JP6057827B2

JP6057827B2 - 熱可塑性重合体組成物、およびその用途

熱可塑性重合体組成物、およびその用途 Download PDF

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Publication number: JP6057827B2
Authority: JP; Japan
Prior art keywords: propylene; methyl; olefin; mol; copolymer
Prior art date: 2013-04-25
Legal status : Expired - Fee Related

Application number

JP2013092871A

Other languages

English (en)

Japanese (ja)

Other versions

JP2014214227A (ja

JP2014214227A5 (enrdf_load_stackoverflow

Inventor

貴行植草

Current Assignee

Mitsui Chemicals Inc

Original Assignee

Mitsui Chemicals Inc

Priority date

2013-04-25

Filing date

2013-04-25

Publication date

2017-01-11

2013-04-25 Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc

2013-04-25 Priority to JP2013092871A priority Critical patent/JP6057827B2/ja

2014-11-17 Publication of JP2014214227A publication Critical patent/JP2014214227A/ja

2015-09-17 Publication of JP2014214227A5 publication Critical patent/JP2014214227A5/ja

2017-01-11 Application granted granted Critical

2017-01-11 Publication of JP6057827B2 publication Critical patent/JP6057827B2/ja

Status Expired - Fee Related legal-status Critical Current

2033-04-25 Anticipated expiration legal-status Critical

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239000000203 mixture Substances 0.000 title claims description 94
229920001169 thermoplastic Polymers 0.000 title claims description 41
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 153
239000004711 α-olefin Substances 0.000 claims description 114
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 85
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 75
229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 56
229920000642 polymer Polymers 0.000 claims description 54
229920001577 copolymer Polymers 0.000 claims description 50
125000004432 carbon atom Chemical group C* 0.000 claims description 31
239000000463 material Substances 0.000 claims description 26
150000001336 alkenes Chemical class 0.000 claims description 17
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 17
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 16
150000004291 polyenes Chemical class 0.000 claims description 13
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims description 8
238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims description 4
239000004416 thermosoftening plastic Substances 0.000 claims description 2
-1 polypropylene Polymers 0.000 description 73
229920001155 polypropylene Polymers 0.000 description 72
239000011347 resin Substances 0.000 description 65
229920005989 resin Polymers 0.000 description 65
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 62
238000006116 polymerization reaction Methods 0.000 description 43
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 40
239000005977 Ethylene Substances 0.000 description 40
229920001971 elastomer Polymers 0.000 description 34
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 33
229920005604 random copolymer Polymers 0.000 description 33
239000005060 rubber Substances 0.000 description 29
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OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
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238000002844 melting Methods 0.000 description 22
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238000000034 method Methods 0.000 description 21
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KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 15
238000010521 absorption reaction Methods 0.000 description 14
239000003208 petroleum Substances 0.000 description 14
238000004519 manufacturing process Methods 0.000 description 13
GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 12
238000002156 mixing Methods 0.000 description 12
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229920002725 thermoplastic elastomer Polymers 0.000 description 10
238000005481 NMR spectroscopy Methods 0.000 description 9
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
230000035807 sensation Effects 0.000 description 9
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238000004132 cross linking Methods 0.000 description 8
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239000001257 hydrogen Substances 0.000 description 8
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238000010438 heat treatment Methods 0.000 description 7
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125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
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238000009826 distribution Methods 0.000 description 6
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239000002649 leather substitute Substances 0.000 description 6
239000003446 ligand Substances 0.000 description 6
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 6
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