JP5902691B2 - 長期間静菌性化合物および修復歯科材料におけるその使用 - Google Patents
長期間静菌性化合物および修復歯科材料におけるその使用 Download PDFInfo
- Publication number
- JP5902691B2 JP5902691B2 JP2013529350A JP2013529350A JP5902691B2 JP 5902691 B2 JP5902691 B2 JP 5902691B2 JP 2013529350 A JP2013529350 A JP 2013529350A JP 2013529350 A JP2013529350 A JP 2013529350A JP 5902691 B2 JP5902691 B2 JP 5902691B2
- Authority
- JP
- Japan
- Prior art keywords
- composition
- tooth
- dental
- restorative material
- materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000003385 bacteriostatic effect Effects 0.000 title claims description 25
- 150000001875 compounds Chemical class 0.000 title claims description 23
- 230000007774 longterm Effects 0.000 title description 8
- 239000005548 dental material Substances 0.000 title 1
- 239000000463 material Substances 0.000 claims description 109
- 239000000203 mixture Substances 0.000 claims description 57
- 230000000844 anti-bacterial effect Effects 0.000 claims description 21
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 11
- 229940043810 zinc pyrithione Drugs 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 claims 1
- 229910000497 Amalgam Inorganic materials 0.000 description 31
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 25
- 239000000178 monomer Substances 0.000 description 22
- 239000011787 zinc oxide Substances 0.000 description 13
- 239000000853 adhesive Substances 0.000 description 12
- 230000001070 adhesive effect Effects 0.000 description 12
- 230000000845 anti-microbial effect Effects 0.000 description 9
- 229960001141 pyrithione zinc Drugs 0.000 description 9
- 229940007718 zinc hydroxide Drugs 0.000 description 9
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 9
- 239000004840 adhesive resin Substances 0.000 description 8
- 229920006223 adhesive resin Polymers 0.000 description 8
- 210000003298 dental enamel Anatomy 0.000 description 8
- 230000000306 recurrent effect Effects 0.000 description 8
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 150000002894 organic compounds Chemical class 0.000 description 5
- 231100000252 nontoxic Toxicity 0.000 description 4
- 230000003000 nontoxic effect Effects 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 230000008439 repair process Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 208000002925 dental caries Diseases 0.000 description 3
- 239000003479 dental cement Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000012970 tertiary amine catalyst Substances 0.000 description 3
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 2
- 238000010669 acid-base reaction Methods 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- -1 dimethyl ethyl-4-aminobenzoate Chemical compound 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 238000000016 photochemical curing Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000013615 primer Substances 0.000 description 2
- 239000002987 primer (paints) Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 229960001296 zinc oxide Drugs 0.000 description 2
- VNQXSTWCDUXYEZ-UHFFFAOYSA-N 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione Chemical compound C1CC2(C)C(=O)C(=O)C1C2(C)C VNQXSTWCDUXYEZ-UHFFFAOYSA-N 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- UUEYEUDSRFNIQJ-UHFFFAOYSA-N CCOC(N)=O.CCOC(N)=O.CC(=C)C(O)=O.CC(=C)C(O)=O Chemical compound CCOC(N)=O.CCOC(N)=O.CC(=C)C(O)=O.CC(=C)C(O)=O UUEYEUDSRFNIQJ-UHFFFAOYSA-N 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- 229910000645 Hg alloy Inorganic materials 0.000 description 1
- AMFGWXWBFGVCKG-UHFFFAOYSA-N Panavia opaque Chemical compound C1=CC(OCC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OCC(O)COC(=O)C(C)=C)C=C1 AMFGWXWBFGVCKG-UHFFFAOYSA-N 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 208000002599 Smear Layer Diseases 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 229930006711 bornane-2,3-dione Natural products 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000037123 dental health Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000013070 direct material Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- BLFLLBZGZJTVJG-UHFFFAOYSA-N ethyl ester of p-aminobenzoic acid Natural products CCOC(=O)C1=CC=C(N)C=C1 BLFLLBZGZJTVJG-UHFFFAOYSA-N 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000013071 indirect material Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/60—Preparations for dentistry comprising organic or organo-metallic additives
- A61K6/69—Medicaments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- A61K6/889—Polycarboxylate cements; Glass ionomer cements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dental Preparations (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38316310P | 2010-09-15 | 2010-09-15 | |
| US61/383,163 | 2010-09-15 | ||
| PCT/US2011/051860 WO2012037424A1 (en) | 2010-09-15 | 2011-09-15 | Long term bacteriostatic compounds and their use in restorative dental materials |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014508098A JP2014508098A (ja) | 2014-04-03 |
| JP2014508098A5 JP2014508098A5 (enExample) | 2014-11-06 |
| JP5902691B2 true JP5902691B2 (ja) | 2016-04-13 |
Family
ID=45831977
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013529350A Active JP5902691B2 (ja) | 2010-09-15 | 2011-09-15 | 長期間静菌性化合物および修復歯科材料におけるその使用 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9480627B2 (enExample) |
| EP (1) | EP2616000A4 (enExample) |
| JP (1) | JP5902691B2 (enExample) |
| KR (1) | KR101948330B1 (enExample) |
| CN (1) | CN103108605B (enExample) |
| WO (1) | WO2012037424A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110075310A (zh) | 2011-12-20 | 2019-08-02 | 维奥姆治疗有限公司 | 用于治疗真菌感染的局部油组合物 |
| KR101862448B1 (ko) * | 2013-04-12 | 2018-05-29 | 바이옴 바이오사이언스 피브이티. 엘티디. | 항균제의 조성물과 제제, 그 공정, 및 세균 감염을 치료하는 방법 |
| JP6172713B2 (ja) * | 2013-07-11 | 2017-08-02 | 有限会社漢方歯科医学研究所 | 歯周病原因菌に対する抗菌性を有する歯科用材料及び抗菌性義歯 |
| WO2022182365A1 (en) * | 2021-02-26 | 2022-09-01 | Cao Group, Inc | Methods of endodontic therapy utilizing lasers and anti-microbial restorative materials |
| US20230151225A1 (en) * | 2020-03-31 | 2023-05-18 | Cao Group, Inc. | Blending zinc pyrithione with base materials in order to create quickly applied anti-microbial surfaces |
| BE1029103B1 (nl) * | 2021-02-12 | 2022-09-12 | Zinkh Nv | Tandheelkundig apparaat met antimicrobiële werking |
| WO2022250668A1 (en) * | 2021-05-26 | 2022-12-01 | Cao Group, Inc | Elastomeric endodontic point compositions with zinc pyrithone |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002503520A (ja) * | 1998-02-19 | 2002-02-05 | オラシューティカル エルエルシー | 抗菌義歯接着組成物 |
| US6232367B1 (en) * | 1999-10-07 | 2001-05-15 | Kerr Corporation | Opalescent fillers for dental restorative composites |
| US6326417B1 (en) * | 1999-10-21 | 2001-12-04 | Jeneric/Pentron Incorporated | Anti-microbial dental compositions and method |
| AU2002367019A1 (en) * | 2001-12-21 | 2003-07-30 | Biomat Sciences, Inc. | Process of making dental restorations |
| US6756417B2 (en) * | 2002-03-13 | 2004-06-29 | Ultradent Products, Inc. | Dental bonding compositions for adhering amalgam restoratives to dental substrates |
| US6924325B2 (en) * | 2002-06-21 | 2005-08-02 | Kerr Corporation | Silver-containing dental composition |
| US7378479B2 (en) * | 2002-09-13 | 2008-05-27 | Lubrizol Advanced Materials, Inc. | Multi-purpose polymers, methods and compositions |
| US8980235B2 (en) * | 2003-09-30 | 2015-03-17 | Arch Chemicals, Inc. | Coated metal pyrithione particles for treatment of microorganisms |
| ITFI20040048A1 (it) * | 2004-02-27 | 2004-05-27 | Menarini Farma Ind | Composti biomimetici contenenti idrossiapatiti sostituite con magnesio e carbonato e processi per ottenerli |
| BRPI0516593A (pt) * | 2004-10-14 | 2008-09-16 | Tufts College | polìmeros eletroquimicamente degradáveis |
| US7498367B2 (en) * | 2005-02-21 | 2009-03-03 | Kerr Corporation | Acid-tolerant dental composition |
| KR100671325B1 (ko) * | 2005-04-18 | 2007-01-24 | 양원동 | 은 나노 수복 제 |
| US20070264615A1 (en) * | 2006-05-09 | 2007-11-15 | Heraeus Kulzer Gmbh | Dental restoration aids |
| CA2665945A1 (en) * | 2006-10-10 | 2008-04-17 | Aortech Biomaterials Pty Ltd | Soft tissue implant |
| US8506695B2 (en) * | 2006-10-25 | 2013-08-13 | Hewlett-Packard Development Company, L.P. | Coating compositions |
| US7963769B2 (en) * | 2007-10-08 | 2011-06-21 | Kerr Corporation | Dental adhesive and method of use |
| RU2012104912A (ru) * | 2009-07-17 | 2013-08-27 | КЕЭ-ФЬЮЖН 2200, Инк. | Частицы, содержащие противомикробные агенты |
| GB2461475B (en) * | 2009-11-10 | 2010-09-08 | Landmark Innovations Ltd | Dental impression material |
-
2011
- 2011-09-15 WO PCT/US2011/051860 patent/WO2012037424A1/en not_active Ceased
- 2011-09-15 US US13/257,647 patent/US9480627B2/en active Active
- 2011-09-15 JP JP2013529350A patent/JP5902691B2/ja active Active
- 2011-09-15 EP EP11825994.4A patent/EP2616000A4/en not_active Withdrawn
- 2011-09-15 KR KR1020137006273A patent/KR101948330B1/ko active Active
- 2011-09-15 CN CN201180044606.XA patent/CN103108605B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012037424A1 (en) | 2012-03-22 |
| US9480627B2 (en) | 2016-11-01 |
| US20130252207A1 (en) | 2013-09-26 |
| EP2616000A1 (en) | 2013-07-24 |
| KR101948330B1 (ko) | 2019-04-22 |
| KR20140015249A (ko) | 2014-02-06 |
| CN103108605B (zh) | 2015-12-09 |
| CN103108605A (zh) | 2013-05-15 |
| JP2014508098A (ja) | 2014-04-03 |
| EP2616000A4 (en) | 2014-06-04 |
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