JP6037094B2 - Manufacturing method of charcoal / pH buffer adjusting agent kneaded granular material having air permeability, water retention, adsorptivity and pH adjusting function and method of use thereof - Google Patents

Description

  The present invention relates to polypropylene, polyethylene, which can be used as plant-growing, pest-preventing artificial soil and water purification, nitrite nitrogen low-range stability, pH buffer adjustment base material, water antiseptic prevention purification base material for geothermal regeneration energy, etc. Or a charcoal with aeration, water retention, pH buffer adjustment function composed of a mixture of thermoplastic synthetic resin represented by pets and plant materials such as wheat straw, rice straw, rice husk, wood chips, large sawdust and salt compounds The present invention relates to a pH buffer adjusting agent kneaded resin, a method for using the same, and a method for producing the same.

  Conventionally, resin waste discharged from ordinary households and business establishments has been partially recycled, such as plastic bottles, but most of them are disposed of in landfills. In addition, although rice straw, rice husk generated from rice cultivation, and wood and large sawdust have been recently tried to be used as biomass fuel, most of them are currently disposed of.

On the other hand, in recent years, it has become popular to grow potted plants on verandas etc. in high-rise apartments in urban areas, and to choose vegetables that are cultivated in stores at restaurants and put them on dishes. It is not easy to grow plants in a courtyard or a showroom.
Therefore, development of a plant growing container for efficiently growing plants on a veranda, a rooftop, a courtyard, etc., soil for plant growth, etc. has been made. (For example, see Patent Documents 1 to 4)

  In addition, the increase in the global population, the decrease in greening due to urbanization, the contamination of water and the increase in carbon dioxide concentration in the air increase the temperature rise and the extinction rate of animal and plant species other than human beings. The transformation is happening and the natural ferociousness is beginning to blow.

  Furthermore, the direct release of human wastewater and factory wastewater to date has resulted in pollution of rivers, lakes, and oceans, resulting in pollution of the ocean and groundwater, and currently working to purify water. With the doubt and anxiety about the significance and future of humanity, darkness is spreading in the minds of modern adults.

  In addition, river and sea pollution by mankind including river dam construction, factories, and domestic waste liquids has threatened the life cycle of fish and shellfish living there. Therefore, in modern society, the development of water circulation purification technology that can inhabit many aquatic organisms has become the most important issue for mankind. (For example, see Patent Documents 5 to 11)

  The current installation of air-conditioning equipment in all houses, shops and buildings not only greatly expands Japan's power consumption, but the existence of outdoor units creates a contradiction that further increases summer outdoor air temperature.

  In addition, many people suffered damage from the Great East Japan Earthquake and Tsunami on March 11, 2011, salt damage of the earth, and radioactive contamination of the earth, rivers and seas due to radioactive leaks caused by reactor reactor destruction It has caused serious damage to a wide range of inhabitants, especially farmers and fishermen, and it has become a major problem nationwide in Japan, ranging from the crisis to the survival of municipalities. This nuclear accident in Japan poses questions and concerns about the use of nuclear energy throughout the world.

JP-A-11-103702 JP 2005-137363 A JP 2007-124989 A JP 2008-307013 A JP-A-8-141594 Japanese Patent Laid-Open No. 9-299957 JP 2000-116273 A JP 2000-157101 A JP 2003-265071 A JP 2004-81109 A JP 2007-50363 A Japanese Patent Laid-Open No. 2002-179552 JP 2008-281266 A Japanese Patent Application Laid-Open No. 2010-197016

Kuma Kuma (ed.) (1997): Latest soil science. Asakura Shoten, 216p. Masakazu Ikuni (1989): Weathering of silicate and its products. Soil Chemistry Chapter 2, Quarterly Chemistry Review No. 4, 6-18.

However, in the above prior patent document,
In patent document 1, the artificial soil is manufactured from the porous ceramic, and the manufacturing cost is expensive,
In Patent Document 2, artificial soil has a complicated structure, which is expensive and not practical.
Patent Document 3 is not an artificial soil but a plant growing tool, and the soil uses natural soil,
Although it is described as artificial soil in Patent Document 4, the fact is that a complex in which soil is housed in a pot-shaped support is described as artificial soil, but the soil itself does not have a specific device for artificial soil, and is described above. All prior patent documents do not clearly identify specific examples of hydroponics.

Furthermore, in the above prior patent document,
In patent document 5 and patent document 10, the proposal regarding the purification method of closed system circulating water is a device about the high concentration culture method of nitrite bacteria among the nitrate bacteria which contribute to the purification of closed system circulating water,
In patent document 6, it is a device about the water purification apparatus instrument of a circulating water flow path,
Patent Document 7 is a device for purifying circulating water using a transport tank, a transport device, and a transport method for live fish and shellfish, and has proposed a filter mat as a filtering means.
Patent Documents 8 and 9 devise a device for rearing and aquaculture of fireflies. Regarding the purification of circulating water, “the description of the fine particle layer and the porous material layer include inorganic powder obtained by pulverizing glass, brick, etc. Inorganic foams such as foam glass formed by mixing and heating with foaming agents such as silicon carbide, lump-shaped charcoal such as charcoal formed in bulk, shells such as oyster shells, pumice, Raschig rings The formed synthetic resin or ceramic porous body or a mixture of them is used to form a single layer or multiple layers, etc. Among them, the inorganic foam has a large surface area and a fine pore. Therefore, ammonia, organic matter, algae, etc. can be adsorbed or removed by filtration and a biofilm inhabited by bacteria is formed, and the adsorbed ammonia, organic matter, etc. are decomposed by bacteria such as nitrifying bacteria. Is preferably used because it is excellent in purification of Rukoto can be water. Only the description of "no filtration methods much different conventional tropical fish,
Patent Document 11 proposes a purification device using ceramic, which increases the cost.

  One of the problems to be solved by the present invention is to produce an artificial soil that can be regenerated at a low cost, is friendly to the global environment where crops that could not be produced in the past, are safe, and can adjust the soil pH. is there.

  In addition, it is possible to adjust the environmentally friendly eco-art shape and the above-mentioned soil pH by reusing biomass and salt compounds, such as industrial waste of synthetic resin, wood waste, large sawdust, rice straw, rice husk etc. Using artificial soil, it is possible to grow various animals and plants not only on land soil but also in verandas and kitchen gardens of urban high-rise dwellings, indoors, on the rooftops of buildings, and underground. This also contributes to the reduction of carbon dioxide concentration in the air, the suppression of temperature rise and the peace of mind of human society.

  In addition, the problem to be solved by the present invention is to appropriately mix artificial soil with adjustable soil pH into clayey soil or desert sandy soil, thereby allowing air permeability and water retention to the soil. It is to have a suitable soil pH suitable for the crop.

  Furthermore, the problem to be solved by the present invention is the combination of land and land that can grow rice plants and grow various plant species such as melon, watermelon, corn, various beans, and tea trees that did not grow in conventional hydroponics. Forming a hydroponic pot of the mold to allow many crops to grow on this system.

Furthermore, the problem to be solved by the present invention is to manufacture an inexpensive purification / adsorption / pH adjustment base material for circulating water for purification of the closed system circulating water, and the simple and inexpensive closed system circulating water, By suppressing eutrophication by increasing the concentration of nitrogen compounds ( nitrite nitrogen ) in the water, the abnormal occurrence of phytoplankton is suppressed, and the concentration ratio of nitrogenous fertilizer (N) and phosphorus fertilizer (P) is 7: It is to construct a purification substrate system that suppresses approaching the balance region of 1, suppresses the spoilage of water by stabilizing the pH of water at around 7.0.

  Furthermore, this water purification system adjusts the ratio of nitrogen (N) and phosphorus (P) fertilizer to moderately suppress the occurrence of zooplankton following the abnormal occurrence of phytoplankton due to water eutrophication. It is to keep the water transparent and to ensure that the aquatic life inhabiting the water is kept in a moderately comfortable state, thereby suppressing water deficiency and spoilage.

  Furthermore, closed water purification (tank) that allows various aquatic organisms to inhabit, grow and cultivate comfortably, using water that has been controlled for oxygen deficiency and spoilage with an inexpensive purification / adsorption / pH control substrate. ) Creating a pond.

  In addition, by using water that has reduced oxygen deficiency and spoilage with an inexpensive purification / adsorption / pH adjustment base material for the circulating water, create air conditioning systems for homes and buildings that use environmentally friendly renewable energy. It is.

  Furthermore, we propose a water purification facility system for rivers and lakes that have been polluted by the current human society, using water that has been reduced in oxygen deficiency and spoilage with the low-cost purification, adsorption, and pH-adjusting base material of the circulating water. To create.

The present invention is a kneaded material (charcoal / pH adjuster kneaded resin lump) effectively used by adding a salt compound to the resin waste and the vegetable waste. The charcoal / pH adjuster kneaded resin lump can be effectively processed for use as a plant-growing granular material that can efficiently grow plants, such as woody biomass, large sawdust, wheat straw, rice straw, rice husk etc. The vegetable biomass resin obtained by mixing together a thermoplastic resin typified by the polypropylene, polyethylene or (pet resin) polyethylene terephthalate and a salt compound and carbonized by heat treatment at 300 ° C to 400 ° C.

The charcoal / pH adjuster kneaded resin lump is decomposed lightly by the heat treatment at 300 ° C. to 400 ° C. and the plant material such as wood waste / large sawdust or wheat straw / rice straw / rice husk carbonized by the heat treatment at 300 ° C. to 400 ° C. It is a kneaded product of a thermoplastic resin typified by the small molecule polypropylene, polyethylene or (pet resin) polyethylene terephthalate and a salt compound. First, a charcoal / pH buffer adjusting agent kneaded resin lump having air permeability, water retention, adsorptivity and pH adjusting function is produced.

Furthermore, the present invention provides a charcoal / pH adjuster kneaded resin, which is a kneaded product of the resin waste, the resin waste effectively using the plant waste, the plant waste, and a salt compound that is a pH adjuster. constructed of mass producing carbonized BIOMATICS scan granular resin having a plant efficiently breathable water retention, absorptive, pH buffering adjusting function that can be effectively processed using the granular materials for growing a plant capable of growing Therefore, the charcoal / pH-adjusted kneaded resin mass, which is a kneaded product obtained by adding and mixing a powder of a salt compound that is a pH buffer adjusting agent to the plant waste that is the resin and biomass into particles of about 5 mm or less by crushing and grinding in a crusher, it is to produce a charcoal-pH adjusting agent kneaded particulate material containing carbide BIOMATICS scan with breathable water retention and absorption properties and pH buffering adjusting function.

Furthermore, the present invention provides a method for crushing the resin waste, the resin waste effectively using the plant waste, and the charcoal / pH adjuster kneaded resin lump which is a kneaded product of the plant waste and a salt compound. The surface area of charcoal and pH compound kneaded particles was expanded by crushing and crushing into particles of about 5 mm or less with a machine to improve air permeability, water retention, adsorbability and pH buffer adjustment function.
Wood charcoal, wood sawdust, wheat straw, rice straw, rice husk and salt compound powder particles, which are carbonized plant biomass, are exposed from a resin that has been lightly decomposed into small molecules by heat treatment at 300 ° C to 400 ° C. Is a water-retaining charcoal / pH adjuster-mixed granular material particle that retains the same adsorptivity and breathability as charcoal, and also has a deodorizing property, and has a pH buffer adjustment function. The charcoal / pH adjuster kneaded granular material particle is a resin in which carbonized particles and salt compound powder particles are lightly decomposed into small molecules by heat treatment and bonded to each other. It is a kneaded granular material, and the charcoal / pH adjuster kneaded granular material is used as the plant-growing granular material or a closed system circulating water purification / adsorption / pH buffer adjustment base material.

As described above, the charcoal / pH adjuster-mixed granular material of the present invention is composed of the above-mentioned plant wood chips, large sawdust or wheat straw / rice straw / rice husk (P in FIG. 1) and the polypropylene and polyethylene as shown in FIG. Alternatively, it is a biomass / salt compound kneaded resin in which a thermoplastic resin represented by a pet (R in FIG. 1) and a pH buffer adjuster (salt compound) powder (α in FIG. 1) are mixed together and carbonized by heat treatment. The woody biomass, large sawdust, rice straw, rice husk (P in FIG. 1) and the thermoplastic synthetic resin (R in FIG. 1) typified by polypropylene, polyethylene or pet, and a salt compound (α in FIG. 1). since the are kneaded with a pressure of about 50kg / cm2,300 ℃ than 400 kneader under conditions of less ° C. the (ruder) (1 in FIG. 1) plant biomass material is carbonized, carbon biomass thermoplastic This is a kneaded product in which the resin is lightly decomposed to be reduced in molecular weight and carbonized particles and salt compound powders are bonded to each other.
Crushing and crushing into charcoal / pH buffer adjuster kneaded resin lump (M in Fig. 1) with air permeability, water retention, adsorptivity and pH buffer adjustment function into particles of about 5mm or less with a crusher (2 in Fig. 1) The manufactured charcoal / pH buffer adjuster-mixed granular material (MS in FIG. 1) is low in production cost, has no decomposition toxin of synthetic resin, has high granular shape maintenance strength, and can be recycled.

  In addition, the charcoal / pH buffer adjuster-mixed granular material (MS in FIG. 1) of the present invention retains the breathability and adsorptivity, which are the characteristics of charcoal, and has a low molecular weight thermoplastic resin (carbonized particles). Since the structures are bonded to each other in (R) of FIG. 1, the water retention is increased and the pH buffering function of water is also provided.

  Furthermore, the charcoal / pH buffer adjuster kneaded granular material of the present invention (MS in FIG. 1) is lighter and cheaper than conventional ceramic granular materials, has a higher shape retention strength than charcoal, and can be recycled and reused.

  Therefore, the charcoal / pH buffer adjuster-mixed granular material (MS in FIG. 1) of the present invention is not shown when it is mixed properly in soil containing a lot of clay, but it is a property of clay soil, which is not shown in the figure. However, the bad properties are improved and the soil pH is adjusted appropriately.

  Therefore, when the charcoal / pH buffer adjuster kneaded granular material (MS in FIG. 1) of the present invention is laid on a lower layer of about 30 cm of soil having a lot of sand, water retention and soil pH can be adjusted in the sand.

  Furthermore, the charcoal / pH buffer adjuster kneaded resin mass (M in FIG. 1) of the present invention is a part of the charcoal / pH buffer adjuster kneaded granular material (MS in FIG. 1), which is pulverized into particles of about 5 mm or less. Granular material (MS) of 3mm or less is generally mixed with organic fertilizer (Y) in the ratio of charcoal / pH buffer adjuster mixed granular material (MS): peat moss: fermented fertilizer = 6: 3: 1. Making artificial soil for plant cultivation (MSa) makes artificial soil for plant cultivation optimal for hydroponics (MSa in Figs. 2, 3, 4, 6, 7), and melon that did not grow in conventional hydroponics (P4 in Fig. 6), watermelon, corn, potatoes (P5 in Fig. 7), and various plant species such as various beans and tea trees can be grown (in the case of melon and watermelon, charcoal and pH Buffer modifier kneaded granular material (MS): peat moss: fermented fertilizer = 5: 3: 2 is optimal). That is, the hydroponic pot (Wp) used in the present invention is composed of a net-like bottomed frame (Wp1) and a basin box (Wp2) as shown in FIGS. Since the depth of (Wp1) is about 15-20 cm, melon, watermelon, corn, potato, asparagus, blueberry, tea tree, etc. can grow. At this time, the plant grows without watering for a few days if it is firmly rooted, so it is suitable for young couples to grow as a home garden on the veranda of an apartment.

Furthermore, plant fertilizer using only agricultural soil and charcoal / pH buffer adjuster kneaded resin mass (M) pulverized into particles of about 5 mm or less into the charcoal / pH buffer adjuster kneaded granular material (MS) with organic fertilizer When co-cultivated bitter gourd (bitter melon) in a hydroponic pot (WP) using plant-grown granular material (artificial soil MSa) made by mixing (Y), the charcoal / pH buffer adjuster kneaded resin mass It was made by mixing organic fertilizer (Y) with granular material (MS) of about 3 mm or less of the charcoal / pH buffer adjuster mixed granular material (MS) pulverized into particles of about 5 mm or less (M). The bitter gourd (bitter gourd) hydroponically cultivated with granular material for plant cultivation (artificial soil MSa) grows faster and grows about twice as fast as the bitter gourd (bitter gourd) using only the soil for agricultural use. And the size has grown about twice.
When only the charcoal / pH buffer adjuster mixed granular material (MS) is used as the plant growing granular material (artificial soil MSa), the charcoal / pH buffer adjuster mixed granular material (MS) itself is essentially a plant nutrient. Is not included, so it is necessary to add fertilizer.

Originally, the soil means that “the rocks that formed the land before the creatures entered the land were struck by the rain in which strong acidic substances contained in the primitive atmosphere were dissolved, and were blown and weathered by the wind. It seems to have formed fine substances such as clay and sand on the surface, such as regolith and clastic aterials. However, there was no life and no organic matter. Only when organisms appeared on land, regolith had the opportunity to convert to soil. The reason for the process of change from regolith to soil seems to be the formation of soil on the volcanic ejecta. There is a study of Tezuka (1961) that traced the process of soil formation and vegetation development on lava erupted at various ages in Izu Oshima in the past. According to the report, it took almost 200 years for lava to accumulate weathered sandy debris and create a desert landscape. The plant remains enter the sand, organic matter begins to accumulate, animals and microorganisms that use it settle down, and gradually change to a medium more suitable for living organisms. As a result, in the next stage, species that are better adapted to the new medium will dominate and the so-called transitional stage will advance. In more than 1,000 years, regolith turns into soil more deeply with the transition of plants, and by storing organic matter and nutrients in it, evergreen broad-leaved trees adapted to the climate of Oshima (camellia, shii, Tabs etc.) until the main forest is nurtured. ... Soil is nurtured by living organisms, and as a result, has the ability to support and nourish living organisms. Thus, when considering soil in relation to living organisms, it is assumed that all conditions for survival of living organisms such as temperature, light, air, and water are satisfied. And this point is emphasized in the previous section that it is only the surface of the earth. ( Non- Patent Document 1)

Furthermore, “Soil is somehow popular and soil is academic. But it is also true that the expression of soil has some kind of friendliness. That is because the soil is our immediate presence. If you look at how soil is defined, in most cases you will find that the following three items are common.
1. A loosely bound natural substance that covers the surface of the earth.
2. A mixture of rock weathering products and plant degradation residues.
3. A substance that can support the growth of plants.
In order for the soil to form, rock weathering must occur. Some weathered products include particles that are physically crushed, for example mechanically, but many are products of chemical reactions. Weathered products vary depending on the physical and chemical conditions where the weathering occurred. For this reason, the type of soil varies significantly depending on the location on the earth. Soil classification is an important and difficult task in soil science. The constituent components of the soil can be divided into coarse inorganic substances, colloidal inorganic substances, organic substances, organisms, soil solutions, and soil air. Various conditions are necessary for soil to maintain the life of plants. Temperature, precipitation, etc. are basic conditions that determine whether plants can grow or not, but this is not a physical or chemical factor required for soil, but a climatic factor. Is excluded. A possible physical and chemical factor for soil is its ability to retain water and nutrients (N, P, K as well as various essential trace elements). However, even if this becomes extreme, the condition is bad. In soils with low water permeability, when the water in the soil is poorly flowed and dissolved oxygen reacts with organic matter in the soil and is consumed, plant roots are immersed in oxygen-free water. Suffocated, and finally suffocated. In addition to the ability to retain water, the opposite water permeability and breathability are also required. In the case of elements that serve as nutrients, if they are strongly bound to the soil particles, it becomes impossible for the plant to absorb them.
Let's suppose that the soil is an aggregate of inorganic fine particles made of rock weathering and contains no organic matter. Most of these fine particles are aluminosilicates called clay minerals, and hydrated oxides represented by Fe2O3 · nH2O and Al2O3 · nH2O. In the state where moisture coexists, these particles adhere to each other and eventually become a single lump, creating an environment unsuitable for plant growth. The organic matter is adsorbed on the surface of these inorganic particles and serves to prevent direct contact between the inorganic particles. Such an organic substance is a high-molecular substance containing OH groups and COOH groups generated by decomposition of plants, has ion exchange properties, and contributes to loosely holding elements necessary for plant growth. The water retained in the capillary of particles constituting the soil is the soil solution. There is a certain equilibrium between the soil solution and the particles based on ion exchange and adsorption, which serves to control the concentration of dissolved species in the soil solution. Spring water is a dilute solution, but the concentration of dissolved species varies from rain to rain and is not constant even in a series of rains. Despite this rain, the composition of spring water is constant. This may be the result of the concentration adjustment by solution-particle equilibrium in the soil, as described above. The soil controls the composition of the atmosphere by growing plants, and also plays a role in coordinating the outflow of precipitation in cooperation with the overgrown plants (forests). In other words, soil is an environmental controller on the Earth's surface. It should be noted that soil is not an important resource for mankind but based solely on food production. ( Non- Patent Document 2)

In other words, the soil was originally based on “bacteria / plants / animals formed on the earth's surface called mineral regolith or clastic materials, which are weathered, crushed, and dusted from primitive earth rocks. The organic matter (nutrient fertilizer) of the excrement and carcasses of the carcasses is attached, adsorbed and mixed. ]

The charcoal / pH buffer adjuster kneaded granular material (MS) corresponding to the base of the artificial soil of the present invention is an “inorganic regolith or debris that has been weathered, crushed and finely divided into rocks”. (Clastic materials) ”Similarly, organic fertilizer is not included in the material, and the organic matter contained is a thermoplastic synthetic resin and biomass (plant material) synthesized by humans with a pressure of about 50 kg / cm2, 300 Plant biomass material is carbonized in the process of kneading using a kneader (ruder) (1 in Fig. 1) under the condition of not less than 400 ° C and not more than 400 ° C, and the carbonized biomass is decomposed into small molecules by lightly decomposing the thermoplastic resin. Only the thermoplastic synthetic resin with carbonized particles bonded to each other and the remaining plant material that is not carbonized, and the bacteria are also almost killed and decomposed by heat, and there is something equivalent to organic fertilizer. Not.

Furthermore, as described in paragraph (0034) , “soil (soil) is a weathered, crushed and finely divided fine particle of rock, most of which are aluminosilicates called clay minerals, Fe2O3 · nH2O, Al2O3 -Hydrated oxide typified by nH2O], which is a compound salt with almost all metal ions and the like bonded to it.

On the other hand, the granular material for plant growth (artificial soil MSa) of the present invention comprises a plant material (P), a thermoplastic synthetic resin (R), and a salt compound (α) at a pressure of about 50 kg / cm ² , 300 ° C. to 400 ° C. About 3 mm or less of the charcoal / pH buffer adjuster kneaded granular material (MS) obtained by pulverizing the charcoal / pH buffer adjuster kneaded resin lump (M) heated and mixed under the conditions below within 5 mm or less. Is a granular material for plant cultivation (artificial soil MSa) made by mixing organic fertilizer (Y) with the granular material (MS), and the mixed granular material (MS) contains a salt compound (carbonate compound / phosphoric acid) Salt compound, rice husk ground powder, limestone (calcite / marble) carbonate mineral ground powder, zeolite aluminosilicate mineral ground powder, tourmaline borosilicate mineral ground powder, borax ( borax) borate mineral pulverized powder etc.) It is contained Len. This is very similar to the structure of natural soil, and corresponds to the fertilizer content in the paragraph ( 0034 ). “... Organic matter is adsorbed on the surface of these inorganic particles, and direct contact between the inorganic particles does not occur. Has a role to prevent. Such an organic substance is a high-molecular substance containing OH groups and COOH groups generated by decomposition of plants, has ion exchange properties, and contributes to loosely holding elements necessary for plant growth. The organic matter of organic fertilizer (Y) of the plant-growing granular material (artificial soil MSa) made by mixing organic fertilizer (Y) with the charcoal / pH buffer adjuster mixed granular material (MS) of the present invention Is working. The granular diameter of the plant-growing granular material (artificial soil MSa) is preferably about 3 mm or less.

  That is, the artificial soil of the present invention is an artificial soil based on the process of creating an original natural soil that can adjust the fertilizer balance and pH range of the soil according to the type of the plant to be grown.

  The current soil is made of agricultural chemicals and chemical fertilizers, and the soil is inclined to the acidic range, or contaminated soil due to salt damage, acid rain, urbanization, radioactivity, etc. has increased, and contamination and depletion of groundwater has become a problem. Farmers in the country have begun to make efforts to make soil, and can be used as “model making” for the soil production confirmation experiment.

  On the other hand, some of the artificial soils have begun to announce and sell dried sludge from septic tanks as inexpensive soil, but there are water pollution problems and purification technologies and rules for domestic and industrial wastewater. Is considered a very dangerous soil substitute in modern society where it has not been completed.

Furthermore, as in the previous paragraph ( 0034 ), general plants and animals are nurtured and inhabited.
1. A loosely bound natural substance that covers the surface of the earth.
2. A mixture of rock weathering products and plant degradation residues.
3. A substance that can support the growth of plants. For example, in the soils of broad-leaved forests such as beech and dense forests in nature, many organisms inhabit, and in the life cycle of organisms such as defoliation and excretion, nutrients and moisture are coarse-grained inorganic matter, colloidal inorganic matter , Organic matter, organisms, soil solutions, and soil air are stored as constituents of these, “water held in the capillaries of the particles constituting the soil is the soil solution, and ions between the soil solution and the particles There is a certain equilibrium based on exchange and adsorption that serves to control the concentration of dissolved species in the soil solution. Spring water is a dilute solution, but the concentration of dissolved species varies from rain to rain and is not constant even in a series of rains. Despite this rain, the composition of spring water is constant. This may be the result of the concentration adjustment by solution-particle equilibrium in the soil, as described above.

The charcoal / pH buffer adjuster mixed granular material (MS in FIG. 1) of the present invention has air permeability, water retention, adsorptivity and pH buffer adjustment function. 14, FIG. 15, FIG. 16) can be effectively used as a purification material. This is because the charcoal / pH buffer adjuster kneaded granular material (MS in FIG. 1) adsorbs ammonia, organic matter, algae, etc. by the carbonized constituent parts of the plant biomass such as wood chips, large sawdust or wheat straw / rice straw / rice husks. Or filter to form a biofilm inhabited by bacteria, and adsorbed ammonia and organic matter can be decomposed by nitrite nitrogen oxidizing bacteria (nitrite bacteria) This is because the salt compound kneaded together in the charcoal / pH buffer adjuster kneaded granular material (MS in FIG. 1) plays the role of adjusting the pH buffer of water. Because. At this time, it is desirable that the granular diameter of the charcoal-mixed granular material (S in FIG. 1) be unified to a size of about 3 mm to 5 mm. Using the charcoal / pH buffer adjuster kneaded granular material (purification base material MS) kneaded with calcium carbonate salt and calcium phosphate salt, the water in the closed circulation septic tank (pond) where aquatic organisms live is adjusted to pH 7.2, It has been stably maintained for more than one year at a nitrite nitrogen concentration of around 0.12 ppm.

  FIGS. 14 and 16 are a plan view of a closed-system circulating water purification pond (tank) 13 and a cross-sectional view of an example of the embodiment 15. The animals and plants in FIG. The material (MS in Fig. 1) has been inhabiting and growing in a healthy manner without exchanging for more than a year, and the fish swimming well in Fig. 16 is a white sea bream that has traditionally been impossible at public fisheries test stations. It is a photograph of a juvenile fish just before the release that was 100% successful in incubation and breeding in a closed-system circulating water purification pond (tank). Eggs of large fish (鮭) contain a large amount of serous protein, but the charcoal / pH buffer adjuster-mixed granular material (MS in Fig. 1) is reliably purified from the serum protein eluted into water during incubation. This is proof.

  In the current unseasonable weather such as global warming and power shortage due to the nuclear power plant accident, thrifting of electric energy etc. is screamed. Currently, the air conditioning system for houses and buildings (16 in FIG. 18) uses a circulation system for compression heating and volatile cooling between the indoor unit 27 and the outdoor unit 38 using a refrigerant (gas G: formerly chlorofluorocarbon) heat exchanger. However, the amount of electricity consumed by this refrigerant gas circulation system consumes a very large amount of electricity compared to the amount of electricity consumed by the fan. Therefore, as shown in Patent Document 13 and Patent Document 14, a system for reusing outdoor unit discharge / waste heat energy 41 (heat pump unit 38 in FIG. 18) has been developed, and the environment-friendly conventional air conditioner system has been developed. There are systems that aim at about one-third of electricity consumption.

  However, although the air conditioner system (FIG. 18) reuses the heat energy 41 released from the outdoor unit 38, it is not renewable energy using natural energy. Therefore, the coolant water for purifying and circulating the circulating water of the present invention using the charcoal / pH buffer adjuster kneaded granular material (MS in FIG. 1) is dug deep in FIG. 17 (h2: about 8 m or more, L2: 30 cm). In order to cool the circulating / refrigerant water (Wt6) to geothermal heat with the geothermal energy exchange device 1 (23), and conversely to make it hot water, constructing an air conditioning system that allows the solar water heater (solar energy exchange device 2) 10 to pass through, There is no corrosion of circulating / refrigerant water (Wt6). The flow path of the circulating water is switched by the switching device (19). The amount of electricity used in this air conditioning system is the geothermal energy exchange device 1 (23) and the solar water heater (solar energy exchange device 2) (10) using the circulating water purification device (Wt1 to 4) and the circulating / refrigerant water (Wt6). There is only the amount of electricity that moves the fan that sends the air made by the pump 25 (Wt4) and the radiator (radiator) 18 for circulating between them, and is less than one-fifth of the amount of electricity consumed by the conventional air conditioning system It is possible to build an air conditioning system for houses and buildings that uses more environmentally friendly natural renewable energy.

  FIG. 19 is an implementation photograph of a two-layer closed-type closed water purification pond, and the construction structure is an application of FIG. 13 (plan view) and FIG. 15 (cross-sectional view). This two-layer circulation pond is constructed by an upper pond 45 (Wt1) and a lower pond 46 (Wt5). From the lower pond 46 (Wt5) to the upper pond 45 (Wt1), a magnet pump (turbine, FIG. 16 Wt4) pumps circulating water (W2) and removes large debris and floc from the upper pond 45 (Wt1) with a nylon mat (8 in FIGS. 15 and 16) of the filtration tank (Wt2). Wt3) purification material (charcoal / pH buffer adjuster kneaded granular material) (MSb in Fig. 1) purified and recycled circulating purified water 44 (Wt15, W1) through the circulating water circulation pipe (Wt13) lava stone skin ( The surface (Mb1) of Md) is made into a waterfall and dropped again onto the lower pond 46 (Wt5), and then aquatic organisms or large garbage removal nets hidden under the gravel in the lower pond 46 (Wt5) ( In the upper pond 45 (Wt1) by the magnet pump (water turbine, Wt4 in FIGS. 13 to 16) in St1or St2) It pumped circulating. The two-layer circulation type closed-system circulating water purification pond device (Wt) only adds the amount of water evaporated without replacing the purification material (charcoal / pH buffer adjuster kneaded granular material) (MSb in Fig. 1) for more than one year. Circulating water (W2) has been bred for more than a year without rot, and aquatic organisms (plants, fish, fireflies, etc.) that live in this water can be bred.

  This means that the charcoal / pH buffer adjuster kneaded granular material (MS in FIG. 1) of the present invention can be used in the circulating / refrigerant water (Wt6) of the housing / building air conditioning system in FIG. Proves that it can be used for at least one year without rot.

  Furthermore, the charcoal / pH buffer adjuster kneaded granular material (MS in FIG. 1) of the present invention can circulate and purify contaminated rivers and lakes in combination with the natural osmotic water method, as shown in FIG. There is ability.

  Furthermore, as shown in FIG. 21 (conceptual plan view of the whole) and FIG. 22 (conceptual sectional view of the purification rotation circulation connecting portion) using the charcoal / pH buffer adjuster kneaded granular material (MS in FIG. 1) of the present invention. A closed aquatic organism circulation purification pond (Wt) for gardens, courtyards and showrooms can be constructed. The construction structure is the application of FIG. 13 (plan view) and FIG. 15 (cross-sectional view).

  At the stage of charcoal / pH buffer adjuster kneaded resin mass (M in Fig. 1) before crushing and crushing, lava-like rock ecological art as shown in Fig. 8, Fig. 9, Fig. 11, Fig. 12, and Fig. 14 A shape is made. This is a lava-like panel Mb (Figs. 8, 9, 12, 14 and 19) Lava-style gardening pot Mc (Figs. 10 and 11) Lava-style rock Md (Fig. 19). It is useful for the exterior and the like. As a prior art of a garden pot containing lava particles, there is Patent Document 12, which is a synthetic processed product of lava particles and cement particles and is heavy. The charcoal / pH buffer adjuster kneaded resin mass (M in Fig. 1) of the present invention cannot be made in the same shape as a natural lava stone. It looks like the surface of the skin (Mb1), is light in weight, and can be used as a panel on which moss (P7) grows, as a flowerpot for gardening, or as a lava-style rock.

It is a flowchart for demonstrating the manufacturing method of the charcoal and pH buffer adjustment agent kneading | mixing granular material (MS) in connection with this invention. Charcoal / pH buffer adjuster mixed resin lump (M) prepared by adding pH buffer adjuster (α) to resin waste (R) and plant material (P) according to the present invention was slowly cooled and crushed. It is a schematic image figure of artificial soil (MSa) for pH buffer conditioner mixed plant growth made by adding and mixing organic fertilizer (Y) to charcoal / pH buffer conditioner mixed granular material (MS). It is a schematic sectional drawing for demonstrating the growing method using the charcoal and pH buffer adjustment agent mixed plant cultivation artificial soil (MSa) using FIG. Fig. A is a seed planting and Fig. B is an image of the grown plant. It is the implementation photography figure (tomato) of FIG. Fig. 4 is an implementation photograph (bitter gourd) separate from Fig. 4, comparing the difference in growth between planter natural soil 5 and hydroponic pot (Wp) for charcoal and pH buffered artificial soil for mixed plant cultivation (MSa). Yes. FIG. 6 is another implementation photograph (melon) different from FIG. 5. It is an implementation photograph figure (potato) different from FIG. It is an image figure of the eco-art shape object (lava-like panel Mb) shape | molded with the charcoal and pH adjuster kneading | mixing resin lump (M) in connection with this invention. It is the implementation photography figure of the lava-like surface of the lava-like panel (Mb) of FIG. It is an image figure of the eco-art shape object (lava wind garden pot for plant cultivation Mc) shape | molded with the charcoal and pH adjuster kneading | mixing resin lump (M) in connection with this invention. It is the implementation photography figure of the lava wind gardening pot (Mc) of FIG. Planted and grown plants (P11, 12), moss (P7) grown on a lava surface, and water tray 6. It is a photograph figure of the Example of the lava-like panel (Mb) of FIG. Moss (P7) growing on the lava surface of the panel, circulating water in the closed circulating water purification pond (W2), and Shiraito waterfall circulating aerated water (W1). It is an explanatory conceptual top view of a closed type circulating water purification pond (Wt) using the purification material (MSb) made from a charcoal / pH adjuster kneaded granular material according to the present invention. It is a photograph figure of the Example of FIG. 13 in connection with this invention. FIG. 2 is an explanatory conceptual cross-sectional view of a closed circulating water purification pond (Wt) using a purification material (MSb) made of charcoal / pH adjusting agent-mixed granular material according to the present invention. FIG. 15 is an implementation photograph different from FIG. 14 (bringing fry immediately before release from a white cocoon egg). Fig. A is a closed circulatory water purification pond (Wt) for breeding eggs using a charcoal / pH adjuster kneaded granular material water purification material (MSb). Fig. B is a charcoal / pH adjuster kneaded granular material water purification. This is a general-purpose ornamental closed-circulation water purification tank using wood (MSb). It is a system explanation conceptual diagram of the air conditioner for houses and buildings using rainwater circulating water by deep geothermal use regenerated energy using the charcoal / pH adjusting agent kneaded granular material water purification material (MSb) according to the present invention. It is a conceptual explanatory drawing of the refrigerant gas type air conditioner currently used which is not the air conditioning system apparatus of FIG. It is an implementation photograph figure of an example of a medaka, a riverina, and a firefly breeding tank in the implementation photograph figure (two-layer type closed circulation water purification pond) different from FIG. It is a conceptual cross-sectional explanatory drawing of the river and lake water circulation purification facility combined with a large permeated water natural deep geothermal regeneration energy using a water purification material (MSb) made of charcoal / pH adjuster kneaded granular material according to the present invention. It is the Example conceptual diagram of the closed-type circular rotation circulating water purification pond for gardens using the water purification material (MSb) made from the charcoal and pH adjuster kneading granular material in connection with the present invention. It is a cross-sectional conceptual diagram of the purification rotation circulation connection part of the rotation circulation purified water of FIG.

  DESCRIPTION OF EMBODIMENTS Embodiments for carrying out the present invention will be described in detail with reference to FIGS. In the following description, first, a method for producing a charcoal / pH adjuster kneaded granular material according to the present invention will be described, and then a method for using the produced charcoal / pH adjuster kneaded granular material will be described.

(Example of manufacturing method)
In Fig. 1, new materials of thermoplastic synthetic resin such as polypropylene, polyethylene or pet can be used, but recycled material (R) is mainly used. Using plant materials (P) such as wheat straw, rice straw, rice husks, wood chips, large sawdust etc. that are biomass but are still discarded as plant materials, this synthetic resin (R) and plant materials (P) A kneaded product (charcoal and charcoal / pH buffer adjusting material) α, which is kneaded and slowly cooled using a kneader (ruder) (1 in FIG. 1) under a pressure of about 50 kg / square centimeter and a temperature of 300 ° C. to 400 ° C. The pH buffer adjusting agent kneaded resin lump M is crushed and pulverized by a crusher (2 in FIG. 1) to produce a charcoal / pH buffer adjusting agent kneaded granular material (MS in FIG. 1). According to the present invention, since the resin (R), the plant material (P), and the salt compound (pH buffer adjusting material) α are kneaded under a temperature condition of 300 ° C. or more and 400 ° C. or less, the plant material is carbonized. In addition, the air permeability, water retention and adsorbability of the kneaded material (charcoal / pH buffer adjuster kneaded resin lump) M can be given to the part with air permeability / water retention and pH buffer adjustment function. Therefore, moss grows on the rock surface of the kneaded material (charcoal / pH buffer adjuster kneaded resin lump) M. Moreover, as an example of the raw material mixing ratio at the time of mixing, it was carried out with thermoplastic synthetic resin (R) 20 to 30%, plant material 40 to 50%, and salt compound about 25% (calcium carbonate, calcium phosphate, etc.).

  In addition, the kneaded product (charcoal / pH buffer adjuster kneaded resin lump) M is crushed and pulverized into particles of about 5 mm or less by a crusher (2 in FIG. 1), and the charcoal / pH buffer adjuster kneaded granular material (MS in FIG. 1) The surface area of charcoal and salt compound is widened and the air permeability, water retention, adsorptivity and pH buffer adjustment function are improved. A in FIG. 2 is the resin waste (R) in FIG. 1A. Charcoal with a wider and higher functionality due to the addition of salt compound (α) to charcoal mixed resin block (Ma) mixed only with plant material (P). The pH buffer adjuster kneaded resin lump (M) is represented in FIG. 2B. In FIG. 2C, the charcoal and pH buffer adjuster kneaded resin lump (M) are crushed and pulverized. Buffer modifier kneaded granular material (MS), charcoal / pH buffer adjuster kneaded granular material (MS) and organic fertilizer (Y) blended with organic fertilizer (Y) in Fig. 2D This shows the production process of artificial soil (MSa) for the growth of mixed plants. Therefore, the artificial soil (MSa) for growing plant with mixed pH buffer adjuster can adjust the air permeability, water retention, adsorptivity, pH buffer adjusting function and soil fertilizer distribution amount to favorable conditions for plant growth environment.

  Moreover, as shown in FIG. 1, first, as the material of the charcoal / pH buffer adjuster kneaded granular material (MS) according to the present invention, resin waste (R), plant material (P) and salt compound (α ). Resin waste (R) is a thermoplastic resin such as polypropylene, polyethylene, pet, etc., and is accepted from scraps, etc. from general molding factories, and plant material (P) is rice straw, rice husk generated by rice cultivation Chips, wood chips, large saw chips, etc. generated by sawing are accepted from general farmers, sawmills, etc., and salt compounds crush mineral salt such as rice husk waste and zeolite at seaside paddy processing plants. It can be obtained by crushing.

Next, the received resin waste (R), plant material (P) and salt compound (α) are put into a kneading machine (1 in FIG. 1), and the pressure is about 50 kg / cm ² and is not less than 300 ° C. and not more than 400 ° C. Kneading under high pressure and high temperature. As a result, the plant material (P) is carbonized, and the resin waste (R), the plant material (P) carbide and the pulverized powder of the salt compound (α) are uniformly mixed and kneaded ( Charcoal / pH buffer adjuster kneaded resin lump) M is produced. The pressure in the kneader (1) is limited to about 50 kg / cm ² if the viscous resin kneaded product (charcoal / pH buffer adjuster kneaded resin lump) M can be extruded and discharged from the kneader (1). Not. Further, the temperature in the kneader (1) is set to 300 ° C. or more and 400 ° C. or less, but if this temperature is too high, energy loss increases, so that the temperature does not completely decompose at the melting point of the thermoplastic resin (R) or more. It is desirable to maintain the value slightly above ° C.

  Next, after the above-mentioned kneaded product (charcoal / pH buffer adjuster kneaded resin lump) M is gradually cooled, it is crushed to 5 mm or less with a pulverizer (2) (13 mm mesh) and a pulverizer (2) (8 mm mesh). It can be pulverized to obtain a charcoal / pH buffer adjuster kneaded granular material (MS).

  In addition, in the said embodiment, although the case where resin waste (R), such as a polypropylene, polyethylene, a pet, was used was demonstrated, resin which is not waste can also be used, and it is attached to plant material (P). , Rice straw, rice husk, wheat straw, chips, wood chips, large sawdust, etc., which are usually discarded, but of course, non-waste plant materials can also be used, and salt compounds (α) can also be used. Various mineral salt crushed and pulverized powders can be used.

  As described above, according to the present invention, it is possible to produce a charcoal / pH buffer adjusting agent kneaded granular material (MS) from a kneaded material (charcoal / pH buffer adjusting agent kneaded resin lump) M while effectively using waste. it can.

The charcoal / pH buffer adjuster kneaded granular material (MS) obtained as described above has a high water retention of at least 30% and is pulverized to 5 mm or less.・ High water retention and adsorptivity and pH buffer adjustment function,
Since the functional character of the charcoal / pH buffer adjuster kneaded granular material (MS) is charcoal / pH buffer adjuster kneaded resin,
1) Personality with high water retention.
2) Personality with high air permeability.
3) Personality with high adsorptivity.
4) A characteristic of stable pH adjustment of water.
5) Various salt compounds can be added, and the pH adjustment range of water can be changed.
6) Harder than single charcoal, has high granular shape maintenance strength, and can keep large contact area of material (MS).
7) High shape maintenance ability and high recyclability.
Due to the characteristics described in 1), 2), 3), 4), 5), 6), and 7) above, the charcoal / pH buffer adjuster-mixed granular material (MS) has a functional character with high water and air purifying ability,
1] Granules for plant cultivation suitable for hydroponics (artificial soil MSa for cultivation of mixed plants with pH buffer adjuster) (Example 1 of usage method)
2] Circulation purification pond (Example 2 of usage method) using water purification granular material (purification base material MSb) suitable for water purification
3] It can be used for high water purification ability, shape maintenance ability and recyclability (Usage Example 3).
In addition, the charcoal / pH buffer adjuster kneaded resin mass (M) has air permeability, water retention, bactericidal properties, and pH buffer adjustment function than ordinary clay pots and plastic pots,
4] Lava-like panel with moss (Mb), lava-style gardening pot (Mc) and lava-style rock (Md) (Example 4 of usage method) Eco-art made of charcoal / pH buffer adjuster kneaded resin with high functionality Become a shape.

(Example 1 of usage)
Next, a method of using the charcoal / pH buffer adjusting agent kneaded granular material (MS) of the present invention will be described with reference to FIGS.

The charcoal / pH buffer adjuster kneaded granular material (MS) of the present invention can be used as a plant growing granular material (pH buffer adjuster kneaded plant artificial soil MSa).

  Fig. 2 represents the artificial soil (MSa) for growing plant with mixed pH buffer adjuster mixed with charcoal / pH buffer adjuster mixed granular material (MS) and organic fertilizer (Y). Since the buffer conditioner-mixed granular material (MS) is heat-treated at about 300 ° C, the original charcoal / pH buffer adjuster-mixed granular material (MS) itself does not contain nutrients necessary for plants. It is necessary to mix with natural soil, or to mix charcoal / pH buffer adjuster kneaded granular material (MS) and organic fertilizer (Y). Fig. 3A shows a net-like bottomed frame (WP1), C is a basin box (WP2), and the net-like bottomed frame (WP1) overlaps and fits on top of the basin box (WP2). This is a planting box (WP) for hydroponics. In this case, since the roots of the cultivated plants are backlit, the light outside the overlapped joints between the net-shaped bottom frame (WP1) and the top of the basin box (WP2) is used for hydroponics. It must be installed so as not to be plugged into the garden box (WP).

  Fig. 3A shows water (W) on a basin box (WP2), and a net-like bottomed frame (WP1) having a mesh-like bottom above it, artificial soil (MSa) for growing the pH buffer adjusting agent mixed plant. Is spread to a thickness of about 10 to 15 cm, and plant seeds (Se) are seeded therein. Since the charcoal / pH buffer adjuster mixed granular material (MS) itself does not contain fertilizer, if only charcoal / pH buffer adjuster mixed granular material (MS) is used as a granular material for plant growth, the fertilizer should be charcoal. -It is necessary to mix with pH buffer adjuster kneaded granular material (MS).

  In addition, when hydroponics is performed in the above-mentioned state, if water is sufficiently supplied in advance, the artificial soil (MSa) for growing a pH buffer adjuster mixed plant has a high water retention rate and is required for germination of seeds (Se). Moisture and nutrients from the above fertilizer can be given to the seed (Se), which promotes germination of the seed (Se) and contributes to the growth after germination. And as shown to FIG. 3B, when a plant (P1) grows and a root reaches water (W), a water | moisture content can be replenished directly from water (W) and it grows smoothly.

  When the seeds (Se) germinate and the plants (P1) grow, the plant-grown granular material for pH buffer adjuster mixed plant growing artificial soil (MSa) contains carbides and salt compounds, It has a water purification effect. When a water sample soaked with the charcoal / pH buffer adjuster kneaded granular material (MS) is collected and subjected to chemical analysis, no characteristic element is detected, and the pH is 7 at 20 ° C. 0.0 neutral range. In addition, as long as there is water in the lower basin box (WP2), the water that has evaporated evaporates through the net above the water in the artificial soil (MSa) due to the nature of the water retaining resin.

  FIG. 4 is a photograph of hydroponics using the artificial soil (MSa) for growing the above-mentioned pH buffer adjusting agent mixed plant of Tomato Momotaro Fukusei (P2). P2a indicates the leaves of Tomato Momotaro Fukusei (P2), WP indicates the hydroponic pot, WP3 indicates the support rod of the growing plant Tomato Momotaro Fukusei (P2), MSa indicates the artificial soil for growing the pH buffer adjuster mixed plant ing.

  FIG. 5 is a photograph of the practice cultivation of bitter gourd (Igauri P3). WP is a hydroponic pot, 3 is a bitter gourd support bar, 4 is bitter gourd grown in natural soil, 5 is a planter containing the natural soil, and the growth state is when the bitter gourd growth in natural soil is XX line The growth of the bitter gourd (P3) of hydroponics on the artificial soil (MSa) for growing mixed plants with the pH buffer adjuster of the present invention almost reached twice the roof of the building.

  Moreover, FIG. 6 is a cultivation execution photograph of the melon (P4) using the artificial soil (MSa) for cultivation of a mixed plant of the pH buffer adjusting agent of the present invention, and is a hydroponic pot (WP) and a support rod (WP3).

  Furthermore, FIG. 7A is a cultivated photographic image of potato (P5) using the artificial soil (MSa) for growing a plant mixed with pH buffer of the present invention, and FIG. 7B is an explanatory diagram. Stem (P51), leaf (P52), hydroponics pot (WP), net-shaped bottomed frame (WP1), basin box (WP2), basin box water (W), basin box (WP2) depth h1 is 15 to 20 cm and the thickness of the artificial soil layer is 10 to 15 cm.

  Although not shown in the drawings, the artificial soil (MSa) for growing plant with mixed pH buffer regulator of the present invention (MSa) has various air permeability (such as clay soil, desert soil, soil with poor water quality, etc.) Helps improve water retention, soil pH, and soil water purification.

(Example 2 of usage)
Moreover, the charcoal / pH buffer adjuster kneaded granular material (MS) of the present invention can be used as a purified water granular material (purified base material MSb).

A method of using the charcoal / pH buffer adjuster kneaded granular material (MS) as a water purification substrate (MSb) will be described. FIG. 13 is a schematic plan view of an aquatic organism breeding tank (Wt) with a purification tank for closed system circulating water, and FIG. 15 is a sectional view of its purification function part. In the sedimentation tank (Wt1), nylon mat (8) filtration tank (Wt2) and adsorption / liquid filtration tank (Wt3), the purified granular material (purification base material MSb) is stored and installed. Wt4 is a water wheel, pump, aeration, Wt6 is a circulating water channel, Wt5 is a breeding tank, Wt7 is a circulating water circulation outlet, Wt8 is an inlet for a purification function of circulating water, 7 is a circulating water temperature controller (chiller), Wt10 wire mesh Metal plate, Wt12 is the cleaning valve, Wt9 is the water replenishment passage, Wt16 is the lower partition plate of the purification function unit, Wt11 is the upper partition plate of the purification function unit, Wt13 is the circulating water circulation pipe, Wt14 is the air vent hole, Wt15 (W1) Indicates purified / aerated circulating water.
The charcoal / pH buffer adjuster mixed granular material (MS) of the present invention is used for the purification granular material (purification base material) in the adsorption / liquid filtration tank (Wt3) responsible for the most important function of the circulating water purification function tank. MSb) is an important water purification system that helps to absorb bacteria that are stored and installed and cannot be removed by the wastewater nylon mat filter tank (Wt2) and bacteria that detoxify and detoxify nitrite nitrogen. Controls the function as a substrate (MSb).

FIGS. 14 and 16 are photographs of the closed-type circulating water purification tank (Wt) using the charcoal / pH buffer adjuster-mixed granular material (MS) of the present invention, Wt1 to 4 being the septic tank, and Wt4 being the circulation. Water tube, 8 is nylon mat, MSb is water purification granular material (purification base material), St1 and St2 are aquatic organisms or large dust removal nets, Wt4 is a magnet pump, Wt13 circulating water circulation pipe, Wt14 is an air vent hole, P7 is Moss, P13 is a lava-style garden pot plant, Mc is a lava-style garden pot, W2 is circulating water, W1 (Wt15) is a (waterfall type) aerated circulating purified water, Mb is a lava-like panel, and F1 is a birch breeder It is a fry just before the release. The present invention is the first to succeed in breeding white rabbit eggs in a closed circulating water septic tank (Wt). The concentration of nitrite nitrogen in water that can be used to grow aquatic organisms is 0.26 ppm or less. Nitrite nitrogen concentration of water inhabited by aquatic organisms in a closed circulation water septic tank (Wt) using the charcoal / pH buffer adjuster mixed granular material (MS) of the present invention is 0.12 ppm. The pH was 7.2. FIG. 19 is also a photograph of an embodiment of the closed circulating water purification tank (Wt) using the charcoal / pH buffer adjuster mixed granular material (MS) of the present invention. The tank (pond) is above (45 Wt1) and below (46 Wt5). Stage type.

(Example 3 of usage)
Next, considering the charcoal / pH buffer adjuster mixed granular material (MS) of the present invention in combination with the ability to purify circulating water and the granular shape maintenance strength, as shown in FIG. A building air conditioner can be constructed as a refrigerant circulating water / natural energy utilization system using a circulating purification system for rainwater stored water. This will be described below.
In FIG. 17, 9 is rainwater, 10 is a solar water heater (about 30 ° C), 11 is a circulating water pipe to the solar water heater, 12 is an eaves receiving rainwater, 13 is a rainwater inflow pipe, 14 is a faucet, 15 is Water pump, 16 housing, 17 air conditioner indoor unit, 18 radiator, 19 water channel switching device, 20 underground storage tank (spare tank), 21 deep block (reservoir reinforcement part), 22 garden faucet Water distribution channel, 23 is a geothermal (about 16 ℃) energy use tank, h2 is about 8m, L2 is about 30cm, 24 is a section of underground ground, 25 (Wt4) is a pump for pumping regenerated circulating water, 26 is a gravel layer , 32 is a flow of conditioned air, Wt1 to 4 are circulating water purifiers, St3 is a strainer, L1 is about 10 cm, and Wt6 is a (refrigerant) conditioned air circulating water flow path. By using the water purification granular material (purification base material MSb), which is the charcoal / pH buffer adjuster mixed granular material (MS) of the present invention, the natural regenerative energy of geothermal and solar heat is converted into a global environment using natural circulating water as a medium. It is possible to create an air conditioning system for houses and buildings that consumes less electricity.

  FIG. 18 is a conceptual cross-sectional view of an air conditioner (air conditioner) using a conventional refrigerant gas (G) that is already widely used in many houses. 16 is a house, 27 is an outdoor unit, 28 is room temperature air, 29 is an indoor unit heat converter, 30 is a filter, 31 is a fan, 32 is an air-conditioning airflow, 33 is a dew condensation / dehumidifier, 34 is a room temperature exhaust medium passage pipe , G: Medium flow, 35: Condensation / dehumidification water discharge pipe, 36: Discharge liquid, 37: Medium passage pipe after discharge of indoor temperature, 38: Outdoor unit, 39: Outdoor unit heat converter, 40: Outdoor unit heat A discharge fan, 41 is outdoor heat release, 42 is a heat pump unit, and 43 is a hot water storage tank unit. Although the heat pump unit (42) and hot water storage tank unit systems have been improved in terms of environment and electricity consumption, these conventional air-conditioning systems using refrigerant gas (G) still consume a large amount of electricity. Does not use any renewable energy.

  Furthermore, considering the charcoal / pH buffer adjuster kneaded granular material (MS) of the present invention by utilizing the ability as a purification base for circulating water and the function of maintaining the granular shape, the charcoal / pH buffer adjuster kneaded granule The material (MS) was 0.5kg to 1.0kg, and over 50L of water could be repeatedly purified for more than one year. Further, the charcoal / pH buffer adjuster kneaded granular material (MS) has a high shape maintaining ability and is easy to recycle and replace. When the above-described properties as a purification base material, the gravel layer passage infiltration method, and geothermal regeneration energy are used in combination, it is possible to purify and regenerate water in polluted rivers and polluted lakes, as shown in FIG. 24 is underground ground profile, 48 is polluted lake, 48a is eutrophication lake surface foam, 49 seepage water, 50 is first gravel layer, 51 is lake infiltration water flow, 52 is second gravel Layer, 53 is a vertical slot, St4 is a strainer, 54 is a primary natural purification geothermal cooling lake infiltration water, 55 is a closure lid of a lake natural infiltration water primary natural purification geothermal cooling tank, 25 (Wt4) is a pumping pump , 56 is the primary natural purification geothermal cooling lake permeated water pumping passage, 57 is the lake permeated water purified water flow path, [Wt1 is the sedimentation tank, Wt2 is the nylon mat filtration tank, Wt3 is the adsorption / flow filtration tank purification granular material ( Purification base MSb)] secondary artificial septic tank, 58 secondary filtered purified water geothermal cooling storage tank, 59 filtered filtered water flow path, 60 filtered filtered water pumping pipe, 61 (Wi4) pumped filtered purified water Pump, 62 lake purification water lake return channel, 63 (Wt15) represents purification / aeration return water, 63a represents diffusion purification of purification / aeration return water.

(Example 4 of how to use)
Furthermore, the charcoal / pH buffer adjusting agent kneaded resin mass (M) has air permeability, water retention, bactericidal properties, and pH buffer adjusting function, and is shown in FIGS. 8, 9, 10, 11, 12, and 14. As shown in FIG. 19, a lava-like panel with moss (Mb), a lava-style gardening pot (Mc), and a lava stone-like skin rock (Md) with high functionality charcoal and pH buffer adjuster kneaded resin eco-art shape You can shape things.

  FIG. 8 is a lava-like panel (Mb), which is an eco-art shape made of a charcoal / pH buffer adjuster kneaded resin mass (M) having air permeability, water retention, bactericidal properties, and pH buffer adjustment functions. . Mb1 is a shelf-like structure that protrudes and projects on the surface of the lava panel, on which moss balls (P6) on which plants P8 have grown are placed. The moss balls (P6) are rooted in a shelf-like structure (Mb1), P7 indicates a moss plant, and P3-6 and P8-14 indicate other growing plants. The lava surface (Mb1) of the lava-like panel (Mb) of FIG. 9, the lava-style garden pot (Mc) of FIG. 11, the moss (P7) grown on the surface of the lava-style garden pot (Mc), and the lava of FIG. Lava-like garden pot (Mc) and lava-like panel surface (Mb) with moss (P7) and plant (P13) in Fig. 14 planted on lava skin surface (Mb1) of lamellar panel (Mb) A shelf-like structure (Mb1) and lava stone that are formed in a protruding shape from a lava-like panel (Mb) with moss (P7) grown on (Mb1), and the moss (P7) and growing plant (P14) in FIG. Lava stone-like skin rock (Md) and lava-like panel rock (Mb) and lava-style gardening pots (Mc) are falling into the shape of rock-like rock (Md) and waterfall-like circulating water 44 (Wt15 / W1) ) And lava stone-like skin rock (Md).

  Thermoplastic synthetic resin (R) typified by polypropylene, polyethylene or pet of the present invention and plant material (P) typified by wheat straw, rice straw, rice husk, wood chips, large sawdust and salt compound (α) at 300 ° C. or more The charcoal / pH buffer adjuster kneaded resin mass (M), which is characterized by being kneaded under the following temperature conditions, is a charcoal / pH buffer adjuster kneaded resin, so that it is more breathable, bactericidal, and pH buffered than ordinary pots. It has an adjustment function, and has higher art and functionality as a plant gardening pot than other gardening pots. It can be molded into lava-like panels (Mb), lava-style gardening pots (Mc) and lava-stone-like skin rocks (Md), which are eco-art shapes made of the charcoal / pH buffer adjuster kneading resin. Moss (P7) grows on the lava skin (Mb1), which is the lava wind surface, and the roots of the growing plant (P14 in FIG. 19) grow.

  At this time, when the artificial soil (MSa) for growing a plant mixed with the pH buffer adjuster of the present invention is used as the plant growth soil, it seems that diseases and pests do not reach the growing plant. In addition, it is difficult to form the eco-art shape (Mb / Mc / Md) into the same shape, but it looks like it is made of natural lava stone, and it has a lava-like appearance.

  Examples 1 to 4 of the above usage examples (Example 1) Charcoal / pH buffer adjuster kneaded granular material (MS) Granular material for plant growth (pH buffer adjuster mixed plant created from granular diameter of 3 mm or less Artificial soil MSa) and (Example 2) Charcoal / pH buffer adjuster kneaded granular material (MS) Water purification granular material (purification base material MSb) created from granular diameter 3 mm to 5 mm or less (Example 3) ) Water purification granular material (purification base material MSb), combined use of gravel layer osmosis water and geothermal regeneration energy to purify and regenerate water in contaminated rivers and lakes [Example 4] Charcoal and pH buffer By integrating eco-art shapes created with the resin kneading resin mass (M) and their technology, it is possible to construct a closed circulation water purification pond (Wt) for gardens, courtyards and showrooms. FIG. 21 shows a closed-system circular circulating water purification pond (Wt), and the water flow (62) circularizes the closed-system circular circulating water purification pond (Wt) from the falling pond part (65) of the aeration input water 61 (Wt15). It flows to the circulating water infiltration geothermal regeneration energy pumping pond (64), and is circulated back to the fall pond part (65) again through the purified water geothermal regeneration energy water circulation pipe 60 (Wt13) by the pumping pump 25 (Wt4). . FIG. 22 flows to the permeated geothermal regeneration energy pumping pond (64) of the closed system circulating water of FIG. 21, and through the purified water geothermal regeneration energy water circulation pipe 60 (Wt13) by the pumping pump 25 (Wt4), the fall pond part (65) again. It is a secondary cross section of the circulating water reproduction | regeneration purification part which returns to FIG. Strainer 1 (63), gravel permeation filtration layer (66), strainer 2 (St4), vertical groove hole (67), gravel (68), ground underground section (69), circulating percolated geothermal regenerative energy water (70) The closed system circulation septic tank (Wt1 to 3), the rock (71), the bridge (72), the table (73), the waterside plant (P17 / 18/19/20), and the tree (P15 / 16). The size of the closed circular circulating water purification pond (Wt) can be changed according to the size of the satoyama, park, garden, courtyard, and showroom. In addition, when constructing a closed circular circulating water purification pond (Wt) indoors, a chiller may be installed in an air conditioning facility or circulation pond at room temperature instead of installing an infiltration geothermal regeneration energy device. That is, a large-scale closed-system circular circulating water purification pond (Wt) can be constructed by using all the embodiments of the present invention and the technology thereof.

  Purification of rivers and lakes, fish farming and rearing on land, rooftop greening of cities and high-rise buildings, air purification and carbon dioxide reduction, heating city cooling and reduction of updrafts, natural recovery, no impact of weather It can be used for industrialization of agricultural chemical-free agriculture and expansion of multi-dimensional arable land area.

DESCRIPTION OF SYMBOLS 1 Kneading machine 2 Pulverizer P Vegetable material R Resin waste α pH buffer adjusting material M Kneaded material (charcoal / pH adjusting agent kneaded resin lump)
MS Charcoal / pH adjuster kneaded granular material
MSa Artificial soil for charcoal / pH buffer adjuster mixed plant cultivation
MSb Charcoal / pH adjuster kneaded granular material Water purification material
Wp hydroponic pot
WP1 Net-like bottom frame
WP2 basin box Se seed P1 plant W water
Wt closed circulation water purification pond
St strainer

Claims (6)

Pressure about 50Kg / cm ² , Kneading a material composed of a crushed and ground powder of a thermoplastic synthetic resin, a plant material, and a salt compound containing a mineral salt using a kneader at a high pressure and high temperature of 300 ° C. to 400 ° C. And synthetic resin decomposition and molecularization at the same time, the carbonized particles of the plant material and the crushing and pulverization powder of the salt compound as the pH buffer adjustment material are simultaneously proceeded with the small synthetic resin. Pressure of 50 kg / cm at which the resin kneaded material with viscosity adhered to can be extruded and discharged from the kneader. ² A charcoal / pH buffer adjusting agent kneaded resin lump characterized by being produced by being discharged from a kneader at a certain degree and gradually cooled and solidified.
Under high pressure and high temperature, using a kneading machine, kneading a material composed of a crushed and pulverized powder of a thermoplastic synthetic resin, a vegetable material and a salt compound containing a mineral salt, carbonization of the vegetable material and decomposition of the synthetic resin Simultaneously, the carbonized particles of the plant material and the crushing and pulverizing powder of the salt compound that is the pH buffer adjusting material are simultaneously progressed with a synthetic resin that has been reduced in molecular weight, and has a viscosity that is adhered to each other. When the resin kneaded product is extruded and discharged from the kneader, the discharge pressure is 50 kg / cm if the viscous resin kneaded product can be extruded and discharged from the kneader. ² 2. The charcoal / pH buffer adjuster kneaded resin mass according to claim 1, wherein the mass is discharged by a pressure not limited to a degree and then solidified by slow cooling.
The charcoal / pH buffer adjusting agent kneaded resin lump is obtained by simultaneously carbonizing the plant material and decomposing and lowering the molecular weight of the synthetic resin with the kneader, and by combining the carbonized particles of the plant material with the small molecule synthetic resin. Resin kneaded product that has been gradually cooled and solidified by discharging the kneaded connection of the crushed and pulverized powder of the salt compound, which is a pH buffer adjusting material, at the same time, and discharging the resin kneaded material having a viscosity adhered to each other at a pressure capable of being pushed out and discharged from the kneader. The charcoal / pH buffer adjuster kneaded resin lump according to claim 1.2, wherein: The charcoal / pH buffer adjusting agent kneaded resin lump is a charcoal / pH buffer adjusting agent kneaded resin lump that can be crushed into particles with a crusher, and the charcoal / pH buffer adjusting agent kneaded resin lump is granulated in accordance with the intended use. The charcoal / pH buffer adjuster kneaded resin mass produced by crushing the formed charcoal / pH buffer adjuster kneaded resin mass and having water retention, air permeability, adsorptivity and pH buffer adjusting power, A charcoal / pH buffer adjuster-mixed granular material characterized by having a higher shape maintaining power.
The charcoal / pH buffer adjusting agent kneaded resin material used by crushing the charcoal / pH buffer adjusting agent kneaded resin lump into a granule according to the purpose of use is the particle size of the granular material to be crushed by a crusher, The charcoal / pH buffer adjuster kneading product according to claim 4, which is produced by crushing a charcoal / pH buffer adjuster kneaded resin mass, which can be selectively used as a water recycle water purification base material and a soil improvement material or artificial soil. Granular material.
The thermoplastic synthetic resin is made of polypropylene, polyethylene or polyethylene terephthalate, the plant material is made of wheat straw, rice straw, rice husk, wood chips, and sawdust, and the crushed and ground powder of the salt compound is a salt compound in accordance with the intended use. Carbonate / phosphate compound ground powder, rice husk ground powder, limestone carbonate mineral ground powder, aluminosilicate mineral ground powder, borosilicate mineral ground powder, borate mineral ground powder The charcoal / pH buffer according to claims 4 and 5, which is produced by crushing a charcoal / pH buffer adjusting agent kneaded resin lump, wherein the pH buffer adjusting material is a salt compound such as Conditioner kneaded granular material.

Corrected as above.
I think that the points pointed out by the examiner's teacher have improved.
Thank you for your permission.