JP6305761B2 - Solid powder cosmetic - Google Patents

Description

  The present invention relates to a solid powder cosmetic.

  The solid powder cosmetic manufacturing method includes a dry method in which powder and an oil agent as a binder are mixed and then compacted, and a volatile solvent is added to a cosmetic base material composed of powder and oil to form a slurry, which is then filled into a container. Then, there is a wet method in which a volatile solvent is removed by drying to obtain a cosmetic. The solid powder cosmetic obtained by the wet method is in a slurry state, so that the uniform dispersion of the powder and the oil advances, and has a fine powder quality and a moist feeling. In the wet method, it is necessary to uniformly disperse the base powder and oil in the slurry in order to maximize the characteristics. As such a solvent excellent in the dispersion ability of the base material, volatile hydrocarbons and low-boiling alcohols are known, and are widely used for obtaining solid powder cosmetics by an actual wet method (Patent Document 1). 2).

  However, volatile hydrocarbons and low-boiling alcohols are dangerous, so when used in the production of solid powder cosmetics, they should be used after being managed with a special storage warehouse. It was necessary to pay attention in terms of work safety and environmental measures, such as setting the drying conditions so as not to exceed the point, and recovering and disposing of the volatile solvent removed by drying again. In addition, volatile hydrocarbons obtained by refining petroleum cannot be used when petroleum is depleted in the future.

  From such a background, it has been attempted to use water as a volatile solvent. However, when water is used to prepare a slurry, it is difficult to uniformly disperse the oil agent, and the resulting product is from the surface to the inside. The oil dispersion state becomes uneven, and there are problems in use such as the amount of powder removal and spreading to the skin differing depending on the location of the cosmetic used, and the impact resistance is poor.

  In order to solve such problems, the impact resistance is improved by suppressing the blending amount of oil agents with poor dispersibility and using solid powder oil (Patent Document 3) or containing a film-forming polymer. Attempts have been made (Patent Document 4). In addition, an attempt has been made to improve the dispersibility of a base material by further adding a polyhydric alcohol and / or a hydrophilic surfactant to a base material composed of a specific powder raw material and an oil agent (Patent Document 5). ).

Japanese Patent Application Laid-Open No. 64-9909 Japanese Patent Publication No. 06-104612 JP 2007-269696 A Japanese Patent No. 3455476 JP 2010-47528 A

However, as in Patent Documents 3 and 4, when solid powder oil or a film-forming polymer is used in the base material, it is derived from these components and becomes a powdery and uncomfortable feeling of use.
Further, as in Patent Document 5, when a solid powder cosmetic base material contains a polyhydric alcohol or a hydrophilic surfactant, a new problem arises that the cosmetic coating film is vulnerable to water and sweat.
In this way, in wet-filled solid powder cosmetics using water, by improving the dispersion of the cosmetic base material in the slurry, development of a formulation with excellent usability and sufficient impact resistance Is awaited.

  As a result of intensive studies on each of the powder and the oil in the base material, the present inventor has identified the oil having a specific IOB value, the layered silicate mineral, and the hydrophilic spherical powder in view of the above situation. By using this ratio, the base material components are evenly dispersed even in the slurry prepared using water, and the slurry can be filled with good fluidity to every corner of the cosmetic container. The present inventors have found that a solid powder cosmetic material having excellent impact resistance can be obtained.

In the present invention, a cosmetic base material containing a powder and an oil agent, and a single or two or more mixed solvents selected from water and an aqueous solvent are mixed to form a slurry, filled in a container, and then the solvent is added. A solid powder cosmetic obtained by removing the following components (A), (B) and (C):
(A) Oil agent that is liquid at 25 ° C. and has an IOB value of 0.2 or more: 50% by mass or more of the total amount of oil agent in the cosmetic base material,
(B) Layered silicate mineral: 1 to 50% by mass of the total amount of the cosmetic base material,
(C) Hydrophilic spherical powder: 0.1 to 10% by mass of the total amount of the cosmetic base material
The present invention relates to a solid powder cosmetic containing

Further, the present invention is selected from a cosmetic base material prepared by mixing an oil containing the following component (A) and a powder containing the following components (B) and (C), water and an aqueous solvent. It is related with the manufacturing method of the solid powder cosmetics characterized by mixing the single or 2 or more types of mixed solvent made into a slurry form, filling a container, and then removing this solvent.
(A) Oil that is liquid at 25 ° C. and has an IOB value of 0.2 or more: 50% by mass or more of the total amount of oil in the cosmetic base material (B) Layered silicate mineral: 1 of the total amount of cosmetic base material ~ 50% by mass
(C) Hydrophilic spherical powder: 0.1 to 10% by mass of the total amount of the cosmetic base material

  The solid powder cosmetic of the present invention can prepare a slurry in which base material components are uniformly dispersed and fluidity is good even in wet filling using water as a solvent, and as a result, excellent usability can be obtained. It has sufficient impact resistance.

The oil agent of component (A) used in the present invention is liquid at 25 ° C. and has an IOB value of 0.2 or more, preferably 0.25 or more. By using such an oil agent, the oil agent can be uniformly dispersed in the water slurry.
Here, the IOB value is an index for predicting the physical properties of organic compounds, and is described in “Fragrance Journal”, vol. 50, pp. 79-82 (1981) and the like, the scores of “organic value (IV)” and “inorganic value (OV)” were added to each part of the structure of the compound and added together to obtain the total IV score. It is obtained as a value divided by the OV score. Van Der Waals force is considered to be “organic” in terms of physical properties and “inorganic” in terms of physical properties due to electrical affinity. Compounds with higher IOB values are more likely to cause electrical interactions Is done.

Oils that are liquid at 25 ° C. and have an IOB value of 0.2 or higher include silicone oils such as methylphenylpolysiloxane (IOB = 0.28); higher alcohols such as octyldodecanol (IOB = 0.26) Diisostearyl malate (IOB = 0.28), dilauryl glutamate (phytosteryl / octyldodecyl) (IOB = 0.3), tri (caprylic / capric) glycerin (IOB = 0.3), hydroxystearin 2-ethylhexyl acid (IOB = 0.31), propylene glycol dicaprylate (IOB = 0.32), glyceryl tri-2-ethylhexanoate (IOB = 0.35), octyldodecyl lactate (IOB = 0.36), Ester oil such as diisopropyl sebacate (IOB = 0.4); castor oil (IOB = 0.4) ) Vegetable oils and the like; such as a fatty acid such as isostearic acid (IOB = 0.43) and the like.
Among these, since a slurry having particularly good fluidity can be prepared, diglyceryl monoisostearate (IOB = 0.81) and diglyceryl diisostearate (IOB = 0.41), which are esters of isostearic acid and glycerin. Diglyceryl triisostearate (IOB = 0.26) is preferred.

  The oil agent of component (A) can be used alone or in combination of two or more, and the content is the dispersibility of the oil agent in the slurry, the feeling of use and impact resistance of the resulting solid powder cosmetic. Therefore, it is 50 mass% or more of the total amount of the oil agent in the cosmetic base material, preferably 55 mass% or more, and more preferably 60 mass% or more. And from the point of the water resistance of a cosmetic film, 95 mass% or less of the total amount of the oil agent in a cosmetic base material is preferable, and 90 mass% or less is more preferable. Moreover, content of the oil agent of a component (A) is 50 mass% or more of the oil agent total amount in a cosmetic base material, 55-95 mass% is preferable and 60-90 mass% is more preferable.

The layered silicate mineral of component (B) used in the present invention is one that is used in ordinary cosmetics, and examples thereof include sericite, mica, synthetic mica, kaolin, montmorillonite, hectorite and the like. Of these, sericite, mica, synthetic mica and kaolin are preferred.
By the presence of these minerals in the cosmetic base material, the entire powder base material is easily wetted with water and uniformly dispersed, and the fluidity of the slurry is increased and the physical properties are easily filled.
These layered silicate minerals are preferably used without hydrophobizing surface treatment since the fluidity of the slurry is deteriorated.

  The layered silicate mineral of component (B) can be used singly or in combination of two or more, and the content is a cosmetic because the powder is uniformly dispersed and there is no color unevenness in appearance. It is 1 mass% or more in a base material, 5 mass% or more is preferable and 10 mass% or more is more preferable. And since the fluidity | liquidity of a slurry is enough and it is excellent in a usability | use_condition, it is 50 mass% or less in a cosmetics base material, 45 mass% or less is preferable, and 40 mass% or less is more preferable. Moreover, content of a component (B) is 1-50 mass% in a cosmetics base material, 5-45 mass% is preferable, and 10-40 mass% is more preferable.

The hydrophilic spherical powder of component (C) used in the present invention is a hydrophilic one selected by the following operation. That is, 15 g of water and 15 g of liquid paraffin (manufactured by SONNEBORN, CARNATION) are placed in a glass bottle to form a two-layer system. After 0.1 g of powder is placed here, the lid is capped and stirred vigorously up and down. Put. When the liquid is again divided into two layers, the liquid dispersed on the aqueous phase side is made hydrophilic.
The spherical powder is a powder having a substantially spherical shape, and may be a spheroid, a spherical powder having irregularities on the surface, or the like. The rate is preferably 1.5 or less, more preferably 1.2 or less, and even more preferably 1.1 or less.

As the hydrophilic spherical powder, spherical silica powder is preferable. In addition, spherical nylon powder, spherical urethane powder and the like that have been hydrophilicized by introducing a hydroxyl group or a carboxyl group on a surface that is originally hydrophobic can also be used.
By using the hydrophilic spherical powder, the fluidity of the slurry is increased, and the amount of the cosmetic to be applied to the applicator is adjusted to the optimum amount.

  The hydrophilic spherical powder of component (C) can be used singly or in combination of two or more. The content is soft from the surface of the solid powder cosmetic, and the cosmetic can be easily applied to the applicator. It is 0.1 mass% or more in a material base material, 0.3 mass% or more is preferable and 0.5 mass% or more is more preferable. And from the point of impact resistance, it is 10 mass% or less in a cosmetics base material, 8 mass% or less is preferable, and 5 mass% or less is more preferable. Moreover, content of a component (C) is 0.1-10 mass% in a cosmetics base material, 0.3-8 mass% is preferable, and 0.5-5 mass% is more preferable.

  In the solid powder cosmetic of the present invention, the cosmetic base material other than the above components can be used as long as it is used in ordinary cosmetics, and other powders, oils, additives and the like can be used. Can be used.

Examples of powders other than the above include, for example, titanium mica, titanium oxide-coated synthetic phlogopite, iron oxide-coated synthetic phlogopite, iron oxide-coated mica titanium, iron oxide-coated mica, koji-coated mica titanium, carmine-coated mica titanium, titanium oxide. / Titanium oxide coated glass flakes, titanium oxide / iron oxide coated glass flakes, iron oxide coated glass flakes, silver coated glass flakes, gold coated glass flakes; silica coated aluminum powder; titanium oxide / silica multilayer coated silica Flakes: Polyethylene terephthalate / epoxy / aluminum laminate powder, polyethylene terephthalate / aluminum laminate powder, polyethylene terephthalate / polyurethane-11 / aluminum laminate powder, polyethylene terephthalate / polymethyl methacrylate laminate powder, polyethylene Bright powder such as terephthalate / polyolefin laminated powder; organic pigments such as red 104, red 202, red 226, yellow 4, yellow 5, blue 1, black 401, yellow 4 Al Lake organic pigment pigments such as lake, blue No. 1 Al lake; inorganic colored pigments such as yellow iron oxide, red iron oxide, black iron oxide, chromium oxide, chromium hydroxide, carbon black, ultramarine, bitumen, manganese violet; zinc oxide White pigments such as titanium oxide; extender pigments such as boron nitride; metal salt pigments such as barium sulfate, calcium carbonate, magnesium carbonate, aluminum silicate, and magnesium silicate; inorganic pigments such as silica and alumina; polyethylene powder, polypropylene powder, poly Methyl methacrylate powder, nylon powder, polytetrafluoroethylene powder, Metal soap powder and the like is a higher fatty acid metal salts; acylated lysine powder lauroyl lysine; corn powder, silicone rubber powder, silk powder, urethane powder, cellulose powder, resin powder such as polyfluoroethylene.
The size, shape, and the like of these powders are not limited and can be used alone or in combination of two or more. These powders may be appropriately surface-treated.

  The content of the powder is preferably 70% by mass or more, more preferably 75% by mass or more, and more preferably 80% by mass in the cosmetic base material as the total amount of the powder in order to sufficiently exert the cosmetic effect of imparting color and gloss. % Or more is more preferable. And from the point of shape retention property, 97 mass% or less is preferable, 96 mass% or less is more preferable, and 95 mass% or less is still more preferable. In addition, the content of the powder is preferably 70 to 97% by mass, more preferably 75 to 96% by mass, and still more preferably 80 to 95% by mass in the cosmetic base material as the total amount of the powder.

In addition, the oil agent other than the component (A) used for the cosmetic base material may be any oil used for ordinary cosmetics, for example, hydrocarbon oil, higher fatty acid, higher alcohol, various ester oils, silicone oil. And fluorine-based oils such as perfluoroalkyl ether.
It is preferable to add such an oil because the moist feeling of the final product and the adhesion to the skin are improved.

  These oil agents can be used singly or in combination of two or more, and the content of the oil agent is sufficient to exert effects such as shape retention, moist feeling of the final product, and adhesion to the skin. In the cosmetic base material, 3 mass% or more is preferable, 4 mass% or more is more preferable, and 5 mass% or more is still more preferable. And in order to avoid that the cosmetics surface solidifies and a usability | use_condition deteriorates, 30 mass% or less is preferable in a cosmetics base material as a total amount of oil agent, 25 mass% or less is more preferable, and 20 mass% or less is preferable. Further preferred. In addition, the content of the oil agent is preferably 3 to 30% by mass, more preferably 4 to 25% by mass, and still more preferably 5 to 20% by mass in the cosmetic base material as the total amount of the oil agent.

Moreover, a surfactant can also be mix | blended with a cosmetics base material in order to assist uniform dispersion | distribution of a component.
As the surfactant, any surfactant can be used as long as it is used in ordinary cosmetics, and examples thereof include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. . For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified organopolysiloxane, Examples include polyether-modified organopolysiloxane and lecithin.
As the surfactant, a nonionic surfactant is preferable.

  In addition, in cosmetic base materials, in order to improve the performance and quality of products, components used in ordinary cosmetics, such as moisturizers, pH adjusters, antioxidants, antibacterial and antifungal agents, UV absorption Various additives such as an agent, a fragrance, and a cosmetic ingredient can be appropriately blended within a range not impairing the effects of the present invention.

The cosmetic base is prepared by stirring and mixing the above ingredients using an apparatus for producing an ordinary powder cosmetic.
More specifically, the cosmetic base material is first mixed with an oil agent containing the component (A), and dissolved by heating as necessary. On the other hand, the powder containing components (B) and (C) is uniformly mixed. The powder is prepared by adding an oil agent to the powder and uniformly dispersing and pulverizing the powder.
By mixing the cosmetic base material thus obtained and a single or two or more mixed solvents selected from water and an aqueous solvent into a slurry, filling the container, and then removing the solvent, A solid powder cosmetic can be obtained.

Among the solvents used for mixing with the cosmetic base material, the aqueous solvent is preferably a low-boiling alcohol such as ethyl alcohol, propyl alcohol, isopropyl alcohol, or butyl alcohol.
As the solvent, water alone or an aqueous alcohol solution in which a low-boiling alcohol is dissolved in water is preferable. The low boiling alcohol concentration in the aqueous alcohol solution is preferably 50% by mass or less. The higher the alcohol concentration in the aqueous alcohol solution, the better the dispersion of the cosmetic base material during slurry preparation, and a solid powder cosmetic with excellent use feeling and sufficient impact resistance can be obtained. However, in the solid powder cosmetic of the present invention, it is possible to obtain a solid powder cosmetic having a very good feeling of use and sufficient impact resistance without using any low-boiling point alcohol. The low-boiling alcohol concentration in it can be more preferably 25% by mass or less, still more preferably 10% by mass or less, and particularly preferably 5% by mass or less.

  In the present invention, when a slurry is prepared using a cosmetic base material, water or an aqueous solvent, or a mixed solvent of two or more kinds, the cosmetic base material from the point that the slurry has fluidity suitable for filling. It is preferable to use 50 to 120 parts by mass of one or two or more mixed solvents selected from water and an aqueous solvent with respect to 100 parts by mass, and more preferably 70 to 100 parts by mass.

  After the cosmetic base material is mixed with one or two or more mixed solvents selected from water and an aqueous solvent, the container is filled and the solvent is removed by heating and drying. The heating temperature and the apparatus are not limited, but in order to dry and distill all the solvent, the temperature is preferably 30 ° C. or higher, more preferably 50 ° C. or higher. As the drying apparatus, it is preferable to use a hot air circulation type dryer without exposing the cosmetic to a high temperature locally.

  In the present invention, the wet-filling slurry containing the amphiphilic ester in the cosmetic base material is wetted by the powder and the slurry is rich in fluidity. It is most suitable for use in a wet back filling method, which is a kind of wet method for filling slurry.

  In addition, the slurry used in the present invention has high fluidity and can be uniformly filled into the cosmetic container, so that it is suitable for three-dimensional molding by back filling. The three-dimensional molding by back filling means that the surface is three-dimensionally molded, and the bottom of the container is pressed after pressing the member engraved with the cosmetic surface pattern and the three-dimensional shape inverted to the container opening at the time of back filling. In this molding method, the slurry is press-fitted from the filling hole provided in the upper portion and simultaneously solidified by absorbing the volatile solvent in the slurry from the opening upper pressure contact member. Here, the solid is not limited to a solid powder cosmetic material that is molded into a dome shape or a pyramid shape, but the surface of the solid powder cosmetic material is not a uniform height, This includes designs that are provided.

The solid powder cosmetic of the present invention can be applied as a foundation, eye shadow, teak or the like. In particular, it is suitable for use as an eye shadow.
This invention discloses the following compositions further regarding embodiment mentioned above.

<1> A cosmetic base material containing a powder and an oil agent, and a single or two or more mixed solvents selected from water and an aqueous solvent are mixed to form a slurry, filled in a container, and then the solvent is removed. It is a solid powder cosmetic obtained by doing the following components (A), (B) and (C):
(A) Oil agent that is liquid at 25 ° C. and has an IOB value of 0.2 or more: 50% by mass or more of the total amount of oil agent in the cosmetic base material,
(B) Layered silicate mineral: 1 to 50% by mass of the total amount of the cosmetic base material,
(C) Hydrophilic spherical powder: 0.1 to 10% by mass of the total amount of the cosmetic base material
Containing solid powder cosmetics.

<2> The solid powder cosmetic according to <1>, wherein the oil agent of component (A) is preferably an IOB value of 0.25 or more.
<3> The solid according to <1> or <2>, wherein the oil agent of component (A) is preferably a polyglycerin fatty acid ester selected from diglyceryl monoisostearate, diglyceryl diisostearate and diglyceryl triisostearate Powder cosmetic.
<4> The content <1> to <3, wherein the content of the component (A) is preferably 55 to 95% by mass, more preferably 60 to 90% by mass, based on the total amount of the oil in the cosmetic base material. > The solid powder cosmetic of any one of>.

<5> Any of the above <1> to <4>, wherein the layered silicate mineral of component (B) preferably contains one or more selected from sericite, mica, synthetic mica and kaolin The solid powder cosmetic according to 1.
<6> Any one of <1> to <5>, wherein the content of the component (B) is preferably 5 to 45% by mass, more preferably 10 to 40% by mass in the cosmetic base material. The solid powder cosmetic according to 1.
<7> The hydrophilic spherical powder of component (C) is preferably one or two selected from spherical silica powder, spherical nylon powder that has been hydrophilicized by introducing a hydroxyl group or a carboxyl group, and spherical urethane powder. Solid powder cosmetics any one of said <1>-<6> containing a seed | species or more.
<8> The above-mentioned <1> to <7, wherein the content of the component (C) is preferably 0.3 to 8% by mass, more preferably 0.5 to 5% by mass in the cosmetic base material. > The solid powder cosmetic of any one of>.

The content of <9> powder is preferably 70 to 97% by mass, more preferably 75 to 96% by mass, and still more preferably 80 to 95% by mass as the total amount of powder in the cosmetic base material. % Solid powder cosmetic according to any one of <1> to <8>.
<10> The content of the oil agent is preferably 3 to 30% by mass, more preferably 4 to 25% by mass, and further preferably 5 to 20% by mass as the total amount of the oil agent in the cosmetic base material. The solid powder cosmetic according to any one of <1> to <9>.
<11> Any of the above <1> to <10>, wherein the solvent is preferably water alone or an aqueous alcohol solution in which a low-boiling alcohol selected from ethyl alcohol, propyl alcohol, isopropyl alcohol and butyl alcohol is dissolved in water. The solid powder cosmetic according to claim 1.

<12> The solid powder cosmetic according to any one of <1> to <11>, wherein the slurry is back-filled from a hole provided in a bottom surface of the container.
<13> The solid powder cosmetic according to any one of <1> to <12>, wherein the surface is three-dimensionally molded.
<14> The solid powder cosmetic according to any one of <1> to <13>, which is a foundation, eye shadow, or teak.

<15> A cosmetic base prepared by mixing an oil containing the following component (A) and a powder containing the following components (B) and (C), alone or selected from water and an aqueous solvent A method for producing a solid powder cosmetic comprising mixing two or more mixed solvents to form a slurry, filling the container, and then removing the solvent.
(A) Oil that is liquid at 25 ° C. and has an IOB value of 0.2 or more: 50% by mass or more of the total amount of oil in the cosmetic base material (B) Layered silicate mineral: 1 of the total amount of cosmetic base material ~ 50% by mass
(C) Hydrophilic spherical powder: 0.1 to 10% by mass of the total amount of the cosmetic base material

  EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, the technical scope of this invention is not limited by these Examples. In addition, the numerical value in a table | surface shows content (mass%). Prior to the examples, the evaluation methods employed in each example will be described.

(1) Slurry fluidity:
Fill the syringe with the discharge port of 30mm inner diameter, length 280mm and diameter 1mm with 50g slurry, and apply the air pressure of 0.4Mpa to discharge the slurry from the discharge port according to the following criteria. evaluated.
(Evaluation criteria)
A: The entire amount was discharged continuously.
○: After discharging half or more, the discharge port was clogged.
Δ: The discharge port was clogged before half of the amount was discharged.
X: It was not possible to discharge at all.

(2) Appearance:
Ten solid powder cosmetics were produced under the same conditions, and the generation ratio of solid powder cosmetics with uneven color (a dark part and a light part are recognized) was evaluated according to the following criteria.
(Evaluation criteria)
A: Occurrence rate of uneven color is 0/10.
○: The occurrence ratio of color unevenness is 1/10 to 2/10.
(Triangle | delta); The generation | occurrence | production ratio of uneven color is 3/10 to 5/10.
X: Occurrence rate of uneven color is 6/10 to 10/10.

(3) Usability:
Twenty female panelists conducted sensory evaluation on the feeling of use (powder removal amount, good spreadability) when each solid powder cosmetic was applied to the skin. The results are shown by the following criteria.
(Evaluation criteria)
◎; More than 17 people answered good.
○: 12 to 16 people answered good.
Δ: 8 to 11 people answered good.
×: The number of people who answered good is 7 or less.

(4) Impact resistance:
Each solid powder cosmetic was incorporated in a makeup compact and repeatedly dropped onto a plywood having a height of 50 cm to a thickness of 15 mm in the horizontal direction, and the number of times until abnormalities such as chipping, cracking and cracking occurred was evaluated. The evaluation criteria are as follows.
(Evaluation criteria)
A: 11 times or more.
○: 7 to 10 times.
Δ: 5 to 6 times.
X: 4 times or less.

Examples 1-8, Comparative Examples 1-5
A solid powder cosmetic was produced with the composition shown in Table 1 below, and the test was conducted. The results are also shown in Table 1.

(Method for producing solid powder cosmetic)
A: Components 1 to 6 are mixed and dissolved by heating to 70 ° C.
B: Components 7 to 16 are mixed uniformly.
C: A was added to B and uniformly dispersed, and after pulverization, a cosmetic base material was obtained.
D: A slurry was prepared by mixing 100 parts by mass of C and 100 parts by mass of the solvent.
In Example 8, 80 parts by mass of water and 20 parts by mass of ethanol were mixed in advance and used.
E: The slurry of D was filled by back filling into an aluminum metal pan (2.7 cm × 2.7 cm square, 4 mm thick) having a hole with a diameter of 1 mm on the bottom.
F: The molded product was dried in a 50 ° C. dryer for 7 hours.

  As is clear from the results in Table 1, in Examples 1 to 8, all of the slurry fluidity, appearance, feeling of use, and impact resistance were good.

  When a solid powder cosmetic was produced with the following component composition and subjected to the above evaluation test, all of the fluidity, appearance, feeling of use and impact resistance of the slurry were good.

Example 9 (dome-shaped solid powder teak color)
(Ingredient) (mass%)
1. Diglyceryl triisostearate (IOB = 0.26) * 4
6.0
2. White petrolatum 1.5
3. Tri (capryl / capric acid) glycerin 2.5
4). Mica 10.0
5. Synthetic mica * 8 20.0
6). Spherical silica powder * 10 3.0
7). Titanium oxide 1.0
8). Covered with stearoyl aluminum glutamate (4%) Red No. 226 4.0
9. Yellow No. 4 aluminum lake 1.0
10. Bengala 2.0
11. Mica titanium 20.0
12 Tocopherol 0.1
13. Methylparaben 0.2
14 Sodium dehydroacetate 0.1
15. Barium sulfate balance
Total 100

(Production method)
A: Components 1 to 3 are mixed and heated to 70 ° C. to dissolve.
B: Components 4 to 15 are mixed uniformly.
C: A was added to B and dispersed uniformly, and after pulverization, a cosmetic base material was obtained.
D: A slurry was prepared by mixing 100 parts by mass of C and 100 parts by mass of water.
E: Slurry of D was filled by back filling into an aluminum metal pan having a hole with a diameter of 1 mm on the bottom.
In that case, the dome-shaped solid powder cheek color was prepared by making the opening top pressure contact member of the aluminum metal pan into an inverted dome shape.
F: The molded product was dried in a 50 ° C. dryer for 7 hours.

Example 10 (pyramid solid powder eye shadow)
(Ingredient) (mass%)
1. Diglyceryl diisostearate (IOB = 0.41) * 2
3.0
2. Methylphenyl polysiloxane * 11 5.0
3. Diisostearyl malate (IOB = 0.28) * 3 6.0
4). Octyldodecanol (IOB = 0.26) * 5 3.0
5. Sorbitan monoisostearate 0.1
6). Synthetic mica * 12 20.0
7). Boron nitride * 13 30.0
8). Aluminum stearate 3.0
9. Spherical silica powder * 10 1.0
10. Titanium oxide coated glass powder * 14 5.0
11. Titanium oxide coated synthetic phlogopite * 15 5.0
12 Titanium oxide / anhydrous silica composite coated mica titanium * 16 5.0
13. Silver-coated glass powder (average particle size 25 μm) * 17 2.0
14 Bengala 0.1
15. Tocopherol 0.1
16. Methylparaben 0.2
17. Sodium dehydroacetate 0.1
18. Lauroyl lysine-coated barium sulfate balance
Total 100
* 11: Silicone SH556 FLUID (manufactured by Dow Corning Toray)
* 12: PDM-40L (Topy Industries, Ltd.)
* 13: SHP-5 (manufactured by Mizushima Alloy Iron Company)
* 14: Metashine MC1040RS (manufactured by Nippon Sheet Glass Co., Ltd.)
* 15: Helios R100S (Topy Industries, Ltd.)
* 16: Chimiron Splendid Gold (Merck)
* 17: Metashine MC5150PSS1 (manufactured by Nippon Sheet Glass Co., Ltd.)

(Production method)
A: Components 1 to 5 are mixed and dissolved by heating to 70 ° C.
B: Components 6 to 18 are mixed uniformly.
C: A was added to B and dispersed uniformly, and after pulverization, a cosmetic base material was obtained.
D: A slurry was prepared by mixing 100 parts by mass of C and 120 parts by mass of water.
E: The slurry of D was filled and molded into a resin dish having a hole with a diameter of 1 mm on the bottom by back-filling.
At that time, a pyramid-shaped solid powder eye shadow was prepared by changing the opening upper pressure contact member of the resin dish into a reversed pyramid shape.
F: The molded product was dried in a 50 ° C. dryer for 7 hours.

Example 11 (solid powder foundation with brand logo engraved)
(Ingredient) (mass%)
1. Liquid paraffin 5.0
2. Diisostearyl malate (IOB = 0.28) * 3 2.0
3. Diglyceryl monoisostearate (IOB = 0.81) * 1
5.0
4). Mica 15.0
6). Aluminum stearate 3.0
7). Nylon powder * 18 5.0
8). Spherical silica powder * 10 5.0
9. Titanium oxide 20.0
10. Yellow iron oxide 2.0
11. Black iron oxide 0.2
12 Bengala 0.5
13. Mica titanium 5.0
14 Talc balance 15. Cross-linked methylsiloxane powder * 19 3.0
16. Tocopherol 0.1
17. Methylparaben 0.2
18. Sodium dehydroacetate 0.1
Total 100
* 18: SP-500 (Toray Industries, Inc.)
* 19: Trefill E-506S (Toray Dow Corning)

(Production method)
A: Components 1 to 3 are mixed and heated to 70 ° C. to dissolve.
B: Components 4 to 18 are mixed uniformly.
C: A was added to B and dispersed uniformly, and after pulverization, a cosmetic base material was obtained.
D: A slurry was prepared by mixing 100 parts by mass of C and 120 parts by mass of water.
E: The slurry of D was filled and molded into a resin dish having a hole with a diameter of 1 mm on the bottom by back-filling.
At that time, a solid powder foundation in which the brand logo was imprinted was prepared by providing an inverted brand logo sculpture on the upper pressure contact member of the opening of the resin dish.
F: The molded product was dried in a 50 ° C. dryer for 7 hours.

Examples 12-14, Comparative Examples 6-8
In the same manner as in Examples 1 to 8, solid powder cosmetics having the compositions shown in Table 2 were produced, and the fluidity, appearance, usability and impact resistance of the slurry were evaluated. The results are also shown in Table 2.

Claims (4)

A cosmetic base prepared by mixing an oil agent containing the following component (A) and a powder containing the following components (B) and (C), alone or two or more selected from water and an aqueous solvent A method for producing a solid powder cosmetic, comprising mixing the mixed solvent to form a slurry, filling the container, and then removing the solvent.
(A) Polyglycerin fatty acid ester selected from diglyceryl monoisostearate, diglyceryl diisostearate and diglyceryl triisostearate : 50% by mass or more of the total amount of oil in the cosmetic base material (B) layered silicate mineral: makeup 1-50% by mass of the total amount of the base material
(C) Hydrophilic spherical powder: 0.1 to 10% by mass of the total amount of the cosmetic base material Layered silicate minerals component (B), sericite, mica, one or process according to claim 1, wherein the solid powder cosmetic containing two or more selected from synthetic mica and kaolin. The manufacturing method of the solid powder cosmetics of Claim 1 or 2 shape | molded by back-filling a slurry from the hole provided in the container bottom face. Sterically claim 1-3 any one solid powder cosmetic method according to molding the surface.