JP6162348B2 - Decolorization aid and decolorization agent - Google Patents
Decolorization aid and decolorization agent Download PDFInfo
- Publication number
- JP6162348B2 JP6162348B2 JP2016559673A JP2016559673A JP6162348B2 JP 6162348 B2 JP6162348 B2 JP 6162348B2 JP 2016559673 A JP2016559673 A JP 2016559673A JP 2016559673 A JP2016559673 A JP 2016559673A JP 6162348 B2 JP6162348 B2 JP 6162348B2
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- Prior art keywords
- agent
- aid
- hair
- calcium
- oxide
- Prior art date
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- 238000004042 decolorization Methods 0.000 title claims description 45
- 239000003795 chemical substances by application Substances 0.000 claims description 115
- 210000004209 hair Anatomy 0.000 claims description 67
- 239000007854 depigmenting agent Substances 0.000 claims description 22
- 239000003513 alkali Substances 0.000 claims description 20
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 20
- 239000011777 magnesium Substances 0.000 claims description 20
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 19
- 239000011575 calcium Substances 0.000 claims description 19
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 19
- 239000000292 calcium oxide Substances 0.000 claims description 19
- 229910052749 magnesium Inorganic materials 0.000 claims description 19
- 239000000395 magnesium oxide Substances 0.000 claims description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 19
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 19
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 18
- 229910052791 calcium Inorganic materials 0.000 claims description 18
- 230000006378 damage Effects 0.000 claims description 18
- 239000002131 composite material Substances 0.000 claims description 16
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- 238000007254 oxidation reaction Methods 0.000 claims description 13
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- 230000001590 oxidative effect Effects 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 5
- 230000003700 hair damage Effects 0.000 claims description 4
- 238000007447 staining method Methods 0.000 claims description 2
- 230000003113 alkalizing effect Effects 0.000 claims 4
- 230000037380 skin damage Effects 0.000 claims 2
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- 235000011152 sodium sulphate Nutrition 0.000 description 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- ZNYIJXQYUNSKDX-NTISSMGPSA-M sodium;hydron;(2s)-2-(tetradecanoylamino)pentanedioate Chemical compound [Na+].CCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O ZNYIJXQYUNSKDX-NTISSMGPSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- UQZIYBXSHAGNOE-XNSRJBNMSA-N stachyose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO[C@@H]3[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O3)O)O2)O)O1 UQZIYBXSHAGNOE-XNSRJBNMSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229960003495 thiamine Drugs 0.000 description 1
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- 235000019798 tripotassium phosphate Nutrition 0.000 description 1
- SVETUDAIEHYIKZ-IUPFWZBJSA-N tris[(z)-octadec-9-enyl] phosphate Chemical compound CCCCCCCC\C=C/CCCCCCCCOP(=O)(OCCCCCCCC\C=C/CCCCCCCC)OCCCCCCCC\C=C/CCCCCCCC SVETUDAIEHYIKZ-IUPFWZBJSA-N 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- LNRUEZIDUKQGRH-YZUCMPLFSA-N umbelliferose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 LNRUEZIDUKQGRH-YZUCMPLFSA-N 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 210000003135 vibrissae Anatomy 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000010374 vitamin B1 Nutrition 0.000 description 1
- 239000011691 vitamin B1 Substances 0.000 description 1
- 235000019164 vitamin B2 Nutrition 0.000 description 1
- 239000011716 vitamin B2 Substances 0.000 description 1
- 235000019158 vitamin B6 Nutrition 0.000 description 1
- 239000011726 vitamin B6 Substances 0.000 description 1
- 150000003700 vitamin C derivatives Chemical class 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 235000019168 vitamin K Nutrition 0.000 description 1
- 239000011712 vitamin K Substances 0.000 description 1
- 150000003721 vitamin K derivatives Chemical class 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940011671 vitamin b6 Drugs 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 229940046010 vitamin k Drugs 0.000 description 1
- 229940118846 witch hazel Drugs 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
本発明は、脱色助剤及び脱色剤、より詳しくは体毛のダメージ(損傷)を大幅に改善した、脱色助剤及び脱色剤に関する。 The present invention relates to a decolorization aid and a decolorization agent, and more particularly to a decolorization aid and a decolorization agent that have greatly improved damage (damage) to hair.
従来から、(体毛)脱色剤が広く一般に使用されている。脱色剤は、体毛本来の色(メラニン色素)を除去するものであり、現在、脱色剤は、染色剤とともに広汎な使用がなされている。特に、染毛剤(料)は、体毛(特に、頭髪、髭)を様々なカラーに染色することができるものとして、個人のスタイル、デザイン、嗜好に合わせて使用されている。このため、嗜好者は、様々な色に染める際に、より染色性が高い染色手段を希望することがあり、染色の前に脱色剤を使用することがよく行われる。脱色剤により体毛からメラニン色素を抜くことにより、その後、染色剤を使用して体毛を染色する際、染色剤の染色力、定着率等を達成することが可能となる。 Conventionally, (body hair) depigmenting agents have been widely used. The depigmenting agent removes the original color (melanin pigment) of body hair, and at present, the decoloring agent is widely used together with the dyeing agent. In particular, hair dyes (materials) are used in accordance with individual styles, designs, and preferences as they can dye body hair (especially, hair and wrinkles) in various colors. For this reason, a taster may desire a dyeing means with higher dyeability when dyeing various colors, and a decoloring agent is often used before dyeing. By removing the melanin pigment from the body hair with the decolorizing agent, it is possible to achieve the staining power, the fixing rate, etc. of the staining agent when the hair is subsequently dyed using the staining agent.
しかしながら、脱色剤は、そもそも、体毛が本来備えているメラニン色素を脱色して抜くものであることから、体毛に著しい損傷を与えることとなり、体毛本来の機能を阻害することがある。そのため、脱色剤を頻繁に使用することは好ましくない。また、脱色剤は、アルカリ剤及び過硫酸塩を包含する第1剤と、過酸化水素を包含する第2剤とにより構成されてなるものが一般的である。しかしながら、これらの剤を体毛に使用すると、体毛のみならず、体膚を損傷し、痒み、爛れ、アレルギー性皮膚炎を生じることもありうる。このため、脱色する動物(人間含む)及び脱色を行う施術者の体、特に、指、手、腕等に対して、十分配慮して調剤した脱色剤であることが望まれる。また、アルカリ剤、過酸化物は、保存安定性が優れず、かつ、長期反応安定性を実現することができないものが多い。 However, since the depigmenting agent decolorizes and removes the melanin pigment originally provided in the body hair, it will cause significant damage to the body hair and may inhibit the original function of the body hair. Therefore, it is not preferable to use a decoloring agent frequently. Moreover, the decoloring agent is generally composed of a first agent containing an alkali agent and a persulfate and a second agent containing hydrogen peroxide. However, when these agents are used on body hair, not only the body hair but also the skin may be damaged, and itching, itching, and allergic dermatitis may occur. For this reason, it is desired to be a decolorizing agent prepared with sufficient consideration for the animals (including humans) to be decolorized and the body of the practitioner performing decoloring, in particular, fingers, hands, arms, and the like. Further, many alkali agents and peroxides are not excellent in storage stability and cannot realize long-term reaction stability.
これに対して、保存安定性を向上させるために、特許文献1(特開2015−17138)によれば、炭酸系のアンモニウム塩を含有する薬剤において、リン酸塩を併用させることが提案されている。また、特許文献2(特開2012−167054)では、アルカリ剤を包含する第1剤及び酸化剤が配合された第2剤を備える染毛剤又は毛髪脱色剤として用いられる毛髪処理剤において、第1剤のpHを9.8未満に設定し、更に、第1剤には炭酸系アンモニウム塩及びリン酸系アンモニウム塩を配合し、かつ、第1剤における炭酸系アンモニウム塩の配合濃度を7.5質量%未満としたものが提案されている。 On the other hand, in order to improve the storage stability, according to Patent Document 1 (Japanese Patent Application Laid-Open No. 2015-17138), it is proposed to use a phosphate in a medicine containing a carbonated ammonium salt. Yes. Moreover, in patent document 2 (Unexamined-Japanese-Patent No. 2012-167054), in the hair treatment agent used as a hair dye or a hair decoloring agent provided with the 1st agent containing an alkaline agent and the 2nd agent with which the oxidizing agent was mix | blended, The pH of one agent is set to less than 9.8, and further, a carbonate ammonium salt and a phosphate ammonium salt are added to the first agent, and the compounding concentration of the carbonate ammonium salt in the first agent is 7. What was made less than 5 mass% is proposed.
しかしながら、本発明者等の検討によれば、アルカリ剤及び過硫酸塩を包含する第1剤と、過酸化水素を包含する第2剤とにより構成されてなる脱色剤にあっては、やはり、体毛及び体膚の損傷を十分に抑制することができるものは存在しておらず、未だ、この点において十分改良することが必要であるとの認識に至った。 However, according to the study by the present inventors, in the decoloring agent constituted by the first agent containing the alkali agent and persulfate and the second agent containing hydrogen peroxide, There is no one that can sufficiently suppress damage to body hair and skin, and it has been recognized that there is still a need for improvement in this respect.
従って、本発明者等は、脱色剤における脱色力をそのままに、脱色剤を使用した際に生じる体毛及び体膚の損傷を大幅に改善することができる、新規な脱色助剤及びそれを用いた脱色剤の開発が極めて必要であることを認識したのである。 Therefore, the present inventors have used a novel decolorization aid that can greatly improve the damage to hair and skin that occurs when using a decoloring agent while maintaining the decoloring power in the decoloring agent. He recognized that the development of depigmenting agents was extremely necessary.
本発明者は、マグネシウム(Mg)及び/又はカルシウム(Ca)の酸化物を採用することにより、脱色する体毛及び体膚並びに脱色をする施術者の体(特に、体膚)に損傷を与えることなく、十分な脱色を行うことができる脱色助剤及びそれを用いた脱色剤を提案することができるとの知見を得た。本発明はかかる知見に基づいてなされたものである。 By adopting magnesium (Mg) and / or calcium (Ca) oxides, the inventor damages the hair and skin to be decolorized and the body (especially the body skin) to be decolorized. In addition, the present inventors have found that a decoloring aid capable of performing sufficient decolorization and a decoloring agent using the same can be proposed. The present invention has been made based on such findings.
従って、本発明が提案する脱色助剤は、
脱色剤に使用されるものであり、
酸化マグネシウム、酸化カルシウム、又はマグネシウム及びカルシウムの複合酸化物を含んでなるものである。Therefore, the decoloring aid proposed by the present invention is:
Used for depigmenting agents,
Magnesium oxide, calcium oxide, or a composite oxide of magnesium and calcium.
本発明によれば、従来の脱色剤と比較して、体毛及び体膚の損傷を抑制し或いは保護しつつ、迅速かつ簡易に体毛からメラニン色素を脱色することが可能であるという効果を発揮させることができる。 According to the present invention, as compared with a conventional depigmenting agent, it is possible to quickly and easily decolorize melanin from body hair while suppressing or protecting damage to body hair and skin. be able to.
〔定義〕
「脱色助剤」とは、脱色目的に使用される、脱色剤による急激な脱色を抑制し、体毛及び体膚への刺激及び損傷を緩和する機能を発揮させるものであり、脱色剤以外の助剤として、脱色剤に包含される助剤添加剤として、又は、脱色セットの一構成物である助剤として、用いられるものである。
「脱色剤」とは、体毛の色素であるメラニンを分解して脱色することを主目的として使用される剤であり、「ヘアブリーチ、ヘアライトナー」等とも呼ばれるものである。
「脱染剤」とは、体毛が本来有する色素(特に、メラニン色素)を脱色するのではなく、体毛に施された着色剤(染色剤)を除去することを主目的として使用される剤である。従って、この意味において、「脱色剤」は、「脱染剤」とは区分けされてなるものである。
「脱色剤」は、「医薬品、医療機器等の品質、有効性及び安全性の確保等に関する法律」に基づいて、「医薬部外品」に該当するものであり、一般的に、「美容用剤」、「健康・生活用品」、「化粧品」に属するものであってよい。
「体毛」とは、動物の体表に存在するものであり、頭髪、耳毛、鼻毛、腋毛、胸毛、腹毛、陰毛、脛毛、産毛、揉み上げ、髭、睫毛、眉毛、柔毛、埋没毛又は指毛等を意味し、本発明にあっては、好ましくは、頭髪、睫毛、眉毛、揉み上げ、髭、脛毛、腹毛、陰毛等を対象とする。
「体膚」とは、体を構成する体表面に形成された皮膚を意味する。
「動物」とは、人類を含む動物を意味する。[Definition]
“Decolorization aid” is used for the purpose of decolorization and suppresses the rapid decolorization caused by the decolorization agent and exerts the function of mitigating irritation and damage to body hair and skin. As an agent, it is used as an auxiliary agent included in a decoloring agent or as an auxiliary agent which is a component of a decoloring set.
The “depigmenting agent” is an agent mainly used for decolorizing by decomposing melanin, which is a pigment of body hair, and is also called “hair bleach, hair lightener” or the like.
“Decoloring agent” is an agent used mainly for the purpose of removing the coloring agent (dyeing agent) applied to the hair rather than decolorizing the pigment inherent in the body hair (particularly melanin pigment). is there. Therefore, in this sense, the “decoloring agent” is separated from the “decoloring agent”.
“Decolorizers” fall under the category of “quasi-drugs” based on the “Law for the Quality, Effectiveness and Safety of Pharmaceuticals, Medical Devices, etc.” It may belong to “agents”, “health / life products”, and “cosmetics”.
“Body hair” is present on the animal's body surface, head hair, ear hair, nasal hair, eyelashes, chest hair, abdomen, pubic hair, tibia, vellus hair, brushed hair, eyelashes, eyelashes, eyebrows, soft hair, buried In the present invention, hair, finger hair, and the like are preferred, and preferably hair, eyelashes, eyebrows, squeezed hair, eyelashes, tibia, abdomen, pubic hair, and the like.
“Body skin” means skin formed on the body surface constituting the body.
“Animal” means animals including humans.
[本発明の第1の態様]
本発明の第1の態様により提案される脱色助剤は、
脱色剤に使用されるものであり、
酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物並びにこれらの混合物を含んでなるものである。[First embodiment of the present invention]
The decolorization aid proposed by the first aspect of the present invention is:
Used for depigmenting agents,
Magnesium oxide, calcium oxide, a composite oxide of magnesium and calcium, and a mixture thereof.
本発明にあっては、酸化マグネシウム及び酸化カルシウムは、天然物由来又は化学合成によって得られるものであってよく、好ましくは、天然物由来のものがよい。酸化マグネシウムは、水酸化マグネシウムを焼成して得られるものであり、海水またはマグネシウムを有意量包含するものから抽出して得ることもできる。酸化カルシウムは、炭酸カルシウムの熱分解反応生成物、石灰(岩)、貝殻などをか焼して得ることが可能である。マグネシウム及びカルシウムの複合酸化物は、上記酸化物の製造によって得られる副産物であってよく、また通常の方法で製造されてなるものが使用可能である。 In the present invention, magnesium oxide and calcium oxide may be derived from a natural product or obtained by chemical synthesis, and preferably derived from a natural product. Magnesium oxide is obtained by baking magnesium hydroxide, and can also be obtained by extracting from seawater or a substance containing a significant amount of magnesium. Calcium oxide can be obtained by calcining a thermal decomposition reaction product of calcium carbonate, lime (rock), shells and the like. The complex oxide of magnesium and calcium may be a byproduct obtained by the production of the above oxide, and those produced by a usual method can be used.
本発明の好ましい態様によれば、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物は、多孔性のものが好ましくは使用される。多孔性の場合、そのBET比表面積は、20m2/g以上であり、好ましくは40m2/g以上であり、100m2/g以上であるものが好ましい。According to a preferred embodiment of the present invention, a porous oxide is preferably used as the composite oxide of magnesium oxide, calcium oxide, magnesium and calcium. In the case of porosity, the BET specific surface area is 20 m 2 / g or more, preferably 40 m 2 / g or more, and preferably 100 m 2 / g or more.
[本発明の第2の態様]
本発明の第2の態様により提案される脱色剤(一剤型)は、
アルカリ剤又は酸化助剤(好ましくは両者)と、及び脱色助剤とを含んでなり、
前記脱色助剤が、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなるものである。[Second embodiment of the present invention]
The depigmenting agent (one agent type) proposed by the second aspect of the present invention is:
An alkali agent or an oxidation aid (preferably both), and a decolorization aid,
The decolorization assistant comprises magnesium oxide, calcium oxide, a composite oxide of magnesium and calcium, or a mixture thereof.
〔アルカリ剤〕
本発明に用いるアルカリ剤は、いずれのものも使用可能であり、従来のもの、或いは、今後登場するであろうものを使用することが可能である。
アルカリ剤の具体例としては、無機又は有機のアルカリ剤の一種又は二種以上の混合物を用いることができる。無機アルカリ剤の具体例としては、アンモニア;炭酸ナトリウム、炭酸カリウム、炭酸アンモニウム等の炭酸塩;炭酸水素ナトリウム、炭酸水素カリウム、炭酸水素アンモニウム等の炭酸水素塩;酒石酸カリウムナトリウムなどの酒石酸塩;クエン酸三ナトリウム、クエン酸三カリウムなどのクエン酸塩;リン酸三ナトリウム、リン酸三カリウムなどのリン酸塩;ピロリン酸ナトリウムなどのピロリン酸塩;ケイ酸ナトリウムなどのケイ酸塩;メタケイ酸ナトリウムなどのメタケイ酸塩;酢酸ナトリウム、酢酸カリウム、酢酸カルシウムなどの酢酸塩等を例示することができる。
有機アルカリ剤の具体例としては、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、イソプロパノールアミン、2−アミノ−2−メチル−1−プロパノール、2−アミノ−2−メチル−1,3−プロパンジオール等を例示することができる。(Alkaline agent)
Any alkali agent used in the present invention can be used, and conventional ones or those that will appear in the future can be used.
As a specific example of the alkali agent, one or a mixture of two or more inorganic or organic alkali agents can be used. Specific examples of the inorganic alkaline agent include ammonia; carbonates such as sodium carbonate, potassium carbonate, and ammonium carbonate; bicarbonates such as sodium bicarbonate, potassium bicarbonate, and ammonium bicarbonate; tartrate salts such as potassium sodium tartrate; Citrates such as trisodium phosphate and tripotassium citrate; phosphates such as trisodium phosphate and tripotassium phosphate; pyrophosphates such as sodium pyrophosphate; silicates such as sodium silicate; sodium metasilicate Examples thereof include metasilicates such as: acetates such as sodium acetate, potassium acetate, and calcium acetate.
Specific examples of the organic alkali agent include monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1,3-propanediol and the like. It can be illustrated.
〔酸化助剤〕
酸化助剤の具体例としては、過硫酸ナトリウム、過硫酸カリウム、過硫酸アンモニウム等の過硫酸塩等を例示することができる。[Oxidation aid]
Specific examples of the oxidation aid include persulfates such as sodium persulfate, potassium persulfate, and ammonium persulfate.
〔脱色助剤〕
脱色助剤は、本発明の第1の態様で説明したのと同様であってよい。[Decolorization aid]
The decoloring aid may be the same as described in the first aspect of the present invention.
本発明にあっては、脱色助剤の混合比率は、脱色助剤を除いた脱色剤量に対する質量比において、1:0.1以上であり、1:2以下であり、好ましくは1:0.6以上であり、1:1以下である。 In the present invention, the mixing ratio of the decoloring aid is 1: 0.1 or more, 1: 2 or less, preferably 1: 0 in terms of the mass ratio to the amount of decoloring agent excluding the decoloring aid. .6 or more and 1: 1 or less.
[本発明の第3の態様]
本発明の第3の態様により提案される脱色剤は、
第1剤と第2剤とを備えてなり、
前記第1剤が、アルカリ剤又は酸化助剤(好ましくは両者)と、及び脱色助剤とを含んでなり、
前記脱色助剤が、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなるものであり、
前記第2剤が、酸化剤を含有してなるものである。[Third Aspect of the Present Invention]
The depigmenting agent proposed by the third aspect of the present invention is:
Comprising a first agent and a second agent;
The first agent comprises an alkali agent or an oxidation aid (preferably both), and a decolorization aid,
The decolorization aid comprises magnesium oxide, calcium oxide, a composite oxide of magnesium and calcium, or a mixture thereof,
The second agent contains an oxidizing agent.
〔第2剤:酸化剤〕
本発明に用いる酸化剤(第2剤)は、いずれのものも使用可能であり、従来のもの、或いは、今後登場するであろうものを使用することが可能である。
酸化剤の具体例としては、過酸化水素、過ホウ酸ナトリウム、過酸化尿素、過酸化メラミン、硫酸ナトリウム・過酸化水素付加物、ピロリン酸ナトリウム・過酸化水素付加物、第二リン酸ナトリウム・過酸化水素付加物、過炭酸ナトリウム、臭素酸ナトリウムなどが挙げられる。[Second agent: oxidizing agent]
Any of the oxidizing agents (second agents) used in the present invention can be used, and conventional ones or those that will appear in the future can be used.
Specific examples of the oxidizing agent include hydrogen peroxide, sodium perborate, urea peroxide, melamine peroxide, sodium sulfate / hydrogen peroxide adduct, sodium pyrophosphate / hydrogen peroxide adduct, dibasic sodium phosphate, Examples include hydrogen peroxide adduct, sodium percarbonate, sodium bromate and the like.
本発明にあっては、第2剤(酸化剤)の混合比率は、脱色助剤を含む第1剤の全量に対して、体積比で1:1以上であり、1:5以下であり、好ましくは1:2以上であり、1:3以下であり、質量比で1:1以上であり、1:10以下であり、好ましくは1:5以上であり、1:6以下である。 In the present invention, the mixing ratio of the second agent (oxidizing agent) is 1: 1 or more and 1: 5 or less by volume with respect to the total amount of the first agent including the decolorization aid. Preferably, it is 1: 2 or more, 1: 3 or less, and mass ratio is 1: 1 or more, 1:10 or less, preferably 1: 5 or more, and 1: 6 or less.
アルカリ剤、酸化助剤、及び脱色助剤は、本発明の第1及び第2の態様で説明したのと同様であってよい。 The alkali agent, the oxidation aid, and the decolorization aid may be the same as those described in the first and second aspects of the present invention.
[本発明の第4の態様]
本発明の第4の態様により提案される脱色セットは、
第1剤と、第2剤と、第3剤を備えてなり、
前記第1剤が、アルカリ剤又は酸化助剤(好ましくは両者)を含んでなり、
前記第2剤が、脱色助剤を含んでなり、
前記脱色助剤が、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなるものであり、
前記第3剤が、酸化剤を含有してなるものである。[Fourth aspect of the present invention]
The decolorization set proposed by the fourth aspect of the present invention is:
Comprising a first agent, a second agent, and a third agent;
The first agent comprises an alkali agent or an oxidation aid (preferably both),
The second agent comprises a decolorization aid;
The decolorization aid comprises magnesium oxide, calcium oxide, a composite oxide of magnesium and calcium, or a mixture thereof,
The third agent contains an oxidizing agent.
本発明の第4の態様による脱色セットを構成する、アルカリ剤、酸化助剤、酸化剤、脱色助剤は、本発明の第1乃至3の態様で説明したのと同様であってよい。 The alkaline agent, the oxidation aid, the oxidizing agent, and the decolorization aid constituting the decolorization set according to the fourth aspect of the present invention may be the same as those described in the first to third aspects of the present invention.
[本発明の第5の態様]
本発明の第5の態様により提案される染色セットは、
脱色剤と、染色剤とを備えてなり、
脱色剤が、本発明による第2又は3の態様によるものである。[Fifth aspect of the present invention]
The staining set proposed by the fifth aspect of the present invention is:
A depigmenting agent and a dyeing agent,
The depigmenting agent is according to the second or third aspect of the present invention.
〔染色剤〕
染色剤は、酸化染毛剤(ヘアカラー、ヘアダイ、白髪染め等)、非酸化染毛剤である永久染毛剤;ヘアマニキュア、酸性カラー、カラーリンス、カラートリートメント等の半永久染毛料;ヘアカラースプレー、ヘアマスカラ、カラースティック等の一次染毛料、毛髪着色料であってよい。染色剤(染毛剤)は、市販されているものを使用することが可能である。[Dyeing agent]
Dyeing agents include oxidative hair dyes (hair colors, hair dyes, white hair dyes, etc.), permanent hair dyes that are non-oxidative hair dyes; semi-permanent hair dyes such as hair manicures, acidic colors, color rinses, color treatments; hair color sprays Primary hair dyes such as hair mascara and color sticks, and hair coloring agents. A commercially available dyeing agent (hair dyeing agent) can be used.
本発明の第5の態様による染色セットを構成する、アルカリ剤、酸化助剤、酸化剤、脱色助剤は、本発明の第1乃至4の態様で説明したのと同様であってよい。 The alkali agent, the oxidation aid, the oxidation agent, and the decolorization aid constituting the dyeing set according to the fifth aspect of the present invention may be the same as those described in the first to fourth aspects of the present invention.
[本発明の第6の態様]
本発明の第6の態様により提案される脱色方法は、
体毛に、脱色助剤又は脱色剤を付与し、
前記体毛から色素を除去することを含んでなるものであり、
前記脱色助剤が、本発明の第1の態様によるものであり、
前記脱色剤が、本発明による第2又は3の態様によるものである。[Sixth aspect of the present invention]
The decolorization method proposed by the sixth aspect of the present invention is:
Apply decoloring aid or decoloring agent to body hair,
Removing pigment from the body hair,
The decolorization aid is according to the first aspect of the present invention,
The depigmenting agent is according to the second or third aspect of the present invention.
[本発明の第7の態様]
本発明の第7の態様により提案される染色方法は、
体毛に、脱色助剤又は脱色剤を付与し、
前記体毛から色素を除去し、
前記体毛を染色剤で染色することを含んでなるものであり、
前記脱色助剤が、本発明の第1の態様によるものであり、
前記脱色剤が、本発明による第2又は3の態様によるものである。[Seventh aspect of the present invention]
The staining method proposed by the seventh aspect of the present invention is:
Apply decoloring aid or decoloring agent to body hair,
Remove pigment from the hair,
Dyeing the body hair with a dyeing agent,
The decolorization aid is according to the first aspect of the present invention,
The depigmenting agent is according to the second or third aspect of the present invention.
[本発明の第8態様]
本発明の第8の態様により提案される美容用剤は、上記した本発明の第1態様から第5の態様のものと同様であってよい。
(1)美容用剤であって、
脱色用であり、
酸化マグネシウム、酸化カルシウム、又はマグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなる、美容用剤である。
(2)美容用剤であって、
アルカリ剤又は酸化助剤と、及び脱色助剤とを備えてなり、
前記脱色助剤が、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなる、美容用剤である。
(3)美容用剤であって、
脱色用であって、
第1剤と、及び第2剤とを備えてなり、
前記第1剤が、アルカリ剤又は酸化助剤と、及び脱色助剤とを含んでなり、
前記脱色助剤が、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなるものであり、
前記第2剤が、酸化剤を含有してなる、美容用剤である。[Eighth aspect of the present invention]
The cosmetic agent proposed by the eighth aspect of the present invention may be the same as that of the first to fifth aspects of the present invention described above.
(1) A cosmetic agent,
For decolorization,
A cosmetic agent comprising magnesium oxide, calcium oxide, or a composite oxide of magnesium and calcium or a mixture thereof.
(2) A cosmetic agent,
Comprising an alkali agent or an oxidation aid, and a decolorization aid,
The decolorization aid is a cosmetic agent comprising magnesium oxide, calcium oxide, a composite oxide of magnesium and calcium, or a mixture thereof.
(3) A cosmetic agent,
For decolorization,
Comprising a first agent and a second agent;
The first agent comprises an alkali agent or an oxidation aid, and a decolorization aid,
The decolorization aid comprises magnesium oxide, calcium oxide, a composite oxide of magnesium and calcium, or a mixture thereof,
The second agent is a cosmetic agent containing an oxidizing agent.
[任意成分]
本発明においては、脱色助剤、脱色剤、アルカリ剤、酸化助剤、酸化剤(本発明の第1の態様から本発明の第7の態様を包含する)は、それ自体又は他の剤との組み合わせた剤において、以下の任意成分を包含するものであってよい。本発明にあっては、任意成分として、体毛及び体表面皮膚保護、再染色性、品質維持及び成分安定性等を目的として、以下のものを好ましくは含むことができる。[Optional ingredients]
In the present invention, a decoloring aid, a decoloring agent, an alkali agent, an oxidizing aid, and an oxidizing agent (including the first aspect of the present invention to the seventh aspect of the present invention) itself or other agents In the combined agent, the following optional components may be included. In the present invention, the following can be preferably included as optional components for the purpose of protecting hair and body surface skin, re-staining properties, maintaining quality, and component stability.
医薬部外品として利用可能な任意成分の具体例としては、増粘剤、天然及び合成の水溶性高分子、界面活性剤、紫外線吸収剤、金属イオン封鎖剤、低級アルコール、多価アルコール、単糖、オリゴ糖、多糖、アミノ酸、有機アミン、合成樹脂エマルジョン、防腐剤、ビタミン類、植物抽出エキス、酸化防止剤、酸化防止助剤、香料、着色剤、粉末成分等の一種又は二種以上を組合せて用いることができる。 Specific examples of optional ingredients that can be used as quasi drugs include thickeners, natural and synthetic water-soluble polymers, surfactants, UV absorbers, sequestering agents, lower alcohols, polyhydric alcohols, simple substances. One or more of sugar, oligosaccharides, polysaccharides, amino acids, organic amines, synthetic resin emulsions, preservatives, vitamins, plant extracts, antioxidants, antioxidant assistants, fragrances, colorants, powder components, etc. Can be used in combination.
<増粘剤>
増粘剤としては、例えば、イソステアリン酸ジエタノールアミド、ウンデシレン酸モノエタノールアミド、オレイン酸ジエタノールアミド、牛脂脂肪酸モノエタノールアミド、ステアリン酸ジエタノールアミド、ステアリン酸ジエチルアミノエチルアミド、ヤシ油脂肪酸エタノールアミド、ヤシ油脂肪酸ジエタノールアミド、ラウリン酸イソプロパノールアミド、ラウリン酸エタノールアミド、ラウリン酸ジエタノールアミド、ラノリン脂肪酸ジエタノールアミド、カルボキシメチルセルロースナトリウム、ヒドロキシエチルセルロース、カルボキシビニルポリマー、カラギーナン、キサンタンガム等の動物系高分子の一種又は二種以上が挙げられる。また、本発明にあっては、後記する〔任意成分〕において例示される物質、例えば、天然及び合成の水溶性高分子、界面活性剤、多価アルコール、単糖、オリゴ糖、多糖、アミノ酸、有機アミン、合成樹脂エマルジョン等についても、増粘剤として利用することも可能である。<Thickener>
Examples of thickeners include, for example, isostearic acid diethanolamide, undecylenic acid monoethanolamide, oleic acid diethanolamide, beef tallow fatty acid monoethanolamide, stearic acid diethanolamide, stearic acid diethylaminoethylamide, coconut oil fatty acid ethanolamide, coconut oil fatty acid One or more animal polymers such as diethanolamide, lauric acid isopropanolamide, lauric acid ethanolamide, lauric acid diethanolamide, lanolin fatty acid diethanolamide, sodium carboxymethyl cellulose, hydroxyethyl cellulose, carboxyvinyl polymer, carrageenan, xanthan gum Can be mentioned. Further, in the present invention, substances exemplified in the following [optional component], for example, natural and synthetic water-soluble polymers, surfactants, polyhydric alcohols, monosaccharides, oligosaccharides, polysaccharides, amino acids, Organic amines and synthetic resin emulsions can also be used as thickeners.
<水溶性高分子>
天然の水溶性高分子としては、例えば、アラビアガム、トラガカントガム、ガラクタン、グアガム、キャロブガム、カラヤガム、カラギーナン、ペクチン、クインスシード(マルメロ)、アルゲコロイド(カッソウエキス)、デンプン(コメ、トウモロコシ、バレイショ、コムギ)等の植物系高分子、デキストラン、サクシノグルカン、ブルラン等の微生物系高分子、及びコラーゲン、ケラチン、カゼイン、アルブミン、ゼラチン等の動物系高分子の一種又は二種以上が挙げられる。<Water-soluble polymer>
Examples of natural water-soluble polymers include gum arabic, gum tragacanth, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, quince seed (malmello), algae colloid (gypsum extract), starch (rice, corn, potato, wheat). 1 type or 2 types or more of plant type polymers, such as microbial polymers, such as dextran, succinoglucan, and bullulan, and animal type polymers, such as collagen, keratin, casein, albumin, gelatin.
天然及び合成の水溶性高分子としては、例えば、カルボキシメチルデンプン、メチルヒドロキシプロピルデンプン等のデンプン系高分子、メチルセルロース、ニトロセルロース、メチルヒドロキシプロピルセルロース、セルロース硫酸ナトリウム、ヒドロキシプロピルセルロース、カルボキシメチルセルロース、カルボキシメチルセルロースナトリウム、結晶セルロース、セルロース末等のセルロース系高分子、及びアルギン酸ナトリウム、アルギン酸プロピレングリコールエステル等のアルギン酸系高分子等の一種又は二種以上が挙げられる。 Examples of natural and synthetic water-soluble polymers include starch polymers such as carboxymethyl starch and methylhydroxypropyl starch, methylcellulose, nitrocellulose, methylhydroxypropylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxymethylcellulose, carboxy One type or two or more types of cellulose-based polymers such as sodium methylcellulose, crystalline cellulose, and cellulose powder, and alginic acid-based polymers such as sodium alginate and propylene glycol alginate can be used.
合成の水溶性高分子としては、例えば、ポリビニルアルコール、ポリビニルメチルエーテル、ポリビニルピロリドン、カルボキシビニルポリマー(カーボポール)等のビニル系高分子、ポリエチレングリコール20,000、40,000、60,000等のポリオキシエチレン系高分子、ポリオキシエチレンポリオキシプロピレン共重合体共重合系高分子、ポリアクリル酸ナトリウム、ポリエチルアクリレート、ポリアクリルアミド等のアクリル系高分子、ポリエチレンイミン、及びカチオンポリマー等が挙げられる。
無機の水溶性高分子としては、例えば、ベントナイト、ケイ酸AlMg(ビーガム)、ラポナイト、ヘクトライト、及び無水ケイ酸等の一種又は二種以上が挙げられる。Examples of the synthetic water-soluble polymer include vinyl polymers such as polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, and carboxyvinyl polymer (Carbopol), polyethylene glycol 20,000, 40,000, 60,000 and the like. Examples include polyoxyethylene polymers, polyoxyethylene polyoxypropylene copolymer copolymers, acrylic polymers such as sodium polyacrylate, polyethyl acrylate, and polyacrylamide, polyethyleneimine, and cationic polymers. .
Examples of the inorganic water-soluble polymer include one or more of bentonite, AlMg silicate (beegum), laponite, hectorite, and anhydrous silicic acid.
<界面活性剤>
界面活性剤としては、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、非イオン性界面活性剤等の一種又は二種以上の混合物を用いることができる。
アニオン界面活性剤としては、例えば、セッケン用素地、ラウリン酸ナトリウム、ラウリン酸カリウム、パルミチン酸ナトリウム、パルミチン酸カリウム、ミリスチン酸カリウム等の脂肪酸セッケン、ラウリル硫酸ナトリウム、ラウリル硫酸カリウム、ラウレス硫酸ナトリウム等の高級アルキル硫酸エステル塩、POE−ラウリル硫酸トリエタノールアミン(ラウレス硫酸TEA)、POE−ラウリル硫酸ナトリウム等のアルキルエーテル硫酸エステル塩、ラウロイルサルコシンナトリウム等のN−アシルサルコシン酸、N−ミリストイル−N−メチルタウリンナトリウム、ヤシ油脂肪酸メチルタウリッドナトリウム、ラウリルメチルタウリッドナトリウム等の高級脂肪酸アミドスルホン酸塩、POE−オレイルエーテルリン酸ナトリウム、POE−ステアリルエーテルリン酸等のリン酸エステル塩、ジ−2−エチルヘキシルスルホコハク酸ナトリウム、モノラウロイルモノエタノールアミドポリオキシエチレンスルホコハク酸ナトリウム、ラウリルポリプロピレングリコールスルホコハク酸ナトリウム等のスルホコハク酸塩、リニアドデシルベンゼンスルホン酸ナトリウム、リニアドデシルベンゼンスルホン酸トリエタノールアミン、リニアドデシルベンゼンスルホン酸等のアルキルベンゼンスルホン酸塩、N−ラウロイルグルタミン酸モノナトリウム、N−ステアロイルグルタミン酸ジナトリウム、N−ミリストイル−L−グルタミン酸モノナトリウム等のN−アシルグルタミン酸塩、硬化ヤシ油脂肪酸グリセリン硫酸ナトリウム等の高級脂肪酸エステル硫酸エステル塩、ロート油等の硫酸化油、POE−アルキルエーテルカルボン酸、POE−アルキルアリルエーテルカルボン酸塩、α−オレフィンスルホン酸塩、高級脂肪酸エステルスルホン酸塩、二級アルコール硫酸エステル塩、高級脂肪酸アルキロールアミド硫酸エステル塩、ラウロイルモノエタノールアミドコハク酸ナトリウム、N−パルミトイルアスパラギン酸ジトリエタノールアミン、カゼインナトリウム、ココイルグリシンカリウム、ラウロイルグルタミン酸ナトリウム等の一種又は二種以上が挙げられる。<Surfactant>
As the surfactant, one or a mixture of two or more of an anionic surfactant, a cationic surfactant, an amphoteric surfactant, a nonionic surfactant and the like can be used.
Examples of the anionic surfactant include soap bases, fatty acid soaps such as sodium laurate, potassium laurate, sodium palmitate, potassium palmitate, potassium myristate, sodium lauryl sulfate, potassium lauryl sulfate, sodium laureth sulfate, etc. Higher alkyl sulfates, alkyl ether sulfates such as POE-lauryl sulfate triethanolamine (laures sulfate TEA), POE-sodium lauryl sulfate, N-acyl sarcosine acids such as sodium lauroyl sarcosine, N-myristoyl-N-methyl Higher fatty acid amide sulfonates such as sodium taurine, coconut oil fatty acid methyl tauride sodium, sodium lauryl methyl tauride, sodium POE-oleyl ether phosphate, Phosphoric acid ester salts such as OE-stearyl ether phosphoric acid, sulfosuccinic acid salts such as sodium di-2-ethylhexyl sulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, linear dodecylbenzene sulfone N, such as sodium acid, alkylbenzene sulfonates such as linear dodecyl benzene sulfonate triethanolamine, linear dodecyl benzene sulfonic acid, monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, monosodium N-myristoyl-L-glutamate -Acyl glutamate, higher fatty acid ester sulfate such as hydrogenated coconut oil fatty acid sodium glycerol sulfate, rho Sulfated oil such as oil, POE-alkyl ether carboxylic acid, POE-alkyl allyl ether carboxylate, α-olefin sulfonate, higher fatty acid ester sulfonate, secondary alcohol sulfate ester salt, higher fatty acid alkylolamide sulfate One type or two or more types of ester salt, sodium lauroyl monoethanolamide succinate, ditriethanolamine N-palmitoyl aspartate, sodium caseinate, potassium cocoylglycine, sodium lauroyl glutamate and the like can be mentioned.
カチオン界面活性剤としては、例えば、塩化ステアリルトリメチルアンモニウム、塩化ラウリルトリメチルアンモニウム等のアルキルトリメチルアンモニウム塩、塩化ジステアリルジメチルアンモニウムジアルキルジメチルアンモニウム塩、塩化ポリ(N,N’−ジメチル−3,5−メチレンピペリジニウム)、塩化セチルピリジニウム等のアルキルピリジニウム塩、アルキル四級アンモニウム塩、アルキルジメチルベンジルアンモニウム塩、アルキルイソキノリニウム塩、ジアルキルモリホニウム塩、POE−アルキルアミン、アルキルアミン塩、ポリアミン脂肪酸誘導体、アミルアルコール脂肪酸誘導体、塩化ベンザルコニウム、塩化ベンゼトニウム、有機変性モンモリロナイト等の有機変性粘土鉱物等の一種又は二種以上が挙げられる。 Examples of the cationic surfactant include alkyltrimethylammonium salts such as stearyltrimethylammonium chloride and lauryltrimethylammonium chloride, distearyldimethylammonium dialkyldimethylammonium chloride, and poly (N, N′-dimethyl-3,5-methylene chloride). Piperidinium), alkyl pyridinium salts such as cetyl pyridinium chloride, alkyl quaternary ammonium salts, alkyl dimethyl benzyl ammonium salts, alkyl isoquinolinium salts, dialkyl morpholinium salts, POE-alkyl amines, alkyl amine salts, polyamine fatty acids Derivatives, amyl alcohol fatty acid derivatives, benzalkonium chloride, benzethonium chloride, organic modified clay minerals such as organic modified montmorillonite, etc.
両性界面活性剤としては、例えば、2−ウンデシル−N,N,N−(ヒドロキシエチルカルボキシメチル)−2−イミダゾリンナトリウム、2−ココイル−2−イミタゾリニウムヒドロキサイド−1−カルボキシエチロキシ2ナトリウム塩等のイミダゾリン系両性界面活性剤;2−ヘプタデシル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、ラウリルジメチルアミノ酢酸ベタイン、コカミドプロピルベタインやラウリルベタイン等のアルキルベタイン、アミドベタイン、スルホベタイン、ココベタイン等のベタイン系界面活性剤等の一種又は二種以上が挙げられる。 Examples of amphoteric surfactants include 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy 2 Imidazoline-based amphoteric surfactants such as sodium salt; 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, cocamidopropyl betaine, lauryl betaine and other alkylbetaines, amide betaines, One type or two or more types of betaine surfactants such as sulfobetaine and cocobetaine can be used.
非イオン界面活性剤としては、例えば、POE−ソルビタンモノオレエート、POE−ソルビタンモノステアレート、POE−ソルビタンモノオレエート、POE−ソルビタンテトラオレエート等のPOE−ソルビタン脂肪酸エステル類、POE−ソルビットモノラウレート、POE−ソルビットモノオレエート、POE−ソルビットペンタオレエート、POE−ソルビットモノステアレート等のPOE−ソルビット脂肪酸エステル類、POE−グリセリンモノステアレート、POE−グリセリンモノイソステアレート、POE−グリセリントリイソステアレート等のPOE−グリセリン脂肪酸エステル類、POE−モノオレエート、POE−ジステアレート、POE−モノジオレエート、ジステアリン酸エチレングリコール等のPOE−脂肪酸エステル類、POE−ラウリルエーテル、POE−オレイルエーテル、POE−ステアリルエーテル、POE−ベヘニルエーテル、POE−2−オクチルドデシルエーテル、POE−コレスタノールエーテル等のPOE−アルキルエーテル類、プルロニック等のプルロニック型類、POE・POP−セチルエーテル、POE・POP−2−デシルテトラデシルエーテル、POE・POP−モノブチルエーテル、POE・POP−水添ラノリン、POE・POP−グリセリンエーテル等のPOE・POP−アルキルエーテル類、テトロニック等のテトラPOE・テトラPOP−エチレンジアミン縮合物類、POE−ヒマシ油、POE−硬化ヒマシ油、POE−硬化ヒマシ油モノイソステアレート、POE−硬化ヒマシ油トリイソステアレート、POE−硬化ヒマシ油モノピログルタミン酸モノイソステアリン酸ジエステル、POE−硬化ヒマシ油マレイン酸等のPOE−ヒマシ油誘導体やPOE−硬化ヒマシ油誘導体、POE−ソルビットミツロウ等のPOE−ミツロウ・ラノリン誘導体、ヤシ油脂肪酸ジエタノールアミド(コカミドDEA)、ラウリン酸モノエタノールアミド、脂肪酸イソプロパノールアミド等のアルカノールアミド、POE−プロピレングリコール脂肪酸エステル、POE−アルキルアミン、POE−脂肪酸アミド、ショ糖脂肪酸エステル、POE−ノニルフェニルホルムアルデヒド縮合物、アルキルエトキシジメチルアミンオキシド、トリオレイルリン酸、セスキカプリル酸ポリグリセリル、ジカプリル酸ポリグリセリル、モノラウリン酸ポリグリセリル、モノステアリン酸ポリグリセリル、モノオレイン酸ポリグリセリル、ジステアリン酸ポリグリセリル、ジオレイン酸ポリグリセリル等のポリグリセリン脂肪酸エステル、メチルポリシロキサン・セチルメチルポリシロキサン・ポリ(オキシエチレン・オキシプロピレン)メチルポリシロキサン共重合体等の変性シリコーン、ソルビタンモノオレエート、ソルビタンモノイソステアレート、ソルビタンモノラウレート、ソルビタンモノパルミテート、ソルビタンモノステアレート、ソルビタンセスキオレエート、ソルビタントリオレエート、ペンタ−2−エチルヘキシル酸ジグリセロールソルビタン、テトラ−2−エチルヘキシル酸ジグリセロールソルビタン等のソルビタン脂肪酸エステル類、モノ綿実油脂肪酸グリセリン、モノエルカ酸グリセリン、セスキオレイン酸グリセリン、モノステアリン酸グリセリン、α,α’−オレイン酸ピログルタミン酸グリセリン、モノステアリン酸グリセリン、モノオレイン酸グリセリン等のグリセリン脂肪酸エステル類、モノイソステアリン酸ジグリセリル、ジイソステアリン酸ジグリセリル、縮合リシノレイン酸ジグリセリル、縮合リシノレイン酸テトラグリセリル等のポリグリセリン脂肪酸エステル、モノステアリン酸プロピレングリコール等のプロピレングリコール脂肪酸エステル類、硬化ヒマシ油誘導体、グリセリンアルキルエーテル、デシルグルコシド等の一種又は二種以上が挙げられる。 Nonionic surfactants include, for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan fatty acid esters such as POE-sorbitan tetraoleate, POE-sorbite mono POE-sorbite fatty acid esters such as laurate, POE-sorbite monooleate, POE-sorbite pentaoleate, POE-sorbite monostearate, POE-glycerol monostearate, POE-glycerol monoisostearate, POE-glycerol POE-glycol fatty acid esters such as triisostearate, POE-monooleate, POE-distearate, POE-monodiolate, ethylene glycol distearate, etc. POE-alkyl ethers such as acid esters, POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, and pluronic type such as pluronic POE • POP-cetyl ether, POE • POP-2-decyltetradecyl ether, POE • POP-monobutyl ether, POE • POP-hydrogenated lanolin, POE • POP-alkyl ethers such as POE • POP-glycerin ether Tetra POE / Tetra POP-ethylenediamine condensates such as Tetronic, POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE-hardened castor oil triisostearate POE-hardened castor oil monopyroglutamic acid monoisostearic acid diester, POE-castor oil derivatives such as POE-hardened castor oil maleic acid, POE-hardened castor oil derivatives, POE-honey beeswax lanolin derivatives such as POE-sorbite beeswax, palm Oil fatty acid diethanolamide (cocamide DEA), alkanolamides such as lauric acid monoethanolamide, fatty acid isopropanolamide, POE-propylene glycol fatty acid ester, POE-alkylamine, POE-fatty acid amide, sucrose fatty acid ester, POE-nonylphenylformaldehyde Condensate, alkylethoxydimethylamine oxide, trioleyl phosphate, polyglyceryl sesquicaprylate, polyglyceryl dicaprylate, polyglyceryl monolaurate, Modification of polyglyceryl fatty acid esters such as polyglyceryl monostearate, polyglyceryl monooleate, polyglyceryl distearate, polyglyceryl dioleate, methylpolysiloxane / cetylmethylpolysiloxane / poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer, etc. Silicone, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, tetra-2 -Sorbitan fatty acid esters such as diglycerol sorbitan ethylhexylate, mono-cotton oil fatty acid glycerin, mono-erucic acid glycerin Phosphorus, glyceryl sesquioleate, glyceryl monostearate, α, α'-oleic acid pyroglutamate glycerin, glyceryl fatty acid esters such as glyceryl monostearate, glyceryl monooleate, diglyceryl monoisostearate, diglyceryl diisostearate, Polyglycerin fatty acid esters such as condensed diglyceryl ricinoleate and tetraglyceryl condensed ricinoleate, propylene glycol fatty acid esters such as propylene glycol monostearate, hardened castor oil derivatives, glycerin alkyl ether, decyl glucoside, etc. Can be mentioned.
<紫外線吸収剤>
紫外線吸収剤としては、例えば、パラアミノ安息香酸(以下、PABA と略す)、PABAモノグリセリンエステル、N,N−ジプロポキシPABAエチルエステル、N,N−ジエトキシPABAエチルエステル、N,N−ジメチルPABAエチルエステル、N,N−ジメチルPABAブチルエステル、N,N−ジメチルPABAエチルエステル等の安息香酸系紫外線吸収剤;ホモメンチル−N−アセチルアントラニレート等のアントラニル酸系紫外線吸収剤;アミルサリシレート、メンチルサリシレート、ホモメンチルサリシレート、オクチルサリシレート、フェニルサリシレート、ベンジルサリシレート、p−イソプロパノールフェニルサリシレート等のサリチル酸系紫外線吸収剤;オクチルシンナメート、エチル−4−イソプロピルシンナメート、メチル−2,5−ジイソプロピルシンナメート、エチル−2,4−ジイソプロピルシンナメート、メチル−2,4−ジイソプロピルシンナメート、プロピル−p−メトキシシンナメート、イソプロピル−p−メトキシシンナメート、イソアミル−p−メトキシシンナメート、オクチル−p−メトキシシンナメート(2−エチルヘキシル−p−メトキシシンナメート)、2−エトキシエチル−p−メトキシシンナメート、シクロヘキシル−p−メトキシシンナメート、エチル−α−シアノ−β−フェニルシンナメート、2−エチルヘキシル−α−シアノ−β−フェニルシンナメート、グリセリルモノ−2−エチルヘキサノイル−ジパラメトキシシンナメート等の桂皮酸系紫外線吸収剤;2,4−ジヒドロキシベンゾフェノン、2,2’−ジヒドロキシ−4−メトキシベンゾフェノン、2,2’−ジヒドロキシ−4,4’−ジメトキシベンゾフェノン、2,2’,4,4’−テトラヒドロキシベンゾフェノン、2−ヒドロキシ−4−メトキシベンゾフェノン、2−ヒドロキシ−4−メトキシ−4’−メチルベンゾフェノン、2−ヒドロキシ−4−メトキシベンゾフェノン−5−スルホン酸塩、4−フェニルベンゾフェノン、2−エチルヘキシル−4’−フェニル−ベンゾフェノン−2−カルボキシレート、2−ヒドロキシ−4−n−オクトキシベンゾフェノン、4−ヒドロキシ−3−カルボキシベンゾフェノン等のベンゾフェノン系紫外線吸収剤;3−(4’−メチルベンジリデン)−d,l−カンファー、3−ベンジリデン−d,l−カンファー、ウロカニン酸、ウロカニン酸エチルエステル、2−フェニル−5−メチルベンゾキサゾール、2,2’−ヒドロキシ−5−メチルフェニルベンゾトリアゾール、2−(2’−ヒドロキシ−5’−t−オクチルフェニル)ベンゾトリアゾール、2−(2’−ヒドロキシ−5’−メチルフェニル)ベンゾトリアゾール、ジベンザラジン、ジアニソイルメタン、4−メトキシ−4’−t−ブチルジベンゾイルメタン、5−(3,3−ジメチル−2−ノルボルニリデン)−3−ペンタン−2−オン、及び2,4,6−トリアニリノ−p−(カルボ−2’−エチルヘキシル−1’−オキシ)1,3,5−トリアジン、4−tent−ブチル−4’−メトキシジベンゾイルメタン等の一種又は二種以上が挙げられる。<Ultraviolet absorber>
Examples of the ultraviolet absorber include paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl PABA ethyl ester. Benzoic acid ultraviolet absorbers such as N, N-dimethyl PABA butyl ester and N, N-dimethyl PABA ethyl ester; anthranilic acid ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; amyl salicylate, menthyl salicylate, Salicylic acid UV absorbers such as homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate; octylcinnamate, ethyl-4-isopropyl Nannamate, methyl-2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl- p-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl-α-cyano- Cinnamic acid-based ultraviolet absorbers such as β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate; 2,4-dihydroxybenzophenone, 2, 2 ' Dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4 -Methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4 -Benzophenone ultraviolet absorbers such as n-octoxybenzophenone and 4-hydroxy-3-carboxybenzophenone; 3- (4'-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor, urocanin Acid, ethyl urocanate Ter, 2-phenyl-5-methylbenzoxazole, 2,2′-hydroxy-5-methylphenylbenzotriazole, 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole, 2- (2 '-Hydroxy-5'-methylphenyl) benzotriazole, dibenzalazine, dianisoylmethane, 4-methoxy-4'-t-butyldibenzoylmethane, 5- (3,3-dimethyl-2-norbornylidene) -3-pentane 2-one and 2,4,6-trianilino-p- (carbo-2'-ethylhexyl-1'-oxy) 1,3,5-triazine, 4-tent-butyl-4'-methoxydibenzoylmethane 1 type or 2 types or more, etc. are mentioned.
<金属イオン封鎖剤>
金属イオン封鎖剤としては、例えば、エデト酸二ナトリウム、エデト酸塩、及びヒドロキシエタンジホスホン酸等の一種又は二種以上が挙げられる。<Metal ion sequestering agent>
Examples of the sequestering agent include one or more of edetate disodium, edetate, and hydroxyethane diphosphonic acid.
<低級アルコール>
低級アルコールとしては、例えば、メタノール、エタノール、プロパノール、イソプロパノール、イソブチルアルコール、t−ブチルアルコール等の一種又は二種以上が挙げられる。<Lower alcohol>
Examples of the lower alcohol include one or more of methanol, ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol, and the like.
<糖類>
単糖としては、例えば、D−グリセリルアルデヒド、ジヒドロキシアセトン等の三炭糖、D−エリトロース、D−エリトルロース、D−トレオース等の四炭糖、L−アラビノース、D−キシロース、L−リキソース、D−アラビノース、D−リボース、D−リブロース、D−キシルロース、L−キシルロース等の五炭糖、D−グルコース、D−タロース、D−ブシコース、D−ガラクトース、D−フルクトース、L−ガラクトース、L−マンノース、D−タガトース等の六炭糖、アルドヘプトース、ヘプツロース等の七炭糖、オクツース等の八炭糖、2−デオキシ−D−リボース、6−デオキシ−L−ガラクトース、6−デオキシ−L−マンノース等のデオキシ糖、D−グルコサミン、D−ガラクトサミン、シアル酸、アミノウロン酸、ムラミン酸等のアミノ糖、及びD−グルクロン酸、D−マンヌロン酸、L−グルロン酸、D−ガラクツロン酸、L−イズロン酸等のウロン酸等の一種又は二種以上が挙げられる。<Sugar>
Examples of monosaccharides include tricarbon sugars such as D-glyceryl aldehyde and dihydroxyacetone, tetracarbon sugars such as D-erythrose, D-erythrulose, and D-threose, L-arabinose, D-xylose, L-lyxose, D -Five carbon sugars such as arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, D-glucose, D-talose, D-bucose, D-galactose, D-fructose, L-galactose, L- Hexoses such as mannose and D-tagatose, pentoses such as aldheptose and heptulose, octoses such as octus, 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose Deoxy sugars such as D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, mura Amino sugars, and D- glucuronic acid, such as phosphate, D- mannuronic acid, L- guluronic acid, D- galacturonic acid, one or two or more of such uronic acids such as L- iduronic acid.
オリゴ糖としては、例えば、ショ糖、グンチアノース、ウンベリフェロース、ラクトース、プランテオース、イソリクノース類、α,α−トレハロース、ラフィノース、リクノース類、ウンビリシン、及びスタキオースベルバスコース類等の一種又は二種以上が挙げられる。 Examples of oligosaccharides include one or two or more of sucrose, gnocyanose, umbelliferose, lactose, planteose, isoliquinoses, α, α-trehalose, raffinose, lycnose, umbilicin, and stachyose verbose courses. Is mentioned.
多糖としては、例えば、セルロース、コンドロイチン硫酸、デキストリン、グルコマンナン、キチン、ガラクタン、デルマタン硫酸、グリコーゲン、アラビアガム、ヘパラン硫酸、トラガントガム、ケラタン硫酸、コンドロイチン、ムコイチン硫酸、グアガム、デキストラン、ケラト硫酸、ローカストビンガム、サクシノグルカン、及びカロニン酸等の一種又は二種以上が挙げられる。 Examples of the polysaccharide include cellulose, chondroitin sulfate, dextrin, glucomannan, chitin, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, tragacanth gum, keratan sulfate, chondroitin, mucoitin sulfate, guar gum, dextran, kerato sulfate, locust bin gum , Succinoglucan, and caronic acid.
<アミン類>
アミノ酸として、例えば、スレオニン、システイン等の中性アミノ酸、ヒドロキシリジン等の塩基性アミノ酸が挙げられる。また、アミノ酸誘導体として、例えば、アシルサルコシンナトリウム(ラウロイルサルコシンナトリウム)、アシルグルタミン酸塩、アシルβ−アラニンナトリウム、及びグルタチオン等の一種又は二種以上が挙げられる。<Amines>
Examples of amino acids include neutral amino acids such as threonine and cysteine, and basic amino acids such as hydroxylysine. Examples of the amino acid derivative include one or two or more of acyl sarcosine sodium (lauroyl sarcosine sodium), acyl glutamate, acyl β-alanine sodium, and glutathione.
有機アミンとしては、例えば、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、モルホリン、トリイソプロパノールアミン、2−アミノ−2−メチル−1,3−プロパンジオール、及び2−アミノ−2−メチル−1−プロパノール等の一種又は二種以上が挙げられる。 Examples of organic amines include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol. 1 type or 2 types or more, etc. are mentioned.
<エマルジョン>
合成樹脂エマルジョンとしては、例えば、アクリル酸アルキル共重合体エマルジョン、メタクリル酸アルキル重合体エマルジョン、アクリル酸アルキル共重合体エマルジョン、メタクリル酸アルキル共重合体エマルジョン、アクリル酸・アクリル酸アルキル共重合体エマルジョン、メタクリル酸・メタクリル酸アルキル共重合体エマルジョン、アクリル酸アルキル・スチレン共重合体エマルジョン、メタクリル酸アルキル・スチレン共重合体エマルジョン、酢酸ビニル重合体エマルジョン、ポリ酢酸ビニルエマルジョン、酢酸ビニル含有共重合体エマルジョン、ビニルピロリドン・スチレン共重合体エマルジョン、シリコーン含有共重合体エマルジョン等の一種又は二種以上が挙げられる。<Emulsion>
Synthetic resin emulsions include, for example, alkyl acrylate copolymer emulsions, alkyl methacrylate polymer emulsions, alkyl acrylate copolymer emulsions, alkyl methacrylate copolymer emulsions, acrylic acid / alkyl acrylate copolymer emulsions, Methacrylic acid / alkyl methacrylate copolymer emulsion, alkyl acrylate / styrene copolymer emulsion, alkyl methacrylate / styrene copolymer emulsion, vinyl acetate polymer emulsion, polyvinyl acetate emulsion, vinyl acetate-containing copolymer emulsion, One type or two or more types of vinyl pyrrolidone / styrene copolymer emulsion, silicone-containing copolymer emulsion, etc. may be mentioned.
<防腐剤>
防腐剤としては、例えば、メチルパラベン、エチルパラベン、ブチルパラベン、フェノキシエタノール等の一種又は二種以上が挙げられる。<Preservative>
Examples of the preservative include one or more of methyl paraben, ethyl paraben, butyl paraben, phenoxyethanol and the like.
<ビタミン類>
ビタミン類としては、例えば、ビタミンA、ビタミンB1、ビタミンB2、ビタミンB6、ビタミンE、ビタミンK及びそれらの誘導体、パントテン酸及びその誘導体、ビオチン等の一種又は二種以上が挙げられる。<Vitamins>
Examples of vitamins include one or more of vitamin A, vitamin B1, vitamin B2, vitamin B6, vitamin E, vitamin K and derivatives thereof, pantothenic acid and derivatives thereof, and biotin.
<植物抽出エキス>
植物抽出エキスとしては、アロエベラ、ウイッチヘーゼル、ハマメリス、キュウリ、レモン、ラベンダー、ローズ等の一種又は二種以上が挙げられる。<Plant extract>
Examples of the plant extract include one or more of aloe vera, witch hazel, hammamels, cucumber, lemon, lavender and rose.
<酸化防止剤>
酸化防止剤としては、例えば、油溶性ビタミンC誘導体、トコフェロール類及びそれらの誘導体並びにそれらの塩、ジブチルヒドロキシトルエン、ブチルヒドロキシアニソール、及び没食子酸エステル類等の一種又は二種以上が挙げられる。<Antioxidant>
Examples of the antioxidant include one or more of oil-soluble vitamin C derivatives, tocopherols and derivatives thereof, and salts thereof, dibutylhydroxytoluene, butylhydroxyanisole, and gallic acid esters.
<酸化防止助剤>
酸化防止助剤としては、例えば、リン酸、クエン酸、マレイン酸、マロン酸、コハク酸、フマル酸、ケファリン、ヘキサメタフォスフェイト、フィチン酸、及びエチレンジアミン四酢酸等の一種又は二種以上が挙げられる。<Antioxidant aid>
Examples of the antioxidant aid include one or more of phosphoric acid, citric acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid. It is done.
本発明によれば、脱色における体毛の保護を有効に行うことが可能となり、脱色後、染色が連続的に直ちに行うことができ、美容(理容)及び医療業界において、経済的、時間的なメリットを付与することが可能となる。 According to the present invention, it is possible to effectively protect hair in decolorization, and after decoloring, dyeing can be performed continuously and immediately, and in the beauty (barber) and medical industries, economical and time advantages Can be given.
本発明の内容について、以下の実施例によりさらに詳細に説明するが、本発明の発明には、これら実施例によって制限されて解釈されるものではない。また、本発明の全範囲は、本明細書に開示された事項及び実施例に基づいて、当業者が容易に実施できることは言うまでもない。 The contents of the present invention will be described in more detail with reference to the following examples. However, the present invention is not construed as being limited by these examples. It goes without saying that the full scope of the present invention can be easily implemented by those skilled in the art based on the matters and examples disclosed in the present specification.
調剤
以下の剤を下記表1の組成に従って脱色剤を調製した。
第1剤(アルカリ剤又は酸化助剤)
A:ミルボン社製、商品名:パウダーブリーチ、有効成分:過硫酸アンモニウム、過硫酸カリウム、過硫酸ナトリウム
B:ルベル社製、商品名:プラチナブリーチ、有効成分:過硫酸カリウム、過硫酸アンモニウム
C:アリミノ社製、商品名:ブリーチ120、有効成分:過硫酸アンモニウム、過硫酸カリウム Dispensing agents were prepared according to the composition shown in Table 1 below.
First agent (alkaline agent or oxidation aid)
A: Made by Milbon, trade name: powder bleach, active ingredient: ammonium persulfate, potassium persulfate, sodium persulfate B: Made by Lubel, trade name: platinum bleach, active ingredient: potassium persulfate, ammonium persulfate C: Arimino Product name: Bleach 120, active ingredient: ammonium persulfate, potassium persulfate
第2剤(脱色助剤)
D:タテホ化学工業社製、商品名:TATEHOMAG、主成分:酸化マグネシウム
E:井上石灰工業社製、商品名:QC−X、主成分:酸化カルシウムSecond agent (decolorization aid)
D: manufactured by Tateho Chemical Industry Co., Ltd., trade name: TATEHOMAG, main component: magnesium oxide E: manufactured by Inoue Lime Industry Co., Ltd., trade name: QC-X, main component: calcium oxide
第3剤(酸化剤)
F:ミルボン社製、商品名:オルディーブオキシダン、有効成分:過酸化水素(6%)
G:ルベル社製、商品名:マテリアオキシ、有効成分:過酸化水素(6%)
H:アリミノ社製、商品名:アジアンカラーデザインエキスパート、有効成分:過酸化水素(6%)
I:上記Hと、30%過酸化水素水(和光純薬工業社製)を体積比7:1で混合したもの(過酸化水素の最終濃度:9%)
J:上記Hと、30%過酸化水素水を体積比3:1で混合したもの(過酸化水素の最終濃度:12%)
F: Made by Milbon, trade name: Oldive oxydane, active ingredient: hydrogen peroxide (6%)
G: Rebel, product name: materiaoxy, active ingredient: hydrogen peroxide (6%)
H: Made by Arimino, trade name: Asian color design expert, active ingredient: hydrogen peroxide (6%)
I: The above H and 30% hydrogen peroxide solution (manufactured by Wako Pure Chemical Industries, Ltd.) mixed at a volume ratio of 7: 1 (final concentration of hydrogen peroxide: 9%)
J: The above H and 30% hydrogen peroxide water mixed at a volume ratio of 3: 1 (final concentration of hydrogen peroxide: 12%)
脱色剤
上記で用意した剤を下記表2の組成表に基づいて(質量比)、脱色剤を調製した。
[評価試験]
〔試験1:脱色力〕
試験用毛髪(長さ10cm×幅0.5cmの束:日本人、黒髪)の一部を脱色し、その脱色力を、同じ第1剤を用いた比較例を対象とした対比比較によって下記基準によって評価し、その結果を下記表3に記載した。
<評価基準>
評価◎:比較例と同等に、脱色された。
評価○:比較例より若干弱いものの、十分に脱色された。
評価△:脱色が不十分であった。
評価×:脱色がされなかった。[Evaluation test]
[Test 1: Decolorizing power]
A portion of test hair (bundle of length 10 cm × width 0.5 cm: Japanese, black hair) is decolorized, and the decolorization power is determined by the following comparison by comparison with a comparative example using the same first agent. The results are shown in Table 3 below.
<Evaluation criteria>
Evaluation A: Decolorized as in the comparative example.
Evaluation (circle): Although it was a little weaker than a comparative example, it fully decolored.
Evaluation Δ: Decolorization was insufficient.
Evaluation x: Decolorization was not performed.
〔試験2:皮膚への刺激〕
試験1において、調製した脱色剤を5人が指で触り、指先に刺激を感じたかどうかを評価し、その結果を下記表3に記載した。
<評価基準>
評価◎:5人中、誰も刺激を感じなかった。
評価○:5人中、1人又は2人が刺激を感じた。
評価△:5人中、3人又は4人が刺激を感じた。
評価×:5人中、5人全員が刺激を感じた。[Test 2: Skin irritation]
In Test 1, it was evaluated whether five people touched the prepared depigmenting agent with a finger and felt irritation on the fingertip, and the results are shown in Table 3 below.
<Evaluation criteria>
Evaluation A: No one of the five felt irritation.
Evaluation ○: One or two of the five felt irritation.
Evaluation Δ: 3 or 4 out of 5 felt irritation.
Evaluation x: 5 people out of 5 felt irritation.
〔試験3:体毛損傷〕
試験1において、試験後に、毛髪を流水で洗浄し、ドライヤー(パナソニック社製TURBODRY1200)で乾燥後の、毛髪の損傷の有無を下記基準によって評価し、その結果を下記表3に記載した。
<評価基準>
評価◎:キューティクルの損傷が全くなく、脱色剤の影響を受けず、完全な毛髪であった。
評価○:損傷(数枚のキューティクルの剥離)が若干見受けられたが、目立つものではなかった。
評価△:損傷(キューティクル及びコルテックスの剥離)が散見された。
評価×:損傷(キューティクル及びコルテックスの剥離と、メデュラが露出)が見られた。[Test 3: Hair damage]
In Test 1, after the test, the hair was washed with running water and dried with a drier (Panasonic Corporation TURBODRY 1200), and the presence or absence of hair damage was evaluated according to the following criteria. The results are shown in Table 3 below.
<Evaluation criteria>
Evaluation A: The cuticle was not damaged at all, was not affected by the decoloring agent, and was a complete hair.
Evaluation (circle): Although damage (several cuticle peeling) was seen, it was not conspicuous.
Evaluation (triangle | delta): Damage (peeling of a cuticle and cortex) was seen occasionally.
Evaluation x: Damage (detachment of cuticle and cortex, and exposure of medulla) was observed.
〔試験4:脱色後の連続染色〕
脱色後に毛髪を流水で洗浄した後、直ちに、褐色の染色剤(花王社製、リーゼプリティア泡カラー:マロンブラウン)を用いて染色を行い、さらに流水で洗浄したときの毛髪の状態を下記基準によって評価し、その結果を下記表3に記載した。
<評価基準>
評価◎:染色が完全に行われ、洗浄による染料の流失も見られなかった。
評価○:染色は十分に行われたものの、洗浄による若干の染料の流失が見られた。
評価△:染色が不十分で、洗浄による染料の流失も目立った。
評価×:染色できなかった。[Test 4: Continuous dyeing after decolorization]
After decolorization, the hair is washed with running water, and then immediately dyed with a brown dye (Kao Co., Ltd., Liese Prettyr Foam Color: Maron Brown). The results are shown in Table 3 below.
<Evaluation criteria>
Evaluation (double-circle): Dyeing was performed completely and no dye was washed away by washing.
Evaluation (circle): Although dyeing | staining was fully performed, some runoff of the dye by washing | cleaning was seen.
Evaluation (triangle | delta): Dyeing | staining was inadequate and the runoff of the dye by washing | cleaning was also conspicuous.
Evaluation x: Dyeing was not possible.
Claims (10)
脱色剤に使用されるものであり、
酸化マグネシウム、酸化カルシウム、又はマグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなり、
前記脱色剤に使用する際、前記助剤の混合比率が、前記助剤を除いた前記脱色剤量に対する質量比で1:0.1以上1:2以下である、助剤。 Auxiliary agent that suppresses or protects hair and skin damage,
Used for depigmenting agents,
Magnesium oxide, Ri name contains a composite oxide or a mixture of these calcium oxide, or magnesium and calcium,
When used in the bleaching agent, the mixing ratio of the aid is 1 weight ratio relative to the bleaching agent amount excluding the aid: 0.1 to 1: 2 Ru der hereinafter aids.
アルカリ剤又は酸化助剤と、及び
体毛及び体膚の損傷を抑制し又は保護する助剤とを備えてなり、
前記助剤が、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなり、
前記助剤の混合比率が、前記助剤を除いた前記脱色剤量に対する質量比で1:0.1以上1:2以下である、脱色剤。 A depigmenting agent,
It comprises an alkali or oxidizing aid, and the hair and body peel of damage by suppressing or protected to aid,
The auxiliary agent comprises magnesium oxide, calcium oxide, a composite oxide of magnesium and calcium, or a mixture thereof;
The mixing ratio of the aid is 1 weight ratio relative to the bleaching agent amount excluding the aid: 0.1 to 1: 2 Ru der hereinafter bleaching agent.
第1剤と、及び第2剤とを備えてなり、
前記第1剤が、アルカリ剤又は酸化助剤と、及び体毛及び体膚の損傷を抑制し又は保護する助剤とを含んでなり、
前記助剤が、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなり、
前記第2剤が、酸化剤を含有してなり、
前記第2剤の混合比率が、前記第1剤の全量に対して、体積比で1:1以上であり1:5以下である、脱色剤。 A depigmenting agent,
Comprising a first agent and a second agent;
Wherein the first agent comprises an alkali or oxidizing aid, and the hair and to suppress damage to the body peel or protection to that aid,
The auxiliary agent comprises magnesium oxide, calcium oxide, a composite oxide of magnesium and calcium, or a mixture thereof;
The second agent is, Ri Na contain an oxidizing agent,
A decolorizing agent , wherein the mixing ratio of the second agent is 1: 1 or more and 1: 5 or less by volume ratio with respect to the total amount of the first agent.
第1剤と、第2剤と、及び第3剤とを備えてなり、
前記第1剤が、アルカリ剤又は酸化助剤を含んでなり、
前記第2剤が、体毛及び体膚の損傷を抑制し又は保護する助剤を含んでなり、
前記助剤が、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなり、
前記第3剤が、酸化剤を含有してなる、
前記第3剤の混合比率が、前記第1剤及び前記第2剤の全量に対して、体積比で1:1以上であり1:5以下である、脱色セット。 A decolorization set,
Comprising a first agent, a second agent, and a third agent;
The first agent comprises an alkali agent or an oxidation aid,
The second agent comprises an auxiliary agent that suppresses or protects damage to body hair and skin,
The aid is Ri Na include magnesium oxide, calcium oxide, a composite oxide or a mixture of these magnesium and calcium,
The third agent contains an oxidizing agent,
The decolorization set in which the mixing ratio of the third agent is 1: 1 or more and 1: 5 or less by volume with respect to the total amount of the first agent and the second agent .
脱色剤と、染色剤とを備えてなり、
脱色剤が、請求項2又は3に記載されたものである、染色セット。 A staining set,
A depigmenting agent and a dyeing agent,
The dyeing | staining set whose decoloring agent is what was described in Claim 2 or 3.
体毛に、体毛及び体膚の損傷を抑制し又は保護する助剤及び脱色剤を付与し、
前記体毛から色素を除去することを含んでなり、
前記助剤が、請求項1に記載されたものであり、
前記脱色剤が、請求項2又は請求項3に記載されたものである、脱色方法。 A method of decolorizing,
To the hair, an auxiliary agent and a decoloring agent that suppresses or protects damage to the hair and skin,
Removing pigment from the hair,
The auxiliary agent is the one described in claim 1,
4. A decoloring method, wherein the decoloring agent is the one described in claim 2 or claim 3.
体毛に、体毛及び体膚の損傷を抑制し又は保護する助剤及び脱色剤を付与し、
前記体毛から色素を除去し、
前記体毛を染色剤で染色することを含んでなり、
前記助剤が、請求項1に記載されたものであり、
前記脱色剤が、請求項2又は請求項3に記載されたものである、染色方法。 A method of dyeing,
Hair, the grant hair and body damage peel the suppression or protection to that aid and decolorizing agents,
Remove pigment from the hair,
Dyeing the body hair with a dyeing agent;
The auxiliary agent is the one described in claim 1,
The dyeing | staining method whose said decoloring agent is what was described in Claim 2 or Claim 3.
脱色剤に使用されるものであり、
体毛及び体膚の損傷を抑制し又は保護する助剤を含んでなり、
前記助剤が、酸化マグネシウム、酸化カルシウム、又はマグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなり、
前記脱色剤に使用する際、前記助剤の混合比率が、前記助剤を除いた前記脱色剤量に対する質量比で1:0.1以上1:2以下である、美容用剤。 A cosmetic agent,
Used for depigmenting agents,
Comprising an auxiliary agent that suppresses or protects hair and skin damage,
The aid is magnesium oxide, Ri name contains a composite oxide or a mixture of these calcium oxide, or magnesium and calcium,
When used in the bleaching agent, the mixing ratio of the aid is in a mass ratio relative to the bleaching agent amount excluding the aid 1: 0.1 or more 1: 2 Ru der hereinafter cosmetic agent.
脱色剤として、アルカリ剤又は酸化助剤と、及び
体毛及び体膚の損傷を抑制し又は保護する助剤とを備えてなり、
前記助剤が、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなり、
前記助剤の混合比率が、前記助剤を除いた前記脱色剤量に対する質量比で1:0.1以上1:2以下である、美容用剤。 A cosmetic agent,
As bleaching agent, it comprises an alkali or oxidizing aid, and the hair and body peel of damage by suppressing or protected to aid,
The aid is Ri Na include magnesium oxide, calcium oxide, a composite oxide or a mixture of these magnesium and calcium,
The mixing ratio of the aid is 1 weight ratio relative to the bleaching agent amount excluding the aid: 0.1 to 1: 2 Ru der hereinafter cosmetic agent.
脱色用であって、
第1剤と、及び第2剤とを備えてなり、
前記第1剤が、アルカリ剤又は酸化助剤と、及び、体毛及び体膚の損傷を抑制し又は保護する助剤とを含んでなり、
前記助剤が、酸化マグネシウム、酸化カルシウム、マグネシウム及びカルシウムの複合酸化物又はこれらの混合物を含んでなり、
前記第2剤が、酸化剤を含有してなり、
前記第2剤の混合比率が、前記第1剤の全量に対して、体積比で1:1以上であり1:5以下である、美容用剤。
A cosmetic agent,
For decolorization,
Comprising a first agent and a second agent;
Wherein the first agent is an alkali or oxidizing aids, and comprises a aid for suppressing damage to hair and body peel or protection,
The auxiliary agent comprises magnesium oxide, calcium oxide, a composite oxide of magnesium and calcium, or a mixture thereof;
The second agent contains an oxidizing agent,
A cosmetic agent in which the mixing ratio of the second agent is 1: 1 or more and 1: 5 or less by volume with respect to the total amount of the first agent.
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JP2002241249A (en) * | 2001-02-19 | 2002-08-28 | Hoyu Co Ltd | Hair dyeing method |
JP2002326916A (en) * | 2001-05-02 | 2002-11-15 | Mandom Corp | Hair decolorant |
WO2009122873A1 (en) * | 2008-03-31 | 2009-10-08 | ホーユー 株式会社 | Oxidant-containing composition |
WO2012159926A2 (en) * | 2011-05-20 | 2012-11-29 | L'oreal | Keratin fibre bleaching composition in compressed form with persulfate and an ammonium salt |
JP2013147467A (en) * | 2012-01-20 | 2013-08-01 | Hoyu Co Ltd | Hair bleaching/decoloring agent composition |
JP2013147468A (en) * | 2012-01-20 | 2013-08-01 | Hoyu Co Ltd | Hair bleaching/decoloring agent composition |
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FR1207436A (en) * | 1958-04-15 | 1960-02-16 | Lawrence Richard Bruce Inc | Bleaching composition for hair |
FR2820312B1 (en) * | 2001-02-02 | 2003-05-02 | Oreal | PULVERULENT COMPOSITION FOR THE DECOLORATION OF HUMAN KERATINIC FIBERS |
ES2562020T3 (en) * | 2001-03-19 | 2016-03-02 | L'avant Garde Inc. | Composition to simultaneously lighten and color the hair using acidic and basic dyes stable to fading |
FR2824735A1 (en) * | 2001-05-16 | 2002-11-22 | Oreal | PULVERULENT COMPOSITION FOR THE DECOLORATION OF HUMAN KERATINIC FIBERS |
US6703004B2 (en) * | 2002-04-03 | 2004-03-09 | Revlon Consumer Products Corporation | Method and compositions for bleaching hair |
FR2864444B1 (en) * | 2003-12-29 | 2006-02-03 | Oreal | ANHYDROUS DECOLORATION PASTE COMPRISING AT LEAST ONE CERAMIC TYPE COMPOUND AND METHOD IMPLEMENTING THE SAME |
DE102004045414A1 (en) * | 2004-09-18 | 2006-03-30 | Henkel Kgaa | Process for the fashionable color change of keratin-containing fibers |
FR2887768B1 (en) * | 2005-06-29 | 2007-08-17 | Oreal | COMPOSITION FOR THE SIMULTANEOUS DECOLORATION AND COLORING OF KERATIN FIBERS COMPRISING ANIONIC OR NON-IONIC COLORANT AND AN ORGANIC INERT LIQUID |
AU2009243078B2 (en) * | 2008-04-29 | 2015-06-04 | Hair Systems, Inc. | Composition and method for cream bleach product |
DE202009008383U1 (en) * | 2009-06-15 | 2009-08-27 | Szaidel Cosmetic Gmbh | Cosmetic preparation for bleaching keratinic fibers, in particular human hair |
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2016
- 2016-06-14 WO PCT/JP2016/067601 patent/WO2017013964A1/en active Application Filing
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JP2002241249A (en) * | 2001-02-19 | 2002-08-28 | Hoyu Co Ltd | Hair dyeing method |
JP2002326916A (en) * | 2001-05-02 | 2002-11-15 | Mandom Corp | Hair decolorant |
WO2009122873A1 (en) * | 2008-03-31 | 2009-10-08 | ホーユー 株式会社 | Oxidant-containing composition |
WO2012159926A2 (en) * | 2011-05-20 | 2012-11-29 | L'oreal | Keratin fibre bleaching composition in compressed form with persulfate and an ammonium salt |
JP2013147467A (en) * | 2012-01-20 | 2013-08-01 | Hoyu Co Ltd | Hair bleaching/decoloring agent composition |
JP2013147468A (en) * | 2012-01-20 | 2013-08-01 | Hoyu Co Ltd | Hair bleaching/decoloring agent composition |
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JPWO2017013964A1 (en) | 2017-07-20 |
CN107708653A (en) | 2018-02-16 |
WO2017013964A1 (en) | 2017-01-26 |
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