JP5956686B2 - 天然ガス流からの重質炭化水素の除去 - Google Patents
天然ガス流からの重質炭化水素の除去 Download PDFInfo
- Publication number
- JP5956686B2 JP5956686B2 JP2015525542A JP2015525542A JP5956686B2 JP 5956686 B2 JP5956686 B2 JP 5956686B2 JP 2015525542 A JP2015525542 A JP 2015525542A JP 2015525542 A JP2015525542 A JP 2015525542A JP 5956686 B2 JP5956686 B2 JP 5956686B2
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- natural gas
- stream
- gas
- heavy
- heavy hydrocarbons
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 1156
- 239000003345 natural gas Substances 0.000 title claims description 567
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 539
- 229930195733 hydrocarbon Natural products 0.000 title claims description 537
- 239000004215 Carbon black (E152) Substances 0.000 claims description 216
- 239000007788 liquid Substances 0.000 claims description 187
- 239000007789 gas Substances 0.000 claims description 185
- 238000000034 method Methods 0.000 claims description 159
- 238000001179 sorption measurement Methods 0.000 claims description 159
- 238000000926 separation method Methods 0.000 claims description 137
- 239000003949 liquefied natural gas Substances 0.000 claims description 52
- 230000008929 regeneration Effects 0.000 claims description 46
- 238000011069 regeneration method Methods 0.000 claims description 46
- 239000003463 adsorbent Substances 0.000 claims description 41
- 238000001816 cooling Methods 0.000 claims description 35
- 230000008569 process Effects 0.000 claims description 35
- 239000012071 phase Substances 0.000 claims description 33
- 239000012808 vapor phase Substances 0.000 claims description 20
- 238000004891 communication Methods 0.000 claims description 17
- 239000012530 fluid Substances 0.000 claims description 16
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 239000007791 liquid phase Substances 0.000 claims description 12
- 238000010792 warming Methods 0.000 claims description 10
- 238000003763 carbonization Methods 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 238000012545 processing Methods 0.000 claims description 8
- 230000000779 depleting effect Effects 0.000 claims description 7
- 230000001172 regenerating effect Effects 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 230000026676 system process Effects 0.000 claims description 5
- 238000004064 recycling Methods 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 description 15
- 239000000203 mixture Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000010992 reflux Methods 0.000 description 7
- 238000005057 refrigeration Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 6
- 238000003795 desorption Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 238000007710 freezing Methods 0.000 description 4
- 230000008014 freezing Effects 0.000 description 4
- 238000005191 phase separation Methods 0.000 description 4
- 239000003507 refrigerant Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- -1 100 ppm or more Chemical class 0.000 description 1
- 101100261173 Arabidopsis thaliana TPS7 gene Proteins 0.000 description 1
- GLQOALGKMKUSBF-UHFFFAOYSA-N [amino(diphenyl)silyl]benzene Chemical compound C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(N)C1=CC=CC=C1 GLQOALGKMKUSBF-UHFFFAOYSA-N 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000010582 gas stream method Methods 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000011064 split stream procedure Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
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- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
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- F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
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- C—CHEMISTRY; METALLURGY
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- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J2200/40—Features relating to the provision of boil-up in the bottom of a column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/40—Processes or apparatus using other separation and/or other processing means using hybrid system, i.e. combining cryogenic and non-cryogenic separation techniques
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/60—Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
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- F25J2210/00—Processes characterised by the type or other details of the feed stream
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- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
- F25J2220/64—Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/30—Compression of the feed stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/90—Processes or apparatus involving steps for recycling of process streams the recycled stream being boil-off gas from storage
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- General Chemical & Material Sciences (AREA)
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- Separation By Low-Temperature Treatments (AREA)
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Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
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US13/565,881 US20140033762A1 (en) | 2012-08-03 | 2012-08-03 | Heavy Hydrocarbon Removal From A Natural Gas Stream |
USPCT/US2012/049506 | 2012-08-03 | ||
US13/565,881 | 2012-08-03 | ||
PCT/US2012/049506 WO2014021900A1 (en) | 2012-08-03 | 2012-08-03 | Heavy hydrocarbon removal from a natural gas stream |
US13/611,169 US9631864B2 (en) | 2012-08-03 | 2012-09-12 | Heavy hydrocarbon removal from a natural gas stream |
US13/611,169 | 2012-09-12 | ||
PCT/US2013/052933 WO2014022510A2 (en) | 2012-08-03 | 2013-07-31 | Heavy hydrocarbon removal from a natural gas stream |
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JP (1) | JP5956686B2 (ru) |
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AU (1) | AU2013296552B2 (ru) |
BR (1) | BR112015002328B1 (ru) |
CA (1) | CA2880441C (ru) |
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CN104893773B (zh) * | 2014-06-20 | 2018-02-23 | 康泰斯(上海)化学工程有限公司 | 管道天然气重烃脱除单元及重烃脱除方法 |
CN104990827B (zh) * | 2015-06-15 | 2019-02-01 | 北京科技大学 | 低挥发性有机气体在吸附材料上吸附量的测定方法及设备 |
KR101733770B1 (ko) | 2015-07-08 | 2017-05-08 | 주식회사 케이티 | 가상랜을 이용하여 사내 단말의 보안을 관리하는 사내 보안 관리 장치, 사내 보안 관리 시스템 및 사내 보안 관리 방법 |
CN109219476A (zh) * | 2016-05-31 | 2019-01-15 | 埃克森美孚上游研究公司 | 用于变吸附方法的装置和系统 |
US11402155B2 (en) | 2016-09-06 | 2022-08-02 | Lummus Technology Inc. | Pretreatment of natural gas prior to liquefaction |
RU2640050C1 (ru) * | 2017-02-02 | 2017-12-26 | Публичное акционерное общество криогенного машиностроения (ПАО "Криогенмаш") | Способ удаления тяжелых углеводородов при сжижении природного газа и устройство для его осуществления |
US10821394B2 (en) * | 2018-06-20 | 2020-11-03 | Uop Llc | Temperature swing adsorption process for heavy hydrocarbon removal |
US11034903B2 (en) * | 2018-06-27 | 2021-06-15 | Uop Llc | Adsorption process for treating natural gas |
CN112505161B (zh) * | 2020-12-01 | 2022-04-29 | 西南石油大学 | 一种测量天然气中芳香烃物质含量及析出量的装置及方法 |
WO2023288162A1 (en) | 2021-07-16 | 2023-01-19 | Exxonmobil Upstream Research Company | Methods for operating hydrocarbon removal systems from natural gas streams |
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US3594983A (en) * | 1969-06-17 | 1971-07-27 | Process Services Inc | Gas-treating process and system |
US3792590A (en) * | 1970-12-21 | 1974-02-19 | Airco Inc | Liquefaction of natural gas |
GB1419380A (en) | 1972-03-03 | 1975-12-31 | British Gas Corp | Purification of natural gas |
US5325673A (en) | 1993-02-23 | 1994-07-05 | The M. W. Kellogg Company | Natural gas liquefaction pretreatment process |
CA2133302A1 (en) | 1993-10-06 | 1995-04-07 | Ravi Kumar | Integrated process for purifying and liquefying a feed gas mixture with respect to its less strongly adsorbed component of lower volatility |
FR2714722B1 (fr) * | 1993-12-30 | 1997-11-21 | Inst Francais Du Petrole | Procédé et appareil de liquéfaction d'un gaz naturel. |
US5451249A (en) * | 1994-06-14 | 1995-09-19 | International Fuel Cells | Landfill gas treatment system |
US7325415B2 (en) | 2002-01-18 | 2008-02-05 | Cool Energy Limited | Process and device for production of LNG by removal of freezable solids |
AU2003900534A0 (en) * | 2003-02-07 | 2003-02-20 | Shell Internationale Research Maatschappij B.V. | Process and apparatus for removal of a contaminant from a natural gas feed stream |
US6662589B1 (en) * | 2003-04-16 | 2003-12-16 | Air Products And Chemicals, Inc. | Integrated high pressure NGL recovery in the production of liquefied natural gas |
US20070267328A1 (en) | 2003-10-30 | 2007-11-22 | Neumann Klaus D K | Process and System for Removing Contaminants from a Natural Gas Stream |
US7600395B2 (en) * | 2004-06-24 | 2009-10-13 | Conocophillips Company | LNG system employing refluxed heavies removal column with overhead condensing |
US7165423B2 (en) | 2004-08-27 | 2007-01-23 | Amec Paragon, Inc. | Process for extracting ethane and heavier hydrocarbons from LNG |
MY146497A (en) | 2004-12-08 | 2012-08-15 | Shell Int Research | Method and apparatus for producing a liquefied natural gas stream |
CA2615439C (en) | 2005-07-26 | 2015-04-14 | Exxonmobil Upstream Research Company | Method of purifying hydrocarbons and regeneration of adsorbents used therein |
US8529662B2 (en) * | 2007-05-18 | 2013-09-10 | Exxonmobil Research And Engineering Company | Removal of heavy hydrocarbons from gas mixtures containing heavy hydrocarbons and methane |
FR2921470B1 (fr) | 2007-09-24 | 2015-12-11 | Inst Francais Du Petrole | Procede de liquefaction d'un gaz naturel sec. |
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US20110185896A1 (en) * | 2010-02-02 | 2011-08-04 | Rustam Sethna | Gas purification processes |
CN202297537U (zh) * | 2011-09-30 | 2012-07-04 | 新地能源工程技术有限公司 | 采用富氢氮气预冷的富含甲烷气体的净化装置 |
CN102643694B (zh) * | 2012-04-27 | 2014-12-03 | 新地能源工程技术有限公司 | 一种天然气干燥及液化工艺方法和装置 |
US20140033762A1 (en) * | 2012-08-03 | 2014-02-06 | Air Products And Chemicals, Inc. | Heavy Hydrocarbon Removal From A Natural Gas Stream |
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JP2015531013A (ja) | 2015-10-29 |
BR112015002328B1 (pt) | 2024-01-09 |
KR101643110B1 (ko) | 2016-08-10 |
CA2880441A1 (en) | 2014-02-06 |
RU2015107256A (ru) | 2016-09-27 |
WO2014022510A2 (en) | 2014-02-06 |
MY176383A (en) | 2020-08-04 |
KR20150041641A (ko) | 2015-04-16 |
BR112015002328A2 (pt) | 2017-07-04 |
EP2880134B1 (en) | 2019-05-15 |
AU2013296552A1 (en) | 2015-03-12 |
CN104685036B (zh) | 2017-07-11 |
CN104685036A (zh) | 2015-06-03 |
RU2599582C2 (ru) | 2016-10-10 |
WO2014022510A3 (en) | 2014-07-03 |
AU2013296552B2 (en) | 2016-09-15 |
EP2880134A2 (en) | 2015-06-10 |
PE20150658A1 (es) | 2015-05-11 |
CA2880441C (en) | 2017-07-18 |
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