JP2023109187A - Cold sensation imparting composition - Google Patents
Cold sensation imparting composition Download PDFInfo
- Publication number
- JP2023109187A JP2023109187A JP2022010564A JP2022010564A JP2023109187A JP 2023109187 A JP2023109187 A JP 2023109187A JP 2022010564 A JP2022010564 A JP 2022010564A JP 2022010564 A JP2022010564 A JP 2022010564A JP 2023109187 A JP2023109187 A JP 2023109187A
- Authority
- JP
- Japan
- Prior art keywords
- mass
- cooling sensation
- imparting composition
- polyoxyethylene
- glyceryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 230000035807 sensation Effects 0.000 title abstract description 8
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- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 11
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 235000002568 Capsicum frutescens Nutrition 0.000 claims abstract description 5
- 229940116257 pepper extract Drugs 0.000 claims abstract description 4
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- 239000002826 coolant Substances 0.000 claims description 10
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 10
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- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 2
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Abstract
Description
本発明は、頭皮や皮膚に冷感を付与する冷感付与組成物に関する。 TECHNICAL FIELD The present invention relates to a cooling sensation imparting composition that imparts a cooling sensation to the scalp and skin.
シャンプー、ボディシャンプーなどの洗浄剤は、基本機能の洗浄性に加えて、使用中や使用後に冷感を感じられることが好まれる場合がある。そのため、メントールなどの冷感剤を含有させることにより冷感を付与しているが、単に冷感剤を加えるのみでは高い冷感を付与することができず、使用後の冷感の持続性をも得られるものではない。 In some cases, detergents such as shampoos and body shampoos are preferred to have a cooling sensation during and after use, in addition to their basic function of detergency. Therefore, a cooling sensation is imparted by adding a cooling agent such as menthol, but simply adding a cooling agent cannot impart a high cooling sensation, and it is difficult to maintain the cooling sensation after use. cannot be obtained.
そこで、優れた冷感を発揮させるために、冷感物質と温感物質とを配合した毛髪用洗浄剤組成物（特許文献１）や、冷感物質とバニリルブチルエーテルを含有した冷感剤組成物（特許文献２）などが提案されている。しかし、冷感を単に高めるだけでは、冷感が痛みや灼熱感などの不快な刺激として感じられる場合があるという問題がある。 Therefore, in order to exhibit an excellent cooling sensation, a hair cleanser composition containing a cooling sensation substance and a warming substance (Patent Document 1), and a cooling agent composition containing a cooling sensation substance and vanillyl butyl ether. (Patent Document 2) and the like have been proposed. However, simply enhancing the cold sensation has the problem that the cold sensation may be perceived as an unpleasant stimulus such as pain or a burning sensation.
したがって、本発明の目的は、高い冷感を付与することができ、しかも痛みや灼熱感などの不快な刺激が無く、付与した冷感の持続性にも優れる冷感付与組成物を提供することにある。 Accordingly, an object of the present invention is to provide a cooling sensation-imparting composition that can impart a strong cooling sensation, does not cause unpleasant stimuli such as pain and burning sensation, and is excellent in the persistence of the imparted cooling sensation. It is in.
本発明者らは、上記課題に鑑みて鋭意検討した結果、一定量の冷感剤とトウガラシエキスに加え、一定量のエトキシジグリコールとを組み合わせた組成物が、使用時には高い冷感を付与することができるとともに、痛みや灼熱感などの不快な刺激が無く、しかも付与した冷感の持続性にも優れることを見出し、本発明を完成するに至った。 The inventors of the present invention have made intensive studies in view of the above problems, and found that a composition in which a certain amount of ethoxydiglycol is combined with a certain amount of a cooling sensation agent and a capsicum extract imparts a high cooling sensation when used. The present invention has been completed on the basis of the finding that the cooling sensation is excellent in the longevity of the cooling sensation imparted without causing unpleasant stimuli such as pain and burning sensation.
すなわち、本発明の冷感付与組成物は、（Ａ）１～５質量％の冷感剤、（Ｂ）０．００５～０．５質量％のトウガラシエキス、および（Ｃ）０．１～２質量％のエトキシジグリコールを含有することを特徴とする。 That is, the cooling sensation imparting composition of the present invention comprises (A) 1 to 5% by mass of a cooling agent, (B) 0.005 to 0.5% by mass of red pepper extract, and (C) 0.1 to 2 It is characterized by containing mass % of ethoxydiglycol.
本発明の冷感付与組成物は、（Ａ）冷感剤が、メントール、ｌ－メンチルグリセリルエーテル、カンファ、ボルネオールおよびユーカリプトールからなる群から選ばれる２種以上を含有することが好ましく、少なくともｌ－メンチルグリセリルエーテルと、ユーカリプトールとを含有することがより好ましい。 In the cooling sensation imparting composition of the present invention, (A) the cooling agent preferably contains two or more selected from the group consisting of menthol, l-menthyl glyceryl ether, camphor, borneol and eucalyptol, and at least More preferably, it contains l-menthyl glyceryl ether and eucalyptol.
本発明の冷感付与組成物は、さらに（Ｄ）非イオン性界面活性剤を含有することが好ましく、ポリオキシエチレン鎖を有する非イオン性界面活性剤を含有することがより好ましい。 The cooling sensation imparting composition of the present invention preferably further contains (D) a nonionic surfactant, more preferably a nonionic surfactant having a polyoxyethylene chain.
本発明の冷感付与組成物は、エタノールを含有することが好ましい。 The cooling sensation imparting composition of the present invention preferably contains ethanol.
また、本発明の冷感付与組成物は、洗浄剤組成物であることが好ましい。 Moreover, it is preferable that the cooling sensation imparting composition of the present invention is a detergent composition.
本発明の冷感付与組成物は、上記構成を有することで、使用時には高い冷感を付与することができるとともに、痛みや灼熱感などの不快な刺激が無く、しかも付与した冷感の持続性にも優れるという効果を奏する。 The cooling sensation-imparting composition of the present invention has the above-described structure, so that it can impart a high cooling sensation when used, does not cause unpleasant stimuli such as pain and burning sensation, and provides a long-lasting cooling sensation. It also has the effect of being excellent.
本発明の冷感付与組成物は、（Ａ）冷感剤、（Ｂ）トウガラシエキス、および（Ｃ）エトキシジグリコールを必須に含有する。 The cooling sensation imparting composition of the present invention essentially contains (A) a cooling agent, (B) capsicum extract, and (C) ethoxydiglycol.
〔（Ａ）冷感剤〕
本発明の冷感剤は、化粧料に用いられるものであれば特に限定されないが、メントール、ｌ－メンチルグリセリルエーテル、カンファ、ボルネオール、ユーカリプトールなどを例示することができ、持続的な高い冷感を付与するために２種以上を組合せて用いるのが好ましい。なかでも高い冷感を発揮しつつ、痛みや灼熱感などの不快な刺激を抑制するために、少なくとも（ａ１）ｌ－メンチルグリセリルエーテルと（ａ２）ユーカリプトールとを組み合わせて用いるのがより好ましい。
[(A) cooling agent]
The cooling sensation agent of the present invention is not particularly limited as long as it is used in cosmetics, but examples include menthol, l-menthyl glyceryl ether, camphor, borneol, eucalyptol, etc. It is preferable to use two or more of them in combination in order to impart a feeling. Among them, it is more preferable to use at least (a1) l-menthyl glyceryl ether and (a2) eucalyptol in combination in order to suppress unpleasant stimuli such as pain and burning while exhibiting a high cooling sensation. .
なお、（ａ１）ｌ－メンチルグリセリルエーテルと（ａ２）ユーカリプトールとを組み合わせて用いる場合、その質量割合〔（ａ１）／（ａ２）〕は、０．２以上であることが好ましく、０．４以上であることがより好ましい。また、質量割合〔（ａ１）／（ａ２）〕は、２以下であることが好ましく、１．５以下であることがより好ましい。これらから、好ましい質量割合〔（ａ１）／（ａ２）〕は、０．２～２であり、より好ましくは０．４～１．５である。 When (a1) l-menthyl glyceryl ether and (a2) eucalyptol are used in combination, the mass ratio [(a1)/(a2)] is preferably 0.2 or more, and 0.2. 4 or more is more preferable. Also, the mass ratio [(a1)/(a2)] is preferably 2 or less, more preferably 1.5 or less. From these, the mass ratio [(a1)/(a2)] is preferably 0.2 to 2, more preferably 0.4 to 1.5.
冷感剤の含有量は、使用時および使用後に高い冷感を付与する観点から、冷感付与組成物中、好ましくは１質量％以上であり、より好ましくは１．５質量％以上である。また、使用時および使用後の不快な刺激感を抑制する観点から、冷感付与組成物中、好ましくは５質量％以下であり、より好ましくは４．５質量％以下である。これらから、好ましい含有量は、冷感付与組成物中、１～５質量％であり、より好ましくは１．５～４．５質量％である。 The content of the cooling sensation agent is preferably 1% by mass or more, more preferably 1.5% by mass or more, in the cooling sensation imparting composition from the viewpoint of imparting a high cooling sensation during and after use. In addition, from the viewpoint of suppressing unpleasant irritation during and after use, it is preferably 5% by mass or less, more preferably 4.5% by mass or less, in the cooling sensation imparting composition. Based on these, the preferred content is 1 to 5% by mass, more preferably 1.5 to 4.5% by mass, in the cooling sensation imparting composition.
〔（Ｂ）トウガラシエキス〕
本発明のトウガラシエキスは、トウガラシの茎、葉、果実などを、水、エタノール、グリセリン、１，３－ブチレングリコールなどの水性溶媒により抽出することができる。また、トウガラシエキスは市販品を用いることもでき、例えば、商品名トウガラシチンキ（丸善製薬株式会社）、商品名トウガラシチンキ（香栄興業株式会社）、商品名トウガラシエキス－１５（アルプス薬品工業株式会社）などを例示することができる。
[(B) Capsicum extract]
The hot pepper extract of the present invention can be extracted from hot pepper stems, leaves, fruits, etc. with an aqueous solvent such as water, ethanol, glycerin, 1,3-butylene glycol. In addition, a commercially available red pepper extract can also be used. ) can be exemplified.
トウガラシエキスの含有量は、使用時および使用後に高い冷感を付与する観点から、冷感付与組成物中、好ましくは０．００５質量％以上であり、より好ましくは０．０１質量％以上である。また、温感よりも冷感を付与する観点から、冷感付与組成物中、好ましくは０．５質量％以下であり、より好ましくは０．４質量％以下である。これらから、好ましい含有量は、冷感付与組成物中、０．００５～０．５質量％であり、より好ましくは０．０１～０．４質量％である。 The content of the hot pepper extract is preferably 0.005% by mass or more, more preferably 0.01% by mass or more in the composition for providing a cooling sensation, from the viewpoint of imparting a high cooling sensation during and after use. . Moreover, from the viewpoint of imparting a cooling sensation rather than a warming sensation, it is preferably 0.5% by mass or less, more preferably 0.4% by mass or less, in the cooling sensation imparting composition. From these, the preferred content is 0.005 to 0.5% by mass, more preferably 0.01 to 0.4% by mass, in the composition for imparting cooling sensation.
〔（Ｃ）エトキシジグリコール〕
エトキシジグリコールは、化粧料に用いられるものであれば特に限定されず、その含有量は、冷感の持続性の観点から、冷感付与組成物中、好ましくは０．１質量％以上であり、より好ましくは０．２質量％以上である。また、それ以上の持続効果が期待できなくなることから、冷感付与組成物中、好ましくは２質量％以下であり、より好ましくは１．５質量％以下である。これらから、好ましい含有量は、冷感付与組成物中、０．１～２質量％であり、より好ましくは０．２～１．５質量％である。
[(C) ethoxydiglycol]
Ethoxydiglycol is not particularly limited as long as it is used in cosmetics, and its content is preferably 0.1% by mass or more in the cooling sensation imparting composition from the viewpoint of the persistence of cooling sensation. , more preferably 0.2% by mass or more. Further, since a longer lasting effect cannot be expected, it is preferably 2% by mass or less, more preferably 1.5% by mass or less, in the cooling sensation-imparting composition. From these, the preferred content is 0.1 to 2% by mass, more preferably 0.2 to 1.5% by mass, in the cooling sensation imparting composition.
〔（Ｄ）非イオン性界面活性剤〕
冷感付与組成物には、冷感の持続性の観点から、非イオン性界面活性剤を含有させることができる。具体的には、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ポリオキシエチレン脂肪酸エステル、アルキル（ポリ）グリコシド、ポリオキシエチレンアルキルエーテル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンラノリン、ポリオキシエチレンフィトステロール、ポリオキシエチレンコレステロールなどが挙げられ、１種を単独で用いることができ、２種以上を組合せて用いることもできる。
[(D) nonionic surfactant]
The cooling sensation imparting composition can contain a nonionic surfactant from the viewpoint of the persistence of the cooling sensation. Specifically, glycerin fatty acid ester, sorbitan fatty acid ester, sucrose fatty acid ester, polyoxyethylene fatty acid ester, alkyl (poly) glycoside, polyoxyethylene alkyl ether, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, Polyoxyethylene hydrogenated castor oil, polyoxyethylene lanolin, polyoxyethylene phytosterol, polyoxyethylene cholesterol and the like can be mentioned, and one kind can be used alone or two or more kinds can be used in combination.
グリセリン脂肪酸エステルとしては、モノグリセリン脂肪酸エステル及びポリグリセリン脂肪酸エステルのいずれも含む。モノグリセリン脂肪酸エステルとしては、例えば、モノカプリル酸グリセリル、モノカプリン酸グリセリル、モノラウリン酸グリセリル、モノミリスチン酸グリセリル、モノパルミチン酸グリセリル、モノステアリン酸グリセリル、モノイソステアリン酸グリセリル、モノベヘン酸グリセリル、モノオレイン酸グリセリ、モノエルカ酸グリセリル、セスキオレイン酸グリセリル、ジステアリン酸グリセリル、ジイソステアリン酸グリセリル、ジアラキン酸グリセリルなどが挙げられる。ポリグリセリン脂肪酸エステルとしては、例えば、モノカプリル酸ジグリセリル、モノカプリル酸デカグリセリル、モノカプリン酸ヘキサグリセリル、モノラウリン酸テトラグリセリル、モノラウリン酸ヘキサグリセリル、モノラウリン酸デカグリセリル、モノラウリン酸ポリ（４～１０）グリセリル、モノミリスチン酸デカグリセリル、モノステアリン酸デカグリセリル、モノイソステアリン酸デカグリセリル、モノステアリン酸ポリ（２～１０）グリセリル、モノオレイン酸ジグリセリル、モノオレイン酸ヘキサグリセリル、セスキオレイン酸ジグリセリル、ジイソステアリン酸ポリ（２～１０）グリセリル、ジステアリン酸ポリ（６～１０）グリセリル、トリイソステアリン酸ジグリセリル、トリステアリン酸ポリ（１０）グリセリル等の上記モノグリセリン脂肪酸エステルの重合度２～１０のポリグリセリン脂肪酸エステルなどが挙げられる。 Glycerin fatty acid esters include both monoglycerin fatty acid esters and polyglycerin fatty acid esters. Examples of monoglycerin fatty acid esters include glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, monooleic acid. glyceryl, glyceryl monoerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, glyceryl dialachinate and the like. Examples of polyglycerin fatty acid esters include diglyceryl monocaprylate, decaglyceryl monocaprylate, hexaglyceryl monocaprate, tetraglyceryl monolaurate, hexaglyceryl monolaurate, decaglyceryl monolaurate, and poly(4-10) monolaurate. Glyceryl, decaglyceryl monomyristate, decaglyceryl monostearate, decaglyceryl monoisostearate, poly(2-10)glyceryl monostearate, diglyceryl monooleate, hexaglyceryl monooleate, diglyceryl sesquioleate, diisostearin Polyglycerin fatty acid with a polymerization degree of 2 to 10 of the above monoglycerin fatty acid ester such as poly(2-10) glyceryl acid, poly(6-10) glyceryl distearate, diglyceryl triisostearate, poly(10) glyceryl tristearate and esters.
ソルビタン脂肪酸エステルとしては、例えば、モノオレイン酸ソルビタン、モノステアリン酸ソルビタン、モノイソステアリン酸ソルビタン、モノパルミチン酸ソルビタン、モノラウリン酸ソルビタン、トリオレイン酸ソルビタン、トリステアリン酸ソルビタン、セスキステアリン酸ソルビタン、セスキオレイン酸ソルビタン、セスキイソステアリン酸ソルビタン、ヤシ油脂肪酸ソルビタンなどが挙げられる。 Examples of sorbitan fatty acid esters include sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monopalmitate, sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, and sesquioleic acid. Sorbitan, sorbitan sesquiisostearate, sorbitan coconut oil fatty acid, and the like.
ショ糖脂肪酸エステルとしては、例えば、ショ糖ラウリン酸エステル、ショ糖オレイン酸エステル、ショ糖ミリスチン酸エステル、ショ糖パルミチン酸エステル、ショ糖ステアリン酸エステル、ショ糖ベヘニン酸エステルなどが挙げられる。 Examples of sucrose fatty acid esters include sucrose laurate, sucrose oleate, sucrose myristate, sucrose palmitate, sucrose stearate, and sucrose behenate.
ポリオキシエチレン脂肪酸エステルとしては、ポリオキシエチレンモノ脂肪酸エステル及びポリオキシエチレンジ脂肪酸エステルのいずれをも含む。ポリオキシエチレンモノ脂肪酸エステルとしては、例えば、モノオレイン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、モノラウリン酸ポリエチレングリコールなどが挙げられる。ポリオキシエチレンジ脂肪酸エステルとしては、例えば、ジラウリン酸ポリエチレングリコール、ジミリスチン酸ポリエチレングリコール、ジパルミチン酸ポリエチレングリコール、ジステアリン酸ポリエチレングリコール、ジイソステアリン酸ポリエチレングリコール、ジベヘン酸ポリエチレングリコールなどが挙げられる。 Polyoxyethylene fatty acid esters include both polyoxyethylene mono-fatty acid esters and polyoxyethylene di-fatty acid esters. Examples of polyoxyethylene monofatty acid esters include polyethylene glycol monooleate, polyethylene glycol monostearate, and polyethylene glycol monolaurate. Examples of polyoxyethylene difatty acid esters include polyethylene glycol dilaurate, polyethylene glycol dimyristate, polyethylene glycol dipalmitate, polyethylene glycol distearate, polyethylene glycol diisostearate, and polyethylene glycol dibehenate.
アルキル（ポリ）グリコシドとしては、例えば、メチルグルコシド、セトステアリルグルコシド、オクチルグルコシド、２－エチルヘキシルポリグルコシド、デシルグルコシド、ラウリルグルコシドなどが挙げられる。 Alkyl (poly)glycosides include, for example, methyl glucoside, cetostearyl glucoside, octyl glucoside, 2-ethylhexyl polyglucoside, decyl glucoside, lauryl glucoside and the like.
ポリオキシエチレンアルキルエーテルとしては、例えば、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンポリオキシプロピレンラウリルエーテルなどが挙げられる。 Examples of polyoxyethylene alkyl ethers include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether and the like.
ポリオキシエチレングリセリン脂肪酸エステルとしては、例えば、オレイン酸ポリオキシエチレングリセリル、ステアリン酸ポリオキシエチレングリセリル、イソステアリン酸ポリオキシエチレングリセリル、ヤシ油脂肪酸ポリオキシエチレングリセリル、ジイソステアリン酸ポリオキシエチレングリセリル、トリイソステアリン酸ポリオキシエチレングリセリルなどが挙げられる。 Examples of polyoxyethylene glycerin fatty acid esters include polyoxyethylene glyceryl oleate, polyoxyethylene glyceryl stearate, polyoxyethylene glyceryl isostearate, polyoxyethylene glyceryl coconut oil fatty acid, polyoxyethylene glyceryl diisostearate, and triisostearic acid. Examples include polyoxyethylene glyceryl.
ポリオキシエチレンソルビタン脂肪酸エステルとしては、例えば、モノラウリン酸ポリオキシエチレンソルビタン、モノパルミチン酸ポリオキシエチレンソルビタン、モノステアリン酸ポリオキシエチレンソルビタン、モノオレイン酸ポリオキシエチレンソルビタン、モノイソステアリン酸ポリオキシエチレンソルビタン、モノヤシ油脂肪酸ポリオキシエチレンソルビタン、トリステアリン酸ポリオキシエチレンソルビタン、トリオレイン酸ポリオキシエチレンソルビタンなどが挙げられる。 Examples of polyoxyethylene sorbitan fatty acid esters include polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monoisostearate, monococonut oil fatty acid polyoxyethylene sorbitan, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan trioleate, and the like.
これら非イオン性界面活性剤のうち、ポリオキシエチレン鎖を有する非イオン性界面活性剤を用いることが好ましく、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレンアルキルエーテルを用いることがより好ましい。 Among these nonionic surfactants, it is preferable to use nonionic surfactants having a polyoxyethylene chain, such as polyoxyethylene hydrogenated castor oil, polyoxyethylene glycerin fatty acid ester, and polyoxyethylene alkyl ether. is more preferred.
なかでも、イソステアリン酸ＰＥＧ－５グリセリル（ＨＬＢ＝８）、イソステアリン酸ＰＥＧ－６グリセリル（ＨＬＢ＝８）、ステアリン酸ＰＥＧ－５グリセリル（ＨＬＢ＝９）、イソステアリン酸ＰＥＧ－８グリセリル（ＨＬＢ＝１０）、イソステアリン酸ＰＥＧ－１０グリセリル（ＨＬＢ＝１０）、ステアリン酸ＰＥＧ－１０グリセリル（ＨＬＢ＝１１）、イソステアリン酸ＰＥＧ－１５グリセリル（ＨＬＢ＝１２）、ステアリン酸ＰＥＧ－１５グリセリル（ＨＬＢ＝１３）、イソステアリン酸ＰＥＧ－２０グリセリル（ＨＬＢ＝１３）、ステアリン酸ＰＥＧ－２０グリセリル（ＨＬＢ＝１４）、ヤシ油脂肪酸ＰＥＧ－７グリセリル（ＨＬＢ＝１３）、ポリオキシエチレン（１５）硬化ヒマシ油（ＨＬＢ＝８）、ポリオキシエチレン（１００）硬化ヒマシ油（ＨＬＢ＝１５）、ポリオキシエチレン（２００）硬化ヒマシ油（ＨＬＢ＝１７）などのＨＬＢ８～１７であるポリオキシエチレン鎖を有する非イオン性界面活性剤を用いることが更に好ましい。 PEG-5 glyceryl isostearate (HLB=8), PEG-6 glyceryl isostearate (HLB=8), PEG-5 glyceryl stearate (HLB=9), PEG-8 glyceryl isostearate (HLB=10), among others. , PEG-10 Glyceryl Isostearate (HLB=10), PEG-10 Glyceryl Stearate (HLB=11), PEG-15 Glyceryl Stearate (HLB=12), PEG-15 Glyceryl Stearate (HLB=13), Isostearin PEG-20 Glyceryl Acid (HLB=13), PEG-20 Glyceryl Stearate (HLB=14), PEG-7 Glyceryl Cocoate (HLB=13), Polyoxyethylene (15) Hydrogenated Castor Oil (HLB=8) , Polyoxyethylene (100) hydrogenated castor oil (HLB = 15), polyoxyethylene (200) hydrogenated castor oil (HLB = 17), etc. It is more preferable to use
非イオン性界面活性剤の含有量は、本発明の効果を発揮すれば特に限定されないが、冷感の持続性の観点から、冷感付与組成物中、好ましくは２質量％以上であり、より好ましくは３質量％以上である。また、それ以上の持続効果が期待できなくなることから、冷感付与組成物中、好ましくは１５質量％以下であり、より好ましくは１２質量％以下である。これらから、好ましい含有量は、冷感付与組成物中、２～１５質量％であり、より好ましくは３～１２質量％である。 The content of the nonionic surfactant is not particularly limited as long as the effect of the present invention is exhibited, but from the viewpoint of the persistence of the cooling sensation, it is preferably 2% by mass or more in the cooling sensation imparting composition, and more Preferably, it is 3% by mass or more. In addition, since a longer lasting effect cannot be expected, it is preferably 15% by mass or less, more preferably 12% by mass or less, in the cooling sensation imparting composition. From these, the preferred content is 2 to 15% by mass, more preferably 3 to 12% by mass, in the composition for imparting cooling sensation.
〔他の成分〕
本発明の冷感付与組成物は、必要に応じて、通常の化粧料に用いられる各種成分を含有することができる。具体的には、例えば、脂肪酸石けん、ポリオキシエチレンエーテルカルボン酸塩、Ｎ－アシルサルコシン塩、アルキル硫酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、アルキルりん酸塩、ポリオキシエチレンアルキルエーテルりん酸塩などの陰イオン性界面活性剤；アルキルアミン塩、ジアルキルジメチルアンモニウム塩などの陽イオン性界面活性剤；アルキルベタイン、アミドスルホベタイン、脂肪酸アミドプロピルベタイン、アルキルアミンオキシドなどの両性界面活性剤；油脂、高級アルコール、エステル油、植物油、炭化水素油、ロウ類等の油性成分；ポリアクリル酸、カルボキシビニルポリマー、アクリル酸・メタクリル酸アルキル共重合体、（アクリレーツ／メタクリル酸ステアレス－２０）コポリマー、キサンタンガム、カラギーナン、エチルセルロース、ヒドロキシプロピルメチルセルロース、カチオン化セルロース類等の水溶性増粘剤；１，３－ブチレングリコール、ジプロピレングリコール、ソルビトール、マルチトール、トレハロースなどの多価アルコール；イソプロピルメチルフェノール、フェノキシエタノール、メチルパラベンなどの殺菌剤；グリチルリチン酸、トラネキサム酸、アラントインなどの抗炎症剤；ビタミン類；アミノ酸類；収斂剤；保湿剤；パール化剤；スクラブ剤；美白剤；粉体；色素；顔料；（Ｂ）成分以外の動植物抽出物；酸；アルカリ；水などが挙げられる。
[Other ingredients]
The cooling sensation-imparting composition of the present invention can contain various components used in ordinary cosmetics, if necessary. Specific examples include fatty acid soaps, polyoxyethylene ether carboxylates, N-acylsarcosine salts, alkyl sulfates, polyoxyethylene alkyl ether sulfates, alkyl phosphates, polyoxyethylene alkyl ether phosphates, and the like. anionic surfactants; cationic surfactants such as alkylamine salts and dialkyldimethylammonium salts; Oily components such as alcohol, ester oil, vegetable oil, hydrocarbon oil, wax; polyacrylic acid, carboxyvinyl polymer, acrylic acid/methacrylate alkyl copolymer, (acrylates/steareth-20 methacrylate) copolymer, xanthan gum, carrageenan , ethyl cellulose, hydroxypropylmethyl cellulose, cationic celluloses and other water-soluble thickeners; 1,3-butylene glycol, dipropylene glycol, sorbitol, maltitol, trehalose and other polyhydric alcohols; isopropylmethylphenol, phenoxyethanol, methylparaben, etc. anti-inflammatory agents such as glycyrrhizic acid, tranexamic acid, allantoin; vitamins; amino acids; astringents; moisturizing agents; animal and plant extracts other than; acid; alkali; water and the like.
また、本発明の冷感付与組成物には、使用時に高い冷感を付与する観点から、エタノールを含有させることが好ましい。その含有量は、冷感付与組成物中、好ましくは３～８質量％であり、より好ましくは４～７質量％である。 In addition, it is preferable to incorporate ethanol into the composition for imparting cooling sensation of the present invention from the viewpoint of imparting a high cooling sensation during use. The content thereof is preferably 3 to 8% by mass, more preferably 4 to 7% by mass, in the cooling sensation imparting composition.
本発明の冷感付与組成物は、シャンプー、ボディシャンプー、清拭剤、化粧水、ボディローションなどに用いることができ、シャンプー、ボディシャンプー、清拭剤などの洗浄剤に好適に用いることができる。 The cooling sensation imparting composition of the present invention can be used for shampoos, body shampoos, cleansing agents, lotions, body lotions and the like, and can be suitably used for cleansing agents such as shampoos, body shampoos and cleansing agents.
以下、本発明を実施例に基づいて更に詳細に説明するが、本発明はこれら実施例にのみ限定されるものではない。尚、含有量は特記しない限り「質量％」を表す。 EXAMPLES The present invention will be described in more detail below based on examples, but the present invention is not limited only to these examples. In addition, content represents "mass %" unless otherwise specified.
（実施例１～１１および比較例１～５）
下記の表１～３に示す配合成分を配合し、冷感付与組成物をシャンプーの態様で調製した。なお、表中の含有量（冷感付与組成物１００質量％中の含有量）は、純分の含有量（単位：質量％）で示した。
(Examples 1-11 and Comparative Examples 1-5)
A cooling sensation imparting composition was prepared in the form of a shampoo by blending the ingredients shown in Tables 1 to 3 below. The content in the table (the content in 100% by mass of the cooling sensation imparting composition) is indicated by the pure content (unit: mass%).
（評価）
実施例および比較例で得られた各冷感付与組成物について、下記の評価を５名の評価員にて行った。評価結果は表１～３中に示した。
(evaluation)
Five evaluators performed the following evaluations on each of the cooling sensation imparting compositions obtained in Examples and Comparative Examples. The evaluation results are shown in Tables 1-3.
実施例および比較例で得られた各冷感付与組成物の適量を掌にとり、毎日行うシャンプーと同様にして頭髪を洗浄した。冷感の評価は、洗い流し直後ならびに３０分経過後の頭皮に感じる冷感（冷感の持続性）の強度を０点（全く冷感を感じない）～５点（明瞭に冷感を感じる）の６段階で評価した。評価は、各冷感付与組成物につき、５名の評価員が行い、各評価員の評点の平均点を基準とし、２点未満を「×」、２点から３．５点未満を「△」、３．５点以上を「〇」とした。 Appropriate amounts of each of the cooling sensation imparting compositions obtained in Examples and Comparative Examples were applied to the palm of the hand, and the hair was washed in the same manner as daily shampooing. Evaluation of the cooling sensation was based on the strength of the cooling sensation (duration of cooling sensation) felt on the scalp immediately after rinsing and after 30 minutes had passed, from 0 points (no cooling sensation at all) to 5 points (clear cooling sensation). was evaluated in six stages. Evaluation was performed by 5 evaluators for each cooling sensation imparting composition, and based on the average score of each evaluator, less than 2 points were "x", 2 points to less than 3.5 points were "△ ”, and 3.5 points or more were set as “○”.
また、頭皮への痛みや灼熱感などの不快な刺激については、洗い流し直後ならびに３０分経過後の強度を０点（明瞭に不快な刺激を感じる）～５点（全く不快な刺激を感じない）の６段階で評価した。評価は、各冷感付与組成物につき、５名の評価員が行い、各評価員の評点の平均点を基準とし、２点未満を「×」、２点から３．５点未満を「△」、３．５点以上を「〇」とした。 In addition, regarding unpleasant stimuli such as pain and burning sensation to the scalp, immediately after washing off and after 30 minutes, the intensity is 0 points (distinctly unpleasant irritation is felt) to 5 points (absolutely no unpleasant irritation is felt). was evaluated in six stages. Evaluation was performed by 5 evaluators for each cooling sensation imparting composition, and based on the average score of each evaluator, less than 2 points were "x", 2 points to less than 3.5 points were "△ ”, and 3.5 points or more were set as “○”.
本発明の冷感付与組成物の処方例を以下に示す。 Formulation examples of the cooling sensation imparting composition of the present invention are shown below.
（処方例１：シャンプー）
ｌ－メントール：１．０質量％
ｌ－メンチルグリセリルエーテル０．２質量％
ユーカリプトール：１．０質量％
トウガラシエキス：０．０１質量％
エトキシジグリコール：０．２質量％
ＰＯＥ（１００）硬化ヒマシ油：１．５質量％
モノイソステアリン酸ＰＯＥ（２０）グリセリル：３．０質量％
ＰＯＥ（２）ラウリルエーテル硫酸ナトリウム：２０．０質量％
ラウリン酸アミドプロピルベタイン：５．０質量％
グリセリン：７．０質量％
１，３－ブチレングリコール：３．０質量％
エタノール：５．０質量％
ポリクオタニウム－１０：０．２質量％
クエン酸：０．１質量％
安息香酸ナトリウム：０．３質量％
フェノキシエタノール：０．５質量％
エデト酸ナトリウム塩：０．１質量％
緑茶抽出液：０．０５質量％
グリチルリチン酸ジカリウム：０．１質量％
イソプロピルメチルフェノール：０．１質量％
精製水：残部
合計：１００．０質量％
(Prescription example 1: Shampoo)
l-menthol: 1.0% by mass
l-menthyl glyceryl ether 0.2% by mass
Eucalyptol: 1.0% by mass
Red pepper extract: 0.01% by mass
Ethoxydiglycol: 0.2% by mass
POE (100) hydrogenated castor oil: 1.5% by mass
POE (20) glyceryl monoisostearate: 3.0% by mass
POE (2) sodium lauryl ether sulfate: 20.0% by mass
Lauramidopropyl betaine: 5.0% by mass
Glycerin: 7.0% by mass
1,3-butylene glycol: 3.0 mass%
Ethanol: 5.0% by mass
Polyquaternium-10: 0.2% by mass
Citric acid: 0.1% by mass
Sodium benzoate: 0.3% by mass
Phenoxyethanol: 0.5% by mass
Edetate sodium salt: 0.1% by mass
Green tea extract: 0.05% by mass
Dipotassium glycyrrhizinate: 0.1% by mass
Isopropylmethylphenol: 0.1% by mass
Purified water: Remaining total: 100.0% by mass
（処方例２：ボディシャンプー）
ｌ－メントール：３．０質量％
ｌ－メンチルグリセリルエーテル：１．０質量％
ユーカリプトール：０．５質量％
トウガラシエキス：０．３質量％
エトキシジグリコール：１．０質量％
モノラウリン酸ポリグリセリル－１０：０．５質量％
イソステアリン酸ＰＥＧ－８グリセリル：５．０質量％
Ｎ－ラウロイル－Ｌ－アスパラギン酸ナトリウム液：２．０質量％
ＰＯＥ（１）ラウリルエーテル硫酸ナトリウム：１．０質量％
ラウリン酸アミドプロピルヒドロキシスルホベタイン：３．０質量％
ラウリン酸：７．０質量％
ミリスチン酸：４．０質量％
パルミチン酸：３．０質量％
ステアリン酸：１．０質量％
グリセリン：３．０質量％
カルボキシビニルポリマー：０．２質量％
水酸化カリウム：７．０質量％
シリカ：０．０５質量％
ベントナイト：０．２質量％
ポリリン酸ナトリウム：０．０５質量％
パラオキシ安息香酸メチル：０．２質量％
フェノキシエタノール：０．５質量％
イソプロピルメチルフェノール：０．０５質量％
トリクロサン：０．２質量％
ハッカ油：０．０５質量％
カミツレ抽出液：０．０５質量％
パールカルク抽出液：０．０５質量％
精製水：残部
合計：１００．０質量％
(Prescription example 2: body shampoo)
l-menthol: 3.0 mass%
l-menthyl glyceryl ether: 1.0% by mass
Eucalyptol: 0.5% by mass
Red pepper extract: 0.3% by mass
Ethoxydiglycol: 1.0% by mass
Polyglyceryl monolaurate-10: 0.5% by mass
PEG-8 glyceryl isostearate: 5.0% by mass
Sodium N-lauroyl-L-aspartate liquid: 2.0% by mass
POE (1) sodium lauryl ether sulfate: 1.0% by mass
Lauramidopropyl hydroxysulfobetaine: 3.0% by mass
Lauric acid: 7.0% by mass
Myristic acid: 4.0% by mass
Palmitic acid: 3.0% by mass
Stearic acid: 1.0% by mass
Glycerin: 3.0% by mass
Carboxyvinyl polymer: 0.2% by mass
Potassium hydroxide: 7.0% by mass
Silica: 0.05% by mass
Bentonite: 0.2% by mass
Sodium polyphosphate: 0.05% by mass
Methyl paraoxybenzoate: 0.2% by mass
Phenoxyethanol: 0.5% by mass
Isopropylmethylphenol: 0.05% by mass
Triclosan: 0.2% by mass
Peppermint oil: 0.05% by mass
Chamomile extract: 0.05% by mass
Pearl calc extract: 0.05% by mass
Purified water: Remaining total: 100.0% by mass
（処方例３：顔用清拭剤）
ｌ－メントール：１．５質量％
ｌ－メンチルグリセリルエーテル：０．２５質量％
ユーカリプトール：０．３質量％
トウガラシエキス：０．１質量％
エトキシジグリコール：０．５質量％
ＰＰＧ－６デシルテトラデセス―２０：０．３質量％
ポリグリセリル―４ラウリルエーテル：０．２質量％
エタノール：４０．０質量％
グリセリン：３．０質量％
１，３－ブチレングリコール：１．０質量％
ヒアルロン酸ナトリウム：０．１質量％
アスコルビン酸ナトリウム：０．０５質量％
Ｌ－グルタミン酸：０．０１質量％
Ｌ－アルギニン：０．０１質量％
Ｌ－プロリン：０．０１質量％
ハマメリス抽出液：０．０１質量％
大豆たんぱく抽出液：０．０１質量％
香料：適量
精製水：残部
合計：１００．０質量％
(Prescription Example 3: Facial cleaning agent)
l-menthol: 1.5% by mass
l-menthyl glyceryl ether: 0.25 mass%
Eucalyptol: 0.3% by mass
Red pepper extract: 0.1% by mass
Ethoxydiglycol: 0.5% by mass
PPG-6 decyltetradeceth-20: 0.3 mass%
Polyglyceryl-4 lauryl ether: 0.2% by mass
Ethanol: 40.0% by mass
Glycerin: 3.0% by mass
1,3-butylene glycol: 1.0 mass%
Sodium hyaluronate: 0.1% by mass
Sodium ascorbate: 0.05% by mass
L-glutamic acid: 0.01 mass%
L-arginine: 0.01% by mass
L-proline: 0.01% by mass
Hamamelis extract: 0.01% by mass
Soybean protein extract: 0.01% by mass
Perfume: Appropriate amount Purified water: Balance Total: 100.0% by mass
Claims (7)
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