JP6527212B2 - Process for producing flammable gas from carbon dioxide acid and oxyhydrogen gas - Google Patents
Process for producing flammable gas from carbon dioxide acid and oxyhydrogen gas Download PDFInfo
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- JP6527212B2 JP6527212B2 JP2017225146A JP2017225146A JP6527212B2 JP 6527212 B2 JP6527212 B2 JP 6527212B2 JP 2017225146 A JP2017225146 A JP 2017225146A JP 2017225146 A JP2017225146 A JP 2017225146A JP 6527212 B2 JP6527212 B2 JP 6527212B2
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 90
- 239000001569 carbon dioxide Substances 0.000 title claims description 45
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 45
- 238000000034 method Methods 0.000 title claims description 10
- 239000002253 acid Substances 0.000 title 1
- 239000007789 gas Substances 0.000 claims description 100
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- 238000002485 combustion reaction Methods 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 3
- 229910001882 dioxygen Inorganic materials 0.000 claims 3
- 230000009172 bursting Effects 0.000 claims 1
- 238000005868 electrolysis reaction Methods 0.000 claims 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000002737 fuel gas Substances 0.000 description 7
- 239000000446 fuel Substances 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 239000002803 fossil fuel Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- VNWKTOKETHGBQD-YPZZEJLDSA-N carbane Chemical compound [10CH4] VNWKTOKETHGBQD-YPZZEJLDSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Description
本発明は、二酸化炭素と水をから生成した酸水素ガスとを反応させて、可燃性ガス体を製造する方法に関する。 The present invention relates to a method for producing a flammable gas by reacting carbon dioxide and an oxyhydrogen gas produced from water.
現在、二酸化炭素は地球温暖化の最大の要因と言われているが、この防止対策や別の化合物に変換して再利用する工業的対策や技術的方法は無く、経済の発展に伴って増加の一途をたどっており、その結果引き起こされる温暖化による地球環境への悪影響は想像を遥か超えるものとなっている。例えば、気温の高温化による異常気象、海流の変化による高潮、生態系への悪影響、渇水や洪水、海面上昇による陸地の水没、農作物の収穫不良による食物の不足など人類の生存を脅かす危機は枚挙に暇がない。従って、この二酸化炭素を再利用してその増加を抑えること急務である。 At present, carbon dioxide is said to be the main cause of global warming, but there is no industrial measure or technical method to convert it into another compound and reuse it, and it will increase with economic development. The global warming caused by the resulting global environmental impacts is far beyond imagination. For example, the crisis that threatens human survival such as abnormal weather due to high temperature, storm surge due to change of ocean current, adverse effect on ecosystem, drought and flood, land submersion due to rising sea level, lack of food due to poor harvest of crops etc. I have no time for Therefore, it is urgent to recycle this carbon dioxide and to control its increase.
発明者は、以前に水を特殊な振動撹拌で電気分解を行うことにより、ナノ・マイクロバブル（酸素と水素ガスが微細な泡となったもの）が生成しこれが破裂することにより従来の酸水素ガスとは異なる安全な酸素と水素の結合体のガス（従来の酸水素ガスとの混同を避けるため、以後ＯＨＭＡＳＡ−ＧＡＳと称す）を得ることに成功している（特許文献１〜３）。このガスには、Ｈ２Ｏクラスターが含まれているため、従来の酸水素ガスのように爆発することはなく安全であることが確認されている（非特許文献１）。 The inventor has previously electrolyzed water with special vibrational stirring to form nano / micro bubbles (the one in which oxygen and hydrogen gas are in the form of fine bubbles), which are ruptured to form a conventional oxyhydrogen. It has succeeded in obtaining a safe gas of a combination of oxygen and hydrogen (hereinafter referred to as OHMASA-GAS to avoid confusion with conventional oxyhydrogen gas) different from gas (Patent Documents 1 to 3). Since this gas contains H 2 O clusters, it has been confirmed that it does not explode like the conventional oxyhydrogen gas and is safe (Non-Patent Document 1).
このＯＨＭＡＳＡ−ＧＡＳを用いて溶接、溶断又はろうづけ等の作業を行う場合、アセチレンやプロパンガスを用いて実施する場合に比べて、約６０〜７０％のコスト低減が可能であること見出している（特許文献２、特許文献３）。また、ＯＨＭＡＳＡ−ＧＡＳ５０％＋ＬＰガス５０％の混合比で発電した場合、ＬＰガス１００％で発電した場合のコストの約半分、設備投資がほとんどかからないことも報告されている（非特許文献１）。 When performing work such as welding, fusion cutting or brazing using this OHMASA-GAS, it is found that cost reduction of about 60 to 70% is possible as compared with the case of using acetylene or propane gas. (Patent Document 2, Patent Document 3). In addition, it is also reported that when power is generated at a mixing ratio of OHMASA-GAS 50% + LP gas 50%, about half of the cost when power is generated with 100% LP gas and that equipment investment is hardly incurred (Non-patent Document 1).
本発明は、上記のようにＯＨＭＡＳＡ−ＧＡＳに基づいて、二酸化炭素の利用と削減を達成することを目的としたものである。 The present invention aims to achieve carbon dioxide utilization and reduction based on OHMASA-GAS as described above.
上記目的は、請求項１に記載の方法によって、達成される。請求項１の方法は、以下の（１）〜（８）のいずれかの構成に関連するものである。 The above object is achieved by the method according to claim 1 . The method of claim 1 relates to any one of the following configurations (1) to (8) .
（１）所定の混合比率の二酸化炭素とＯＨＭＡＳＡ−ＧＡＳとを、所定の圧力及び所定の温度において反応させることを特徴とする可燃性ガス体の製造方法。 (1) A method for producing a flammable gas comprising reacting carbon dioxide in a predetermined mixing ratio with OHMASA-GAS at a predetermined pressure and a predetermined temperature.
（２）前記圧力は０．１ＭＰａ〜１０ＭＰａであることを特徴とする前記（１）に記載の可燃性ガス体の製造方法。 (2) The method for producing a flammable gas according to (1), wherein the pressure is 0.1 MPa to 10 MPa.
（３）前記温度は５℃〜５０℃であることを特徴とする前記（１）に記載の可燃性ガス体の製造方法。 (3) The method for producing a combustible gas according to (1), wherein the temperature is 5 ° C to 50 ° C.
（４）前記混合比率は、二酸化炭素が９０％〜１０％、ＯＨＭＡＳＡ−ＧＡＳが１０％〜９０％であることを特徴とする前記（１）に記載の可燃性ガス体の製造方法。 (4) The method for producing a combustible gas according to (1), wherein the mixing ratio is 90% to 10% of carbon dioxide and 10% to 90% of OHMASA-GAS.
（５）前記（１）ないし（４）の何れか１項に記載の方法により製造した可燃性ガス体を燃焼させる際に発生する二酸化炭素をリサイクルして、前記（１）ないし（４）の何れか１項に記載の方法に再利用することを特徴とするシステム。 (5) The carbon dioxide generated when the combustible gas produced by the method according to any one of the above (1) to (4) is burned is recycled, A system for reuse in the method according to any one of the preceding claims.
（６）前記（１）ないし（４）の何れか１項に記載の方法により製造した可燃性ガス体は、プロパンガス及びメタンガスを含む化石燃料と任意の比率で混合して新たな燃料が生成できることを特徴とする可燃性ガス体。 (6) The combustible gas produced by the method according to any one of the above (1) to (4) is mixed with a fossil fuel containing propane gas and methane gas in any ratio to produce a new fuel A flammable gas that can be characterized.
（７）ＯＨＭＡＳＡ−ＧＡＳ発生装置及びガス混合タンクを含んで成るシステムであって、前記ガス混合タンクは、前記発生装置からのＯＨＭＡＳＡ−ＧＡＳ、並びに外部のガス燃焼機からの排ガスの１０〜５０％を受け入れて、そこで二酸化炭素とＯＨＭＡＳＡ−ＧＡＳを反応させて新規の燃料ガスを合成することができることを特徴とするシステム。 (7) A system comprising an OHMASA-GAS generator and a gas mixing tank, wherein the gas mixing tank is 10 to 50% of the OHMASA-GAS from the generator and the exhaust gas from an external gas burner A system capable of reacting carbon dioxide with OHMASA-GAS to synthesize a new fuel gas.
（８）ＯＨＭＡＳＡ−ＧＡＳ発生装置の電解槽内の電極を構成する白金に二酸化炭素を直接に吹き付けて、発生するＯＨＭＡＳＡ−ＧＡＳと反応させて可燃性ガスを合成することを特徴とするシステム。 (8) A system characterized in that carbon dioxide is directly sprayed on platinum constituting an electrode in an electrolytic cell of an OHMASA-GAS generator to react with the generated OHMASA-GAS to synthesize a flammable gas.
（９）可燃性ガス又は可燃性ガスとＯＨＭＡＳＡ−ＧＡＳの混合ガスを、発電機、ボイラー又は自動車の燃料として燃焼させ、大気中への二酸化炭素の新たな排出をほぼ無くすため、前記燃焼により発生する排ガス中の二酸化炭素を再度利用して、ＯＨＭＡＳＡ−ＧＡＳと反応させることを特徴とするシステム。 (9) A combustible gas or a mixed gas of combustible gas and OHMASA-GAS is burned as a fuel for a generator, a boiler or a car, and it is generated by the combustion to almost eliminate new emission of carbon dioxide to the atmosphere. A system characterized by reusing carbon dioxide in the exhaust gas to react with OHMASA-GAS.
本発明により、二酸化炭素を有効利用して、その削減を図ることができるので、地球温暖化の抑制が可能となった。また、二酸化炭素と反応させるＯＨＭＡＳＡ−ＧＡＳは、安価な深夜電力を利用して生成できるので、本発明による新燃料ガスは低コストで製造することが可能である。 According to the present invention, carbon dioxide can be effectively used and the reduction thereof can be achieved, thereby suppressing global warming. In addition, since OHMASA-GAS to be reacted with carbon dioxide can be generated using inexpensive late-night power, the new fuel gas according to the present invention can be manufactured at low cost.
地球の大気中に過剰に存在する二酸化炭素を新燃料として使えることを発見した事は、地球規模的な大発見である。 The discovery of the use of excess carbon dioxide in the Earth's atmosphere as a new fuel is a global discovery.
本発明の新燃料ガスの原料として用いる二酸化炭素は、大気中に存在するガス体でも、物体を燃焼して生成する二酸化炭素でもよく、特定の二酸化炭素を指定するものではなく、普通一般的に言われている二酸化炭素のいずれでもよい。 The carbon dioxide used as the raw material of the new fuel gas of the present invention may be a gas existing in the atmosphere or carbon dioxide produced by burning an object, and does not designate a specific carbon dioxide, and is generally and generally Any of the said carbon dioxide may be used.
しかしながら、二酸化炭素と反応させる「酸水素ガス」は、従来の酸水素ガスではなく、発明者が既に権利化している方法（特許文献１〜３）によって得られる酸水素ガス（即ちＯＨＭＡＳＡ−ＧＡＳ）を用いないと反応しない。 However, the “oxygen hydrogen gas” to be reacted with carbon dioxide is not a conventional oxygen hydrogen gas, but an oxygen hydrogen gas (ie, OHMASA-GAS) obtained by a method (patent documents 1 to 3) already owned by the inventor It does not react without using.
以下、二酸化炭素とＯＨＭＡＳＡ−ＧＡＳとを反応させて新燃料を生成及びその結果得られた新燃料の燃焼試験の実施例を説明する。 Hereinafter, an example of a combustion test of new fuel obtained by reacting carbon dioxide and OHMASA-GAS to produce a new fuel will be described.
直径１００ｍｍ、高さ８００ｍｍ、容積約６．２８リットルの高圧ガラス管を真空引き（ゲージ圧−０．１ＭＰａ）した後、ＯＨＭＡＳＡ−ＧＡＳを０．３ＭＰａ（ゲージ圧）まで充填し、次いで０．８ＭＰａ（ゲージ圧）になるまで二酸化炭素を充填した。この混合ガスを１．５ＭＰａ（ゲージ圧）の圧力になるまで加圧機で圧縮した。圧縮後の高圧ガラス管の中には、水滴や蒸気など液状物と思われる物体は観察されず、気体のみであった。 A high pressure glass tube with a diameter of 100 mm, a height of 800 mm and a volume of about 6.28 liters is evacuated (gauge pressure-0.1 MPa), then filled with OHMASA-GAS to 0.3 MPa (gauge pressure), and then 0.8 MPa The carbon dioxide was filled up to (gauge pressure). This mixed gas was compressed with a press to a pressure of 1.5 MPa (gauge pressure). In the high-pressure glass tube after compression, an object thought to be a liquid such as water droplets or steam was not observed, and it was only gas.
実施例１の混合反応ガスを１５分後にバーナーにて燃焼試験を行った。その結果、青味がかったシャープな火炎が観察された。もし、実施例１の気体が、単にＯＨＭＡＳＡ−ＧＡＳと二酸化炭素の混合気体ならば、燃焼するのはＯＨＭＡＳＡ−ＧＡＳガスのみであるから、以前に行ったＯＨＭＡＳＡ−ＧＡＳの燃焼試験から考えて、火炎の色は無色であるはずである。しかしながら、実施例１の気体を燃焼させた火炎の色は青味を帯びており、ＯＨＭＡＳＡ−ＧＡＳと二酸化炭素が反応して生成した炭素と水素及び酸素を有する新規な燃料ガスが生成されたことは明白である。また、この燃焼は３００℃〜５００℃の範囲であり、且つ安全で安定していた。 The mixed reaction gas of Example 1 was subjected to a combustion test with a burner after 15 minutes. As a result, a bluish sharp flame was observed. If the gas of Example 1 is only a mixed gas of OHMASA-GAS and carbon dioxide, it is only OHMASA-GAS gas which burns. The color of should be colorless. However, the color of the flame burning the gas of Example 1 is bluish, and a novel fuel gas having carbon, hydrogen and oxygen generated by the reaction of OHMASA-GAS and carbon dioxide is generated. Is obvious. Moreover, this combustion was in the range of 300 ° C. to 500 ° C., and was safe and stable.
実施例１で用いた高圧ガラス管に、二酸化炭素とＯＨＭＡＳＡ−ＧＡＳを７０：３０、５０：５０又は３０：７０の比率にとなるように混合し、ゲージ圧が１ＭＰａ及び１．５ＭＰａとなるまで圧縮した。圧縮後の高圧ガラス管の中には、水滴や蒸気など液状物と思われる物体は観察されず、気体のみであった。 Carbon dioxide and OHMASA-GAS are mixed in a ratio of 70:30, 50:50 or 30:70 in the high pressure glass tube used in Example 1 until the gauge pressure becomes 1 MPa and 1.5 MPa. Compressed. In the high-pressure glass tube after compression, an object thought to be a liquid such as water droplets or steam was not observed, and it was only gas.
このことから、上記の混合比率、圧縮圧力の範囲内では、液状物と思われる物体は観察されず、気体のみであることを確認した。 From this, it was confirmed that the substance considered to be a liquid was not observed within the range of the above-mentioned mixing ratio and compression pressure, and it was only gas.
実施例３で生成したガスを１５分、１週間、１ケ月経過した後にバーナーで燃焼試験を行った。その結果、実施例２と同様に、青味がかったシャープな火炎が観察され、時間経過による差異は無かった。 The gas produced in Example 3 was subjected to a combustion test with a burner after 15 minutes, one week, and one month had passed. As a result, as in Example 2, a bluish sharp flame was observed, and there was no difference with time.
実施例３と同様な条件において、温度を５℃、１５℃又は３０℃と変化させたが、高圧ガラス管の中には、水滴や蒸気など液状物と思われる物体は観察されず、気体のみであった。 The temperature was changed to 5 ° C., 15 ° C. or 30 ° C. under the same conditions as in Example 3. However, in the high-pressure glass tube, no object thought to be a liquid such as water droplets or steam was observed. Met.
プロパンガス及びメタンガスを含む化石燃料を０．１〜５％、二酸化炭素を２０〜５０％、残部をＯＨＭＡＳＡ−ＧＡＳとなるように混合して反応させた。この反応生成物の燃焼試験を行ったところ、青色を帯びた火炎が観察され、このことにより、カーボンの燃焼が確認できた。プロパンガス及びメタンガスを含む化石燃料を０．５％、二酸化炭素を３５％、残部をＯＨＭＡＳＡ−ＧＡＳが最適な混合比率であった。 0.1 to 5% of fossil fuel containing propane gas and methane gas, 20 to 50% of carbon dioxide, and the rest were mixed and reacted so as to be OHMASA-GAS. When the combustion test of this reaction product was conducted, a bluish flame was observed, which confirmed the combustion of carbon. The optimal mixing ratio was 0.5% fossil fuel containing propane gas and methane gas, 35% carbon dioxide, and the remainder OHMASA-GAS.
なお、上記実施例では高圧ガラス管にて反応させたが、生成した気体は従来から用いているステンレス、鋼板製の容器に保存したが、容器が変化することもなく安定していた。 In the above example, the reaction was carried out with a high pressure glass tube, but the generated gas was stored in a container made of stainless steel and steel plate conventionally used, but the container was stable without any change.
実施例３と同様な方法で、二酸化炭素とＯＨＭＡＳＡ−ＧＡＳの混合比率を変えて比較したところ、二酸化炭素が１０〜５０％、ＯＨＭＡＳＡ−ＧＡＳが９０〜５０％の混合比率において最適な燃焼を得ることができた。 When the mixing ratio of carbon dioxide and OHMASA-GAS is changed and compared in the same manner as in Example 3, optimum combustion is obtained at a mixing ratio of 10 to 50% of carbon dioxide and 90 to 50% of OHMASA-GAS. I was able to.
２つの混合比率による熱量は下記の通りであった。
（１）二酸化炭素：２０％ ＯＨＭＡＳＡ−ＧＡＳ：８０％
４４．８ＭＪ／ｍ３（１０，７００Ｋｃａｌ／ｍ３）
（２）二酸化炭素：４０％ ＯＨＭＡＳＡ−ＧＡＳ：６０％
４３．９ＭＪ／ｍ３（１０，５００Ｋｃａｌ／ｍ３）
なお、測定は、一般的な気体の熱量測定に準じた方法により行った。
The heat quantity by two mixing ratios was as follows.
(1) Carbon dioxide: 20% OHMASA-GAS: 80%
44.8 MJ / m3 (10,700 Kcal / m3)
(2) Carbon dioxide: 40% OHMASA-GAS: 60%
43.9 MJ / m3 (10, 500 Kcal / m3)
In addition, the measurement was performed by the method according to general calorie measurement of gas.
実施例に述べたように、ＯＨＭＡＳＡ−ＧＡＳは炭酸ガスと反応して、新規の燃料ガスを生成することが判明したので、ＯＨＭＡＳＡ−ＧＡＳ発生装置と組み合わせて、二酸化炭素を削減するシステムを構成することが可能となる。二酸炭素削減システムは、ＯＨＭＡＳＡ−ＧＡＳ発生装置及びガス混合タンク（クッションタンク）から成り、ガス混合タンクは、前記発生装置からのＯＨＭＡＳＡ−ＧＡＳ、並びに外部のガス燃焼機（エンジン、ボイラーなど）からの排ガスの１０〜５０％を受け入れて、そこで二酸化炭素とＯＨＭＡＳＡ−ＧＡＳを反応させて新規の燃料ガスを合成することができる。 As described in the example, OHMASA-GAS has been found to react with carbon dioxide gas to generate a new fuel gas, so in combination with the OHMASA-GAS generator, a system to reduce carbon dioxide is constructed. It becomes possible. The carbon dioxide reduction system consists of an OHMASA-GAS generator and a gas mixing tank (cushion tank), and the gas mixing tank is from the OHMASA-GAS from the generator and an external gas burner (engine, boiler, etc.) 10 to 50% of the exhaust gas from the carbon dioxide, where carbon dioxide and OHMASA-GAS can be reacted to synthesize a new fuel gas.
更には、上記ガス混合タンクを省いて、二酸化炭素が１０〜５０％、ＯＨＭＡＳＡ−ＧＡＳが９０〜５０％の混合比率となるようにＯＨＭＡＳＡ−ＧＡＳ発生装置の電解槽内の電極を構成する白金に二酸化炭素を直接に吹き付けて、発生するＯＨＭＡＳＡ−ＧＡＳと反応させて新規の可燃性ガスを合成するも可能である。 Furthermore, the above-mentioned gas mixing tank is omitted, platinum constituting the electrode in the electrolytic cell of the OHMASA-GAS generator so that the mixing ratio of carbon dioxide is 10 to 50% and OHMASA-GAS is 90 to 50%. It is also possible to spray carbon dioxide directly and react with the generated OHMASA-GAS to synthesize a new flammable gas.
これを更に発展させて、可燃性ガス又は可燃性ガスとＯＨＭＡＳＡ−ＧＡＳの混合ガスを、発電機、ボイラー又は自動車等の燃料として燃焼させ、その燃焼より発生する排ガス中の二酸化炭素を再度、ＯＨＭＡＳＡ−ＧＡＳと反応させて可燃性ガスを合成し、利用することで、大気中への新たな二酸化炭素の排出をほぼ無くすシステムを構築することも可能である。 By further developing this, the combustible gas or the mixed gas of the combustible gas and OHMASA-GAS is burned as fuel for a generator, a boiler or a car, and carbon dioxide in the exhaust gas generated from the combustion is reused again. -It is also possible to construct a system that substantially eliminates new carbon dioxide emissions to the atmosphere by reacting with GAS to synthesize combustible gas and using it.
これらのシステムにより、二酸化炭素の再利用及び削減が図られ、安価に新たな熱源が得られることになる。 By these systems, carbon dioxide can be reused and reduced, and a new heat source can be obtained inexpensively.
本発明による、二酸化炭素とＯＨＭＡＳＡ−ＧＡＳを反応させて得られる新規の燃料ガスは、爆発などの危険もないので、家庭、自動車、船舶用の燃料など従来使用されていた化石燃料に置き換えるか、又は化石燃料と混合して幅広く使用できることが特徴である。 Since the novel fuel gas obtained by reacting carbon dioxide and OHMASA-GAS according to the present invention does not have the danger of explosion or the like, it should be replaced with conventionally used fossil fuels such as household, automobile and marine fuels, It is characterized in that it can be widely used mixed with fossil fuels.
Claims (1)
当該電気分解により発生した酸素と水素とを、前記振動させながら撹拌することによって、酸素ガスの微細な泡と水素ガスの微細な泡を生成させることと、Generating oxygen gas and hydrogen gas bubbles by stirring the oxygen and hydrogen generated by the electrolysis while vibrating the oxygen gas and the hydrogen gas;
当該酸素ガスの微細な泡と当該水素ガスの微細な泡とが破裂することによって、酸素と水素とが結合した可燃性ガスであって、ＨIt is a flammable gas in which oxygen and hydrogen are combined by bursting the fine bubbles of the oxygen gas and the fine bubbles of the hydrogen gas, and H ２2 Ｏクラスターを含有する可燃性ガスを得ることと、Obtaining a flammable gas containing O clusters,
前記可燃性ガスの１０％〜９０％と、二酸化炭素の９０％〜１０％とを、圧力容器内に、０．１ＭＰａ〜１０ＭＰａの圧力になるまで、５℃〜５０℃の温度で、圧縮して充填することと、Compress 10% to 90% of the flammable gas and 90% to 10% of carbon dioxide in the pressure vessel at a temperature of 5 ° C to 50 ° C until a pressure of 0.1 MPa to 10 MPa is reached. Filling, and
前記ガスと前記二酸化炭素との混合ガスを、前記圧力容器から得て燃焼させることと、Obtaining a mixed gas of the gas and the carbon dioxide from the pressure vessel and burning it;
当該燃焼を熱源として利用することと、Using the combustion as a heat source;
を備える、二酸化炭素の利用と削減方法。, Carbon dioxide utilization and reduction methods.
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