JP6523297B2 - 調節可能なレベルの金属含有抗凝集剤を含むゴム - Google Patents

調節可能なレベルの金属含有抗凝集剤を含むゴム Download PDF

Info

Publication number
JP6523297B2
JP6523297B2 JP2016543014A JP2016543014A JP6523297B2 JP 6523297 B2 JP6523297 B2 JP 6523297B2 JP 2016543014 A JP2016543014 A JP 2016543014A JP 2016543014 A JP2016543014 A JP 2016543014A JP 6523297 B2 JP6523297 B2 JP 6523297B2
Authority
JP
Japan
Prior art keywords
copolymer
ppm
weight
polyvalent metal
amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2016543014A
Other languages
English (en)
Japanese (ja)
Other versions
JP2017502152A (ja
Inventor
ディヴィッド・トンプソン
クリントン・ランド
Original Assignee
アランセオ・シンガポール・プライヴェート・リミテッド
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by アランセオ・シンガポール・プライヴェート・リミテッド filed Critical アランセオ・シンガポール・プライヴェート・リミテッド
Publication of JP2017502152A publication Critical patent/JP2017502152A/ja
Application granted granted Critical
Publication of JP6523297B2 publication Critical patent/JP6523297B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/18Suspension polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/08Butenes
    • C08F210/10Isobutene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/06Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/07Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from polymer solutions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/12Powdering or granulating
    • C08J3/124Treatment for improving the free-flowing characteristics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/10Materials in mouldable or extrudable form for sealing or packing joints or covers
    • C09K3/1006Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/08Butenes
    • C08F210/10Isobutene
    • C08F210/12Isobutene with conjugated diolefins, e.g. butyl rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08J2323/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08J2323/22Copolymers of isobutene; butyl rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2401/00Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • C08J2401/02Cellulose; Modified cellulose
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2200/00Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
    • C09K2200/06Macromolecular organic compounds, e.g. prepolymers
    • C09K2200/0607Rubber or rubber derivatives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2200/00Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
    • C09K2200/06Macromolecular organic compounds, e.g. prepolymers
    • C09K2200/0607Rubber or rubber derivatives
    • C09K2200/061Butyl rubber

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Sealing Material Composition (AREA)
  • Graft Or Block Polymers (AREA)
JP2016543014A 2013-12-23 2014-12-22 調節可能なレベルの金属含有抗凝集剤を含むゴム Active JP6523297B2 (ja)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
EP13199416.2 2013-12-23
EP13199416 2013-12-23
EP14160630 2014-03-19
EP14160630.1 2014-03-19
EP14175017 2014-06-30
EP14175017.4 2014-06-30
EP14175966.2 2014-07-07
EP14175966 2014-07-07
PCT/CA2014/051247 WO2015095958A1 (en) 2013-12-23 2014-12-22 Rubbers with tunable levels of metal containing anti-agglomerants

Publications (2)

Publication Number Publication Date
JP2017502152A JP2017502152A (ja) 2017-01-19
JP6523297B2 true JP6523297B2 (ja) 2019-05-29

Family

ID=53477245

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2016543014A Active JP6523297B2 (ja) 2013-12-23 2014-12-22 調節可能なレベルの金属含有抗凝集剤を含むゴム

Country Status (10)

Country Link
US (1) US10000632B2 (https=)
EP (1) EP3087138B1 (https=)
JP (1) JP6523297B2 (https=)
KR (1) KR102351737B1 (https=)
CN (1) CN106232709B (https=)
CA (1) CA2934807C (https=)
RU (1) RU2706122C2 (https=)
SA (1) SA516371387B1 (https=)
SG (2) SG10201810330XA (https=)
WO (1) WO2015095958A1 (https=)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015095957A1 (en) 2013-12-23 2015-07-02 Lanxess Inc. Ultra pure rubber
CN106232709B (zh) 2013-12-23 2020-10-13 阿朗新科新加坡私人有限公司 具有可调水平的含金属防聚剂的橡胶
SG11201605114SA (en) 2013-12-23 2016-07-28 Arlanxeo Singapore Pte Ltd Novel anti-agglomerants for elastomeric ethylene/α-olefin copolymers
CA2934812C (en) 2013-12-23 2023-07-25 Arlanxeo Singapore Pte. Ltd. Anti-agglomerants for the rubber industry
US10703865B2 (en) 2013-12-23 2020-07-07 Arlanxeo Singapore Pte. Ltd. Highly pure halogenated rubbers
SG11201608799PA (en) * 2014-04-30 2016-11-29 Arlanxeo Singapore Pte Ltd Diluent for the production of butyl rubber
CN106536619B (zh) * 2014-06-30 2021-02-12 阿朗新科新加坡私人有限公司 用于橡胶工业的新型防聚剂
DE102017208338A1 (de) * 2017-05-17 2018-11-22 Rema Tip Top Ag Chloropren-Klebstoff-System
US20200385550A1 (en) * 2017-12-14 2020-12-10 Compagnie Generale Des Etablissements Michelin Aircraft tire
JP6973505B2 (ja) * 2017-12-15 2021-12-01 日本電気株式会社 セルロース系樹脂組成物、成形体及びこれを用いた製品
CN109107127B (zh) * 2018-09-10 2020-05-12 河海大学 基于传感技术的篮球训练毯
US20220251330A1 (en) * 2019-07-19 2022-08-11 Zeon Corporation Acrylic rubber bale excellent in storage stability and water resistance

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2580490A (en) 1948-01-30 1952-01-01 Standard Oil Dev Co Method for starting up low-tem-perature isoolefin polymerization
US2856394A (en) 1955-10-06 1958-10-14 Exxon Research Engineering Co Polyisobutylene polymerization process having coarse and fine molecular weight control
US3085074A (en) * 1959-11-16 1963-04-09 Burke Aqueous dispersions of halogenated, polymer modified butyl rubber, process of makingsame, and vulcanization thereof
US3301810A (en) 1961-03-24 1967-01-31 Exxon Research Engineering Co Isoolefin-multiolefin copolymers through ultrasonic homogenizers
NL134120C (https=) 1961-11-24 1900-01-01
US3553156A (en) * 1966-12-15 1971-01-05 Du Pont Separation of ethylene copolymer elastomers from their solvent solutions
US3976609A (en) * 1967-07-13 1976-08-24 Bayer Aktiengesellschaft Process for the preparation of distributions
US3496135A (en) * 1968-02-02 1970-02-17 Du Pont Crude epdm copolymer stabilized with a lewis base
JPS541741B1 (https=) * 1969-08-13 1979-01-29
US4059651A (en) 1970-03-11 1977-11-22 Exxon Research & Engineering Co. Curable blends of EPDM and polypropylene
US3726843A (en) * 1970-11-03 1973-04-10 Du Pont Process for isolating epdm elastomers from their solvent solutions
BE794266A (fr) 1972-01-20 1973-07-19 Exxon Research Engineering Co Procede de preparation d'emulsions de butyl-caoutchoucs sulfones
NL7206711A (https=) 1972-05-18 1973-11-20
DE2325550A1 (de) 1973-05-19 1974-12-05 Huels Chemische Werke Ag Verfahren zur herstellung rieselfaehiger, pulverfoermiger kautschuk-fuellstoffmischungen
US4946940A (en) * 1983-12-23 1990-08-07 Exxon Research And Engineering Company Phase separation processes
US5071913A (en) 1987-12-11 1991-12-10 Exxon Chemical Patents Inc. Rubbery isoolefin polymers exhibiting improved processability
US4946899A (en) 1988-12-16 1990-08-07 The University Of Akron Thermoplastic elastomers of isobutylene and process of preparation
DE4426756A1 (de) * 1994-07-28 1996-02-01 Bayer Ag Verfahren zur Herstellung von C¶4¶-C¶1¶¶6¶-Alkylkautschuken nach dem Slurry-Verfahren
DE19631731A1 (de) * 1996-08-06 1998-02-12 Bayer Ag Halogenierte Butylkautschuke mit einem geringen Halogengehalt
CA2216062A1 (en) * 1997-09-19 1999-03-19 Bayer Inc. Silica-containing rubber composition
KR20020046165A (ko) 2000-12-12 2002-06-20 빌프리더 하이더 타이어 트레드용 고무 조성물
WO2004058827A1 (en) 2002-12-20 2004-07-15 Exxonmobil Chemical Patents Inc. Polymerization processes
DE60332866D1 (de) * 2002-12-20 2010-07-15 Exxonmobil Chem Patents Inc Polymere mit neuen sequenzverteilungen
US20040244978A1 (en) * 2003-06-04 2004-12-09 Sun Drilling Products Corporation Lost circulation material blend offering high fluid loss with minimum solids
CA2458750C (en) 2004-02-23 2012-02-07 Bayer Inc. Isoolefin-diolefin production process and apparatus therefor
US7629397B2 (en) * 2006-06-23 2009-12-08 Exxonmobil Chemical Patents Inc. Phase separation process utilizing a hydrofluorocarbon
EP2269727A1 (de) 2009-07-01 2011-01-05 LANXESS International SA Rohrreaktor und Verfahren zur kontinuierlichen Polymerisation
KR20120115355A (ko) * 2010-01-07 2012-10-17 라이온 코폴리머, 엘엘씨 양립화된 실리카, 니트릴 고무, 스티렌 부타디엔 고무, 탄성체 화합물, 및/또는 재활용 물질을 포함한 조성물
US20110166262A1 (en) * 2010-01-07 2011-07-07 Lion Copolymer, Llc Process for making compatibilized silica and nitrile polymer compositions
US9993793B2 (en) 2010-04-28 2018-06-12 The Procter & Gamble Company Delivery particles
US9079990B2 (en) 2010-06-01 2015-07-14 Exxonmobil Chemical Patents Inc. Methods of production of alkylstyrene/isoolefin polymers
EP2471594A1 (de) 2010-12-29 2012-07-04 LANXESS International SA Reaktor und Verfahren zur kontinuierlichen Polymerisation
US9156932B2 (en) 2011-12-21 2015-10-13 The Goodyear Tire & Rubber Company Method of making a graft copolymer
EP2607102B1 (en) * 2011-12-21 2016-09-14 The Goodyear Tire & Rubber Company Method of making a graft polymer, copolymer and tire
CN106232709B (zh) 2013-12-23 2020-10-13 阿朗新科新加坡私人有限公司 具有可调水平的含金属防聚剂的橡胶
WO2015095957A1 (en) * 2013-12-23 2015-07-02 Lanxess Inc. Ultra pure rubber
EP3161069B1 (en) 2014-06-30 2020-12-02 BASF South East Asia Pte. Ltd. Novel anti-agglomerants for polyisobutylene production

Also Published As

Publication number Publication date
EP3087138B1 (en) 2021-06-09
RU2016129296A (ru) 2018-01-29
KR102351737B1 (ko) 2022-01-14
US10000632B2 (en) 2018-06-19
US20160319119A1 (en) 2016-11-03
EP3087138A1 (en) 2016-11-02
EP3087138A4 (en) 2019-04-17
SG10201810330XA (en) 2018-12-28
SG11201605111YA (en) 2016-07-28
RU2016129296A3 (https=) 2018-05-23
SA516371387B1 (ar) 2019-09-01
CN106232709B (zh) 2020-10-13
WO2015095958A1 (en) 2015-07-02
CN106232709A (zh) 2016-12-14
CA2934807C (en) 2022-12-06
CA2934807A1 (en) 2015-07-02
RU2706122C2 (ru) 2019-11-14
JP2017502152A (ja) 2017-01-19
KR20160115921A (ko) 2016-10-06

Similar Documents

Publication Publication Date Title
JP7073288B2 (ja) ゴム工業のための新規な抗凝集剤
JP6523297B2 (ja) 調節可能なレベルの金属含有抗凝集剤を含むゴム
US11584815B2 (en) Sealant comprising a polymeric composition including a lower critical solution temperature compound
JP6592081B2 (ja) ゴム工業のための新規な抗凝集剤

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20160818

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20170814

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20171006

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20171206

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20180406

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20180702

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20180926

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20190104

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20190401

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20190425

R150 Certificate of patent or registration of utility model

Ref document number: 6523297

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250