structure of thermoset shellac.
セラック以外の熱硬化性樹脂としては、エポキシ樹脂を使用することができる。エポキシ樹脂には適宜改良剤、希釈剤を加えることができる。フェノール樹脂、ユリア樹脂、メラミン樹脂は、施術時にホルムアルデヒドが発生し、人体に有毒なため、使用することができない。 An epoxy resin can be used as a thermosetting resin other than shellac. A modifier and a diluent can be added to the epoxy resin as appropriate. Phenol resin, urea resin and melamine resin can not be used because they generate formaldehyde at the time of treatment and are toxic to human body.
セラックはアルコールを溶媒として溶解することができる。また、セラックのアルコール溶液を対象物に塗布し、乾燥させることにより、対象物の表面に光沢性・防湿性のある皮膜を形成することができる。 Shellac can be dissolved in alcohol as a solvent. Also, by applying an alcohol solution of shellac to an object and drying it, a film having a gloss and moisture resistance can be formed on the surface of the object.
本発明において、アルコールは、エタノール、メタノール、ブタノール、１−プロパノール、２−プロパノール、グリセリン又はグリコールなどを適宜選択することができるが、特に、人体への安全性が高く、セラックの溶解度も高いうえ、取扱いが容易で、安価に入手することが可能なエタノールが好ましい。 In the present invention, as alcohol, ethanol, methanol, butanol, 1-propanol, 2-propanol, glycerin or glycol can be appropriately selected, but in particular, the safety to human body is high and the solubility of shellac is also high. Preferred is ethanol, which is easy to handle and can be obtained inexpensively.
アルコールでセラックを溶解することにより、セラックを毛髪に塗布しやすい液状にし、毛髪に皮膜を形成しやすくする。 Dissolving the shellac with alcohol makes the shellac a liquid that is easy to apply to the hair and makes it easy to form a film on the hair.
また、セラックは、フェノール、エーテルにも溶解する。フェノール類としては、通常、染毛剤など化粧品用途で使用可能なものを、安全に使用できる濃度で用いる。また、エーテル類としては、保湿剤・乳化剤として化粧品用途で使用可能なものを、安全に使用できる濃度で用いる。 Also, shellac dissolves in phenol and ether. As phenols, those which can be used in cosmetic applications such as hair dyes are generally used at concentrations that can be safely used. Moreover, as ether, what can be used for cosmetics use as a moisturizer and an emulsifier is used in the density | concentration which can be used safely.
また、セラックは、アルカリにも溶解する。アルカリとしては、アンモニア水、ホウ砂、炭酸ナトリウム、水酸化ナトリウム、水酸化カリウム、モルホリンなどを挙げることができる。摂氏５０〜６０度に加温した所定量の水において、セラック１００ｇに対し、添加するアルカリの質量の目安は、以下のとおりである。
２５％アンモニア水：１２〜１３ｇ
ホウ砂：２０〜２２ｇ
炭酸ナトリウム：６〜８ｇ
水酸化ナトリウム：５〜７ｇ
水酸化カリウム：７〜８ｇ
モルホリン：１０〜１１ｇ
Also, shellac dissolves in alkali. Examples of the alkali include aqueous ammonia, borax, sodium carbonate, sodium hydroxide, potassium hydroxide, morpholine and the like. In a predetermined amount of water heated to 50 to 60 degrees Celsius, a standard of the mass of alkali to be added with respect to 100 g of shellac is as follows.
25% ammonia water: 12 to 13 g
Borax: 20 to 22 g
Sodium carbonate: 6 to 8 g
Sodium hydroxide: 5 to 7 g
Potassium hydroxide: 7 to 8 g
Morpholine: 10 to 11 g
また、エポキシ樹脂はケトンを溶媒として溶解することができる。ケトンとしては、アセトン、メチルエチルケトン、メチルイソブチルケトンを挙げることができる。 Epoxy resins can also be dissolved using ketones as solvents. Examples of ketones include acetone, methyl ethyl ketone and methyl isobutyl ketone.
本発明において、セラック、エポキシ樹脂等の熱硬化性樹脂のアルコール、ケトン、フェノール、エーテル又はアルカリを溶媒とする溶液に、さらに増粘剤を添加することができる。添加される増粘剤としては、セルロース又はその誘導体、アルギン酸等が挙げられる。 In the present invention, a thickener can be further added to a solution of a thermosetting resin such as shellac or epoxy resin in which alcohol, ketone, phenol, ether or alkali is used as a solvent. As a thickener to be added, cellulose or a derivative thereof, alginic acid and the like can be mentioned.
増粘剤を添加することにより、アルコール、ケトン、フェノール、エーテル又はアルカリから選ばれた溶媒に溶解したセラック、エポキシ樹脂等の熱硬化性樹脂が、時間の経過に伴いアルコール、ケトン、フェノール、エーテル又はアルカリから選ばれた溶媒と、セラック、エポキシ樹脂等の熱硬化性樹脂とに再び分離することを防止する。また、毛髪成形剤に含まれるセラックが均一に分散された状態を維持することができる。さらに、毛髪成形剤の粘性が高められるため、施術時に毛髪に毛髪成形剤を塗布する取扱いが容易となる。このため、均一に、毛髪に毛髪成形剤を塗布し、毛髪成形剤に含まれるセラック、エポキシ樹脂等の熱硬化性樹脂を配置することが容易になる。 Thermosetting resins such as shellac dissolved in a solvent selected from alcohols, ketones, phenols, ethers or alkalis by adding a thickener, and alcohols, ketones, phenols, ethers over time. Alternatively, separation again into a solvent selected from alkali and thermosetting resin such as shellac and epoxy resin is prevented. In addition, the shellac contained in the hair-forming agent can be maintained in a uniformly dispersed state. Furthermore, since the viscosity of the hair shaping agent is increased, the handling of applying the hair shaping agent to the hair at the time of treatment becomes easy. For this reason, it becomes easy to apply | coat a hair shaping agent to hair uniformly, and to arrange thermosetting resins, such as shellac and an epoxy resin contained in a hair shaping agent.
毛髪成形剤には、さらに、熱による毛髪への影響を軽減するため、必要に応じて、毛髪保護剤を配合することができる。このほか、毛髪への有効成分として、例えば、アミノ酸、ケラチン、植物抽出物等を配合することができる。 The hair-forming agent may further contain a hair-protecting agent, if necessary, to reduce the influence of heat on the hair. In addition, as an active ingredient to hair, for example, amino acids, keratin, plant extracts and the like can be blended.
なお、本発明の毛髪成形剤は、熱硬化性樹脂の有する接着作用を利用して、毛髪を整髪する整髪料ではない。 The hair-forming agent of the present invention is not a hair-setting agent for setting hair by utilizing the adhesive action of a thermosetting resin.
本発明に係る毛髪成形剤が毛髪に塗布され、毛髪成形剤が塗布された毛髪が加熱されることにより、毛髪成形剤に含まれる熱硬化性樹脂が、熱硬化した皮膜を形成し、毛髪を成形する。また、体熱を利用して毛髪成形剤が塗布された毛髪に熱が与えられた状態にすることにより、毛髪成形剤に含まれる熱硬化性樹脂が皮膜を形成し、毛髪を成形する。 The hair-forming agent according to the present invention is applied to the hair, and the hair to which the hair-forming agent is applied is heated, whereby the thermosetting resin contained in the hair-forming agent forms a thermally cured film to form the hair. To mold. Further, by applying heat to the hair to which the hair forming agent is applied using body heat, the thermosetting resin contained in the hair forming agent forms a film and shapes the hair.
特に、セラックの硬化層は、三次元網目構造となるために、毛髪の形状を保ちながらも、その網目を通して着色料やトリートメント剤を含浸しやすくなり、毛髪を矯正したあとでも、染毛やトリートメントを行うことができる。 In particular, because the hardened layer of shellac has a three-dimensional network structure, it becomes easy to impregnate the coloring agent and the treatment agent through the mesh while maintaining the shape of the hair, and even after correcting the hair, hair dyeing and treatment It can be performed.
次に、本発明に係る毛髪成形剤を使用してくせ毛の矯正及び毛髪のスタイリングの施術を行う方法について説明する。 Next, a method of using the hair-forming agent according to the present invention and performing hair straightening and hair styling operations will be described.
本発明に係る毛髪のスタイリングの施術方法は、毛髪成形剤をそれぞれの毛髪の表面に塗布する第１工程と、毛髪成形剤を塗布した毛髪に所定方向に張力を与え、又は湾曲させる第２工程と、毛髪成形剤を塗布された毛髪表面を加熱装置により加熱することにより毛髪に前記熱硬化性天然樹脂の熱硬化した皮膜を形成する第３工程を有する。 The method for styling hair according to the present invention comprises a first step of applying a hair shaping agent to the surface of each hair, and a second step of applying tension or bending in a predetermined direction to the hair to which the hair shaping agent has been applied. And a third step of forming a thermosetting film of the thermosetting natural resin on the hair by heating the hair surface to which the hair forming agent has been applied by a heating device.
第１工程は、毛髪成形剤を、手、刷毛又はスプレーを用いて、毛髪を成形しようとする部位にまんべんなく塗布する。毛髪成形剤を塗布する前に、毛髪を洗髪し、タオルドライしておくと塗布しやすい。また、洗髪の際、熱硬化性樹脂を含有する洗髪料を使用し、毛髪の表面の凹凸を熱硬化性樹脂で埋めることで、前記毛髪成形剤をより定着しやすくすることができる。 In the first step, the hair shaping agent is evenly applied to the site where the hair is to be shaped using a hand, a brush or a spray. It is easy to apply hair by washing the hair and applying towel drying before applying the hair shaping agent. Further, at the time of hair washing, a hair-washing agent containing a thermosetting resin is used, and the unevenness of the surface of the hair is filled with the thermosetting resin, whereby the hair-forming agent can be more easily fixed.
毛髪成形剤を塗布することにより、毛髪成形剤が毛髪の凹凸に含浸して凹部を埋めるとともに、毛髪の周囲に毛髪成形剤に含まれるセラック、エポキシ樹脂等の熱硬化性樹脂を配置する。 By applying the hair-forming agent, the hair-forming agent impregnates the unevenness of the hair to fill the recess, and a thermosetting resin such as shellac or epoxy resin contained in the hair-forming agent is disposed around the hair.
第２工程は、毛髪成形剤を塗布した毛髪を、ブラシや櫛を用いて伸ばしたり曲げることにより、所定方向に張力を与え、又はロッド等の器具に巻き付けて湾曲させることにより仮に形状を付ける。また、毛髪成形剤に含まれるセラック、エポキシ樹脂等の熱硬化性樹脂には接着作用があるため、ブラシや櫛をかけることにより、理美容上不自然な質感で硬化することを防止する。 The second step stretches or bends the hair on which the hair forming agent is applied with a brush or a comb to apply tension in a predetermined direction, or temporarily shapes it by winding and curving it on a device such as a rod. In addition, since thermosetting resins such as shellac and epoxy resin contained in the hair forming agent have an adhesive action, they are prevented from curing with an unnatural texture in terms of beauty and beauty by applying a brush or a comb.
第３工程は、前記第２工程により張力を与え、又は湾曲させた状態で、毛髪成形剤を塗布された毛髪に加熱装置である電熱器を使用して熱を与え、毛髪に熱硬化性天然樹脂の熱硬化した皮膜を形成する。電熱器は、ドライヤー、ヘアアイロンなどから適宜選択することができる。 The third step heats the hair on which the hair-forming agent is applied, using an electric heater, which is a heating device, in the tensioned or curved state in the second step, to heat harden the hair. Form a thermoset film of the resin. The electric heater can be appropriately selected from a dryer, a hair iron and the like.
セラック、エポキシ樹脂等の熱硬化性樹脂は、加熱することにより、分子間に架橋構造が形成され、分子が三次元網目構造をとって重合する。第３工程では、毛髪の周囲に配置されるセラック、エポキシ樹脂等の熱硬化性樹脂に架橋反応を生じさせ、セラック、エポキシ樹脂等の熱硬化性樹脂が熱硬化して皮膜を形成する。すなわち、上述のように毛髪にブラシや櫛などで張力を与えた状態で熱硬化させればその形状が維持され、また、湾曲させた状態で熱硬化させれば同形状が固定される。 By heating a thermosetting resin such as shellac or epoxy resin, a cross-linked structure is formed between molecules, and the molecules are polymerized in a three-dimensional network structure. In the third step, a crosslinking reaction is caused in a thermosetting resin such as shellac or epoxy resin disposed around the hair, and the thermosetting resin such as shellac or epoxy resin is thermally cured to form a film. That is, as described above, when the hair is thermally cured in a tensioned state with a brush or a comb, the shape is maintained, and when the hair is thermally cured in a curved state, the same shape is fixed.
セラックは、体温程度の温度でも徐々に硬化するが、体温よりも高い摂氏４３度以上の温度を及ぼすことにより、より早く熱硬化処理をすることができる。他方、２５０度以上の熱を加えると、毛髪の損傷が大きくなり、好ましくない。 The shellac cures gradually even at a temperature around body temperature, but can be cured more quickly by applying a temperature of 43 ° C. or higher higher than the body temperature. On the other hand, if heat of 250 degrees or more is applied, the damage to the hair becomes large, which is not preferable.
電熱器としては、毛髪にのみ高温の熱を加えることのできるヘアアイロンが好ましい。毛髪成形剤を塗布された毛髪に摂氏７０度以上の熱を加えることにより、毛髪成形剤に含まれるセラック、エポキシ樹脂等の熱硬化性樹脂の熱硬化が進展し、毛髪に熱硬化した皮膜を形成する。摂氏１７０度で３０秒ないし７分加熱することにより、毛髪成形剤に含まれるセラックが熱硬化した皮膜を形成する。特に、白セラックや脱色セラックを使用した毛髪成形剤であれば、摂氏１５０度で３０秒ないし５分加熱することにより、毛髪成形剤に含まれるセラックが熱硬化した皮膜を形成する。 As an electric heater, the hair iron which can apply high temperature heat only to hair is preferable. By applying heat of 70 ° C. or more to the hair to which the hair forming agent has been applied, the heat curing of the thermosetting resin such as shellac and epoxy resin contained in the hair forming agent progresses, and the thermally cured film is formed on the hair Form. By heating at 170 degrees Celsius for 30 seconds to 7 minutes, the shellac contained in the hair-forming agent forms a thermally cured film. In particular, in the case of a hair forming agent using white shellac or decolorized shellac, the shellac contained in the hair forming agent forms a thermally cured film by heating at 150 ° C. for 30 seconds to 5 minutes.
電熱器としてドライヤーを使用する場合は、毛髪に塗布した毛髪成形剤に熱を加える際に、温風が皮膚に触れるため、熱傷が生じない程度に適宜温度を調節する必要がある。 When a dryer is used as the electric heater, warm air touches the skin when applying heat to the hair-forming agent applied to the hair, so it is necessary to adjust the temperature appropriately to the extent that burns do not occur.
加熱装置としてパーマ用機器を使用する場合は、毛髪に塗布した毛髪成形剤に熱を加える際に、パーマ用機器から生じる熱が皮膚にも及ぶため、熱傷が生じない程度に適宜温度を調節する必要がある。また、毛根付近や毛髪の束の内側にも熱を及びやすくし、セラック又はエポキシ樹脂の熱硬化を促進するため、パーマ用機器用プレスを用いることができる。 When a permanent device is used as a heating device, when heat is applied to the hair-forming agent applied to the hair, the heat generated from the permanent device is also applied to the skin, so the temperature is adjusted appropriately to the extent that burns do not occur. There is a need. In addition, in order to facilitate heat transfer to the vicinity of hair roots and the inside of a bundle of hair and to accelerate the thermal curing of shellac or epoxy resin, a press for perming may be used.
また、本発明においては、セラック溶液が体熱で次第に硬化し、皮膜を形成する作用を利用して、電熱器を用いることなく、自然に、または風を当てることにより常温で硬化させ、毛髪に皮膜を形成することもできる。 Further, in the present invention, the shellac solution is gradually cured by body heat to form a film, and it is cured at room temperature naturally or by applying a wind without using an electric heater, to the hair. It is also possible to form a film.
第３工程の後に、洗髪し、適宜毛髪を整える。 After the third step, wash the hair and properly prepare the hair.
毛髪成形剤に含まれるセラック、エポキシ樹脂等の熱硬化性樹脂が毛髪の凹凸を埋め、毛髪を滑らかにすることにより、くせ毛が矯正される。また、硬化したセラック、エポキシ樹脂等の熱硬化性樹脂の皮膜が毛髪を取り囲んで成形及び支持することにより、毛髪に生じるうねり、縮れなどのくせが矯正されるとともに、張力を与えた状態で表面のセラック又はエポキシ樹脂を硬化させればその形状が維持され、また、湾曲させた状態で表面のセラック又はエポキシ樹脂を硬化させればその形状が維持されるように、ヘアスタイルを自然な風合いで成形することができる。 A thermosetting resin such as shellac or epoxy resin contained in the hair-forming agent fills the unevenness of the hair and smoothes the hair, thereby straightening hair is corrected. In addition, the film of thermosetting resin such as hardened shellac, epoxy resin, etc. surrounds and shapes and supports the hair, so that the curls, curls and the like generated on the hair are corrected and the surface is applied with tension. Curing shellac or epoxy resin maintains its shape, and curing the shellac or epoxy resin on the surface in a curved state maintains its shape, giving the hairstyle a natural feel It can be molded.
また、毛髪そのものの組織を改変することなく、毛髪の周囲に皮膜を付加するため、毛髪を染色・脱色した後に、毛髪成形剤を使用して毛髪のくせの矯正やヘアスタイルの成形を行っても、染色・脱色した毛髪の色を保つことができる。 Also, in order to add a film around the hair without modifying the structure of the hair itself, the hair is dyed and decolorized, and then the hair shaping agent is used to carry out hair straightening correction and hairstyle shaping. Also, the color of the dyed / bleached hair can be maintained.
また、セラック、エポキシ樹脂等の熱硬化性樹脂の硬化層は、三次元網目状組織となるために、毛髪の形状を保ちながらも、その網目を通して着色料やトリートメント剤を含浸しやすくなり、毛髪を矯正したあとでも、染毛やトリートメントを行うことができる。 In addition, since the cured layer of thermosetting resin such as shellac and epoxy resin has a three-dimensional network structure, it becomes easy to impregnate the coloring agent and the treatment agent through the network while maintaining the shape of the hair. Even after correcting the hair, you can perform hair dyeing and treatment.
また、毛髪にセラック、エポキシ樹脂等の熱硬化性樹脂の皮膜が、毛髪の保護膜として作用し、カラーリングや白髪染めの退色が抑えられ、毛髪の損傷、はね、湿度による膨張を抑制し、手触り感が向上し、手入れしやすい毛髪状態を維持することができる。 In addition, a film of thermosetting resin such as shellac or epoxy resin acts on the hair as a protective film of the hair, thereby suppressing discoloration of coloring and graying, and suppressing swelling due to hair damage, splashing, humidity, The feeling of touch is improved, and it is possible to maintain an easy-to-care hair condition.
さらに、毛髪に形成されたセラックの皮膜により、毛髪のつや出し効果も生じる。 In addition, the shellac film formed on the hair also produces a polish effect on the hair.
以下、実施例を挙げて本発明の具体例をさらに詳細に説明するが、本発明はこれらに限定されるものではない。 EXAMPLES Hereinafter, specific examples of the present invention will be described in more detail by way of examples, but the present invention is not limited thereto.
［実施例１］
毛髪成形剤
脱色セラック粉末 １ｇ
エタノール ９ｇ
水 ９０ｇ
計 １００ｇ
Example 1
Hair forming agent Decolorized shellac powder 1 g
9 g of ethanol
Water 90g
100g in total
霧吹きでくせのあるそれぞれの毛髪に毛髪成形剤をまんべんなく塗布し、櫛を用いて毛根から毛先の方向に張力を与え、摂氏約１５０度に発熱するヘアアイロンを使用してそれぞれの毛髪に５分間断続的に熱を加えた。その後、毛髪のカラーリングの施術を行った。その結果、くせのある毛髪がストレートに成形された状態が約１か月持続した。また、湿度による毛髪の膨張が抑制された。さらに、施術から約１か月後においても、カラーリングの退色が抑制された。 Apply hair shaping agent evenly to each misty hair, apply a tension from hair roots to hair tips using a comb, and apply 5 to each hair using a hair iron that heats to about 150 degrees Celsius. Heat was applied intermittently for a minute. After that, a hair coloring treatment was performed. As a result, the state in which the hazy hair was formed into a straight shape lasted for about one month. Moreover, the swelling of the hair by humidity was suppressed. Furthermore, even after about 1 month after the operation, the color fading was suppressed.
［実施例２］
毛髪成形剤
白セラック粉末 １．５ｇ
エタノール １０ｇ
ヒドロキシプロピルセルロース ０．２ｇ
加水分解ケラチン ０．５ｇ
アミノ酸複合体 ０．５ｇ
水 ８７．３ｇ
計 １００ｇ
Example 2
Hair forming agent White shellac powder 1.5 g
10 g of ethanol
Hydroxypropyl cellulose 0.2 g
Hydrolyzed keratin 0.5g
Amino acid complex 0.5g
Water 87.3g
100g in total
枝毛傾向のある毛髪を切り揃えた後、刷毛でそれぞれの毛髪に毛髪成形剤をまんべんなく塗布し、櫛を用いて毛根から毛先の方向に張力を与え、さらにロッドに毛髪を巻き付け、摂氏１１０度で毛髪に向けて熱を与えるパーマ用機器でそれぞれの毛髪に継続的に３０分間熱を与えた。その結果、毛髪がウェーブを有するように成形された状態が約１か月持続した。また、施術から約１か月後においても、毛髪の枝毛の増加が抑制された。 After trimming hair with a tendency to split hair, apply a hair-forming agent evenly to each hair with a brush, apply a tension from the hair roots to the hair tips with a comb, and wind the hair around a rod, Each hair was continuously heated for 30 minutes with a permanent device that heats the hair at 30 degrees. As a result, the state in which the hair was shaped to have a wave lasted for about one month. In addition, the increase in split hair of the hair was suppressed even about one month after the operation.
［実施例３］
毛髪成形剤
白セラック粉末 １．５ｇ
エタノール １０ｇ
ヒドロキシプロピルセルロース ０．２ｇ
加水分解ケラチン ０．５ｇ
アミノ酸複合体 ０．５ｇ
水 ８７．３ｇ
計 １００ｇ
[Example 3]
Hair forming agent White shellac powder 1.5 g
10 g of ethanol
Hydroxypropyl cellulose 0.2 g
Hydrolyzed keratin 0.5g
Amino acid complex 0.5g
Water 87.3g
100g in total
白髪染めを行った毛髪に、刷毛でそれぞれの毛髪に毛髪成形剤をまんべんなく塗布し、櫛を用いて毛根から毛先の方向に張力を与え、摂氏約１５０度に発熱するヘアアイロンを使用してそれぞれの毛髪に５分間断続的に熱を加えた。その結果、くせのある毛髪がストレートに成形された状態が約１か月持続した。さらに、黒髪とは髪質の異なるために生じる白髪のはね現象が抑制された。また、施術から約１か月後においても、白髪染めの退色が抑制された。 The hair forming agent is evenly applied to each hair with brush, to the hair dyed gray hair, and tension is applied from the hair root to the hair tip using a comb, and using a hair iron that generates approximately 150 degrees Celsius. Heat was applied intermittently to the hair for 5 minutes. As a result, the state in which the hazy hair was formed into a straight shape lasted for about one month. Furthermore, the splashing phenomenon of gray hair caused by the difference in hair quality from black hair was suppressed. In addition, fading of gray hair dye was suppressed even about one month after the operation.
Claims (2)
前記毛髪成形剤は、それぞれの毛髪の表面に塗布され、毛髪の凹凸に含浸して凹部を埋めるとともに、前記セラックを毛髪の周囲に配置させ、
毛髪の形状を仮形成したあと、又は形状固定しながら、毛髪を摂氏43度以上250度未満で加熱することにより毛髪に前記セラックによる三次元網目構造の硬化性の皮膜を均一に形成する方法において用いられる毛髪成形剤。 What is claimed is: 1. A hair forming agent comprising shellac , said shellac 's solvent selected from alcohol, phenol, ether or alkali, and a thickener, which is free of a reducing agent,
The hair-forming agent is applied to the surface of each hair to impregnate the unevenness of the hair to fill in the recesses and to place the shellac around the hair,
In a method for uniformly forming a curable film of a three-dimensional network structure by the shellac on a hair by heating the hair at 43 ° C. or more and less than 250 ° C. after temporarily forming the shape of the hair or fixing the shape . hair shaping agent used.
前記毛髪成形剤をそれぞれの毛髪の表面に塗布する工程と、前記毛髪成形剤を塗布した毛髪に所定方向に張力を与え、又は湾曲させる工程と、前記毛髪成形剤を塗布された毛髪表面を三次元網目構造の皮膜を均一に形成するため摂氏43度以上250度未満で加熱装置により加熱することにより毛髪に前記セラックの熱硬化した皮膜を形成する工程を有する毛髪のスタイリングの施術方法。 And shellac, an alcohol, a phenol, the shellac selected from ethers or alkaline solvent, and a thickening agent, using the hair shaping agent which does not contain a reducing agent to form the shellac coating to the hair a single surface A method of hair styling,
The steps of applying the hair forming agent to the surface of each hair, applying tension or bending in a predetermined direction to the hair to which the hair forming agent has been applied, and tertiary forming the hair surface to which the hair forming agent has been applied A method of styling hair comprising the step of forming a thermosetting film of said shellac on hair by heating with a heating device at 43 ° C. or more and less than 250 ° C. in order to uniformly form a film of original network structure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013129922A JP6541295B2 (en) | 2013-06-20 | 2013-06-20 | Hair shaping agent and method of styling hair using the hair shaping agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013129922A JP6541295B2 (en) | 2013-06-20 | 2013-06-20 | Hair shaping agent and method of styling hair using the hair shaping agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015003880A JP2015003880A (en) | 2015-01-08 |
| JP6541295B2 true JP6541295B2 (en) | 2019-07-10 |
Family
ID=52300076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013129922A Active JP6541295B2 (en) | 2013-06-20 | 2013-06-20 | Hair shaping agent and method of styling hair using the hair shaping agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6541295B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6518425B2 (en) * | 2013-10-21 | 2019-05-22 | 資生ケミカル株式会社 | Permanent wave aid containing shellac, permanent wave agent, and permanent wave treatment method using the same |
| JP6326575B2 (en) * | 2013-10-21 | 2018-05-23 | 資生ケミカル株式会社 | Wave forming agent containing shellac, and wave forming method using the same |
| JP6542183B2 (en) * | 2016-11-11 | 2019-07-10 | アース製薬株式会社 | Liquid oral composition |
| JP7281931B2 (en) * | 2019-03-22 | 2023-05-26 | 株式会社ミルボン | Hair composition and hair treatment method |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07537B2 (en) * | 1990-11-09 | 1995-01-11 | 株式会社ジャパンハッピー | Cold permanent wave treatment agent for hair |
| DE4419457A1 (en) * | 1994-06-03 | 1995-12-07 | Wella Ag | Hair treatment products and methods of use |
| JP2824213B2 (en) * | 1994-08-31 | 1998-11-11 | タカラベルモント株式会社 | 1st agent for permanent wave |
| JP3825655B2 (en) * | 2001-05-30 | 2006-09-27 | タカラベルモント株式会社 | First agent for permanent wave |
-
2013
- 2013-06-20 JP JP2013129922A patent/JP6541295B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2015003880A (en) | 2015-01-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104159567B (en) | The method for being used to protect and repair keratin fiber using anionic polysaccharide | |
| JP6541295B2 (en) | Hair shaping agent and method of styling hair using the hair shaping agent | |
| CN103260595A (en) | Compositions and methods for treating keratin based fibers | |
| CN101500533A (en) | Method and composition for permanently shaping hair | |
| TWI663988B (en) | Hair deformation treatment agent | |
| CN103391763A (en) | Method for chemically modifying the internal region of a hair shaft | |
| CN111148500A (en) | Novel composition for straightening hair | |
| JP6659727B2 (en) | Composition for keratin fibers | |
| WO2011155076A1 (en) | Compositions and process for treating keratin fibers | |
| US20170360679A1 (en) | Chitosan: Aldehyde Film-Coated Fibers or Hairs, Related Methods and Compositions | |
| WO2016006529A1 (en) | Hair treatment agent | |
| CN106999380B (en) | Hair deforming agent | |
| US20180353401A1 (en) | A hair care composition, process for preparing the same and method of use thereof | |
| JP2012532864A (en) | Permanent deformation method of keratin fiber | |
| JP2019123701A (en) | Hair treatment agent | |
| CN111372561A (en) | Hair treatment method | |
| CN105555254A (en) | Process for treating keratin fibres with an oxidised polysaccharide and a sphingosine compound | |
| TWI802784B (en) | Hair treatment method | |
| CN106999381A (en) | Hair deformation process agent | |
| JP5379970B2 (en) | 1st hair shape control agent | |
| JP2023063378A (en) | Hair cosmetic | |
| ES2728456T5 (en) | Hair treatment procedure | |
| JP6657204B2 (en) | Hair molding composition | |
| JP3037481B2 (en) | Waving lotion and method of using the same | |
| TW201922219A (en) | Hair treatment method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20160520 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20160526 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20160520 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20170419 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20170606 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170804 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180130 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20180330 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180524 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20181106 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190204 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20190205 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20190416 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190528 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190611 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6541295 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313117 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |