JP6353459B2 - リグノセルロース複合材料を調製するための接着剤系 - Google Patents
リグノセルロース複合材料を調製するための接着剤系 Download PDFInfo
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- JP6353459B2 JP6353459B2 JP2015545788A JP2015545788A JP6353459B2 JP 6353459 B2 JP6353459 B2 JP 6353459B2 JP 2015545788 A JP2015545788 A JP 2015545788A JP 2015545788 A JP2015545788 A JP 2015545788A JP 6353459 B2 JP6353459 B2 JP 6353459B2
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- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000011093 chipboard Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- ZHMPXIDAUXCKIQ-UHFFFAOYSA-N cyclohexane-1,2,4-triol Chemical compound OC1CCC(O)C(O)C1 ZHMPXIDAUXCKIQ-UHFFFAOYSA-N 0.000 description 1
- PFURGBBHAOXLIO-UHFFFAOYSA-N cyclohexane-1,2-diol Chemical compound OC1CCCCC1O PFURGBBHAOXLIO-UHFFFAOYSA-N 0.000 description 1
- FSDSKERRNURGGO-UHFFFAOYSA-N cyclohexane-1,3,5-triol Chemical compound OC1CC(O)CC(O)C1 FSDSKERRNURGGO-UHFFFAOYSA-N 0.000 description 1
- RLMGYIOTPQVQJR-UHFFFAOYSA-N cyclohexane-1,3-diol Chemical compound OC1CCCC(O)C1 RLMGYIOTPQVQJR-UHFFFAOYSA-N 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- RUYJNKYXOHIGPH-UHFFFAOYSA-N dialuminum;trioxido(trioxidosilyloxy)silane Chemical compound [Al+3].[Al+3].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] RUYJNKYXOHIGPH-UHFFFAOYSA-N 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 229940079868 disodium laureth sulfosuccinate Drugs 0.000 description 1
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- YGAXLGGEEQLLKV-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-2-sulfonatobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)CC(C([O-])=O)S([O-])(=O)=O YGAXLGGEEQLLKV-UHFFFAOYSA-L 0.000 description 1
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 description 1
- QBGLSLJCCRQTCW-UHFFFAOYSA-L disodium;4-octoxy-4-oxo-3-sulfonatobutanoate Chemical compound [Na+].[Na+].CCCCCCCCOC(=O)C(S([O-])(=O)=O)CC([O-])=O QBGLSLJCCRQTCW-UHFFFAOYSA-L 0.000 description 1
- 238000007606 doctor blade method Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- BRWZYZWZBMGMMG-UHFFFAOYSA-J dodecanoate tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O BRWZYZWZBMGMMG-UHFFFAOYSA-J 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000009503 electrostatic coating Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- GKIPXFAANLTWBM-UHFFFAOYSA-N epibromohydrin Chemical compound BrCC1CO1 GKIPXFAANLTWBM-UHFFFAOYSA-N 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229960002442 glucosamine Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- QVTWBMUAJHVAIJ-UHFFFAOYSA-N hexane-1,4-diol Chemical compound CCC(O)CCCO QVTWBMUAJHVAIJ-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 231100000003 human carcinogen Toxicity 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 150000002483 hydrogen compounds Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- BJHIKXHVCXFQLS-PQLUHFTBSA-N keto-D-tagatose Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)C(=O)CO BJHIKXHVCXFQLS-PQLUHFTBSA-N 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 125000000160 oxazolidinyl group Chemical group 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 description 1
- OIGNJSKKLXVSLS-VWUMJDOOSA-N prednisolone Chemical compound O=C1C=C[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 OIGNJSKKLXVSLS-VWUMJDOOSA-N 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- IHRQVOBHLWHVSE-UHFFFAOYSA-N sulfamide;toluene Chemical compound NS(N)(=O)=O.CC1=CC=CC=C1 IHRQVOBHLWHVSE-UHFFFAOYSA-N 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/13—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board all layers being exclusively wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/02—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/542—Shear strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2405/00—Adhesive articles, e.g. adhesive tapes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/20—Presence of organic materials
- C09J2400/30—Presence of wood
- C09J2400/303—Presence of wood in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/20—Presence of organic materials
- C09J2400/30—Presence of wood
- C09J2400/306—Presence of wood in the pretreated surface to be joined
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyurethanes Or Polyureas (AREA)
- Veneer Processing And Manufacture Of Plywood (AREA)
Description
a)水性プライマー組成物;および
b)ポリウレタン接着剤組成物
を含み、
前記水性プライマー組成物が:
水溶性界面活性剤、水乳化性界面活性剤およびそれらの混合物からなる群から選択される、組成物の重量に対して10重量%以下の界面活性剤;および
水溶性ポリオール、水分散性ポリオール、水乳化性ポリオールおよびそれらの混合物からなる群から選択される、組成物の重量に対して0〜25重量%のポリオールであって、5000ダルトン未満の分子量を有するポリオール
を含み、
但し、水性プライマー組成物が、前記ポリオール、またはヒドロキシル官能性と5000ダルトン未満の分子量とを有する界面活性剤の少なくとも1つを含むべきである、
接着剤系が提供される。
(a)少なくとも2つのリグノセルロース表面を供給する工程;
(b)上記に規定の接着剤系を供給する工程;および
(c)リグノセルロース表面の少なくとも1つの少なくとも一部に前記接着剤系を適用
する工程;および
(d)少なくとも1つのリグノセルロース表面と他方のリグノセルロース表面との間に
接着結合を形成するのに適当な条件下で、それらを接触させる工程
を含む方法が提供される。
本明細書で用いられる場合、EN391とは、「集成材−接着剤層の離層試験」と題された欧州規格 EN391:2001を意味する。
本発明の水性プライマー組成物は:
水溶性界面活性剤、水乳化性界面活性剤およびそれらの混合物からなる群から選択される、組成物の重量に対して10重量%以下の界面活性剤;および
水溶性ポリオール、水分散性ポリオール、水乳化性ポリオールおよびそれらの混合物からなる群から選択される、組成物の重量に対して0〜25重量%のポリオールであって、5000ダルトン未満の分子量を有するポリオールを含み、
但し、組成物は、前記ポリオール、またはヒドロキシル官能性と5000ダルトン未満の分子量とを有する界面活性剤の少なくとも1つを含むべきである。
水溶性界面活性剤、水乳化性界面活性剤およびそれらの混合物からなる群から選択される、組成物の重量に対して5重量%以下、好ましくは1重量%以下の界面活性剤;および
水溶性ポリオール、水分散性ポリオール、水乳化性ポリオールおよびそれらの混合物からなる群から選択される、組成物の重量に対して20重量%以下、好ましくは5重量%以下のポリオール
を含んでよい。
プライマー組成物は、水溶性界面活性剤、水乳化性界面活性剤およびそれらの混合物からなる群から選択される10重量%以下、通常は5重量%以下、好ましくは0.01〜1重量%の界面活性剤を含む。
プライマー組成物は、水溶性ポリオール、水分散性ポリオール、水乳化性ポリオールおよびそれらの混合物からなる群から選択される25重量%以下、通常は20重量%以下、好ましくは0.1〜5重量%のポリオールを含む。水溶性、水分散性または水乳化性ポリオールは、5000ダルトン未満、より好ましくは2000ダルトン未満の分子量を有する、ジヒドロキシ化合物若しくは多官能ヒドロキシ化合物またはポリマー化合物である。一般的には、選択されたポリオールは120℃において安定であるべきである。さらに、好ましい実施形態において、ポリオールは、Griffinにより下記に規定の少なくとも10、例えば12以上の親水親油バランス(HLB)により特徴付けられる。
本発明の接着剤系の好ましい実施形態において、遊離NCO基を有するプレポリマーを含む一成分系ポリウレタン接着剤組成物が用いられる。より詳細には、その一成分系ポリウレタン接着剤組成物は、
遊離NCO基を有するプレポリマーであって、イソシアネートと反応する化合物を含む少なくとも1つの成分Aとイソシアネートを含む少なくとも1つの成分Bとから得られるプレポリマー;
0〜40重量%、好ましくは0.1〜30重量%のフィラー;
0〜20重量%の慣用の添加剤および助剤;および
0〜20重量%の活性剤
を含むべきである。
スズメルカプチドが挙げられる。イソシアネートの性質によってが、用いられる触媒の量は一般的に、触媒される混合物の0.005〜10重量%の範囲である。
十分には規定されない幾何学的形状を有するリグノセルロース基材、例えばチップボード、ファイバーボードおよびパーティクルボード等が、本発明におけるリグノセルロース複合材料の調製において接着されてよいが、好ましいリグノセルロース基材としては、最終的な複合材料の構造において明確且つ事前に決定された相対的な幾何学的関係で組み合わせる目的のために切断または成形される、ホールボード(whole board)、ハーフエッジボード(half−edged board)、角材(square)、木材ストリップおよび/またはベニヤ板が挙げられる。付随して、好ましいリグノセルロース複合材料は、共に貼り合わされる少なくとも2つの木板、ハーフエッジボード、角材、ベニヤ板、木材ストリップを含む積層品である。
プライマー組成物は、例えば浸水、浸漬、ハケ塗り、ロール塗布、ドクターブレード塗布、印刷法、エアアトマイズスプレー(air−atomized spray)、エアアシストスプレー、エアレススプレー、高容量低圧スプレー、エアアシストエアレススプレーおよび高速回転ベル等の従来の適用方法により適用してよい。
19×60×400mmの寸法を有し且つ構造用途のためのカナダ規格CSA112.9により設定された要求を満たす6対のダグラスファーのサンプル(比重0.59;0〜10%の年輪角)を調製した。実験室でこれらのサンプルを従来法で平削りした。
サザンイエローパインから構成される4対の木材表面をそれぞれ調製した。第1の合わせる面にはプライマーを適用しなかった。残りの3対に対し、プライマーCを20〜30g/m2の塗布量で、合わせられる木材の両側に適用した。5分間、1時間および8時間のプライマー浸透時間を与えた後、次いで接着剤を200g/m2の量で、合わせられる全8側に適用した。合わせたまたは組み立てたパーツを室温において3〜4時間の間、0.8〜1MPaでプレスした。
20mmの厚さ、135mmの幅の寸法を有するササザンイエローパイン(0.55〜0.65の比重)の厚板を調製した。これらの厚板を実験室で平削りした。
この実施例は、サザンイエローパイン種(比重0.62)に関して接着剤の耐久性の改良における様々なプライマー(A、BおよびC)の有効性を示す。
この実施例は、本発明に係る様々なプライマー(B、CおよびD)を用いて達成される、複数の高密度な材種に関して用いられる接着剤の耐久性の改良を示す。
この実施例は、異なるHLB値およびOH数を有する界面活性剤がプライマーとして用いられても有効であり得ることを示し、ここではサザンイエローパイン種(比重0.60〜0.71)に関する。
本開示の接着剤およびプライマー並びにアセチル化木材を用いて接着結合を作製した。ASTM D5751により規定のタイプIおよびタイプIIのブロックせん断を用いて接着結合を試験し、ASTM D2559の離層の部分についても行った。これらの試験に用いた本発明の接着剤は接着剤K1である。全ての試験に用いた本発明のプライマーはプライマーCである。
本発明の当初の開示は、少なくとも以下の態様を包含する。
[1]リグノセルロース複合材料を調製するための接着剤系であって:
a)水性プライマー組成物;および
b)ポリウレタン接着剤組成物
を含み、
前記水性プライマー組成物が:
水溶性界面活性剤、水乳化性界面活性剤およびそれらの混合物からなる群から選択される、前記組成物の重量に対して10重量%以下の界面活性剤;および
水溶性ポリオール、水分散性ポリオール、水乳化性ポリオールおよびそれらの混合物からなる群から選択される、前記組成物の重量に対して0〜25重量%のポリオールであって、5000ダルトン未満の分子量を有するポリオール
を含み、
但し、前記水性プライマー組成物が、前記ポリオール、またはヒドロキシル官能性と5000ダルトン未満の分子量とを有する界面活性剤の少なくとも1つを含むべきである、接着剤系。
[2]前記水性プライマー組成物が:
水溶性界面活性剤、水乳化性界面活性剤およびそれらの混合物からなる群から選択される、前記組成物の重量に対して5重量%以下、好ましくは1重量%以下の界面活性剤;および
水溶性ポリオール、水分散性ポリオール、水乳化性ポリオールおよびそれらの混合物からなる群から選択される、前記組成物の重量に対して20重量%以下、好ましくは5重量%以下のポリオール
を含む、前記[1]に記載の接着剤系。
[3]前記プライマー組成物が、前記組成物の重量に対して少なくとも80重量%の水を含む、前記[1]または[2]に記載の接着剤系。
[4]前記プライマー組成物が、前記組成物の重量に対して10重量%以下の共溶媒をさらに含む、前記[1]〜[3]のいずれかに記載の接着剤系。
[5]前記プライマー組成物の前記界面活性剤が:シロキサン系界面活性剤;アルキル多糖を含むアルキルポリグルコシド;アルコキシル化脂肪酸;アルコキシル化アルコール;アルキルスルホコハク酸塩;アセチレンジオール;およびそれらの混合物からなる群から選択される、前記[1]〜[4]のいずれかに記載の接着剤系。
[6]前記プライマー組成物の前記界面活性剤が、ゲル浸透クロマトグラフィーによりポリスチレン標準に対して決定された400〜25000の数平均分子量(Mn)を有する界面活性剤から選択される、前記[1]〜[5]のいずれかに記載の接着剤系。
[7]前記プライマー組成物の前記ポリオールが、120℃において安定であり且つ2000ダルトン未満の分子量を有する、少なくとも1つのジヒドロキシ化合物若しくは多官能ヒドロキシ化合物またはポリマー化合物を含む、前記[1]〜[6]のいずれかに記載の接着剤系。
[8]前記プライマー組成物の前記ポリオールが、少なくとも10、例えば12以上の親水親油バランス(HLB)により特徴付けられる、前記[1]〜[7]のいずれかに記載の接着剤系。
[9]前記プライマー組成物が、6〜8、好ましくは6.5〜7.5の範囲のpHを有する、前記[1]〜[8]のいずれかに記載の接着剤系。
[10]前記ポリウレタン接着剤組成物が、湿気硬化型の一成分系ポリウレタン接着剤組成物である、前記[1]〜[9]のいずれかに記載の接着剤系。
[11]前記一成分系ポリウレタン接着剤組成物が:
遊離NCO基を有するプレポリマーであって、イソシアネートと反応する化合物を含む少なくとも1つの成分Aと、イソシアネートを含む少なくとも1つの成分Bとから得られるプレポリマー;
0〜40重量%、好ましくは0.1〜30重量%のフィラー;
0〜20重量%の慣用の添加剤および助剤;および
0〜20重量%の活性剤
を含む、前記[10]に記載の接着剤系。
[12]遊離NCO基を有する前記プレポリマーが:
i)前記プレポリマーに基づいて、5〜30重量%、好ましくは10〜25重量%のNCO含有量;
ii)2.2〜3、好ましくは2.4〜2.9の官能価;および
iii)300〜35,000mPa・s、好ましくは1000〜10,000mPa・sの20℃における粘度
により特徴付けられる、前記[11]に記載の接着剤系。
[13]リグノセルロース接着物品の製造方法であって:
(a)少なくとも2つのリグノセルロース表面を供給する工程;
(b)前記[1]〜[12]のいずれかに記載の接着剤系を供給する工程;
(c)前記リグノセルロース表面の少なくとも1つの少なくとも一部に前記接着剤系を
適用する工程;および
(d)前記少なくとも1つのリグノセルロース表面と他方のリグノセルロース表面との
間に接着結合を形成するのに適当な条件下で、それらを接触させる工程
を含む方法。
[14]前記接着剤系を適用する前記工程c)が:
前記リグノセルロース表面の少なくとも1つの少なくとも一部に、前記プライマー組成物を適用すること;および
1〜15分、好ましくは1〜5分後に、前記リグノセルロース表面の前記一部に、前記ポリウレタン接着剤組成物を適用すること
を含む、前記[13]に記載の方法。
[15]前記[13]または[14]に記載の方法により得られる接着結合リグノセルロース物品。
[16]欧州規格 EN391:2001および/またはカナダ規格協会(CSA)規格 112.9の要求を満たす、前記[15]に記載のリグノセルロース物品。
[17]アセチル化木材を含む、前記[15]に記載のリグノセルロース物品。
[18]ASTM D2559の要求を満たす、前記[15]または[17]に記載のリグノセルロース物品。
Claims (15)
- リグノセルロース複合材料を調製するための接着剤系であって:
a)水性プライマー組成物;および
b)ポリウレタン接着剤組成物
を含み、
前記水性プライマー組成物が:
水溶性界面活性剤、水乳化性界面活性剤およびそれらの混合物からなる群から選択される、前記組成物の重量に対して10重量%以下の界面活性剤;および
水溶性ポリオール、水分散性ポリオール、水乳化性ポリオールおよびそれらの混合物からなる群から選択される、前記組成物の重量に対して0〜25重量%のポリオールであって、5000ダルトン未満の分子量を有するポリオール
を含み、
但し、前記水性プライマー組成物が、前記ポリオール、またはヒドロキシル官能性と5000ダルトン未満の分子量とを有する界面活性剤の少なくとも1つを含む、接着剤系。 - 前記水性プライマー組成物が:
水溶性界面活性剤、水乳化性界面活性剤およびそれらの混合物からなる群から選択される、前記組成物の重量に対して5重量%以下の界面活性剤;および
水溶性ポリオール、水分散性ポリオール、水乳化性ポリオールおよびそれらの混合物からなる群から選択される、前記組成物の重量に対して20重量%以下のポリオール
を含む、請求項1に記載の接着剤系。 - 前記プライマー組成物が、前記組成物の重量に対して少なくとも80重量%の水を含む、請求項1または2に記載の接着剤系。
- 前記プライマー組成物が、前記組成物の重量に対して10重量%以下の共溶媒をさらに含む、請求項1〜3のいずれかに記載の接着剤系。
- 前記プライマー組成物の前記界面活性剤が:シロキサン系界面活性剤;アルキル多糖を含むアルキルポリグルコシド;アルコキシル化脂肪酸;アルコキシル化アルコール;アルキルスルホコハク酸塩;アセチレンジオール;およびそれらの混合物からなる群から選択される、請求項1〜4のいずれかに記載の接着剤系。
- 前記プライマー組成物の前記界面活性剤が、ゲル浸透クロマトグラフィーによりポリスチレン標準に対して決定された400〜25000の数平均分子量(Mn)を有する界面活性剤から選択される、請求項1〜5のいずれかに記載の接着剤系。
- 前記プライマー組成物の前記ポリオールが2000ダルトン未満の分子量を有する、少なくとも1つのジヒドロキシ化合物若しくは多官能ヒドロキシ化合物またはポリマー化合物を含む、請求項1〜6のいずれかに記載の接着剤系。
- 前記プライマー組成物の前記ポリオールが、少なくとも10の親水親油バランス(HLB)により特徴付けられる、請求項1〜7のいずれかに記載の接着剤系。
- 前記プライマー組成物が、6〜8の範囲のpHを有する、請求項1〜8のいずれかに記載の接着剤系。
- 前記ポリウレタン接着剤組成物が、湿気硬化型の一成分系ポリウレタン接着剤組成物である、請求項1〜9のいずれかに記載の接着剤系。
- 前記一成分系ポリウレタン接着剤組成物が:
遊離NCO基を有するプレポリマーであって、イソシアネートと反応する化合物を含む少なくとも1つの成分Aと、イソシアネートを含む少なくとも1つの成分Bとから得られるプレポリマー;
0〜40重量%のフィラー;
0〜20重量%の慣用の添加剤および助剤;および
0〜20重量%の活性剤
を含む、請求項10に記載の接着剤系。 - 遊離NCO基を有する前記プレポリマーが:
i)前記プレポリマーに基づいて、5〜30重量%のNCO含有量;
ii)2.2〜3の平均イソシアネート官能価;および
iii)300〜35,000mPa・sの20℃における粘度
により特徴付けられる、請求項11に記載の接着剤系。 - リグノセルロース接着物品の製造方法であって:
(a)少なくとも2つのリグノセルロース表面を供給する工程;
(b)請求項1〜12のいずれかに記載の接着剤系を供給する工程;
(c)前記リグノセルロース表面の少なくとも1つの少なくとも一部に前記接着剤系を
適用する工程;および
(d)前記少なくとも1つのリグノセルロース表面と他方のリグノセルロース表面との
間に接着結合を形成するのに適当な条件下で、それらを接触させる工程
を含む方法。 - 前記接着剤系を適用する前記工程c)が:
前記リグノセルロース表面の少なくとも1つの少なくとも一部に、前記プライマー組成物を適用すること;および
1〜15分後に、前記リグノセルロース表面の前記一部に、前記ポリウレタン接着剤組成物を適用すること
を含む、請求項13に記載の方法。 - リグノセルロース表面がアセチル化木材から供給される、請求項13または14に記載の方法。
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CN107414970A (zh) * | 2017-05-24 | 2017-12-01 | 德华兔宝宝装饰新材股份有限公司 | 一种仿树瘤科技木装饰单板的制备方法 |
WO2020175277A1 (ja) * | 2019-02-26 | 2020-09-03 | 富士フイルム株式会社 | 内視鏡用接着剤及びその硬化物、並びに内視鏡及びその製造方法 |
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AU2013354196A1 (en) | 2015-06-18 |
CN105121584B (zh) | 2017-09-26 |
RU2015126548A (ru) | 2017-01-13 |
RU2646638C2 (ru) | 2018-03-06 |
CN105121584A (zh) | 2015-12-02 |
WO2014086797A1 (en) | 2014-06-12 |
JP2016507596A (ja) | 2016-03-10 |
BR112015012793A2 (pt) | 2017-07-11 |
EP2928977A1 (en) | 2015-10-14 |
CA2892749A1 (en) | 2014-06-12 |
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