JP6110134B2 - Acidic beverage - Google Patents

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JP6110134B2
JP6110134B2 JP2012286328A JP2012286328A JP6110134B2 JP 6110134 B2 JP6110134 B2 JP 6110134B2 JP 2012286328 A JP2012286328 A JP 2012286328A JP 2012286328 A JP2012286328 A JP 2012286328A JP 6110134 B2 JP6110134 B2 JP 6110134B2
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acidic
manno
oligosaccharide
beverage
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高橋 知也
知也 高橋
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Kao Corp
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Description

本発明は、酸性飲料に関する。   The present invention relates to an acidic beverage.

マンノオリゴ糖は、マンノースを構成糖とするオリゴ糖であり、例えば、整腸作用、血圧調節作用、免疫賦活作用、体脂肪低減作用などの生理機能を有することが報告されている。近年、このようなマンノオリゴ糖の生理機能に着目し、例えば、2以上10分子以下のマンノースが結合したオリゴ糖類を0.15〜10重量%含有するコーヒー飲料(特許文献1)、ココナッツ果実の胚乳に酵素を作用させて分離・精製したマンノオリゴ糖を含有する食品(特許文献2)などが提案されている。   Manno-oligosaccharide is an oligosaccharide having mannose as a constituent sugar, and has been reported to have physiological functions such as intestinal regulation, blood pressure regulation, immunostimulation, and body fat reduction. In recent years, paying attention to the physiological function of such manno-oligosaccharides, for example, a coffee beverage (Patent Document 1) containing 0.1 to 10% by weight of oligosaccharides to which 2 to 10 molecules of mannose are bound, and endosperm of coconut fruit Foods containing manno-oligosaccharides separated and purified by allowing an enzyme to act on them (Patent Document 2) have been proposed.

一方、麦芽エキスは、ビール飲料の主原料として使用され、ビールの旨味を醸成する成分として広く知られている。   On the other hand, a malt extract is used as a main raw material for beer beverages, and is widely known as a component that brews the umami of beer.

特開2008−22778号公報JP 2008-22778 A 国際公開第2008/062813号International Publication No. 2008/062813

マンノオリゴ糖の生理作用を効果的に発現させるためには、その有効量を継続して摂取することが必要であり、またそれを簡便に達成する手段として飲料の形態とすることが有利である。しかしながら、マンノオリゴ糖を含有する飲料は酸味が強く、継続して摂取する上で障害となりやすい。そのため、マンゴオリゴ糖の酸味が低減された飲みやすい飲料の開発が求められている。
したがって、本発明の課題は、マンゴオリゴ糖の酸味が低減された飲料を提供することにある。
In order to effectively manifest the physiological action of mannooligosaccharide, it is necessary to continuously take its effective amount, and it is advantageous to make it in the form of a beverage as a means to achieve it easily. However, beverages containing manno-oligosaccharides have a strong acidity and tend to be an obstacle to continuous consumption. Therefore, development of the drink which is easy to drink in which the acidity of mango-oligosaccharide was reduced is calculated | required.
Therefore, the subject of this invention is providing the drink by which the acidity of mango oligosaccharide was reduced.

本発明者は、マンノオリゴ糖の酸味が低減された飲料を開発すべく検討を行った。その結果、マンノオリゴ糖を含有する飲料に炭酸ガスを導入すると、マンノオリゴ糖の酸味がある程度緩和されることが分かった。本発明者は、更に詳細に検討したところ、炭酸ガスに麦芽エキスを組み合わせ、pHを特定範囲内に制御することで、マンノオリゴ糖の酸味が更に低減され、かつ炭酸感の豊かな酸性飲料が得られることを見出した。   The present inventor has studied to develop a beverage in which the sour taste of manno-oligosaccharide is reduced. As a result, it was found that when carbon dioxide gas was introduced into a beverage containing mannooligosaccharide, the acidity of mannooligosaccharide was alleviated to some extent. The present inventor has examined in more detail, and by combining malt extract with carbon dioxide gas and controlling the pH within a specific range, an acidic beverage having a rich carbonic feeling with a reduced acidity of manno-oligosaccharide can be obtained. I found out that

すなわち、本発明は、次の成分(A)〜(C);
(A)マンノオリゴ糖 0.4〜2質量%、
(B)麦芽エキス 固形分換算で0.1〜4.3質量%、及び
(C)炭酸ガス
を含有し、pH3〜4である、酸性飲料を提供するものである。
That is, the present invention includes the following components (A) to (C);
(A) Manno-oligosaccharide 0.4-2 mass%,
(B) Malt extract It provides 0.1 to 4.3 mass% in terms of solid content, and (C) carbonic acid gas, and provides an acidic beverage having a pH of 3 to 4.

本発明によれば、マンノオリゴ糖の酸味が低減され、かつ炭酸感の豊かな酸性飲料を提供することができる。したがって、本発明の酸性飲料は、飲みやすく、長期に亘ってマンノオリゴ糖を継続して摂取するのに適しており、種々の生理効果を十分に期待することができる。   ADVANTAGE OF THE INVENTION According to this invention, the acidity of manno-oligosaccharide can be reduced, and an acidic drink with a rich carbonation feeling can be provided. Therefore, the acidic beverage of the present invention is easy to drink and is suitable for continuously ingesting manno-oligosaccharides over a long period of time, and various physiological effects can be sufficiently expected.

本発明の酸性飲料は、(A)マンノオリゴ糖を含有する。ここで、本明細書において「(A)マンノオリゴ糖」とは、マンノースを構成糖とするオリゴ糖を意味し、構成糖の数が異なる種々のオリゴ糖を含む混合物であってもよい。
(A)マンノオリゴ糖としては、D−マンノースがβ−1,4結合してできたβ−1,4−マンノオリゴ糖が好ましく、分子中のマンノースの単位数は2〜10が好ましく、2〜6が更に好ましい。
The acidic beverage of the present invention contains (A) a manno-oligosaccharide. As used herein, “(A) mannooligosaccharide” means an oligosaccharide having mannose as a constituent sugar, and may be a mixture containing various oligosaccharides having different numbers of constituent sugars.
(A) The mannooligosaccharide is preferably a β-1,4-mannooligosaccharide formed by bonding D-mannose to β-1,4. The number of mannose units in the molecule is preferably 2 to 10, and 2 to 6 Is more preferable.

このような(A)マンノオリゴ糖は、例えば、こんにゃく等に含まれるグルコマンナンやグァーガム等に含まれるガラクトマンナンを酸分解や酵素分解する方法、コプラミールから酵素分解によりマンノビオースを製造する方法、あるいはコーヒー豆又はコーヒー抽出残渣等を加水分解する方法等の公知の方法により得ることができる。具体的な操作は、例えば、特開昭63−49093号公報、特開平11−18793号公報、特開平2−200147号公報等の記載を参照することができる。中でも、コーヒー豆又はコーヒー抽出残渣から得られるものが好ましい。なお、コーヒー豆の種類や産地に特に制限はなく、アラビカ種、ロブスタ種、リベリカ種等いずれの種類のコーヒー豆でもよく、更にブラジル、コロンビア産等いずれの産地のコーヒー豆も使用することができる。コーヒー豆は、単独で使用しても、2種以上をブレンドして使用してもよい。また、コーヒー豆の焙煎度は特に限定されず、極浅炒り、浅炒り、中炒り、深炒りに焙煎したコーヒー豆を使用することが可能であり、これら焙煎コーヒー豆を、一般的な粉砕機、ロールミルなどを用いて種々の形状のものに粉砕した焙煎コーヒー豆を用いることもできる。また、コーヒー抽出残渣としては、通常のコーヒー飲料又はインスタントコーヒー製造工程において、コーヒー抽出液を抽出した後のコーヒー抽出粕であれば、いかなる製法のコーヒー抽出残渣であっても使用することができる。
また、(A)マンノオリゴ糖は、市販品を使用してもよく、例えば、マンノース単位数が2〜10のマンノオリゴ糖として、コーヒーオリゴ糖(味の素ゼネラルフーズ社製)を挙げることができる。
Such (A) manno-oligosaccharide is, for example, a method of acid-decomposing or enzymatically decomposing galactomannan contained in konjac and the like, a method of producing mannobiose by enzymatic decomposition from copra meal, or coffee beans Or it can obtain by well-known methods, such as the method of hydrolyzing a coffee extraction residue etc. For specific operations, for example, descriptions in JP-A-63-49093, JP-A-11-18793, JP-A-2-200147 and the like can be referred to. Especially, what is obtained from a coffee bean or a coffee extraction residue is preferable. In addition, there is no restriction | limiting in particular in the kind and production place of a coffee bean, Any kind of coffee beans, such as an arabica kind, a Robusta kind, and a Riberica kind, may be used, and also coffee beans of any origin, such as Brazil and Colombia, can be used. . The coffee beans may be used alone or in combination of two or more. In addition, the roasting degree of coffee beans is not particularly limited, and it is possible to use coffee beans roasted for shallow roasting, shallow roasting, medium roasting, and deep roasting. It is also possible to use roasted coffee beans that have been pulverized into various shapes using a simple pulverizer or roll mill. Moreover, as a coffee extraction residue, any coffee extraction residue of any manufacturing method can be used as long as it is a coffee extraction cake after extracting a coffee extract in a normal coffee beverage or instant coffee manufacturing process.
Moreover, (A) Manno-oligosaccharide may use a commercial item, for example, coffee oligosaccharide (made by Ajinomoto General Foods Co., Ltd.) can be mentioned as a manno-oligosaccharide with 2-10 mannose units.

本発明の酸性飲料中の(A)マンノオリゴ糖の含有量は、0.4〜2質量%であるが、より一層の酸味の低減の観点から、1.7質量%以下が好ましく、1.4質量%以下がより好ましく、1.1質量%以下が更に好ましく、また生理効果の観点から、0.5質量%以上が好ましく、0.6質量%以上がより好ましく、0.7質量%以上が更に好ましい。(A)マンノオリゴ糖の含有量の範囲としては、本発明の酸性飲料中に0.5〜1.7質量%が好ましく、0.6〜1.4質量%がより好ましく、0.7〜1.1質量%が更に好ましい。
飲料中のマンノオリゴ糖の含有量は、例えば、パルスドアンペロメトリー検出を行う高速液体クロマトグラフィー(HPLC)を用いた分析法により測定することができる。
The content of the (A) mannooligosaccharide in the acidic beverage of the present invention is 0.4 to 2% by mass, but is preferably 1.7% by mass or less from the viewpoint of further reducing acidity, and 1.4 % By mass or less is more preferable, 1.1% by mass or less is more preferable, and from the viewpoint of physiological effects, 0.5% by mass or more is preferable, 0.6% by mass or more is more preferable, and 0.7% by mass or more is preferable. Further preferred. (A) As a range of content of manno-oligosaccharide, 0.5-1.7 mass% is preferable in the acidic drink of this invention, 0.6-1.4 mass% is more preferable, 0.7-1 More preferably, 1% by mass.
The content of the manno-oligosaccharide in the beverage can be measured, for example, by an analysis method using high performance liquid chromatography (HPLC) that performs pulsed amperometric detection.

本発明の酸性飲料は、マンノオリゴ糖の酸味を低減するために、(B)麦芽エキスを含有する。ここで、「(B)麦芽エキス」とは、麦芽を水若しくはエタノールなどの水溶性有機溶媒、又は水と水溶性有機溶媒の混合溶媒にて抽出して得られた液体をいう。また、「麦芽」とは、大麦その他の穀類の種子に、水分を加え適温に設定して発芽させたものであり、「モルト」ともいう(日本語大辞典 発行所株式会社講談社、発行年1989年)。穀類としては、二条大麦、六条大麦、小麦、オート麦、ライ麦、米、トウモロコシ、大豆等を使用することができる。発芽方法としては、例えば、Kasten発芽法、Wanderhaufen発芽法、Flexibox発芽法、Tower発芽法、Trommel発芽法等が挙げられ、適宜選択することができる。   The acidic beverage of the present invention contains (B) malt extract in order to reduce the sourness of mannooligosaccharide. Here, “(B) malt extract” refers to a liquid obtained by extracting malt with water or a water-soluble organic solvent such as ethanol, or a mixed solvent of water and a water-soluble organic solvent. “Mort” is the seeds of barley and other cereals that have been sprouted with water added at an appropriate temperature, and are also referred to as “Mort” (Kodansha Co., Ltd. Year). As cereals, Nijo barley, Rojo barley, wheat, oats, rye, rice, corn, soybeans and the like can be used. Examples of the germination method include a Kasten germination method, a Wanderhaufen germination method, a Flexibox germination method, a Tower germination method, and a Tromel germination method, and can be appropriately selected.

麦芽エキスの具体例としては、例えば、次の(i)〜(iv)を挙げることができる。
(i)麦芽に温水を加え、麦芽の内在酵素(主としてα−アミラーゼ、β−アミラーゼ、グルコアミラーゼ、プロテアーゼ等)の反応により、麦芽中に存在するデンプンを糖に分解し(糖化)、タンパク質をアミノ酸に分解した後に、圧搾又は抽出して得られるもの。これは「麦汁」ともいう。
(ii)麦芽から得られた抽出液中又は抽出前の麦芽中の酵素を失活させた後に、別途1種又は2種以上の酵素を添加することにより、デンプンやタンパク質を選択的に分解したり、糖やアミノ酸の含有量を適度にコントロールしたもの。
(iii)麦芽の内在酵素を失活させた後、酵素反応を行わずに、圧搾又は抽出して得られたもの。
(iv)麦芽の内在酵素を失活させずに、かつ酵素反応を行わずに、圧搾又は抽出して得られたもの。
また、(B)麦芽エキスとして、酵素を作用させた後に酵母を接種して発酵させたものを使用することも可能であるが、アルコール低含有飲料を簡便に製造する観点から、非発酵のものが好ましい。
Specific examples of the malt extract include the following (i) to (iv).
(I) Warm water is added to the malt, and the starch present in the malt is decomposed into sugar (saccharification) by the reaction of malt endogenous enzymes (mainly α-amylase, β-amylase, glucoamylase, protease, etc.) What is obtained by pressing or extracting after decomposing into amino acids. This is also called “wort”.
(Ii) After inactivating the enzyme in the extract obtained from malt or in the malt before extraction, starch or protein is selectively decomposed by adding one or more enzymes separately. Or with moderately controlled sugar and amino acid content.
(Iii) What was obtained by squeezing or extracting without deactivating an enzyme reaction after inactivating the endogenous enzyme of malt.
(Iv) What was obtained by squeezing or extracting without deactivating the endogenous enzyme of the malt and without carrying out the enzyme reaction.
In addition, as (B) malt extract, it is possible to use a fermented yeast inoculated with an enzyme, but it is non-fermented from the viewpoint of easily producing a low alcohol-containing beverage. Is preferred.

本発明においては、(B)麦芽エキスとして、濃縮して液糖状にしたものを使用することもできる。麦芽エキスは、酸味の低減の観点から、固形分中の脂質含有量が0.1質量%以上が好ましく、0.2質量%以上がより好ましく、0.3質量%以上が更に好ましく、0.4質量%以上が更に好ましく、そして、0.85質量%以下が好ましく、0.83質量%以下がより好ましく、0.81質量%以下が更に好ましく、0.8質量%以下が更に好ましく、0.65質量%以下が更に好ましく、0.6質量%以下が殊更に好ましい。かかる固形分中の脂質含有量の範囲としては、0.1〜0.85質量%が好ましく、0.2〜0.83質量%がより好ましく、0.3〜0.81質量%が更に好ましく、0.4〜0.8質量%が更に好ましく、0.4〜0.65質量%が更に好ましく、0.4〜0.6質量%が殊更に好ましい。ここで、本明細書において「固形分」とは、試料を105℃の電気恒温乾燥機で3時間乾燥して揮発成分を除いた残分をいう。   In the present invention, (B) malt extract that has been concentrated to a liquid sugar can also be used. The malt extract has a lipid content in the solid content of preferably 0.1% by mass or more, more preferably 0.2% by mass or more, still more preferably 0.3% by mass or more, from the viewpoint of reducing acidity. More preferably 4% by mass or more, 0.85% by mass or less, more preferably 0.83% by mass or less, still more preferably 0.81% by mass or less, still more preferably 0.8% by mass or less, 0 It is more preferably not more than .65% by mass, particularly preferably not more than 0.6% by mass. The range of the lipid content in the solid content is preferably 0.1 to 0.85% by mass, more preferably 0.2 to 0.83% by mass, and still more preferably 0.3 to 0.81% by mass. 0.4 to 0.8 mass% is more preferable, 0.4 to 0.65 mass% is further preferable, and 0.4 to 0.6 mass% is even more preferable. As used herein, “solid content” refers to a residue obtained by drying a sample for 3 hours with an electric constant temperature dryer at 105 ° C. to remove volatile components.

本発明の酸性飲料中の(B)麦芽エキスの含有量は、固形分換算で0.1〜4.3質量%であるが、より一層の酸味の低減の観点から、0.15質量%以上が好ましく、0.2質量%以上がより好ましく、0.3質量%以上が更に好ましく、0.4質量%以上が更に好ましく、またpHを上昇させず規定の範囲内とする観点、又は酸味料若しくは調整剤の配合量を低減できる観点から、4質量%以下が好ましく、3.5質量%以下がより好ましく、3質量%以下が更に好ましく、2.8質量%以下が更に好ましい。(B)麦芽エキスの含有量の範囲としては、本発明の酸性飲料中に、固形分換算で0.15〜4質量%が好ましく、0.2〜3.5質量%がより好ましく、0.3〜3質量%が更に好ましく、0.4〜2.8質量%が更に好ましい。   The content of the (B) malt extract in the acidic beverage of the present invention is 0.1 to 4.3% by mass in terms of solid content, but from the viewpoint of further reducing acidity, it is 0.15% by mass or more. Preferably, 0.2% by mass or more is more preferable, 0.3% by mass or more is more preferable, 0.4% by mass or more is more preferable, and the viewpoint of keeping the pH within a specified range without increasing the pH, or acidulant Or from a viewpoint which can reduce the compounding quantity of a regulator, 4 mass% or less is preferable, 3.5 mass% or less is more preferable, 3 mass% or less is further more preferable, and 2.8 mass% or less is still more preferable. (B) As content range of malt extract, 0.15-4 mass% is preferable in conversion of solid content in the acidic drink of this invention, 0.2-3.5 mass% is more preferable, and 0.2. It is more preferably 3 to 3% by mass, and further preferably 0.4 to 2.8% by mass.

本発明の酸性飲料中の(A)マンノオリゴ糖と(B)麦芽エキス中の固形分との質量比〔(B)/(A)〕は、より一層の酸味の低減の観点から、0.1以上が好ましく、0.15以上がより好ましく、0.3以上が更に好ましく、0.7以上が殊更に好ましく、また酸味と炭酸感とのバランスの観点から、4.3以下が好ましく、4以下がより好ましく、3.5以下が更に好ましく、3以下が更に好ましい。かかる質量比〔(B)/(A)〕の範囲としては、0.1〜4.3が好ましく、0.15〜4がより好ましく、0.3〜3.5が更に好ましく、0.7〜3が更に好ましい。   The mass ratio [(B) / (A)] of the (A) mannooligosaccharide in the acidic beverage of the present invention and the solid content in the (B) malt extract is 0.1 from the viewpoint of further reducing the acidity. The above is preferable, 0.15 or more is more preferable, 0.3 or more is more preferable, 0.7 or more is more preferable, and 4.3 or less is preferable and 4 or less is preferable from the viewpoint of the balance between acidity and carbonic acid feeling. Is more preferably 3.5 or less, further preferably 3 or less. The range of the mass ratio [(B) / (A)] is preferably 0.1 to 4.3, more preferably 0.15 to 4, still more preferably 0.3 to 3.5, and 0.7 ~ 3 is more preferred.

また、本発明の酸性飲料は、(C)炭酸ガスを含有する。圧入する(C)炭酸ガスは、炭酸感の付与の観点から、ガス容量比で1以上が好ましく、1.5以上がより好ましく、1.8以上が更に好ましく、そして、3以下が好ましく、2.7以下がより好ましく、2.5以下が更に好ましい。(C)炭酸ガスの含有量の範囲は、ガス容量比で1〜3が好ましく、1.5〜2.7がより好ましく、1.8〜2.5が更に好ましい。ここで、本明細書において「ガス容量比(ガスボリューム)」とは、20℃における酸性飲料の容量に対する溶解している炭酸ガス容量の比率をいう。   Moreover, the acidic drink of this invention contains (C) carbon dioxide gas. The (C) carbon dioxide gas to be injected is preferably 1 or more in terms of gas volume ratio, more preferably 1.5 or more, still more preferably 1.8 or more, and preferably 3 or less, from the viewpoint of imparting carbonic acid feeling. .7 or less is more preferable, and 2.5 or less is more preferable. (C) The range of carbon dioxide content is preferably 1 to 3, more preferably 1.5 to 2.7, and still more preferably 1.8 to 2.5 in terms of gas volume ratio. Here, “gas volume ratio (gas volume)” in this specification refers to the ratio of the volume of dissolved carbon dioxide gas to the volume of acidic beverage at 20 ° C.

本発明の酸性飲料は、アルコール飲料としても、非アルコール飲料としてもよいが、非アルコール飲料が好ましい。ここで、本明細書において「非アルコール飲料」とは、アルコール含有量が0質量%の飲料のみならず、適用される法規(日本にあっては酒税法)に定められた酒類に該当しないアルコール含有量も包含する概念である。
また、非アルコール飲料の場合、ビール様の風味を有するビアテイスト飲料が好ましい。非アルコール飲料中のアルコール含有量は、1質量%未満が好ましく、0.7質量%未満がより好ましく、0.5質量%未満が更に好ましく、0.3質量%未満が更に好ましく、0質量%であってもよい。一方、アルコール飲料の場合、アルコール含有量は1質量%以上において、嗜好性に合わせて適宜選択可能である。なお、「アルコール含有量が0質量%」とは、後掲の実施例に記載の「アルコールの分析」において、アルコールの含有量が検出限界以下である場合も包含する概念である。
The acidic beverage of the present invention may be an alcoholic beverage or a non-alcoholic beverage, but a non-alcoholic beverage is preferred. As used herein, “non-alcoholic beverage” refers not only to beverages with an alcohol content of 0% by mass, but also to alcohols that do not correspond to alcoholic beverages stipulated by applicable regulations (the liquor tax law in Japan). It is a concept that includes the content.
In the case of a non-alcoholic beverage, a beer-taste beverage having a beer-like flavor is preferable. The alcohol content in the non-alcoholic beverage is preferably less than 1% by mass, more preferably less than 0.7% by mass, still more preferably less than 0.5% by mass, still more preferably less than 0.3% by mass, and 0% by mass. It may be. On the other hand, in the case of an alcoholic beverage, the alcohol content can be appropriately selected according to palatability at 1% by mass or more. The “alcohol content of 0% by mass” is a concept encompassing the case where the alcohol content is below the detection limit in the “alcohol analysis” described in the examples below.

本発明の酸性飲料のpH(20℃)は3〜4であるが、酸味感と炭酸感のバランスの観点から、3.2以上が好ましく、3.3以上が更に好ましく、そして、3.9以下が好ましく、3.8以下が更に好ましい。pHの範囲としては、3.2〜3.9が好ましく、3.3〜3.8が更に好ましい。   The acidic beverage of the present invention has a pH (20 ° C.) of 3 to 4, but is preferably 3.2 or more, more preferably 3.3 or more, and 3.9 from the viewpoint of the balance between sourness and carbonated feeling. The following is preferable, and 3.8 or less is more preferable. The pH range is preferably 3.2 to 3.9, more preferably 3.3 to 3.8.

本発明の酸性飲料のpHを上記範囲内に調整するために、pH調整剤を含有することができる。pH調整剤としては、例えば、アスコルビン酸、クエン酸、グルコン酸、コハク酸、酒石酸、乳酸、フマル酸、リンゴ酸、アジピン酸等の有機酸、リン酸等の無機酸及びそれらの塩類から選ばれる1種又は2種以上を使用することができる。   In order to adjust the pH of the acidic beverage of the present invention within the above range, a pH adjuster can be contained. The pH adjuster is selected from, for example, ascorbic acid, citric acid, gluconic acid, succinic acid, tartaric acid, organic acids such as lactic acid, fumaric acid, malic acid and adipic acid, inorganic acids such as phosphoric acid, and salts thereof. 1 type (s) or 2 or more types can be used.

本発明の酸性飲料は、更に香料、ビタミン、ミネラル、酸化防止剤、各種エステル類、色素類、乳化剤、保存料、調味料、甘味料、果汁エキス、野菜エキス、花蜜エキス、品質安定剤等の添加剤を1種又は2種以上を組み合わせて含有させることができる。これら添加剤の含有量は、本発明の目的を損なわない範囲内で適宜設定することができる。香料として、例えば、モルトフレーバー、ホップフレーバー、ビールフレーバー、アルコールフレーバー及びカラメルフレーバーから選ばれる少なくとも1種を配合すると、ビアテイストを高めることができる。   The acidic beverage of the present invention further includes flavorings, vitamins, minerals, antioxidants, various esters, pigments, emulsifiers, preservatives, seasonings, sweeteners, fruit juice extracts, vegetable extracts, nectar extracts, quality stabilizers, etc. One or more additives can be contained in combination. The content of these additives can be appropriately set within a range that does not impair the object of the present invention. For example, when at least one selected from malt flavor, hop flavor, beer flavor, alcohol flavor and caramel flavor is blended as a fragrance, the beer taste can be enhanced.

また、本発明の酸性飲料は、ポリエチレンテレフタレートを主成分とする成形容器(いわゆるPETボトル)、金属缶、金属箔やプラスチックフィルムと複合された紙容器、瓶等の通常の包装容器に充填し、容器詰飲料として提供することができる。その場合、例えば、金属缶のような容器に充填後、加熱殺菌できる場合にあっては適用されるべき法規(日本にあっては食品衛生法)に定められた殺菌条件で製造できる。PETボトル、紙容器のようにレトルト殺菌できないものについては、あらかじめ上記と同等の殺菌条件、例えばプレート式熱交換器などで高温短時間殺菌後、一定の温度まで冷却して容器に充填する等の方法が採用できる。また無菌下で、充填された容器に別の成分を配合して充填してもよい。   In addition, the acidic beverage of the present invention is filled in a normal packaging container such as a molded container (so-called PET bottle) mainly composed of polyethylene terephthalate, a metal can, a paper container combined with a metal foil or a plastic film, a bottle, It can be provided as a packaged beverage. In this case, for example, when the container can be heat sterilized after being filled in a container such as a metal can, it can be manufactured under the sterilization conditions stipulated in the applicable regulations (the Food Sanitation Law in Japan). For PET bottles and paper containers that cannot be sterilized by retort, sterilize under the same conditions as above, for example, after sterilizing at high temperature and short time with a plate heat exchanger, etc. The method can be adopted. Moreover, you may mix | blend another component with the filled container under aseptic conditions.

以上、本発明の酸性飲料について説明したが、マンノオリゴ糖由来の酸味の抑制方法においても、上記と同様の構成を採用することができる。     As mentioned above, although the acidic drink of this invention was demonstrated, also in the suppression method of the sour taste derived from a manno-oligosaccharide, the structure similar to the above is employable.

前述の実施形態に関し、本発明は以下の酸性飲料、マンノオリゴ糖由来の酸味の抑制方法を開示する。
<1>
次の成分(A)〜(C);
(A)マンノオリゴ糖 0.4〜2質量%、
(B)麦芽エキス 固形分換算で0.1〜4.3質量%、及び
(C)炭酸ガス
を含有し、pH3〜4である、酸性飲料。
Regarding the above-described embodiment, the present invention discloses the following acidic beverage and method for suppressing acidity derived from manno-oligosaccharides.
<1>
The following components (A) to (C);
(A) Manno-oligosaccharide 0.4-2 mass%,
(B) Malt extract An acidic beverage containing 0.1 to 4.3% by mass in terms of solid content and (C) carbon dioxide and having a pH of 3 to 4.

マンノオリゴ糖を含有する酸性飲料のマンノオリゴ糖由来の酸味の抑制方法であって、(A)マンノオリゴ糖を0.4〜2質量%、(B)麦芽エキスを固形分換算で0.1〜4.3質量%、及び(C)炭酸ガスを配合し、pHを3〜4に調整する、マンノオリゴ糖由来の酸味の抑制方法。   It is a method for suppressing acidity derived from manno-oligosaccharide in an acidic beverage containing manno-oligosaccharide, wherein (A) manno-oligosaccharide is 0.4-2 mass%, and (B) malt extract is 0.1-4. A method for suppressing acidity derived from mannooligosaccharides, comprising 3% by mass and (C) carbon dioxide gas and adjusting the pH to 3 to 4.

<2>
(A)マンノオリゴ糖が、好ましくはβ−1,4−マンノオリゴ糖である、前記<1>記載の酸性飲料又は前記<2>記載のマンノオリゴ糖由来の酸味の抑制方法(以下、「酸性飲料又はマンノオリゴ糖由来の酸味の抑制方法」を「酸性飲料等」と称する)。
<3>
(A)マンノオリゴ糖は、マンノースの単位数が、好ましくは2〜10、更に好ましくは2〜6である、前記<1>又は<2>記載の酸性飲料等。
<4>
(A)マンノオリゴ糖が、好ましくはコーヒー豆又はコーヒー抽出残差から得られるものである、前記<1>〜<3>のいずれか一に記載の酸性飲料等。
<5>
(A)マンノオリゴ糖の含有量が、好ましくは1.7質量%以下、より好ましくは1.4質量%以下、更に好ましくは1.1質量%以下であって、好ましくは0.5質量%以上、より好ましくは0.6質量%以上、更に好ましくは0.7質量%以上である、前記<1>〜<4>のいずれか一に記載の酸性飲料等。
<6>
(A)マンノオリゴ糖の含有量が、好ましくは0.5〜1.7質量%、より好ましくは0.6〜1.4質量%、更に好ましくは0.7〜1.1質量%である、前記<1>〜<5>のいずれか一に記載の酸性飲料等。
<7>
(B)麦芽エキスが、好ましくは下記の(i)〜(iv)のいすれかである、前記<1>〜<6>のいずれか一に記載の酸性飲料等。
(i)麦芽に温水を加え、麦芽の内在酵素(主としてα−アミラーゼ、β−アミラーゼ、グルコアミラーゼ、プロテアーゼ等)の反応により、麦芽中に存在するデンプンを糖に分解し、タンパク質をアミノ酸に分解した後に、圧搾又は抽出して得られるもの。
(ii)麦芽から得られた抽出液中又は抽出前の麦芽中の酵素を失活させた後に、別途1種又は2種以上の酵素を添加することにより、デンプンやタンパク質を選択的に分解するか、又は糖やアミノ酸の含有量をコントロールしたもの。
(iii)麦芽の内在酵素を失活させた後、酵素反応を行わずに、圧搾又は抽出して得られたもの。
(iv)麦芽の内在酵素を失活させずに、かつ酵素反応を行わずに、圧搾又は抽出して得られたもの。
<2>
(A) The manno-oligosaccharide is preferably β-1,4-mannooligosaccharide, the acidic beverage according to <1> or the method for suppressing acidity derived from the manno-oligosaccharide according to <2> (hereinafter referred to as “acidic beverage or The “mano-oligosaccharide-derived acidity control method” is referred to as “acidic beverages”).
<3>
(A) The mannooligosaccharide is preferably an acidic beverage according to the above <1> or <2>, wherein the number of units of mannose is preferably 2 to 10, more preferably 2 to 6.
<4>
(A) The acidic beverage or the like according to any one of <1> to <3>, wherein the mannooligosaccharide is preferably obtained from coffee beans or coffee extraction residuals.
<5>
(A) The content of mannooligosaccharide is preferably 1.7% by mass or less, more preferably 1.4% by mass or less, still more preferably 1.1% by mass or less, and preferably 0.5% by mass or more. The acidic beverage according to any one of <1> to <4>, more preferably 0.6% by mass or more, and still more preferably 0.7% by mass or more.
<6>
(A) The content of mannooligosaccharide is preferably 0.5 to 1.7% by mass, more preferably 0.6 to 1.4% by mass, and still more preferably 0.7 to 1.1% by mass. Acidic drinks as described in any one of said <1>-<5>.
<7>
(B) The acidic beverage or the like according to any one of <1> to <6>, wherein the malt extract is preferably any of the following (i) to (iv).
(I) Add warm water to the malt, decompose the starch present in the malt into sugars and decompose proteins into amino acids by the reaction of malt endogenous enzymes (mainly α-amylase, β-amylase, glucoamylase, protease, etc.) After being pressed or extracted.
(Ii) After inactivating the enzyme in the extract obtained from the malt or in the malt before extraction, the starch and protein are selectively decomposed by adding one or more enzymes separately. Or a controlled content of sugar or amino acid.
(Iii) What was obtained by squeezing or extracting without deactivating an enzyme reaction after inactivating the endogenous enzyme of malt.
(Iv) What was obtained by squeezing or extracting without deactivating the endogenous enzyme of the malt and without carrying out the enzyme reaction.

<8>
(B)麦芽エキスが、好ましくは非発酵のものである、前記<1>〜<7>のいずれか一に記載の酸性飲料等。
<9>
(B)麦芽エキスは、固形分中の脂質含有量が、好ましくは0.1質量%以上、より好ましくは0.2質量%以上、更に好ましくは0.3質量%以上、更に好ましくは0.4質量%以上であって、好ましくは0.85質量%以下、より好ましくは0.83質量%以下、更に好ましくは0.81質量%以下、更に好ましくは0.8質量%以下、更に好ましくは0.65質量%以下、更に好ましくは0.6質量%以下である、前記<1>〜<8>のいずれか一に記載の酸性飲料等。
<10>
(B)麦芽エキスは、固形分中の脂質含有量が、好ましくは0.1〜0.85質量%、より好ましくは0.2〜0.83質量%、更に好ましくは0.3〜0.81質量%、更に好ましくは0.4〜0.8質量%、更に好ましくは0.4〜0.65質量%、更に好ましくは0.4〜0.6質量%である、前記<1>〜<9>のいずれか一に記載の酸性飲料等。
<11>
(B)麦芽エキスの含有量が、固形分換算で、好ましくは0.15質量%以上、より好ましくは0.2質量%以上、更に好ましくは0.3質量%以上、更に好ましくは0.4質量%以上であって、好ましくは4質量%以下、より好ましくは3.5質量%以下、更に好ましくは3質量%以下、更に好ましくは2.8質量%以下である、前記<1>〜<10>のいずれか一に記載の酸性飲料等。
<12>
(B)麦芽エキスの含有量が、固形分換算で、好ましくは0.15〜4質量%、より好ましくは0.2〜3.5質量%、更に好ましくは0.3〜3質量%、更に好ましくは0.4〜2.8質量%である、前記<1>〜<11>のいずれか一に記載の酸性飲料等。
<13>
(C)炭酸ガスの含有量が、ガス容量比で、好ましくは1以上、より好ましくは1.5以上、更に好ましくは1.8以上であって、好ましくは3以下、より好ましくは2.7以下、更に好ましくは2.5以下である、前記<1>〜<12>のいずれか一に記載の酸性飲料等。
<8>
(B) The acidic beverage according to any one of <1> to <7>, wherein the malt extract is preferably non-fermented.
<9>
(B) The malt extract has a lipid content in the solid content of preferably 0.1% by mass or more, more preferably 0.2% by mass or more, still more preferably 0.3% by mass or more, and still more preferably 0.00%. 4 mass% or more, preferably 0.85 mass% or less, more preferably 0.83 mass% or less, still more preferably 0.81 mass% or less, still more preferably 0.8 mass% or less, and still more preferably. The acidic beverage or the like according to any one of <1> to <8>, which is 0.65% by mass or less, more preferably 0.6% by mass or less.
<10>
(B) The malt extract preferably has a lipid content in the solid content of 0.1 to 0.85 mass%, more preferably 0.2 to 0.83 mass%, and still more preferably 0.3 to 0.00. <1> to 81% by mass, more preferably 0.4 to 0.8% by mass, further preferably 0.4 to 0.65% by mass, and still more preferably 0.4 to 0.6% by mass. <9> Acidic drinks as described in any one.
<11>
The content of (B) malt extract is preferably 0.15% by mass or more, more preferably 0.2% by mass or more, still more preferably 0.3% by mass or more, and further preferably 0.4% in terms of solid content. <1> to <<%, preferably 4% by mass or less, more preferably 3.5% by mass or less, further preferably 3% by mass or less, and further preferably 2.8% by mass or less. 10> The acidic drink according to any one of 10>.
<12>
(B) The content of the malt extract is preferably 0.15 to 4% by mass, more preferably 0.2 to 3.5% by mass, still more preferably 0.3 to 3% by mass, in terms of solid content. The acidic beverage or the like according to any one of <1> to <11>, preferably 0.4 to 2.8% by mass.
<13>
(C) The content of carbon dioxide gas is preferably 1 or more, more preferably 1.5 or more, still more preferably 1.8 or more, preferably 3 or less, more preferably 2.7, in terms of gas volume ratio. The acidic beverage or the like according to any one of <1> to <12>, further preferably 2.5 or less.

<14>
(C)炭酸ガスの含有量が、ガス容量比で、好ましくは1〜3、より好ましくは1.5〜2.7、更に好ましくは1.8〜2.5である、前記<1>〜<13>のいずれか一に記載の酸性飲料等。
<15>
当該酸性飲料が、好ましくはアルコール飲料又は非アルコール飲料である、前記<1>〜<14>のいずれか一に記載の酸性飲料等。
<16>
当該酸性飲料が、好ましくはビアテイスト飲料である、前記<1>〜<15>のいずれか一に記載の酸性飲料等。
<17>
当該酸性飲料が非アルコール飲料の場合、非アルコール飲料中のアルコール含有量が、好ましくは1質量%未満、より好ましくは0.7質量%未満、更に好ましくは0.5質量%未満、更に好ましくは0.3質量%未満、更に好ましくは0質量%である、前記<15>又は<16>記載の酸性飲料等。
<18>
当該酸性飲料が非アルコール飲料の場合、非アルコール飲料中のアルコール含有量が、適用される法規(日本にあっては酒税法)に定められた酒類に該当しないアルコール含有量である、前記<15>又は<16>記載の酸性飲料等。
<19>
当該酸性飲料がアルコール飲料の場合、アルコール飲料中のアルコール含有量が、好ましくは1質量%以上である、前記<15>又は<16>記載の酸性飲料等。
<20>
pH(20℃)が、好ましくは3.2以上、更に好ましくは3.3以上であって、好ましくは3.9以下、更に好ましくは3.8以下である、前記<1>〜<19>のいずれか一に記載の酸性飲料等。
<21>
pH(20℃)が、好ましくは3.2〜3.9、更に好ましくは3.3〜3.8である、前記<1>〜<20>のいずれか一に記載の酸性飲料等。
<14>
(C) Carbon dioxide gas content is preferably 1 to 3, more preferably 1.5 to 2.7, and still more preferably 1.8 to 2.5, in terms of gas volume ratio. <13> The acidic beverage according to any one of the above.
<15>
The acidic beverage according to any one of <1> to <14>, wherein the acidic beverage is preferably an alcoholic beverage or a non-alcoholic beverage.
<16>
The acidic beverage according to any one of <1> to <15>, wherein the acidic beverage is preferably a beer-taste beverage.
<17>
When the acidic beverage is a non-alcoholic beverage, the alcohol content in the non-alcoholic beverage is preferably less than 1% by mass, more preferably less than 0.7% by mass, still more preferably less than 0.5% by mass, still more preferably. The acidic beverage or the like according to <15> or <16>, which is less than 0.3% by mass, more preferably 0% by mass.
<18>
When the acidic beverage is a non-alcoholic beverage, the alcohol content in the non-alcoholic beverage is an alcohol content that does not correspond to alcoholic beverages stipulated in applicable laws and regulations (the liquor tax law in Japan), <15 > Or <16> acidic beverage or the like.
<19>
When the acidic beverage is an alcoholic beverage, the alcoholic beverage according to <15> or <16> or the like, wherein the alcohol content in the alcoholic beverage is preferably 1% by mass or more.
<20>
<1> to <19>, wherein the pH (20 ° C.) is preferably 3.2 or more, more preferably 3.3 or more, preferably 3.9 or less, more preferably 3.8 or less. Acidic drinks as described in any one of these.
<21>
The acidic beverage according to any one of <1> to <20>, wherein pH (20 ° C.) is preferably 3.2 to 3.9, more preferably 3.3 to 3.8.

<22>
好ましくはpH調整剤を含有する、前記<1>〜<21>のいずれか一に記載の酸性飲料等。
<23>
pH調整剤が、好ましくは有機酸、無機酸及びそれらの塩から選ばれる1種又は2種以上である、前記<22>記載の酸性飲料等。
<24>
pH調整剤が、好ましくはアスコルビン酸、クエン酸、グルコン酸、コハク酸、酒石酸、乳酸、フマル酸、リンゴ酸、アジピン酸及びリン酸及びそれらの塩から選ばれる1種又は2種以上である、前記<22>又は<23>記載の酸性飲料等。
<25>
更に、好ましくは香料、ビタミン、ミネラル、酸化防止剤、各種エステル類、色素類、乳化剤、保存料、調味料、甘味料、果汁エキス、野菜エキス、花蜜エキス及び品質安定剤から選ばれる1種又は2種以上を含有する、前記<1>〜<24>のいずれか一に記載の酸性飲料等。
<26>
好ましくは容器詰酸性飲料である、前記<1>〜<25>のいずれか一に記載の酸性飲料等。
<27>
容器が、好ましくはPETボトル、金属缶、金属箔若しくはプラスチックフィルムと複合された紙容器、又は瓶である、前記<26>記載の酸性飲料等。
<28>
加熱殺菌されたものである、前記<1>〜<27>のいずれか一に記載の酸性飲料等。
<29>
(A)マンノオリゴ糖と(B)麦芽エキス中の固形分との質量比〔(B)/(A)〕が好ましくは0.1以上、より好ましくは0.15以上、更に好ましくは0.3以上、更に好ましくは0.7以上であって、好ましくは4.3以下、より好ましくは4以下、更に好ましくは3.5以下、更に好ましくは3以下である、前記<1>〜<28>のいずれか一に記載の酸性飲料。
<30>
(A)マンノオリゴ糖と(B)麦芽エキス中の固形分との質量比〔(B)/(A)〕が好ましくは0.1〜4.3、更に好ましくは0.15〜4、更に好ましくは0.3〜3.5、更に好ましくは0.7〜3である、前記<1>〜<29>のいずれか一に記載の酸性飲料。
<22>
The acidic beverage or the like according to any one of <1> to <21>, which preferably contains a pH adjuster.
<23>
The acidic beverage or the like according to the above <22>, wherein the pH adjuster is preferably one or more selected from organic acids, inorganic acids and salts thereof.
<24>
The pH adjuster is preferably one or more selected from ascorbic acid, citric acid, gluconic acid, succinic acid, tartaric acid, lactic acid, fumaric acid, malic acid, adipic acid and phosphoric acid and their salts. Acidic beverages according to the above <22> or <23>.
<25>
Furthermore, preferably one selected from flavors, vitamins, minerals, antioxidants, various esters, pigments, emulsifiers, preservatives, seasonings, sweeteners, fruit juice extracts, vegetable extracts, nectar extracts and quality stabilizers. Acidic drinks as described in any one of said <1>-<24> containing 2 or more types.
<26>
The acidic beverage according to any one of <1> to <25>, which is preferably a container-packed acidic beverage.
<27>
The acidic beverage according to the above <26>, wherein the container is preferably a PET bottle, a metal can, a paper container combined with a metal foil or a plastic film, or a bottle.
<28>
The acidic beverage or the like according to any one of <1> to <27>, which is heat-sterilized.
<29>
The mass ratio [(B) / (A)] of (A) mannooligosaccharide and (B) malt extract is preferably 0.1 or more, more preferably 0.15 or more, and still more preferably 0.3. More preferably, it is 0.7 or more, preferably 4.3 or less, more preferably 4 or less, further preferably 3.5 or less, and further preferably 3 or less, <1> to <28>. Acidic drink as described in any one of.
<30>
The mass ratio [(B) / (A)] of (A) mannooligosaccharide and (B) the solid content in the malt extract is preferably 0.1 to 4.3, more preferably 0.15 to 4, more preferably. Is 0.3 to 3.5, more preferably 0.7 to 3, the acidic beverage according to any one of <1> to <29>.

<31>
(A)マンノオリゴ糖と(B)麦芽エキスを、(A)マンノオリゴ糖と(B)麦芽エキス中の固形分との質量比〔(B)/(A)〕が好ましくは0.1以上、より好ましくは0.15以上、更に好ましくは0.3以上、更に好ましくは0.7以上であって、好ましくは4.3以下、より好ましくは4以下、更に好ましくは3.5以下、更に好ましくは3以下となるように配合する、前記<1>〜<28>のいずれか一に記載のマンノオリゴ糖由来の酸味の抑制方法。
<32>
(A)マンノオリゴ糖と(B)麦芽エキスを、(A)マンノオリゴ糖と(B)麦芽エキス中の固形分との質量比〔(B)/(A)〕が好ましくは0.1〜4.3、更に好ましくは0.15〜4、更に好ましくは0.3〜3.5、更に好ましくは0.7〜3となるように配合する、前記<1>〜<28>、<31>のいずれか一に記載のマンノオリゴ糖由来の酸味の抑制方法。
<31>
(A) Manno-oligosaccharide and (B) malt extract, (A) Manno-oligosaccharide and (B) The mass ratio of the solid content in the malt extract [(B) / (A)] is preferably 0.1 or more. Preferably it is 0.15 or more, more preferably 0.3 or more, still more preferably 0.7 or more, preferably 4.3 or less, more preferably 4 or less, still more preferably 3.5 or less, still more preferably The method for suppressing acidity derived from a manno-oligosaccharide according to any one of <1> to <28>, which is blended so as to be 3 or less.
<32>
The mass ratio [(B) / (A)] of (A) mannooligosaccharide and (B) malt extract to (A) mannooligosaccharide and (B) malt extract is preferably 0.1-4. 3, more preferably from 0.15 to 4, more preferably from 0.3 to 3.5, and even more preferably from 0.7 to 3, the above <1> to <28>, <31> The method for suppressing acidity derived from a manno-oligosaccharide according to any one of the above.

1.麦芽エキスの固形分量の分析
試料1gを秤量瓶に正確に量り取り、105℃の電気恒温乾燥機で3時間乾燥して揮発成分を取り除き、乾燥後の質量を量り、固形分量とした。
1. Analysis of solid content of malt extract 1 g of a sample was accurately weighed in a weighing bottle, dried for 3 hours with an electric constant temperature dryer at 105 ° C. to remove volatile components, and the mass after drying was measured to obtain the solid content.

2.麦芽エキスの脂質量の分析
脂質の分析は「ソックスレー抽出法」により日本食品分析センターにおいて定量した。
試料100gを採取し、珪藻土を加え、乾燥後、乳鉢ですりつぶし、円筒ろ紙に詰めた。次に、ジエチルエーテル溶媒で常温下、16時間の抽出を行った。次に、抽出液から溶媒を留去し、留去後の試料を105℃で1時間乾燥し、乾燥後の脂質の質量を量り、試料中の含有量を算出した。
2. Analysis of Lipid Content of Malt Extract Lipid analysis was quantified at the Japan Food Analysis Center by “Soxhlet extraction method”.
A sample of 100 g was collected, diatomaceous earth was added, dried, ground in a mortar, and packed into a cylindrical filter paper. Next, extraction was performed for 16 hours at room temperature with a diethyl ether solvent. Next, the solvent was distilled off from the extract, the sample after the distillation was dried at 105 ° C. for 1 hour, the mass of the dried lipid was measured, and the content in the sample was calculated.

3.炭酸ガスの分析
「最新・ソフトドリンクス(最新・ソフトドリンクス編集委員会、株式会社光琳、平成15年9月30日発行)」の第VI編 3−1−2ガス内圧力の検査に記載の方法を用いた
。具体的には、以下のとおりである。
1)測定前に製品を恒温槽にて20℃程度(18〜22℃)まで温め、液温を均一にした。
2)ガスボリュームを測定機にかけ、スニフト(スニフトバルブを開放し、大気圧までゲージを戻す)を行う。スニフト操作を行うことによりヘッドスペース中のエアーを抜いた。
3)次に激しく振動させゲージ圧が一定値を示したら、その値を読み、製品の温度を測定し、表(スニフト用ガスボリュームチャート)よりガスボリュームを求めた。
3. Analysis of carbon dioxide As described in Volume 3-3-1-2 Gas Pressure Inspection of "Latest Soft Drinks (Latest Soft Drinks Editorial Committee, Kohan Co., Ltd., issued on September 30, 2003)" The method of was used. Specifically, it is as follows.
1) Before the measurement, the product was warmed to about 20 ° C. (18-22 ° C.) in a thermostatic bath to make the liquid temperature uniform.
2) Apply the gas volume to the measuring instrument and perform snift (open the snift valve and return the gauge to atmospheric pressure). The air in the headspace was removed by performing a sniffing operation.
3) Next, vigorously vibrate and when the gauge pressure showed a constant value, the value was read, the temperature of the product was measured, and the gas volume was determined from the table (sniff gas volume chart).

4.アルコールの分析(エタノールの分析)
エタノールの分析は、次に示すガスクロマトグラフ法にしたがって行った。
分析機器は、GC-14B(島津製作所社製)を使用した。分析機器の装置構成は次の通りである。
・検出器 :FID
・カラム :Gaskuropack55、80〜100mesh、φ3.2mm×3.1mm
4). Analysis of alcohol (ethanol analysis)
The analysis of ethanol was performed according to the gas chromatographic method shown below.
GC-14B (manufactured by Shimadzu Corporation) was used as an analytical instrument. The apparatus configuration of the analytical instrument is as follows.
・ Detector: FID
・ Column: Gaskuropack55, 80-100mesh, φ3.2mm × 3.1mm

分析条件は次の通りである。
・温度 :試料注入口及び検出機250℃、カラム130℃
・ガス圧力:ヘリウム(キャリアガス)140kPa、水素 60kPa、空気 50kPa
・注入量 :2μL
The analysis conditions are as follows.
・ Temperature: Sample inlet and detector 250 ℃, column 130 ℃
・ Gas pressure: Helium (carrier gas) 140kPa, hydrogen 60kPa, air 50kPa
・ Injection volume: 2μL

以下の手順にて分析用試料を調製した。
検体5gを量りとり、これに水を加えて25mLに定容した。その溶液をディスクろ過し、試料溶液とした。調製した試料溶液をガスクロマトグラフ分析に供した。
A sample for analysis was prepared by the following procedure.
A sample (5 g) was weighed, and water was added thereto to make a constant volume of 25 mL. The solution was subjected to disk filtration to obtain a sample solution. The prepared sample solution was subjected to gas chromatographic analysis.

5.官能評価
各酸性飲料について、飲用試験を実施した。飲料試験は、4名の専門パネルが各酸性飲料の炭酸感、酸味感について下記の基準により評価し、その後協議により評点を決定した。
5. Sensory evaluation A drinking test was carried out for each acidic beverage. In the beverage test, four specialized panels evaluated the acidity and sourness of each acidic beverage according to the following criteria, and then determined the score by consultation.

「炭酸感」の評価基準
評点5:炭酸感がとても強い
4:炭酸感が強い
3:炭酸感がやや強い
2:炭酸感がやや弱い
1:炭酸感が弱い
Evaluation criteria for “carbonic acid” Score 5: Carbonic acid is very strong 4: Carbonic acid is strong 3: Carbonic acid is slightly strong 2: Carbonic acid is slightly weak 1: Carbonic feeling is weak

「酸味感」の評価基準
評点5:酸味がとてもマイルド
4:酸味がマイルド
3:酸味がややマイルド
2:酸味がややある
1:酸味がある
Evaluation criteria for “taste” Score 5: Very mild acidity 4: Mild acidity 3: Mild acidity 2: Some acidity 1: Some acidity

実施例1〜11及び比較例1〜6
表1に示すマンノオリゴ糖及び麦芽エキスをイオン交換水に混合溶解し50gにした後、pH調整剤で所定のpHに調整した。次に4℃に冷却した炭酸ガス容量比4.0の炭酸水で全量100g(炭酸ガスの容量比2.0)とし、スクリュー管に充填した。得られた容器詰酸性飲料の分析結果、官能評価の結果を表1に併せて示す。
Examples 1-11 and Comparative Examples 1-6
The manno-oligosaccharide and malt extract shown in Table 1 were mixed and dissolved in ion-exchanged water to 50 g, and then adjusted to a predetermined pH with a pH adjuster. Next, the total amount was adjusted to 100 g (capacity ratio of carbon dioxide gas: 2.0) with carbonated water having a carbon dioxide capacity ratio of 4.0, which was cooled to 4 ° C., and filled into a screw tube. The analysis results and sensory evaluation results of the obtained container-packed acidic beverage are also shown in Table 1.

Figure 0006110134
Figure 0006110134

表1から、一定量のマンノオリゴ糖と炭酸ガスとを含有するpH3〜4の酸性飲料に、麦芽エキスを一定量配合することで、マンノオリゴ糖由来の酸味が低減され、炭酸感の豊かな酸性飲料が得られることが明らかとなった。   From Table 1, acidic beverages with a rich sense of carbonic acid can be reduced in sourness derived from mannooligosaccharides by blending a certain amount of malt extract into acidic beverages of pH 3-4 containing a certain amount of mannooligosaccharides and carbon dioxide. It became clear that

Claims (9)

次の成分(A)〜(C);
(A)マンノオリゴ糖 0.4〜2質量%、
(B)麦芽エキス 固形分換算で0.1〜4.3質量%、及び
(C)炭酸ガス
を含有し、
(A)マンノオリゴ糖と(B)麦芽エキス中の固形分との質量比〔(B)/(A)〕が0.1〜3.5であり、
pH3〜4である、酸性飲料。
The following components (A) to (C);
(A) Manno-oligosaccharide 0.4-2 mass%,
(B) Malt extract 0.1 to 4.3% by mass in terms of solid content, and (C) carbon dioxide gas,
(A) Mass ratio [(B) / (A)] of manno-oligosaccharide and solid content in (B) malt extract is 0.1-3.5,
An acidic beverage having a pH of 3-4.
(A)マンノオリゴ糖がβ−1,4−マンノオリゴ糖である、請求項1記載の酸性飲料。 (A) mannooligosaccharides are beta-1,4 mannooligosaccharides, claim 1 Symbol placement of acidic beverages. (A)マンノオリゴ糖は、マンノースの単位数が2〜10である、請求項1又は2に記載の酸性飲料。 (A) Manno-oligosaccharide is the acidic drink of Claim 1 or 2 whose unit number of a mannose is 2-10. (A)マンノオリゴ糖がコーヒー豆又はコーヒー抽出残渣から得られるものである、請求項1〜のいずれか一項に記載の酸性飲料。 (A) mannooligosaccharides are obtained from coffee beans or coffee extraction residue, the acid beverage according to any one of claims 1-3. (B)麦芽エキスが非発酵のものである、請求項1〜のいずれか一項に記載の酸性飲料。 (B) The acidic beverage according to any one of claims 1 to 4 , wherein the malt extract is non-fermented. (B)麦芽エキスは、固形分中の脂質含有量が0.1〜0.85質量%である、請求項1〜のいずれか一項に記載の酸性飲料。 (B) The malt extract is an acidic beverage according to any one of claims 1 to 5 , wherein the lipid content in the solid content is 0.1 to 0.85 mass%. (C)炭酸ガスの含有量がガス容量比で1〜3である、請求項1〜のいずれか一項に記載の酸性飲料。 (C) The acidic drink according to any one of claims 1 to 6 , wherein the content of carbon dioxide gas is 1 to 3 in terms of gas volume ratio. ビアテイスト飲料である、請求項1〜のいずれか一項に記載の酸性飲料。 The acidic drink according to any one of claims 1 to 7 , which is a beer-taste drink. マンノオリゴ糖を含有する酸性飲料のマンノオリゴ糖由来の酸味の抑制方法であって、
(A)マンノオリゴ糖 0.4〜2質量%、
(B)麦芽エキス 固形分換算で0.1〜4.3質量%、及び
(C)炭酸ガスを
(A)マンノオリゴ糖に対する(B)麦芽エキスの固形分との質量比〔(B)/(A)〕が0.1〜3.5となるように配合し、pHを3〜4に調整する、マンノオリゴ糖由来の酸味の抑制方法。
A method for suppressing acidity derived from manno-oligosaccharides in acidic beverages containing manno-oligosaccharides,
(A) Manno- oligosaccharides 0 . 4-2% by mass,
(B) 0.1-4.3 wt% malt equi scan solid content conversion, and (C) carbon dioxide,
(A) It mix | blends so that mass ratio [(B) / (A)] with the solid content of (B) malt extract with respect to manno-oligosaccharide may be set to 0.1-3.5, and pH is adjusted to 3-4. The method of suppressing acidity derived from a manno-oligosaccharide.
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