JP6007378B2 - Hair adjustment method - Google Patents

Description

The present invention relates to a hair conditioning method for adjusting hair such as perm, color and treatment, and a mixture.

  Conventionally, in the beauty / barber field, various hair adjustments such as perms, hair colors, and treatments have been carried out.

  For example, in the case of a permanent that adjusts the wave of hair, a first agent containing a reducing agent and a second agent containing an oxidizing agent are used. In the permanent, the hair shape is fixed by cutting the cystine bond (SS bond) with the first agent and adjusting the hair shape, and then returning the cystine bond with the second agent.

  Moreover, if it is a hair color which changes the color of hair, an oxidation hair dye, a non-oxidation hair dye, a decoloring agent, an acid hair dye, a basic dye, etc. are used. For example, in the case of an oxidative hair dye, a first agent containing a dye and an alkali agent and a second agent containing a hydrogen peroxide solution are used. When this oxidative hair dye is used, a chemical reaction occurs when the first agent and the second agent are mixed, and the melanin pigment in the hair is decomposed and decolored. At the same time, the oxidative dye that has penetrated into the hair is oxidized. Color develops by polymerization.

  In addition, a treatment agent is used for treatments that nourish the hair. This treatment agent is composed of various substances that nourish the hair. When this treatment agent is used, the treatment agent is permeated into the hair by applying the water after steaming and heating the hair.

  Adjustment of hair such as perm and hair color is carried out by a procedure of leaving the drug for a certain period of time while the drug is applied to the hair, and then washing the drug away. In addition, hair adjustment by treatment is performed by a procedure in which urea is applied to the hair by spraying, then steamed and heated, and then the treatment agent is applied. For this reason, a certain standing time or procedure is required for the hair adjustment. If the standing time is long, there is a problem that the hair and scalp are damaged, and if there are many procedures, there is a problem that it takes time.

  The inventor specializes in the care of damaged hair and scalp and has seen the various damages that hair conditioning agents have done on the hair and scalp. In order not to put a burden on the hair and scalp, drug control and time reduction are important points. The present inventor holds about 220 seminars per year and teaches more than 60,000 beauticians hair conditioning. However, the reality is that there is no end to damage to the hair and scalp, and there is a limit in the hair conditioning agents currently used. Moreover, even if it treats hair, the treatment agent currently used and the procedure of use cannot obtain a big effect, and the limit is felt.

  A prior art search was conducted upon filing this patent application, and a cold perm treatment method was proposed (see Patent Document 1). In this method, after treatment with a first agent consisting of a reducing agent for cold perm, and before treatment with a second agent consisting of an oxidizing agent for cold perm, the hair is then treated with strongly electrolytic acid water. It is characterized by processing. This is said to reduce hair damage.

JP 2000-139546 A

  However, Patent Document 1 requires a standing time of 20 minutes to 40 minutes, which is the same as the standing time after applying the first agent, and cannot prevent hair damage during this period. .

In view of the above-described problems, an object of the present invention is to provide a hair conditioning method and a mixture that shorten time, reduce hair damage, or care for hair.

The present invention relates to a hair conditioning method for adjusting the state of hair with a color agent, a permanent agent, or a treatment agent , which is a hair conditioning agent, wherein the hair is composed of alkaline reduced ionized water before the hair conditioning agent is used. A pretreatment step for allowing the conditioning aid to penetrate into the hair, and / or an application step for treating the hair using a mixture of the hair conditioning aid mixed with at least a part of the hair conditioning agent, and the alkali A hair conditioning method using alkaline reduced ion water having a mineral content of 0.3% or less as the reduced ion water, wherein the mineral contained in the alkali reduced ion water is negatively charged. It is characterized by being.

  According to the present invention, the standing time can be shortened and hair damage can be reduced.

The block diagram which shows a hair adjustment adjuvant, a color agent, and a permanent agent. The block diagram which shows a hair adjustment adjuvant and a treatment agent. Explanatory drawing of the hair dyed by Examples 1, 2 and Comparative Examples 1, 2, 3. FIG. Explanatory drawing of the color fading state by the shampoo of Example 1 and Comparative Example 2. FIG. Explanatory drawing of the color fading state by the shampoo of Example 3. FIG. Explanatory drawing of the hair which gave the permanent by Example 4 and Comparative Examples 4 and 5. FIG. Explanatory drawing of the wave drop state by the shampoo of Example 4 and Comparative Example 4. FIG. Explanatory drawing of the wave drop state by the shampoo of Example 5. FIG.

Hereinafter, an embodiment of the present invention will be described with reference to the drawings.
FIG. 1 is an explanatory diagram for explaining the configurations of a hair conditioning aid, a color agent, and a permanent agent, and FIG. 2 is an explanatory diagram for explaining the configurations of a hair conditioning aid and a treatment agent.

  FIG. 1 (A) shows a hair conditioning aid 1, a color 1 agent 2, and a color 2 agent 3 used for hair dyeing. FIG. 1B shows a mixture 4 and a color 2 agent 3 in which a hair conditioning aid 1 and a color 1 agent 2 are mixed. FIG. 1C shows a mixture 5 in which the mixture 4 and the color 2 agent 3 are mixed.

FIG. 1 (D) shows a hair conditioning aid 1, a permanent 1 agent 7 and a permanent 2 agent 8 used for the permanent. FIG. 1E shows a mixture 9 in which the hair conditioning aid 1 and the perm 1 are mixed, and a perm 2 8.
FIG. 2A shows the hair conditioning aid 1 and the treatment agent 11 used for the treatment. FIG. 2B shows a mixed agent 12 in which the hair conditioning aid 1 and the treatment agent 11 are mixed.

<Hair conditioning aid>
The hair conditioning aid 1 can be made into alkaline reduced ionic water electrolyzed by adding an additive to distilled water, and further electrolytically reduced ionic water (for example, electrolytically reduced ionic water S-) subjected to a deoxygenation step or the like. 100, electrolytic reducing ionic water S-120, or electrolytic reducing ionic water S-109). The additive may be, for example, silicon, magnesium, sulfuric acid or the like, or a plurality of these, and may be an additive that becomes a mineral. The hair conditioning aid 1 is a liquid composed of alkali reduced ionic water, such as alkali reduced ionic water itself, or a solution obtained by diluting alkali reduced ionic water with alkali ion water, mineral water, or purified water. When diluting, the dilution can be 3 times or less, and preferably 2 times or less.

  Electroreductive ionic water, which is a kind of alkaline reduced ionic water, can be obtained by performing a deoxygenation step, an electrolysis step, and a stabilization step on pure water.

  The deoxygenation step can be a step of performing deoxygenation treatment by an appropriate method such as an ion exchange membrane method, whereby the concentration of dissolved oxygen in pure water is reduced from the normal value of 8 ppm to 1 ppm or less.

  In the electrolysis process, using a high-voltage electrolyzer, an electrode is placed in deoxygenated pure water to electrolyze the pure water, and water on the cathode chamber side where the negative electrode is placed is taken out. It can be set as the process of performing an electrolysis process. The voltage of the electrolyzer can be 200 V or higher, preferably 250 V or higher, and preferably about 300 V. Here, a mineral having a large negative charge is contained in the water on the cathode chamber side, and the water on the cathode chamber side having a stronger negative charge is used as the alkali reduced ion water of the present invention.

The stabilization process executes a stabilization process in which the deionized water electrolyzed in the electrolysis process is laid down for a predetermined period in a state where a predetermined pressure is applied in a sealed stabilization tank. .
The predetermined pressure can be 4 kg / cm 2 or more, preferably 12 kg / cm 2.
The predetermined period can be 2 to 3 days.

In this way, alkali-reduced ionic water (including electrolytically-reducible ionic water) taken out from the device of the negative electrode chamber in which negative charges are strengthened is obtained.
The alkali-reduced ionic water thus obtained has a structure in which dissolved oxygen is 4 ppm, osmotic pressure is 107 milliosmoles with respect to water 1, and negatively charged minerals are contained in less than 0.3%.

  Alkaline reduced ionic water (including electrolytically reduced ionic water) can be adjusted to pH 8 or higher, preferably 9.5 or higher, more preferably pH 10 or higher, and pH 10.5 to 12.5. More preferably, pH 11.5 to 12.5 is more preferable, and pH around 12 is suitable.

Further, the alkali-reduced ion water (including electrolytically-reducible ion water) preferably contains a small amount (less than 0.3%) of negatively charged mineral ions that can be legally called water. Specifically, the mineral ions in the alkali reduced ion water (including electrolytically reduced ion water) can be 0.3% or less, and preferably less than 0.3%. Further, the lower limit value of mineral ions is preferably 0.01% or more, and more preferably 0.05% or more. Mineral ions may be any one or more of sodium, potassium, magnesium, phosphorus, chlorine, and silicon, and may include all of these or other configurations.
Alkaline reduced ionic water (including electrolytically reduced ionic water) is preferably lower than the surface tension of water, 72 mN / m (25 °), preferably 60 mN / m (25 °) or less, and 56 mN / m (25 It is preferable that the degree is about 0).
The osmotic pressure of alkali-reduced ionic water (including electrolytically-reducible ionic water) is preferably 90 to 120 milliosmoles, more preferably 100 to 110 milliosmoles with respect to water 1.

<Hair conditioner>
The hair conditioner refers to various agents that adjust hair, such as color agents that adjust the color of hair, permanent agents that adjust the wave degree of hair, and treatment agents that adjust hair cuticles.

<Coloring agent>
Coloring agents include dyes and aliants in color 1 agent 2 and oxidative hair dyes containing hydrogen peroxide in color 2 agent 3 and non-oxidative hair dyes that dye hair with polyphenols such as iron ions and tannins. , Acidic hair dyes that negatively charge acidic dyes ionically bind with the positive part of the keratin protein in the hair to color the hair, bleaching agents that decompose melanin using hydrogen peroxide, hair by melanin and hair dyeing An appropriate color agent such as a decoloring agent for decolorizing the pigment formed therein or a semi-permanent hair coloring agent for coating the hair cuticle with a dye by ionic bonding can be used. About 1 agent, alkaline is more preferable than weak acidity.

<Perm agent>
The permanent agent can be used for both wave forming and curly hair straightening, and is composed of a permanent agent 7 containing a reducing agent and an alkaline agent and a permanent agent 2 containing an oxidizing agent. An appropriate permanent agent can be used. It is preferable to use a permanent agent other than a strong acid. About 1 agent, alkaline is more preferable than weak acidity.

<Treatment agent>
Treatment agents include polymer feather (φ-type) keratin or keratin such as α-type keratin or γ-type keratin, collagen such as low to high molecular weight PPT, medium molecular collagen or silylated collagen, various amino acids, NMF, poly It can be composed of an appropriate substance such as glutamic acid such as glutamic acid that replenishes treatment components inside the hair. The treatment agent is preferably a liquid type rather than a cream type, and is more preferable because PPT (Polypeptide) is most strongly effective. Further, the treatment agent is preferably neutral to alkaline rather than acidic. The treatment agent preferably contains nutrients for hair.

<Color process>
The process of coloring hair using the hair conditioning aid 1 (color process) is as follows.

(1) Pretreatment step In the pretreatment step, the hair conditioning aid 1 is applied to the hair and allowed to stand for a predetermined time, and then water is removed. The hair conditioning aid applied at this time can be 100% alkali reduced ionic water or alkali reduced ionic water diluted to a predetermined concentration. By this pretreatment process, the state of the hair changes to a state in which the color agent can easily penetrate. That is, since the hair conditioning aid 1 has a low surface tension, the penetration rate of the color agent into the hair can be shortened. In addition, although it is preferable to perform this pre-processing process, it is also possible to abbreviate | omit a pre-processing process. Moreover, it is preferable not to wash the hair with a shampoo or the like before and after the pretreatment step. When washed with shampoo, the surfactant adheres to the hair and impedes the penetration of the colorant, but this can be prevented by not shampooing.

(2) Color agent application step In the color agent application step, as preparation before application, the color 1 agent 2 and the hair adjustment auxiliary agent 1 are mixed at a predetermined ratio, and further the color 2 agent 3 is mixed with the mixture 4 at a predetermined ratio. Mix. The mixing ratio of Color 1 Agent 2, Hair Adjustment Aid 1 and Color 2 Agent 3 is such that the ratio of Hair Adjustment Aid 1 in Mixture 5 where all are mixed can be 10% to 50%, 15% It is preferable to set it as -35%, and it is more preferable to set it as 20%-25%. The ratio of the color 1 agent 2 and the color 2 agent 3 can be a recommended ratio set by the manufacturer of the color agent according to the color agent, for example, a ratio of 1: 1, etc. Can do.

(3) Leaving step The leaving step can be 15 minutes or less, preferably 8 minutes or less, and more preferably about 5 minutes.

(4) Post-treatment step In the post-treatment step, the oxidation accelerator and the hair conditioning aid 1 are applied. The oxidation accelerator can be, for example, hematin, and it is preferable to carry out the penetration even when applied. The hair conditioning aid 1 is applied evenly over the entire hair by spraying and penetrates into the hair. Note that only the hair conditioning aid 1 may be applied without applying the oxidation accelerator. Even without an oxidation accelerator, a sufficient effect can be obtained with the hair conditioning aid 1.

(5) Leaving step In the leaving step, the applied hematin and hair conditioning auxiliary 1 are left for a predetermined time. This predetermined time can be set to 1 minute, for example.

(6) Sinking step In the sinking step, the hair is washed with water.

(7) Shampoo process In the shampoo process, the hair is washed with the shampoo.

(8) Finishing process In the finishing process, the hair is set by drying with a dryer.

  By performing color (hair dyeing) by the above steps, hair can be dyed in a short time. By shortening the time, the time that the hair is damaged by the color 1 agent 2 and the color 2 agent 3 can be shortened, and the damage to the hair can be reduced more than usual. Moreover, since the hair adjustment adjuvant 1 exhibits the treatment effect which protects a cuticle, it can also reduce damage to hair by performing hair dyeing in the state which exhibited this treatment effect.

  Furthermore, since the color preparation (Color 1 preparation 2 and Color 2 preparation 3) permeates into the hair sufficiently by the hair conditioning aid 1, the color preparation is sufficiently absorbed into the hair, not in a state where the color preparation is attached to the surface. A beautifully penetrated finish can be obtained.

  In addition, since the color agent has sufficiently penetrated into the hair, a good hair dyeing state can be maintained even if the number of days passes and the hair is washed many times.

  As described above, the present invention simultaneously solves the conflicting problem that a sufficient standing time is required to finish the hair in a sufficient hair dye state, and it is preferable to shorten the standing time in order to reduce hair damage. can do.

  Furthermore, the hair after dyeing according to the present invention is fresh and elastic, and feels very smooth when touched by hand. Therefore, the hair is not damaged by the hair dyeing, and the hair quality is better than before the hair dyeing, and the satisfaction of the user can be improved.

<Perm process>
The process of perming the hair using the hair conditioning aid 1 (perm process) is as follows.

(1) Pretreatment step In the pretreatment step, the hair conditioning aid 1 is soaked and left for 3 minutes, and then water is removed. By not shampooing before this pretreatment step, the hair conditioning aid 1 penetrates well into the hair. In addition, the hair conditioning aid 1 is sufficiently infiltrated into the hair in this pretreatment step, so that the hair damage caused by the following permanent agents (perm 1 agent 7 and perm 2 agent 8) is suppressed, and the permanent agent Promotes hair penetration and shortens SS bond breaking time.

(2) WIDING In winging, hair is wound around a rod of an appropriate size according to the customer's request.

(3) One agent application step In the one agent application step, the hair adjustment aid 1 is mixed with the permanent agent 7 at a predetermined ratio, and the mixture 9 is applied to the hair. The ratio of Perm 1 to Hair Adjustment Aid 1 can be 10% or more, preferably 20% or more, and preferably 40% or more. It is more preferable. When the hair conditioning aid 1 is about pH 12, the ratio of the permanent agent 7 and the hair conditioning aid 1 can be 10% to 90% of the hair conditioning aid 1 in the mixture 9; % To 80%, preferably 40% to 80%, more preferably 50% to 80%. When the hair conditioning aid 1 has a pH of about 10, the ratio of the permanent agent 7 and the hair conditioning aid 1 can be 10% to 70% of the hair conditioning aid 1 in the mixture 9. 20 % To 60%, preferably 30% to 50%, more preferably about 40%.

  It is noted that the hair of a person who performs perm for the first time (the hair of virgin perm) is better than the hair of a person who has performed perm in the past (ordinary hair). It is preferable to reduce the ratio. For example, in the case of virgin perm, the proportion of the hair conditioning aid 1 in the mixture 9 is preferably 10% to 50%, more preferably about 40%. Moreover, in the case of the hair which is easy to get permanent, it is preferable to make the ratio of the hair adjustment adjuvant 1 in the mixture 9 relatively larger than the case of normal hair.

(4) Leaving process In the neglecting process, it is left naturally for a predetermined time. This predetermined time is shorter than the normal leaving time recommended by the manufacturer for the permanent agent to be used (normal leaving time), and can be set to be half or less of the normal standing time. It is preferably 4 or less, more preferably about 1/5 of the normal standing time. Since the hair-binding auxiliary agent 1 can complete the separation of the SS bond in a short time, the hair damage can be suppressed by shortening the standing time accordingly.

(5) Intermediate water washing step In the intermediate water washing step, the perm 1 agent and the hair conditioning aid 1 are washed from the hair by washing with water to remove moisture.

(6) Two-agent application step In the two-agent application step, the permanent agent 8 is applied so as to hang down on the hair.

(7) Leaving process In the leaving process, the process is left for a predetermined time. This predetermined time can be shorter than the normal leaving time recommended by the manufacturer for the permanent agent to be used (normal leaving time), and is preferably less than half the normal leaving time. More preferably, it is about 1/3 of the time. This leaving step can be, for example, 1 minute.

(8) Hair adjustment auxiliary agent application process In the hair adjustment auxiliary agent application process, the hair adjustment auxiliary agent 1 is applied to the hair by spraying or the like and allowed to penetrate.

(9) Leaving process In the leaving process, the process is left for a predetermined time. This leaving step can be set to the same time as the above (7) leaving step, for example, 1 minute.

(10) Rod out In the rod out, the hair wound around the rod is unwound and the rod is removed.

(11) Water flushing process In the water flushing process, water is washed on the hair.

(12) Pre-rinsing step In the pre-rinsing step, the hair is rinsed.

(13) Finishing process In the finishing process, the hair is set by drying with a dryer.

  By performing perm by the above steps, perm can be performed in a short time. By shortening the time, the time that the hair is damaged by the permanent 1 agent 7 or the permanent 2 agent 8 can be shortened, and the hair damage can be reduced more than usual. Moreover, since the hair adjustment adjuvant 1 exhibits the treatment effect which protects a cuticle, it can also reduce the damage of hair by performing a permanent in the state which exhibited this treatment effect.

  Furthermore, since the permanent agent (perm 1 agent 7 and perm 2 agent 8) permeates the hair sufficiently by the hair adjustment aid 1, a beautiful finish with the perm firmly applied to the entire hair can be obtained.

  In addition, since the permanent is performed while the cuticle is protected, the hair after the permanent can be prevented from spreading and spreading, and a beautifully finished finish can be obtained.

  Furthermore, since the hair adjustment auxiliary agent 1 firmly perms, even if the number of days elapses and the hair is washed many times, a good perm state can be maintained.

  As described above, the present invention simultaneously solves the conflicting problem that a sufficient standing time is required to finish in a sufficient permanent state, and that it is preferable to shorten the standing time in order to reduce hair damage. be able to.

  Furthermore, the hair after perming according to the present invention is fresh and elastic, and feels very smooth when touched by hand. Therefore, the hair is not damaged by the perm, and the hair quality is better than before the perm, and the satisfaction of the user can be improved.

<Treatment process>
The process (treatment process) of treating hair using the hair conditioning aid 1 is as follows.

(1) Treatment agent application process
In the treatment agent application step, the hair adjustment aid 1 and the treatment agent 11 are mixed at a predetermined ratio, and the mixture 12 is applied to the hair. The ratio of the hair conditioning aid 1 to the treatment agent 11 can be 20% or more, preferably 40% to 90%, preferably 50% to 80%. % Is more preferable.

(2) Finishing process
In the finishing process, the hair is set by drying with a dryer.

  By performing the treatment by the above steps, the treatment agent 11 can be firmly penetrated into the hair in a short time. Specifically, even if the stock solution of the treatment agent 11 is applied as it is, it does not readily penetrate into the hair. For this reason, in a normal procedure, in order to promote the penetration of the treatment agent 11 into the hair, as a pretreatment, urea is sprayed on the hair and then steamed and warmed. Work to do is done. However, since the treatment agent 11 instantaneously penetrates into the hair by the hair adjustment aid 1, it is possible to save labor and shorten the time by eliminating work such as steaming and moistening. In addition, the treatment agent 11 can penetrate into the hair more firmly than the conventional method of steaming and moistening. Further, by not performing shampooing in advance, it is possible to prevent the surfactant contained in the shampoo from interfering with the penetration of the treatment agent 11 into the hair by the hair conditioning aid 1.

Thus, the treatment agent 11 penetrates firmly into the inside of the hair, so that the elasticity of the hair increases, and the texture changes from a sponge-like texture to a textured texture.
Furthermore, since the treatment agent 11 penetrates firmly into the hair, the duration of the treatment effect can be extended.

  Furthermore, the hair after treatment according to the present invention is fresh and elastic, and feels very smooth when touched by hand. Accordingly, it is possible to finish with very good hair quality and to improve user satisfaction.

As described above, the present invention can be treated by adding one type of hair conditioning aid 1 called alkali reduced ion water to the hair conditioning agent that is usually used by practitioners such as hairdressers. It is possible to prevent mistakes in the inventory, and inventory management is easy, so that it can be used conveniently.
Moreover, it can be used free of preservatives by using alkaline reduced ion water (specifically, in the range of pH 12 ± 0.5) exceeding pH 11.0 as the hair conditioning aid 1.

Examples of the present invention will be described below.
<Hair dyeing method>
First, examples of the hair dyeing method will be described.
As a color agent, a product of Nakano Pharmaceutical Co., Ltd. was used, Caradeco pave (NB5p) was used for Color 1 agent 2, and Caradecoxide N06 was used for Color 2 agent 3.
The hair conditioning aid 1 was used without diluting electrolytic reducing ionic water S-100 of AI System Product Co., Ltd., which is a kind of alkaline reduced ionic water. This electrolytic reducing ionic water S-100 contains 0.3% of a negatively charged mineral at pH 12 and has a surface tension of 56 mN / m (25 °).

  Using these color 1 agent 2, color 2 agent 3, and hair conditioning aid 1, hair is dyed in the above-described steps (1) to (8) of the color process, and the dyeing state and dyeing result of the hair dyeing result The durability of the hair and the damage to the hair were evaluated. The dyeing state was visually evaluated for the color density and the presence or absence of unevenness. The duration of dyeing was visually evaluated for color fading after multiple shampooing. The hair damage was touched by a hairdresser for sensory evaluation on the gloss, softness, moisture retention, and suppression of hair damage after treatment.

  Table 1 below shows the composition, time, and the like in each step for Examples 1, 2, and 3 and Comparative Examples 1, 2, and 3. In Table 1, “Leve” refers to “Hair conditioning aid 1” of the present invention, Examples 1 and 2 use pH 12, and Example 3 uses pH 10.

In Example 1, the concentration of the hair conditioning aid 1 in the color agent application step is about 20% (color 1 agent 2: hair conditioning aid 1: color 2 agent 3 = 2: 1: 2) and the standing time is 5 minutes. In Examples 2 and 3, the concentration of the hair conditioning aid 1 in the color agent coating step is about 5% (Color 1 agent 2: Hair conditioning aid 1: Color 2 agent). 3 = 10: 1: 10), and this is an example of a hair dyeing method when the standing time is 5 minutes.

  Comparative Example 1 is an example of a hair dyeing method performed according to the procedure and time recommended by the manufacturer of the colorant, and Comparative Example 2 is an example of a hair dyeing method when the standing time is slightly shortened, and Comparative Example 3 These are examples of the hair dyeing method when leaving time is shortened to the same time as Example 1,2.

<Dyeing condition>
◎: Color penetrates to the inside of the hair and is dyed well without unevenness ○: No unevenness but the inside of the hair is dyed well and the surface of the hair is well dyed △: No unevenness but penetrates to the inside Not dyed on the surface of the hair ×: The color is thin and the dyeing is insufficient

<Duration of dyeing>
(Double-circle): Even if shampoo is performed 4 times, there is almost no color fading.
○: Shampoo is applied 4 times and there is a slight color fading.
(Triangle | delta): The state which has discolored greatly after shampooing 4 times.
X: A state in which the color is greatly faded by shampooing four times and the color is considerably lightened.

<Hair damage>
A: Touched with a finger, moistened with no roughness, and bundles of hair bundles.
○: Touched with a finger, moistened with little roughness, and a bundle of hair bundles to some extent.
(Triangle | delta): The state which has a little roughness and the hair | bristle bundle has spread a little when touched with a finger.
X: A state in which the hair bundles are scattered and spread when touched with a finger.

  FIG. 3 is an explanatory view showing photographs of hair dyed in Examples 1 and 2 and Comparative Examples 1, 2 and 3 shown in Table 1. In this example, a yak wig is used. Actually, it is dyed brown and the difference in color is clearly seen, but even if the color photograph is grayscale (monochrome photograph) as shown in the figure, the difference in density appears.

As shown in FIG. 3 (A), the hair before dyeing is white.
As shown in FIG. 3B, the hair dyed in Example 1 is dyed well.
As shown in FIG. 3C, the hair dyed by Example 2 is dyed well.
As shown in FIG. 3D, the hair dyed by Comparative Example 1 is well dyed on the surface.
As shown in FIG. 3 (E), the hair dyed in Comparative Example 2 is dyed well to some extent on the surface.
As shown in FIG. 3 (F), the hair dyed according to Comparative Example 3 is clearly light in color and insufficiently dyed.

  Thus, in Examples 1 and 2, the color permeated to the inside of the hair even though the standing time after application of the colorant was set to 5 minutes, which is 1/6 of 30% recommended by the manufacturer. Hair dyeing has been realized.

  FIG. 4 is an explanatory diagram of a color fading state by a photograph of each state in which Example 1 and Comparative Example 2 are shampooed four times.

  4 (A) to 4 (D) show shampooed hair with the color according to Example 1, FIG. 4 (A) after one shampoo, FIG. 4 (B) after two shampoos, FIG. 4 (C) is after 3 times of shampooing, and FIG. 4 (D) is after 4 times of shampooing. As shown in the figure, even when shampooing is performed four times, the color is hardly lost, and a good hair dyeing state is maintained.

  4 (E) to 4 (H) are hairs that have been colored according to Comparative Example 2, FIG. 4 (E) is after one shampoo, FIG. 4 (F) is after two shampoos, and FIG. G) is after 3 times of shampooing, and FIG. 4 (H) is after 4 times of shampooing. As shown in the figure, at the first shampoo, the color has already faded slightly before the shampoo shown in FIG. 3 (E). White hair is visible.

FIG. 5 is an explanatory diagram of a color fading state by a photograph of hair dyed by Example 3 shown in Table 1 and photographs of each state in which the hair is shampooed a plurality of times.
FIG. 5A is a photograph of the hair colored according to Example 3, and FIGS. 5B to 5D are the hair shampooed with color according to Example 3. FIG. FIG. 5B shows shampooing twice, FIG. 5C shows shampooing four times, and FIG. 5D shows shampooing six times. As shown in the figure, even if shampooing is performed 6 times, the color is hardly lost, and a good hair dyeing state is maintained.

  Thus, in the conventional method, the color loss due to the shampoo is severe even in 20 minutes, which is slightly shorter than 30 minutes, which is the manufacturer's recommended time for the leaving step after the color agent coating step, whereas only 5 in Example 1 according to the present invention. Even if the shampoo is repeated for a minute, the hair can be finished in a good dyed state with almost no color fading.

  In addition, since the leaving step is only 1/6 of the normal amount, damage to the hair can be greatly reduced.

  Also, color 1 agent 2, color 2 agent 3 and hair adjustment auxiliary 1 are not mixed at the same time, but color 2 agent 3 and hair adjustment auxiliary 1 are mixed and then color 2 agent 3 is further mixed. Thus, it is possible to prevent the color 2 agent 3 and the hair adjustment auxiliary 1 from reacting and not exhibiting the effect of the hair adjustment auxiliary 1.

<Perm method>
Next, an example of the permanent method will be described.
The present invention can be used for both a perm that waves the hair and a perm that straightens the curly hair. In this embodiment, a permanent that waves the hair will be described.

  Design Direct Wave of Alumino Co., Ltd. is used as a permanent agent, Design Direct Wave 1st Agent (080CYS) for Perm 1 Agent 7, Design Direct Wave 2 Agent (CYS Thio 120, Hydrogen Peroxide Type) for Perm 2 Agent 8 ) Was used.

  The hair conditioning aid 1 was used without diluting electrolytic reducing ionic water S-100 of AI System Product Co., Ltd., which is a kind of alkaline reduced ionic water.

  Using these perm 1 agent, perm 2 agent 8 and hair conditioning aid 1, perm is applied to the hair in the steps (1) to (13) of the perm process described above, and the resulting perm state, perm Persistence and hair damage were evaluated. The state of the perm was visually evaluated for the degree of wave application. Permanent persistence was evaluated visually by applying several shampoos to weaken the wave. The hair damage was touched by a hairdresser for sensory evaluation on the gloss, softness, moisture retention, and suppression of hair damage after treatment.

  The following Table 2 shows the composition and time in each step for Examples 4 and 5 and Comparative Examples 4 and 5. In Table 2, “Leve” refers to “Hair conditioning aid 1” of the present invention, Example 4 uses pH 12, and Example 5 uses pH 10.

Example 4 is an example of a permanent method when the concentration of the hair conditioning aid 1 in the one-agent application step is about 60% and the standing time is 3 minutes, and Example 5 is a hair adjustment in the one-agent application step. This is an example of a permanent method when the concentration of the adjuvant 1 is about 40% and the standing time is 3 minutes. The ratio of the hair conditioning aid 1 of Example 4 is higher than that of Example 5 because the hair conditioning aid 1 having a pH of 12 than the pH of 10 can reduce the amount of use of the permanent agent to increase the penetration of the permanent agent. It is due to that.

  Comparative Example 4 is an example of a perm method carried out in accordance with the procedure and time recommended by the manufacturer of the permanent agent, and Comparative Example 5 is an example of a perm method in which the standing time is adjusted to Example 4 in the procedure recommended by the manufacturer. It is.

<Perm state>
A: A state where the waves are applied in a uniform and uniform manner.
○: A state where the waves are applied evenly and uniformly.
Δ: Slightly waved but insufficient.

<Permanent persistence>
A: The wave before shampoo is almost maintained even after 8 times of shampooing.
Δ: Wave is considerably weakened by 8 shampoos.
X: The state in which waves are almost eliminated by 8 times of shampooing

<Hair damage>
A: Touched with a finger, moistened with no roughness, and bundles of hair bundles.
(Triangle | delta): When it touches with a finger, it is a little rough and the state that the hair | bristle bundle is gathered to some extent.
X: A state in which the hair bundles are scattered and spread when touched with a finger.

  FIG. 6 is an explanatory view showing a photograph of hair subjected to perm in Example 4 and Comparative Examples 4 and 5 shown in Table 2. This procedure uses human hair wigs.

As shown in FIG. 6 (A), the hair before the permanent treatment is straight.
As shown in FIG. 6 (B), the hair subjected to the perm according to Example 4 is firmly and well waved and the hair bundle is gathered.
As shown in FIG. 6 (C), the hair subjected to the perm according to Comparative Example 4 is wavy to some extent, but the hair bundles are scattered.
As shown in FIG. 6 (D), the hair subjected to perm according to Comparative Example 5 is in a state where the hair bundle is gathered but the wave is weak and insufficient.

  As described above, in Examples 4 and 5, although the standing time after applying Perm 1 agent 7 was set to 3 minutes, which is 1/5 of 15/15 recommended by the manufacturer, the hair bundle was firmly fixed. A good perm with a wave can be realized.

  FIG. 7 is an explanatory view of a wave drop state by a photograph of each state where Example 4 and Comparative Example 4 are shampooed eight times.

  7 (A) to 7 (D) are hairs that have been shampooed after the perm according to Example 4, FIG. 7 (A) is after 2 shampoos, and FIG. 7 (B) is after 4 shampoos. FIG. 7C shows six times after shampooing, and FIG. 7D shows eight times after shampooing. As shown in the figure, even when shampooing is performed 8 times, almost no wave is lost, the hair is well-organized, and a good wave close to that of the permanent is maintained.

  7 (E) to 7 (H) show shampooed hair after applying the permanent according to Comparative Example 4, FIG. 7 (E) is after 2 times of shampoo, and FIG. 7 (F) is after 4 times of shampoo. FIG. 7 (G) shows 6 times after shampooing, and FIG. 7 (H) shows 8 times after shampooing. As shown in the figure, each time shampooing is repeated, the wave loosely collapses, and the hair unit becomes worse and spreads.

  FIG. 8 is an explanatory view showing a photograph of hair subjected to perm by Example 5 shown in Table 2, and a photograph of hair subjected to shampooing a plurality of times. This procedure uses human hair wigs.

  As shown in FIG. 8 (A), the hair subjected to the perm according to Example 5 is firmly and well waved and the hair bundle is gathered. Thus, in Example 5, even though the standing time after applying Perm 1 agent 7 was set to 3 minutes, which is 1/5 of 15 recommended by the manufacturer, the wave was firmly waved in a state where the hair bundles were gathered. A good perm with a velocities has been achieved.

  8 (B) to 8 (E) show shampooed hair after applying the permanent according to Example 5, FIG. 8 (B) shows two times after shampooing, and FIG. 8 (C) shows four times after shampooing. FIG. 8 (D) shows 6 times after shampooing, and FIG. 8 (E) shows 8 times after shampooing. As shown in the figure, even when shampooing is performed 8 times, almost no wave is lost, the hair is well-organized, and a good wave close to that of the permanent is maintained.

  Thus, in the conventional method, even if the leaving step after the permanent agent application step is 15 minutes, which is the manufacturer's recommended time, the wave deterioration due to shampoo is severe, whereas in Example 4 according to the present invention, the leaving step is only 3 minutes. Even if shampoo is repeated depending on the process, it can be finished in a good wave state in which the wave is hardly broken.

  In addition, since the leaving step is only 1/5 of the normal, the damage to the hair can be greatly reduced.

<Treatment method>
Next, an example of the treatment method will be described.
In the present invention, various treatment agents applied to hair can be used. In this embodiment, treatment agents that nourish hair are described.

  As the treatment agent 11, a moist seed, a little seed series of Little Scientist GS Co., Ltd. was used. In addition, the same results as moist seeds were obtained when the smooth seeds and lively seeds of the same series were also used.

  The hair conditioning aid 1 was used without diluting electrolytic reducing ionic water S-100 of AI System Product Co., Ltd., which is a kind of alkaline reduced ionic water.

  Using these treatment agent 11 and hair conditioning aid 1, hair was treated according to the procedures (1) to (2) of the treatment step described above, and the resulting treatment state and treatment persistence were evaluated. The condition of the treatment was touched by a hairdresser for sensory evaluation of the elasticity and moistness of the hair.

  Table 3 below shows the composition and time in each step for Examples 6 and 7 and Comparative Examples 6 and 7. In Table 2, “Leve” refers to “Hair conditioning aid 1” of the present invention, Example 6 uses pH 12, and Example 7 uses pH 10.

  Examples 6 and 7 are examples of treatment methods when the concentration of the hair conditioning aid 1 in the treatment agent application step is about 20%.

  Comparative Examples 6 and 7 are examples of treatment methods performed with procedures and times recommended by the manufacturer of the treatment agent 11. In Comparative Example 6, an operation of applying urea by spraying is added in the pretreatment process so that a treatment effect can be obtained even in the case of bristles, etc., and in Comparative Example 7, the application of urea is omitted for normal hair. ing.

<State of treatment>
A: The treatment agent penetrates firmly to the inside, and when it is touched with a finger, it is sufficiently elastic and has a moist feel.
○: The treatment agent penetrates into the interior to some extent, and when touched with a finger, it has a certain elasticity and a slightly sticky feel can be obtained.
Δ: The treatment agent penetrates the surface a little, is slightly elastic when touched with a finger, and the surface is not rusted.
X: The treatment agent is not permeated, and the surface on which the elasticity is felt when touched with a finger is also rough.

<Durability of treatment>
A: A treatment effect can be obtained over a long period of time.
○: A state where the treatment effect can be obtained over a long period of time.
Δ: Treatment effect is obtained, but the duration is short.
X: A state where the treatment effect hardly lasts.

<Simpleness of work>
A: No work other than applying treatment agent is required.
X: Many operations are required in addition to applying the treatment agent.

Thus, according to the present invention, according to the present invention, the work that had to be performed by watering the hair, steaming and heating, applying the treatment agent on the hair, and further squeezing the hair was performed according to the present invention. It is only necessary to apply the agent, and the work can be simplified and the time can be shortened.
In addition, since the treatment agent 11 penetrates into the hair exceptionally compared to the conventional method, a higher treatment effect can be obtained.

The present invention is not limited to the above-described embodiment, and can be various embodiments.
For example, a combination of two or more of a perm method, a color method, and a treatment method can be applied to the hair.

  The present invention can be used for hair adjustment such as perm, hair color, and treatment.

DESCRIPTION OF SYMBOLS 1 ... Hair adjustment adjuvant 2 ... Color 1 agent 3 ... Color 2 agent 4, 5, 12 ... Mixture 7 ... Perm 1 agent 8 ... Perm 2 agent 9 ... Mixture 11 ... Treatment agent

Claims (4)

A hair conditioning method that adjusts the state of hair with a color agent, a permanent agent, or a treatment agent that is a hair conditioning agent ,
A pretreatment step for allowing hair conditioning aids composed of alkali reduced ion water to penetrate into the hair before using the hair conditioning agent;
Or / and
An application step of treating the hair with a mixture of the hair conditioning aid mixed with at least a part of the hair conditioning agent;
As the alkali reduced ion water, an alkali reduced ion water having a mineral content of 0.3% or less ,
The hair conditioning method, wherein the mineral contained in the alkali-reduced ionized water is negatively charged . The hair conditioning method according to claim 1 , wherein after the hair is treated with the hair conditioning agent, the hair conditioning aid is applied and left to stand . By not washing the hair with shampoo, the surfactant is not attached to the hair, and before using the hair conditioner, the hair conditioning aid penetrates into the hair, and further, the hair conditioner is used without washing with shampoo. <br/> claim 1 or 2 hair adjustment method according to adjust the hair. Alkaline reduced ionized water containing negatively charged minerals is mixed with hair conditioner color, perm or treatment.
Admixture .