JP6462476B2 - Elastic tile base material - Google Patents
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Description
本発明は、変形追従性と施工性に優れたポリマーセメント系弾性タイル下地調整材に関
する。
The present invention relates to a polymer cement-based elastic tile foundation adjusting material excellent in deformation followability and workability.
近年、集合住宅のエントランス部の内壁、床、室内の床等にタイルが施工されることが多く、その場合の張付け材としては施工が容易であり、変形追従性に優れることから弾性接着剤を用いることが増えてきている。セメント系弾性接着材として、セメントにポリマー、軽量細骨材、普通細骨材、短繊維及び保水剤を配合することは知られている(例えば、特許文献1参照)。また、有機弾性接着剤を施工する際のコンクリート躯体への下地調整材として反応性ケイ素基を有するポリエーテル系重合体を含む接着剤が考案されている(例えば、特許文献2参照)。しかし、躯体コンクリートの含水率が高い場合や施工前に降雨の影響で躯体コンクリートが濡れた場合には、このような下地調整材の施工は困難となり、躯体コンクリートの含水率が8%以下になるのを待つ必要がある。そのため、降水量が多い期間は、工期が延びるおそれがある。また、乾湿繰返しによるストレスや温度変化による繰返しの膨張と収縮によるストレスに対し軽量骨材とポリマーでヤング率を小さくし変形追従性を改善したセメント系下地調整材と施工方法が考案されている(例えば、特許文献3参照)。 In recent years, tiles are often constructed on the inner walls, floors, indoor floors, etc. of entrances to apartment buildings, and in that case, the adhesive is easy to construct and has excellent deformation followability. Increasing use. As a cement-based elastic adhesive, it is known that a polymer, a lightweight fine aggregate, a normal fine aggregate, a short fiber, and a water retention agent are blended in cement (for example, see Patent Document 1). In addition, an adhesive containing a polyether polymer having a reactive silicon group has been devised as a base conditioner for a concrete frame when an organic elastic adhesive is applied (see, for example, Patent Document 2). However, if the moisture content of the frame concrete is high or if the frame concrete gets wet due to the influence of rainfall before construction, it will be difficult to construct such a foundation conditioner, and the moisture content of the frame concrete will be 8% or less. I have to wait for it. Therefore, the construction period may be extended during periods when there is a lot of precipitation. In addition, a cement-based foundation conditioning material and a construction method have been devised that reduce the Young's modulus and improve deformation followability with lightweight aggregate and polymer against stress due to repeated drying and drying and stress due to repeated expansion and contraction due to temperature change ( For example, see Patent Document 3).
しかし、この方法では、東日本大震災以降多発する地震による大きな変形には追従できないおそれがある。 However, this method may not be able to follow large deformations caused by earthquakes that have occurred frequently since the Great East Japan Earthquake.
また、昨今の施工対象の多様化から、広範囲な面に効率良く施工できる下地材が求められている。弾性タイル下地調整材に軽量化や変形追従性を得る上で必要な軽量骨材に、パーライトやガラスビーズ等の無機系の中空粒子を使用すると、特に吹付け施工などを行う場合、ポンプ圧送時に圧送ホース内圧によりモルタル中の水分がパーライト、ガラスビーズの空隙に取られ閉塞を起こす。その結果、吹付け施工ができなくなるといった支障をきたすため施工上の制約があった。また、軽量骨材にエチレン酢酸ビニルと炭酸カルシウムの複合発泡体を使用するだけでは使用材料間の比重差から圧送ホース内で材料分離を起こし、閉塞するおそれがあるうえ吹付け時に結合材と骨材が分離する可能性が高く施工に支障をきたすおそれがあった。 In addition, with the recent diversification of construction targets, there is a demand for a base material that can be efficiently constructed over a wide range of surfaces. When inorganic hollow particles such as pearlite and glass beads are used for the lightweight aggregate necessary for weight reduction and deformation followability of the elastic tile base preparation, especially when spraying, etc., when pumping The water pressure in the mortar is taken up by the space between the pearlite and glass beads due to the internal pressure of the pressure hose, causing clogging. As a result, there was a restriction in construction because it hindered spraying construction. In addition, if only a composite foam of ethylene vinyl acetate and calcium carbonate is used for the lightweight aggregate, there is a risk of material separation in the pumping hose due to the difference in specific gravity between the materials used, and there is a risk of clogging. There is a high possibility that the material will be separated, which may hinder construction.
したがって、本発明の課題は、躯体コンクリートの変形に対する優れた追従性、躯体コンクリートおよびタイル張付けモルタルとの長期付着耐久性、およびコテ作業性等の左官施工性に優れるだけに留まらず、吹付け施工にも十分適した弾性タイル下地調整材を提供することにある。 Therefore, the problem of the present invention is not only excellent in the followability to deformation of the frame concrete, long-term adhesion durability with the frame concrete and tiled mortar, and plastering workability such as trowel workability, spraying construction It is another object of the present invention to provide an elastic tile base preparation that is well suited to the above.
そこで本発明者は、前記課題を解決できる弾性タイル下地調整材について種々検討した結果、セメント系の弾性タイル下地調整材を構成する材料に、普通骨材と軽量骨材からなる細骨材中の軽量骨材に特定の発泡率で発泡させた有機系樹脂を使用し、普通細骨材と発泡樹脂細骨材の配合量、ポリマーの配合量、一般に耐アルカリ性を呈する高分子繊維の繊維長と混和量等を調整することにより、地震による大きな変形にも追従し長期間安定的に高い付着強度を発現するとともに良好な施工性も得られることを見出し、本発明を完成させた。 Therefore, as a result of various studies on the elastic tile foundation adjusting material that can solve the above-mentioned problems, the present inventor has made the cement-based elastic tile foundation adjusting material a fine aggregate composed of a normal aggregate and a lightweight aggregate. Uses an organic resin foamed at a specific foaming rate for lightweight aggregates, blending amount of ordinary fine aggregate and foamed resin fine aggregate, blending amount of polymer, fiber length of polymer fiber generally exhibiting alkali resistance and By adjusting the amount of mixing, etc., it was found that high adhesion strength can be expressed stably for a long time following large deformation caused by an earthquake, and good workability can be obtained, and the present invention has been completed.
すなわち、本発明は、次の[1]〜[7]を提供するものである。 That is, the present invention provides the following [1] to [7].
[1](A1)ポルトランドセメント100質量部に対し、(A2)膨張材が4.5〜5.2質量部、(B)発泡率9〜14倍である発泡樹脂細骨材を2.36〜7.23質量部、(C)普通細骨材を68〜92質量部、(D)ポリマーディスパージョン及び/又は再乳化粉末樹脂を固形分換算で6.05〜7.40質量部、(E)繊維長10mm以下の高分子繊維を0.05〜0.25質量部含有する弾性タイル下地調整材。
[2]施工厚さ5mm以上の厚塗りに適した弾性タイル下地調整材であって、(A1)ポルトランドセメント100質量部に対し、(A2)膨張材が4.5〜5.2質量部、(B)発泡率9〜14倍である発泡樹脂細骨材を3.02〜7.23質量部、(C)普通細骨材を68〜91質量部、(D)ポリマーディスパージョン及び/又は再乳化粉末樹脂を固形分換算で6.05〜7.40質量部、(E)繊維長10mm以下の高分子繊維を0.05〜0.25質量部含有する弾性タイル下地調整材。
[3]施工厚さ5mm未満の薄塗りに適した弾性タイル下地調整材であって、(A1)ポルトランドセメント100質量部に対し、(A2)膨張材が4.5〜5.2質量部、(B)発泡率9〜14倍である発泡樹脂細骨材を2.36〜6.33質量部、(C)普通細骨材を71〜92質量部、(D)ポリマーディスパージョン及び/又は再乳化粉末樹脂を固形分換算で6.05〜7.40質量部、(E)繊維長10mm以下の高分子繊維を0.05〜0.25質量部含有する弾性タイル下地調整材。
[4]発泡樹脂細骨材がエチレン−酢酸ビニル共重合体、ポリプロピレン、ポリスチレン、ポリウレタンである前記[1]〜[3]のいずれかの弾性タイル下地調整材。
[5]発泡樹脂細骨材がエチレン−酢酸ビニル共重合体またはポリプロピレンである前記[1]〜[3]のいずれかの弾性タイル下地調整材。
[6]さらに(G)シラン系撥水剤を0.22〜0.36質量部含有する前記[1]〜[5]のいずれかの弾性タイル下地調整材。
[7]消泡剤を含有しないことを特徴とする前記[1]〜[6]のいずれかの弾性タイル下地調整材。
[1] (A1) 2.36 parts by mass of foamed resin fine aggregate having an expansion ratio of 4.5 to 5.2 parts by mass and (B) an expansion ratio of 9 to 14 times with respect to 100 parts by mass of Portland cement. To 7.23 parts by mass, (C) 68 to 92 parts by mass of ordinary fine aggregate, (D) 6.05 to 7.40 parts by mass of polymer dispersion and / or re-emulsified powder resin in terms of solid content, ( E) An elastic tile base material containing 0.05 to 0.25 parts by mass of a polymer fiber having a fiber length of 10 mm or less.
[2] An elastic tile foundation adjusting material suitable for thick coating with a construction thickness of 5 mm or more, (A1) with respect to 100 parts by mass of Portland cement, (A2) 4.5 to 5.2 parts by mass of an expansion material, (B) 3.02 to 7.23 parts by mass of foamed resin fine aggregate having a foaming rate of 9 to 14 times, (C) 68 to 91 parts by mass of ordinary fine aggregate, (D) polymer dispersion and / or An elastic tile base material containing 6.0 to 7.40 parts by mass of the re-emulsified powder resin in terms of solid content and (E) 0.05 to 0.25 parts by mass of a polymer fiber having a fiber length of 10 mm or less.
[3] An elastic tile foundation adjusting material suitable for thin coating with a construction thickness of less than 5 mm, (A1) with respect to 100 parts by mass of Portland cement, (A2) 4.5 to 5.2 parts by mass of an expansion material, (B) 2.36 to 6.33 parts by mass of foamed resin fine aggregate having a foaming ratio of 9 to 14 times, (C) 71 to 92 parts by mass of ordinary fine aggregate, (D) polymer dispersion and / or An elastic tile base material containing 6.0 to 7.40 parts by mass of the re-emulsified powder resin in terms of solid content and (E) 0.05 to 0.25 parts by mass of a polymer fiber having a fiber length of 10 mm or less.
[4] The elastic tile foundation adjusting material according to any one of [1] to [3], wherein the foamed fine resin aggregate is an ethylene-vinyl acetate copolymer, polypropylene, polystyrene, or polyurethane.
[5] The elastic tile base adjusting material according to any one of [1] to [3], wherein the foamed fine resin aggregate is an ethylene-vinyl acetate copolymer or polypropylene.
[6] The elastic tile base preparation according to any one of [1] to [5], further comprising (G) 0.22 to 0.36 parts by mass of a silane-based water repellent.
[7] The elastic tile base material according to any one of [1] to [6], which does not contain an antifoaming agent.
本発明の弾性タイル下地調整材を用いれば、優れた変形追従性が得られ、長期間安定的に躯体コンクリートおよびタイル張付けモルタルと高い付着強さが得られる。さらに、発泡樹脂骨材の発泡率と混和量、普通細骨材量、ポリマー量、高分子繊維の繊維長と混和量を最適に調整することでコテ塗り施工もポンプ圧送による吹付け施工も可能になる。 By using the elastic tile foundation adjusting material of the present invention, excellent deformation followability can be obtained, and high adhesion strength can be obtained stably for a long period of time with concrete and tiled mortar. Furthermore, it is possible to apply troweling or spraying by pumping by optimally adjusting the foaming ratio and blending amount of foamed resin aggregate, ordinary fine aggregate amount, polymer amount, polymer fiber length and blending amount. become.
本発明の弾性タイル下地調整材は、(A1)ポルトランドセメント100質量部に対し、(A2)膨張材が4.5〜5.2質量部、(B)発泡率9〜14倍である発泡樹脂細骨材を2.36〜7.23質量部、(C)普通細骨材を68〜92質量部、(D)ポリマーディスパージョン及び/又は再乳化粉末樹脂を固形分換算で6.05〜7.40質量部、(E)繊維長10mm以下の高分子繊維を0.05〜0.25質量部含有する。 The elastic tile base preparation of the present invention is (A1) a foamed resin having an expansion material of 4.5 to 5.2 parts by mass and (B) an expansion ratio of 9 to 14 times with respect to 100 parts by mass of Portland cement. 2.36 to 7.23 parts by mass of fine aggregate, (C) 68 to 92 parts by mass of ordinary fine aggregate, (D) 6.05 to 5 in terms of solid content in terms of polymer dispersion and / or re-emulsified powder resin. 7.40 parts by mass, (E) 0.05 to 0.25 parts by mass of a polymer fiber having a fiber length of 10 mm or less is contained.
本発明において、弾性タイル下地調整材とは、タイル張りを施す躯体コンクリートを必要に応じて表面処理した後、タイル張りの前に塗布される調整材である。また、厚塗りとは、施工厚さ5mm以上の場合であり、一般に躯体コンクリートに不陸がある場合に施される。薄塗りとは、施工厚さ5mm未満の場合であり、一般に躯体コンクリートに不陸がない場合に施工される。 In the present invention, the elastic tile foundation adjusting material is an adjusting material that is applied before tiling after surface-treating the frame concrete to be tiled as necessary. Moreover, thick coating is a case where the construction thickness is 5 mm or more, and is generally applied when there is unevenness in the frame concrete. Thin coating is a case where the construction thickness is less than 5 mm, and is generally constructed when there is no unevenness in the frame concrete.
本発明の弾性タイル下地調整材には、硬化成分として(A1)ポルトランドセメントを含有する。本発明のポルトランドセメントとしては、市販のポルトランドセメントが使用可能である。例えば、普通ポルトランドセメント、早強ポルトランドセメント、中庸熱ポルトランドセメント、耐硫酸塩ポルトランドセメントなどが使用できる。その他、高炉セメント、シリカセメント等の各種混合セメント、白色セメント、アルミナセメント等の特殊セメントも使用可能である。 The elastic tile base preparation of the present invention contains (A1) Portland cement as a curing component. A commercially available Portland cement can be used as the Portland cement of the present invention. For example, ordinary Portland cement, early-strength Portland cement, moderately hot Portland cement, sulfate-resistant Portland cement and the like can be used. In addition, various cements such as blast furnace cement and silica cement, and special cements such as white cement and alumina cement can be used.
本発明の弾性タイル下地調整材に使用できる(A2)膨張材としては、モルタルやコンクリートに使用可能なものであれば特に限定されず、水和膨張性の膨張材として生石灰を有効成分とするものやカルシウムサルフォアルミネートを有効成分とするものを挙げることができる。膨張材を配合使用することで、主に乾燥収縮が抑制され、施工箇所の形状寸法安定性が図れるとともに収縮亀裂の発生を防ぐことができる。例えば、太平洋マテリアル(株)製の商品名「太平洋エクスパン(構造用)」や商品名「太平洋ジプカル」等が挙げられるが、これに限定されるものではない。 The (A2) expansion material that can be used for the elastic tile base preparation of the present invention is not particularly limited as long as it can be used for mortar and concrete, and quick lime is an active ingredient as a hydrated expansion expansion material. And calcium sulfoaluminate as an active ingredient. By blending and using the expansion material, drying shrinkage is mainly suppressed, and the shape and dimension stability of the construction site can be achieved and the occurrence of shrinkage cracks can be prevented. For example, trade name “Pacific Expan (for structure)” manufactured by Taiheiyo Material Co., Ltd., trade name “Pacific Gypcal” and the like can be mentioned, but the invention is not limited thereto.
(A2)膨張材の使用量は、施工厚さによらず(A1)ポルトランドセメント100質量部に対し4.5〜5.2質量部が必要であり、4.5〜5.1質量部が好ましく、4.5〜5.0質量部がより好ましい。4.5質量部未満では、収縮低減効果が十分に得られず、ひび割れの発生するおそれがある。5.2質量部を超えると過膨張のおそれがあるとともに遅れ膨張の発生するおそれがあり適当ではない。 (A2) The amount of the expansion material used is 4.5 to 5.2 parts by mass with respect to 100 parts by mass of Portland cement (A1) regardless of the construction thickness, and 4.5 to 5.1 parts by mass. Preferably, 4.5-5.0 mass parts is more preferable. If the amount is less than 4.5 parts by mass, the shrinkage reduction effect cannot be sufficiently obtained, and cracks may occur. If the amount exceeds 5.2 parts by mass, overexpansion may occur and delayed expansion may occur, which is not appropriate.
本発明に用いる細骨材は、(B)発泡率9〜14倍である発泡樹脂細骨材、および(C)普通細骨材の2種を含む。本発明では、普通細骨材に加えて、(B)9〜14倍という特定の範囲の発泡率を有する発泡樹脂細骨材を使用する点に特徴がある。 The fine aggregate used in the present invention includes (B) a foamed resin fine aggregate having a foaming ratio of 9 to 14 times, and (C) a normal fine aggregate. The present invention is characterized in that, in addition to the ordinary fine aggregate, (B) a foamed resin fine aggregate having a foaming ratio in a specific range of 9 to 14 times is used.
本発明に用いられる(B)発泡率9〜14倍である発泡樹脂細骨材としては、発泡率を9〜14倍にせしめて発泡させた有機系樹脂からなる中空状の粒であれば特に限定されないが、発泡によって閉口気孔率40〜90%の有機材質の軽量細骨材が特に断熱性及び防変性を付与するうえで好ましい。尚、本発明において、発泡率とは、発泡前の粒とそれが発泡した後の粒との嵩体積の増加倍率を表す。発泡率9倍未満のものでは曲げ強さ、圧縮強さ、引張強さ、ヤング率が低下するため、タイル張り材との付着力が低下する。その結果、長期付着耐久性も低下するため好ましくない。また、発泡率14倍を超えるものでは厚付け性が低下するため、発泡樹脂細骨材を使用した意味を失うため好ましくない。発泡樹脂細骨材の樹脂としては、所望の変形追従性が得やすいことから、例えば、エチレン酢酸ビニル共重合体、ポリプロピレン、ポリスチレン、ポリウレタン等を挙げることができるが、広範囲の用途に適することからエチレン酢酸ビニル共重合体、ポリプロピレンがより好ましい。 (B) The foamed resin fine aggregate having a foaming rate of 9 to 14 times used in the present invention is particularly a hollow particle made of an organic resin foamed with a foaming rate of 9 to 14 times. Although it is not limited, a lightweight fine aggregate made of an organic material having a closed porosity of 40 to 90% by foaming is particularly preferable for imparting heat insulating properties and degeneration. In the present invention, the foaming rate represents the increase ratio of the bulk volume between the grain before foaming and the grain after foaming. When the foaming rate is less than 9 times, the bending strength, compressive strength, tensile strength, and Young's modulus are lowered, and thus the adhesive force with the tiled material is lowered. As a result, the long-term adhesion durability is also unfavorable. In addition, when the foaming ratio exceeds 14 times, the thickness is reduced, so that the meaning of using the foamed resin fine aggregate is lost. As the resin for the foamed resin fine aggregate, desired deformation followability can be easily obtained. For example, ethylene vinyl acetate copolymer, polypropylene, polystyrene, polyurethane, and the like can be mentioned, but they are suitable for a wide range of applications. More preferred are ethylene vinyl acetate copolymer and polypropylene.
また、(B)発泡樹脂細骨材の粒径は、細骨材として使用したモルタルの施工性及び強度の点から0.09〜3.0mmが好ましい。したがって、施工厚さは、20mmを超えない方が良い。さらに、本発明に用いられる(B)発泡率9〜14倍である発泡樹脂細骨材は、粒径が0.09〜3.0mmの範囲で、嵩比重は0.07〜0.12がより好ましい。嵩比重が小さすぎると単位容積質量が低下し、良好なフレッシュ性状と良好な硬化性状が得られず、施工性も低下する。嵩比重が大きすぎると単位容積質量が大きくなり過ぎ、強度発現性も大きくなる。そのため、変形追従性が低下する。また、施工性は低下してダレやすくなる。 Moreover, the particle diameter of the (B) foamed resin fine aggregate is preferably 0.09 to 3.0 mm from the viewpoint of workability and strength of the mortar used as the fine aggregate. Therefore, the construction thickness should not exceed 20 mm. Further, (B) the foamed resin fine aggregate having a foaming rate of 9 to 14 times used in the present invention has a particle size in the range of 0.09 to 3.0 mm and a bulk specific gravity of 0.07 to 0.12. More preferred. If the bulk specific gravity is too small, the unit volume mass is lowered, a good fresh property and a good curability cannot be obtained, and workability is also lowered. If the bulk specific gravity is too large, the unit volume mass becomes too large, and the strength development is also increased. For this reason, the deformation followability is lowered. Moreover, workability will fall and it will become easy to sag.
(B)発泡樹脂細骨材の使用量は、(A1)ポルトランドセメント100質量部に対し2.36〜7.23質量部必要である。2.36質量部未満では、静弾性係数が大きくなり変形追従性が低下する。7.23質量部を超えると曲げ強さと躯体コンクリートおよびタイル張り材等との付着強さが低下する。 (B) The amount of the foamed resin fine aggregate used is 2.36 to 7.23 parts by mass with respect to 100 parts by mass of (A1) Portland cement. If it is less than 2.36 parts by mass, the static elastic modulus is increased and the deformation followability is lowered. When it exceeds 7.23 parts by mass, the bending strength and the adhesion strength between the concrete and the tiled material are lowered.
(B)発泡樹脂細骨材の配合量は施工厚さ5mm以上厚塗りする場合、(A1)ポルトランドセメントに対し3.02〜7.23質量部が好ましく、より好ましくは4.00〜7.14質量部であり、さらに好ましくは、4.34〜6.00質量部である。
(B)発泡樹脂細骨材の配合量は施工厚さ5mm未満の薄塗りをする場合、(A1)ポルトランドセメントに対し2.36〜6.33質量部が好ましく、より好ましくは2.36〜5.78質量部であり、さらに好ましくは、3.28〜5.50質量部である。
(B) When the coating amount of the foamed resin fine aggregate is 5 mm or more thick, (A1) 3.02 to 7.23 parts by mass is preferable with respect to Portland cement, more preferably 4.00 to 7.7. 14 parts by mass, and more preferably 4.34 to 6.00 parts by mass.
(B) The amount of the foamed resin fine aggregate is preferably 2.36 to 6.33 parts by mass, more preferably 2.36 to the (A1) Portland cement when thinly applied with a construction thickness of less than 5 mm. 5.78 parts by mass, and more preferably 3.28-5.50 parts by mass.
軽量骨材としては、発泡質無機系粒のパーライト、ガラスビーズ等の使用は、タイル下地調整材用としてポンプ圧送し、吹付け施工することは施工的に適さない。特に、ポンプ圧送管や吹付装置の吹出口が閉塞するおそれがある。 For lightweight aggregates, the use of foamed inorganic particles such as pearlite, glass beads, etc. is not suitable in terms of construction by pumping and spraying for use as a tile base material. In particular, there is a possibility that the pumping pipe and the outlet of the spraying device are blocked.
(C)普通細骨材としては、石灰砂、珪砂、寒水石、川砂、陸砂、砕砂等が挙げられる。(C)普通細骨材の粒径は1.2〜0.045mmが好ましい。粗粒率は、1.4〜1.9が好ましい。(C)普通細骨材の配合量は、施工厚さによらず、(A1)ポルトランドセメント100質量部に対し68〜92質量部必要である。68質量部未満では、強度が低下し混和した効果がない。92質量部を超えると本発明の弾性タイル下地調整材の静弾性係数が大きくなり、変形追従性が低下する。
施工厚さ5mm以上厚塗りする場合は、(A1)セメント100質量部に対し68〜91質量部が好ましく、75〜86質量部がより好ましく、75〜83質量部がさらに好ましい。
施工厚さ5mm未満の薄塗りをする場合、(C)普通細骨材は、(A1)セメント100質量部に対し71〜92質量部が好ましく、75〜86質量部がより好ましく、75〜83質量部がさらに好ましい。
(C) Examples of ordinary fine aggregates include lime sand, quartz sand, cold water stone, river sand, land sand, and crushed sand. (C) The particle size of the ordinary fine aggregate is preferably 1.2 to 0.045 mm. The coarse particle ratio is preferably 1.4 to 1.9. (C) The amount of ordinary fine aggregate is 68 to 92 parts by mass with respect to 100 parts by mass of (A1) Portland cement, regardless of the construction thickness. If it is less than 68 mass parts, the intensity | strength falls and there is no mixed effect. When it exceeds 92 parts by mass, the static elastic modulus of the elastic tile base preparation of the present invention is increased, and the deformation followability is lowered.
In the case of thickening the construction thickness of 5 mm or more, 68 to 91 parts by mass is preferable with respect to 100 parts by mass of (A1) cement, 75 to 86 parts by mass is more preferable, and 75 to 83 parts by mass is more preferable.
When thinly applying less than 5 mm, the (C) ordinary fine aggregate is preferably 71 to 92 parts by mass, more preferably 75 to 86 parts by mass, and 75 to 83 parts per 100 parts by mass of (A1) cement. Part by mass is more preferable.
本発明に用いられる(D)ポリマーとしては、再乳化形粉末樹脂及び/又はポリマーディスパージョンが使用可能である。再乳化形粉末樹脂としては、JIS A 6203に規定されたものを使用でき、ポリマーディスパージョンとしては、同じくJIS A 6203に規定されたものを使用することができる。すなわち、前記再乳化形粉末樹脂としては、エチレン酢酸ビニル、酢酸ビニル/バーサチック酸ビニルエステル、酢酸ビニル/バーサチック酸ビニル/アクリル酸エステル、ポリアクリル酸エステルなどを主成分とする粉末状の樹脂を使用することができる。また、再乳化形粉末樹脂の製造方法は限定されることなく、粉末化方法やブロッキング防止法などのいずれの製法によって製造してもよい。また、前記ポリマーディスパージョンとしては、エチレン酢酸ビニル、ポリアクリル酸エステル、又はスチレンブタジエンなどを主成分とする樹脂を使用することができる。また、これらのポリマーを2種以上併用することも可能である。 As the polymer (D) used in the present invention, a re-emulsifying powder resin and / or a polymer dispersion can be used. As the re-emulsifying powder resin, those defined in JIS A 6203 can be used, and as the polymer dispersion, those similarly defined in JIS A 6203 can be used. That is, as the re-emulsifying powder resin, a powdery resin mainly composed of ethylene vinyl acetate, vinyl acetate / vinyl versatate, vinyl acetate / vinyl versatate / acrylic acid ester, polyacrylic acid ester, etc. is used. can do. Moreover, the manufacturing method of re-emulsification type powder resin is not limited, You may manufacture by any manufacturing methods, such as a pulverization method and a blocking prevention method. Further, as the polymer dispersion, a resin mainly composed of ethylene vinyl acetate, polyacrylic acid ester, styrene butadiene, or the like can be used. Two or more of these polymers can be used in combination.
(D)ポリマーディスパージョンおよび再乳化粉末樹脂の配合量は、施工厚さによらず(A1)ポルトランドセメント100質量部に対し固形分換算で6.05〜7.40質量部が必要であり、好ましくは6.10〜7.20質量部であり、より好ましくは、6.20〜6.67質量部である。6.05質量部未満では、破断時の変位量が低下するため良好な変形追従性が得られない。7.40質量部を超えると粘性が高くなり施工性が低下する。 (D) The amount of the polymer dispersion and the re-emulsified powder resin is 6.05 to 7.40 parts by mass in terms of solid content with respect to 100 parts by mass of (A1) Portland cement, regardless of the construction thickness. Preferably it is 6.10-7.20 mass parts, More preferably, it is 6.20-6.67 mass parts. If the amount is less than 6.05 parts by mass, the amount of displacement at the time of breakage is reduced, so that good deformation followability cannot be obtained. If the amount exceeds 7.40 parts by mass, the viscosity increases and the workability decreases.
本発明に使用できる(E)高分子繊維としては短繊維と収束型があるがどちらも使用可能である。有機繊維としては、ナイロン、ビニロン、ポリプロピレン、ポリエステル、アクリル等が使用可能であり、2種類以上併用することも可能である。 The (E) polymer fiber that can be used in the present invention includes a short fiber and a convergent type, but both can be used. As the organic fiber, nylon, vinylon, polypropylene, polyester, acrylic and the like can be used, and two or more kinds can be used in combination.
変形追従性に加え、ダレ防止等のコテ作業性を同時に向上させるためには、繊維長が10mm以下の高分子繊維の使用が有効である。繊維長が10mmを超えると曲げ強さの向上はできるが、モルタルとの付着性が大きくなり破断時の変形量が小さくなるとともに破断時のひずみが小さくなって変形追従性の向上には寄与しないので好ましくない。 Use of polymer fibers having a fiber length of 10 mm or less is effective in order to simultaneously improve the workability such as prevention of sagging in addition to deformation followability. When the fiber length exceeds 10 mm, the bending strength can be improved, but the adhesion to the mortar is increased, the amount of deformation at breakage is reduced, and the strain at breakage is reduced, which does not contribute to improvement in deformation followability. Therefore, it is not preferable.
本発明に使用できる(E)高分子繊維の配合量は、(A)セメント100質量部に対し0.05〜0.25質量部が必要であり、0.10〜0.17質量部がより好ましい。0.05質量部未満では混和した効果がなく、0.25質量部を超えるとコテ作業性が低下するとともに、単位体積当たりの繊維量が過剰なため付着強さが低下する。 The blending amount of the (E) polymer fiber that can be used in the present invention is required to be 0.05 to 0.25 parts by mass with respect to 100 parts by mass of (A) cement, and more preferably 0.10 to 0.17 parts by mass. preferable. If the amount is less than 0.05 parts by mass, the mixing effect is not obtained. If the amount exceeds 0.25 parts by mass, the workability of the iron is lowered, and the amount of fibers per unit volume is excessive, so that the adhesion strength is lowered.
本発明の弾性タイル下地調整材には、施工後の弾性タイル下地調整材の乾燥を防止し、良好な施工性を得るため、(F)保水剤を配合することができる。(F)保水剤としてはセルロース誘導体が好ましい。セルロース誘導体としては、水に溶解するものであればいずれのものでも良く、例えばメチルセルロース、カルボキシメチルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシエチルメチルセルロース、ヒドロキシプロピルセルロース、セルロース硫酸エステル等の水溶性セルロース誘導体が挙げられる。これらの中でもメチルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルメチルセルロースが好ましい。 In the elastic tile base preparation of the present invention, (F) a water retention agent can be blended in order to prevent drying of the elastic tile base preparation after construction and obtain good workability. (F) As a water retention agent, a cellulose derivative is preferable. Any cellulose derivative may be used as long as it is soluble in water, for example, water-soluble cellulose derivatives such as methylcellulose, carboxymethylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, hydroxyethylmethylcellulose, hydroxypropylcellulose, and cellulose sulfate. Can be mentioned. Among these, methyl cellulose, hydroxypropyl methyl cellulose, and hydroxyethyl methyl cellulose are preferable.
(F)保水剤の配合量は、(A1)ポルトランドセメント100質量部に対し0.11〜0.27質量部が好ましい。保水剤をこの範囲で配合することにより、施工後の弾性タイル下地調整材の乾燥が防止でき、また、適正な施工性が得られる。 (F) As for the compounding quantity of a water retention agent, 0.11-0.27 mass part is preferable with respect to 100 mass parts of (A1) Portland cement. By mix | blending a water retention agent in this range, drying of the elastic tile base | substrate adjustment material after construction can be prevented, and appropriate workability is obtained.
施工厚さ5mm以上の厚塗りをする場合、(F)保水剤の配合量は、(A1)セメント100質量部に対し0.11〜0.21質量部が好ましく、0.11〜0.20質量部がより好ましく、0.15〜0.20質量部がさらに好ましい。
施工厚さ5mm未満の薄塗りをする場合、(F)保水剤の配合量は、(A1)セメント100質量部に対し0.23〜0.27質量部が好ましく、0.24〜0.27質量部がより好ましい。
In the case of thick coating with a construction thickness of 5 mm or more, the blending amount of (F) water retention agent is preferably 0.11 to 0.21 parts by mass, and 0.11 to 0.20 with respect to 100 parts by mass of (A1) cement. A mass part is more preferable and 0.15-0.20 mass part is further more preferable.
In the case of thin coating with a construction thickness of less than 5 mm, the blending amount of the water retention agent (F) is preferably 0.23 to 0.27 parts by mass, and 0.24 to 0.27 with respect to 100 parts by mass of the cement (A1). Part by mass is more preferable.
本発明の弾性タイル下地調整材には、施工面に撥水性を付与する目的で(G)撥水剤を使用してもよい。本発明に使用できる(G)撥水剤は、セメントモルタルに混和し高アルカリ条件下で反応性のシラノールとなるシラン化合物が好ましい。例えば、有機シラン、ポリシラン等である。具体例としては、アクゾノーベル(株)製の商品名「シール80」等であるが、記載例に限定されるものではない。反応性シラノールは、シラノール基間の架橋や無機化合物との反応により表面が疎水性に変性される。そのため、シラン系撥水剤は練混ぜ性状が良く、本発明の弾性タイル下地調整材は硬化後適切な撥水性を発揮する。 In the elastic tile base preparation of the present invention, (G) a water repellent may be used for the purpose of imparting water repellency to the construction surface. The (G) water repellent that can be used in the present invention is preferably a silane compound that is mixed with cement mortar and becomes reactive silanol under high alkaline conditions. For example, organic silane, polysilane and the like. Specific examples include trade name “Seal 80” manufactured by Akzo Nobel Co., Ltd., but are not limited to the description examples. The surface of reactive silanol is modified to be hydrophobic by crosslinking between silanol groups or reaction with an inorganic compound. Therefore, the silane water repellent has good kneading properties, and the elastic tile base preparation of the present invention exhibits appropriate water repellency after curing.
(G)撥水剤の配合量は、撥水性の付与及び経済性の点から、(A1)ポルトランドセメント100質量部に対し、0.22〜0.36質量部が好ましい。 (G) The blending amount of the water repellent is preferably 0.22 to 0.36 parts by mass with respect to 100 parts by mass of (A1) Portland cement from the viewpoint of imparting water repellency and economy.
本発明の弾性タイル下地調整材に消泡剤を混和することは好ましくない。消泡剤は、シリコーン系と脂肪酸系があり、消泡効果と付随して得られる撥水効果がある。消泡剤を混和すると硬化後表層部が必要以上な撥水性を呈するため、塗り重ねた場合1層目と2層目の付着力が低下する。したがって、消泡剤を混和することは好ましくないが、撥水剤と併用するとさらに塗り重ね界面及び表層部の撥水性が高まるため付着力が低下するので好ましくない。 It is not preferable to add an antifoaming agent to the elastic tile base preparation of the present invention. Antifoaming agents are classified into a silicone type and a fatty acid type, and have an antifoaming effect and a water repellent effect obtained in association therewith. When an antifoaming agent is mixed, the surface layer portion after curing exhibits more water repellency than necessary, and thus the adhesion of the first layer and the second layer decreases when it is repeatedly applied. Therefore, it is not preferable to mix an antifoaming agent, but if it is used in combination with a water repellent, the water repellent property at the coating interface and the surface layer portion is further increased, and thus the adhesive force is reduced.
本発明の弾性タイル下地調整材の練混ぜ水量は、水セメント比で51〜63%が好ましく、施工厚さ5mm以上厚塗りする場合、水セメント比で52〜63%が好ましく、施工厚さ5mm未満の薄塗りを行う場合には、水セメント比で51〜63%が好ましい。より詳細には、本発明の弾性タイル下地調整材を施工厚さ5mm以上金ゴテで塗り付ける場合、水セメント比は、練り混ぜ性、施工性等の点で51〜63%が好ましい。本発明の弾性タイル下地調整材を吹付け施工で厚さ5mm以上塗り付ける場合、水セメント比は、練り混ぜ性、ポンプ圧送性の点から、52〜63%が好ましい。本発明の弾性タイル下地調整材を施工厚さ5mm未満に金ゴテで塗り付ける場合、水セメント比は、練り混ぜ性、施工性の点から51〜63%が好ましい。本発明の弾性タイル下地調整材を吹付け施工で厚さ5mm未満に塗り付ける場合、水セメント比は、練り混ぜ性、圧送性の点から51〜63%が好ましい。 The amount of kneading water of the elastic tile base preparation of the present invention is preferably 51 to 63% in terms of water cement, and when thicker than 5 mm in construction thickness, it is preferably 52 to 63% in terms of water cement and construction thickness of 5 mm. In the case of performing thin coating less than 51%, the water cement ratio is preferably 51 to 63%. More specifically, when applying the elastic tile foundation adjusting material of the present invention with a gold trowel having a thickness of 5 mm or more, the water-cement ratio is preferably 51 to 63% in terms of kneading property, workability and the like. When applying the elastic tile base preparation of the present invention to a thickness of 5 mm or more by spraying, the water-cement ratio is preferably 52 to 63% from the viewpoint of kneading and pumpability. When applying the elastic tile base preparation of the present invention to a construction thickness of less than 5 mm with a gold trowel, the water-cement ratio is preferably 51 to 63% in terms of kneading and construction properties. When the elastic tile base preparation of the present invention is applied to a thickness of less than 5 mm by spraying, the water-cement ratio is preferably 51 to 63% from the viewpoint of kneading and pumping properties.
本発明の弾性タイル下地調整材の性能を効率良く発揮させるコンシステンシーは、フロー値170〜190mmであることが好ましい。フロー値がこの範囲であると、コテ作業性及び吹付け性状が良好であり、躯体コンクリートとの付着性が良好であり、ダレが生じず、厚付けも薄付けも可能であり、施工効率が良好である。また、良好な施工作業性を確保する上で、セメント系下地調整剤のフレッシュ状態での単位容積質量を1.3〜1.65に調整するのが好ましい。単位容積質量が小さすぎる下地調整材は、タイル下地の調整に使用した場合、付着強さが十分に得られない可能性があり、塗料下地の調整に使用した場合には軽量骨材量が多く平滑な仕上がり面が得られず、ピンホールが発生する可能性がある。したがって、塗装下地の調整に使用するためには、表面を平滑にするしごき材が必要になり施工効率の低下と製造コストの増加を引き起こす。また、単位容積質量が大きすぎる下地調整材は、厚塗りが難しくヤング率が高くなる。そのため、高い変形追従性が得られないおそれがある。 The consistency for efficiently exhibiting the performance of the elastic tile foundation adjusting material of the present invention is preferably a flow value of 170 to 190 mm. If the flow value is within this range, the ironing workability and spraying properties are good, the adhesion to the concrete is good, there is no sag, thickening and thinning are possible, and the construction efficiency is high. It is good. Moreover, when ensuring favorable construction workability | operativity, it is preferable to adjust the unit volume mass in the fresh state of a cement-type foundation | substrate regulator to 1.3-1.65. If the base material whose unit volume mass is too small is used to adjust the tile base, there is a possibility that sufficient adhesion strength may not be obtained, and if used for the paint base, the amount of lightweight aggregate is large. A smooth finished surface cannot be obtained, and pinholes may occur. Therefore, in order to use it for the adjustment of the coating base, a ironing material for smoothing the surface is required, which causes a decrease in construction efficiency and an increase in manufacturing cost. In addition, the base material having an excessively large unit volume mass is difficult to be thickly coated and has a high Young's modulus. Therefore, there is a possibility that high deformation followability cannot be obtained.
本発明の弾性タイル下地調整材の製造方法は、特に限定されるものではなく、一般的にセメントモルタルやセメントペーストと概ね同様な方法で製造することができる。例えば、市販のモルタルミキサーに配合材料を投入し、適宜練り混ぜるだけで容易に得ることができる。 The manufacturing method of the elastic tile base preparation of the present invention is not particularly limited, and can be generally manufactured by a method substantially similar to cement mortar and cement paste. For example, it can be easily obtained simply by putting the compounding material into a commercially available mortar mixer and kneading as appropriate.
次に実施例を挙げて本発明を詳細に説明する。 EXAMPLES Next, an Example is given and this invention is demonstrated in detail.
実施例1〜24及び比較例31〜52
表1記載の材料で表11、表13、表15、表17記載の処方で弾性タイル下地調整材を製造した。
Examples 1-24 and Comparative Examples 31-52
The elastic tile base material was manufactured using the materials shown in Table 1 and the formulations shown in Table 11, Table 13, Table 15, and Table 17.
得られた弾性タイル下地調整材を用いて、フレッシュ性状、硬化性状、コテ作業性、吹付け性状を評価した。これらの評価方法を次に示し、評価結果を表12、表14、表16、表18に示した。 Using the obtained elastic tile base material, fresh properties, curable properties, iron workability, and spray properties were evaluated. These evaluation methods are shown below, and the evaluation results are shown in Table 12, Table 14, Table 16, and Table 18.
<フレッシュ性状の確認>
各試験は20℃の試験室で実施した。
1−1.フロー試験
JISR5201により測定した。
1−2.単位容積質量の測定
500mLステンレス製容器を用い、JISA1171により測定した。
<Confirmation of fresh properties>
Each test was conducted in a 20 ° C. test room.
1-1. Flow test Measured according to JIS R5201.
1-2. Measurement of unit volume mass It measured by JISA1171 using a 500 mL stainless steel container.
<フレッシュ性状の評価基準>
フレッシュ性状は、タイル下地調整材として実現場で施工した際、コテ作業性と吹付け性状が優れている必要がある。各試験項目の評価基準は次の通りとなる。表2に評価基準を示し、総合評価基準を表3に示す。
<Fresh properties evaluation criteria>
The fresh properties need to have excellent iron workability and spraying properties when constructed at the realization site as a tile base material. The evaluation criteria for each test item are as follows. Table 2 shows the evaluation criteria, and Table 3 shows the overall evaluation criteria.
<硬化性状の確認>
各試験は20℃の試験室で実施した。
2−1.曲げ強さ試験
JISA1171に従って作製した4×4×16cmの試験体を用い、材齢28日でたわみ量0.5mm/min一定で曲げ強さ試験を実施した。試験はn=3とし、平均値を試験値とした。
<Confirmation of curing properties>
Each test was conducted in a 20 ° C. test room.
2-1. Bending Strength Test Using a 4 × 4 × 16 cm specimen prepared according to JIS A1171, a bending strength test was carried out at a constant deflection of 0.5 mm / min at a material age of 28 days. In the test, n = 3, and the average value was the test value.
載荷は図1に示すように中央集中載荷とした。 The loading was a centralized loading as shown in FIG.
2−2.圧縮強さ試験
材齢28日で曲げ強さ試験終了後の試験体を用い、たわみ量0.5mm/min一定で圧縮強さ試験を実施した。試験はn=6とし、平均値を試験値とした。
2-2. Compressive strength test A compressive strength test was carried out at a constant deflection of 0.5 mm / min using a specimen after the bending strength test was completed at 28 days of age. In the test, n = 6, and the average value was the test value.
2−3.割裂引張強さ試験
JISA1171に従って作製したφ5×10cmの試験体を用い、材齢28日でたわみ量0.5mm/min一定で割裂引張強さ試験を実施した。また、図2に示す位置にひずみゲージを張り、破断時のひずみを測定した。割裂引張強さ及び破断時の評価基準を表8に示す。
2-3. Split Tensile Strength Test Using a φ5 × 10 cm specimen prepared according to JIS A1171, a split tensile strength test was carried out at a constant deflection of 0.5 mm / min at a material age of 28 days. Further, a strain gauge was stretched at the position shown in FIG. 2, and the strain at break was measured. Table 8 shows the split tensile strength and the evaluation criteria at break.
2−4.静弾性係数の測定
JISA1171に従って作製した各試料のφ5×10cm試験体を材齢28日でJIS
1149により静弾性係数を測定した。試験はn=3で実施し、平均値を試験値とした。
2-4. Measurement of static elastic modulus Φ5 × 10cm specimens of each sample prepared according to JISA 1171 were JIS 28 days old.
The static elastic modulus was measured by 1149. The test was conducted with n = 3, and the average value was taken as the test value.
2−5.付着試験
JISA6916CM-2により太平洋マテリアル(株)製商品名太平洋トフコンEの5倍液を150g/m2塗布した70×70×20mmのモルタル板を用いて各試料を5mm厚さで塗り付けた。標準養生で材齢28日まで養生し、付着強さを測定した。試験はn=3で実施し、平均値を試験値とした。図3に試験体の縦断面図を示す。
2-5. Adhesion test Each sample was applied in a thickness of 5 mm using a 70 × 70 × 20 mm mortar plate coated with 150 g / m 2 of a 5 times solution of Taiheiyo Material Co., Ltd. trade name Taiheiyo Tofucon E manufactured by Taiheiyo Material Co., Ltd. according to JIS A6916CM-2. Curing was performed up to the age of 28 days with standard curing, and the adhesion strength was measured. The test was conducted with n = 3, and the average value was taken as the test value. FIG. 3 shows a longitudinal sectional view of the test body.
<硬化性状の評価基準>
硬化性状の評価基準を表4に示す。
<Evaluation criteria for curing properties>
Table 4 shows the evaluation criteria of the curing properties.
<硬化性状の総合評価基準>
硬化性状の総合評価基準を表5に示す。
<Comprehensive evaluation criteria for curing properties>
Table 5 shows the overall evaluation criteria for the curing properties.
<コテ作業性の確認>
コテ作業性の評価試験
20℃の試験室で450×900×60mmコンクリート版に4mmおよび8mm厚さで400×450mmの範囲に金ゴテで各試料を塗り付け、コテ作業性の評価を行った。評価基準を表6に示す。
<Confirmation of iron workability>
Evaluation test of trowel workability Each sample was applied to a 450 × 900 × 60 mm concrete plate in a range of 4 mm and 8 mm thickness in a range of 400 × 450 mm with a gold trowel in a 20 ° C. test room, and the trowel workability was evaluated. Table 6 shows the evaluation criteria.
総合評価
コテ作業性の総合評価基準を表7に示す。
Comprehensive evaluation Table 7 shows the comprehensive evaluation criteria for iron workability.
<吹付け性状の確認>
100Lモルタルミキサーで練り上げた試料を吐出量8〜12L/分のモルタルポンプを用いて20m圧送した。圧送された試料は、コンプレッサーを繋げた吹付けノズルで900×1800×12mmの構造用合板を2枚連結し、1800×1800×12mmの壁体とした。ポンプ圧送性,吹付け性状を確認した。連続吹付けが可能であった時間と吹付け厚さ、ダレの有無を確認した。吹付け厚さは4mmおよび8mmとし、評価基準を表8に示す。
<Confirmation of spray properties>
The sample kneaded with a 100 L mortar mixer was pumped by 20 m using a mortar pump with a discharge rate of 8 to 12 L / min. Two samples of structural plywood of 900 × 1800 × 12 mm were connected to the pressure-fed sample with a spray nozzle connected with a compressor to form a wall of 1800 × 1800 × 12 mm. The pumping performance and spraying properties were confirmed. The time when continuous spraying was possible, the spraying thickness, and the presence or absence of sagging were confirmed. The spraying thickness was 4 mm and 8 mm, and the evaluation criteria are shown in Table 8.
総合評価
吹付け性状の総合評価基準を表9に示す。
Comprehensive evaluation Table 9 shows the comprehensive evaluation criteria for spray properties.
<全総合評価>
物性試験結果、コテ作業性の総合評価結果、吹付け性状の総合評価結果を考慮した全総合評価基準を表10に示す。
<Overall evaluation>
Table 10 shows all the comprehensive evaluation criteria in consideration of the physical property test result, the overall evaluation result of the iron workability, and the comprehensive evaluation result of the spray property.
Claims (7)
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