JP6459210B2 - Water-in-oil emulsion composition for roll-in - Google Patents

Water-in-oil emulsion composition for roll-in Download PDF

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JP6459210B2
JP6459210B2 JP2014097253A JP2014097253A JP6459210B2 JP 6459210 B2 JP6459210 B2 JP 6459210B2 JP 2014097253 A JP2014097253 A JP 2014097253A JP 2014097253 A JP2014097253 A JP 2014097253A JP 6459210 B2 JP6459210 B2 JP 6459210B2
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智明 熊谷
智明 熊谷
勉 吉岡
勉 吉岡
幹生 中野
幹生 中野
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本発明は、ロールイン用油中水型乳化組成物に関し、更に詳しくは、パイ、デニッシュペストリーなどの層状膨化小麦粉食品を製造するに適したロールイン用油中水型乳化組成物及びそれを使用してなる層状膨化小麦粉食品に関する。   The present invention relates to a water-in-oil emulsion composition for roll-in, and more particularly, to a roll-in water-in-oil emulsion composition suitable for producing layered puffed flour foods such as pies and Danish pastries, and the use thereof The present invention relates to a layered puffed flour food.

コンビニエンスストア、量販店などで販売されるクロワッサン、パイ、デニッシュペストリーなどの層状膨化小麦粉食品はそのボリューム感、歯切れの良さ、口どけの良さからさまざまな種類が店頭に並んでいる。これらの層状膨化小麦粉食品は一般的に連続生産ラインで製造され、その工程は小麦粉生地を捏ね上げ、ロールイン用油中水型乳化組成物を小麦粉生地で包み展延、折りたたみを繰り返すことで油中水型乳化組成物と小麦粉生地の積層構造を形成させ、様々な形に成形し、ホイロで発酵させ、オーブンで焼き上げるというものである。   Various types of layered puffed flour foods such as croissants, pies, and Danish pastries sold at convenience stores and mass retailers are lined up in stores due to their volume, crispness, and crispness. These layered puffed flour foods are generally produced on a continuous production line, and the process is to pulverize the flour dough, wrap the roll-in water-in-oil emulsified composition with the flour dough, spread and fold the oil repeatedly A laminated structure of a water-in-water emulsified composition and flour dough is formed, formed into various shapes, fermented with a proofer, and baked in an oven.

上記層状膨化小麦粉食品は製造からおよそ2日から5日程度の期間販売されるのが一般的であるが、経時的に品質が劣化していく課題がある。具体的にはパサつきが感じられ、口どけが悪く感じられるようになったり、食感が硬くなり、ヒキが出て歯切れが悪くなったりするなどである。   The layered puffed flour food is generally sold for a period of about 2 to 5 days from manufacture, but there is a problem that the quality deteriorates with time. Specifically, they may feel dry and feel uncomfortable, or the texture becomes stiff, and the cracks appear and the crispness becomes worse.

一般的に層状小麦粉膨化食品の経時的な食感の悪化の主要因は小麦粉の主成分である澱粉の再結晶化と理解されており、改善方法は乳化剤等を主成分とする生地改良剤等を添加することである。上記の通り、捏ね上げられた小麦粉生地はロールイン用油中水型組成物を包み展延、折りたたみを繰り返される。また、様々な形に成形され、ホイロで発酵させオーブンで焼き上げられるという複雑な工程を経ることになる。当然のことながら小麦粉生地への改良剤の添加は少なからず生地物性の変化を引き起こす。この生地物性の変化は、捏ね上げのための時間、温度の調節や、生地の硬さの変化に対応した展延作業の調節、発酵の進行度の変化に対応した発酵温度、時間の調節など工程の最適化を要求するため、生地改良剤などによる生地食感の改善は途方もない労力を必要とし簡便な方法とは言えない。   It is generally understood that the main cause of deterioration in texture over time of layered flour-expanded food is recrystallization of starch, which is the main ingredient of wheat flour. Is to add. As described above, the crushed flour dough is wrapped in a water-in-oil composition for roll-in and spread and folded repeatedly. Moreover, it is formed into various shapes, and is subjected to a complicated process in which it is fermented in a proofer and baked in an oven. As a matter of course, the addition of an improving agent to the flour dough causes a considerable change in dough physical properties. This change in dough physical properties includes adjustment of time and temperature for kneading, adjustment of spreading work corresponding to changes in dough hardness, adjustment of fermentation temperature and time corresponding to changes in fermentation progress, etc. Since optimization of the process is required, improvement of the texture of the dough with a dough improving agent or the like requires tremendous effort and cannot be said to be a simple method.

また、連続ラインで生産される層状小麦粉膨化食品は効率よく大量に生産することで低価格での商品提供という価値を作り出している。そのため、いくつかの商品に同じ生地を使用するのが一般的である。そのため生地改良剤などの使用は多数の商品に影響を及ぼすことになり実際には改善の有効な手段となりきっていないのが現状である。   In addition, the layered flour-expanded food produced in a continuous line creates the value of providing products at a low price by efficiently mass-producing food. Therefore, it is common to use the same fabric for several products. For this reason, the use of dough improving agents affects a large number of products, and is actually not an effective means for improvement.

パンの物性改良方法としては油脂からのアプローチもなされている。非特許文献1によれば、油相中に飽和モノグリセライドを含有させた練り込み用油脂を用いることでソフトなパンが得られるとあり、焼成2日後までの効果が記載されている。しかし練り込み油脂の配合は生地物性に影響するため、前述の生地改良剤同様の問題を伴う。   As a method for improving the physical properties of bread, an approach from fats and oils is also made. According to Non-Patent Document 1, a soft bread can be obtained by using a kneading fat containing saturated monoglyceride in the oil phase, and the effect until 2 days after baking is described. However, the composition of kneaded fats and oils affects the physical properties of the dough, and therefore involves the same problems as the above-mentioned dough improving agent.

一方、ロールイン用油脂であれば生地物性への影響を抑えながら簡便に最終製品の改良が可能と考えられる。ロールイン用油脂による層状膨化小麦粉食品の食感改良方法としては、例えば、モノグリセリド有機酸エステルを含有し油相のSFCを2〜40%(40℃)としたロールイン用油脂組成物(特許文献1)、システイン類とカルボン酸を含有するロールイン用油中水型乳化油脂組成物(特許文献2)、β型油脂結晶を油相中5%以上かつ有機酸により水相のpH1〜6とした油中水型ロールイン用乳化油脂組成物(特許文献3)、などが開示されている。これらはいずれもサクサクとした食感の付与や維持を課題とするものである。一方、主として連続ラインにより生産され数日間、具体的には例えば焼成後2〜5日間陳列・販売される層状膨化小麦粉食品においては経時的なソフトさ、しっとり感の維持が要求される場面が多い。   On the other hand, it is considered that the final product can be easily improved while suppressing the influence on the physical properties of the roll-in oil and fat. Examples of methods for improving the texture of layered swollen wheat flour foods with roll-in fats and oils include, for example, oil compositions for roll-in containing monoglyceride organic acid esters and SFC in the oil phase of 2 to 40% (40 ° C) (Patent Documents) 1) Water-in-oil type emulsified oil / fat composition for roll-in containing cysteines and carboxylic acid (Patent Document 2), β-type oil / fat crystals in the oil phase at 5% or more and the pH of the aqueous phase from 1 to 6 with organic acid An emulsified oil / fat composition for water-in-oil type roll-in (Patent Document 3) is disclosed. All of these have a problem of imparting and maintaining a crisp texture. On the other hand, in the case of layered puffed flour foods that are mainly produced on a continuous line and are displayed and sold for several days, for example, for 2 to 5 days after baking, there are many situations where it is required to maintain softness and moist feeling over time. .

特開2000―253816号公報JP 2000-253816 A 特開2001―45969号公報JP 2001-45969 A 特開2007―116985号公報JP 2007-116985 A

田中康夫、松本博編「製パン材料の科学」:114〜116頁(光琳、平成4年9月30日発行)Yasuo Tanaka and Hiroshi Matsumoto “Science of Baking Materials”: 114-116 (Kohan, published on September 30, 1992)

パイ、デニッシュペストリーなどの層状膨化小麦粉食品は経時的な品質の劣化、より具体的にはパサつきが感じられ、口どけが悪く感じられるようになったり、食感が硬くなり、ヒキが出て歯切れが悪くなったりするなどの問題がある。本発明においては、特に焼成後の日数が経過してもこれらの問題を抑え、かつ作業性や生地物性への影響を抑制して簡便かつ汎用的な製造方法を提供することを課題とする。   Layered swollen flour foods such as pies and Danish pastries will deteriorate in quality over time, more specifically, puffy, will feel uncomfortable, will have a hard texture, and will have cracks There are problems such as crispness getting worse. In the present invention, it is an object of the present invention to provide a simple and versatile production method that suppresses these problems even when the number of days after baking has elapsed and suppresses the influence on workability and physical properties of the dough.

本発明者らは、特定の成分を含有させたロールイン用油中水型乳化組成物を用いることで上記課題を解決しうる知見を得、本発明を完成するに至った。   The present inventors have obtained knowledge that can solve the above problems by using a water-in-oil emulsion composition for roll-in containing a specific component, and have completed the present invention.

即ち、本発明は
(1)炭素数16〜22の飽和脂肪酸を構成脂肪酸とするモノグリセリドを0.9〜5重量%含有し、且つ、有機酸及び/又は有機酸塩を0.2〜2重量%含有することを特徴とするロールイン用油中水型乳化組成物、
(2)有機酸及び/又は有機酸塩がクエン酸ナトリウムである、(1)に記載のロールイン用油中水型乳化組成物、
(3)(1)ないし(2)いずれかに記載のロールイン用油中水型乳化組成物を使用してなる、層状膨化小麦粉食品、
(4)炭素数16〜22の飽和脂肪酸を構成脂肪酸とするモノグリセリドを0.9〜5重量%、且つ、有機酸及び/又は有機酸塩を0.2〜2重量%配合することを特徴とする、ロールイン用油中水型乳化組成物の製造方法、
(5)有機酸及び/又は有機酸塩がクエン酸ナトリウムである、(4)に記載のロールイン用油中水型乳化組成物の製造方法、
(6)(1)ないし(2)いずれかに記載のロールイン用油中水型乳化組成物を使用することを特徴とする、層状膨化小麦粉食品の製造方法、である。
That is, the present invention includes (1) 0.9 to 5% by weight of a monoglyceride having a saturated fatty acid having 16 to 22 carbon atoms as a constituent fatty acid, and 0.2 to 2% by weight of an organic acid and / or an organic acid salt. % Water-in-oil emulsion composition for roll-in,
(2) The water-in-oil emulsion composition for roll-in according to (1), wherein the organic acid and / or organic acid salt is sodium citrate,
(3) A layered puffed flour food comprising the water-in-oil emulsified composition for roll-in according to any one of (1) to (2),
(4) A monoglyceride containing a saturated fatty acid having 16 to 22 carbon atoms as a constituent fatty acid is blended in an amount of 0.9 to 5% by weight, and an organic acid and / or an organic acid salt is blended in an amount of 0.2 to 2% by weight. A method for producing a water-in-oil emulsion composition for roll-in,
(5) The method for producing a water-in-oil emulsion composition for roll-in according to (4), wherein the organic acid and / or organic acid salt is sodium citrate,
(6) A method for producing a layered puffed flour food, characterized in that the water-in-oil emulsion composition for roll-in according to any one of (1) to (2) is used.

本発明によれば、製造時の生地物性や作業性に影響することなく、焼成後の日数経過後であってもソフトさ、しっとり感が維持されたパイ、デニッシュペストリーなどの層状膨化小麦粉食品が提供できる。   According to the present invention, there is provided a layered puffed flour food such as pie or Danish pastry in which softness and moist feeling are maintained even after the lapse of days after baking without affecting dough physical properties and workability during production. Can be provided.

本発明のロールイン用油中水型乳化組成物の油脂原料としては公知の食用油脂類をいずれも使用することが出来、例えば、菜種油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油、パーム油、シア脂、サル脂、カカオ脂、ヤシ油、パーム核油等の植物性油脂並びに乳脂、牛脂、ラード、魚油、鯨油等の動物性油脂が例示でき、上記油脂類の単独又は混合油或いはそれらの硬化、分別、エステル交換等を施した加工油脂が利用できる。   Any known edible fats and oils can be used as the fat and oil raw material of the water-in-oil type emulsion composition for roll-in of the present invention, such as rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, and rice bran oil. , Corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil, shea fat, monkey fat, cocoa butter, palm oil, palm kernel oil and other vegetable oils and fats, beef tallow, lard, fish oil, Animal fats and oils such as whale oil can be exemplified, and single or mixed oils of the above fats and oils or processed fats and oils subjected to hardening, fractionation, transesterification and the like can be used.

本発明のロールイン用油中水型乳化組成物を構成する油脂原料は、10℃におけるSFCが30〜80、20℃におけるSFCが10〜65、30℃におけるSFCが2〜35であるのが好ましい。下限未満ではロールイン用油中水型乳化組成物が軟らかすぎて、ロールイン作業時に生地が縮んで焼成品の内層が不均一になったり、油中水型乳化組成物が生地に練り込まれて焼成品の内層が詰まってしまったりする場合がある。上限を超える場合はロールイン用油中水型乳化組成物が硬くなりすぎて可塑性を失い、ロールイン作業時に油中水型乳化組成物が割れて焼成品の内層が不均一になる場合がある。   The oil and fat raw material constituting the water-in-oil emulsion composition for roll-in of the present invention has an SFC of 30 to 80 at 10 ° C, an SFC of 10 to 65 at 20 ° C, and an SFC of 2 to 35 at 30 ° C. preferable. Below the lower limit, the water-in-oil emulsion composition for roll-in is too soft, the dough shrinks during the roll-in operation, the inner layer of the baked product becomes uneven, or the water-in-oil emulsion composition is kneaded into the dough. As a result, the inner layer of the fired product may become clogged. If the upper limit is exceeded, the water-in-oil emulsion composition for roll-in may become too hard and lose its plasticity, and the water-in-oil emulsion composition may crack during roll-in operation and the inner layer of the baked product may become uneven. .

本発明のロールイン用油中水型乳化組成物は炭素数16〜22の飽和脂肪酸を構成脂肪酸とするモノグリセリドを0.9〜5重量%、好ましくは1.0〜3.5重量%、更に好ましくは1.05〜2重量%含有し、且つ有機酸及び/又は有機酸塩を0.2〜2重量%、好ましくは0.35〜1.75重量%、更に好ましくは0.5〜1.5重量%を含有することを特徴とする。いずれか一方若しくは両方が、含有されない若しくは下限未満の場合は目的とする層状膨化小麦粉食品の継時的な品質劣化抑制効果が得られない。炭素数16〜22の飽和脂肪酸を構成脂肪酸とするモノグリセリドが上限を超える場合は層状膨化小麦粉食品の口どけが悪くなる場合がある。有機酸及び/又は有機酸塩が上限を超える場合は、有機酸及び/又は有機酸塩に由来する風味が著しく感じられ層状膨化小麦粉食品の商品価値を損なってしまう場合がある。   The water-in-oil emulsified composition for roll-in of the present invention contains 0.9 to 5% by weight, preferably 1.0 to 3.5% by weight, of monoglyceride containing a saturated fatty acid having 16 to 22 carbon atoms as a constituent fatty acid. Preferably it contains 1.05 to 2% by weight, and the organic acid and / or organic acid salt is 0.2 to 2% by weight, preferably 0.35 to 1.75% by weight, more preferably 0.5 to 1%. .5% by weight is contained. When either one or both are not contained or less than the lower limit, the effect of suppressing quality deterioration over time of the intended layered puffed flour food product cannot be obtained. When the monoglyceride which uses a saturated fatty acid having 16 to 22 carbon atoms as the constituent fatty acid exceeds the upper limit, the layered puffed flour food may be unsatisfactory. When the organic acid and / or organic acid salt exceeds the upper limit, the flavor derived from the organic acid and / or organic acid salt may be felt remarkably and the commercial value of the layered puffed flour food product may be impaired.

本発明においては上記モノグリセリドと有機酸及び/又は有機酸塩を、ロールイン用油中水型乳化組成物中に含有させることが特徴である。これにより小麦粉生地の物性に影響することなく、簡便に最終製品での効果が得られる。半面、これらを単独あるいは併用して小麦粉生地中に直接添加した場合は、伸展性の増加など生地物性の変化を伴うため個別に生産工程の調節や最適化が必要となり、簡便性や汎用性に劣るものとなってしまう。   The present invention is characterized in that the monoglyceride and the organic acid and / or the organic acid salt are contained in the water-in-oil emulsion composition for roll-in. Thereby, the effect in the final product can be easily obtained without affecting the physical properties of the flour dough. On the other hand, when these are added directly or in combination to the flour dough, it is necessary to individually adjust and optimize the production process due to changes in dough physical properties such as increased extensibility. It will be inferior.

本発明のロールイン用油中水型乳化組成物に含有させる有機酸及び/又は有機酸塩はいずれにおいても層状膨化小麦粉食品の継時的な品質の劣化の抑制に有効であるが、風味の面から有機酸塩が好ましい。上記有機酸としてはクエン酸、コハク酸、グルコン酸、酢酸、酒石酸、乳酸、フマル酸、リンゴ酸、イタコン酸、フィチン酸、αケトグルタル酸等が挙げられる。有機酸塩としては前述の有機酸のナトリウム塩、カリウム塩、カルシウム塩などが挙げられる。有機酸及び/又は有機酸塩は単独又は複数種類を組み合わせて使用することができる。また、有機酸/有機酸塩の種類によっては特有の風味を有し最終製品の用途が限られてしまう場合があるためクエン酸ナトリウムが好ましく、クエン酸三ナトリウムが汎用的で最も好ましい。   The organic acid and / or organic acid salt contained in the water-in-oil emulsion composition for roll-in of the present invention is effective in suppressing deterioration of quality over time of the layered puffed flour food. From the aspect, an organic acid salt is preferable. Examples of the organic acid include citric acid, succinic acid, gluconic acid, acetic acid, tartaric acid, lactic acid, fumaric acid, malic acid, itaconic acid, phytic acid, and α-ketoglutaric acid. Examples of organic acid salts include sodium salts, potassium salts, calcium salts, and the like of the aforementioned organic acids. The organic acid and / or organic acid salt can be used alone or in combination. Also, depending on the type of organic acid / organic acid salt, it may have a unique flavor and the use of the final product may be limited, so sodium citrate is preferred, and trisodium citrate is the most versatile and most preferred.

本発明の油中水型乳化組成物は必要に応じて乳化剤を添加しても良い。乳化剤としてはレシチン、グリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、シュガーエステル、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステルおよび酢酸モノグリセリド、酒石酸モノグリセリド、酢酸酒石酸混合モノグリセリド、クエン酸モノグリセリド、ジアセチル酒石酸モノグリセリド、乳酸モノグリセリド、コハク酸モノグリセリド、リンゴ酸モノグリセリド等各種有機酸モノグリセリド、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウムなどが挙げられる。   An emulsifier may be added to the water-in-oil emulsion composition of the present invention as necessary. As emulsifiers, lecithin, glycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, sugar ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, propylene glycol fatty acid ester and acetic acid monoglyceride, tartaric acid monoglyceride, mixed tartaric acid monoglyceride Citric acid monoglyceride, diacetyltartaric acid monoglyceride, lactic acid monoglyceride, succinic acid monoglyceride, various organic acid monoglycerides such as malic acid monoglyceride, stearoyl calcium lactate, and stearoyl sodium lactate.

本発明においては上記の原料、添加物の他に、所望により、色素、抗酸化剤、香料などの油溶性成分、食塩、糖類、粉乳、発酵乳などの水溶性成分を使用することができる。   In the present invention, in addition to the above-mentioned raw materials and additives, oil-soluble components such as pigments, antioxidants and fragrances, and water-soluble components such as salt, saccharides, powdered milk and fermented milk can be used as desired.

本発明のロールイン用油中水型乳化組成物の製造法については特に限定されないが、常法通り油相と水相とを予備乳化した後、パーフェクター、ボテーター、コンビネーターなどで急冷捏和することにより製造することができる。油相は、融解した油脂に必要に応じて色素、抗酸化剤、香料等の油溶性成分を添加、溶解/分散させ調製することができる。水相は水又は温水に水溶性の乳成分、必要に応じて食塩、糖類、無機塩類等を添加、溶解/分散させ調製することができる。   The method for producing the water-in-oil emulsion composition for roll-in of the present invention is not particularly limited, but after pre-emulsification of the oil phase and the aqueous phase as usual, it is quenched with a perfector, a botter, a combinator, etc. Can be manufactured. The oil phase can be prepared by adding and dissolving / dispersing oil-soluble components such as pigments, antioxidants, and fragrances as necessary to the melted fats and oils. The aqueous phase can be prepared by adding and dissolving / dispersing a water-soluble milk component in water or warm water, and if necessary, sodium chloride, saccharides, inorganic salts and the like.

本発明の層状膨化小麦粉食品は、小麦粉を主原料とし水、塩などを加えて混捏し得られる小麦粉生地(ドウ)を薄く延ばし、これにロールイン用油中水型乳化組成物を載せて折りたたみ、再び薄く延ばすことを繰り返して層状生地を作り、必要に応じ発酵、成形、焼成することにより得ることが出来る。このようにして得られる層状膨化小麦粉食品の具体例としてはデニッシュペストリー、クロワッサン、パイ等が例示できる。また、経時的な品質劣化が効果的に抑制されるため、数日間陳列・販売される製品において特に好適である。   The layered puffed flour food of the present invention is made by spreading a flour dough, which can be kneaded by adding water, salt, etc. with wheat flour as a main ingredient, and folding it on a roll-in water-in-oil emulsion composition It is possible to obtain a layered dough by repeating the thinning again and then fermenting, shaping and baking as necessary. Specific examples of the layered puffed flour food thus obtained include Danish pastries, croissants, and pies. Moreover, since deterioration of quality over time is effectively suppressed, it is particularly suitable for products that are displayed and sold for several days.

以下に実施例を示し、本発明をより詳細に説明する。なお、例中%及び部はいずれも断りのない限り重量基準を意味する。   The following examples illustrate the present invention in more detail. In the examples, “%” and “parts” mean weight basis unless otherwise specified.

[ロールイン用油中水型乳化組成物の調製]
<実施例1>
パーム分別硬化油(上昇融点38℃)21部、菜種硬化油(上昇融点35℃)16部、大豆油21部、飽和モノグリセリド(『エマルジーMS』理研ビタミン株式会社製)1.1部、大豆レシチン(『SLPペースト』辻製油株式会社製)0.3部、を60℃で混合し、油相を得た。別途60℃の水10部、砂糖・ぶどう糖果糖液糖30部にクエン酸三ナトリウム0.6部を溶解させ水相を得た。油相と水相とを60℃で混合攪拌し予備乳化させ、コンビネーターにより急冷捏和し、組織良好なロールイン用油中水型乳化組成物を得た。
[Preparation of water-in-oil emulsion composition for roll-in]
<Example 1>
Palm fraction hardened oil (rising melting point 38 ° C) 21 parts, rapeseed hardened oil (rising melting point 35 ° C) 16 parts, soybean oil 21 parts, saturated monoglyceride ("Emulsy MS" manufactured by Riken Vitamin Co., Ltd.) 1.1 parts, soy lecithin 0.3 parts (“SLP paste” manufactured by Sakai Oil Co., Ltd.) were mixed at 60 ° C. to obtain an oil phase. Separately, 0.6 part of trisodium citrate was dissolved in 10 parts of water at 60 ° C. and 30 parts of sugar / fructose fructose liquid sugar to obtain an aqueous phase. The oil phase and the aqueous phase were mixed and stirred at 60 ° C., preliminarily emulsified, and rapidly cooled and kneaded with a combinator to obtain a water-in-oil emulsion composition for roll-in having a good structure.

<実施例2〜7、比較例1〜3>
表1、2の配合に従い、実施例1に準じてロールイン用油中水型乳化組成物を得た。
<Examples 2-7, Comparative Examples 1-3>
According to the composition of Tables 1 and 2, a water-in-oil emulsion composition for roll-in was obtained according to Example 1.

<実施例8>
パーム分別硬化油(上昇融点38℃)30部、菜種硬化油(上昇融点35℃)24部、大豆油30部、飽和モノグリセリド(『エマルジーMS』理研ビタミン株式会社製)1.1部、大豆レシチン(『SLPペースト』辻製油株式会社製)0.3部、を60℃で混合し、油相を得た。別途60℃の水14部にクエン酸三ナトリウム0.6部を溶解させ水相を得た。油相と水相とを60℃で混合攪拌し予備乳化させ、コンビネーターにより急冷捏和し、組織良好なロールイン用油中水型乳化組成物を得た。
<Example 8>
30 parts of fractionated palm oil (increased melting point 38 ° C), 24 parts of rapeseed oil (increased melting point 35 ° C), 30 parts of soybean oil, 1.1 parts of saturated monoglyceride ("Emulsy MS" manufactured by Riken Vitamin Co., Ltd.), soybean lecithin 0.3 parts (“SLP paste” manufactured by Sakai Oil Co., Ltd.) were mixed at 60 ° C. to obtain an oil phase. Separately, 0.6 part of trisodium citrate was dissolved in 14 parts of water at 60 ° C. to obtain an aqueous phase. The oil phase and the aqueous phase were mixed and stirred at 60 ° C., preliminarily emulsified, and rapidly cooled and kneaded with a combinator to obtain a water-in-oil emulsion composition for roll-in having a good structure.

<比較例4〜6>
表2の配合に従い、実施例8に準じてロールイン用油中水型乳化組成物を得た。
<Comparative Examples 4-6>
According to the formulation in Table 2, a water-in-oil emulsion composition for roll-in was obtained according to Example 8.

[試験1](デニッシュ焼成テスト)
表4に記載の小麦粉生地原料を練り上げ、28℃、湿度75%の庫内にて60分間発酵させた後、−18℃のフリーザーで60分間リタードをとった。実施例1〜7及び比較例1〜2のロールイン用油中水型乳化組成物を折り込み(対粉50%)、リバースシーターで3つ折りを2回行った後、−7℃のフリーザーで60分間リタードをとり、リバースシーターで3つ折りを1回行った後、−7℃のフリーザーで45分間リタードをとった。続いてリバースシーターで生地厚8mmまで延ばし、50mm×150mmの短冊状にカットし、2本をツイストした後リング状に成形し、直径18cmのエンゼル型に入れ、32℃、湿度75%の庫内で60分間発酵させた後、庫内温度210℃のオーブンで16分間焼成し、デニッシュを得た。
[Test 1] (Danish baking test)
The flour dough raw materials shown in Table 4 were kneaded and fermented in a chamber at 28 ° C. and 75% humidity for 60 minutes, and then retarded for 60 minutes with a −18 ° C. freezer. The water-in-oil emulsion composition for roll-in of Examples 1 to 7 and Comparative Examples 1 to 2 was folded (50% to the powder), and then folded in three on a reverse sheeter, and then 60 in a freezer at -7 ° C. After taking the retard for 1 minute, the sheet was folded once on the reverse sheeter and then retarded for 45 minutes with a freezer at -7 ° C. Subsequently, the dough is stretched to a thickness of 8 mm with a reverse sheeter, cut into a strip of 50 mm × 150 mm, twisted into two, then formed into a ring, put into an angel mold with a diameter of 18 cm, and stored at 32 ° C. and 75% humidity. And then baked for 16 minutes in an oven with an internal temperature of 210 ° C. to obtain a Danish.

[試験2](クロワッサン焼成テスト)
表6に記載の小麦粉生地原料を練り上げ、28℃、湿度75%の庫内にて60分間発酵させた後、−18℃のフリーザーで60分間リタードをとった。実施例8及び比較例5〜8のロールイン用油中水型乳化組成物を折り込み(対粉60%)、リバースシーターで3つ折りを2回行った後、−7℃のフリーザーで60分間リタードをとり、リバースシーターで3つ折りを1回行った後、−7℃のフリーザーで45分間リタードをとった。続いて、リバースシーターで生地厚4mmまで延ばし、55gを成形し、32℃、湿度75%の庫内で60分間発酵させた後、庫内温度210℃のオーブンで17分間焼成し、クロワッサンを得た。
[Test 2] (Croissant firing test)
The flour dough raw materials shown in Table 6 were kneaded and fermented for 60 minutes in a chamber at 28 ° C and 75% humidity, and then retarded for 60 minutes with a freezer at -18 ° C. The water-in-oil emulsion composition for roll-in of Example 8 and Comparative Examples 5 to 8 was folded (60% powder), folded twice with a reverse sheeter, and then retarded for 60 minutes with a -7 ° C freezer. Then, the plate was folded once on a reverse sheeter and then retarded for 45 minutes with a freezer at -7 ° C. Subsequently, the dough thickness is extended to 4 mm with a reverse sheeter, 55 g is formed, fermented in a chamber at 32 ° C. and 75% humidity for 60 minutes, and then baked in an oven at 210 ° C. for 17 minutes to obtain a croissant. It was.

実施例1〜7及び比較例1〜3のデニッシュ、実施例8及び比較例4〜6のクロワッサンについてパネラー7名による官能評価を行い、焼成1日後は風味・口溶け、食感(しっとり感、ソフト感)について、焼成4日後は食感(しっとり感、ソフト感)について評価した結果を表1,2に示した。   A sensory evaluation was performed by seven panelists on the Danish of Examples 1 to 7 and Comparative Examples 1 to 3, and the croissants of Example 8 and Comparative Examples 4 to 6, and after 1 day of baking, the taste, mouth melt, texture (moist feeling, softness) Tables 1 and 2 show the evaluation results of the texture (moist feeling, soft feeling) after 4 days of baking.

[評価基準]
(風味、口溶け)
○:良好
△:やや劣るが可
×:不良
(しっとり感)
○:良好
△:ややパサつき感あるが許容範囲
×:パサつき強く、不良
(ソフト感)
○:良好
△:やや硬いが許容範囲
×:硬く、不良
いずれも△以上を合格とした。
[Evaluation criteria]
(Flavor, melt in mouth)
○: Good △: Slightly inferior but acceptable ×: Poor (moist feeling)
○: Good △: Slightly sticky but acceptable range ×: Strong and bad (soft)
◯: Good △: Slightly hard, but acceptable range ×: Hard, bad for any defect was passed or better.

[焼成1日後の評価]
実施例は風味・口溶け、しっとり感、ソフト感すべてにおいて良好であった。実施例4〜6の風味に関しては、実施例4はやや酸味が感じられ、実施例5はやや独特な旨みが感じられ、実施例6はやや酸味とやや独特な旨みが感じられたため、最終的な層状膨化小麦粉食品の風味(用途)が限定されてしまう場合があるものの、おおむね良好といえる範囲であった。一方、比較例5は塩味が強く、風味において不良であった。比較例6は口溶けが悪く、また食感も硬く、ソフト感において不良であった。
[Evaluation 1 day after firing]
The examples were good in all of the flavor, melting in the mouth, moist feeling and soft feeling. Regarding the flavors of Examples 4 to 6, since Example 4 felt a slightly sour taste, Example 5 felt a slightly unique taste, and Example 6 felt a slightly sour taste and slightly unique taste. Although the flavor (use) of the layered puffed flour food may be limited, it was generally in a good range. On the other hand, Comparative Example 5 had a strong salty taste and was poor in flavor. Comparative Example 6 was poor in melting in the mouth, hard in texture, and poor in soft feeling.

[焼成4日後の評価]
実施例はいずれもしっとり感、ソフト感ともに良好であった。実施例3は若干のパサつきと硬さが感じられたものの、良好と判断できる範囲であった。一方、比較例の食感はいずれも硬くパサつきが感じられ、しっとり感、ソフト感ともに不良であった。
[Evaluation 4 days after firing]
In all the examples, both moist and soft feelings were good. Example 3 was in a range where it could be judged as good, although a slight sag and hardness were felt. On the other hand, the textures of the comparative examples were both hard and puffy, and both the moist and soft feelings were poor.

(表1)(単位:重量部)

Figure 0006459210
(Table 1) (Unit: parts by weight)
Figure 0006459210

(表2)(単位:重量部)

Figure 0006459210
(Table 2) (Unit: parts by weight)
Figure 0006459210

(比較例7)
表3の配合に従い、実施例1に準じてロールイン用油中水型乳化組成物を得た。続いて表4に記載の小麦粉生地配合に飽和モノグリセリド1.1部、クエン酸三ナトリウム0.6部を加えて練り上げ、試験1に準じてデニッシュを製造した。作業中、小麦粉生地の伸展性が他の実施例・比較例に比べて顕著に増加したため条件の変更調整が必要となり、工程がより煩雑であった。層状膨化小麦粉食品の口溶けにも劣っていた。
(Comparative Example 7)
According to the formulation in Table 3, a water-in-oil emulsion composition for roll-in was obtained according to Example 1. Subsequently, 1.1 parts of saturated monoglyceride and 0.6 part of trisodium citrate were added to the flour dough composition shown in Table 4 and kneaded, and Danish was produced according to Test 1. During the work, the extensibility of the flour dough was significantly increased as compared with other examples and comparative examples, so that the condition change adjustment was necessary, and the process was more complicated. It was inferior to the mouth melting of the layered puffed flour food.

(表3)(単位:重量部)

Figure 0006459210
(Table 3) (Unit: parts by weight)
Figure 0006459210

(表4)試験1:デニッシュ用小麦粉生地配合(単位:重量部)

Figure 0006459210
(Table 4) Test 1: Compounding flour flour for Danish (unit: parts by weight)
Figure 0006459210

(表5)デニッシュ製造条件

Figure 0006459210
(Table 5) Danish production conditions
Figure 0006459210

(表6)試験2:クロワッサン用の小麦粉生地配合(単位:重量部)

Figure 0006459210
(Table 6) Test 2: Mixing flour dough for croissants (unit: parts by weight)
Figure 0006459210

(表7)クロワッサン製造条件

Figure 0006459210
(Table 7) Production conditions for croissants
Figure 0006459210

Claims (3)

炭素数16〜22の飽和脂肪酸を構成脂肪酸とするモノグリセリドを0.9〜5重量%含有し、且つ、クエン酸ナトリウム0.35〜1.75重量%含有することを特徴とする、ロールイン用油中水型乳化組成物。 A roll-in characterized in that it contains 0.9 to 5% by weight of monoglyceride containing a saturated fatty acid having 16 to 22 carbon atoms as a constituent fatty acid and 0.35 to 1.75% by weight of sodium citrate. Water-in-oil emulsion composition. 炭素数16〜22の飽和脂肪酸を構成脂肪酸とするモノグリセリドを0.9〜5重量%配合し、且つ、クエン酸ナトリウム0.35〜1.75重量%配合することを特徴とする、ロールイン用油中水型乳化組成物の製造方法。 A roll-in characterized in that 0.9 to 5% by weight of monoglyceride containing a saturated fatty acid having 16 to 22 carbon atoms as a constituent fatty acid and 0.35 to 1.75% by weight of sodium citrate. For producing a water-in-oil emulsion composition. 請求項1に記載のロールイン用油中水型乳化組成物を使用することを特徴とする、層状膨化小麦粉食品の製造方法。 Use of the water-in-oil emulsion composition for roll-in according to claim 1 , a method for producing a layered expanded flour food product.
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