JP6359140B2 - Membrane module - Google Patents

Description

  The present invention relates to a membrane module provided with a hollow fiber membrane.

  A hollow fiber membrane is known as a membrane used in a membrane filtration method using a microfiltration membrane or an ultrafiltration membrane. Membrane modules using hollow fiber membranes are widely used for various membrane separation applications because they have a large membrane area and can be downsized. As this type of membrane module, one having a hollow fiber membrane bundle composed of a plurality of hollow fiber membranes whose both ends are fixed by a resin portion is known.

  By the way, in such a membrane module, the surface of the hollow fiber membrane may be damaged during the filtration operation or for other reasons to cause leakage of the liquid to be treated. When the leak occurs, sufficient filtration performance is not exhibited, and the turbidity of the processing liquid increases.

  As a repair when a leak occurs, for example, a technique is known in which after inserting the tip of a wax rod into the end opening of a hollow fiber membrane, the wax rod is broken to seal the end opening ( For example, see Patent Document 1).

JP-A-61-407

  However, since the end of the hollow fiber membrane is fixed to the resin portion in a randomly curved state, the conventional wax rod cannot follow this curve and is inserted into the end opening of the hollow fiber membrane. At this time, the end opening of the hollow fiber membrane could not be sufficiently sealed because it was broken in the middle.

  This invention is made | formed in view of such a subject, and it aims at providing the membrane module which can seal the hollow fiber membrane which the leak generate | occur | produced reliably.

  The present invention is a membrane module comprising a hollow fiber membrane bundle composed of a plurality of hollow fiber membranes and a resin part for fixing the hollow fiber membrane bundle at an end, wherein at least one end of the hollow fiber membrane is opened at the resin part. The hollow fiber membrane is provided with an opening sealing member made of a resin having a rod shape and inserted into the opening of the hollow fiber membrane, and the hollow fiber membrane has a resin portion partially or entirely in the film thickness direction. The constituent resin is infiltrated and cured, and the opening sealing member has one end whose outer diameter is smaller than the inner diameter of the opening and the other end opposite to the one end, and from one end side to the other end side. The outer diameter is enlarged, and the opening sealing member is deformed and contacts the inner peripheral surface of the opening to seal the opening.

  Since the rod-shaped opening sealing member has an outer diameter at one end smaller than the inner diameter of the opening of the hollow fiber membrane, it is easy to insert the one end into the opening of the hollow fiber membrane. Moreover, since the outer diameter of the opening sealing member increases from one end side to the other end side as it is inserted from one end, the portion that matches the inner diameter of the opening just contacts the inner peripheral surface of the opening. The opening can be sealed. Furthermore, since the opening sealing member is made of a resin having flexibility, for example, even when the hollow fiber membrane is fixed to the resin portion in a curved state, the opening sealing member is deformed following the curve, The opening can be reliably sealed.

  The present invention is a membrane module comprising a hollow fiber membrane bundle composed of a plurality of hollow fiber membranes and a resin part for fixing the hollow fiber membrane bundle at an end, wherein at least one end of the hollow fiber membrane is opened at the resin part. The hollow fiber membrane is provided with an opening sealing member made of a resin having a rod shape and inserted into the opening of the hollow fiber membrane, and the hollow fiber membrane has a resin portion partially or entirely in the film thickness direction. The constituent resin is infiltrated and cured, and the opening sealing member has one end whose outer diameter is smaller than the inner diameter of the opening and the other end opposite to the one end, and from one end side to the other end side. The outer diameter is enlarged, and the opening sealing member is softer than the hardened hollow fiber membrane, and abuts against the inner peripheral surface of the opening to seal the opening.

  Since the rod-shaped opening sealing member has an outer diameter at one end smaller than the inner diameter of the opening of the hollow fiber membrane, it is easy to insert the one end into the opening of the hollow fiber membrane. Moreover, since the outer diameter of the opening sealing member increases from one end side to the other end side as it is inserted from one end, the portion that matches the inner diameter of the opening just contacts the inner peripheral surface of the opening. The opening can be sealed. Furthermore, since the opening sealing member is made of a flexible resin and is softer than the cured hollow fiber membrane, for example, the case where the hollow fiber membrane is fixed to the resin portion in a curved state. However, it can be deformed following this curve, and the opening can be reliably sealed.

  Further, in the above opening sealing member, the tapered portion may have a circular cross section perpendicular to the longitudinal direction.

  Furthermore, the outer diameter of the end portion on one end side of the opening sealing member is 20% or more and 95% or less with respect to the inner diameter of the opening, and the outer diameter of the end portion on the other end side is relative to the inner diameter of the opening. It may be 110% or more and 300% or less.

  Further, in the above opening sealing member, the outer diameter from one end to a position of at least 5 to 60 mm may be smaller than the inner diameter of the opening.

  Furthermore, 50-300 degreeC may be sufficient as melting | fusing point of resin used for an opening sealing member. In addition, melting | fusing point of resin may be measured according to prescription | regulation of JISK0064: 1992.

  Furthermore, 100-2000 MPa may be sufficient as the bending elastic modulus of resin used for an opening sealing member. Note that the flexural modulus of the resin may be measured in accordance with JIS K7171.

  Further, the durometer type D hardness of the resin used for the opening sealing member may be 15 to 90D. The durometer type D hardness of the resin may be measured in accordance with JIS K7215: 1986.

Further, the Charpy impact strength of the resin used for the opening sealing member may be 1 to 30 kJ / m ² at 23 ° C. In addition, the Charpy impact strength of the resin may be measured in accordance with JIS K7111-1: 2006.

Further, the density of the resin used for the opening sealing member may be 0.8 to 2.2 g / cm ³ . The resin density may be measured in accordance with JIS K7112: 1999.

  Further, the resin used for the opening sealing member may be polyethylene.

  Further, the resin used for the opening sealing member may be low density polyethylene.

  Furthermore, the resin used for the opening sealing member may be high-density polyethylene.

  Further, the resin used for the opening sealing member may be polypropylene.

  Further, the resin used for the opening sealing member may be ultra high molecular weight polyethylene.

  According to the present invention, a hollow fiber membrane in which a leak has occurred can be reliably sealed.

It is a longitudinal cross-sectional view which shows typically the membrane module which concerns on embodiment. It is an end view of a membrane module. It is the top view and sectional view which show the opening sealing member which concerns on embodiment. It is a longitudinal cross-sectional view which expands and shows the edge part of the membrane module of FIG. It is sectional drawing along the VV line of the membrane module shown in FIG. It is sectional drawing for demonstrating the repair method of the membrane module which concerns on embodiment. It is a top view which shows the modification of an opening sealing member.

  Preferred embodiments of the present invention will be described below with reference to the drawings.

  The membrane module 1 (refer FIG. 1) which concerns on this embodiment is utilized in various fields, such as water and sewage, food industry, general industry, medical treatment, and chemistry.

  As shown in FIGS. 1 and 2, the membrane module 1 according to this embodiment includes a hollow fiber membrane bundle 3 composed of a plurality of hollow fiber membranes 2 and a plurality of hollow fiber membranes at both ends of the hollow fiber membrane bundle 3. A potting material (resin part) 4 for fixing the two members together, and a cylindrical casing 5 for housing the hollow fiber membrane bundle 3 are provided. In the membrane module 1, caps 6 for connecting pipes can be attached to both ends of the casing 5 by nuts 7, respectively. By tightening the nut 7, the portions are sealed by the O-ring 8 disposed in the groove of the cap 6. The membrane module 1 is vertically symmetric and has the same structure at both ends. Components having the same structure are denoted by the same reference numerals, and description thereof will be omitted as appropriate.

  Both ends of the hollow fiber membrane 2 are opened in the potting material 4. That is, at both ends of the hollow fiber membrane 2, the potting material 4 is not in contact with the end surface of the hollow fiber membrane 2, and the potting material 4 is in contact with the outer peripheral surface of the hollow fiber membrane 2. Therefore, the opening P of the hollow fiber membrane 2 is in an exposed state avoiding the potting material 4. An opening sealing member 10 is inserted into the openings P of some of the hollow fiber membranes 2 (details will be described later). In FIG. 2, the opening P into which the opening sealing member 10 is inserted is indicated by a black circle.

  As the hollow fiber membrane 2, a microfiltration membrane, an ultrafiltration membrane, or the like can be used. The material of the hollow fiber membrane 2 is not particularly limited, and polysulfone, polyethersulfone, polyacrylonitrile, polyimide, polyetherimide, polyamide, polyetherketone, polyetheretherketone, polyethylene, polypropylene, poly (4-methylpentene), Examples include ethylene-vinyl alcohol copolymer, cellulose, cellulose acetate, polyvinylidene fluoride, ethylene-tetrafluoroethylene copolymer, polytetrafluoroethylene, and the like, and these composite materials can also be used.

The hollow fiber membrane 2 preferably has an inner diameter of 50 μm to 3000 μm, more preferably 500 to 2000 μm, and a ratio of the inner diameter to the outer diameter (inner / outer diameter ratio) of 0.3 to 0.8. Are preferably used. In particular, the higher filtration capacity is better, and in order to increase the filtration rate, it is preferable to use a hollow fiber membrane 2 having a filtration capacity of 0.8 ml / min / cm ² at 0.1 MPa and 25 ° C. or higher. A material having a high bursting strength and compressive strength and having a pressure resistance of 0.5 MPa or more is preferable.

  The hollow fiber membrane bundle 3 is formed by bundling a plurality of hollow fiber membranes 2 together. The number of the hollow fiber membranes 2 is, for example, 3000 hollow fiber membrane bundles 3 having a diameter of 150 mm.

  The potting material 4 is formed by filling a predetermined adhesive resin between the hollow fiber membranes 2 at both ends of the hollow fiber membrane bundle 3 and then curing. The adhesive resin is preferably a polymer material such as an epoxy resin, vinyl ester resin, urethane resin, unsaturated polyester resin, olefin polymer, silicone resin, or fluorine-containing resin. In addition, the potting material 4 needs to have a pressure resistance that can withstand a differential pressure generated during use, and for that purpose, it is desirable to have an appropriate hardness. On the other hand, in order to prevent the hollow fiber membrane 2 from being broken due to the flow of fluid during physical cleaning for a longer period of time, it is desirable to use an adhesive resin having an appropriate softness.

  The casing 5 has nozzles 5a for fluid entry and exit in the vicinity of both ends thereof. In terms of ease of processing and weight reduction, the casing 5 is preferably made of plastics. Specific examples of plastics include polyethylene, polypropylene, polysulfone, polyethersulfone, polyvinylidene fluoride, ABS resin, and chloride. A vinyl resin etc. are mentioned. The casing 5 has an outer diameter of 80 to 250 mm, a length of preferably 500 to 2500 mm, an outer diameter of 160 to 180 mm, and a length of 800 to 1100 mm. Is particularly preferred.

  Partition plates 11 are inserted at both ends of the hollow fiber membrane bundle 3 accommodated in the casing 5 in order to reduce the uneven density distribution of the hollow fiber membrane 2. Furthermore, a rod-shaped rod member may be inserted into both ends of the hollow fiber membrane bundle 3 so as to reduce the uneven density distribution of the hollow fiber membrane 2. The partition plate 11 and the bar member may be formed using the same material as the potting material 4 or may be another material having a pseudo physical property value. For example, epoxy resin, vinyl ester resin, urethane resin Further, it may be formed of a polymer material such as an unsaturated polyester resin, an olefin polymer, a silicone resin, or a fluorine-containing resin. The surfaces of the partition plate 11 and the bar member may be intentionally roughened, and consideration may be given to increase the bonding (adhesion) strength when the potting material 4 is filled and cured.

  The partition plate 11 is fitted with two rectangular flat plates so as to be orthogonal to each other, and has a shape having four partition pieces 11 a extending radially from the center of the intersecting line. The dimension of the partition piece 11 a corresponds to approximately half of the inner diameter at both ends of the casing 5. Both ends of the hollow fiber membrane bundle 3 are substantially divided into four equal parts in the casing 5 by the four partitioning pieces 11a. Further, the rod member 12 is inserted into both ends of each of the hollow fiber membrane bundles 3 divided into four in this way.

  According to the membrane module 1 configured as described above, when the liquid to be treated is introduced into the membrane module 1 through any one of the caps 6, the concentrated water is passed through the remaining one of the caps 6. 1 and the filtered water filtered by the hollow fiber membrane 2 is discharged from the membrane module 1 through the two nozzles 5a (internal pressure filtration).

  In such a membrane module 1, if the surface of the hollow fiber membrane 2 is scratched, the liquid to be treated may leak. Therefore, the opening sealing member 10 is inserted into the opening P at the end of the hollow fiber membrane 2 where the leak has occurred. The opening sealing member 10 will be described in detail below.

  Fig.3 (a) is a top view which shows the opening sealing member which concerns on embodiment, FIG.3 (b) is sectional drawing along the III (b) -III (b) line. As shown in FIGS. 3A and 3B, the opening sealing member 10 has an outer diameter from one end 10a, the other end 10b opposite to the one end 10a, and from the one end 10a side to the other end 10b side. Includes a tapered portion T having a linear taper shape that gradually expands. In the present embodiment, the tapered portion T is continuously provided from one end 10a to the other end 10b. That is, the opening sealing member 10 has a taper portion T as a whole from one end 10a to the other end 10b. The end portion on the one end 10a side of the taper portion T coincides with the one end 10a, and the other end of the taper portion T. The end on the 10b side coincides with the other end 10b.

  The tapered portion T has a circular cross section perpendicular to the longitudinal direction. A part of the tapered portion T is a sealing portion S that contacts the inner peripheral surface of the opening P and seals the opening P. Further, a non-insertable portion R that can be excised is provided between the other end 10b and the sealing portion S. The outer diameter D1 of the one end 10a is smaller than the inner diameter D2 (see FIGS. 4 and 5) of the opening P of the hollow fiber membrane 2. Thereby, it becomes easy to insert the opening sealing member 10 into the opening P. The outer diameter D3 of the other end 10b is larger than the inner diameter D2 of the opening P. The position of the sealing portion S of the tapered portion T depends on the inner diameter D2 of the hollow fiber membrane 2. For example, when the inner diameter D2 is narrow due to individual differences, it is closer to one end 10a, and when it is wider, it is closer to the other end 10b. However, since the area | region which can become the sealing part S in a fixed range is decided, the other end 10b side becomes the non-insertion part R rather than the area | region. The non-insertion portion R is in a range of 5 mm or more from the other end 10b.

  The taper angle of the taper portion T is 0.1 to 5 °, and the outer diameter D1 of the end portion 10a side of the taper portion T, that is, the one end 10a in this embodiment is 20% of the inner diameter D2 of the opening P. Above, it is 95% or less. Further, the outer diameter D3 of the tapered portion T on the other end 10b side, that is, in this embodiment, the other end 10b is 110% or more and 300% or less with respect to the inner diameter D2 of the opening P.

  The opening sealing member 10 is made of a flexible resin. Examples of this resin include low density polyethylene, high density polyethylene, polypropylene, and ultrahigh molecular weight polyethylene. Since the liquid temperature may exceed 70 ° C. when the membrane module 1 is washed, a resin having a melting point (heat resistance) higher than that is preferable, and it is measured according to JIS K0064: 1992, although it depends on the temperature of the liquid used. The melting point is more preferably 50 to 300 ° C. The opening sealing member 10 is manufactured by, for example, injection molding. The melting point is, for example, about 112 ° C. for low density polyethylene, about 130 ° C. for high density polyethylene, and about 130 to 165 ° C. for polypropylene. The melting point of paraffin (wax) used for the wax rod is generally 40 to 65 ° C.

  4 is an enlarged longitudinal sectional view showing an end portion of the membrane module of FIG. 2, and FIG. 5 is a sectional view taken along line VV of the membrane module shown in FIG. As shown in FIG. 4, the end of the hollow fiber membrane 2 is fixed to the potting material 4 in a state of being curved in a random manner. Since the opening sealing member 10 has flexibility, the opening P at the end of the hollow fiber membrane 2 can be reliably sealed following the curvature.

  In order to follow the curve without damaging the hollow fiber membrane 2 in this way, the bending elastic modulus of the resin constituting the opening sealing member 10 measured in accordance with JIS K7171 is 100 to 2000 MPa. It is preferable. The flexural modulus is, for example, about 180 MPa for low density polyethylene, 900 MPa for high density polyethylene, and about 1500 MPa for polypropylene. The bending elastic modulus of the potting material 4 is, for example, about 600 MPa with urethane resin.

For the same reason, the resin preferably has a hardness (durometer type D hardness) measured by a type D durometer specified in JIS K7215: 1986 of 15 to 90D. The Charpy impact strength measured in accordance with the regulations is preferably 1-30 kJ / m ² at 23 ° C., and the density measured in accordance with the regulations of JIS K7112: 1999 is 0.8-2.2 g / cm. ³ is preferred.

  Next, a repair method for the membrane module 1 will be described below. First, the nut 7 is turned using a torque wrench or the like, and the nut 7, the cap 6 and the O-ring 8 are removed from the membrane module 1. Then, the membrane module 1 is submerged in water, and an air introduction ferrule is attached to one of the nozzles 5a, and a blind ferrule is attached to the other one of the nozzles 5a.

  Subsequently, air (air) is supplied from one of the nozzles 5a into the casing 5 through the air introduction ferrule to a predetermined pressure while gradually increasing the pressure from a low pressure to the space around the hollow fiber membrane bundle 3 Pressurize. The predetermined pressure is, for example, 0.2 MPa, and is a pressure that does not allow air to permeate into the hollow portion in the case of the hollow fiber membrane 2 that does not have a flaw or the like that generates a leak.

  Thereby, in the hollow fiber membrane 2 in which the leak has occurred, air is supplied to the hollow portion communicating with the opening P, and as a result, bubbles are generated from the opening P. Therefore, among the plurality of hollow fiber membranes 2, the hollow fiber membrane 2 in which air has flowed out from the opening P can be identified as the hollow fiber membrane 2 in which a leak has occurred (identification step). The air supplied into the casing 5 is filtered and oil-free.

  Subsequently, as shown in FIG. 6, the opening sealing member 10 is inserted into the opening P of the hollow fiber membrane 2 where the leak has occurred, and the opening P is sealed (sealing step). First, as shown in FIG. 6A, an opening sealing member 10 is prepared. Subsequently, as shown in FIG. 6B, the opening sealing member 10 is inserted into the inside of the opening P of the specified hollow fiber membrane 2 from the one end 10a side (insertion step). The degree of insertion is such that it can be pushed in by hand. At this time, a part of the opening sealing member 10 protruding from the opening P includes the sealing portion S on the one end 10a side and the non-insertion portion R on the other end 10b side.

  Then, as shown in FIG.6 (c), the non-insertion part R is cut | disconnected among the parts protruded from the opening P of the opening sealing member 10 (cutting process). The cutting is performed, for example, at a position about 5 mm from the opening P using a nipper or the like. Subsequently, as shown in FIG. 6D, the sealed portion S, which is the remaining remaining portion after cutting, is press-fitted into the opening P (press-fitting step). For the press-fitting, for example, a hammer is used little by little. At this time, the height of the opening sealing member 10 protruding from the opening P is 1 mm or less.

  Subsequently, the membrane module 1 is submerged again in the water, and air is supplied into the casing 5 to pressurize the space around the hollow fiber membrane bundle 3, and air is introduced from the opening P into which the opening sealing member 10 is inserted. Make sure that it does not flow out (repair confirmation process).

  Finally, the membrane module 1 is removed from the water, and the nut 7 is turned using a torque wrench or the like, and the O-ring 8, the cap 6 and the nut 7 are attached to the membrane module 1.

  Next, the effect of the opening sealing member 10, the membrane module 1, and the repair method of the membrane module 1 is demonstrated. Since the rod-shaped opening sealing member 10 has an outer diameter D1 at one end 10a smaller than an inner diameter D2 at the opening P at the end of the hollow fiber membrane 2, when the one end 10a is inserted into the opening P, the one end 10a side It is easy to insert the opening sealing member 10 into the opening P. Moreover, since the opening sealing member 10 is provided with the sealing part S which contacts the inner peripheral surface of the opening P and seals the opening P, the opening P can be sealed.

  Furthermore, the opening sealing member 10 is made of a flexible resin such as polyethylene, polypropylene, or ultrahigh molecular weight polyethylene, and the flexural modulus of the resin is preferably 100 to 2000 MPa. For this reason, even when the end portion of the hollow fiber membrane 2 is curved and fixed to the potting material 4, the hollow fiber membrane 2 is inserted into the opening P following the curve without being bent halfway like a wax rod. Since it is attached, the opening P can be reliably sealed. Further, the opening sealing member 10 can be easily detached without being broken halfway like a wax rod before being pressed into the opening P. Therefore, it is possible to perform temporary sealing when specifying the hollow fiber membrane in which the leak has occurred, and confirm whether or not the specified location is correct.

  Further, if the opening sealing member 10 is made of a hard metal such as stainless steel, the hollow fiber membrane 2 may be cracked or torn and the hollow fiber membrane 2 may be damaged. In particular, at the end fixed by the potting material 4, part or all of the hollow fiber membrane 2 in the film thickness direction is in a state in which the resin constituting the potting material 4 has been infiltrated and cured, and thus the resin has infiltrated. Compared to the state where there is no crack, cracks are likely to occur. Even in such a case, the opening sealing member 10 is made of a resin that is more flexible than the hollow fiber membrane 2 so that cracks are less likely to occur.

  The opening sealing member 10 has a linear taper shape, and the outer diameter gradually increases from one end 10a to the other end 10b. Therefore, even if the inner diameter D2 of the opening P has a distribution, the opening sealing member 10 has a distribution from the other end 10b. In the meantime, the sealing part S which contacts the inner surface of the opening P and seals the opening P can be provided. For example, in the case of the hollow fiber membrane 2 having an inner diameter of 1.4 mm, there is an error of about 0.1 mm before and after, and the inner diameter D2 of the opening P may actually have a distribution in the range of 1.3 to 1.5 mm. . Thus, even if there is a solid difference in the inner diameters of the plurality of hollow fiber membranes 2, the opening P can be sealed by adjusting the length of the opening sealing member 10 inserted into the opening P. .

  The taper angle is 0.1 to 5 °, the outer diameter D1 of the one end 10a of the taper portion T is 20% or more and 95% or less with respect to the inner diameter D2 of the opening P, and the other end 10b of the taper portion T. The outer diameter D3 is 110% or more and 300% or less with respect to the inner diameter D2 of the opening P. According to this, since the taper portion T has a very gentle linear taper shape, the outer diameter is substantially the same as the inner diameter D2 of the opening P, and a sufficient range is easily secured against the inner peripheral surface of the opening P. It is easy to be done. That is, it is easy to ensure a sufficient axial length as the sealing portion S. For this reason, it is difficult for the opening sealing member 10 to separate from the opening P, and the opening P can be reliably sealed.

  Furthermore, since the outer diameter from the one end 10a to the position of at least 5 to 60 mm is smaller than the inner diameter D2 of the opening P, the opening sealing member 10 can have a length inserted into the opening P of at least 5 mm. Therefore, since the opening sealing member 10 is inserted into the curved hollow fiber membrane 2 at a length of at least 5 mm, it is difficult to separate from the opening P and the opening P can be reliably sealed. . Moreover, by making the length inserted into the opening P smaller than 60 mm, the opening sealing member 10 is inserted into the portion of the flexible hollow fiber membrane 2 that is not fixed by the potting material 4, and the portion is damaged. Can be prevented.

  Moreover, in the opening sealing member 10, since the cross section orthogonal to the longitudinal direction L from the one end 10a toward the sealing portion S is circular and has the same shape as the opening P of the hollow fiber membrane 2, the opening P is sealed. It becomes easy.

  Moreover, in the repair method of the membrane module 1, a sealing process can be implemented only with commercially available tools, such as a nipper and a hammer.

  Further, in the repair method of the membrane module 1, before the sealing step in water, the membrane module 1 is submerged in water, and air is supplied into the casing 5 to pressurize the space around the hollow fiber membrane bundle 3, Among the plurality of hollow fiber membranes 2, there is provided a specific step of identifying the hollow fiber membrane 2 in which air has flowed out from the opening P as the hollow fiber membrane 2 in which a leak has occurred. Thus, since air is made to flow out from the opening P in water, the hollow fiber membrane 2 in which the leak has occurred can be easily identified visually.

  Further, in the repairing method of the membrane module 1, after the sealing step, the membrane module 1 is submerged in water, and air is supplied into the casing 5 to pressurize the space around the hollow fiber membrane bundle 3 to open the sealing. A repair confirmation process is provided for confirming that air does not flow out from the opening P into which the stop member 10 is inserted. As with the specific process, since it is confirmed that air does not flow out in water, the repair can be easily confirmed visually.

  In the present embodiment, the tapered portion T is provided continuously from the one end 10a to the other end 10b, and the opening sealing member 10 is described as being entirely the tapered portion T from the one end 10a to the other end 10b. However, it is not limited to this. The tapered portion T may be a part of the opening sealing member 10, for example, as shown in FIG. 7. As shown in FIG. 7, the opening sealing member 10 includes a tapered portion T whose outer diameter gradually increases from one end 10 a to a position 10 c closer to the other end 10 b than the sealing portion S. The position 10c is an end of the tapered portion T on the other end 10b side. The taper portion T has a linear taper shape, and has a cylindrical shape with the same outer diameter from the position 10c to the other end 10b.

  In addition, the opening sealing member 10 may seal not only the hollow fiber membrane 2 in which leakage has occurred but also the hollow fiber membrane 2 in which leakage has not occurred. Thereby, for example, the filtration capacity of the membrane module 1 can be adjusted.

EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited to these examples.
[Preparation of opening sealing member]

The opening sealing member (repair nail) shown in FIG. 3 was produced by injection molding using commercially available low density polyethylene, high density polyethylene, and polypropylene. As a comparative example, a wax rod was also produced based on Patent Document 1. Table 1 shows the main physical property values of the produced opening sealing member. Each physical property value was measured based on the JIS standard described in the above-described embodiment for carrying out the invention.

［エア加圧による封止効果確認］ Subsequently, using the produced opening sealing member, according to the method for repairing the membrane module described in the embodiment for carrying out the invention, the opening of the leaked hollow fiber membrane was sealed, and the membrane module was repaired. . About the membrane module which repaired, while confirming the drive property of the opening sealing member to the hollow fiber membrane which the leak generate | occur | produced, the following confirmation and evaluation were performed. Table 2 summarizes the results.

[Confirmation of sealing effect by air pressurization]

  About the hollow fiber membrane repaired by inserting the opening sealing member produced using low density polyethylene, high density polyethylene, and polypropylene into the opening, air of 0.3 MPa is provided from the opposite side of the repaired hollow fiber membrane. Pressurization was performed. It was confirmed that no leak occurred in the repaired part for 3 minutes after pressurization.

On the other hand, an attempt was made to insert an opening sealing member produced using a wax rod into the opening, but it was broken at the time of attachment, and sufficient insertion could not be performed. Thereafter, air pressurization of 0.3 MPa was performed from the opposite side of the hollow fiber membrane for which repair was attempted. It was confirmed that a leak occurred and repair was not possible.
[Evaluation of durability of repaired parts by cold cycle operation]

After confirming the sealing effect by air pressurization (leak test) on the membrane module repaired by sealing the opening with an opening sealing member made of low density polyethylene, high density polyethylene, and polypropylene, 20 A cold cycle operation at ˜75 ° C. was performed 1500 cycles. Subsequently, the leak inspection was performed again, and it was confirmed that the leak sealing effect by the opening sealing member was maintained.
[Evaluation of repaired part durability by repeated filtration / backwash pressure operation]

  After confirming the sealing effect by air pressurization (leak test) on the membrane module repaired by sealing the opening with an opening sealing member made of low-density polyethylene, high-density polyethylene, and polypropylene, filtration is performed. The operation was performed at a pressure of 50 to 70 kPa and a backwash pressure of 70 kPa. The water temperature was room temperature. The process of performing filtration and backwashing for 60 sec and 15 sec, respectively, was 1 cycle, and 150,000 cycle operation was performed. Subsequently, the leak inspection was performed again, and it was confirmed that the leak sealing effect by the opening sealing member was maintained.

DESCRIPTION OF SYMBOLS 1 ... Membrane module, 2 ... Hollow fiber membrane, 3 ... Hollow fiber membrane bundle, 4 ... Potting material (resin part), 5 ... Casing, 10 ... Opening sealing member, 10a ... One end (the edge part of the one end side of a taper part) ), 10b, the other end (the end portion on the other end side of the taper portion), 10c, a position (an end portion on the other end side of the taper portion), 11 a partition plate, D1, an outer diameter of one end, D2, an inner diameter of the opening , D3 ... outer diameter of the other end, L ... longitudinal direction, P ... opening, S ... sealing part, T ... taper part, R ... non-insertion part.

Claims (15)

A membrane module comprising: a hollow fiber membrane bundle comprising a plurality of hollow fiber membranes; and a resin portion for fixing the hollow fiber membrane bundle at an end portion, wherein at least one end portion of the hollow fiber membrane is opened at the resin portion. And
An opening sealing member made of a flexible resin in a rod shape that is inserted into the opening of the hollow fiber membrane,
The hollow fiber membrane is hardened by impregnating the resin constituting the resin part into part or all in the film thickness direction,
The opening sealing member has one end whose outer diameter is smaller than the inner diameter of the opening, and the other end opposite to the one end, and the outer diameter increases from the one end side to the other end side,
The opening sealing member deforms and contacts the inner peripheral surface of the opening to seal the opening ,
The opening sealing member is a membrane module that is more flexible than the cured hollow fiber membrane . A membrane module comprising: a hollow fiber membrane bundle comprising a plurality of hollow fiber membranes; and a resin portion for fixing the hollow fiber membrane bundle at an end portion, wherein at least one end portion of the hollow fiber membrane is opened at the resin portion. And
An opening sealing member made of a flexible resin in a rod shape that is inserted into the opening of the hollow fiber membrane,
The hollow fiber membrane is hardened by impregnating the resin constituting the resin part into part or all in the film thickness direction,
The opening sealing member has one end whose outer diameter is smaller than the inner diameter of the opening, and the other end opposite to the one end, and the outer diameter increases from the one end side to the other end side,
The opening sealing member is more flexible than the cured hollow fiber membrane, and is in contact with the inner peripheral surface of the opening to seal the opening.   The membrane module according to claim 1 or 2, wherein the opening sealing member has a circular cross section perpendicular to the longitudinal direction.   The outer diameter of the end portion on the one end side of the opening sealing member is 20% or more and 95% or less with respect to the inner diameter of the opening, and the outer diameter of the end portion on the other end side is relative to the inner diameter of the opening. The membrane module according to any one of claims 1 to 3, which is 110% or more and 300% or less.   5. The membrane module according to claim 1, wherein in the opening sealing member, an outer diameter from the one end to a position of at least 5 to 60 mm is smaller than an inner diameter of the opening.   The membrane module according to any one of claims 1 to 5, wherein a melting point of the resin used for the opening sealing member is 50 to 300 ° C.   The membrane module according to any one of claims 1 to 6, wherein the resin used for the opening sealing member has a flexural modulus of 100 to 2000 MPa.   The membrane module according to any one of claims 1 to 7, wherein a durometer type D hardness of the resin used for the opening sealing member is 15 to 90D. The membrane module according to any one of claims 1 to 8, wherein Charpy impact strength of the resin used for the opening sealing member is 1 to 30 kJ / m ² at 23 ° C. The membrane module according to any one of claims 1 to 9, wherein a density of the resin used for the opening sealing member is 0.8 to 2.2 g / cm ³ .   The membrane module according to any one of claims 1 to 10, wherein the resin used for the opening sealing member is polyethylene.   The membrane module according to any one of claims 1 to 11, wherein the resin used for the opening sealing member is low-density polyethylene.   The membrane module according to any one of claims 1 to 11, wherein the resin used for the opening sealing member is high-density polyethylene.   The membrane module according to claim 1, wherein the resin used for the opening sealing member is polypropylene.   The membrane module according to any one of claims 1 to 11, wherein the resin used for the opening sealing member is ultra high molecular weight polyethylene.

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