JP6375324B2 - 植物部位からバイオモルフィックシリカのナノ粒子を得る方法であって、前記植物部位はその高含有量によって特徴付けられる方法。 - Google Patents
植物部位からバイオモルフィックシリカのナノ粒子を得る方法であって、前記植物部位はその高含有量によって特徴付けられる方法。 Download PDFInfo
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- JP6375324B2 JP6375324B2 JP2016027327A JP2016027327A JP6375324B2 JP 6375324 B2 JP6375324 B2 JP 6375324B2 JP 2016027327 A JP2016027327 A JP 2016027327A JP 2016027327 A JP2016027327 A JP 2016027327A JP 6375324 B2 JP6375324 B2 JP 6375324B2
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- Prior art keywords
- silica
- biomorphic
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- nanoparticles
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- 239000000377 silicon dioxide Substances 0.000 title claims description 57
- 238000000034 method Methods 0.000 title claims description 46
- 239000002105 nanoparticle Substances 0.000 title claims description 25
- 241000196324 Embryophyta Species 0.000 claims description 51
- 230000008569 process Effects 0.000 claims description 30
- 238000000354 decomposition reaction Methods 0.000 claims description 21
- 150000002500 ions Chemical class 0.000 claims description 17
- 235000007164 Oryza sativa Nutrition 0.000 claims description 16
- 235000009566 rice Nutrition 0.000 claims description 15
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 229910017604 nitric acid Inorganic materials 0.000 claims description 14
- 239000012074 organic phase Substances 0.000 claims description 14
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 11
- 230000002441 reversible effect Effects 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 239000011777 magnesium Substances 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000011591 potassium Substances 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 230000002829 reductive effect Effects 0.000 claims description 5
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- 210000005069 ears Anatomy 0.000 claims description 4
- 240000007594 Oryza sativa Species 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 241000195955 Equisetum hyemale Species 0.000 claims description 2
- -1 rice husks Chemical compound 0.000 claims description 2
- 240000005979 Hordeum vulgare Species 0.000 claims 1
- 235000007340 Hordeum vulgare Nutrition 0.000 claims 1
- 239000010902 straw Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 description 15
- 241000209094 Oryza Species 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- 238000005336 cracking Methods 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
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- 238000002485 combustion reaction Methods 0.000 description 4
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- 239000000047 product Substances 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229920002488 Hemicellulose Polymers 0.000 description 3
- 239000007857 degradation product Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000007385 chemical modification Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000758993 Equisetidae Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910002656 O–Si–O Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000000035 biogenic effect Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
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- 238000001035 drying Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000009993 protective function Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Silicon Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CZ2015-210A CZ305968B6 (cs) | 2015-03-26 | 2015-03-26 | Metoda získávání nanočástic biomorfního oxidu křemičitého z rostlinných částí charakteristických jeho vysokým obsahem |
| CZPV2015-210 | 2015-03-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2016183092A JP2016183092A (ja) | 2016-10-20 |
| JP6375324B2 true JP6375324B2 (ja) | 2018-08-15 |
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| Application Number | Title | Priority Date | Filing Date |
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| JP2016027327A Expired - Fee Related JP6375324B2 (ja) | 2015-03-26 | 2016-02-16 | 植物部位からバイオモルフィックシリカのナノ粒子を得る方法であって、前記植物部位はその高含有量によって特徴付けられる方法。 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP6375324B2 (cs) |
| CZ (1) | CZ305968B6 (cs) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2688090B2 (es) * | 2017-03-29 | 2019-07-22 | Univ Cordoba | Procedimiento para la obtencion de biosilice a partir de cascara de arroz |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4214920A (en) * | 1979-03-23 | 1980-07-29 | Exxon Research & Engineering Co. | Method for producing solar cell-grade silicon from rice hulls |
| CN1027440C (zh) * | 1992-01-25 | 1995-01-18 | 交通部公路科学研究所 | 从稻壳内提取高纯度二氧化硅的方法 |
| KR100414888B1 (ko) * | 2000-02-09 | 2004-01-13 | 알케이케미칼 주식회사 | 쌀겨로부터 실리카를 추출하는 방법 |
| RU2191159C1 (ru) * | 2001-05-25 | 2002-10-20 | Хачатуров Николай Артемович | Способ получения ультрадисперсного аморфного или нанокристаллического диоксида кремния |
| GB0800193D0 (en) * | 2008-01-05 | 2008-02-13 | Univ York | Biorefinery products in structural materials |
| CN101973554B (zh) * | 2010-09-16 | 2012-10-31 | 昆明理工大学 | 一种制备介孔二氧化硅材料的方法 |
| WO2012148561A2 (en) * | 2011-02-28 | 2012-11-01 | Texas State University - San Marcos | Silica nanoaggregates and organosilicon complexes and methods of forming them from biomass materials |
-
2015
- 2015-03-26 CZ CZ2015-210A patent/CZ305968B6/cs not_active IP Right Cessation
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2016
- 2016-02-16 JP JP2016027327A patent/JP6375324B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CZ2015210A3 (cs) | 2016-05-25 |
| CZ305968B6 (cs) | 2016-05-25 |
| JP2016183092A (ja) | 2016-10-20 |
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