JP5995447B2 - ガソリン製造装置 - Google Patents
ガソリン製造装置 Download PDFInfo
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- JP5995447B2 JP5995447B2 JP2012007216A JP2012007216A JP5995447B2 JP 5995447 B2 JP5995447 B2 JP 5995447B2 JP 2012007216 A JP2012007216 A JP 2012007216A JP 2012007216 A JP2012007216 A JP 2012007216A JP 5995447 B2 JP5995447 B2 JP 5995447B2
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J7/00—Apparatus for generating gases
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
- B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
- B01J2208/023—Details
- B01J2208/024—Particulate material
- B01J2208/025—Two or more types of catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/061—Methanol production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/06—Heat exchange, direct or indirect
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/56—Specific details of the apparatus for preparation or upgrading of a fuel
- C10L2290/562—Modular or modular elements containing apparatus
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Hydrogen, Water And Hydrids (AREA)
Description
CH4+H2O→3H2+CO・・・(式1)
CO+H2O→H2+CO2・・・(式2)
CO+2H2→CH3OH・・・(式3)
CO2+3H2→CH3OH+H2O・・・(式4)
2CH3OH→CH3OCH3+H2O・・・(式5)
1/2nCH3OCH3→(CH2)n+1/2nH2O・・・(式6)
11 反応管
12 燃焼部、
13 原料供給ライン
14 燃料供給ライン
15 廃熱回収部
16 煙突
17 排ガス−スチーム熱交換器
18 改質ガス供給ライン
19 改質ガス熱交換器
20 メタノール合成塔
22 メタノール供給ライン
30 ガソリン合成塔
32 ガソリン供給ライン
34 反応管
35 仕切部材
36 ダクト
40 空気予熱装置
41 燃焼用空気導入ライン
42 排ガス−燃焼用空気熱交換器
43 ファン
44 燃焼用空気供給ライン
45 スチーム−燃焼用空気熱交換器
Claims (5)
- メタノールからガソリンを製造するガソリン製造装置を備えるガソリン製造システムであって、
前記ガソリン製造装置が、
メタノールからガソリンを合成する反応管であって、前記反応管が、メタノールからジメチルエーテルを合成するジメチルエーテル合成用触媒と、ジメチルエーテルからガソリンを合成するガソリン合成用触媒との2種類の触媒が2段階に充填されている反応管と、
前記反応管の外側を空気が流れる流路と
を備え、前記反応管内で生じる合成熱と前記流路を流れる空気とで熱交換を行うとともに、前記流路が、前記反応管の前記ジメチルエーテル合成用触媒が充填されている部分の外側を流れた後、前記反応管の前記ガソリン合成用触媒が充填されている部分の外側を流れるように構成されているガソリン製造システム。 - 天然ガスを水蒸気改質して改質ガスを生成する水蒸気改質装置と、
前記水蒸気改質装置で生成した改質ガスから、前記ガソリン製造装置に供給するメタノールを合成するメタノール合成装置と、
前記水蒸気改質装置に供給する燃焼用空気として、前記ガソリン製造装置で熱交換を行った空気を供給する燃焼用空気供給ラインと
を更に備える請求項1に記載のガソリン製造システム。 - 前記反応管で生成されたガソリンを含む生成物と、前記反応管に供給するメタノールとで熱交換を行う第1のメタノール−ガソリン熱交換器と、
前記ガソリン製造装置の前記反応管と直列に配置され、前記第1のメタノール−ガソリン熱交換器で熱交換された前記生成物からガソリンを合成する第2のガソリン製造装置と
を更に備える請求項1に記載のガソリン製造システム。 - 前記第2のガソリン製造装置で生成されたガソリンと、前記第1のメタノール−ガソリン熱交換器に供給される前のメタノールとで熱交換を行う第2のメタノール−ガソリン熱交換器を更に備える請求項3に記載のガソリン製造システム。
- 前記第2のメタノール−ガソリン熱交換器に供給される前の前記第2のガソリン製造装置で生成されたガソリンによる熱交換でスチームを発生させるスチーム−ガソリン熱交換器を更に備える請求項4に記載のガソリン製造システム。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012007216A JP5995447B2 (ja) | 2012-01-17 | 2012-01-17 | ガソリン製造装置 |
US14/368,735 US9284234B2 (en) | 2012-01-17 | 2012-12-13 | Gasoline production device |
CA2862796A CA2862796C (en) | 2012-01-17 | 2012-12-13 | Gasoline production device |
PCT/JP2012/082328 WO2013108526A1 (ja) | 2012-01-17 | 2012-12-13 | ガソリン製造装置 |
AU2012366430A AU2012366430B2 (en) | 2012-01-17 | 2012-12-13 | Gasoline producing device |
EP12866393.7A EP2806014B1 (en) | 2012-01-17 | 2012-12-13 | Gasoline producing device and method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012007216A JP5995447B2 (ja) | 2012-01-17 | 2012-01-17 | ガソリン製造装置 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013147534A JP2013147534A (ja) | 2013-08-01 |
JP5995447B2 true JP5995447B2 (ja) | 2016-09-21 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012007216A Active JP5995447B2 (ja) | 2012-01-17 | 2012-01-17 | ガソリン製造装置 |
Country Status (6)
Country | Link |
---|---|
US (1) | US9284234B2 (ja) |
EP (1) | EP2806014B1 (ja) |
JP (1) | JP5995447B2 (ja) |
AU (1) | AU2012366430B2 (ja) |
CA (1) | CA2862796C (ja) |
WO (1) | WO2013108526A1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP6116801B2 (ja) * | 2012-01-17 | 2017-04-19 | 三菱重工業株式会社 | ガソリンを製造するシステム又は方法 |
US9981896B2 (en) | 2016-07-01 | 2018-05-29 | Res Usa, Llc | Conversion of methane to dimethyl ether |
US9938217B2 (en) | 2016-07-01 | 2018-04-10 | Res Usa, Llc | Fluidized bed membrane reactor |
WO2018004993A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Reduction of greenhouse gas emission |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
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US1972937A (en) * | 1930-03-05 | 1934-09-11 | Selden Co | Process for effecting catalytic reactions |
US4058576A (en) * | 1974-08-09 | 1977-11-15 | Mobil Oil Corporation | Conversion of methanol to gasoline components |
US4523046A (en) | 1982-02-25 | 1985-06-11 | Mobil Oil Corporation | Method for gasoline yield enhancement in the fixed bed methanol-to-gasoline process |
RU2098173C1 (ru) * | 1996-04-09 | 1997-12-10 | Инженерно-техническая фирма в форме товарищества с ограниченной ответственностью "Цеоконсалт" | Установка каталитического получения высокооктановых бензиновых фракций и ароматических углеводородов |
US6103143A (en) * | 1999-01-05 | 2000-08-15 | Air Products And Chemicals, Inc. | Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon |
JP4427173B2 (ja) * | 2000-08-16 | 2010-03-03 | 三菱重工業株式会社 | 合成ガスの製造方法 |
DE102004003003A1 (de) * | 2004-01-20 | 2005-09-01 | Basf Ag | Verfahren und Vorrichtung zur kontinuierlichen Herstellung einer chemischen Verbindung |
TWI324244B (en) * | 2006-01-18 | 2010-05-01 | Lg Chemical Ltd | Shell-and-tube reactor or heat exchanger, method for producing an oxide by using the same, and method for increasing the heat transfer coefficient of first tubes of the same |
WO2007111997A2 (en) * | 2006-03-23 | 2007-10-04 | Velocys Inc. | Process for making styrene using microchannel process technology |
EP2121873A2 (en) * | 2006-12-13 | 2009-11-25 | Haldor Topsoe A/S | Process for the synthesis of hydrocarbon constituents of gasoline |
US8034308B2 (en) * | 2009-06-09 | 2011-10-11 | Honeywell International, Inc. | Multi-stage multi-tube shell-and-tube reactor |
-
2012
- 2012-01-17 JP JP2012007216A patent/JP5995447B2/ja active Active
- 2012-12-13 US US14/368,735 patent/US9284234B2/en active Active
- 2012-12-13 CA CA2862796A patent/CA2862796C/en active Active
- 2012-12-13 EP EP12866393.7A patent/EP2806014B1/en active Active
- 2012-12-13 AU AU2012366430A patent/AU2012366430B2/en active Active
- 2012-12-13 WO PCT/JP2012/082328 patent/WO2013108526A1/ja active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2013108526A1 (ja) | 2013-07-25 |
JP2013147534A (ja) | 2013-08-01 |
US20140356257A1 (en) | 2014-12-04 |
AU2012366430B2 (en) | 2016-04-14 |
AU2012366430A1 (en) | 2014-07-31 |
EP2806014A4 (en) | 2015-07-29 |
CA2862796A1 (en) | 2013-07-25 |
EP2806014B1 (en) | 2021-05-12 |
US9284234B2 (en) | 2016-03-15 |
EP2806014A1 (en) | 2014-11-26 |
CA2862796C (en) | 2016-08-02 |
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