JP5119922B2 - Plastic oil composition - Google Patents

Plastic oil composition Download PDF

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JP5119922B2
JP5119922B2 JP2007533160A JP2007533160A JP5119922B2 JP 5119922 B2 JP5119922 B2 JP 5119922B2 JP 2007533160 A JP2007533160 A JP 2007533160A JP 2007533160 A JP2007533160 A JP 2007533160A JP 5119922 B2 JP5119922 B2 JP 5119922B2
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oil
fat composition
melting point
plastic fat
low melting
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JPWO2007026525A1 (en
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智明 熊谷
淳 垣本
友紀 木村
徹 中西
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Fuji Oil Co Ltd
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Fuji Oil Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/16Fatty acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/10Ester interchange

Description

本発明は、可塑性油脂組成物に関し、更に詳しくは、小麦粉生地と共に使用する際に適した可塑性油脂組成物及びそれを使用してなる膨化食品に関する。   The present invention relates to a plastic fat composition, and more particularly to a plastic fat composition suitable for use with a flour dough and a puffed food using the same.

食パン、菓子パン、デニッシュペストリー、パイなどのパン類に代表される膨化食品はオーブンフレッシュベーカリー、いわゆる町のパン屋さんをはじめスーパー、コンビニエンスストアなど様々な場所で売られており、人気を集めている。パンを製造する際、原料として小麦粉、砂糖、食塩、卵など様々使用される中で、バター、マーガリン、ショートニングに代表される可塑性油脂が欠かせないものとして使われており、その効果としてはパンのボリュームをアップさせたり、食感をソフトにしたり、歯切れをよくしたり、また、風味をアップさせたりする。   Boiled food represented by bread such as bread, sweet bread, Danish pastry, pie, etc. are sold in various places such as oven fresh bakery, so-called bakery in town, supermarket, convenience store etc. . In the production of bread, flour, sugar, salt, eggs, etc. are used as raw materials, but plastic oils and fats typified by butter, margarine, and shortening are indispensable. Increase the volume of the food, soften the texture, improve crispness, and increase the flavor.

小麦粉含有膨化食品においては、小麦粉生地と共に使用する可塑性油脂組成物の添加量によって主に3つのカテゴリーに分類することができる。1つは可塑性油脂組成物をほとんど含まないもので、フランスパンが挙げられ、そのひきの強い食感が特徴となっている。2つ目は可塑性油脂組成物の添加量が対小麦粉100部に対して3〜25部程度のもので、コッペパン、食パン、菓子パン、ロール類(テーブルロール、バターロール、バンズ等)、バラエティーブレッド(レーズンパン、胚芽パン等)、ブリオッシュなどがあり、可塑性油脂組成物は生地に練り込んで使用するのが一般的である。3つ目は可塑性油脂組成物の添加量が多いもので、デニッシュペストリー、クロワッサン、パイなどに代表される層状の膨化食品であり、一般的に生地に可塑性油脂組成物を対小麦粉100部に対して3〜25部程度練り込んだ後、ロールイン用可塑性油脂組成物を対小麦粉100部に対して20〜100部折り込むものである。   The flour-containing swollen food can be classified mainly into three categories according to the amount of the plastic fat composition used together with the flour dough. One is one that contains almost no plastic fat composition and includes French bread, which is characterized by its strong texture. Second, the amount of the plastic oil / fat composition added is about 3 to 25 parts per 100 parts of flour, such as copper bread, bread, sweet bread, rolls (table roll, butter roll, buns, etc.), variety bread ( Raisin bread, germ bread, etc.), brioche, etc., and the plastic fat composition is generally kneaded into dough. The third is a large amount of the plastic fat composition added, and is a layered puffed food represented by Danish pastries, croissants, pies, etc. Generally, the plastic fat composition is added to the flour for 100 parts of flour. After kneading about 3 to 25 parts, the roll-in plastic fat composition is folded into 20 to 100 parts per 100 parts of flour.

従来の食パン、コッペパン、菓子パン、ロール類(テーブルロール、バターロール、バンズ等)、バラエティーブレッド(レーズンパン、胚芽パン等)、ブリオッシュなど、練り込み用可塑性油脂組成物が使用されるパンにおいて、消費者の一つの大きなニーズであるソフトなパンを製造することは非常に難しいことであった。この課題を解決すべく、様々な可塑性油脂に関する発明がなされてきたが、一例を挙げると、特許文献1では動植物性油脂及び/又はその硬化油脂100重量部に、モノグリセリド0.1〜5.0重量部及びジアセチル酒石酸モノグリセリド0.1〜5.0重量部を配合し、該配合物を急冷可塑化してなることを特徴とする製パン練込油脂組成物が開示されている。   Conventional bread, cupe bread, sweet bread, rolls (table roll, butter roll, buns, etc.), variety bread (raisin bread, germ bread, etc.), brioche, etc. It was very difficult to produce soft bread, which is one of the big needs of consumers. In order to solve this problem, inventions related to various plastic oils and fats have been made. To give an example, in Patent Document 1, monoglyceride 0.1 to 5.0 is added to 100 parts by weight of animal and vegetable oils and / or hardened oils and fats thereof. There is disclosed a bread kneading fat and oil composition characterized by blending 0.1 part by weight and 0.1 part by weight of diacetyltartaric acid monoglyceride and quenching plasticization of the blend.

その他、合成乳化剤など添加物を使用せずにソフトなパンを製造することを目的として油脂原料以外の原料の添加に関する発明も多々ある。例を挙げると特許文献2、特許文献3、特許文献4などである。   In addition, there are many inventions related to the addition of raw materials other than fat raw materials for the purpose of producing soft bread without using additives such as synthetic emulsifiers. Examples include Patent Document 2, Patent Document 3, Patent Document 4, and the like.

油脂原料によりソフトなパンを製造する発明として特許文献5では、S1US2(S1及びS2は飽和脂肪酸、Uは不飽和脂肪酸を表す)で表されるトリグリセリドとUS3U(S3は飽和脂肪酸、Uは不飽和脂肪酸を表す)で表されるトリグリセリドとからなるコンパウンド結晶を含有することを特徴とする製パン練り込み用油脂組成物が開示されている。しかしながら上記発明では可塑性油脂組成物の練り込み適性に注力した発明であって、焼成後の膨化食品中の油脂の結晶化挙動には着眼しておらず、充分に満足できるレベルにパンをソフトにすることはできなかった。   In Patent Document 5, as an invention for producing soft bread from fats and oils, triglyceride represented by S1US2 (S1 and S2 are saturated fatty acids, U represents unsaturated fatty acids) and US3U (S3 is saturated fatty acids, U is unsaturated) An oil and fat composition for bread kneading is disclosed, comprising a compound crystal composed of triglyceride represented by (fatty acid). However, in the above invention, the invention focuses on the kneading suitability of the plastic fat composition and does not focus on the crystallization behavior of the fat in the expanded food after baking, and softens the bread to a sufficiently satisfactory level. I couldn't.

特開平5−219886号公報Japanese Patent Laid-Open No. 5-219886 特開平08−196198号公報Japanese Patent Laid-Open No. 08-196198 特開平10−248480号公報Japanese Patent Laid-Open No. 10-248480 特開2002−153208号公報JP 2002-153208 A 特開2003−210107号公報Japanese Patent Laid-Open No. 2003-210107

このような状況に鑑み、従来になく非常にソフトなパンなどの膨化食品を製造することができる可塑性油脂組成物を提供することを目的とする。   In view of such a situation, an object is to provide a plastic fat composition capable of producing a puffed food such as a very soft bread, which has never existed before.

本発明者らは、最適な練り込み適性と焼成後の膨化食品中の油脂結晶化挙動に着眼し、鋭意研究を行った結果、油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCが8.0%以下であって、得られた油脂組成物の20℃で15時間放置した後の硬さが50g/cm〜2000g/cmである可塑性油脂組成物により、上記課題を解決できるという知見を得、本発明を完成するに至ったのである。
即ち本発明の第1は、小麦粉生地と共に使用する油脂組成物であって、油相中にSUSで表されるトリグリセリドとXUU又はUXU(Xは任意の脂肪酸)で表されるトリグリセリドを主に含有し、SUSで表されるトリグリセリドが(Sはパルミチン酸、ステアリン酸から選ばれる1種類又は2種類である飽和脂肪酸、Uはオレイン酸、リノール酸、リノレン酸から選ばれるシス型不飽和脂肪酸)であり、XUU又はUXU(Xは任意の脂肪酸)で表されるトリグリセリドが菜種油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油、パーム油分別低融点部、ラード分別低融点部、乳脂分別低融点部、ヤシ油分別低融点部、パーム核油分別低融点部、カカオ脂分別低融点部、サル脂分別低融点部及びシア脂分別低融点部由来であり、SUSで表されるトリグリセリドが油相中6〜50重量%であり、XUU又はUXUで表されるトリグリセライドが油相中36〜80重量%であって、油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCが2.0%以下であって、得られた油脂組成物の20℃で15時間放置した後の硬さが50g/cm〜2000g/cmであり、当該油脂組成物は小麦粉100部に対して3〜25部を小麦粉生地に練り込む使用である、練り込み用可塑性油脂組成物である。第2は、SUSで表されるトリグリセリドが油相中15〜42重量%である、第1記載の練り込み用可塑性油脂組成物である。第3は、XUU又はUXUで表されるトリグリセライドが油相中40〜75重量%である、第1記載の練り込み用可塑性油脂組成物である。第4は、得られた油脂組成物の20℃で15時間放置した後の硬さが70g/cm〜1800g/cmである、第1記載の練り込み用可塑性油脂組成物である。第5は、XUU又はUXUで表されるトリグリセリドにおいてXが炭素数16以下の飽和脂肪酸又は不飽和脂肪酸である、第1記載の練り込み用可塑性油脂組成物である。第6は、構成する脂肪酸が炭素数12以上の飽和脂肪酸及びトランス型不飽和脂肪酸から選ばれる1種類又は2種類以上であるトリグリセライドが可塑性油脂組成物を構成する油相中5重量%以下である、第1乃至第5の何れか1に記載の練り込み用可塑性油脂組成物である。第7は、第1乃至第6の何れか1に記載の練り込み用可塑性油脂組成物を使用してなる膨化食品である。
The inventors of the present invention focused on optimal kneading suitability and oil crystallization behavior in the expanded food after baking, and as a result of intensive research, the oil phase was placed at 60 ° C. for 1 hour and then at 25 ° C. a less SFC is 8.0% when placed for 24 hours, the hardness after 15 hours at 20 ° C. the resulting fat composition is 50g / cm 2 ~2000g / cm 2 plastic fat composition The present inventors have obtained the knowledge that the above problems can be solved by the product, and have completed the present invention.
That is, the first of the present invention is an oil and fat composition used together with wheat flour dough, and mainly contains triglyceride represented by SUS and triglyceride represented by XUU or UXU (X is an arbitrary fatty acid) in the oil phase. The triglyceride represented by SUS is (S is one or two saturated fatty acids selected from palmitic acid and stearic acid, U is a cis unsaturated fatty acid selected from oleic acid, linoleic acid, and linolenic acid) Yes, triglyceride represented by XUU or UXU (X is any fatty acid) is rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose Oil, palm oil fractionation low melting point, lard fractionation low melting point, milk fat fractionation low melting point, palm oil fractionation low melting point, palm kernel oil fractionation low melting point, cocoa butter The low melting point part, the salfat fractionation low melting part and the shea fat fractionation low melting part are derived, the triglyceride represented by SUS is 6 to 50% by weight in the oil phase, and the triglyceride represented by XUU or UXU is the oil phase. 36 to 80% by weight, and the SFC when the oil phase is placed at 60 ° C. for 1 hour and then placed at 25 ° C. for 24 hours is 2.0% or less, The hardness after leaving at 20 ° C. for 15 hours is 50 g / cm 2 to 2000 g / cm 2 , and the fat composition is used for kneading 3 to 25 parts into flour dough for 100 parts of flour. It is a plastic oil composition for embedding. 2nd is the plastic fat composition for kneading | mixing of 1st whose triglyceride represented by SUS is 15 to 42 weight% in an oil phase. 3rd is the plastic fat composition for kneading | mixing of 1st whose triglyceride represented by XUU or UXU is 40 to 75 weight% in an oil phase. Fourth, 20 ° C. at left the hardness after 15 hours of the resulting fat composition is 70g / cm 2 ~1800g / cm 2 , a kneading for plastic fat composition of the first described. The fifth is the plastic fat composition for kneading according to the first aspect, wherein in the triglyceride represented by XUU or UXU, X is a saturated fatty acid or unsaturated fatty acid having 16 or less carbon atoms. 6thly, the triglyceride whose fatty acid to comprise is 1 type or 2 types or more chosen from a saturated fatty acid and trans-type unsaturated fatty acid of 12 or more carbon atoms is 5 weight% or less in the oil phase which comprises a plastic fat composition. The plastic fat composition for kneading according to any one of 1st to 5th. 7th is the puffed food which uses the plastic fat composition for kneading | mixing of any one of 1st thru | or 6th.

本発明により、従来になく非常にソフトなパンなどの膨化食品を製造することができる練り込み用可塑性油脂組成物を提供することが可能になった。   According to the present invention, it has become possible to provide a kneading plastic fat composition capable of producing a puffed food such as bread that is extremely soft and unprecedented.

本発明の可塑性油脂組成物に使用する油脂原料としては例えば、菜種油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油、パーム油、シア脂、サル脂、カカオ脂、ヤシ油、パーム核油等の植物性油脂並びに乳脂、牛脂、ラード、魚油、鯨油等の動物性油脂が例示でき、上記油脂類の単独又は混合油或いはそれらの硬化、分別、エステル交換等を施した加工油脂が適する。   Examples of fats and oils used in the plastic fat composition of the present invention include rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, Examples include vegetable oils such as palm oil, shea fat, monkey fat, cacao butter, coconut oil, palm kernel oil, and animal fats such as milk fat, beef tallow, lard, fish oil, whale oil, and the like. Alternatively, processed oils and fats that have been cured, fractionated, transesterified, etc. are suitable.

本発明の可塑性油脂組成物は油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCが8.0%以下、好ましくは5.0%以下、更に好ましくは2.0%以下である必要がある。ここで言う油相とは可塑性油脂組成物を構成する油溶性成分全体を指し、原料油脂に所望により添加された乳化剤、香料、酸化防止剤、着色料など油溶性の原料、添加物などが含まれたものを指す。上限を超える場合は得られる焼成品がソフトでなくなってしまい好ましくない。油脂を60℃に1時間置くことにより一般的な食用の可塑性油脂組成物に含有されている油脂は完全に融解するため、パン焼成直後のパン中の融解した油脂の状態を想定できる。25℃に24時間置くことによりパン焼成後に徐々に室温に冷却され、1日後のパン中の油脂の状態を想定できる。すなわち、本発明者らは上記温度処理を油脂に施した場合に焼成1日後のパン中の油脂の固化状態(固体脂含量)を想定できることを見出した。更に、上記温度処理を油脂に施し、SFCが上限以下である場合パンがソフトになること、更にはSFCが0%の場合、すなわち焼成1日後に結晶を生成しない場合、最もソフトなパンが得られることを見出した。SFCは油脂の固体脂指数を表わすものであって測定方法としては、AOCS Official Method第5版Cd16−81に準じて、60℃に60分置いた後、0℃に移し60分置いた後、各測定温度に移し30分後に測定する。
しかしながら、本発明のSFCは可塑性油脂組成物の油相(但し実施例に示したような乳化剤など油溶性添加物を使用していない場合の油相は原料油脂のみである)を60℃で1時間置いた後、25℃にて24時間置いた後25℃で測定したものである。
The plastic fat composition of the present invention has an SFC of 8.0% or less, preferably 5.0% or less, more preferably 2 when the oil phase is placed at 60 ° C. for 1 hour and then placed at 25 ° C. for 24 hours. Must be 0.0% or less. The oil phase mentioned here refers to the entire oil-soluble component constituting the plastic fat composition, and includes oil-soluble raw materials and additives such as emulsifiers, fragrances, antioxidants, and coloring agents that are optionally added to the raw oil and fat. Points to When the upper limit is exceeded, the fired product obtained is not soft, which is not preferable. Since the fats and oils contained in a general edible plastic fat composition are completely melted by placing the fats and oils at 60 ° C. for 1 hour, it is possible to assume the state of the melted fats and oils in the bread immediately after baking. By placing it at 25 ° C. for 24 hours, it is gradually cooled to room temperature after baking, and the state of fats and oils in the bread after 1 day can be assumed. That is, the present inventors have found that when the above-mentioned temperature treatment is applied to fats and oils, the solidified state (solid fat content) of the fats and oils in the bread one day after baking can be assumed. Furthermore, when the above-mentioned temperature treatment is applied to fats and oils and the SFC is below the upper limit, the bread becomes soft, and when the SFC is 0%, that is, when no crystals are formed after one day of baking, the softest bread is obtained. I found out that SFC represents the solid fat index of fats and oils, and as a measuring method, according to AOCS Official Method 5th edition Cd16-81, after 60 minutes at 60 ° C., after moving to 0 ° C. and 60 minutes, It moves to each measurement temperature and measures 30 minutes later.
However, the SFC of the present invention has an oil phase of the plastic fat composition (provided that the oil phase is only the raw oil and fat when no oil-soluble additive such as an emulsifier as shown in the Examples is used) at 60 ° C. It was measured at 25 ° C. after 24 hours at 25 ° C.

従来の可塑性油脂組成物では最適な練り込み適性を持たせるために、融解後いかなる冷却条件においても結晶析出が早く、固化し易い原料油脂を用いることが通例となっており、油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCが8.0%以下となる特性を有する可塑性油脂組成物はほとんど使用されていなかった。
これらの内容については後に段落番号〔0042〕、〔0043〕で詳しく説明する。
In order to provide the optimum kneading suitability in the conventional plastic fat composition, it is customary to use a raw fat / oil which is easy to solidify quickly and crystallizes under any cooling condition after melting. After 1 hour at 25 ° C., a plastic fat composition having a characteristic that the SFC is 8.0% or less when placed at 25 ° C. for 24 hours has been hardly used.
These contents will be described in detail later in paragraph numbers [0042] and [0043].

また、本発明の可塑性油脂組成物は20℃で15時間放置した後の硬さが50g/cm〜2000g/cmであり、好ましくは70g/cm〜1800g/cmであり、更に好ましくは100g/cm〜1600g/cm、最も好ましくは250g/cm〜1400g/cmである。下限未満である場合、油脂原料以外を捏ね上げた生地に添加する場合、ミキサー内で生地が滑ってしまい油脂を練り込むことができなくなり好ましくない。液状油脂など一部下限未満の油脂組成物を他の原料と混合しミキシングを開始する方法も知られているが、原料を混合し捏ね始める段階において油脂組成物を添加するとグルテンの形成を妨げてしまう為、焼成品の食感が悪くなるなど品質が劣り好ましいとはいえない。硬さはレオメーターなどで測定することができ、測定例を挙げると一辺5cmの立方体にカットした可塑性油脂組成物を不動工業株式会社製レオメーターにて直径1cmの円形のプランジャーを用いてプランジャー進入速度毎分5cmにて最大応力を測定するなどして得ることができる。Also, plastic fat composition of the present invention is the hardness after 15 hours at 20 ℃ 50g / cm 2 ~2000g / cm 2, preferably 70g / cm 2 ~1800g / cm 2 , more preferably it is 100g / cm 2 ~1600g / cm 2 , most preferably from 250g / cm 2 ~1400g / cm 2 . When it is less than the lower limit, when it is added to a dough that has been pulverized except for the oil and fat raw material, the dough slips in the mixer and the fat cannot be kneaded, which is not preferable. It is also known to start mixing by mixing an oil composition such as a liquid oil that is less than the lower limit with other raw materials, but adding an oil composition at the stage where the raw materials are mixed and started kneading prevents the formation of gluten. Therefore, it cannot be said that the quality is inferior because the texture of the fired product is deteriorated. The hardness can be measured with a rheometer, and a measurement example is a plan in which a plastic fat composition cut into a cube with a side of 5 cm is used with a rheometer manufactured by Fudo Kogyo Co., Ltd. using a circular plunger with a diameter of 1 cm. The maximum stress can be obtained by measuring the maximum stress at 5 cm / min.

本発明の可塑性油脂組成物は油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCが8.0%以下であって、得られた油脂組成物の20℃で15時間放置した後の硬さが50g/cm〜2000g/cmであるという、膨化食品焼成後に油脂結晶が生成しづらく、かつ膨化食品製造時に最適な練り込み適性を有することが必要であり、両特性を同時に併せ持つことにより非常にソフトな膨化食品を得ることができることを見出した。従来、上記両特性を同時に併せ持つ可塑性油脂組成物は発明されていなかった。また、本発明の可塑性油脂組成物は膨化食品をソフトにするのに加え、口どけが良く、歯切れが良く、ネチャつきがない特徴も併せ持つ。The plastic fat composition of the present invention has an SFC of 8.0% or less when the oil phase is placed at 60 ° C. for 1 hour and then placed at 25 ° C. for 24 hours, and the obtained fat composition is 20 ° C. in that the hardness after 15 hours is 50g / cm 2 ~2000g / cm 2 , fat crystals difficult generated after puffed food baking, and is necessary to have a proper optimal kneaded at puffed food production It was found that a very soft puffed food can be obtained by having both characteristics at the same time. Conventionally, a plastic fat composition having both of the above properties has not been invented. In addition to softening the puffed food, the plastic oil / fat composition of the present invention also has the characteristics of good mouthfeel, crispness, and no stickiness.

本発明者らは更に、上記の膨化食品焼成後に油脂結晶が生成しづらく、かつ膨化食品製造時に最適な練り込み適性を併せ持つための最適な可塑性油脂組成物の構成として以下の発明に至った。   Furthermore, the present inventors have reached the following invention as an optimal plastic oil composition that is difficult to produce fat and oil crystals after baking the above-mentioned expanded food and also has the optimum kneading ability at the time of manufacturing the expanded food.

本発明の可塑性油脂組成物はSUS(Sはパルミチン酸、ステアリン酸から選ばれる1種類又は2種類である飽和脂肪酸、Uはオレイン酸、リノール酸、リノレン酸から選ばれるシス型不飽和脂肪酸)で表されるトリグリセリドとXUU又はUXU(Xは任意の脂肪酸)で表されるトリグリセリドとを主に含有することが好ましい。SUSトリグリセリドは可塑性油脂組成物製造時のような急冷条件下では結晶を生成しやすいが、パン焼成後のように室温にて徐々に冷却される場合には結晶を生成しにくい性質を有しており、ソフトなパンを製造する為に好適であることを本発明者らは見出した。   The plastic fat composition of the present invention is SUS (S is one or two saturated fatty acids selected from palmitic acid and stearic acid, U is a cis-type unsaturated fatty acid selected from oleic acid, linoleic acid, and linolenic acid). It is preferable to mainly contain the triglyceride represented and the triglyceride represented by XUU or UXU (X is an arbitrary fatty acid). SUS triglyceride tends to form crystals under rapid cooling conditions such as the production of plastic fat composition, but has a property that it is difficult to form crystals when it is gradually cooled at room temperature as in baking. The present inventors have found that it is suitable for producing soft bread.

XUU又はUXUで表されるトリグリセリドは常温では結晶を生成しづらい性質を有する為、SUSで表されるトリグリセリドと組み合わせることで適度な可塑性を付与することができ、また、パン焼成後のように室温にて徐々に冷却される場合においても結晶を生成しにくく、ソフトなパンを製造する為に好適であることを本発明者らは見出した。   Since triglyceride represented by XUU or UXU has a property that it is difficult to form crystals at room temperature, it can be imparted with appropriate plasticity by combining with triglyceride represented by SUS. The present inventors have found that it is difficult to produce crystals even in the case of being gradually cooled in order to produce a soft bread.

上記XUU又はUXUで表されるトリグリセリドにおいてXは任意の脂肪酸で構わないが、ステアリン酸、アラキン酸、ベヘン酸など炭素数が18以上の飽和脂肪酸である場合結晶を生成しやすくなるため炭素数16以下の飽和脂肪酸又は不飽和脂肪酸であることが好ましく、不飽和脂肪酸であることが最も好ましい。   In the triglyceride represented by the above XUU or UXU, X may be any fatty acid, but when it is a saturated fatty acid having 18 or more carbon atoms such as stearic acid, arachidic acid, behenic acid, etc., it is easy to produce crystals, so that the number of carbon atoms is 16 The following saturated fatty acids or unsaturated fatty acids are preferable, and unsaturated fatty acids are most preferable.

SUSで表されるトリグリセリドは可塑性油脂組成物を構成する油相中6〜50重量%含有することが好ましく、10〜46重量%含有することが更に好ましく、15〜42重量%含有することが最も好ましい。下限未満の場合は適度な練り込み性とパンをソフトにする効果とを両立させることが難しくなり好ましくない。上限を超える場合は可塑性油脂組成物が硬くなってしまい、20℃において好適な硬さを得られがたくなるため好ましくない。   The triglyceride represented by SUS is preferably contained in the oil phase constituting the plastic fat composition in an amount of 6 to 50% by weight, more preferably 10 to 46% by weight, most preferably 15 to 42% by weight. preferable. If it is less than the lower limit, it is difficult to achieve both an appropriate kneading property and an effect of softening bread, which is not preferable. When the upper limit is exceeded, the plastic fat composition becomes hard, and it is difficult to obtain a suitable hardness at 20 ° C., which is not preferable.

XUU又はUXUで表されるトリグリセライドが可塑性油脂組成物を構成する油相中36〜80重量%であることが好ましく、40〜75重量%であることが更に好ましい。下限未満である場合、上記温度処理により結晶が生成しやすくなり、パンが硬くなってしまい好ましくない。上限を超える場合は可塑性油脂組成物が軟らかくなり、20℃において好適な硬さを得られがたくなるため好ましくない。
XUU又はUXUで表わされるトリグリセリドを多く含有する油脂としては硬化をしていない常温で液体の性状を示す油脂が挙げられ、菜種油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油、パーム油分別低融点部、ラード分別低融点部、乳脂分別低融点部、ヤシ油分別低融点部、パーム核油分別低融点部、カカオ脂分別低融点部、サル脂分別低融点部、シア脂分別低融点部などが好ましく、菜種油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油が更に好ましく、中でも菜種油、大豆油、ヒマワリ種子油、コーン油、サフラワー油が好ましい。
The triglyceride represented by XUU or UXU is preferably 36 to 80% by weight, more preferably 40 to 75% by weight in the oil phase constituting the plastic fat composition. If it is less than the lower limit, the above-mentioned temperature treatment tends to produce crystals, and the bread becomes hard, which is not preferable. When exceeding the upper limit, the plastic fat composition becomes soft, and it is difficult to obtain a suitable hardness at 20 ° C., which is not preferable.
Examples of fats and oils containing a large amount of triglyceride represented by XUU or UXU include fats and oils that exhibit liquid properties at room temperature that are not hardened, rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil , Safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil fractionation low melting point, lard fractionation low melting point, milk fat fractionation low melting point, palm oil fractionation low melting point, palm kernel oil fractionation low melting point, cacao Preferred are oil fraction low melting point, monkey fat fraction low melting point, shea fat fraction low melting point, rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok Oil, sesame oil, and evening primrose oil are more preferable, and rapeseed oil, soybean oil, sunflower seed oil, corn oil, and safflower oil are particularly preferable.

本発明の可塑性油脂組成物は構成する脂肪酸が炭素数12以上の飽和脂肪酸及びトランス型不飽和脂肪酸から選ばれる1種類又は2種類以上であるトリグリセライドが可塑性油脂組成物を構成する油相中5重量%以下あることが好ましく、3重量%以下であることが更に好ましく、2重量%以下であることが最も好ましい。上限を超える場合、60℃で1時間置いた後、25℃にて24時間置いたときに結晶を生成し易くなるため、パンが硬くなってしまうため好ましくない。   The plastic fat composition of the present invention comprises 5 wt% in the oil phase of which the fatty acid constituting the triglyceride is one or more selected from saturated fatty acids having 12 or more carbon atoms and trans unsaturated fatty acids. % Or less, more preferably 3% by weight or less, and most preferably 2% by weight or less. When the upper limit is exceeded, it is not preferable because it becomes easy to produce crystals when placed at 25 ° C. for 24 hours after being placed at 60 ° C. for 1 hour, and the bread becomes hard.

本発明の可塑性油脂組成物は必要に応じて乳化剤を添加しても良いが、消費者の健康志向を考慮して添加しない方が好ましい。乳化剤としては蔗糖脂肪酸エステル、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステルおよび酢酸モノグリセリド、酒石酸モノグリセリド、酢酸酒石酸混合モノグリセリド、クエン酸モノグリセリド、ジアセチル酒石酸モノグリセリド、乳酸モノグリセリド、コハク酸モノグリセリド、リンゴ酸モノグリセリド等各種有機酸モノグリセリド、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、レシチンなどが挙げられる。   Although the emulsifier may be added to the plastic fat composition of the present invention as necessary, it is preferable not to add it in consideration of the health orientation of consumers. As the emulsifier, sucrose fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, propylene glycol fatty acid ester and acetic acid monoglyceride, tartaric acid monoglyceride, mixed monoglyceride of tartaric acid, Citric acid monoglyceride, diacetyltartaric acid monoglyceride, lactic acid monoglyceride, various organic acid monoglycerides such as malic acid monoglyceride, stearoyl calcium lactate, stearoyl sodium lactate, lecithin and the like.

本発明において、上記の原料、添加物の他に、所望により、色素、抗酸化剤、香料などの油溶性成分、食塩、糖類、粉乳、発酵乳などの水溶性成分を使用することができる。   In the present invention, in addition to the above-mentioned raw materials and additives, oil-soluble components such as pigments, antioxidants, and fragrances, and water-soluble components such as salt, saccharides, milk powder, and fermented milk can be used as desired.

本発明の可塑性油脂組成物の製造法については特に限定されないが、常法通り融解した油相に、必要に応じて水相を加え混合攪拌し、パーフェクター、ボテーター、コンビネーターなどで急冷捏和することにより製造することができる。油相のみの場合、作業性を改善するために窒素ガスなどの不活性ガスを入れて製造するのが一般的である。油相は油脂単独でもよいし、必要に応じて色素、抗酸化剤、香料等の油溶性成分を添加、溶解/分散させ調製することができる。水相は水又は温水に水溶性の乳成分、必要に応じて食塩、糖類、無機塩類等を添加、溶解/分散させ調製することができる。   The method for producing the plastic fat composition of the present invention is not particularly limited, but if necessary, an aqueous phase is added to the melted oil phase and mixed and stirred as necessary, and then quenched and quenched with a perfector, a bottor, a combinator, and the like. Can be manufactured. In the case of only the oil phase, it is common to produce an inert gas such as nitrogen gas in order to improve workability. The oil phase may be a single oil or fat, and may be prepared by adding and dissolving / dispersing oil-soluble components such as pigments, antioxidants, and fragrances as necessary. The aqueous phase can be prepared by adding and dissolving / dispersing a water-soluble milk component in water or warm water, and if necessary, sodium chloride, saccharides, inorganic salts and the like.

また、本発明で言う膨化食品とは主に、食パン、菓子パン、ロール類(テーブルロール、バターロール、バンズ等)、バラエティーブレッド(レーズンパン、胚芽パン等)、ブリオッシュ、イーストドーナツ、デニッシュペストリー、クロワッサン、パイ、蒸しパン(肉まん、餡まん等)などのパン類全般を指す。更に、本発明で用いる生地としては、小麦粉を主原料とし、これに必要に応じて、食塩等の調味料、卵、乳製品等の呈味成分、着香料、着色料、油脂類、糖類、イースト、イーストフード等の一種又は二種以上の原材料の必要量を適宜添加し、更に水と混合して得られる生地一般を意味する。本発明の可塑性油脂組成物は、これら生地へ練り込んで用いるのが好適であり、配合量はその使用目的に応じて適宜増減すればよい。前記生地の原材料の他、小麦以外の穀物、例えば、ライ麦、大麦、小麦胚芽、それらの加工品、更には、レーズンを初めとする果実、ナッツ類等を配合することも随意である。   In addition, the puffed food referred to in the present invention mainly includes bread, confectionery bread, rolls (table roll, butter roll, buns, etc.), variety bread (raisin bread, germ bread, etc.), brioche, yeast donut, Danish pastry, croissant. , General bread such as pie, steamed bread (meat buns, salmon buns, etc.). Furthermore, as the dough used in the present invention, flour is the main raw material, and seasoning ingredients such as salt, flavoring ingredients such as eggs and dairy products, flavoring agents, coloring agents, oils and fats, sugars, It means a general dough obtained by appropriately adding a necessary amount of one or more raw materials such as yeast and yeast food and further mixing with water. The plastic fat composition of the present invention is preferably kneaded into these doughs, and the blending amount may be appropriately increased or decreased depending on the purpose of use. In addition to the raw materials for the dough, grains other than wheat, for example, rye, barley, wheat germ, processed products thereof, and fruits such as raisins, nuts, etc. are optionally added.

以下に本発明の実施例を示し本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は、いずれも重量基準を意味する。
また、以下に示す実施例においてSUS含量、XUU・UXU含量はガスクロマトグラフィー、高速液体クロマトグラフィーを用い実測又は算出した。また、可塑性油脂組成物を20℃で15時間放置した後の硬さは一辺5cmの立方体にカットした可塑性油脂組成物を不動工業株式会社製レオメーターにて直径1cm又は直径3mmの円形のプランジャーを用いてプランジャー進入速度毎分5cmにて最大応力を測定、算出した。
EXAMPLES The present invention will be described in more detail with reference to the following examples, but the spirit of the present invention is not limited to the following examples. In the examples, “%” and “part” mean weight basis.
In the following examples, the SUS content and the XUU / UXU content were measured or calculated using gas chromatography and high performance liquid chromatography. Also, after the plastic fat composition was left at 20 ° C. for 15 hours, the hardness of the plastic fat composition cut into a cube having a side of 5 cm was a circular plunger having a diameter of 1 cm or a diameter of 3 mm using a rheometer manufactured by Fudo Kogyo Co., Ltd. Was used to measure and calculate the maximum stress at a plunger approach speed of 5 cm / min.

実験例1
高オレイン酸ヒマワリ油とステアリン酸エチルとを1,3特異性リパーゼを用いてエステル交換した後、分子蒸留にてエチルエステルを除去した油脂の分別中融点部(油脂Aとする)20部、パーム分別中融点部20部、菜種油60部を60℃にて混合攪拌し、コンビネーターにより急冷捏和し、実験例1の組織良好な可塑性油脂組成物を得た。なお、油脂AはSUSを80.2重量%、パーム分別中融点部はSUSを81.8重量%含有していた。
Experimental example 1
High-oleic sunflower oil and ethyl stearate were transesterified using 1,3-specific lipase, and then fractionated mid-melting point of oil / fat from which ethyl ester was removed by molecular distillation (referred to as oil / fat A), palm 20 parts of the fractional melting point and 60 parts of rapeseed oil were mixed and stirred at 60 ° C. and quenched and kneaded with a combinator to obtain a plastic oil composition having a good structure of Experimental Example 1. The fat and oil A contained 80.2% by weight of SUS, and the palm fractionation middle melting point part contained 81.8% by weight of SUS.

実験例1の可塑性油脂組成物に含有する油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCは0.8%であった。また、実験例1の可塑性油脂組成物を20℃で15時間放置した後の硬さは750g/cmであった。
実験例1の可塑性油脂組成物のトリグリセライド組成について、SUS(Sは飽和脂肪酸、Uはシス型不飽和脂肪酸)が32.3重量%であり、XUU又はUXU(Xは任意の脂肪酸)で表されるトリグリセリドは59.0重量%であった。
After placing the oil phase contained in the plastic fat composition of Experimental Example 1 at 60 ° C. for 1 hour, the SFC when placed at 25 ° C. for 24 hours was 0.8%. Moreover, the hardness after leaving the plastic fat composition of Experimental Example 1 at 20 ° C. for 15 hours was 750 g / cm 2 .
Regarding the triglyceride composition of the plastic fat composition of Experimental Example 1, SUS (S is a saturated fatty acid, U is a cis-type unsaturated fatty acid) is 32.3% by weight, and is represented by XUU or UXU (X is an arbitrary fatty acid). The triglyceride content was 59.0% by weight.

比較実験例1
油脂A40部、パーム分別中融点部40部、菜種油20部を60℃にて混合攪拌し、コンビネーターにより急冷捏和し、比較実験例1の組織良好な可塑性油脂組成物を得た。
Comparative Experiment Example 1
40 parts of fat / oil A, 40 parts of palm fractionation melting point part, and 20 parts of rapeseed oil were mixed and stirred at 60 ° C. and rapidly cooled and kneaded with a combinator to obtain a plastic fat composition having a good structure of Comparative Experimental Example 1.

比較実験例1の可塑性油脂組成物に含有する油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCは7.6%であった。また、比較実験例1の可塑性油脂組成物を20℃で15時間放置した後の硬さは8150g/cmであった。
比較実験例1の可塑性油脂組成物のトリグリセライド組成について、SUS(Sは飽和脂肪酸、Uはシス型不飽和脂肪酸)が65.0重量%であり、XUU又はUXU(Xは任意の脂肪酸)で表されるトリグリセリドは24.4重量%であった。
The SFC was 7.6% when the oil phase contained in the plastic fat composition of Comparative Experimental Example 1 was placed at 60 ° C. for 1 hour and then placed at 25 ° C. for 24 hours. Moreover, the hardness after leaving the plastic fat composition of Comparative Experimental Example 1 at 20 ° C. for 15 hours was 8150 g / cm 2 .
About the triglyceride composition of the plastic fat composition of Comparative Experimental Example 1, SUS (S is a saturated fatty acid, U is a cis-type unsaturated fatty acid) is 65.0% by weight, and is represented by XUU or UXU (X is an arbitrary fatty acid). The triglyceride content was 24.4% by weight.

比較実験例2
硬化菜種油(上昇融点35℃)80部、菜種油20部を60℃にて混合攪拌し、コンビネーターにより急冷捏和し、比較実験例2の組織良好な可塑性油脂組成物を得た。
Comparative Experiment Example 2
80 parts of hardened rapeseed oil (increased melting point: 35 ° C.) and 20 parts of rapeseed oil were mixed and stirred at 60 ° C., and rapidly cooled and kneaded with a combinator to obtain a plastic oil composition with good structure of Comparative Experimental Example 2.

比較実験例2の可塑性油脂組成物に含有する油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCは15.9%であった。また、比較実験例2の可塑性油脂組成物を20℃で15時間放置した後の硬さは700g/cmであった。
比較実験例2の可塑性油脂組成物のトリグリセライド組成について、SUS(Sは飽和脂肪酸、Uはシス型不飽和脂肪酸)が0.2重量%であり、XUU又はUXU(Xは任意の脂肪酸)で表されるトリグリセリドは45.1重量%であった。
After placing the oil phase contained in the plastic fat composition of Comparative Experimental Example 2 at 60 ° C. for 1 hour, the SFC when placed at 25 ° C. for 24 hours was 15.9%. Moreover, the hardness after leaving the plastic fat composition of Comparative Experimental Example 2 at 20 ° C. for 15 hours was 700 g / cm 2 .
About the triglyceride composition of the plastic fat composition of Comparative Experimental Example 2, SUS (S is a saturated fatty acid, U is a cis-type unsaturated fatty acid) is 0.2% by weight, and is represented by XUU or UXU (X is an arbitrary fatty acid). The resulting triglyceride was 45.1% by weight.

比較実験例3
硬化菜種油(上昇融点35℃)40部、菜種油60部を60℃にて混合攪拌し、コンビネーターにより急冷捏和し、比較実験例3の組織良好な可塑性油脂組成物を得た。
Comparative Experiment Example 3
40 parts of hardened rapeseed oil (increased melting point: 35 ° C.) and 60 parts of rapeseed oil were mixed and stirred at 60 ° C., and rapidly cooled and kneaded with a combinator to obtain a plastic oil composition with good structure of Comparative Experimental Example 3.

比較実験例3の可塑性油脂組成物に含有する油脂を60℃で1時間置いた後、25℃にて24時間置いたときのSFCは1.4%であった。また、比較実験例3の可塑性油脂組成物を20℃で15時間放置した後の硬さは40g/cmであった。
比較実験例3の可塑性油脂組成物のトリグリセライド組成について、SUS(Sは飽和脂肪酸、Uはシス型不飽和脂肪酸)が0.1重量%であり、XUU又はUXU(Xは任意の脂肪酸)で表されるトリグリセリドは71.8重量%であった。
After placing the fats and oils contained in the plastic fat composition of Comparative Experimental Example 3 at 60 ° C. for 1 hour, the SFC when placed at 25 ° C. for 24 hours was 1.4%. Moreover, the hardness after leaving the plastic fat composition of Comparative Experimental Example 3 at 20 ° C. for 15 hours was 40 g / cm 2 .
About the triglyceride composition of the plastic fat composition of Comparative Experimental Example 3, SUS (S is a saturated fatty acid, U is a cis-type unsaturated fatty acid) is 0.1% by weight, and is represented by XUU or UXU (X is an arbitrary fatty acid). The triglyceride content was 71.8% by weight.

表1に実験例1、比較実験例1、比較実験例2、比較実験例3の配合と結果を纏めた。

Figure 0005119922
Table 1 summarizes the formulations and results of Experimental Example 1, Comparative Experimental Example 1, Comparative Experimental Example 2, and Comparative Experimental Example 3.
Figure 0005119922

次に実験例1、比較実験例1、比較実験例2、比較実験例3の可塑性油脂組成物を使用し、表2の配合、表3の製造条件でコッペパンを焼成し、練り込み性、焼成品のボリューム、内層、焼成1日後の食感についてソフトさ、口融け、歯切れ感、ネチャつきの評価を行った。また、得られた焼成品についてインストロン万能材料試験機(インストロン・ジャパン株式会社製)の圧縮試験により1日後の硬さを測定した。測定には直径35mmのプランジャーを用い、圧縮速度30mm/分で試料を上から圧縮し、30%圧縮時の荷重を測定した。

Figure 0005119922

Figure 0005119922
Next, using the plastic fat composition of Experimental Example 1, Comparative Experimental Example 1, Comparative Experimental Example 2, and Comparative Experimental Example 3, the bread rolls were baked under the formulation shown in Table 2 and the manufacturing conditions shown in Table 3, and kneaded. The product volume, inner layer, and texture after baking were evaluated for softness, melted mouth, crispness, and stickiness. Moreover, the hardness after one day was measured by the compression test of the Instron universal material testing machine (made by Instron Japan Co., Ltd.) about the obtained baked product. A 35 mm diameter plunger was used for measurement, the sample was compressed from above at a compression rate of 30 mm / min, and the load at 30% compression was measured.
Figure 0005119922

Figure 0005119922

実施例1
表2の実施例1の配合において、実験例1の可塑性油脂組成物以外の原料を練り上げ、実験例1の可塑性油脂組成物を添加し更に練り上げた。28℃、湿度75%の庫内にて60分間発酵させた後、75gずつに分割し、15分間ベンチタイムをとった。コッペ状に成形し、38℃、湿度80%の庫内で60分間発酵させた後、上火220℃、下火190℃のオーブンで12分間焼成し実施例1のコッペパンを得た。評価としては良好な練り込み性であり、焼成品のボリューム、内層とも良好であった。食感焼成品のボリューム、内層とも良好であった。焼成品の1日後の食感について、非常にソフトであり、口融け、歯切れ感良好で、ネチャつきもなく良好であった。焼成品の1日後の硬さは134.9gfであった。これらの結果を表4に纏めた。
Example 1
In the formulation of Example 1 in Table 2, raw materials other than the plastic fat composition of Experimental Example 1 were kneaded, and the plastic fat composition of Experimental Example 1 was added and further kneaded. After fermentation for 60 minutes in a chamber at 28 ° C. and 75% humidity, the mixture was divided into 75 g portions and bench time was taken for 15 minutes. After forming into a cupe shape and fermenting for 60 minutes in a chamber at 38 ° C. and 80% humidity, it was baked in an oven at 220 ° C. and 190 ° C. for 12 minutes to obtain a cupe bread of Example 1. Evaluation was good kneading property, and both the volume and the inner layer of the fired product were good. The volume and inner layer of the textured fired product were good. The texture after 1 day of the baked product was very soft, melted in the mouth, had a good crispness, and had no stickiness. The hardness after 1 day of the fired product was 134.9 gf. These results are summarized in Table 4.

比較例1
表2の比較例1の配合において、実施例1と同様な処理を行なった。評価としては練り込み時、可塑性油脂組成物が硬く生地中に均一に分散せず、練り込み性が不良であった。焼成品のボリュームはやや不良で、内層は不均一で不良であった。焼成品の1日後の食感としては硬くソフト感は不良であった。口融けは良好であったものの、歯切れ感はやや不良であり、ネチャつきが見られ不良であった。焼成品1日後の硬さは173.3gfであった。これらの結果を表4に纏めた。
Comparative Example 1
In the formulation of Comparative Example 1 in Table 2, the same treatment as in Example 1 was performed. As an evaluation, at the time of kneading, the plastic fat composition was hard and not uniformly dispersed in the dough, and the kneading property was poor. The volume of the fired product was slightly poor, and the inner layer was uneven and defective. The texture after 1 day of the fired product was hard and soft. Although the melting of the mouth was good, the crispness was slightly poor, and there was a sticky appearance and was poor. The hardness after 1 day of the baked product was 173.3 gf. These results are summarized in Table 4.

比較例2
表2の比較例2の配合において、実施例1と同様な処理を行なった。評価としては良好な練り込み性であり、焼成品の浮き、内層とも良好であったが、焼成品の1日後の食感として実施例1に比べ硬く、ソフト感は不良であった。口融け、歯切れ感、ネチャつきともやや不良であった。焼成品1日後の硬さは161.1gfであった。これらの結果を表4に纏めた。
Comparative Example 2
In the formulation of Comparative Example 2 in Table 2, the same treatment as in Example 1 was performed. Evaluation was good kneading properties, and the baked product floated and the inner layer was good, but the texture after 1 day of the baked product was harder than Example 1 and the soft feeling was poor. Mouth melting, crispness, and stickiness were somewhat poor. The hardness after one day of the baked product was 161.1 gf. These results are summarized in Table 4.

比較例3
表2の比較例3の配合において、実施例1と同様な処理を行なった。評価としては練り込み時、可塑性油脂組成物が軟らかすぎ、ミキサー内で生地が滑り均一に練り込むことができず、練り込み性が不良であった。焼成品の浮きは悪く、内層も不均一で不良であった。焼成品の1日後の食感として実施例1に比べ硬く、ソフト感は不良であった。口融け、歯切れ感はやや不良で、ネチャつきがみられ不良であった。焼成品1日後の硬さは172.9gfであった。これらの結果を表4に纏めた。

Figure 0005119922
Comparative Example 3
In the formulation of Comparative Example 3 in Table 2, the same treatment as in Example 1 was performed. As an evaluation, at the time of kneading, the plastic fat composition was too soft, the dough could not be kneaded uniformly in the mixer, and the kneading property was poor. The fired product was poorly floated, and the inner layer was uneven and defective. The texture after 1 day of the fired product was harder than that of Example 1 and the soft feeling was poor. The mouth melted and the crispness was slightly poor, with a sticky appearance and poor. The hardness after 1 day of the baked product was 172.9 gf. These results are summarized in Table 4.
Figure 0005119922

本発明の概念を簡潔に表5にまとめた。従来技術では比較実験例2のように可塑性油脂組成物を20℃で15時間放置した後の硬さが大きい場合、可塑性油脂組成物を構成する油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCは高くなった。 すなわち、可塑性油脂組成物に適度な練り込み性を付与した場合、焼成1日後には油脂の結晶化が起こりパンがソフトになりにくかった。また、比較実験例3のように可塑性油脂組成物を構成する油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCが低い場合、可塑性油脂組成物を20℃で15時間放置した後の硬さが小さくなった。すなわち、可塑性油脂組成物が焼成1日後に油脂の結晶化を起こさない場合、可塑性油脂組成物は軟らかくなりすぎ、適度な練り込み性を得ることができなかった。   The concept of the present invention is briefly summarized in Table 5. In the prior art, as in Comparative Experimental Example 2, when the hardness of the plastic fat composition after standing at 20 ° C. for 15 hours is large, the oil phase constituting the plastic fat composition is left at 60 ° C. for 1 hour, and then 25 The SFC was higher when placed at 24 ° C. for 24 hours. That is, when an appropriate kneading property was imparted to the plastic fat composition, the fat was crystallized one day after baking, and the bread was not easily softened. Further, when the oil phase constituting the plastic fat composition as in Comparative Experimental Example 3 was placed at 60 ° C. for 1 hour and then SFC when placed at 25 ° C. for 24 hours was low, the plastic fat composition was placed at 20 ° C. The hardness decreased after being left for 15 hours. That is, when the plastic fat composition does not cause crystallization of the fat after one day of baking, the plastic fat composition becomes too soft and an appropriate kneading property cannot be obtained.

本発明の可塑性油脂組成物のように可塑性油脂組成物を20℃で15時間放置した後の硬さが大きく、且つ可塑性油脂組成物を構成する油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCは低いという従来技術では成し得なかった相反する性質を持たせることにより最適な練り込み性を持ちながら焼成1日後に結晶を生成しづらく、従来になく非常にソフトな焼成品を得ることができた。

Figure 0005119922
After the plastic oil / fat composition is left to stand at 20 ° C. for 15 hours like the plastic oil / fat composition of the present invention, the hardness of the plastic oil / fat composition is large, and the oil phase constituting the plastic oil / fat composition is left at 60 ° C. for 1 hour, then 25 It is difficult to produce crystals after one day of firing while having the best kneading property by giving the contradictory properties that could not be achieved by the conventional technology that SFC when kept at ℃ for 24 hours is low. A very soft fired product could be obtained.
Figure 0005119922

本発明は可塑性油脂組成物に関し、更に詳しくは従来になく非常にソフトなパンなどの膨化食品を製造するに適した可塑性油脂組成物及びそれを使用してなる膨化食品に関するものである。   The present invention relates to a plastic fat composition, and more particularly, to a plastic fat composition suitable for producing a puffed food such as bread that is extremely soft and unprecedented, and a puffed food using the same.

Claims (7)

小麦粉生地と共に使用する油脂組成物であって、油相中にSUSで表されるトリグリセリドとXUU又はUXU(Xは任意の脂肪酸)で表されるトリグリセリドを主に含有し、SUSで表されるトリグリセリドが(Sはパルミチン酸、ステアリン酸から選ばれる1種類又は2種類である飽和脂肪酸、Uはオレイン酸、リノール酸、リノレン酸から選ばれるシス型不飽和脂肪酸)であり、XUU又はUXU(Xは任意の脂肪酸)で表されるトリグリセリドが菜種油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油、パーム油分別低融点部、ラード分別低融点部、乳脂分別低融点部、ヤシ油分別低融点部、パーム核油分別低融点部、カカオ脂分別低融点部、サル脂分別低融点部及びシア脂分別低融点部由来であり、SUSで表されるトリグリセリドが油相中6〜50重量%であり、XUU又はUXUで表されるトリグリセライドが油相中36〜80重量%であって、油相を60℃で1時間置いた後、25℃にて24時間置いたときのSFCが2.0%以下であって、得られた油脂組成物の20℃で15時間放置した後の硬さが50g/cm〜2000g/cmであり、当該油脂組成物は小麦粉100部に対して3〜25部を小麦粉生地に練り込む使用である、練り込み用可塑性油脂組成物。Oil and fat composition used together with wheat flour dough, comprising mainly triglyceride represented by SUS and triglyceride represented by XUU or UXU (X is an arbitrary fatty acid) in the oil phase, and represented by SUS (S is one or two saturated fatty acids selected from palmitic acid and stearic acid, U is a cis-type unsaturated fatty acid selected from oleic acid, linoleic acid, and linolenic acid), and XUU or UXU (X is The triglyceride represented by any fatty acid is rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil fractionation low melting point , Lard fractionation low melting point, milk fat fractionation low melting point, coconut oil fractionation low melting point, palm kernel oil fractionation low melting point, cocoa butter fractionation low melting point, monkey fat fraction The low melting point part and the shea fat fractionation low melting point part are derived, the triglyceride represented by SUS is 6 to 50% by weight in the oil phase, and the triglyceride represented by XUU or UXU is 36 to 80% by weight in the oil phase. Then, after placing the oil phase at 60 ° C. for 1 hour, the SFC when it was placed at 25 ° C. for 24 hours was 2.0% or less, and the obtained fat composition was allowed to stand at 20 ° C. for 15 hours. after hardness is 50g / cm 2 ~2000g / cm 2 , the oil composition is used for kneading 3-25 parts per 100 parts of flour wheat dough, kneading for plastic fat composition. SUSで表されるトリグリセリドが油相中15〜42重量%である、請求項1記載の練り込み用可塑性油脂組成物。The plastic fat composition for kneading according to claim 1, wherein the triglyceride represented by SUS is 15 to 42% by weight in the oil phase. XUU又はUXUで表されるトリグリセライドが油相中40〜75重量%である、請求項1記載の練り込み用可塑性油脂組成物。The plastic fat composition for kneading according to claim 1, wherein the triglyceride represented by XUU or UXU is 40 to 75% by weight in the oil phase. 得られた油脂組成物の20℃で15時間放置した後の硬さが70g/cm〜1800g/cmである、請求項1記載の練り込み用可塑性油脂組成物。Hardness after 15 hours at 20 ° C. The resulting fat composition is 70g / cm 2 ~1800g / cm 2 , claim 1 kneading for plastic fat composition. XUU又はUXUで表されるトリグリセリドにおいてXが炭素数16以下の飽和脂肪酸又は不飽和脂肪酸である、請求項1記載の練り込み用可塑性油脂組成物。The plastic fat composition for kneading according to claim 1, wherein in the triglyceride represented by XUU or UXU, X is a saturated fatty acid or unsaturated fatty acid having 16 or less carbon atoms. 構成する脂肪酸が炭素数12以上の飽和脂肪酸及びトランス型不飽和脂肪酸から選ばれる1種類又は2種類以上であるトリグリセライドが可塑性油脂組成物を構成する油相中5重量%以下である、請求項1乃至請求項5の何れか1項に記載の練り込み用可塑性油脂組成物。The triglyceride whose fatty acid is one or two or more selected from saturated fatty acids having 12 or more carbon atoms and trans unsaturated fatty acids is 5% by weight or less in the oil phase constituting the plastic fat composition. The plastic fat composition for kneading according to any one of claims 5 to 5. 請求項1乃至請求項6の何れか1項に記載の練り込み用可塑性油脂組成物を使用してなる膨化食品。The puffed food formed using the plastic fat composition for kneading according to any one of claims 1 to 6.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995007620A1 (en) * 1993-09-14 1995-03-23 Unilever N.V. Natural triglyceride fats
WO2003071876A1 (en) * 2002-02-28 2003-09-04 Unilever N.V. Triglyceride fat suitable for spread manufacture
JP2004121114A (en) * 2002-10-03 2004-04-22 Fuji Oil Co Ltd Oil and fat for kneading into bread and method for producing the same
JP2004513658A (en) * 2000-11-21 2004-05-13 ユニリーバー・ナームローゼ・ベンノートシヤープ Edible spread with natural fat phase
JP2004204067A (en) * 2002-12-25 2004-07-22 Asahi Denka Kogyo Kk Plastic oil and fat composition

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3418029B2 (en) * 1995-01-23 2003-06-16 鐘淵化学工業株式会社 Fat composition and method for producing bread using the same
JPH10248480A (en) * 1997-03-18 1998-09-22 Fuji Oil Co Ltd Fat composition for bread
JP4268749B2 (en) * 2000-11-17 2009-05-27 植田製油株式会社 Water-in-oil emulsified fat composition
JP2003000136A (en) * 2001-06-25 2003-01-07 Asahi Denka Kogyo Kk Puff-improving agent and oil and fat composition for roll-in
JP5170930B2 (en) * 2001-11-15 2013-03-27 株式会社Adeka Bread dough and bread
JP4514378B2 (en) * 2001-12-06 2010-07-28 株式会社Adeka Oil composition for baked confectionery
JP4155743B2 (en) * 2002-01-25 2008-09-24 株式会社Adeka Oil composition for roll-in
JP2004305048A (en) * 2003-04-03 2004-11-04 Asahi Denka Kogyo Kk Oil-and-fat composition for being kneaded into pastry

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995007620A1 (en) * 1993-09-14 1995-03-23 Unilever N.V. Natural triglyceride fats
JP2004513658A (en) * 2000-11-21 2004-05-13 ユニリーバー・ナームローゼ・ベンノートシヤープ Edible spread with natural fat phase
WO2003071876A1 (en) * 2002-02-28 2003-09-04 Unilever N.V. Triglyceride fat suitable for spread manufacture
JP2004121114A (en) * 2002-10-03 2004-04-22 Fuji Oil Co Ltd Oil and fat for kneading into bread and method for producing the same
JP2004204067A (en) * 2002-12-25 2004-07-22 Asahi Denka Kogyo Kk Plastic oil and fat composition

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
JPN6011062873; JAOCS Vol.62, No.2, 1985, pp.376-385 *
JPN6011062874; Food Research International Vol.42, 2009, pp.1153-1162 *
JPN7011004340; VEGETABLE OILS IN FOOD TECHNOLOGY: Composition, Properties and Uses , 2002, 第62頁 *
JPN7011004341; 油脂・油糧ハンドブック 第230-239頁, 1988 *
JPN7011004342; CONFECTIONERY FATS HANDBOOK , 2003, 第176頁 *
JPN7012002040; 無類井健夫・庄下順子: '植物油のトリアシルグリセリン組成の分析と油脂の配合推定への応用' 日本油脂化学会誌 第45巻第1号, 1996, pp.29-36 *

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