JP6017283B2 - Polishing tool - Google Patents

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JP6017283B2
JP6017283B2 JP2012262964A JP2012262964A JP6017283B2 JP 6017283 B2 JP6017283 B2 JP 6017283B2 JP 2012262964 A JP2012262964 A JP 2012262964A JP 2012262964 A JP2012262964 A JP 2012262964A JP 6017283 B2 JP6017283 B2 JP 6017283B2
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abrasive
polishing
lump
base material
polishing tool
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JP2013136146A (en
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達也 鹿野
達也 鹿野
井上 純
純 井上
比呂志 野口
比呂志 野口
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Aion Co Ltd
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Description

本発明は、研磨用具、特にスポンジのような樹脂発泡体の表面に、研磨砥粒を保持させてなる研磨用具に関する。さらに詳しくは、清掃研磨面に付着した汚れなどの夾雑物を、水を供給しながら除去するのに適した研磨用具に関する。   The present invention relates to a polishing tool, and more particularly to a polishing tool in which polishing abrasive grains are held on the surface of a resin foam such as a sponge. More specifically, the present invention relates to a polishing tool suitable for removing contaminants such as dirt adhering to a cleaning polishing surface while supplying water.

家庭内のキッチンシンク、バス、トイレなどの設備や備品、自動車や電車やバスなどの車両窓ガラス、その他陶磁器などに付着した汚れを除去することに用いることのできる研磨用具が従来より種々提案されている(たとえば、特許文献1、特許文献2、特許文献3、特許文献4)。   Various kinds of polishing tools that can be used to remove dirt attached to equipment and equipment such as kitchen sinks, baths, and toilets in the home, vehicle window glass such as cars, trains, and buses, and other ceramics have been proposed. (For example, Patent Document 1, Patent Document 2, Patent Document 3, and Patent Document 4).

上掲の各特許文献のうち、特許文献1によると、手で持ちやすい大きさの吸水性のない独立気泡型スポンジと、吸水性のあるシート状の連続気孔型スポンジと、微粒子の砥材を付着させた研磨布紙シートと、をこの順に重ねて一体化させたクリーニング用具が提案されている。また、この特許文献1では、研磨布紙シートが通水用の多数の孔又はスリットを備えること、砥材にダイヤモンドの微粒子を用いること、などについても言及されている。そして、このクリーニング用具によると、独立気泡型スポンジを手に持ち、研磨布紙シートに水をつけて清掃対象面に擦り付けると、研磨布紙シート上の砥材で研磨対象面(清掃研磨面)が研磨されて汚れが落ち、連続気孔型スポンジのクッション作用により清掃研磨面を損傷する危険が少なく、連続気孔型スポンジの保水作用によって、清掃研磨作業を連続的に行う場合でも水をつけ直す回数が少なくて済む、とされている。さらに、連続気孔型スポンジの多数の孔又はスリットを通して連続気孔型スポンジと清掃研磨面との間で水が行き来するので、連続気孔型スポンジの保水性が十分に生かされる、とも説明されている。   Of each of the above-mentioned patent documents, according to Patent Document 1, a closed cell type sponge without water absorption having a size that can be easily held by hand, a sheet-like continuous pore type sponge with water absorption, and a fine abrasive material. There has been proposed a cleaning tool in which the adhered abrasive cloth paper sheets are integrated in this order. In addition, this Patent Document 1 also mentions that the abrasive cloth paper sheet has a large number of holes or slits for water passage, and that diamond fine particles are used for the abrasive. And according to this cleaning tool, if you hold the closed cell type sponge in your hand, rub the abrasive cloth paper sheet with water and rub it against the surface to be cleaned, the abrasive surface on the abrasive cloth paper sheet (cleaning abrasive surface) The number of times water is re-applied even when cleaning and polishing work is performed continuously due to the water retention function of the continuous pore-type sponge. It is said that there will be less. Furthermore, it is also described that water flows back and forth between the continuous pore type sponge and the cleaning polishing surface through a large number of holes or slits of the continuous pore type sponge, so that the water retention of the continuous pore type sponge is fully utilized.

特許文献2には、手で持ちやすいサイズにカットした独立気泡型スポンジの表面に研磨布紙シートを貼着一体化したガラス等のクリーニング用具が提案されている。そして、このものによると、研磨布紙シートによって水に濡れたガラス表面(清掃研磨面)を研磨すると、ガラス表面に付着して結晶化した金属元素等の汚れが除去される、とされている。また、このクリーニング用具の反対側のスポンジ面をガラス表面に押し付けてガラス表面の水分を掻き取ったり、ガラス表面の水分を薄い水膜にして乾きやすい状態にすることができる、とされている。   Patent Document 2 proposes a cleaning tool such as glass in which an abrasive cloth paper sheet is bonded and integrated on the surface of a closed-cell sponge cut into a size that can be easily held by hand. And according to this, when the glass surface wet with water (cleaning polishing surface) is polished by the abrasive cloth paper sheet, dirt such as crystallized metal elements adhering to the glass surface is removed. . In addition, the sponge surface on the opposite side of the cleaning tool can be pressed against the glass surface to scrape off the moisture on the glass surface, or the moisture on the glass surface can be made into a thin water film to make it easy to dry.

特許文献3には、研磨効果を持つ微粒子を単独で又は結合材と共にスポンジに固定させた研磨材入りスポンジからなる洗浄材が提案されている。この洗浄材によると、使用中に被洗浄物に接触している表層の微粒子だけが洗浄に作用し、被洗浄物に接触していないスポンジ内部からの脱落により余分な微粒子が発生することがないので、微粒子による洗浄効果を保ちながら、洗浄後の微粒子による汚染を回避することができる、とされている。また、スポンジには、連続あるいは独立した気孔を内部に有するポリビニルアセタール系スポンジが用いられ、微粒子には酸化セリウムが採用されている。   Patent Document 3 proposes a cleaning material composed of a sponge containing an abrasive material in which fine particles having an abrasive effect are fixed to a sponge alone or together with a binder. According to this cleaning material, only fine particles on the surface layer that are in contact with the object to be cleaned during use act on the cleaning, and no extra fine particles are generated by dropping off from the sponge that is not in contact with the object to be cleaned. Therefore, it is said that contamination by fine particles after washing can be avoided while maintaining the cleaning effect by fine particles. As the sponge, a polyvinyl acetal sponge having continuous or independent pores is used, and cerium oxide is used as the fine particles.

特許文献4には、アルミノシリケート研磨材粒子を固着させた不織布でなる研磨材料を、スポンジ基材に接着することによって構成した研磨材料についての記載がある。   Patent Document 4 describes a polishing material constituted by adhering an abrasive material made of a nonwoven fabric to which aluminosilicate abrasive particles are fixed to a sponge substrate.

実用新案登録第3166009号公報Utility Model Registration No. 3166209 特開平6−154127号公報JP-A-6-154127 特開平10−130634号公報JP-A-10-130634 特開2005−206675号公報JP 2005-206675 A

上掲の各特許文献によって提案されている研磨用具のうち、特許文献1、同文献2、同文献4に記載されているものは、布紙や不織布といったシート体の一面全体に研磨材としての微粒子を満遍無く一様に散在させている点で共通し、また、微粒子を満遍無く散在させたシート体をスポンジでなる基材の片面の全体又は略全体に貼着させているという点でも共通している。また、スポンジでなる基材に含ませた水を清掃研磨面へ補給しながら、研磨材の微粒子を散在させた上記シート体の一面で清掃研磨面を擦るという作業を通じて、その清掃研磨面を清掃研磨するという点でも共通している。   Among the polishing tools proposed by each of the above-mentioned patent documents, those described in Patent Document 1, Document 2, and Document 4 are used as an abrasive on the entire surface of a sheet body such as cloth or nonwoven fabric. Common in that fine particles are evenly and uniformly dispersed, and the sheet body in which fine particles are uniformly dispersed is adhered to the whole or substantially the entire surface of a sponge base material. But it is common. In addition, the cleaning and polishing surface is cleaned through the operation of rubbing the cleaning and polishing surface with one surface of the above-mentioned sheet body in which fine particles of the abrasive are scattered while supplying water contained in the sponge base material to the cleaning and polishing surface. It is common in that it is polished.

これに対し、特許文献3によって提案されている研磨用具は、基材としてのスポンジの表層部分及び内層部分に研磨効果を持つ微粒子を固定させている、という点で、特許文献1、同文献2、同文献4に記載されているものとは相違している。その反面で、基材としてのスポンジの一面では、そのスポンジの表層部分に固定されている微粒子が一面全体に亘って露出していて、そのようなスポンジの一面で清掃研磨面を擦ることによって、その清掃研磨面を清掃研磨するという点では、特許文献1、同文献2、同文献4に記載されているものと共通しているということが云える。   On the other hand, in the polishing tool proposed by Patent Document 3, the fine particles having a polishing effect are fixed to the surface layer portion and the inner layer portion of the sponge as a base material. This is different from that described in the document 4. On the other hand, on one surface of the sponge as a base material, fine particles fixed to the surface layer portion of the sponge are exposed over the entire surface, and by rubbing the cleaning polishing surface with one surface of such a sponge, It can be said that the cleaning polishing surface is the same as that described in Patent Document 1, Patent Document 2, and Document 4 in terms of cleaning and polishing.

しかしながら、特許文献1、同文献2、同文献3及び同文献4に共通する清掃研磨作用、すなわち、研磨材の微粒子が散在しているシート体又はスポンジの一面で清掃研磨面を擦るという作業を通じて発揮される清掃研磨作用では、汚れの掻取り作用が個々の極小の微粒子だけによって発揮されるに過ぎないため、十分な掻取り作用が発揮されずに汚れが清掃研磨面に残りやすかったり、脱落した微粒子が作業後の清掃研磨面に残留しやすかったりするという問題があった。   However, the cleaning and polishing action common to Patent Document 1, Document 2, Document 3, and Document 4, that is, through the operation of rubbing the cleaning polishing surface with one surface of a sheet body or sponge in which fine particles of the abrasive are scattered. In the cleaning and polishing action that is exhibited, the scratching action of the dirt is only exerted by the individual fine particles, so that the dirt can easily remain on the cleaning and polishing surface without sufficient scraping action. There is a problem that the fine particles that remain are likely to remain on the cleaned and polished surface after work.

また、ガラスなどの清掃研磨面に微粒子を擦り付けて清掃研磨するときには、清掃研磨面に十分な量の水分を常時供給することが、清掃研磨面の傷付きを抑制したり汚れを効率よく除去したりする上で有効である。しかしながら、特許文献1、同文献2、同文献3及び同文献4のように、シート体やスポンジの一面に微粒子を一様に散在させてあると、シート体やスポンジの表面に存在している通水孔が微粒子によって塞がれてしまうことになる。特に、清掃研磨作用を高めるためにシート体やスポンジの一面に微粒子を高密度で散在させたものでは、シート体やスポンジの表面に存在している通水孔の大部分が微粒子によって塞がれてしまうことなるので、シート体やスポンジから清掃研磨面に十分な量の水分が連続的に供給されにくくなり、清掃研磨面が傷付きやすくなったり汚れが除去されにくくなったりする懸念がある。   In addition, when cleaning and polishing by rubbing fine particles against a cleaning polishing surface such as glass, supplying a sufficient amount of moisture to the cleaning polishing surface at all times suppresses scratches on the cleaning polishing surface and efficiently removes dirt. It is effective in doing. However, as in Patent Document 1, Document 2, Document 3, and Document 4, if the fine particles are uniformly scattered on one surface of the sheet body or sponge, the particles are present on the surface of the sheet body or sponge. The water passage hole is blocked by the fine particles. In particular, in the case where fine particles are scattered on one surface of the sheet body or sponge in order to enhance the cleaning and polishing action, most of the water passage holes present on the surface of the sheet body or sponge are blocked by the fine particles. Therefore, it is difficult to continuously supply a sufficient amount of moisture from the sheet body or sponge to the cleaning / polishing surface, and there is a concern that the cleaning / polishing surface may be easily damaged or dirt may be difficult to remove.

さらに、作業後に清掃研磨面に残った水分を除去することに関して、特許文献2のように、独立気泡のスポンジ面を清掃研磨面に押し付けて水分を掻き取ったり、清掃研磨面の水分を薄い水膜にして乾きやすい状態にする、というものでは、水分が乾いたときに、水分中に不可避的に残留した汚れや微粒子がどうしても清掃研磨面に残ってしまうことになる。この点を解決するためには、吸水性に富む布や不織布を別途用いて、清掃研磨面に残った水分を拭き取って除去するという作業を行うことが必要になる。   Furthermore, regarding removal of moisture remaining on the cleaning and polishing surface after work, as in Patent Document 2, the sponge surface of the closed cell is pressed against the cleaning and polishing surface to scrape off the moisture, or the cleaning and polishing surface has a thin water. In the case of making the film easy to dry, when the moisture is dried, dirt and fine particles inevitably remaining in the moisture always remain on the cleaned and polished surface. In order to solve this problem, it is necessary to perform an operation of wiping and removing the water remaining on the cleaning and polishing surface by using a cloth or nonwoven fabric rich in water absorption.

本発明は以上の状況を改善することを意図してなされたものであって、対象物の清掃研磨面に十分な量の水分を常時供給しながら清掃研磨作業を行うことができ、しかも、研磨作用を発揮する微粒子だけでなく、微粒子の塊によって清掃研磨面に付着した汚れなどの夾雑物を除去することができる研磨用具を提供することを目的とする。   The present invention has been made with the intention of improving the above situation, and the cleaning and polishing operation can be performed while always supplying a sufficient amount of moisture to the cleaning and polishing surface of the object. It is an object of the present invention to provide a polishing tool capable of removing not only fine particles exhibiting the action but also foreign matters such as dirt attached to the cleaning polishing surface by the lump of fine particles.

また、本発明は、金属粒子の作用によって耐用寿命(ライフ)を向上させることのできる研磨用具を提供することを目的とする。   Another object of the present invention is to provide a polishing tool capable of improving the service life (life) by the action of metal particles.

本発明に係る研磨用具は、吸水性を有する基材と、この基材に固定されてその基材の表面に間隔を隔てて散在する多数の研磨砥粒塊と、を備えている。そして、上記基材は、気孔径が30〜200μmであり、気孔率が80〜95%である連続気孔型のポリビニルホルマール樹脂のスポンジでなり、個々の上記研磨砥粒塊がバインダによって結合された多数の研磨砥粒の集合体でなり、その研磨砥粒塊が上記基材の表面から膨出されて正面視ドット形状に形成され、この研磨砥粒塊の上記バインダがスポンジの気孔に入り込むことによってその研磨砥粒塊と基材の表面との接合力が高められていると共に、上記基材の裏面は、その全体が、上記基材の吸水性に基づく吸水面として形成されている。 The polishing tool according to the present invention includes a base material having water absorption properties, and a large number of abrasive grain lumps fixed to the base material and scattered on the surface of the base material at intervals. The base material is a continuous pore-type polyvinyl formal resin sponge having a pore diameter of 30 to 200 μm and a porosity of 80 to 95%, and the individual abrasive grain lumps are bonded by a binder. It consists of an aggregate of a large number of abrasive grains, and the abrasive grain lump is swelled from the surface of the substrate to form a dot shape in front view, and the binder of this abrasive grain lump enters the pores of the sponge. Thus, the bonding force between the abrasive grain lump and the surface of the base material is enhanced, and the back surface of the base material is entirely formed as a water absorbing surface based on the water absorption of the base material.

この構成を備えた研磨用具では、基材の吸水性により、その基材に水分を含ませることが可能であり、しかも、水分を基材から清掃研磨面に常時供給させながら清掃研磨作業を行うことができる。特に、多数の研磨砥粒塊の相互間に位置している基材の気孔から十分な量の水分を供給させることができる。そのため、清掃研磨面に供給される水分によって研磨時に発生する摩擦熱が冷却されるという作用が発揮されるだけでなく、水分が潤滑剤として作用して研磨用具を清掃研磨面でスムーズに動かしやすくなり、さらに、研磨時に発生するスラッジが連続的に洗い流される。また、研磨後には、基材の裏面の全体によって形成されている吸水面を用いて清掃研磨面に残った水分を吸収させたり、水分と共に残留した汚れなどの夾雑物や研磨で発生したスラッジを取り除いたりすることができるので、清掃研磨面に夾雑物やスラッジを含む水が残ったまま放置されるという事態を抑制することが可能になる。清掃研磨面への水分の常時供給作用や摩擦熱の冷却作用、水分による潤滑作用、スラッジの連続的な洗い流し作用、研磨後の水分吸収作用などの上記作用は、基材として、骨格構造によって連続気孔を形成している素材を採用することによって顕著に発揮されることが判っている。   With a polishing tool having this configuration, moisture can be contained in the base material due to water absorption of the base material, and cleaning and polishing work is performed while constantly supplying water from the base material to the cleaning polishing surface. be able to. In particular, it is possible to supply a sufficient amount of moisture from the pores of the base material located between a large number of abrasive grains. Therefore, not only the effect that the frictional heat generated during polishing is cooled by the moisture supplied to the cleaning and polishing surface, but also the moisture acts as a lubricant, making it easy to move the polishing tool smoothly on the cleaning and polishing surface. Furthermore, sludge generated during polishing is continuously washed away. In addition, after polishing, the water absorption surface formed by the entire back surface of the base material is used to absorb moisture remaining on the cleaning and polishing surface, or contaminants such as dirt remaining along with moisture and sludge generated by polishing are removed. Since it can be removed, it is possible to suppress a situation in which water containing impurities and sludge remains on the cleaning and polishing surface. The above-mentioned actions such as the constant supply of moisture to the cleaned and polished surface, the cooling action of frictional heat, the lubrication action by moisture, the continuous washing of sludge, the moisture absorption action after polishing, etc., continue as a base material depending on the skeletal structure. It has been found that the use of a material that forms pores is significant.

また、上記構成の研磨用具では、基材を構成しているポリビニルホルマール樹脂で作られた連続気孔型スポンジの気孔に、研磨砥粒塊のバインダが入り込むことによる錨効果(アンカリング)によって、研磨砥粒塊と基材の表面との接合力が高められている。そして、連続気孔型スポンジの気孔径が30μmよりも小さいと、気孔にバインダが入り込みにくくなってそれだけ結合力が弱まるおそれがある。逆に、連続気孔型スポンジの気孔径が200μmよりも大きいと、研磨砥粒塊の塗布効率が低下してドット形状の研磨砥粒塊を形成しにくくなる。連続気孔型スポンジの気孔径が30〜200μmの範囲に収まっていると、塗布効率の低下をきたすことなく上記錨効果による接合力が高まるようになり、研磨時に研磨砥粒塊が脱落するという事態が起こりにくくなる。Further, in the polishing tool having the above-described configuration, polishing is performed by a wrinkle effect (anchoring) caused by the binder of the abrasive grain lump entering the pores of the continuous pore type sponge made of the polyvinyl formal resin constituting the base material. The bonding force between the abrasive grain lump and the surface of the substrate is enhanced. If the pore size of the continuous pore type sponge is smaller than 30 μm, it is difficult for the binder to enter the pores, and the binding force may be weakened accordingly. On the contrary, if the pore diameter of the continuous pore type sponge is larger than 200 μm, the application efficiency of the abrasive grain lump is lowered and it becomes difficult to form the dot-shaped abrasive grain lump. When the pore size of the continuous pore type sponge is within the range of 30 to 200 μm, the bonding force due to the wrinkle effect is increased without reducing the coating efficiency, and the abrasive grain lump is dropped during polishing. Is less likely to occur.

さらに、気孔率が80%よりも少ないと、基材の弾力性や保水性が低くなりすぎ使用感が損なわれ、気孔率が95%よりも多いと、耐久性や研磨砥粒の塗布性が低下する。気孔率が80〜95%の範囲に収まっていると、適度の弾力性や保水性が得られ、耐久性や研磨砥粒の塗布性の低下も抑制される。気孔率は、乾燥機で十分に乾燥させた直方体の上記基材を乾式自動密度計によって測定し、その基材の見掛け体積と真体積とから次式(1)によって算出される値である。Furthermore, if the porosity is less than 80%, the elasticity and water retention of the base material are too low and the feeling of use is impaired, and if the porosity is more than 95%, the durability and applicability of abrasive grains are deteriorated. descend. When the porosity is in the range of 80 to 95%, moderate elasticity and water retention are obtained, and durability and applicability of abrasive grains are also prevented from being lowered. The porosity is a value calculated by the following formula (1) from the apparent volume and the true volume of the base material measured by a dry automatic densimeter after the rectangular parallelepiped sufficiently dried by a dryer.
気孔率(%)=〔(見掛け体積−真体積)/見掛け体積〕×100・・・(1)Porosity (%) = [(apparent volume−true volume) / apparent volume] × 100 (1)

特に、この研磨用具では、基材の表面に間隔を隔てて多数の研磨砥粒塊が散在していて、個々の上記研磨砥粒塊がバインダによって結合された多数の研磨砥粒の集合体でなり、その研磨砥粒塊が基材の表面から膨出されて正面視ドット形状に形成されていることにより、清掃研磨面に付着している汚れや夾雑物を除去する作用が、微細な研磨砥粒によって発揮されるだけでなく、微細な研磨砥粒の集合体でなる研磨砥粒塊によっても発揮されるので、汚れなどの夾雑物や研磨で発生したスラッジの除去作用が高度に発揮され、併せて、研磨砥粒が基材から脱落するという事態が抑制されるという優れた作用が発揮されることになる。なお、基材の表面に散在している多数の研磨砥粒塊は、研磨用具の研磨層を形成している。   In particular, in this polishing tool, a large number of polishing abrasive grain lumps are scattered on the surface of the base material at intervals, and each polishing abrasive lump is an aggregate of a large number of polishing abrasive grains bonded by a binder. The polishing abrasive lump bulges from the surface of the substrate and is formed into a dot shape in front view, so that the action of removing dirt and impurities adhering to the cleaning polishing surface is finely polished. Not only is it demonstrated by abrasive grains, but it is also demonstrated by abrasive abrasive lump that is an aggregate of fine abrasive grains, so it is highly effective in removing contaminants such as dirt and sludge generated by polishing. In addition, the excellent effect that the situation where the abrasive grains fall off from the substrate is suppressed is exhibited. In addition, the many abrasive grain lump scattered on the surface of the base material forms a polishing layer of the polishing tool.

本発明では、上記基材が手に持つことのできるサイズを備えた柔軟なポリビニルホルマール樹脂であり、かつ、その基材の厚さが、1〜30mmである、という構成を採用することが可能である。ここで、基材としてのポリビニルホルマール樹脂に、骨格構造によって連続気孔を形成しているものを採用することが特に好ましいが、本発明では、基材が、骨格構造によって連続気孔を形成しているポリビニルホルマール樹脂であることに限定されるものではない。上記構成であれば、作業者が基材を手で掴んで清掃研磨作業を容易に行うことができることは勿論、基材を電動ツール(オービタルサンダー)に取り付けて研磨作業を行うことも可能である。さらに、基材がポリビニルホルマール樹脂であるので、基材に一定の剛性を付与して容易に屈曲しない状態にしたり、基材に柔軟性を付与して容易に変形する状態にしたりすることが可能であり、後者の場合には、研磨用具を、複雑な形状を有する清掃研磨面に容易に馴染ませて清掃研磨作業を行うことができ、狭い場所であっても作業を容易に行うことができるだけでなく、作業中には、基材の表面に固定されている研磨砥粒塊を清掃研磨面に一様に接触させて研磨することが可能になるという利点がある。特に、基材の厚さが1〜30mmであって、基材が柔軟性を備えていると、基材の屈曲柔軟性が十分に発揮され、清掃研磨面形状に基材が好適に追従する In the present invention, it is possible to adopt a configuration in which the base material is a flexible polyvinyl formal resin having a size that can be held in the hand, and the thickness of the base material is 1 to 30 mm. It is. Here, it is particularly preferable to use a polyvinyl formal resin as a base material in which continuous pores are formed by a skeleton structure, but in the present invention, the base material forms continuous pores by a skeleton structure. It is not limited to being a polyvinyl formal resin. If it is the said structure, it is also possible not only for an operator to grasp a base material by hand but to perform cleaning grinding | polishing work easily, and also to attach a base material to an electric tool (orbital sander) and to perform grinding | polishing work. . Furthermore, since the base material is a polyvinyl formal resin, it is possible to give the base material a certain rigidity so that it does not bend easily, or to give the base material a flexibility so that it can be easily deformed. In the latter case, the polishing tool can be easily adapted to the cleaning and polishing surface having a complicated shape to perform the cleaning and polishing operation, and the operation can be easily performed even in a narrow place. In addition, there is an advantage that during the operation, it is possible to polish the abrasive grain lump fixed to the surface of the base material while uniformly contacting the cleaning abrasive surface. In particular, when the thickness of the base material is 1 to 30 mm and the base material has flexibility, the base material can sufficiently exhibit the bending flexibility, and the base material suitably follows the shape of the cleaning polished surface. .

本発明の研磨用具では、上記研磨砥粒塊の正面視ドット形状が円形又は多角形である、という構成を採用することが可能である。研磨砥粒塊の正面視ドット形状には、正円形、楕円形、長円形といった円形、三角形、四角形、菱形、星形といった多角形が含まれる。特に、菱形や星形を選択しておくと、その形状自体に備わっている先尖り部のエッジによって、対象物の表目に付着している汚れなどの夾雑物の掻取り作用が良好に発揮されるので、それだけ清掃研磨効率が向上する。   In the polishing tool of this invention, it is possible to employ | adopt the structure that the front view dot shape of the said abrasive grain lump is circular or a polygon. The front-view dot shape of the abrasive grain lump includes a circle such as a regular circle, an ellipse, and an oval, and a polygon such as a triangle, a rectangle, a diamond, and a star. In particular, when a diamond or star shape is selected, the edge of the pointed portion of the shape itself can effectively remove dirt and other foreign matters attached to the surface of the object. Therefore, the cleaning and polishing efficiency is improved accordingly.

本発明の研磨用具では、上記研磨砥粒が、ダイヤモンド、立方晶窒化ホウ素、アルミナ、炭化珪素、炭酸カルシウム、ケイ酸塩鉱物、酸化セリウム、酸化ジルコニウム、シリカ、種子粉体、メラミン樹脂、から選ばれる無機粒子又は有機粒子のうちの少なくとも1種類以上でなり、上記バインダが、エポキシ樹脂、メラミン樹脂、フェノール樹脂、シリコーン樹脂から選ばれる熱硬化性樹脂、ポリスチレン系樹脂、エチレン酢酸ビニル樹脂、フッ素樹脂から選ばれる熱可塑性樹脂のうちの少なくとも1種類以上からなる、という構成を採用することが可能である。ここで、ケイ酸塩鉱物にはカオリンが含まれる。   In the polishing tool of the present invention, the abrasive grains are selected from diamond, cubic boron nitride, alumina, silicon carbide, calcium carbonate, silicate mineral, cerium oxide, zirconium oxide, silica, seed powder, and melamine resin. The binder is a thermosetting resin selected from epoxy resin, melamine resin, phenol resin, and silicone resin, polystyrene resin, ethylene vinyl acetate resin, and fluorine resin. It is possible to adopt a configuration in which at least one of the thermoplastic resins selected from the above is used. Here, the silicate mineral includes kaolin.

特に、研磨砥粒として、モース硬度2〜2.5のケイ酸塩鉱物の1種であるカオリンの粒子を用いると、カオリン粒子自体の自己崩壊性が都合よく発揮される。そのため、研磨時に研磨砥粒が清掃研磨面を傷付けてスクラッチを入れるということが抑制される。また、カオリンは他の研磨砥粒に比べて比重が小さいためにバインダ中に分散しやすく、研磨砥粒塊のドットをスクリーン印刷で形成する工程においても砥粒の沈降が生じにくい。その結果、組成の安定した研磨砥粒塊を形成しやすく、そのことが、研磨性能の安定性を向上させることに役立つ。   In particular, when kaolin particles which are one type of silicate mineral having a Mohs hardness of 2 to 2.5 are used as the abrasive grains, the self-disintegrating properties of the kaolin particles themselves are conveniently exhibited. For this reason, it is possible to prevent the abrasive grains from scratching and scratching the cleaning polished surface during polishing. Further, kaolin has a smaller specific gravity than other abrasive grains, so that kaolin is easily dispersed in the binder, and the settling of the abrasive grains hardly occurs in the process of forming dots of the abrasive grain lump by screen printing. As a result, it is easy to form an abrasive grain lump having a stable composition, which helps to improve the stability of the polishing performance.

本発明では、上記研磨砥粒塊が、30〜70wt%の研磨砥粒を含んでいることが望ましい。ここで、30〜70wt%は、研磨砥粒にカオリンを選定した場合の数値範囲を示したものであって、研磨砥粒塊に対する研磨砥粒の重量百分率を意味している。この場合、研磨砥粒が、30wt%より少ないと研磨力が不足しがちになり、70wt%よりも多いと研磨砥粒塊が脆くなって研磨中に研磨砥粒塊の破片が発生しやすくなり、十分な研磨力や研磨持続力が得られにくくなる。研磨砥粒が30〜70wt%の範囲に収まっていると、研磨中に研磨砥粒塊が崩壊してその破片が発生したりすることが少なくなり、十分な研磨力や研磨持続力が得られる In the present invention, it is desirable that the abrasive grain lump contains 30 to 70 wt% of abrasive grains. Here, 30 to 70 wt% indicates a numerical range when kaolin is selected as the polishing abrasive grain, and means a weight percentage of the polishing abrasive grain with respect to the abrasive grain lump. In this case, if the abrasive grain is less than 30 wt%, the polishing power tends to be insufficient, and if it is more than 70 wt%, the abrasive grain lump becomes brittle and the abrasive abrasive lump fragments are likely to occur during polishing. Therefore, it becomes difficult to obtain sufficient polishing power and polishing durability. When the abrasive grains are within the range of 30 to 70 wt%, the abrasive abrasive lump is less likely to collapse and generate fragments during polishing, and sufficient polishing power and polishing durability can be obtained. .

本発明の研磨用具では、上記研磨砥粒塊の数が、4〜12個/cmであることが望ましい。研磨砥粒塊の数が4個/cmより少ないと、基材を屈曲させた場合に研磨砥粒塊そのものにひび割れを生じる可能性が大きくなる。また、研磨砥粒塊の数が12個/cmより多いと、研磨砥粒塊の配列密度が細かくなりすぎ、研磨砥粒塊をドット形状に形成することが困難になる。研磨砥粒塊の数を、4〜12個/cmの範囲に収めると、基材が屈曲しても研磨砥粒にひび割れが生じにくく、しかも、研磨砥粒塊を容易にドット形状に形成することが可能であるなお、研磨砥粒塊のドットの幅寸法(L)と高さ(D)との比(L/D)は、0.1〜1の範囲が好ましい。L/Dが0.1より小さいと研磨砥粒塊が形崩れしやすく、1より大きいと研磨安定性が損なわれやすい。L/Dのさらに好ましい範囲は0.2〜0.5である。 In the polishing tool of the present invention, it is desirable that the number of the abrasive abrasive lump is 4 to 12 / cm 2 . If the number of abrasive grain lumps is less than 4 / cm 2 , there is a high possibility that the abrasive grain lumps themselves will crack when the substrate is bent. Further, when the number of polishing abrasive grains is larger than 12 / cm 2 , the arrangement density of the abrasive abrasive grains becomes too fine, and it becomes difficult to form the abrasive abrasive grains in a dot shape. When the number of abrasive grains is within the range of 4 to 12 pieces / cm 2 , the abrasive grains are not easily cracked even if the substrate is bent, and the abrasive grains are easily formed into a dot shape. Is possible . In addition, the ratio (L / D) of the width dimension (L) and the height (D) of the dots of the abrasive grain lump is preferably in the range of 0.1-1. When L / D is smaller than 0.1, the abrasive grain lump is liable to lose its shape, and when L / D is larger than 1, the polishing stability tends to be impaired. A more preferable range of L / D is 0.2 to 0.5.

本発明の研磨用具では、基材の表面に散在された多数の研磨砥粒塊の全体の表面積が、基材表面積の30〜80%であることが望ましい。多数の研磨砥粒塊の全体の表面積が基材表面積の30%よりも少ないと、十分な研磨効率が得られず、80%よりも多いと、研磨砥粒塊自体が破壊しやすくなり、基材の屈曲性が阻害されやすくなる。多数の研磨砥粒塊の全体の表面積が基材表面積の30〜80%の範囲に収まっていると、研磨砥粒塊が破壊しにくく、基材の屈曲耐久性も向上する。 In the polishing tool of the present invention, the entire surface area of a large number of abrasive grains lump scattered on the surface of the substrate is preferably 30 to 80% of the substrate surface area. If the entire surface area of a large number of abrasive grains is less than 30% of the surface area of the substrate, sufficient polishing efficiency cannot be obtained, and if it is more than 80%, the abrasive grains are likely to be destroyed. The flexibility of the material is likely to be hindered. When the entire surface area of a large number of abrasive grains is within the range of 30 to 80% of the surface area of the substrate, the abrasive grains are hardly broken and the bending durability of the substrate is improved.

本発明の研磨用具では、上記研磨砥粒塊が、上記研磨砥粒と共に金属粒子を含んでいてもよい。研磨砥粒塊に含まれる金属粒子は、フィラーや骨材としての作用を発揮して研磨砥粒塊の強度を高めることに役立つだけでなく、軟質の金属粒子を採用することによって、研磨作業時に研磨砥粒塊の表面で金属粒子が圧潰延伸してその研磨砥粒塊を覆う金属面を形成し、その金属面に研磨砥粒が担持されて研磨作用を発揮ものと推測される。そのため、研磨作業に伴う研磨砥粒の消失が抑制され、当該研磨用具の耐用寿命(ライフ)が向上する。この作用は、上記金属粒子が、銅粒子及び錫粒子から選ばれた1種類以上からなる、という構成を採用することによって顕著に発揮される。   In the polishing tool of the present invention, the abrasive grain lump may contain metal particles together with the abrasive grains. The metal particles contained in the abrasive grain lump not only serve to increase the strength of the abrasive abrasive grain lump by acting as a filler or aggregate, but also by adopting soft metal particles, It is presumed that the metal particles are crushed and stretched on the surface of the abrasive grain lump to form a metal surface covering the abrasive abrasive lump, and the abrasive grains are supported on the metal surface and exhibit a polishing action. Therefore, the disappearance of the abrasive grains accompanying the polishing operation is suppressed, and the useful life (life) of the polishing tool is improved. This effect is remarkably exhibited by adopting a configuration in which the metal particles are composed of one or more selected from copper particles and tin particles.

上記研磨砥粒塊が上記研磨砥粒と共に金属粒子を含んでいる本発明の研磨用具では、基材の表面に散在された多数の研磨砥粒塊の全体の表面積が基材表面積の80%よりも少ないと、十分なライフ向上効果が得られず、90%よりも多いと、研磨砥粒塊自体が破壊しやすくなり、基材1の屈曲性が阻害されやすくなる。多数の研磨砥粒塊の全体の表面積が基材表面積の80〜90%の範囲に収まっていると、ライフ向上効果が得やすくなり、基材の屈曲耐久性も向上する。   In the polishing tool of the present invention in which the abrasive grain lump includes metal particles together with the abrasive grain, the entire surface area of a large number of abrasive grain lump scattered on the surface of the substrate is more than 80% of the substrate surface area. If the amount is less than 90%, a sufficient life improvement effect cannot be obtained. If the amount is more than 90%, the abrasive grain lump itself tends to be broken, and the flexibility of the base material 1 tends to be hindered. When the entire surface area of a large number of abrasive grains is within the range of 80 to 90% of the surface area of the base material, a life improvement effect can be easily obtained, and the bending durability of the base material is also improved.

上記研磨砥粒塊が上記研磨砥粒と共に金属粒子を含んでいる本発明の研磨用具では、個々の上記研磨砥粒塊の最大サイズが1〜1.5mmであることが望ましい。このことは、ドット形状の研磨砥粒塊を形成することを技術的に容易にすることに役立つ。なお、個々の上記研磨砥粒塊の最大サイズは、1〜1.5mmの範囲内でできるだけ細かい形状であることが望ましい。   In the polishing tool of the present invention in which the abrasive abrasive lump includes metal particles together with the abrasive abrasive, it is desirable that the maximum size of each of the abrasive abrasive agglomerates is 1 to 1.5 mm. This is useful for technically facilitating the formation of dot-shaped abrasive grains. In addition, it is desirable that the maximum size of each abrasive grain lump is as fine as possible within the range of 1 to 1.5 mm.

上記研磨砥粒塊が上記研磨砥粒と共に金属粒子を含んでいる本発明の研磨用具では、上記研磨砥粒塊の数が、50個/cm以上であることが望ましい。この研磨砥粒塊の数は、上記した研磨砥粒塊の最大サイズに応じて自ずと設定される。 In the polishing tool of the present invention in which the abrasive grain lump includes metal particles together with the abrasive grain, the number of the abrasive grain agglomerates is preferably 50 / cm 2 or more. The number of this abrasive grain lump is naturally set according to the maximum size of the above-mentioned abrasive grain lump.

上記研磨砥粒塊が上記研磨砥粒と共に金属粒子を含んでいる本発明の研磨用具では、上記研磨砥粒塊が、5〜50wt%の研磨砥粒を含んでいることが望ましい。ここで、研磨砥粒が5wt%より少ないと研磨力が不足しがちになり、50wt%よりも多いと研磨砥粒塊が脆くなって研磨中に研磨砥粒塊の破片が発生しやすくなり、十分な研磨力や研磨持続力が得られにくくなる。研磨砥粒が5〜50wt%の範囲に収まっていると、金属粒子が含まれているとしても、研磨中に研磨砥粒塊が崩壊してその破片が発生したりすることが少なくなり、十分な研磨力や研磨持続力が得られる In the polishing tool of the present invention in which the abrasive grain lump includes metal particles together with the abrasive grain, the abrasive grain lump preferably contains 5 to 50 wt% of abrasive grains. Here, if the abrasive grain is less than 5 wt%, the polishing power tends to be insufficient, and if it is more than 50 wt%, the abrasive grain lump becomes brittle and the abrasive abrasive lump fragments are likely to be generated during polishing. It becomes difficult to obtain sufficient polishing power and polishing durability. When the abrasive grains are within the range of 5 to 50 wt%, even if metal particles are contained, the abrasive grains lump is less likely to break down and generate debris during polishing. High polishing power and polishing durability .

以上説明したように、本発明に係る研磨用具は、吸水性を有する連続気孔型スポンジでなる基材に水分を含ませた後、多数の研磨砥粒塊の相互間に位置している基材の連続気孔の開口から十分な量の水分を清掃研磨面に常時供給させながら清掃研磨作業を行うことができるので、清掃研磨面の温度上昇を抑制しながら研磨用具を清掃研磨面でスムーズに動かすことができる。その上、研磨時に発生する研磨砥粒塊の破片や研磨砥粒などを含むスラッジを連続的に洗い流すことが可能になり、研磨後には、基材の吸水面を用いて清掃研磨面に残った水分を、その水分に含まれている汚れなどの夾雑物や研磨砥粒塊の破片などを含むスラッジと共に吸収させて容易に取り除くことが可能である。そのため、研磨用具を繰り返し頻繁に水に浸けたり、別途用意した布や不織布で残った水分を拭き取ったりする作業を行わずに、清掃研磨作業を容易にかつ迅速に行うことが可能になる。   As described above, the polishing tool according to the present invention is a base material that is located between a large number of abrasive grain lumps after water is contained in a base material made of a continuous pore type sponge having water absorption. Cleaning and polishing work can be performed while constantly supplying a sufficient amount of moisture to the cleaning and polishing surface from the opening of the continuous pores, so that the polishing tool can be moved smoothly on the cleaning and polishing surface while suppressing the temperature rise of the cleaning and polishing surface be able to. In addition, it becomes possible to continuously wash away sludge containing polishing abrasive lump fragments and polishing abrasive grains generated during polishing, and after polishing, it remains on the cleaning polished surface using the water absorption surface of the substrate. It is possible to easily remove moisture by absorbing it together with sludge including contaminants such as dirt contained in the moisture, and fragments of abrasive abrasive lump. Therefore, it is possible to easily and quickly perform the cleaning and polishing operation without performing the operation of repeatedly immersing the polishing tool in water frequently or wiping off the remaining water with a separately prepared cloth or nonwoven fabric.

また、本発明に係る研磨用具では、基材の表面に間隔を隔てて散在する個々の研磨砥粒塊が、基材の表面から膨出されて正面視ドット形状に形成され、かつ、バインダによって結合された多数の研磨砥粒の集合体でなるので、清掃研磨面に付着している汚れなどの夾雑物を除去する作用が向上し、研磨砥粒から基材が脱落して清掃研磨面に残るという事態も抑制される。   Further, in the polishing tool according to the present invention, the individual abrasive grains lump scattered on the surface of the base material are formed in a dot shape in front view by bulging from the surface of the base material, and by the binder Because it is an aggregate of a large number of bonded abrasive grains, the action of removing contaminants such as dirt adhering to the cleaning abrasive surface is improved, and the substrate falls off from the abrasive grains and becomes a cleaning abrasive surface. The situation of remaining is also suppressed.

特に、基材が手に持つことのできるサイズを備えた柔軟なポリビニルホルマール樹脂又は人工皮革から選ばれ、かつ、その基材の厚さが、1〜30mmである、という構成を採用しておくと、研磨用具を、複雑な形状を有する清掃研磨面に容易に馴染ませて清掃研磨作業を容易に行うことができるだけでなく、狭い場所であっても作業を容易に行うことができるようになる。 In particular, a configuration is adopted in which the base material is selected from flexible polyvinyl formal resin or artificial leather having a size that can be held in the hand, and the thickness of the base material is 1 to 30 mm. In addition, the polishing tool can be easily adapted to the cleaning and polishing surface having a complicated shape so that the cleaning and polishing operation can be easily performed, and the operation can be easily performed even in a narrow place. .

さらに、本発明の研磨用具は、基材としての連続気孔型スポンジの表面に一定のパターンで研磨砥粒塊をスクリーン印刷するという簡単な工程を経て製作することができ、その製作工程中に基材に通水孔を形成したりする必要もないので安価に提供することができるという効果も奏される。   Furthermore, the polishing tool of the present invention can be manufactured through a simple process of screen-printing abrasive grains in a predetermined pattern on the surface of a continuous pore-type sponge as a base material. Since there is no need to form a water passage hole in the material, there is an effect that it can be provided at a low cost.

また、本発明では、研磨砥粒塊が、研磨砥粒と共に金属粒子を含んでいるという構成を採用する場合において、銅粒子や錫粒子といった軟質の金属粒子を採用すると、研磨作業時に、軟質の金属粒子が研磨砥粒塊を覆う金属面を形成し、その金属面に研磨砥粒が担持されるようになる。そのため、研磨作業に伴う研磨砥粒の消失が抑制され、当該研磨用具の耐用寿命(ライフ)が向上するという卓越した効果が発揮される。   Further, in the present invention, when adopting a configuration in which the abrasive grain lump includes metal particles together with the abrasive grains, when soft metal particles such as copper particles and tin particles are employed, the soft abrasive particles during the polishing operation are used. The metal particles form a metal surface covering the abrasive grain lump, and the abrasive grains are supported on the metal surface. Therefore, disappearance of the abrasive grains accompanying the polishing operation is suppressed, and an excellent effect that the service life (life) of the polishing tool is improved is exhibited.

本発明に係る研磨用具を説明的に示した斜視図である。1 is a perspective view illustratively showing a polishing tool according to the present invention. 研磨砥粒塊の配列パターンと平面視形状とを例示した説明図である。It is explanatory drawing which illustrated the arrangement | sequence pattern and planar view shape of the abrasive grain lump. 図2の要部の拡大図である。It is an enlarged view of the principal part of FIG. 研磨砥粒塊の側面視形状を示した説明図である。It is explanatory drawing which showed the side view shape of the abrasive grain lump. 研磨砥粒塊の他の側面視形状を示した説明図である。It is explanatory drawing which showed the other side view shape of the abrasive grain lump. 研磨用具を説明的に示した側面図である。It is the side view which showed the polishing tool explanatoryly. 研磨砥粒塊の他の配列パターンと他の平面視形状とを例示した説明図である。It is explanatory drawing which illustrated the other arrangement | sequence pattern and other planar view shape of the abrasive grain lump. 研磨砥粒塊のさらに他の配列パターンとさらに他の平面視形状とを例示した説明図である。It is explanatory drawing which illustrated further another arrangement pattern and other planar view shape of an abrasive grain lump.

図1は本発明に係る研磨用具を説明的に示した斜視図、図2は研磨砥粒塊の配列パターンと平面視形状とを例示した説明図、図3は図2の要部の拡大図、図4は研磨砥粒塊の側面視形状を示した説明図、図5は研磨砥粒塊の他の側面視形状を示した説明図、図6は研磨用具を説明的に示した側面図、図7は研磨砥粒塊の他の配列パターンと他の平面視形状とを例示した説明図、図8は研磨砥粒塊のさらに他の配列パターンとさらに他の平面視形状とを例示した説明図である。   FIG. 1 is a perspective view illustratively showing a polishing tool according to the present invention, FIG. 2 is an explanatory view illustrating an array pattern of polishing abrasive agglomerates and a plan view shape, and FIG. 3 is an enlarged view of the main part of FIG. 4 is an explanatory view showing a side view shape of the abrasive grain lump, FIG. 5 is an explanatory view showing another side view shape of the abrasive abrasive lump, and FIG. 6 is a side view illustratively showing the polishing tool. FIG. 7 is an explanatory view illustrating another arrangement pattern of the abrasive grain lump and another plan view shape, and FIG. 8 illustrates still another array pattern of the abrasive grain lump and another plan view shape. It is explanatory drawing.

本発明に係る研磨用具は、図1のように、基材1の表面に多数の研磨砥粒塊2を散在させた配列で固定させてなり、研磨砥粒塊2は相互に間隔を隔てて配置されていて、その研磨砥粒塊2の相互間では基材1の表面が露出している。   As shown in FIG. 1, the polishing tool according to the present invention is fixed in an array in which a large number of abrasive grain lumps 2 are scattered on the surface of a substrate 1, and the abrasive grain lumps 2 are spaced apart from each other. The surface of the base material 1 is exposed between the abrasive grain lumps 2.

基材1には、ポリビニルホルマール(PVFM)でなる硬質又は柔軟な連続気孔型スポンジが採用されていて、その正面視形状は図2のように正面視矩形に形成されている。基材1は清掃研磨を行う作業者が手に持つことのできるサイズを備えている。この種の基材1は、それ自体に備わっている連続気孔が毛細管現象による吸収性を発揮するので、基材1を水に浸けると、その基材1が水分を吸収する。水分の吸収は、基材1の表面や裏面、側面などの外面で開口している連続気孔に対して行われる。また、その柔軟性を利用して基材1を絞ったり押し付けたりして圧縮すると、基材1に吸収されている基材1の表面又は裏面で開口している連続気孔から水分が外部に絞り出される。したがって、この実施形態に係る基材1の裏面や側面は、吸水面12,13(図1又は図6参照)として作用する。 A hard or flexible continuous pore type sponge made of polyvinyl formal (PVFM) is adopted as the base material 1, and its front view shape is formed in a front view rectangle as shown in FIG . The base material 1 has a size that can be held by an operator who performs cleaning and polishing. Since this type of base material 1 has its own continuous pores exhibit absorbency due to capillary action, when the base material 1 is immersed in water, the base material 1 absorbs moisture. Moisture absorption is performed on continuous pores that are open on the outer surface such as the front surface, back surface, and side surface of the substrate 1. Moreover, when the base material 1 is squeezed or pressed using the flexibility and compressed, moisture is squeezed to the outside from the continuous pores opened on the front surface or the back surface of the base material 1 absorbed by the base material 1. Is issued. Therefore, the back surface and the side surface of the substrate 1 according to this embodiment act as the water absorption surfaces 12 and 13 (see FIG. 1 or FIG. 6).

図6に説明的に示したように、個々の研磨砥粒塊2は、バインダ22によって結合された多数の研磨砥粒21の集合体でなる。   As illustrated in FIG. 6, each abrasive grain lump 2 is an aggregate of a large number of abrasive grains 21 joined by a binder 22.

研磨用具の製作手順の一例を次に説明する。連続気孔型スポンジでなる基材1の表面に、多数の透孔を散在させたマスキングシートを重ね合わせ、その上から研磨砥粒21を含むバインダ22をスクリーン印刷する。この工程を行うと、正面視ドット形状の研磨砥粒塊2が、基材1の表面の多数の箇所で固定される。こうして基材1に固定された研磨砥粒塊2は、図4又は図5のように基材1の表面から膨出している。図4に示した研磨砥粒塊2は側面視ドーム形状を呈するように形成され、図5に示した研磨砥粒塊2は側面視矩形状を呈するように形成されているけれども、研磨砥粒塊2の側面視形状はこれらに限定されない。また、研磨砥粒塊2の正面視ドット形状は、図2又は図3のように正円形であっても、図7又は図8のように菱形であってもよい。また、その他の楕円形、長円形であっても、星形や矩形などの多角形であってもよい。さらに、種々のドット形状の研磨砥粒塊を混在させても、異なる大きさのドット形状の研磨砥粒塊を混在させてもよい。また、研磨砥粒塊2の正面視ドット形状は、図2や図7のように全体に亘って研磨砥粒を含むものであっても、図8のように中央部に空所23を有するものであってもよい。   Next, an example of the manufacturing procedure of the polishing tool will be described. A masking sheet in which a large number of through holes are scattered is superposed on the surface of the substrate 1 made of a continuous pore type sponge, and a binder 22 containing abrasive grains 21 is screen-printed thereon. When this step is performed, the front-view dot-shaped abrasive grain lump 2 is fixed at a number of locations on the surface of the substrate 1. Thus, the abrasive grain lump 2 fixed to the base material 1 swells from the surface of the base material 1 as shown in FIG. The abrasive grain lump 2 shown in FIG. 4 is formed to have a dome shape when viewed from the side, and the abrasive grain lump 2 shown in FIG. 5 is formed to have a rectangular shape when viewed from the side. The side view shape of the lump 2 is not limited to these. Moreover, the front-view dot shape of the abrasive grain lump 2 may be a regular circle as shown in FIG. 2 or FIG. 3 or a diamond shape as shown in FIG. 7 or FIG. Further, it may be other ellipse, oval, or polygon such as star or rectangle. Further, various dot-shaped abrasive abrasive lumps may be mixed, or different sizes of dot-shaped abrasive abrasive lumps may be mixed. Further, even if the front-view dot shape of the abrasive grain lump 2 includes the abrasive grains throughout as shown in FIGS. 2 and 7, it has a void 23 in the center as shown in FIG. It may be a thing.

基材1の表面に固定されている研磨砥粒塊2のバインダ22は、基材1の表面で開口している連続気孔の内部に侵入して基材1と接合している。そのため、錨効果(アンカリング効果)によって研磨砥粒塊2が基材1に強固に一体化している。   The binder 22 of the abrasive grain lump 2 fixed to the surface of the base material 1 penetrates into the continuous pores opened on the surface of the base material 1 and is joined to the base material 1. Therefore, the abrasive grain lump 2 is firmly integrated with the substrate 1 by the wrinkle effect (anchoring effect).

研磨砥粒塊2には、研磨砥粒21と共に、銅粒子や錫粒子などの比較的軟質の金属粒子を含ませることも可能である。   The abrasive grain lump 2 can contain relatively soft metal particles such as copper particles and tin particles together with the abrasive grains 21.

研磨砥粒塊2は基材1の表面だけに形成されていて、裏面には形成されていない。そのため、基材1の表面では、その連続気孔の開口が相隣接する研磨砥粒塊2の相互間に位置し、基材1の裏面では、その連続気孔の開口が裏面の全体に亘って満遍なく存在している。研磨砥粒塊2は、基材1の表面にランダムに散在していても、一定の配列パターンに従って散在していてもよい。たとえば、図2の事例では、研磨砥粒塊2が縦横に千鳥配列されている。また、図7や図8の事例では、研磨砥粒塊2が一定の規則に従って規則正しく配列されている。   The abrasive grain lump 2 is formed only on the surface of the substrate 1 and not on the back surface. Therefore, on the surface of the base material 1, the openings of the continuous pores are located between the adjacent abrasive grain lumps 2, and on the back surface of the base material 1, the openings of the continuous pores are uniformly distributed over the entire back surface. Existing. The abrasive grain lump 2 may be scattered randomly on the surface of the substrate 1 or may be scattered according to a certain arrangement pattern. For example, in the example of FIG. 2, the abrasive abrasive lump 2 is arranged in a staggered manner vertically and horizontally. 7 and 8, the abrasive grain lump 2 is regularly arranged according to a certain rule.

以上のように構成された研磨用具で清掃研磨面を清掃研磨するときには、たとえば、作業者が基材1を手で掴み、基材1の表面の研磨砥粒塊2を清掃研磨面に接触させて擦り合わせる。この場合に、事前に研磨用具全体を水に浸けて基材1に水分を吸収させておく。   When cleaning and polishing the cleaning and polishing surface with the polishing tool configured as described above, for example, an operator holds the base material 1 by hand and brings the abrasive grain lump 2 on the surface of the base material 1 into contact with the cleaning and polishing surface. Rub together. In this case, the entire polishing tool is immersed in water in advance to allow the substrate 1 to absorb moisture.

このような清掃研磨作業を行うと、清掃研磨中には、基材1の連続気孔の開口から水分が清掃研磨面に常時供給される。そのため、清掃研磨面で発生する摩擦熱が冷却されるだけでなく、水分が潤滑剤として作用して研磨用具が清掃研磨面上でスムーズに動くようになる。その上、清掃研磨中に発生するスラッジ、具体的には清掃研磨面に付着した汚れなどの夾雑物や研磨砥粒塊2から出た研磨砥粒などが連続的に洗い流される。また、清掃研磨作業が終了したときには、基材1の吸水面12,13を清掃研磨面に押し付けたり清掃研磨面上で動かしたりすると、基材1に残留水分が吸収される。そのため、別途に布や不織布を用いて残留水分を拭き取ったりするという手間がかからない。残留水分を基材1に吸収させて拭き取ると、その残留水分に含まれている汚れなどの夾雑物や研磨砥粒塊2から出た破片や研磨砥粒なども同時に除去される。   When such a cleaning and polishing operation is performed, moisture is constantly supplied from the opening of the continuous pores of the substrate 1 to the cleaning and polishing surface during the cleaning and polishing. Therefore, not only the frictional heat generated on the cleaning / polishing surface is cooled, but also moisture acts as a lubricant so that the polishing tool moves smoothly on the cleaning / polishing surface. In addition, sludge generated during the cleaning and polishing, specifically, contaminants such as dirt adhering to the cleaning and polishing surface, polishing abrasive particles coming out from the polishing abrasive lump 2 and the like are continuously washed away. In addition, when the cleaning and polishing operation is completed, residual moisture is absorbed by the substrate 1 when the water absorbing surfaces 12 and 13 of the substrate 1 are pressed against the cleaning and polishing surface or moved on the cleaning and polishing surface. Therefore, it does not take time and effort to wipe off residual moisture using a separate cloth or non-woven fabric. When the residual moisture is absorbed by the substrate 1 and wiped off, contaminants such as dirt contained in the residual moisture, debris from the abrasive grain lump 2 and abrasive grains are simultaneously removed.

研磨清掃作業では、研磨砥粒塊2に含まれる研磨砥粒の微粒子だけでなく、研磨砥粒塊2自体も清掃研磨面に付着した汚れなどの夾雑物を掻き取って除去することに役立つ。特に、この実施形態の研磨用具では、個々の研磨砥粒塊2がバインダ22によって結合された多数の研磨砥粒21の集合体でなるので、微細な研磨砥粒によって夾雑物を掻き取る場合に比べて優れた除去作用が得られる。特に、研磨砥粒塊2が図7や図8のような正面視菱形のドット形状に形成されていると、正面視菱形の先尖り部が夾雑物を掻き取るために除去作用が格段に向上する。また、清掃研磨面への水分の供給は、基材1の表面で相隣接する研磨砥粒塊2の相互間で開口している連続気孔を通じて行われる。そのため、研磨砥粒塊2にじゃまされずに十分な量の水分が常時供給される。   In the polishing cleaning operation, not only the fine particles of the polishing abrasive grains contained in the polishing abrasive lump 2, but also the polishing abrasive lump 2 itself is useful for scraping off and removing foreign substances such as dirt adhering to the cleaning and polishing surface. In particular, in the polishing tool of this embodiment, each polishing abrasive grain lump 2 is an aggregate of a large number of polishing abrasive grains 21 bonded by a binder 22, and therefore, when scraping impurities with fine polishing abrasive grains. An excellent removal effect can be obtained. In particular, when the abrasive grain lump 2 is formed in a front rhombus-like dot shape as shown in FIGS. 7 and 8, the sharpness of the rhombus in the front view scrapes away impurities, so that the removal action is remarkably improved. To do. Further, the supply of moisture to the cleaning and polishing surface is performed through continuous pores that are open between adjacent abrasive grain lumps 2 on the surface of the substrate 1. Therefore, a sufficient amount of moisture is always supplied without being disturbed by the abrasive grain lump 2.

この実施形態の研磨用具では、基材1と研磨砥粒塊2の固定が、上記した錨効果によって強固に結合されているので、清掃研磨作業中に研磨砥粒塊2が基材1から脱落したり、研磨砥粒塊2の形状が崩れて研磨砥粒が大量に発生するという事態は起こりにくい。したがって、上記した夾雑物の除去作用が効率よく行われるだけでなく、残留水分中に含まれる研磨砥粒も最低限度に抑えられる。   In the polishing tool of this embodiment, the fixing of the base material 1 and the abrasive grain lump 2 is firmly coupled by the above-described wrinkle effect, so that the abrasive grain lump 2 is detached from the base material 1 during the cleaning and polishing operation. Or the shape of the abrasive grain lump 2 collapses and a large amount of abrasive grains are unlikely to occur. Therefore, not only the above-described contaminant removal operation is efficiently performed, but also the abrasive grains contained in the residual moisture can be minimized.

上記した研磨用具において、その正面視形状を矩形に形成する場合には、基材1が手に持つことのできるサイズを備えていて、その基材1の厚さが1〜30mmであることが望まれる。基材1がこの範囲の厚さであれば、作業者が基材1を手で掴んで清掃研磨作業を容易に行うことができることは勿論、PVFM樹脂の柔軟性を活用して複雑な形状を有する清掃研磨面を無理なく清掃研磨することが可能になる。また、狭い場所での清掃研磨作業を容易に行うことにも役立つ。なお、基材1をオービタルサンダーと呼ばれる回転機械に取り付けて研磨作業を行うことも可能である。ここで、基材1の厚さを、特に5〜20mmに定めておくと、複雑な形状を有する清掃研磨面を楽に清掃研磨したり、狭い場所での清掃研磨作業を楽に無理なく行ったりすることができるという作用が顕著に発揮される。   In the above-described polishing tool, when the front view shape is rectangular, the base material 1 has a size that can be held in the hand, and the thickness of the base material 1 is 1 to 30 mm. desired. If the thickness of the base material 1 is within this range, the operator can easily perform the cleaning and polishing work by grasping the base material 1 by hand. It becomes possible to clean and polish the cleaning / polishing surface having it without difficulty. It is also useful for easily carrying out the cleaning and polishing operation in a narrow place. In addition, it is also possible to attach the base material 1 to a rotating machine called an orbital sander and perform the polishing operation. Here, if the thickness of the base material 1 is set to 5 to 20 mm in particular, the cleaning and polishing surface having a complicated shape can be easily cleaned and polished, or the cleaning and polishing operation in a narrow place can be easily and easily performed. The effect of being able to perform is remarkably exhibited.

研磨砥粒塊2に含まれる研磨砥粒21には、ダイヤモンド、立方晶窒化ホウ素、アルミナ、炭化珪素、炭酸カルシウム、ケイ酸塩鉱物、酸化セリウム、酸化ジルコニウム、シリカ、種子粉体、メラミン樹脂、から選ばれる無機粒子又は有機粒子のうちの少なくとも1種類以上を用いることができる。すなわち、これらの無機粒子又は有機粒子を単独で用いても、異なる種類の無機粒子又は有機粒子を組み合わせて用いてもよい。研磨砥粒21は清掃研磨面の硬度に応じて適宜適切な無機粒子又は有機粒子を選択すべきであり、そのようにすることによって、清掃研磨面の傷付きなどを防ぐことが可能になる。   The abrasive grains 21 contained in the abrasive grain lump 2 include diamond, cubic boron nitride, alumina, silicon carbide, calcium carbonate, silicate mineral, cerium oxide, zirconium oxide, silica, seed powder, melamine resin, At least one or more of inorganic particles or organic particles selected from can be used. That is, these inorganic particles or organic particles may be used alone, or different types of inorganic particles or organic particles may be used in combination. As the polishing abrasive grain 21, appropriate inorganic particles or organic particles should be appropriately selected according to the hardness of the cleaning polishing surface. By doing so, it becomes possible to prevent the cleaning polishing surface from being damaged.

研磨砥粒塊2に、研磨砥粒21に金属粒子を含ませる場合には、金属粒子として、銅粒子や錫粒子を単独で、又は、両者を混ぜて含ませることが可能である。   When the abrasive grains 21 contain metal particles in the abrasive grains 21, copper particles and tin particles can be contained alone or in combination as metal particles.

研磨砥粒21として、モース硬度2〜2.5のケイ酸塩鉱物の1種であるカオリンの粒子を選択すると、次に説明する利点が得られる。すなわち、カオリン粒子はそれ自体が自己崩壊性を備えている。そのため、清掃研磨作業中に研磨砥粒塊2が崩れて研磨砥粒(カオリン粒子)21が清掃研磨面上へ流出しても、研磨砥粒21の自己崩壊性によってその研磨砥粒が微細な粉体に変化してしまうので、清掃研磨面を傷付けてスクラッチを入れるということが抑制される。また、カオリンは他の研磨砥粒に比べて比重が小さいためにバインダ中に分散しやすいため、組成の安定した研磨砥粒塊を形成しやすく、そのことが、研磨性能の安定性を向上させることに役立つ。   When the particles of kaolin, which is one kind of silicate mineral having a Mohs hardness of 2 to 2.5, are selected as the abrasive grains 21, the following advantages can be obtained. That is, kaolin particles themselves have self-disintegrating properties. Therefore, even if the abrasive grain lump 2 collapses during the cleaning and polishing operation and the abrasive grains (kaolin particles) 21 flow out onto the cleaning and polishing surface, the abrasive grains are fine due to the self-disintegrating property of the abrasive grains 21. Since the powder is changed to powder, it is possible to prevent scratching by scratching the cleaning polished surface. In addition, kaolin has a smaller specific gravity than other abrasive grains, so it is easy to disperse in the binder, so it is easy to form abrasive grains with a stable composition, which improves the stability of the polishing performance. It helps.

また、研磨砥粒塊2に研磨砥粒21と共に金属粒子を含ませると、研磨作業時に、軟質の金属粒子が研磨砥粒塊2を覆う金属面を形成し、その金属面に研磨砥粒21が担持されるようになる。そのため、研磨作業に伴う研磨砥粒21の消失が抑制され、当該研磨用具の耐用寿命(ライフ)が向上すると考えられる。   Further, when metal particles are included in the abrasive grain lump 2 together with the abrasive grains 21, soft metal particles form a metal surface that covers the abrasive lump 2 during the polishing operation, and the abrasive grains 21 are formed on the metal surface. Will be carried. Therefore, it is considered that the disappearance of the abrasive grains 21 accompanying the polishing operation is suppressed, and the service life (life) of the polishing tool is improved.

研磨砥粒塊2に含まれるバインダ22には、エポキシ樹脂、メラミン樹脂、フェノール樹脂、シリコーン樹脂から選ばれる熱硬化性樹脂、ポリスチレン系樹脂、エチレン酢酸ビニル樹脂、フッ素樹脂から選ばれる熱可塑性樹脂のうちの少なくとも1種類以上を用いることができる。これらの熱硬化性樹脂や熱可塑性樹脂をバインダ22に採用して研磨砥粒21を混ぜ込むと、場合によっては、研磨砥粒塊2の内部に気泡が閉じ込められてしまうことがある。しかし、そのように気泡が閉じ込められていても、その気泡が清掃研磨作業に悪影響を及ぼすことはない。なお、図6には研磨砥粒塊2に閉じ込められた気泡を符合24で説明的に示してある。   The binder 22 contained in the abrasive grain lump 2 is made of a thermoplastic resin selected from an epoxy resin, a melamine resin, a phenol resin, and a silicone resin, a polystyrene resin, an ethylene vinyl acetate resin, and a fluororesin. At least one of them can be used. When these thermosetting resins or thermoplastic resins are employed in the binder 22 and the abrasive grains 21 are mixed, the bubbles may be trapped inside the abrasive grain lump 2 in some cases. However, even if the bubbles are confined as such, the bubbles do not adversely affect the cleaning and polishing operation. In FIG. 6, the bubbles confined in the abrasive grain lump 2 are illustratively indicated by reference numeral 24.

個々の研磨砥粒塊2は、研磨砥粒塊2に対する重量百分率で、30〜70wt%の研磨砥粒21を含んでいることが望ましい。研磨砥粒21の含有量が30wt%より少ないと研磨力が不足しがちになり、70wt%よりも多いと研磨砥粒塊2が脆くなって清掃研磨中に研磨砥粒塊の破片が発生しやすくなり、十分な研磨力や研磨持続力が得られにくくなる。研磨砥粒が30〜70wt%の範囲に収まっていると、清掃研磨中に研磨砥粒塊が崩壊してその破片が発生したりすることが少なくなり、十分な研磨力や研磨持続力が得られる。この作用は、特に、研磨砥粒が40〜60wt%であるときに顕著に発揮される。   Each polishing abrasive grain lump 2 preferably includes 30 to 70 wt% of polishing abrasive grains 21 in a weight percentage with respect to the polishing abrasive lump 2. If the content of the abrasive grains 21 is less than 30 wt%, the polishing power tends to be insufficient, and if it exceeds 70 wt%, the abrasive grains 2 become brittle and fragments of the abrasive grains are generated during cleaning and polishing. It becomes easy to obtain sufficient polishing power and polishing durability. When the abrasive grains are within the range of 30 to 70 wt%, the abrasive grains lump is less likely to collapse and generate fragments during cleaning and polishing, and sufficient polishing power and polishing durability can be obtained. It is done. This effect is particularly prominent when the abrasive grains are 40 to 60 wt%.

また、基材1の表面に固定された多数の研磨砥粒塊2の全体の表面積は、研磨砥粒塊2が金属粒子を含んでいない場合には、基材1の表面積の30〜80%であることが望ましい。研磨砥粒塊2の全体の表面積が、基材1の表面積の30%よりも少ないと十分な研磨効率が得られず、80%よりも多いと基材1からの水分の供給率が低くなりすぎたり、基材1の屈曲性や耐久性が悪くなったりする。多数の研磨砥粒塊2の全体の表面積が基材1の表面積の30〜80%の範囲に収まっていると、十分な量の水分を清掃研磨面に常時供給させながら高い研磨効率を維持させることが可能になる。この作用は、多数の研磨砥粒塊2の全体の表面積が基材1の表面積の50〜60%である場合に顕著に発揮される。   In addition, the entire surface area of a large number of abrasive grain lumps 2 fixed to the surface of the substrate 1 is 30 to 80% of the surface area of the substrate 1 when the abrasive abrasive lump 2 does not contain metal particles. It is desirable that When the entire surface area of the abrasive grain lump 2 is less than 30% of the surface area of the substrate 1, sufficient polishing efficiency cannot be obtained, and when it is more than 80%, the water supply rate from the substrate 1 is lowered. Or the flexibility and durability of the substrate 1 may be deteriorated. When the entire surface area of a large number of abrasive grains 2 is within the range of 30 to 80% of the surface area of the substrate 1, a high polishing efficiency is maintained while always supplying a sufficient amount of moisture to the cleaned polishing surface. It becomes possible. This effect is remarkably exhibited when the entire surface area of the large number of abrasive grains 2 is 50 to 60% of the surface area of the substrate 1.

研磨砥粒塊2が金属粒子を含んでいる場合には、基材1の表面に散在された多数の研磨砥粒塊2の全体の表面積が、基材表面積の80〜90%であることが望ましい。多数の研磨砥粒塊2の全体の表面積が基材表面積の80%よりも少ないと、十分なライフ向上効果が得られず、90%よりも多いと、研磨砥粒塊自体が破壊しやすくなり、基材1の屈曲性が阻害されやすくなる。多数の研磨砥粒塊の全体の表面積が基材表面積の十分なライフ向上効果が得られず、90%よりも多いと、研磨砥粒塊自体が破壊しやすくなり、基材1の屈曲性が阻害されやすくなる。多数の研磨砥粒塊の全体の表面積が基材表面積の80〜90%の範囲に収まっていると、ライフ向上効果が得やすくなり、基材の屈曲耐久性も向上する。   When the abrasive grain lump 2 contains metal particles, the entire surface area of the many abrasive abrasive lump 2 scattered on the surface of the substrate 1 is 80 to 90% of the substrate surface area. desirable. If the entire surface area of the large number of abrasive grain masses 2 is less than 80% of the surface area of the substrate, a sufficient life improvement effect cannot be obtained, and if more than 90%, the abrasive grain masses themselves are easily destroyed. The flexibility of the base material 1 is likely to be hindered. If the entire surface area of a large number of abrasive grains is not sufficient to improve the surface area of the substrate, and if it is more than 90%, the abrasive grains are likely to be destroyed and the flexibility of the substrate 1 is increased. It becomes easy to be disturbed. When the entire surface area of a large number of abrasive grains is within the range of 80 to 90% of the surface area of the base material, a life improvement effect can be easily obtained, and the bending durability of the base material is also improved.

基材1としてのPVFM樹脂でなる連続気孔型スポンジの気孔径は30〜200μmであることが望ましい。気孔径が30μmよりも小さいと、気孔にバインダ22が入り込みにくくなってそれだけ結合力が弱まるおそれがある。気孔径が200μmよりも大きいと、連続気孔に入り込むバインダ22の量が多くなりすぎて塗布効率が低下し、ドット形状の研磨砥粒塊2を形成しにくくなる。気孔径が30〜200μmの範囲に収まっていると、塗布効率の低下をきたすことなく上記した錨効果による接合力が高まり、清掃研磨作業中に研磨砥粒塊2が脱落するという事態が起こりにくくなる。この作用は、気孔径が60〜130μmである場合に顕著に発揮される。   The pore diameter of the continuous pore type sponge made of PVFM resin as the substrate 1 is desirably 30 to 200 μm. If the pore diameter is smaller than 30 μm, it is difficult for the binder 22 to enter the pores, and the binding force may be weakened accordingly. When the pore diameter is larger than 200 μm, the amount of the binder 22 that enters the continuous pores becomes too large, the coating efficiency is lowered, and it becomes difficult to form the dot-shaped abrasive grain lump 2. When the pore diameter is in the range of 30 to 200 μm, the bonding force due to the above-described wrinkle effect is increased without causing a decrease in coating efficiency, and it is difficult for the abrasive abrasive lump 2 to drop off during the cleaning and polishing operation. Become. This effect is remarkably exhibited when the pore diameter is 60 to 130 μm.

基材1としてのPVFM樹脂でなる連続気孔型スポンジの気孔率は80〜95%であることが望ましい。気孔率は、上記した式(1)によって算出される値である。気孔率が80%よりも少ないと、基材1の弾力性や保水性が低くなりすぎて使用感が損なわれ、気孔率が95%よりも多いと、耐久性や研磨砥粒の塗布性が低下する。気孔率が89〜91%の範囲に収まっていると、適度の弾力性や保水性が得られ、耐久性や研磨砥粒の塗布性の低下も抑制される。   The porosity of the continuous pore type sponge made of PVFM resin as the substrate 1 is desirably 80 to 95%. The porosity is a value calculated by the above equation (1). If the porosity is less than 80%, the elasticity and water retention of the substrate 1 are too low, and the feeling of use is impaired. If the porosity is more than 95%, durability and applicability of abrasive grains are increased. descend. When the porosity is in the range of 89 to 91%, moderate elasticity and water retention are obtained, and durability and applicability of the abrasive grains are also prevented from being lowered.

研磨砥粒塊2が金属粒子を含んでいない場合には、基材1の表面に固定される研磨砥粒塊2の数は4〜12個/cmであることが望ましい。研磨砥粒塊2の数が4個/cmより少ないと、基材1を屈曲させた場合に研磨砥粒塊2そのものにひび割れを生じる可能性が大きくなる。また、研磨砥粒塊2の数が12個/cmより多いと、研磨砥粒塊2の配列密度が細かくなりすぎ、研磨砥粒塊2をドット形状に形成することが困難になる。研磨砥粒塊2の数を4〜12個/cmの範囲に収めると、基材1が屈曲しても研磨砥粒塊2にひび割れが生じにくく、しかも、研磨砥粒塊2を容易にドット形状に形成することが可能である。この作用は、研磨砥粒塊2の数が6〜8個/cmである場合に顕著に発揮される。 When the abrasive grain lump 2 does not contain metal particles, the number of abrasive abrasive lump 2 fixed to the surface of the substrate 1 is desirably 4 to 12 / cm 2 . When the number of the abrasive grain lump 2 is less than 4 pieces / cm 2 , there is a high possibility that the polishing abrasive lump 2 itself is cracked when the substrate 1 is bent. Further, when the number of polishing abrasive lump 2 is more than 12 pieces / cm 2 , the arrangement density of polishing abrasive lump 2 becomes too fine, and it becomes difficult to form polishing abrasive lump 2 in a dot shape. When the number of the abrasive abrasive lump 2 is within the range of 4 to 12 pieces / cm 2 , the abrasive abrasive lump 2 is hardly cracked even if the substrate 1 is bent, and the abrasive abrasive lump 2 is easily formed. It can be formed in a dot shape. This effect is remarkably exhibited when the number of abrasive grains 2 is 6 to 8 / cm 2 .

研磨砥粒塊2が金属粒子を含んでいる場合には、上記研磨砥粒塊2の数が、50個/cm以上であることが望ましい。この研磨砥粒塊2の数は、研磨砥粒塊の最大サイズに応じて自ずと設定される。 When the abrasive grain lump 2 contains metal particles, the number of the abrasive abrasive lump 2 is preferably 50 / cm 2 or more. The number of the abrasive grains lump 2 is naturally set according to the maximum size of the abrasive grains lump.

研磨砥粒塊2が研磨砥粒と共に金属粒子を含んでいる場合には、研磨砥粒塊2が、5〜50wt%の研磨砥粒を含んでいることが望ましい。研磨砥粒が5wt%より少ないと研磨力が不足しがちになり、50wt%よりも多いと研磨砥粒塊が脆くなって研磨中に研磨砥粒塊の破片が発生しやすくなり、十分な研磨力や研磨持続力が得られにくくなる。研磨砥粒が5〜50wt%の範囲に収まっていると、金属粒子が含まれているとしても、研磨中に研磨砥粒塊2が崩壊してその破片が発生したりすることが少なくなり、十分な研磨力や研磨持続力が得られる。この作用は、特に、研磨砥粒が5〜30wt%であるときに顕著に発揮されることが判っている。 In the case where the abrasive grain lump 2 contains metal particles together with the abrasive grains, it is desirable that the abrasive grain lump 2 contains 5 to 50 wt% abrasive grains. If the abrasive grain is less than 5 wt%, the polishing power tends to be insufficient, and if it exceeds 50 wt%, the abrasive grain lump becomes brittle and it is easy to generate fragments of the abrasive grain lump during polishing. It becomes difficult to obtain strength and polishing durability. When the abrasive grains are within the range of 5 to 50 wt%, even if metal particles are contained, the abrasive grain lump 2 is less likely to collapse and generate fragments during polishing, Sufficient polishing power and polishing durability can be obtained. It has been found that this effect is particularly prominent when the abrasive grains are 5 to 30 wt%.

実施例1
エポキシ樹脂10g、硬化剤2g、研磨砥粒としてカオリン10gを混ぜ、PVFM樹脂のスポンジ(PVFMスポンジ)でなる基材の表面に、基材の表面積に対するバインダの表面積(以下「砥石面積」と略する)が50%になるように塗布した後、60℃で乾燥固化させた。得られた研磨材でキッチンシンクを清掃研磨したところ、水の供給が少なくても汚れが良好に落ちた。
Example 1
10 g of epoxy resin, 2 g of curing agent, and 10 g of kaolin as abrasive grains are mixed, and the surface area of the binder made of PVFM resin sponge (PVFM sponge) is abbreviated as the surface area of the binder relative to the surface area of the substrate (hereinafter referred to as “grinding stone area”). ) Was applied at 50%, and then dried and solidified at 60 ° C. When the kitchen sink was cleaned and polished with the resulting abrasive material, the stain was removed well even with a small amount of water supply.

実施例2
エポキシ樹脂10g、硬化剤2g、研磨砥粒としてカオリン10gを混ぜ、PVFMスポンジでなる基材の表面に、砥石面積が30%になるように塗布した後、60℃で乾燥固化させた。得られた研磨材でキッチンシンクを清掃研磨したところ、水の供給が少なくても汚れが良好に落ちた。
Example 2
10 g of an epoxy resin, 2 g of a curing agent, and 10 g of kaolin as abrasive grains were mixed and applied to the surface of a substrate made of PVFM sponge so that the grindstone area was 30%, and then dried and solidified at 60 ° C. When the kitchen sink was cleaned and polished with the resulting abrasive material, the stain was removed well even with a small amount of water supply.

実施例3
エポキシ樹脂10g、硬化剤2g、研磨砥粒として人工ダイヤモンド粒子4g、さらに金属粒子として銅粒子61gを混ぜ、PVFMスポンジでなる基材の表面に、砥石面積が80%になるように約1mmφのドット状に形成させた後、60℃で乾燥させ、さらに80℃で反応させた。得られた研磨材で、スポンジ部に水を含ませた状態でうろこ状の汚れが付着したガラスを清掃研磨したところ、水の供給が少なくても汚れが良好に落ちた。
また、金属粒子によるライフ向上効果を検証するため、電動ツールに貼付のうえ、ガラス面を1.25m/15minにてトラバースしたところ、4mを処理した時点でも研磨砥粒塊は十分に残存していた。
Example 3
10 g of epoxy resin, 2 g of curing agent, 4 g of artificial diamond particles as abrasive grains, and 61 g of copper particles as metal particles are mixed, and a dot of about 1 mmφ is formed on the surface of the substrate made of PVFM sponge so that the grindstone area becomes 80%. After forming into a shape, it was dried at 60 ° C. and further reacted at 80 ° C. When the obtained abrasive was cleaned and polished on a glass with scaly dirt adhered in a state where water was contained in the sponge portion, the dirt was satisfactorily removed even if the supply of water was small.
To verify the life improving effect by the metal particles, upon sticking to the electric tool, it was traversing the glass surface at 1.25 m 2 / 15min, abrasive agglomerates at the time of processing a 4m 2 is sufficiently remained Was.

実施例4
エポキシ樹脂10g、硬化剤2g、研磨砥粒としてアルミナ粒子(♯2000)を12g、さらに金属粒子として錫粒子40gを混ぜ、PVFMスポンジでなる基材の表面に、砥石面積が80%になるように約1mmφのドット状に形成させた後、60℃で乾燥させ、さらに80℃で反応させた。得られた研磨材で、スポンジ部に水を含ませた状態でキッチンシンクを清掃研磨したところ、水の供給が少なくても汚れが良好に落ちた。
Example 4
10 g of epoxy resin, 2 g of curing agent, 12 g of alumina particles (# 2000) as abrasive grains, and 40 g of tin particles as metal particles are mixed so that the surface of the substrate made of PVFM sponge has a grinding wheel area of 80%. After forming into a dot shape of about 1 mmφ, it was dried at 60 ° C. and further reacted at 80 ° C. When the kitchen sink was cleaned and polished with the resulting abrasive in which water was contained in the sponge part, the dirt was satisfactorily removed even when the supply of water was small.

比較例1
エポキシ樹脂10g、硬化剤2g、研磨砥粒としてカオリン10gを混ぜ、PVFMスポンジでなる基材の表面に、砥石面積が100%になるように塗布した後、60℃で乾燥固化させた。得られた研磨材は屈曲性・耐久性がなく、折り曲げると研磨砥粒塊の表面にひび割れが生じる、などの不具合が発生した。細かい部分の研磨に不向きであった。
Comparative Example 1
10 g of epoxy resin, 2 g of curing agent, and 10 g of kaolin as abrasive grains were mixed and applied to the surface of the substrate made of PVFM sponge so that the grindstone area was 100%, and then dried and solidified at 60 ° C. The obtained abrasive material was not flexible and durable, and had problems such as cracking on the surface of the abrasive grain lump when bent. It was not suitable for polishing fine parts.

比較例2
エポキシ樹脂10g、硬化剤2g、研磨砥粒としてカオリン10gを混ぜ、PVFMスポンジでなる基材の表面に、砥石面積が20%になるように塗布した後、60℃で乾燥固化させた。得られた研磨材の屈曲性・耐久性はあったが、研磨力(研磨性能)は実施例1と比較すると劣っていた。
Comparative Example 2
10 g of epoxy resin, 2 g of curing agent, and 10 g of kaolin as abrasive grains were mixed and applied to the surface of a substrate made of PVFM sponge so that the grindstone area was 20%, and then dried and solidified at 60 ° C. Although the obtained abrasive was flexible and durable, its polishing power (polishing performance) was inferior to that of Example 1.

比較例3
エポキシ樹脂10g、硬化剤2g、研磨砥粒としてカオリン10gを混ぜ、250μmの気孔径を持ったPVFMスポンジでなる基材の表面に、砥石面積が50%になるように塗布した後、60℃で乾燥固化させた。得られた研磨材はドット高さが低く、研磨力(研磨性能)は実施例1と比較すると劣っていた。
Comparative Example 3
10 g of epoxy resin, 2 g of curing agent, and 10 g of kaolin as abrasive grains are mixed and applied to the surface of a substrate made of PVFM sponge having a pore size of 250 μm so that the grindstone area becomes 50%, and then at 60 ° C. Dry and solidify. The obtained abrasive had a low dot height, and the polishing power (polishing performance) was inferior to that of Example 1.

比較例4
エポキシ樹脂10g、硬化剤2g、研磨砥粒としてカオリン10gを混ぜ、ウレタン独立気泡型スポンジでなる基材の表面に、砥石面積が50%になるように塗布した後、60℃で乾燥固化させた。得られた研磨材の研磨力(研磨性能)に問題はなかったが、清掃研磨面のスラッジの拭き取り性能が劣っていた。
Comparative Example 4
10 g of epoxy resin, 2 g of curing agent, and 10 g of kaolin as abrasive grains were mixed and applied to the surface of a base material made of urethane closed-cell sponge so that the grindstone area was 50%, and then dried and solidified at 60 ° C. . There was no problem in the polishing power (polishing performance) of the obtained abrasive, but the sludge wiping performance on the cleaned polishing surface was inferior.

比較例5
エポキシ樹脂10g、硬化剤2g、研磨砥粒として人工ダイヤモンド粒子4g、さらに実施例3の金属粒子に代えてゼオライトを混ぜ、PVFMスポンジでなる基材の表面に、砥石面積が80%になるように約1mmφのドット状に形成させた後、60℃で乾燥させ、さらに80℃で反応させた。得られた研磨材で、スポンジ部に水を含ませた状態でうろこ状の汚れが付着したガラスを清掃研磨したところ、水の供給が少なくても汚れが良好に落ちた。
ただし、ライフ向上効果を検証するため、電動ツール(オービタルサンダー)に貼付のうえ、ガラス面を1.25m/15minにてトラバースしたところ、4mを処理した時点で研磨砥粒塊は磨滅消失した。
Comparative Example 5
10 g of epoxy resin, 2 g of curing agent, 4 g of artificial diamond particles as abrasive grains, and zeolite instead of the metal particles of Example 3 are mixed so that the surface of the substrate made of PVFM sponge has a grinding wheel area of 80%. After forming into a dot shape of about 1 mmφ, it was dried at 60 ° C. and further reacted at 80 ° C. When the obtained abrasive was cleaned and polished on a glass with scaly dirt adhered in a state where water was contained in the sponge portion, the dirt was satisfactorily removed even if the supply of water was small.
However, in order to verify the life-improving effect, after it attached to the electric tool (orbital sander), was traversing the glass surface at 1.25m 2 / 15min, abrasive grain mass at the time of processing the 4m 2 is abrasion loss did.

比較例6
エポキシ樹脂10g、硬化剤2g、研磨砥粒としてアルミナ粒子(♯2000)を12g、さらに金属粒子として錫粒子40gを混ぜ、PVFMスポンジでなる基材の表面に、砥石面積が100%になるように塗布形成させた後、60℃で乾燥させ、さらに80℃で反応させた。得られた研磨材は屈曲性がなく、折り曲げると研磨材面にひび割れを生じるなどの不具合が発生した。
Comparative Example 6
10 g of epoxy resin, 2 g of curing agent, 12 g of alumina particles (# 2000) as abrasive grains, and 40 g of tin particles as metal particles are mixed so that the surface of the substrate made of PVFM sponge has a grinding wheel area of 100%. After coating and forming, it was dried at 60 ° C. and further reacted at 80 ° C. The obtained abrasive was not flexible, and problems such as cracking of the abrasive surface occurred when bent.

比較例7
エポキシ樹脂10g、硬化剤2g、研磨砥粒としてアルミナ粒子(♯2000)を12g、さらに金属粒子として錫粒子40gを混ぜ、PVFMスポンジでなる基材の表面に、砥石面積が20%になるように塗布形成させた後、60℃で乾燥させ、さらに80℃で反応させた。得られた研磨材の屈曲性や耐久性はあったが、研磨力(研磨性能)は、実施例4に比べて劣っていた。
Comparative Example 7
10 g of epoxy resin, 2 g of curing agent, 12 g of alumina particles (# 2000) as abrasive grains, and 40 g of tin particles as metal particles are mixed so that the surface of the substrate made of PVFM sponge has a grinding wheel area of 20%. After coating and forming, it was dried at 60 ° C. and further reacted at 80 ° C. Although the obtained abrasive was flexible and durable, the polishing power (polishing performance) was inferior to that of Example 4.

比較例8
エポキシ樹脂10g、硬化剤2g、研磨砥粒として人工ダイヤモンド粒子4g、さらに金属粒子として銅粒子61gを混ぜ、250μmの気孔径を備えたPVFMスポンジでなる基材の表面に、砥石面積が80%になるように塗布形成させた後、60℃で乾燥させ、さらに80℃で反応させた。得られた研磨材は、ドット高さが低く、研磨力(研磨性能)は、実施例3に比べて劣っていた。
Comparative Example 8
10 g of epoxy resin, 2 g of curing agent, 4 g of artificial diamond particles as abrasive grains, and 61 g of copper particles as metal particles are mixed, and the surface of the base material made of PVFM sponge with a pore size of 250 μm has a grinding wheel area of 80%. After coating and forming in such a manner, it was dried at 60 ° C. and further reacted at 80 ° C. The obtained abrasive had a low dot height, and the polishing power (polishing performance) was inferior to that of Example 3.

比較例9
エポキシ樹脂10g、硬化剤2g、研磨砥粒として人工ダイヤモンド粒子4g、さらに金属粒子として銅粒子61gを混ぜ、ウレタン独立気泡型スポンジでなる基材の表面に、砥石面積が80%になるように塗布形成させた後、60℃で乾燥させ、さらに80℃で反応させた。得られた研磨材は、研磨力(研磨性能)を有するものの、スポンジ基材との固着力が乏しく、ドット状の研磨砥粒塊が脱落しやすいほか、スポンジ部が吸水性を有していないことから清掃研磨面のスラッジの拭取り性能が劣っていた。
Comparative Example 9
10 g of epoxy resin, 2 g of curing agent, 4 g of artificial diamond particles as abrasive grains, and 61 g of copper particles as metal particles are mixed and applied to the surface of a base material made of urethane closed cell sponge so that the grindstone area is 80%. After forming, it was dried at 60 ° C. and further reacted at 80 ° C. Although the obtained abrasive has polishing power (polishing performance), it has poor adhesion to the sponge base material, and the dot-shaped abrasive grains lump easily and the sponge does not have water absorption. Therefore, the wiping performance of the sludge on the cleaning polished surface was inferior.

表1には、実施例1〜5、比較例1〜9についての研磨砥粒塊に含まれるエポキシ樹脂、硬化剤、研磨砥粒の含有量、金属粒子の含有量、砥石面積、基材の種類などを掲げ、表2には実施例1〜5、比較例1〜9についての評価結果を掲げた。   In Table 1, the epoxy resin, the curing agent, the content of abrasive grains, the content of metal particles, the grindstone area, and the base material contained in the abrasive grain lump for Examples 1 to 5 and Comparative Examples 1 to 9 Table 2 lists the evaluation results for Examples 1 to 5 and Comparative Examples 1 to 9.

表1
┌────┬─────┬───┬───┬────┬────┬─────────┐
│ │エポキシ │硬化剤│砥 粒│金属粒子│砥石面積│ 基 材 │
│ │樹脂(g)│(g)│(g)│ (g) │ (%) │ (g) │
├────┼─────┼───┼───┼────┼────┼─────────┤
│実施例1│ 10 │ 2 │ 10 │ 0 │ 50 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径100μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│実施例2│ 10 │ 2 │ 10 │ 0 │ 30 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径100μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│実施例3│ 10 │ 2 │ 4 │ 61 │ 80 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径100μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│実施例4│ 10 │ 2 │ 12 │ 40 │ 80 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径100μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│比較例1│ 10 │ 2 │ 10 │ 0 │ 100 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径100μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│比較例2│ 10 │ 2 │ 10 │ 0 │ 20 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径100μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│比較例3│ 10 │ 2 │ 10 │ 0 │ 50 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径250μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│比較例4│ 10 │ 2 │ 10 │ 0 │ 50 │ウレタン独立気泡 │
│ │ │ │ │ │ │型スポンジ │
├────┼─────┼───┼───┼────┼────┼─────────┤
│比較例5│ 10 │ 2 │ 4 │ 0 │ 80 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径100μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│比較例6│ 10 │ 2 │ 12 │ 40 │ 100 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径100μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│比較例7│ 10 │ 2 │ 12 │ 40 │ 20 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径100μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│比較例8│ 10 │ 2 │ 4 │ 61 │ 80 │PVFMスポンジ │
│ │ │ │ │ │ │気孔径250μm │
├────┼─────┼───┼───┼────┼────┼─────────┤
│比較例9│ 10 │ 2 │ 4 │ 61 │ 80 │ウレタン独立気泡 │
│ │ │ │ │ │ │型スポンジ │
└────┴─────┴───┴───┴────┴────┴─────────┘
表2
┌────┬────────────────────────────────┐
│ │ 評価結果 │
├────┼────────────────────────────────┤
│実施例1│良好 │
├────┼────────────────────────────────┤
│実施例2│良好 │
├────┼────────────────────────────────┤
│実施例3│良好 │
├────┼────────────────────────────────┤
│実施例4│良好 │
├────┼────────────────────────────────┤
│比較例1│研磨砥粒塊に部分的ひび割れが発生。 │
├────┼────────────────────────────────┤
│比較例2│研磨力が小さい。 │
├────┼────────────────────────────────┤
│比較例3│研磨砥粒塊をドット状に形成することが困難で研磨力が低い。 │
├────┼────────────────────────────────┤
│比較例4│研磨後のスラッジ洗浄が困難。 │
├────┼────────────────────────────────┤
│比較例5│研磨持続性能が劣る。 │
├────┼────────────────────────────────┤
│比較例6│研磨層にひび割れが発生した。 │
├────┼────────────────────────────────┤
│比較例7│研磨力が劣る。 │
├────┼────────────────────────────────┤
│比較例8│ドット状の研磨砥粒塊を高く膨出させることが困難で、研磨力も劣る。│
├────┼────────────────────────────────┤
│比較例9│ドット状の研磨砥粒塊が剥離しやすい。スラッジ清掃性が劣る。 │
└────┴────────────────────────────────┘
Table 1
┌────┬─────┬───┬───┬────┬────┬┬─────────┐
│ │Epoxy │Hardening agent │Abrasive grain│Metal particle │Whetstone area│ Base material │
│ │Resin (g) │ (g) │ (g) │ (g) │ (%) │ (g) │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Example 1│ 10 │ 2 │ 10 │ 0 │ 50 │PVFM sponge │
│ │ │ │ │ │ │Pore diameter 100μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Example 2│ 10 │ 2 │ 10 │ 0 │ 30 │PVFM sponge │
│ │ │ │ │ │ │Pore diameter 100μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Example 3│ 10 │ 2 │ 4 │ 61 │ 80 │PVFM sponge │
│ │ │ │ │ │ │Pore diameter 100μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Example 4│ 10 │ 2 │ 12 │ 40 │ 80 │PVFM sponge │
│ │ │ │ │ │ │Pore diameter 100μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Comparative Example 1│ 10 │ 2 │ 10 │ 0 │ 100 │PVFM sponge │
│ │ │ │ │ │ │Pore diameter 100μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Comparative Example 2│ 10 │ 2 │ 10 │ 0 │ 20 │PVFM sponge │
│ │ │ │ │ │ │Pore diameter 100μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Comparative Example 3│ 10 │ 2 │ 10 │ 0 │ 50 │PVFM sponge │
│ │ │ │ │ │ │ Pore diameter 250μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Comparative Example 4│ 10 │ 2 │ 10 │ 0 │ 50 │Urethane closed cell │
│ │ │ │ │ │ │ type sponge │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Comparative Example 5│ 10 │ 2 │ 4 │ 0 │ 80 │PVFM sponge │
│ │ │ │ │ │ │Pore diameter 100μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Comparative Example 6│ 10 │ 2 │ 12 │ 40 │ 100 │PVFM sponge │
│ │ │ │ │ │ │Pore diameter 100μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Comparative Example 7│ 10 │ 2 │ 12 │ 40 │ 20 │PVFM sponge │
│ │ │ │ │ │ │Pore diameter 100μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Comparative Example 8│ 10 │ 2 │ 4 │ 61 │ 80 │PVFM sponge │
│ │ │ │ │ │ │ Pore diameter 250μm │
├────┼─────┼───┼───┼────┼────┼┼─────────┤
│Comparative Example 9│ 10 │ 2 │ 4 │ 61 │ 80 │Urethane closed cell │
│ │ │ │ │ │ │ type sponge │
└────┴─────┴───┴───┴────┴────┴┴─────────┘
Table 2
┌────┬────────────────────────────────┐
│ │ Evaluation results │
├────┼────────────────────────────────┤
│Example 1│Good │
├────┼────────────────────────────────┤
│Example 2│Good │
├────┼────────────────────────────────┤
│Example 3│Good │
├────┼────────────────────────────────┤
│Example 4│Good │
├────┼────────────────────────────────┤
│Comparative Example 1│Partial cracks occurred in the abrasive grain lump. │
├────┼────────────────────────────────┤
│Comparative Example 2│Poor polishing power is small. │
├────┼────────────────────────────────┤
| Comparative Example 3 | It is difficult to form the abrasive grain lump in a dot shape and the polishing power is low. │
├────┼────────────────────────────────┤
│Comparative Example 4│It is difficult to clean sludge after polishing. │
├────┼────────────────────────────────┤
│Comparative Example 5│Poor polishing performance is poor. │
├────┼────────────────────────────────┤
| Comparative Example 6 | Cracks were generated in the polishing layer. │
├────┼────────────────────────────────┤
│Comparative Example 7│Poor polishing power. │
├────┼────────────────────────────────┤
| Comparative Example 8 | It is difficult to make the dot-shaped abrasive grains lump highly, and the polishing power is inferior. │
├────┼────────────────────────────────┤
│Comparative Example 9│Dot-like abrasive grains lump easily. Sludge cleanability is poor. │
└────┴────────────────────────────────┘

本発明に係る研磨用具では、その用途に応じて研磨砥粒塊2の組成を変更しておくことも可能である。たとえば、研磨砥粒塊2が、研磨砥粒21と共に金属粒子を含んでいる研磨用具において、鏡やガラスのうろこ状の水垢落しとしての用途には、基材1に、厚さ10mm程度のポリビニルホルマール(PVFM)スポンジを採用し、そのPVFMスポンジの表面に、ダイヤモンド粒子(研磨粒子)と銅粒子(金属粒子)とエポキシ樹脂とを6:83:11の含有比率で含む研磨砥粒塊2を形成したものを用いることが可能である。この場合の研磨用具の縦横サイズは、たとえば75x45mmが適切である。また、ステンレスシンク周りの錆落しや水垢落しとしての用途には、基材1に、厚さ10mm程度のPVFMスポンジを採用し、そのPVFMスポンジの表面に、アルミナ粒子(研磨粒子)と錫粒子(金属粒子)とエポキシ樹脂とを20:66:14の含有比率で含む研磨砥粒塊2を形成したものを用いることが可能である。この場合の研磨用具の縦横サイズは、たとえば75x45mmが適切である。さらに、水道蛇口周りの水垢落し汚れ落しとしての用途には、基材1に、厚さ1.4mm程度の人工皮革を採用し、その人工皮革の表面に、アルミナ粒子(研磨粒子)と錫粒子(金属粒子)とエポキシ樹脂とを20:66:14の含有比率で含む研磨砥粒塊2を形成したものを用いることが可能である。この場合の研磨用具の縦横サイズは、たとえば120x40mm程度の細長い帯状の形状を採用しておくことが適切である。基材1に人工皮革を用いた細長い帯状の研磨用具は、当該研磨用具の中間部を被研磨箇所に巻き付け状に重ねた状態で、その研磨用具の両端を手でつかんで往復移動させるといった作業を容易に行うことができる。   In the polishing tool according to the present invention, the composition of the abrasive grain lump 2 can be changed according to the application. For example, in a polishing tool in which the abrasive grain lump 2 contains metal particles together with the abrasive grains 21, for use as a scaly descaler of mirrors or glass, the base material 1 has a thickness of about 10 mm. A formal abrasive (PVFM) sponge is adopted, and the abrasive lump 2 containing diamond particles (abrasive particles), copper particles (metal particles) and epoxy resin in a content ratio of 6:83:11 on the surface of the PVFM sponge. What is formed can be used. In this case, for example, 75 × 45 mm is appropriate for the vertical and horizontal sizes of the polishing tool. In addition, for the purpose of removing rust and water around the stainless steel sink, a PVFM sponge having a thickness of about 10 mm is adopted as the base material 1, and alumina particles (abrasive particles) and tin particles (on the surface of the PVFM sponge) It is possible to use those in which the abrasive grain lump 2 containing the metal particles) and the epoxy resin in a content ratio of 20:66:14 is formed. In this case, for example, 75 × 45 mm is appropriate for the vertical and horizontal sizes of the polishing tool. Furthermore, for the purpose of removing water and dirt around the water faucet, artificial leather having a thickness of about 1.4 mm is adopted as the base material 1, and alumina particles (abrasive particles) and tin particles are formed on the surface of the artificial leather. What formed the abrasive grain lump 2 which contains (metal particle) and an epoxy resin by the content ratio of 20:66:14 can be used. The vertical and horizontal sizes of the polishing tool in this case are appropriately adopted as an elongated strip shape of about 120 × 40 mm, for example. An elongated belt-like polishing tool using artificial leather as the base material 1 is a work of reciprocating by holding both ends of the polishing tool by hand while the intermediate portion of the polishing tool is wrapped around the portion to be polished. Can be easily performed.

1 基材
2 研磨砥粒塊
12 吸水面
21 研磨砥粒
22 バインダ
DESCRIPTION OF SYMBOLS 1 Base material 2 Abrasive grain lump 12 Water absorption surface 21 Abrasive grain 22 Binder

Claims (14)

吸水性を有する基材と、この基材に固定されてその基材の表面に間隔を隔てて散在する多数の研磨砥粒塊と、を備え、
上記基材は、気孔径が30〜200μmであり、気孔率が80〜95%である連続気孔型のポリビニルホルマール樹脂のスポンジでなり、
個々の上記研磨砥粒塊がバインダによって結合された多数の研磨砥粒の集合体でなり、その研磨砥粒塊が上記基材の表面から膨出されて正面視ドット形状に形成され、この研磨砥粒塊の上記バインダがスポンジの気孔に入り込むことによってその研磨砥粒塊と基材の表面との接合力が高められていると共に、上記基材の裏面は、その全体が、上記基材の吸水性に基づく吸水面として形成されていることを特徴とする研磨用具。
A substrate having water absorption, and a large number of abrasive grains lump fixed to the substrate and scattered on the surface of the substrate at intervals,
The base material is a continuous pore type polyvinyl formal resin sponge having a pore diameter of 30 to 200 μm and a porosity of 80 to 95%,
Becomes a collection of a large number of abrasive grains each of said abrasive agglomerates are bonded by a binder, the abrasive agglomerates is bulged from the surface of the substrate is formed in the front view dot shape, the polishing As the binder of the abrasive grain mass enters the pores of the sponge, the bonding force between the abrasive grain mass and the surface of the base material is enhanced, and the back surface of the base material is entirely composed of the base material. A polishing tool characterized by being formed as a water absorbing surface based on water absorption.
上記基材が手に持つことのできるサイズを備えたポリビニルホルマール樹脂であり、かつ、その基材の厚さが、1〜30mmである請求項1に記載した研磨用具。 The polishing tool according to claim 1, wherein the base material is a polyvinyl formal resin having a size that can be held by a hand, and the thickness of the base material is 1 to 30 mm . 上記研磨砥粒塊の正面視ドット形状が多角形である請求項1又は請求項2に記載した研磨用具。 The polishing tool according to claim 1 or 2 , wherein the polishing abrasive grain lump has a polygonal shape when viewed from the front. 上記研磨砥粒が、ダイヤモンド、立方晶窒化ホウ素、アルミナ、炭化珪素、炭酸カルシウム、ケイ酸塩鉱物、酸化セリウム、酸化ジルコニウム、シリカ、種子粉体、メラミン樹脂、から選ばれる無機粒子又は有機粒子のうちの少なくとも1種類以上でなり、
上記バインダが、エポキシ樹脂、メラミン樹脂、フェノール樹脂、シリコーン樹脂から選ばれる熱硬化性樹脂、ポリスチレン系樹脂、エチレン酢酸ビニル樹脂、フッ素樹脂から選ばれる熱可塑性樹脂のうちの少なくとも1種類以上からなる請求項1ないし請求項3のいずれか1項に記載した研磨用具。
The abrasive grains are inorganic particles or organic particles selected from diamond, cubic boron nitride, alumina, silicon carbide, calcium carbonate, silicate mineral, cerium oxide, zirconium oxide, silica, seed powder, melamine resin. At least one of them,
Claims wherein the binder comprises at least one of a thermoplastic resin selected from an epoxy resin, a melamine resin, a phenol resin, and a silicone resin, a polystyrene resin, an ethylene vinyl acetate resin, and a fluororesin. The polishing tool according to any one of claims 1 to 3 .
上記研磨砥粒が、モース硬度2〜2.5のケイ酸塩鉱物の1種であるカオリンの粒子である請求項4に記載した研磨用具。 The polishing tool according to claim 4 , wherein the abrasive grains are particles of kaolin, which is a kind of silicate mineral having a Mohs hardness of 2 to 2.5. 上記研磨砥粒塊が、30〜70wt%の研磨砥粒を含む請求項5に記載した研磨用具。 The polishing tool according to claim 5 , wherein the abrasive grain lump includes 30 to 70 wt% of abrasive grains. 上記研磨砥粒塊の数が、4〜12個/cm である請求項1ないし請求項6のいずれか1項に記載した研磨用具。 The number of the polishing abrasive agglomerates polishing tool as set forth in any one of claims 1 to 6 which is 4 to 12 / cm 2. 基材の表面に散在された多数の研磨砥粒塊の全体の表面積が、基材表面積の30〜80%である請求項1ないし請求項7のいずれか1項に記載した研磨用具。 The polishing tool according to any one of claims 1 to 7 , wherein the entire surface area of a large number of abrasive grains lump scattered on the surface of the substrate is 30 to 80% of the surface area of the substrate. 上記研磨砥粒塊が、上記研磨砥粒と共に金属粒子を含んでいる請求項1ないし請求項5のいずれか1項に記載した研磨用具。 The polishing tool according to any one of claims 1 to 5 , wherein the abrasive grain lump includes metal particles together with the abrasive grains. 上記金属粒子が、銅粒子及び錫粒子から選ばれた1種類以上からなる請求項9に記載した研磨用具。 The polishing tool according to claim 9 , wherein the metal particles comprise one or more selected from copper particles and tin particles. 基材の表面に散在された多数の研磨砥粒塊の全体の表面積が、基材表面積の80〜90%である請求項9又は請求項10に記載した研磨用具。 The polishing tool according to claim 9 or 10 , wherein the entire surface area of a large number of abrasive grains lump scattered on the surface of the substrate is 80 to 90% of the surface area of the substrate. 個々の上記研磨砥粒塊の最大サイズが1〜1.5mmである請求項9ないし請求項11のいずれか1項に記載した研磨用具。 The polishing tool according to any one of claims 9 to 11 , wherein a maximum size of each of the abrasive abrasive lump is 1 to 1.5 mm. 上記研磨砥粒塊の数が、50個/cm以上である請求項9ないし請求項12のいずれか1項に記載した研磨用具。 The number of the said abrasive grain lump is 50 piece / cm < 2 > or more, The polishing tool of any one of Claim 9 thru | or 12 . 上記研磨砥粒塊が、5〜50wt%の研磨砥粒を含む請求項9ないし請求項13のいずれか1項に記載した研磨用具。 The polishing tool according to any one of claims 9 to 13 , wherein the abrasive grain lump includes 5 to 50 wt% of abrasive grains.
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