JP6101851B1 - White sealant film and package comprising the same - Google Patents

Abstract

A white sealant film having excellent whiteness such as visibility and excellent impact resistance and a package including the same are provided. A white sealant film for packaging 10 having a laminated structure of at least three layers, the laminated structure comprising two surface layers 11 and 13 provided on both sides in the thickness direction, and these surface layers, respectively. 11 and 13, at least one intermediate layer 12 provided between the surface layers 11 and 13, the surface layers 11 and 13 include polyolefin as a resin component, and at least one layer of the intermediate layer 12 includes at least a plant-derived polyolefin as a resin component. It contains 50% by weight or more and contains titanium oxide particles as an additive component. [Selection] Figure 1

Description

  The present invention relates to a white sealant film and a package including the same.

In order to prevent the contents from being deteriorated by external light such as ultraviolet rays, a package provided with a light-shielding layer such as a white colored layer or a metal layer such as aluminum is used.
Patent Document 1 describes a laminated film for packaging in which a white colored layer is used for at least one layer of a multi-layer unstretched olefin sealant in order to protect the package contents and in particular to prevent oxidation of fats and oils.

In recent years, aliphatic polyesters such as polylactic acid, polyhydroxybutyric acid, polycaprolactone, and polybutylene succinate have been developed for the purpose of reducing the amount of petroleum resources used in packaging materials. Furthermore, plant-derived polyethylene (biomass polyethylene) is attracting attention because it is considered that it has the same quality as the raw material monomer, ethylene, only in that it is obtained from biomass compared to petroleum-derived polyethylene. .
Patent Document 2 proposes a sealant film using plant-derived polyethylene.

Japanese Patent No. 5145912 JP 2013-136589 A

  In white sealant films, white pigments such as titanium oxide particles are widely used as pigments for coloring polyolefin white. However, when a white pigment is added in order to improve the visibility, design, light shielding and hiding properties of the film, there is a problem that the affinity between the pigment particles and the resin is low, and the impact resistance of the sealant film is lowered.

  This invention is made | formed in view of the said situation, and makes it a subject to provide a white sealant film excellent in whiteness, such as visibility, and favorable impact resistance, and a package provided with the same.

The present invention is a white sealant film for packaging comprising a laminate structure of at least three layers, wherein the laminate structure is provided between two surface layers provided on both sides in the thickness direction, and between these surface layers. And at least one intermediate layer, wherein the surface layer includes polyolefin as a resin component, and at least one layer of the intermediate layer includes at least 50% by weight of a plant-derived polyolefin as a resin component, and an additive look-containing particles of titanium oxide, and an elastomer as a component, the melting point of the elastomer, to provide a white sealant film characterized by lower than the melting point of the polyolefin derived from the plant.

It is also possible to adopt a configuration in which the amount of titanium oxide added in a layer containing titanium oxide particles as an additive component in the intermediate layer is 10 to 40 parts by weight with respect to 100 parts by weight of the resin component.
It is also possible to employ a configuration in which either one of the two surface layers includes titanium oxide particles.
It is also possible to adopt a configuration in which the titanium oxide has a particle size of 0.1 to 0.3 μm.

It is also possible to adopt a configuration in which the plant-derived degree of the layer containing the plant-derived polyolefin and the titanium oxide particles in the intermediate layer is 50% or more.
Of the two surface layers, a configuration in which the petroleum-derived degree of the surface layer on the side where the white sealant film is bonded to the base material layer is 80% or more can be adopted.

It is also possible to employ a configuration in which the thickness of the intermediate layer is 30 to 70% with respect to the total thickness of the sealant film.
It is also possible to adopt a configuration in which the intermediate layer includes at least one white intermediate layer and a gray intermediate layer stacked next to the white intermediate layer.

  Moreover, this invention provides the package body by which the base material layer is laminated | stacked on either one of the said two surface layers of the said white sealant film via an adhesive agent.

  According to the present invention, in the intermediate layer, by providing a layer containing plant-derived polyolefin and titanium oxide particles, a white sealant film having excellent whiteness such as visibility and excellent impact resistance and the like. A package provided can be provided.

It is sectional drawing which illustrates the laminated structure of a white sealant film.

Hereinafter, the present invention will be described based on preferred embodiments.
In FIG. 1, the laminated structure of the white sealant film of this embodiment is typically shown. This laminated structure includes two surface layers 11 and 13 provided on both sides in the thickness direction, and at least one intermediate layer 12 provided between the surface layers 11 and 13, respectively. The intermediate layer 12 is composed of at least three layers.

The white sealant film 10 is a sealant film for packaging, and is colored white. Here, the white color is a color whose brightness is increased by including particles of titanium oxide (TiO ₂ ), and may have another color. The sealant film is, for example, a film used for sealing the package 20, and the normal package 20 is used by laminating the white sealant film 10 with another base material layer 21.

  Each layer (surface layers 11 and 13 and intermediate layer 12) constituting white sealant film 10 contains polyolefin as a resin component. The polyolefin may be a homopolymer of one olefin or a copolymer (copolymer) of two or more olefins. Examples of the olefin include unsaturated aliphatic hydrocarbons such as ethylene, propylene, 1-butene, 1-hexene, 1-octene, α-olefin, and cycloolefin. Specific examples of the polyolefin include polyethylene, polypropylene, ethylene-α-olefin copolymer, polycycloolefin, and cycloolefin copolymer. These polyolefins may be copolymers containing a small amount of non-olefinic vinyl monomers such as vinyl acetate, vinyl chloride and vinyl alcohol. The polyethylene used for the sealant film is preferably linear low density polyethylene (LLDPE) or low density polyethylene (LDPE).

  The intermediate layer 12 includes at least one colored intermediate layer. In the present specification, the colored intermediate layer is an intermediate layer containing at least 50% by weight or more of plant-derived polyolefin as a resin component and titanium oxide particles as an additive component. At least one layer of the intermediate layer 12 is a white colored intermediate layer (white intermediate layer). The proportion of polyolefin in the resin component of the colored intermediate layer is preferably 50 to 100% by weight.

  The resin component used for the colored intermediate layer may be a plant-derived polyolefin alone or a mixed resin of a plant-derived polyolefin and a petroleum-derived polyolefin. In the present specification, the plant-derived polyolefin is a case where at least a part of the olefin monomer constituting the polyolefin is made of a plant-derived olefin. Moreover, petroleum-derived polyolefin is a case where all of the olefin monomers constituting the polyolefin are composed of petroleum-derived olefins.

  Plant-derived olefins include plant-derived ethylene or propylene. Plant-derived ethylene can be produced by dehydration of ethanol produced by fermentation of biomass derived from plants such as sugar cane and corn. Plant-derived propylene can be produced, for example, by dehydration of propanol produced by biomass fermentation. When the biomass is a carbohydrate such as starch, a saccharide obtained by hydrolyzing the carbohydrate may be fermented.

  Specific examples of the plant-derived polyolefin include polyethylene, which is a polymer of plant-derived ethylene, and polypropylene, which is a polymer of propylene derived from plant. When the plant-derived polyolefin contains an α-olefin such as 1-butene, 1-hexene, 1-octene as a comonomer, these α-olefins may be α-olefins produced by a method derived from biomass such as plants. Well, it may be an α-olefin derived from petroleum.

Petroleum-derived olefins and polyolefins do not contain ¹⁴ radioactive carbons ( ¹⁴ C), whereas plant-derived olefins and polyolefins contain ¹⁴ C, so they can be distinguished from each other. The proportion of carbon derived from biomass (plant-derived degree) can be measured based on the content of ¹⁴ C. The plant-derived degree of the colored intermediate layer is preferably 50 to 100% as the plant-derived degree of the resin component (polyolefin).

  The colored intermediate layer is colored white by containing plant-derived polyolefin and titanium oxide particles, and also has good impact resistance. The reason for this is not necessarily clear, but one hypothesis is that the plant-derived polyolefin contains a low-molecular component, thereby covering the surface of the titanium oxide particles in a thin film, so that the titanium oxide particles are easily compatible with the resin component. It is presumed to be. On the other hand, since polyolefin derived from petroleum does not contain a low molecular component, it is considered that the titanium oxide particles are not easily compatible with the resin component. In addition, plant-derived polyolefins that do not contain titanium oxide particles are considered to be inferior to petroleum-derived polyolefins in terms of heat sealability, impact resistance, and the like due to the inclusion of low molecular components.

  The amount of titanium oxide added in the colored intermediate layer of the present embodiment is preferably 5 to 40 parts by weight and more preferably 10 to 35 parts by weight with respect to 100 parts by weight of the resin component. The particle size of titanium oxide added to the colored intermediate layer is preferably 0.1 to 0.3 μm. The thickness of the colored intermediate layer is preferably 30 to 70% with respect to the total thickness of the white sealant film. Here, the film thickness of the colored intermediate layer is the film thickness when there is only one colored intermediate layer, but the total film thickness when there are two or more colored intermediate layers.

  When the intermediate layer includes two or more colored intermediate layers, it is preferable that at least one layer is a white intermediate layer, and a gray intermediate layer is laminated next to the white intermediate layer. Here, the gray intermediate layer is a colored intermediate layer colored in gray. The gray intermediate layer preferably contains particles of black pigment such as carbon black in addition to titanium oxide particles as an additive component. The added amount of the black pigment is preferably 0.1 to 10 parts by weight with respect to 100 parts by weight of the titanium oxide particles. When the intermediate layer includes the gray intermediate layer, the concealability of the sealant film can be improved.

  In order for the white sealant film to be white when viewed from any thickness direction, it is preferable to provide a white intermediate layer on both sides of the gray intermediate layer. In order for the white sealant film to be white when viewed from one side, the white intermediate layer is preferably provided on the near side of the gray intermediate layer on the line of sight. For example, in a packaging bag, it is preferable that a white intermediate layer is provided between the base material layer and the gray intermediate layer.

  As a method for forming a colored intermediate layer, a resin component and an additive component are blended in the form of pellets or particles, for example, and then the resin component is melted and kneaded with the additive component, and then a film is formed by die or cast. The method of making it. Multi-layering is possible by co-extrusion with other layers constituting the sealant film.

  The colored intermediate layer may further contain an elastomer. As the elastomer, a styrene-based elastomer or an olefin-based elastomer is preferable because it has excellent compatibility or dispersibility with the polyolefin as a resin component. The elastomer contained in the colored intermediate layer is preferably elastomer particles. When the elastomer is in the form of particles, rubber elasticity in the sealant film is exhibited, and impact resistance is improved. Although it does not specifically limit as a particle size of an elastomer, For example, it can select suitably in the range of 0.1-10 micrometers.

The olefin elastomer is not particularly limited as long as it is an olefin polymer having characteristics as an elastomer.
The olefin polymer may be a single olefin homopolymer or a copolymer of two or more olefins. Examples of the olefin homopolymer usable for the olefin elastomer include homopolymers of aliphatic olefins such as polyethylene, polypropylene, poly-1-butene, and polyisobutylene. Examples of the olefin copolymer that can be used for the olefin elastomer include propylene-ethylene copolymer, ethylene-1-butene copolymer, ethylene-1-hexene copolymer, ethylene-1-octene copolymer, and propylene. -Aliphatic olefin copolymers such as ethylene-1-butene copolymer and propylene-1-butene copolymer.

  The styrene-based elastomer is not particularly limited as long as it is a styrene-based polymer having characteristics as an elastomer. For example, a block copolymer having a hard segment made of polystyrene or the like and a soft segment made of polyethylene, polybutadiene, polyisoprene or the like can be mentioned. Examples of the styrenic polymer that can be used for the styrenic elastomer include aromatic olefin-aliphatic olefin copolymers such as styrene-butadiene copolymer, styrene-isoprene copolymer, and styrene-ethylene copolymer. .

  The melting point of the elastomer is preferably lower than the melting point of the resin component constituting the colored intermediate layer. In particular, the melting point of the elastomer is preferably lower than the melting point of the plant-derived polyolefin. Thereby, when using a sealant film for heat sealing | fusion, the particle | grains of an elastomer become easy to fuse | melt and the adhesive strength between sealant films in a package etc. can be strengthened. For example, when the resin component is LLDPE having a melting point of about 121 to 127 ° C., an elastomer having a melting point of 120 ° C. or less is preferable.

  Although the two surface layers 11 and 13 will not be specifically limited if it is a layer containing polyolefin as a resin component, As for the ratio of polyolefin in the resin component of a surface layer, 50 to 100 weight% is preferable. The two surface layers 11 and 13 may have a composition not including particles as an additive component. When the surface layers 11 and 13 do not contain particles, it is preferable that no particles are lost when the sealant film is handled alone.

  Further, either one of the two surface layers 11 and 13 may have a composition containing titanium oxide particles. Thereby, in addition to the white intermediate layer, one surface layer is colored white, so that the whiteness of the sealant film can be improved. When titanium oxide is added to the surface layer, the amount of titanium oxide added is preferably 10 to 40 parts by weight with respect to 100 parts by weight of the resin component. The particle size of titanium oxide added to the surface layer is preferably 0.1 to 0.3 μm.

  Of the two surface layers 11 and 13, the petroleum-derived degree of the surface layer 11 on the side where the white sealant film 10 is bonded to the base material layer 21 is preferably 80% or more. Here, the petroleum-derived degree means the proportion of carbon derived from petroleum, and the sum of the petroleum-derived degree and the plant-derived degree is usually 100%. As described above, since plant-derived polyolefin contains a low molecular component, it may have poor adhesion to the base material layer. For this reason, when the petroleum origin degree of the surface layer on the side bonded to the base material layer is high, the adhesiveness to the base material layer can be improved.

  The method for laminating each layer (for example, the surface layers 11 and 13 and the intermediate layer 12) constituting the white sealant film 10 is not particularly limited, and examples thereof include a dry laminating method, an extrusion laminating method, and a coextrusion method. For example, it is also possible to laminate by a coextrusion method without interposing other materials between the layers.

  The total film thickness of the surface layers 11 and 13 is preferably 30 to 70% with respect to the total film thickness of the white sealant film. Moreover, it is preferable that each film thickness of the surface layers 11 and 13 is 5 to 50% with respect to the total film thickness of a white sealant film, respectively. The film thickness of the intermediate layer 12 (total in the case of two or more layers) is preferably 70 to 30% with respect to the total film thickness of the white sealant film. Although the total film thickness of a white sealant film is not specifically limited, For example, about 50-200 micrometers is illustrated.

  When laminating | stacking the base material layer 21 and the white sealant film 10, an adhesive agent can be interposed as needed. Examples of the adhesive include an anchor agent such as polyurethane, polyether, and alkyl titanate (organic titanium compound), or an adhesive resin such as acid-modified polyolefin. The adhesive may be particularly polyurethane. preferable. Examples of a method for laminating the base material layer 21 and the white sealant film 10 include a dry laminating method and an extrusion laminating method.

  By adhering the base material layer 21 and the white sealant film 10 via an adhesive, it is possible to suppress heating during lamination of the white sealant film 10. In particular, when the intermediate layer of the white sealant film 10 includes particles of an elastomer having a melting point lower than that of the resin component, the resin component is not melted and is adhered using an adhesive, and then laminated with the base material layer 21, The elastomer can maintain the particle morphology.

  The base material layer 21 may have a single-layer configuration composed of one layer, or may have a stacked configuration of two or more layers. Although the layer which comprises the base material layer 21 can be selected suitably, a reinforcement layer, a gas barrier layer, a light shielding layer, a printing layer etc. are mentioned, for example. Examples of a method for laminating each layer constituting the base material layer 21 include a dry laminating method, an extrusion laminating method, a co-extrusion method, and the like, and can be appropriately selected depending on the combination of the respective layers. The whole base material layer 21 may be colorless and transparent, and a part or all of the thickness direction or the surface direction may be colored.

Examples of the reinforcing layer include reinforcing resin layers such as biaxially stretched polyethylene terephthalate (O-PET), biaxially stretched nylon (O—Ny), and biaxially stretched polypropylene (OPP).
The gas barrier layer can be composed of, for example, an inorganic material or a gas barrier resin. As an inorganic substance, metal oxide layers, such as a metal vapor deposition layer and an alumina, are mentioned. Examples of the gas barrier resin include ethylene-vinyl alcohol copolymer (EVOH), vinylidene chloride and the like.

  The form of the package is not particularly limited, and examples thereof include laminated films, tube containers, and packaging bags. The form of the packaging bag can be applied without particular limitation, such as a three-sided bag, a four-sided bag, a jointed bag, a gusseted bag, a self-supporting bag, a pouch, a large bag such as an inner bag for a bag-in-box or a drum can interior bag. The container comprised from the package of this embodiment can also provide accessories, such as a spout, an inlet, a cock, a label, a knob for opening, and a handle.

  As mentioned above, although this invention has been demonstrated based on suitable embodiment, this invention is not limited to the above-mentioned embodiment, A various change is possible in the range which does not deviate from the summary of this invention.

  The white sealant film of the present embodiment is a sealant film having a white color as a whole, but a colored sealant colored in other colors (for example, red, blue, yellow, green, purple, gray, dark color, light color, etc.). It is also possible to apply it to a film.

  Hereinafter, the present invention will be specifically described with reference to examples.

Example 1
100 parts by weight of a linear low density polyethylene derived from petroleum having a melting point of 120 ° C. (Prime Polymer, Moatech (registered trademark)) as the first layer resin material, and derived from a plant having a melting point of 120 ° C. as the second layer resin material 100 parts by weight of linear low density polyethylene LL218 (manufactured by Brasschem), 5 parts by weight of olefin elastomer having a melting point of 80 ° C., 20 parts by weight of particles of rutile titanium oxide (IV) having a particle size of 0.14 μm, As a three-layer resin raw material, 100 parts by weight of a plant-derived linear low-density polyethylene LL218 (manufactured by Brasschem) having a melting point of 120 ° C. is melted and mixed, and then the first layer is formed using an inflation coextrusion film forming machine. Was 30 μm, the second layer was 40 μm, and the third layer was simultaneously formed into a laminate of 30 μm to produce the sealant film of Example 1.

(Example 2)
100 parts by weight of a linear low density polyethylene derived from petroleum having a melting point of 120 ° C. (Prime Polymer, Moatech (registered trademark)) as the first layer resin material, and derived from a plant having a melting point of 120 ° C. as the second layer resin material 100 parts by weight of linear low density polyethylene LL218 (manufactured by Brasschem), 5 parts by weight of an olefin elastomer having a melting point of 80 ° C., 30 parts by weight of rutile titanium oxide (IV) particles having a particle size of 0.14 μm, As a three-layer resin material, 100 parts by weight of plant-derived linear low density polyethylene LL218 (manufactured by Brasschem) having a melting point of 120 ° C., 5 parts by weight of an olefin elastomer having a melting point of 80 ° C., and rutile having a particle size of 0.14 μm After 30 parts by weight of type titanium oxide (IV) particles are melt-mixed, using an inflation coextrusion film-forming machine, the first layer is 30 μm, Two layers 50 [mu] m, the third layer to form a film at the same time so that the laminate of 30 [mu] m, to prepare a sealant film of Example 2.

(Example 3)
20 parts by weight of a plant-derived linear low-density polyethylene LL218 (manufactured by Brasschem) having a melting point of 120 ° C. and a petroleum-derived linear low-density polyethylene (manufactured by Prime Polymer, 80 parts by weight of Motec (registered trademark), 100 parts by weight of plant-derived linear low-density polyethylene LL218 (manufactured by Brasschem) having a melting point of 120 ° C. as the second layer resin material, and olefin elastomer 5 having a melting point of 80 ° C. Part by weight, 30 parts by weight of rutile titanium oxide (IV) particles having a particle size of 0.14 μm, and a plant-derived linear low-density polyethylene LL218 having a melting point of 120 ° C. (manufactured by Brasschem) as the third layer resin material After 100 parts by weight of each were melt-mixed, the first layer was 30 μm, the second layer was 40 μm, the third layer using an inflation coextrusion film forming machine. To form a film at the same time so that the laminate of 30 [mu] m, to prepare a sealant film of Example 3.

Example 4
100 parts by weight of a linear low density polyethylene derived from petroleum having a melting point of 120 ° C. (Prime Polymer, Moatech (registered trademark)) as the first layer resin material, and derived from a plant having a melting point of 120 ° C. as the second layer resin material 100 parts by weight of linear low density polyethylene LL218 (manufactured by Brasschem), 5 parts by weight of an olefin elastomer having a melting point of 80 ° C., 30 parts by weight of rutile titanium oxide (IV) particles having a particle size of 0.14 μm, As a three-layer resin raw material, 100 parts by weight of a plant-derived linear low-density polyethylene LL218 (manufactured by Brasschem) having a melting point of 120 ° C. is melted and mixed, and then the first layer is formed using an inflation coextrusion film forming machine. Of 15 μm, the second layer of 70 μm, and the third layer of 15 μm were simultaneously formed to produce a sealant film of Example 4.

(Example 5)
100 parts by weight of a linear low density polyethylene derived from petroleum having a melting point of 120 ° C. (Prime Polymer, Moatech (registered trademark)) as the first layer resin material, and derived from a plant having a melting point of 120 ° C. as the second layer resin material 100 parts by weight of linear low density polyethylene LL218 (manufactured by Brasschem), 30 parts by weight of rutile titanium oxide (IV) particles having a particle size of 0.14 μm, a plant having a melting point of 120 ° C. as the third layer resin material First, 100 parts by weight of the linear low density polyethylene LL218 (manufactured by Brasschem) was melt-mixed, and then the first layer was 30 μm, the second layer was 40 μm, and the third layer using an inflation coextrusion film forming machine. Were simultaneously formed to form a laminate having a thickness of 30 μm, and the sealant film of Example 5 was produced.

(Example 6)
100 parts by weight of a linear low density polyethylene derived from petroleum having a melting point of 120 ° C. (Prime Polymer, Moatech (registered trademark)) as the first layer resin material, and derived from a plant having a melting point of 120 ° C. as the second layer resin material 100 parts by weight of linear low density polyethylene LL218 (manufactured by Brasschem), 5 parts by weight of an olefin elastomer having a melting point of 80 ° C., 30 parts by weight of rutile titanium oxide (IV) particles having a particle size of 0.14 μm, As a three-layer resin material, 100 parts by weight of plant-derived linear low density polyethylene LL218 (manufactured by Brasschem) having a melting point of 120 ° C., 5 parts by weight of an olefin elastomer having a melting point of 80 ° C., and rutile having a particle size of 0.14 μm Type titanium oxide (IV) particles 20 parts by weight, carbon black 0.5 parts by weight, and a fourth-layer resin raw material having a melting point of 120 ° C. 80 parts by weight of low-density polyethylene LL218 (manufactured by Brasschem) and 20 parts by weight of linear low-density polyethylene derived from petroleum having a melting point of 120 ° C. (manufactured by Prime Polymer, MORETEC (registered trademark)) Using the inflation coextrusion film forming machine, the film was simultaneously formed so that the first layer was 30 μm, the second layer was 40 μm, the third layer was 10 μm, and the fourth layer was 30 μm. A film was prepared.

(Example 7)
100 parts by weight of a linear low density polyethylene derived from petroleum having a melting point of 120 ° C. (Prime Polymer, Moatech (registered trademark)) as the first layer resin material, and derived from a plant having a melting point of 120 ° C. as the second layer resin material Of linear low density polyethylene LL218 (manufactured by Brasschem), 50 parts by weight of petroleum-derived linear low density polyethylene (manufactured by Prime Polymer, Moretec (registered trademark)) having a melting point of 120 ° C., and melting point of 80 ° C. 5 parts by weight of an olefin elastomer, 20 parts by weight of rutile titanium oxide (IV) particles having a particle size of 0.14 μm, and a third layer resin raw material, a linear low-density polyethylene derived from petroleum having a melting point of 120 ° C. ( After melt-mixing 100 parts by weight of Prime Polymer and MORETECH (registered trademark), respectively, using an inflation coextrusion film forming machine, But 30 [mu] m, the second layer 40 [mu] m, and at the same time form a film having a third layer is a laminate of 30 [mu] m, to prepare a sealant film of Example 7.

(Comparative Example 1)
100 parts by weight of petroleum-derived linear low-density polyethylene (manufactured by Prime Polymer, Moretec (registered trademark)) having a melting point of 120 ° C. as the first layer resin material, and derived from petroleum having a melting point of 120 ° C. as the second layer resin material As a resin raw material for the third layer, 100 parts by weight of linear low density polyethylene (manufactured by Prime Polymer, Moatech (registered trademark)), 30 parts by weight of rutile titanium oxide (IV) particles having a particle size of 0.14 μm, After melting and mixing 100 parts by weight of petroleum-derived linear low density polyethylene (Prime Polymer, Moatech (registered trademark)) having a melting point of 120 ° C., the first layer is 30 μm using an inflation coextrusion film forming machine. The second layer was 40 μm and the third layer was 30 μm at the same time to form a laminate, and the sealant film of Comparative Example 1 was produced.

(Comparative Example 2)
100 parts by weight of a linear low density polyethylene derived from petroleum having a melting point of 120 ° C. (Prime Polymer, Moatech (registered trademark)) as the first layer resin material, and derived from a plant having a melting point of 120 ° C. as the second layer resin material 100 parts by weight of linear low-density polyethylene LL218 (manufactured by Brasschem) and 100 parts by weight of plant-derived linear low-density polyethylene LL218 (manufactured by Brasschem) having a melting point of 120 ° C. as the third layer resin raw material, After melt-mixing, using an inflation co-extrusion film-forming machine, the film was simultaneously formed so that the first layer was 30 μm, the second layer was 40 μm, and the third layer was 30 μm, and the sealant film of Comparative Example 2 Was made.

(Comparative Example 3)
100 parts by weight of petroleum-derived linear low-density polyethylene (manufactured by Prime Polymer, Moretec (registered trademark)) having a melting point of 120 ° C. as the first layer resin material, and derived from petroleum having a melting point of 120 ° C. as the second layer resin material As a resin raw material for the third layer, 100 parts by weight of linear low density polyethylene (manufactured by Prime Polymer, Moatech (registered trademark)), 30 parts by weight of rutile titanium oxide (IV) particles having a particle size of 0.14 μm, Plant-derived linear low-density polyethylene LL218 (manufactured by Brasschem) having a melting point of 120 ° C, 100 parts by weight of a plant-derived linear low-density polyethylene LL218 (manufactured by Brasschem) having a melting point of 120 ° C as a resin material for the fourth layer After 100 parts by weight of each were melt-mixed, the first layer was 30 μm, the second layer was 20 μm, and the third layer was 2 using an inflation coextrusion film forming machine. [mu] m, as the fourth layer is a laminate of 30μm to form a film at the same time, to prepare a sealant film of Comparative Example 3.

(Production of packaging bags)
The 1st layer of the sealant film of Examples 1-7 and Comparative Examples 1-3 was each adhere | attached with the base material layer through the adhesive bond layer, and the laminated film was produced. Furthermore, two members on the front side and the back side of the packaging bag are prepared from the obtained laminated film, and the exposed surfaces of the sealant film (the third layer in the case of a three-layer configuration, the fourth layer in the case of a four-layer configuration) The peripheral parts of both members were heat-sealed to produce a flat bag type packaging bag.

(Adhesive strength)
About each of Examples 1-7 and Comparative Examples 1-3, the adhesive strength between two sets of laminated films was measured according to the following measuring method.
The first layers of the sealant films of Examples 1 to 7 and Comparative Examples 1 to 3 were each bonded to a base material layer via an adhesive layer to form a laminated film, and then cut into a length of 10 mm × width of 30 mm. Two sets were prepared.
The two laminated films are arranged so that one end of each of the laminated films extends 10 mm both vertically and horizontally, the other end of one laminated film extends to the left side, and the other end of the other laminated film extends to the right side, and a pressure of 0.5 MPa is applied. A test piece having a bonding area of 100 mm ² and a size of 10 mm in length and 50 mm in width in plan view was obtained by bonding at 150 ° C. for 5 seconds.
The left and right ends of the obtained test pieces of each example were sandwiched with jigs, and a tensile shear test was performed using a tensile shear tester under the conditions of speed = 10 mm / min and chuck distance = 20 mm.
The results were evaluated as “adhesive strength” in the following manner. “◎” when the shear force is 250 N or more, “◯” when the shear force is 180 N or more and less than 250 N, “Δ” when the shear force is 100 N or more and less than 180 N, and “×” if the shear force is less than 100 N ".

(Cohesive failure)
When measuring the adhesive strength, after breaking the heat-sealed portion of the test piece of each example with a bonding area of 100 mm ² , it was visually observed whether or not cohesive failure occurred inside the sealant film, and cohesive failure occurred. The case where there was no cohesive failure was evaluated as “O”, and the case where cohesive failure occurred was evaluated as “X”.

(Visibility)
About the sealant film of Examples 1-7 and Comparative Examples 1-3, the total light transmittance of a wavelength of 550 nm was measured using Shimadzu Corporation spectrophotometer UV-2400PC. “◎” when the total light transmittance at 550 nm is less than 0.15 (15%), “◯” when the total light transmittance is 0.15 (15%) or more and less than 0.20 (20%). A sample having a total light transmittance of 0.20 (20%) or more and less than 0.35 (35%) is indicated by “Δ”, and a sample having a total light transmittance of 0.35 (35%) or more is indicated by “X”. evaluated.

(Biomass degree)
The degree of biomass was evaluated by the ratio of plant-derived polyolefin in the resin component in the entire sealant film.
Specifically, the proportion (wt%) of the plant-derived polyolefin in the resin component of the i-th layer (i is 1 to 3 or 1 to 4) is b _i , and the thickness (μm) of the i-th layer is t _i. When the total film thickness (μm) of the sealant film is T = Σt _i , the biomass degree B (% by weight) of the entire sealant film was calculated by the following formula. However, Σ represents the sum of subscripts i to 1 in the case of a three-layer configuration, and represents the sum of subscripts i to 1 in the case of a four-layer configuration. In addition, in Table 1 mentioned later, the biomass degree was displayed by "%".

B = Σ (b _i × t _i ) / T

(Summary)
Table 1 shows the composition of each layer of the sealant films of Examples 1 to 7 and Comparative Examples 1 to 3, and the evaluation results of the respective sealant films. In Table 1, “plant-derived” represents a plant-derived polyolefin, and “petroleum-derived” represents a petroleum-derived polyolefin. The polyolefin is, for example, polyethylene.

The sealant films of Examples 1 to 7 are all white with good design properties, excellent visibility, and do not cause cohesive failure when the heat-sealed portion is broken, and are excellent in impact resistance.
The sealant film of Example 2 was very excellent in visibility. This is considered to be a result of adding titanium oxide particles to the third layer.
Moreover, the sealant film of Example 6 was very excellent in visibility. This is presumably because the intermediate layer is composed of a white second layer and a gray third layer.

  On the other hand, in the sealant film of Comparative Example 1, the adhesive strength of the heat fusion part was very low, and cohesive failure occurred at the time of breakage. This is thought to be because the second layer (intermediate layer) to which a large amount of titanium oxide particles are added is made of a petroleum-derived polyolefin, so that the resin and the particles are not compatible.

  In addition, in the sealant film of Comparative Example 2, although the degree of biomass was improved by using plant-derived polyethylene for the second layer and the third layer, titanium oxide particles were not added to the second layer (intermediate layer). Therefore, cohesive failure did not occur when the heat-sealed part was broken, but the visibility was very low.

  Moreover, in the sealant film of Comparative Example 3, although the degree of biomass was improved by using plant-derived polyethylene for the third layer and the fourth layer, the adhesive strength of the heat-sealed portion was very low, and the agglomeration occurred at break Destruction occurred. This is thought to be because the second layer (intermediate layer) to which a large amount of titanium oxide particles are added is made of a petroleum-derived polyolefin, so that the resin and the particles are not compatible.

DESCRIPTION OF SYMBOLS 10 ... White sealant film, 11, 13 ... Surface layer, 12 ... Intermediate layer, 20 ... Package, 21 ... Base material layer.

Claims (9)

A white sealant film for packaging consisting of a laminate structure of at least three layers,
The laminated structure includes two surface layers provided on both sides in the thickness direction, and at least one intermediate layer provided between the surface layers,
The surface layer contains polyolefin as a resin component,
It said intermediate layer at least one layer of comprises a polyolefin derived from plants as a resin component at least 50% by weight or more, and the particles of titanium oxide as an additive component, and an elastomer saw including a melting point of the elastomer, from the plant A white sealant film characterized by being lower than the melting point of the polyolefin . The additive amount of the titanium oxide in the layer comprising particles of titanium oxide as an additive component of the intermediate layer, according to claim 1, characterized in that 10 to 40 parts by weight per 100 parts by weight of the resin component White sealant film. White sealant film according to claim 1 or 2 one of the two surface layers, characterized in that it comprises particles of titanium oxide. The white sealant film according to any one of claims 1 to 3 , wherein a particle diameter of the titanium oxide is 0.1 to 0.3 µm. The white sealant film according to any one of claims 1 to 4 , wherein a plant-derived degree of the layer containing the plant-derived polyolefin and the titanium oxide particles in the intermediate layer is 50% or more. . The oil-derived degree of the surface layer on the side where the white sealant film is bonded to the base material layer of the two surface layers is 80% or more, according to any one of claims 1 to 5. The white sealant film as described. The white sealant film according to any one of claims 1 to 6 , wherein a thickness of the intermediate layer is 30 to 70% with respect to a total thickness of the sealant film. The intermediate layer, and the white at least one intermediate layer, white sealant according to any one of claims 1 to 7, characterized in that it comprises said white intermediate layer gray intermediate layer laminated adjacent to the the film. A packaging body, wherein a base material layer is laminated on one of the two surface layers of the white sealant film according to any one of claims 1 to 8 via an adhesive. .

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