JP6297548B2 - Nfcにより安定化された発泡体 - Google Patents

Nfcにより安定化された発泡体 Download PDF

Info

Publication number
JP6297548B2
JP6297548B2 JP2015521582A JP2015521582A JP6297548B2 JP 6297548 B2 JP6297548 B2 JP 6297548B2 JP 2015521582 A JP2015521582 A JP 2015521582A JP 2015521582 A JP2015521582 A JP 2015521582A JP 6297548 B2 JP6297548 B2 JP 6297548B2
Authority
JP
Japan
Prior art keywords
foam
nfc
fibrils
cellulose
octylamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2015521582A
Other languages
English (en)
Japanese (ja)
Other versions
JP2015523443A5 (enExample
JP2015523443A (ja
Inventor
ニコラス・チャング・セルヴィン
レンナルト・バリストレム
ラーシュ−エリク・ヴォーグベリ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cellutech AB
Original Assignee
Cellutech AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cellutech AB filed Critical Cellutech AB
Publication of JP2015523443A publication Critical patent/JP2015523443A/ja
Publication of JP2015523443A5 publication Critical patent/JP2015523443A5/ja
Application granted granted Critical
Publication of JP6297548B2 publication Critical patent/JP6297548B2/ja
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • C08K5/19Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B11/00Preparation of cellulose ethers
    • C08B11/02Alkyl or cycloalkyl ethers
    • C08B11/04Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals
    • C08B11/10Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals substituted with acid radicals
    • C08B11/12Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals substituted with acid radicals substituted with carboxylic radicals, e.g. carboxymethylcellulose [CMC]
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B11/00Preparation of cellulose ethers
    • C08B11/20Post-etherification treatments of chemical or physical type, e.g. mixed etherification in two steps, including purification
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C08B15/05Derivatives containing elements other than carbon, hydrogen, oxygen, halogens or sulfur
    • C08B15/06Derivatives containing elements other than carbon, hydrogen, oxygen, halogens or sulfur containing nitrogen, e.g. carbamates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0028Use of organic additives containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/26Cellulose ethers
    • C08L1/28Alkyl ethers
    • C08L1/286Alkyl ethers substituted with acid radicals, e.g. carboxymethyl cellulose [CMC]
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/26Cellulose ethers
    • C08L1/28Alkyl ethers
    • C08L1/288Alkyl ethers substituted with nitrogen-containing radicals
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D21H11/18Highly hydrated, swollen or fibrillatable fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D21H11/20Chemically or biochemically modified fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/56Foam
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/04Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/048Elimination of a frozen liquid phase
    • C08J2201/0482Elimination of a frozen liquid phase the liquid phase being organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2301/00Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2301/00Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • C08J2301/08Cellulose derivatives
    • C08J2301/26Cellulose ethers
    • C08J2301/28Alkyl ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/14Applications used for foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
JP2015521582A 2012-07-10 2013-07-10 Nfcにより安定化された発泡体 Expired - Fee Related JP6297548B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261670046P 2012-07-10 2012-07-10
US61/670,046 2012-07-10
SE1250822 2012-07-12
SE1250822-2 2012-07-12
PCT/SE2013/050889 WO2014011112A1 (en) 2012-07-10 2013-07-10 Nfc stabilized foam

Publications (3)

Publication Number Publication Date
JP2015523443A JP2015523443A (ja) 2015-08-13
JP2015523443A5 JP2015523443A5 (enExample) 2017-12-14
JP6297548B2 true JP6297548B2 (ja) 2018-03-20

Family

ID=49916400

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2015521582A Expired - Fee Related JP6297548B2 (ja) 2012-07-10 2013-07-10 Nfcにより安定化された発泡体

Country Status (7)

Country Link
US (1) US9556325B2 (enExample)
EP (1) EP2872244A4 (enExample)
JP (1) JP6297548B2 (enExample)
CN (1) CN104640620B (enExample)
CA (1) CA2878276A1 (enExample)
IN (1) IN2015DN00141A (enExample)
WO (1) WO2014011112A1 (enExample)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101570001B1 (ko) * 2014-06-25 2015-11-18 서울대학교산학협력단 나노피브릴화 셀룰로오스를 이용한 nfc 폼 제조 방법 및 이를 이용하여 제조된 nfc 폼
CA2963633A1 (en) * 2014-10-30 2016-05-06 Cellutech Ab Cnf cellular solid material with anionic surfactants
EP3212697B1 (en) * 2014-10-30 2021-01-06 Cellutech AB Cnf cellular solid material
EP3023455A1 (en) 2014-11-21 2016-05-25 Fundacíon Tecnalia Research & Innovation Porous cellulosic materials and process for their preparation
JP2018502742A (ja) * 2014-12-23 2018-02-01 ダウ グローバル テクノロジーズ エルエルシー 処理済み多孔質材料
SE540731C2 (en) 2015-06-26 2018-10-23 Stora Enso Oyj Manufacturing method for a film or a film product comprising an amphiphilic polymer
SE539714C2 (en) * 2016-03-11 2017-11-07 Innventia Ab Method of producing shape-retaining cellulose products, and shape-retaining cellulose products therefrom
US20210283260A1 (en) * 2016-07-08 2021-09-16 Cellutech Ab A cellular solid material drug carrier comprising cellulose nanofibers (cnf) wherein the cellular solid material comprises closed cells
FI20165904A7 (fi) 2016-11-28 2018-05-29 Teknologian Tutkimuskeskus Vtt Oy Elastomeeriset vaahtokuitumateriaalit ja niiden valmistus
JP7172033B2 (ja) * 2017-03-01 2022-11-16 王子ホールディングス株式会社 繊維状セルロース、繊維状セルロース含有組成物、繊維状セルロース分散液及び繊維状セルロースの製造方法
CN111247196B (zh) * 2017-10-17 2023-07-25 切卢特克股份公司 包含cnf和阴离子胶凝多糖的生物复合材料
US11053425B2 (en) 2017-12-19 2021-07-06 Halliburton Energy Services, Inc. Pickering foam drilling fluids
CN112399987A (zh) 2018-07-10 2021-02-23 切卢特克股份公司 纤维素纤维和麸质的多孔材料
SE544302C2 (en) * 2019-12-18 2022-03-29 Stora Enso Oyj Coated paper or paperboard and a method for manufacturing a coated paper or paperboard
US12209358B2 (en) 2020-02-18 2025-01-28 The Hong Kong Research Institute Of Textiles And Apparel Limited Method for preparing water repellent textile substrates and products thereof
EP3868789A1 (en) 2020-02-18 2021-08-25 The Hong Kong Research Institute of Textiles and Apparel Limited Method for preparing water repellent textile substrates and products thereof
CN111705542B (zh) * 2020-05-27 2022-02-15 仙鹤股份有限公司 一种贴片电容器纸的制备方法
AU2022287908A1 (en) 2021-06-09 2023-12-14 Soane Materials Llc Articles of manufacture comprising nanocellulose elements
SE547308C2 (en) * 2021-12-22 2025-06-24 Stora Enso Oyj Foam composition comprising cellulose fibres, water-soluble thickener and surfactants, and method for its preparation
SE547309C2 (en) * 2021-12-22 2025-06-24 Stora Enso Oyj Foam composition comprising cellulose fibres, water -soluble thickener and surfactants, and method for its preparation
CN116905277B (zh) * 2023-07-04 2025-04-04 华南理工大学 一种泡沫成型专用纤维分散发泡剂及其制备方法与应用

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3311115A (en) 1963-10-29 1967-03-28 Buckeye Cellulose Corp Low density aerosol filter
AT403296B (de) * 1995-08-11 1997-12-29 Chemiefaser Lenzing Ag Verfahren zur herstellung eines celluloseformkörpers
FR2767541B1 (fr) * 1997-08-21 1999-10-08 Hutchinson Matiere spongieuse, son procede de fabrication et ses applications
FR2794762B1 (fr) 1999-06-14 2002-06-21 Centre Nat Rech Scient Dispersion de microfibrilles et/ou de microcristaux, notamment de cellulose, dans un solvant organique
EP1263792A1 (en) * 2000-03-09 2002-12-11 Hercules Incorporated Stabilized microfibrillar cellulose
WO2007068127A1 (en) 2005-12-12 2007-06-21 Eth Zurich Ultrastable particle-stabilized foams and emulsions
EP2062922A1 (de) * 2007-11-14 2009-05-27 Basf Se Verfahren zur Herstellung von regenerierten Biopolymeren und die danach erhältlichen regenerierten Erzeugnisse
AT506657A1 (de) * 2008-04-14 2009-10-15 Chemiefaser Lenzing Ag Cellulosebasiertes hydrogel und verfahren zu seiner herstellung
US20100065236A1 (en) 2008-09-17 2010-03-18 Marielle Henriksson Method of producing and the use of microfibrillated paper
GB0818419D0 (en) * 2008-10-08 2008-11-12 Imp Innovations Ltd Nanocomposites
JP2010106055A (ja) * 2008-10-28 2010-05-13 Toray Ind Inc 機能性セルロース組成物およびその製造方法
JP5604444B2 (ja) 2008-12-19 2014-10-08 エスセーアー・ハイジーン・プロダクツ・アーベー 超吸収ポリマーとセルロース系ナノフィブリルとを含む超吸収ポリマー複合材
WO2010073678A1 (ja) * 2008-12-26 2010-07-01 王子製紙株式会社 微細繊維状セルロースシートの製造方法および前記微細繊維状セルロースシートに樹脂含浸した複合体
EP2432933A4 (en) 2009-05-18 2013-07-31 Swetree Technologies Ab PROCESS FOR PRODUCTION AND USE OF MICROFIBRILLED PAPER
FI20095638A0 (fi) 2009-06-09 2009-06-09 Valtion Teknillinen Hydrofobiineja aktiivisten aineiden dispergointiin
JP5397910B2 (ja) * 2010-07-14 2014-01-22 国立大学法人 東京大学 セルロースナノファイバー分散液の製造方法
JP5640591B2 (ja) * 2010-09-14 2014-12-17 コニカミノルタ株式会社 断熱シート
JP5477265B2 (ja) * 2010-11-30 2014-04-23 王子ホールディングス株式会社 微細繊維状セルロースコンポジット多孔性シートの製造方法

Also Published As

Publication number Publication date
CN104640620A (zh) 2015-05-20
IN2015DN00141A (enExample) 2015-06-12
EP2872244A1 (en) 2015-05-20
HK1209680A1 (zh) 2016-04-08
JP2015523443A (ja) 2015-08-13
EP2872244A4 (en) 2016-03-09
WO2014011112A1 (en) 2014-01-16
US20150158995A1 (en) 2015-06-11
CA2878276A1 (en) 2014-01-16
CN104640620B (zh) 2016-10-05
US9556325B2 (en) 2017-01-31

Similar Documents

Publication Publication Date Title
JP2015523443A (ja) Nfcにより安定化された発泡体
Benselfelt et al. The colloidal properties of nanocellulose
Bai et al. Comparison of hydrophilicity and mechanical properties of nanocomposite membranes with cellulose nanocrystals and carbon nanotubes
Wang et al. An ultralight, elastic, cost-effective, and highly recyclable superabsorbent from microfibrillated cellulose fibers for oil spillage cleanup
Zhang et al. A sustainable nanocellulose-based superabsorbent from kapok fiber with advanced oil absorption and recyclability
Garemark et al. Strong, shape-memory lignocellulosic aerogel via wood cell wall nanoscale reassembly
Kwak et al. Prevention of cellulose nanofibril agglomeration during dehydration and enhancement of redispersibility by hydrophilic gelatin
Yang et al. Self-healing and recyclable biomass aerogel formed by electrostatic interaction
Kalashnikova et al. Modulation of cellulose nanocrystals amphiphilic properties to stabilize oil/water interface
Huang et al. Extremely strong and transparent chitin films: a high‐efficiency, energy‐saving, and “Green” route using an aqueous KOH/Urea solution
Laitinen et al. Sustainable stabilization of oil in water emulsions by cellulose nanocrystals synthesized from deep eutectic solvents
Xhanari et al. Reduction of water wettability of nanofibrillated cellulose by adsorption of cationic surfactants
US11827722B2 (en) Cellulose acetate aerogels
EP3212697B1 (en) Cnf cellular solid material
Liu et al. Comparative study of ultra-lightweight pulp foams obtained from various fibers and reinforced by MFC
Paladini et al. Cross-linked cellulose nano-sponges: A small angle neutron scattering (SANS) study
Gicquel et al. Tailoring rheological properties of thermoresponsive hydrogels through block copolymer adsorption to cellulose nanocrystals
Santmarti et al. Prevention of interfibril hornification by replacing water in nanocellulose gel with low molecular weight liquid poly (ethylene glycol)
CA2963633A1 (en) Cnf cellular solid material with anionic surfactants
Xu et al. Porous cellulose aerogels with high mechanical performance and their absorption behaviors
Badakhshanian et al. Enhancement of mechanical properties of nanohydrogels based on natural gum with functionalized multiwall carbon nanotube: study of swelling and drug release
US20160130370A1 (en) Compositions and structures including nonaggregated stabilized charged polysaccharide nanofibers, methods of making nonaggregated stabilized charged polysaccharide nanofibers, and method of making structures
Reid et al. Comparison of polyethylene glycol adsorption to nanocellulose versus fumed silica in water
Missale et al. Cellulose nanocrystal composites with enhanced mechanical properties for robust transparent thin films
Dmitrenko et al. Mixed matrix membranes based on sodium alginate modified by fullerene derivatives with L-amino acids for pervaporation isopropanol dehydration

Legal Events

Date Code Title Description
RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20160217

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20160623

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20170606

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20170825

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20171030

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20171030

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20180130

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20180221

R150 Certificate of patent or registration of utility model

Ref document number: 6297548

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees