JP5902156B2 - Pesticide compositions comprising benzoylurea compounds and chlorfenapyr and their use - Google Patents

Description

  The present invention relates to a pesticidal composition comprising an insecticidal benzoylurea compound of formula I and a compound of formula II as defined below, and the use of such a composition for controlling invertebrate pests. .

  Even with commercial insecticides, acaricides and nematicides available today, damage to crops caused by insects, spiders and nematodes, both during and after harvest, I still get up. Therefore, there is a continuing need to develop new insecticides, acaricides and nematicides.

  One of the typical problems that arise in the field of pest control is that of active ingredients to reduce or avoid undesirable environmental or toxicological effects while still allowing effective pest control. There is a need to reduce the dose.

  Another problem faced relates to the need to make pest control agents highly effective against a broad spectrum of pests.

  There is also a need for pest control agents that have both know-how activity and long-term control, that is, quick action and long-lasting action.

  Another difficulty with the use of pesticides is that repeated and exclusive application of individual pesticide compounds often results in rapid selection of pests that have developed natural or adaptive resistance to the active compound. Is what happens. Therefore, there is a need for pest control agents that help prevent or overcome resistance.

  Accordingly, it is an object of the present invention to develop new pesticides, novel methods for controlling insects, arachnids or nematodes, plants growing from attack or spread of insects, arachnids or nematodes It was to provide a new method for protecting the seed as well as a new method for protecting the seed from insects.

  Accordingly, one object of the present invention is to reduce the dose and / or enhance the activity spectrum and / or combine the know-how activity with long-term control and / or manage tolerance. It was to provide a pesticide that solves at least one of the following.

  The benzoylurea compounds of the formula (I), together with their pesticidal activity, are known, for example, from US 5,874,615 or EP 0161019.

  US 4,698,365 and US 4,623,658 disclose benzoylurea compounds having pesticidal activity, in particular insecticidal and acaricidal properties.

  EP 0347488 describes chlorfenapyr and derivative compounds and mentions their use in mixtures with other insecticides.

  US 4,666,942 discloses a method of using pesticidal benzoylurea compounds and compositions containing benzoylurea in combination with other pesticidal compounds, in particular organophosphate and pyrethroid insecticides. Yes.

  CN 1364413 discloses an insecticidal composition comprising chlorfenapyr and one or more selected insecticidal compounds.

  JP 2006056810 discloses pesticidal compositions containing benzoylurea compounds and mentions those methods for aquatic pests.

  An effective composition with effective and high insecticidal activity is still desirable to combat the pests that can cause significant damage to crops and other plants and to solve the above-mentioned problems.

US 5,874,615 EP 0161019 US 4,698,365 US 4,623,658 EP 0347488 US 4,666,942 CN 1364413 JP 2006056810

  The inventors have found that some or all of these objectives are achieved by a combination of active compounds as defined below. In addition, the present inventors have made it possible to control pests by applying the active compound of formula I and the compound of formula II simultaneously, ie together or separately, or by applying compounds I and II sequentially. It has been found that this is enhanced compared to the control rate that is possible with this compound.

  Surprisingly, it has now been found that the object of the invention can be achieved, at least in certain embodiments, by mixing a benzoylurea of formula I with an active compound of formula II.

Therefore, one embodiment of the present invention is an active ingredient
1) Benzoylurea compound of formula I

(Where
R is halogen, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy or C ₁ -C ₄ alkylthio,
R ¹ is hydrogen, halogen, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy or C ₁ -C ₄ alkylthio,
R ² is fluorine,
R ³ is hydrogen, halogen, nitro, cyano, C ₁ -C ₄ alkyl or C ₁ -C ₄ haloalkyl,
n is an integer of 0, 1, 2 or 3,
R ⁴ is halogen or OR ⁵
R ⁵ is substituted with up to 3 groups independently selected from C ₁ -C ₄ haloalkyl, C ₃ -C ₇ halocycloalkyl, halogen, C ₁ -C ₄ haloalkyl group, cyano group or nitro group phenyl or may not be, a halogen atom, C ₁ -C ₄ haloalkyl group, a cyano group or up to three may also be 2-pyridyl not they are substituted with a group selected from nitro groups independently Or agriculturally acceptable salts thereof, and
2) Compound of formula II

Or providing a pesticidal composition comprising an agronomically acceptable salt thereof in a synergistically effective amount.

  The general name of the compound of formula II is chlorphenapyl, ie 4-bromo-2- (4-chlorophenyl) -1- (ethoxymethyl) -5- (trifluoromethyl) -1H-pyrrole-3-carbonitrile.

  Accordingly, the inventors have found that some objects can be achieved by the compositions defined in this application, ie by combining at least one benzoylurea compound of formula I and a compound of formula II. It was.

  Furthermore, the present invention controls and / or controls pests, in particular invertebrate pests, insects, arachnids or nematodes, by using a composition comprising a synergistically effective amount of a compound of formulas I and II. And a method for preparing such compositions.

  Furthermore, the present invention provides a method for treating and / or protecting a plant from pest attack or spread, wherein the composition according to the invention is against the plant or to the soil or water in which the pest is growing. It relates to a method comprising contacting an object.

  Furthermore, the invention also relates to a method for protecting plant propagation material and / or plants growing therefrom, the method comprising treating the plant propagation material with a composition according to the invention.

  Furthermore, the present invention relates to the use of a composition comprising a compound of formula I and a compound of formula II for the protection of seeds, and the seed before sowing and / or after pregermination and the composition of the present invention. It also relates to a method for protecting the seed, comprising contacting the seed.

  As used herein, the term “pest” is considered to encompass any pest organism including insects, ticks, and nematodes.

As used herein, the term “C ₁ -C ₄ alkyl” per se, as well as related terms such as C ₁ -C ₄ alkoxy, C ₁ -C ₄ haloalkyl or C ₁ -C ₄ haloalkoxy ₁ -C ₄ alkyl "refers to straight or branched aliphatic alkyl group having 1 to 4 carbon atoms, such as methyl, ethyl, propyl, isopropyl, n- butyl, sec- butyl and tert- butyl .

  As used herein, the term `` halogen '' as well as related terms such as `` haloalkyl '' or `` haloalkoxy '' include `` halogen '' as fluorine (F), chlorine (Cl), iodine (I) and Selected from bromine (Br), preferably fluorine and chlorine, more preferably fluorine.

The term “C ₁ -C ₄ alkoxy” as used herein refers to a C ₁ -C ₄ alkyl group as defined above attached through an oxygen atom, such as methoxy, ethoxy, propoxy, isopropoxy, Refers to n-butoxy, sec-butoxy and tert-butoxy.

The term “C ₁ -C ₄ haloalkyl” as used herein further comprises one or more, eg 2, 3, 4, 5 or 6 halogen atoms as defined above, defined C ₁ -C ₄ alkyl group, such as mono, - di - and trifluoromethyl, mono-, - di - and trichloromethyl, 1-fluoroethyl, 1-chloroethyl, 2-fluoroethyl, 2-chloroethyl, 1 , 1-Difluoroethyl, 1,1-dichloroethyl, 1,2-difluoroethyl, 1,2-dichloroethyl, 2,2-difluoroethyl, 2,2-dichloroethyl, 2,2,2-trifluoroethyl And 2,2,2-trichloroethyl.

The term “C ₁ -C ₄ haloalkoxy” as used herein further comprises one or more, eg 2, 3, 4, 5 or 6 halogen atoms as defined above, in defined C ₁ -C ₄ alkoxy group, such as mono, - di - and trifluoromethoxy, mono -, di - and trichloromethoxy, 1-fluoroethoxy, 1-chloroethoxy, 2-fluoroethoxy, 2-chloro Ethoxy, 1,1-difluoroethoxy, 1,1-dichloroethoxy, 1,2-difluoroethoxy, 1,2-dichloroethoxy, 2,2-difluoroethoxy, 2,2-dichloroethoxy, 2,2,2- Refers to trifluoroethoxy and 2,2,2-trichloroethoxy.

The term “C ₁ -C ₂ alkylthio” as used herein refers to a C ₁ -C ₄ alkyl group as defined above attached through a sulfur atom.

The term “C ₃ -C ₆ cycloalkyl” as used herein refers to a monocyclic or bicyclic or polycyclic saturated hydrocarbon group having from 3 to 6 carbon atoms. Examples of monocyclic groups having 3 to 6 carbon atoms include cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl.

"Halogen Good C ₃ optionally substituted by -C ₆ - cycloalkyl" also used herein expressed - the term "C ₃ -C ₆ halocycloalkyl" and, halo cycloalkoxy, Haroshikuro A halocycloalkyl moiety in alkylcarbonyl and the like means 3 to 6 ("C ₃ -C, wherein some or all of the hydrogen atoms are replaced by the halogen atoms described above, in particular fluorine, chlorine and bromine. refers to ₆ halocycloalkyl ") monocyclic or bicyclic or polycyclic saturated hydrocarbon groups having carbon ring members.

In a preferred embodiment of the invention, the substituents R ¹ , R ² , R ³ and R ⁴ in the benzoylurea compound of formula (I) are independent of each other, but in particular in combination, as defined below: Has a preferred meaning:
R is F, Cl or OCH ₃ , preferably F;
R ¹ is H, F, Cl or CH ₃ , preferably F,
R ³ is H, F or Cl, preferably hydrogen (H),
R ⁴ is F, Cl or OR ⁵ , preferably OR ⁵
R ⁵ is C ₁ -C ₄ haloalkyl, phenyl substituted with 1 to 3 halogen atoms or a CF ₃ group, preferably 4- (trifluoromethyl) optionally substituted with halogen It is a phenyl group.

In one preferred embodiment, preference is given to the benzoylurea compound of formula I being flufenoxuron, ie R and R ¹ are F, R ³ is hydrogen and R ⁴ is 2-Cl-4-CF ₃ A pesticidal composition which is a compound of formula I which is -phenoxy (ie CF _{3 in} the para position of the phenoxy group and Cl in the ortho position). Flufenoxuron is 1- [4- (N-[[[4- [2-chloro-4- (trifluoromethyl) phenoxy] -2-fluorophenyl] amino] carbonyl] -2,6-difluorobenzamide ( In the IUPAC nomenclature, the general name 1- [4- (2-chloro-α, α, α-trifluoro-p-tolyloxy) -2-fluorophenyl] -3- (2,6-difluorobenzoyl) urea) And the following formula Ia:

Have

  Flufenoxuron of formula Ia, its preparation and its pesticidal activity are known in the literature (see US 5,874,615 and US 4,698,365). The chlorfenapyr of formula II, its preparation and its pesticidal activity are likewise known from the literature (see EP-A 376 279 and EP-A 375 907).

  More preferably, the composition of the present invention is a combination of a benzoylurea compound of formula Ia (flufenoxuron) and a compound of formula II (chlorfenapyr) in a synergistically effective amount. ".

  The composition of the present invention comprises a synergistically effective amount of a benzoylurea compound of formula I as component (1) and a compound of formula II as component (2).

  In general, a `` synergistically effective amount '' refers to component (1) and component (2) and, in some cases, more active pesticidal components, each of which usually has an insecticidal effect combining two or more components. It is meant to be applied in a weight ratio that is greater than the sum of the individual insecticidal effects of the compound. The synergistic ratio of component (1): component (2) according to the invention is 1: 500 to 100: 1, preferably 1:50 to 10: 1, in particular 5: 1 to 1:20.

  Depending on the nature of the compound employed, the weight ratio of the compound of formula I to the compound of formula II is 100: 1 to 1: 100, preferably 20: 1 to 1:20, in particular 10: 1 to 1:10. To get started.

  More preferred ratios of component (1) and component (2) in a synergistically effective amount are 2: 5, 1: 2, 1: 1.

  A highly preferred ratio of component (1) to component (2) in a synergistically effective amount is 2: 5.

  In preparing the compositions according to the invention, it is preferred to use pure benzoylurea compounds of the formula I and chlorfenapyr, which in some cases also have a pesticidal activity that also resists harmful fungi. A compound or a herbicidal or growth-regulating active compound or fertilizer can be added.

The composition comprising the compounds of formulas I and II according to the invention, or the simultaneous or sequential use of the compounds of formulas I and II, shows significant synergistic effects on the following eye pests:
Insects belonging to the order Lepidoptera, for example, Agrotis ypsilon, Agrotis segetum, Alabama argillacea, Antiticia gemmatalis, Argirestia ella conthia ), Ascia monusteorseis, Autographa gamma, Bupalus piniarius, Cacoecia murinana, Capua reticulana, and Capato reticulana Cheimatobia brumata, Choristoneura fumiferana, Chorisoneura occidentalis, Kirphis unipuncta, Cydia pomonella, Dendolimus roi pini (D) Diaphania nitidalis, Diatraea grandiosella, Dione juno juno, Earias insulana, Elasmopalpus lignosellus, Elia guo ), Evetria bouliana, Feltia subterranea, Galleria mellonella, Grapholitha funebrana, Grapholitha molesta, Heliotis armigera, Heliotis armigera Heliothis virescens, Heliothis zea, Hella undalis, Hibernia defoliaria, Hyphantria cunea, Hyponomeuta Marinels ponomeuta malinellus), Keiferia lycopersicella, Lambdina fiscellaria, Laphygma exigua, Leucoptera coffeella, Leucoptera scila itra (Lithocolletis blancardella), Lobesia botrana, Loxostege sticticalis, Lymantria dispar, Lymantria monacha, Rionetia clercola (rkyo) Malacosoma neustria, Mamestra brassicae, Orgyia pseudotsugata, Ostrinia nubilalis, Panolis flammea, Pectinophora gossi Ella (Pectinophora gossypiella), Peridroma saucia, Farrera bucephala, Phthhorimaea operculella, Phyllocnistis citrella, Pierre pisna Scarbra (Plathypena scabra), Plutella xylostella, Pseudoplusia includens, Rhyacionia frustrana, Scrobipalpula absoluta, Sitotraga sele real Sparganothis pilleriana, Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura, Thaumatia Pitiocampa (Thaumat) opoea pityocampa), Tortrix viridana, Trichoplusia ni, rachiplusia nu, plusia spp, plusia putnami, plusia festukae (plusia) festucae), Prussia oricbalcea, plusia orichalcea, tuta absoluta, and Zeiraphera canadensis,
Coleoptera (Coleoptera), for example, Agrilus sinuatus, Agriotes lineatus, Agriotes obscurus, Amphimallus russtitials, Amphimallus solstitial dispar), Anthonomus grandis, Anthonomus pomorum, Aphthona euphoridae, Athous haemorrhoidalis, Atomaria linearis B piniperda, Britofaga undata, Bruchs rufimanus, Bruchus pisorum, Bruchs lentis, Byctiscus betulae, Byctiscus betulae, Byctiscus betulae Cassida nebulosa, Cerotoma trifurcata, Cetonia aurata, Sortlinks asimilis, Sortlinks napi (Ceuthorrhynchus napi), Kaetokunema cnito s Conoderus vespertinus), Crioceris asparagi, Ctenicera spp., Diabrotica longicornis, Diabrotica semipunctata, Diabrotica semipunctata 12-rot ica Diabrotica speciosa, Diabrotica virgifera, Epilacachna varivestis, Epitrix hirtipennis, Eutinobothrus reiensis (Eutinobothrus) brasiliensis), Hyrobius abietis, Hipera brunneipennis, Hipera postica, Ips typographus, Lema bilineata, Lema bilineata, Lema bilineata ), Leptinotarsa decemlineata, Limonius californicus, Lissorhoptrus oryzophilus, Melanotus communis, Melonetas ethunius , Melolontha melolontha, Oulema oryzae, Otiorrhynchus sulcatus, Otiorrhynchus ovatus, Faedon colearia coleon Phyllobius pyri, Phyllotreta chrysocephala, Phyllophaga spp., Phyllopertha horticola, Phyllotreta nemorum (Phyllotreta nemorum) Popylia japonica, Sitona lineatus and Sitophilus granaria,
Flies, mosquitoes (Diptera), e.g., Aedes aegypti, Aedes albopictus, Aedes vexans, Anastrepha ludens, Anofeles macripis Anopheles maculipennis), Anopheles crucians, Anopheles albimanus, Anopheles gambiae, Anopheles freeborni, Anopheles leucos leucos leucos Anopheles minimus, Anopheles quadrimaculatus, Calliphora vicina, Ceratitis capitata, Chrysomya bezziana, Chrysomya bea Chrysomya macellaria, Chrysops discalis, Chrysops silacea, Chrysops atlanticus, Cochliomyia hominivorx, Cochliomyia hominivor Cordylobia anthropophaga, Culicoides furens, Culex pipiens, Culex nigripalpus, Culex quinquefasciatus, Culex quinquefasciatus , Criseta inornata, Criseta melanura, Dacus cucurbitae, Dacus oleae, Dasineura brassicae, Delia antique Delia antique, Delia coarctata, Delia platura, Delia radicum, Dermatobia hominis, Fania canicularis, Geomiza trypuntata (Geomyza Tripunctata), Gasterophilus intestinalis, Glossina morsitans, Glossina palpalis, Glossina fuscipes, Glossina tachinoides (ides), Glossina tachinoides (ides) Iritans (Haematobia irritans), Haplodiplosis equestris, Hippelates spp., Hylemyia platura, Hypoderma lineens, Hypoderma lineens, Leopconosto rr・ Swallow (Li riomyza sativae, Liriomyza trifolii, liriomyza huidobrensis, Lucilia caprina, Lucilia cuprina, Lucilia pectoral ), Mansonia titillanus, Mayetiola destructor, Musca domestica, Muscina stabulans, Oestrus ovis, Opomy flor um flor , Oscinella frit, Pegomya hysocyami, Phorbia antiqua, Phorbia brassicae, Phorbia coarctata, Phreboto argespes Pso Psorophora columbiae, Psila rosae, Psorophora discolor, Prosimulium mixtum, Rhagoletis cerasi, lagoletispo Sarcophaga haemorrhoidalis, Sarcophaga spp., Simulium vittatum, Stomoxys calcitrans, Tabanus bovinus, Tabanus banus atratus Lineola (Tabanus lineola) and Tabanas similis (Tipula oleracea) and Chipula paludosa (Tipula paludosa),
Thrips (Thysanoptera), e.g., Dichromothrips corbetti, Dichromothrips spp., Frankliniella fusca, Frankliniella occidentalis, ccalilinella Frankliniella tritici, Scirtothrips citri, Tryps oryzae, Tryps palmi and Thrips tabaci,
Termites (Isoptera), e.g., Carotermes flavicollis, Leucotermes flavipes, Heterotermes aureus, Reticulitermes flavipes, Reticulitermes flavipes・ Birginics (Reticulitermes virginicus), Reticulitermes lucifugus (Reticulitermes lucifugus), Termes natalensis and Copttotermes formosanus,
Cockroaches (Blattaria-Blattodea), e.g., Blattella germanica, Blattella asahinae, Periplaneta americana, Periplaneta japonica, Periplaneta japonica, Periplaneta japonica brunnea), Periplaneta fuligginosa, Periplaneta australasiae, and Blatta orientalis,
Hemiptera (Hemiptera), e.g., Acrosternum hilare, Blissus leucopterus, Cyrtopeltis notatus, Dysdercus tusula, tuss Dysdercus intermedius, Eurygaster integriceps, Euschistus impictiventris, Leptogross phyllopus, L Lygus pratensis, Nezara viridula, Piesma quadrata, Solubea insularis, Thyanta perditor, Acrythosiphon onobrychis, Acrythosiphon onobrychis Kiss (Adelges laricis), Aphidula nasturtii, Aphis fabae, Aphis forbesi, Aphis pomi, Aphis gossypii, Aphis gossypii, Aphis gossypii Aphis grossulariae, Aphis schneideri, Aphis spiraecola, Aphis sambuci, Acyrthosiphon pisum, Aulacorthum solumi Foli (Bemisia argentifolii), Bemisia tabaci, Brachycaudus cardui, Brachycaudus helichrysi, Brachycaudus persicae, Brachycaudus persicae, Brachycaudus persicae, Brachycaudus persicae Brevicoryne bras sicae), Capitophorus horni, Cerosipha gossypii, Chaetosiphon fragaefolii, Cryptomyzus ribis, Dreyfusia nordrey piceae), Dysaphis radicola, Dysaulacorthum pseudosolani, Dysaphis plantaginea, unisaphis pyrial, empaska opt ), Hypermyzus lactucae, Macrosiphum avenae, Macrosiphum euphorbiae, Macrosiphon rosae, Megoura viciae , Melanaphis pyrarius, Metopolophium dirhodum, Myzus persicae, Myzus ascalonicus, Myzus cerasi, Myzus cerasis, Myzus cerasis Nasonovia ribis-nigri, Nilaparvata lugens, Pemphigus bursarius, Perkinsiella saccharicida, Perkinsiella saccharicida, Phoros humili (Phorodon humili) mali), Psylla piri, Rhopalomyzus ascalonicus, Rhopalosiphum maidis, Rhopalosiphum padi, Rhopalosiphum padi, Rhopalosiphum insap ), Sappafith Mali (Sappaphis mali), Schizaphis graminum, Schizoneura lanuginosa, Sitobion avenae, Trialeurodes vaporariox, Trialeurodes vaporariorum, opt. (Viteus vitifolii), Cimex lectularius, Cimex hemipterus, Reduvius senilis, Triatoma spp. And Arilus critatus, Arilus critatus
Ants, bees, bees, bees (Hymenoptera), for example, Athalia rosae, Atta cephalotes, Atta capiguara, Atta laevigata Atta robusta, Atta sexdens, Atta texana, Crematogaster spp., Hoplocampa minuta, Hoplocampa testudine test , Monomorium pharaonis, Solenopsis geminata, Solenopsis invicta, Solenopsis richteri, Solenopsis xyloni , Pogoonomyrmex calfornicus ifornicus), Pheidole megacephala, Dasymmuta occidentalis, Bombus spp., Vespula squamosa, Paravespura vulgaris (Paravespula vulgaris) Paravespula pennsylvanica, Paravespula germanica, Dolichovespula maculata, Vespa crabro, Polistes rubiginosa, Camponotus lines humline ),
Crickets, grasshoppers, locusts (Orthoptera), for example, Acheta domestica, Gryllotalpa gryllotalpa, Locusta migratoria, Melanoplus bivittatus Melanoplus femurrubrum, Melanoplus mexicanus, Melanoplus sanguinipes, Melanoplus spretus, Nomadacris septa Na (Schistocerca americana), Sistocerca gregaria, Dokiostaurus maroccanus, Tachycines asynamorus, Oedaleus senegalensis, Zoegalus Egatsusu (Zonozerus variegatus), hieroglyph vinegar Daganenshisu (Hieroglyphus daganensis), Kurausaria-Angurifera (Kraussaria angulifera), Kariputamusu-Itarikusu (Calliptamus italicus), Korutoisetesu Termini Blow (Chortoicetes terminifera), and Rokusutana-Parudarina (Locustana pardalina),
Spiders such as arachnids (Acari), e.g. Argasidae, Ixodidae and Sarcoptidae, e.g. Amblyomma americanum, Amblyomma variegatum ), Ambryomma maculatum, Argas persicus, Boophilus annulatus, Boophilus decoloratus, Boophilus microplus, silma var , Dermacentor andersoni, Dermacentor variabilis, Hyalomma truncatum, Ixodes ricinus, Ixodes rubicund, desxo scapularis), Ixodes holocyclus, Ixodes pacificus, Ornithodorus moubata, Ornithodorus hermsi, Ornithodorus honata, Orata , Otobius megnini, Dermanyssus gallinae, Psoroptes ovis, Rhipicephalus sanguineus, Rhipicephalus tusguitus, phallicus Sarcoptes scabiei, as well as Eriophyidae species, for example, Aculus schlechtendali, Phyllocoptrata oleivora, Eriophyes sheldoni; Tarsonemidae spp., For example, Phytonemus pallidus and Polyphagotarsonemus latus; Sp. For example, Brevipalpus phoenicis; Tetranychidae spp., For example, Tetranychus cinnabarinus, Tetranychus kanzawai, Tetranychus pacific, Tetranychus telarius and Tetranychus urticae, Panonychus ulmi, Panonychus citri, and Oligonychus pratensis; Araneida For example, Latrodex Macta Latrodectus mactans, Loxosceles reclusa, ticks (lxodida), such as Phipicephalus sanguineus, or ticks, such as Mesostigmata, such as Ornitonis Ornithonyssus bacoti and Dermanyssusgallinae, Prostigmata, such as Pymotes tritici, or Astigmata, such as Acarus siro, or further ticks Polygophagotarsoemus latus, Phyllocoptruta oleivora, Eutetranychus banksi, Aculops lycopersici, Pneui, P Eriophyes que rreronis),
Fleas (Siphonaptera), e.g. Ctenocephalides felis, Ctenocephalides canis, Xenopsylla cheopis, Plexex irritans, Tunga penetrans, and Nosopsyllus fasciatus,
Spots, spotted (Thysanura), such as Lepisma saccharina and Thermobia domestica,
Centipedes (Chilopoda), for example, Scutigera coleopterata
optrata),
Millipede (Diplopoda), for example, Narceus spp.
Earwigs (Dermaptera), for example, forficu
la auricularia),
Lice (Phthiraptera), e.g., Pediculus humanus capitis, Pediculus humanus corporis, Pthirus pubis, Haematopinus euryus Switzerland (Haematopinus suis), Linognathus vituli, Bovicola bovis, Menopon gallinae, Menacanthus stramineus and Solenopotes ole sole
Plant parasitic nematodes such as root-knot nematodes, Meloidogyne arenaria, Meloidogyne chitwoodi, Meloidogyne exigua, Meloidogyne hapla, Meloidogyne hapla , Meloidogyne javanica and other Meloidogyne species; cyst nematodes, Globodera rostochiensis, Globodera pallida, Globodera tabacum (Globa tabacum) Other Globodera species, Heterodera avenae, Heterodera glycines, Heterodera schachtii, Heterodera trifolii, and other heterodes Heterodera species; Humpworm nematodes, Anguina funesta, Anguina tritici and other Anguina species; Stem and leaf nematodes, Aplencoides Bessey (Aphelenchoides besseyi), Aphelenchoides fragariae, Apelenchoides ritzemabosi, and other species of the genus Aphelenchoides (Aphelenchoides species); the sting nematode, the genus Veronimus longonus Belonolaimus species; Pine nematodes, Bursaphelenchus xylophilus and other Bursaphelenchus species; Ring nematodes, Criconema species, Criconemella species ), Criconemoides specie s), and Mesocriconema species; stem and bulb nematodes, Ditylenchus destructor, Ditylenchus dipsaci, Ditylenchus myceliophagus and other species of Ditylenchus myceliopharenx (Ditylenchus species); awl nematodes, Dolichodorus species; spiral nematodes, Helicotylenchus dihystera, Helicocotlenchus multicinctus and other Helicotylenchus species, Rotylenchus robustus, and other Rotylenchus species; helminthic nematodes, Hemicycliophora species and Hemicliconophora species Hemicriconemoides species; Hill Hirshmanniella species; lance nematodes, Hoplolimus columbus, Hoplolimus galeatus, and other Hoplolimus species; pseudoroot-knot nematodes, nacobus・ Abelans (Nacobbus aberrans) and other Nacobbus species; needle nematodes, Longidorus elongates and other Longidorus species; pin nematodes, Paratylenchus species; Lesion nematodes, Pratylenchus brachyurus, Pratylenchus coffeae, Pratylenchus curvitatus, Pratylenchus praus Negrektus (Pratylencus neglec tus), Pratylenchus penetrans, Pratylenchus scribneri, Pratylenchus vulnus, Pratylenchus zeae, and other Platylenchus species; Cocopyrus (Radinaphelenchus cocophilus) and other Radinaphelenchus species; perforated nematodes, Radopholus similis and other Radopholus species; nephrogenic nematodes, Rochulencruz Rotylenchulus reniformis and other Rotylenchulus species; Scutellonema species; stubby root nematodes, Trichodorus primitives and other Trichodrus species Species (Trichodorus species); Paratricodorus Minor (Paratrichodorus minor) and other Paratricrichodorus species; stunt nematodes, Tylenchorhynchus claytoni, Tylenchorhynchus dubius and other Turenco Tylenchorhynchus species and Merlinius species; nematodes, Tylenchulus semipenetrans and other Tylenchulus species; dagger nematodes, Xiphinema americanum, Xiphinema index, Xiphinema diversicaudatum and other Xiphinema species; and other plant parasitic nematode species.

  In one highly preferred embodiment, the insect is selected from phytophagous pests.

  One embodiment of the present invention relates to a method for controlling or controlling phytophagous insects selected from Lepidoptera. In this embodiment, preference is given to insects from the family of scallops, in particular Alabama argillacea, Anticarsia gemmatalis, Heliothis virescens, Pseudoplusia includens. ) And Spodoptera frugiperda. Insects selected from the group consisting of Spodoptera frugiperda. Even more preferred are white butterflies (especially Ascia monusteorseis as a target), nymphalidae (especially Dione juno juno as a target), stag beetle (especially as a target) It is an insect selected from the family consisting of Phthhorimaea operculella and tuta absoluta and the long-tailed moth family (especially Plutella xylostella as a target).

  A further embodiment of the invention relates to a method for combating or controlling sessile insects selected from sucking insects, in particular lygus bugs, aphids and whiteflies.

  A further embodiment of the present invention relates to a method for combating or controlling phytophagous insects selected from the order Hemiptera.

  A further embodiment of the present invention relates to a method for combating or controlling phytophagous insects selected from planthoppers (Delphacidae) and leafhoppers (Deltocephalidae). Among the planthoppers, the common planthopper (Laodelphax striatellus), the planthopper (Nilaparvata lugens) and the white planthopper (Sogatella furcifera) are preferred target insects. Among leafhoppers, leafhoppers (Nephotettix cincticeps, Nephotettix nigropictus) and nephotettix virescens are preferred target insects.

  Further embodiments of the present invention are selected from Diptera, more preferably from the family Frosidae (especially Ceratitis capitata as a target) and the family Phyllidae (especially Liriomyza huidobrensis as a target). The present invention relates to a method for controlling or controlling phytophagous insects.

  A further embodiment of the invention relates to a method for controlling or controlling a phytophagous insect selected from Coleoptera among Coleoptera. In this embodiment, preference is given to insects of the beetle family, in particular Diabrotica speciosa as a target.

  A further embodiment of the present invention relates to a method for controlling or controlling a phytophagous insect selected from thrips of the order Lepidoptera. In this embodiment, preference is given to insects of the family Thripidae, in particular Thrips tabaci as a target.

  A further embodiment of the invention relates to a method for combating or controlling a phytophagous insect selected from the true bugs of the hemiptera. In this embodiment, they are insects of the whitefly family (especially Bemisia tabaci as a target) and the waspidae family (especially Brevicoryne brassicae as a target).

  A further embodiment of the present invention relates to a method for controlling or controlling phytophagous insects selected from the order Mite. In this embodiment, preference is given to insects of the family Acaridae, in particular Brevipalpus phoenicis as a target.

  A further embodiment of the present invention relates to a method for controlling or controlling ticks selected from the subfamily Mite. In this embodiment, preference is given to spider mites (especially Tetranychus urticae and Panonychus ulmi), mite mites (especially polyphagotarsonemus latus (target) Polyphagotarsonemus latus)), and ticks of the family Mite (especially Phyllocoptruta oleivora as a target).

  The composition according to the present invention controls the target pests and / or for agricultural plants, seeds, roots and / or fields, feeds, plantations, greenhouses, orchards or vineyards Used to protect plants, including above-ground parts of plants, ornamental plants, plantations or forest trees, and / or any other relevant plant (s).

  A particular embodiment of the present invention is a method of treating and / or protecting a plant from the attack or spread of pests by insects, ticks or nematodes, on the plant or when the plant is grown It relates to a process comprising applying the composition according to the invention to soil or water. Preferably, the composition is applied to agricultural plants.

  The term `` agricultural plant '' means that part (e.g. seed) or all of it is harvested or cultivated on a commercial scale, or feed, food, fiber (e.g. cotton, hemp), chemical process (oil, sugar), It should be understood as a plant that serves as an important source of combustibles (eg wood, bioethanol, biodiesel, biomass) or other chemicals. Agricultural plants can also include horticultural plants, ie plants that grow in the garden (not in the field), such as certain fruits, vegetables and flowers (eg roses). Preferred agricultural plants include, by way of example, cereals such as wheat, rye, barley, triticale, oats, sorghum or rice, beets such as sugar beet or feed beets; fruits such as berries, stones or berries fruits), e.g. apple, melon, watermelon, papaya, passion fruit, pear, plum, peach, almond, cherry, strawberry, raspberry, blackberry or gooseberry; legumes, e.g. drybean, Lentils, peas, alfalfa or soybeans; oil plants such as oilseed rape, oilseed rape, canola, flaxseed, mustard, olive, sunflower, coconut, cacao bean, castor bean, oil palm, groundnut or soy; cucurbits such as pumpkin, cucumber or melon; Fiber plant, eg Cotton, flax, hemp or jute; fruits such as orange, lemon, grapefruit or mandarin; vegetables such as spinach, lettuce, asparagus, cabbage, carrot, onion, tomato, potato, cucumber or paprika; camphoraceae such as avocado, Cinnamon or camphor; for energy plants and raw materials such as corn, soybeans, rape, canola (canola rape), sugar cane or oil palm, corn, tobacco, nuts, coffee, tea, banana, grapes such as table grape, grape juice Grape vine, pepper, hops, turf, natural rubber plant, or ornamental and forestry plants, such as flowers, shrubs, hardwoods or evergreens (e.g. conifers), and plant propagation materials For example, seed Offspring and crop materials of these plants.

  In the context of the present invention, the term “plant” refers to a whole plant, a part of a plant, or a propagation material of a plant, such as seeds, seed pieces, grafts, seedlings or cuttings.

  Certain embodiments relate to a method of treating and / or protecting agricultural plants selected from consequential plants, potatoes, rice, cereals, soybeans, dry beans, cotton, vegetables, sugarcane and horticultural plants. The resulting plants of the present invention are the main types of fruits, e.g., berries, e.g., strawberries, blueberries; nuclear fruits, e.g. peaches, cherries, olives, plums and walnuts; aggregate fruits, e.g. blackberries and raspberries; Compound fruits such as pineapples, figs and mulberries; and false fruits such as apples, pears and strawberries, and citrus fruits such as oranges, grapefruits, kumquats, lemons, limes, tangerines, temples, citrus, tangero, buntan, and Includes citron.

  Plants treated with the composition according to the invention are all genetically modified or transformed plants, for example crops that are resistant to the action of herbicides or fungicides or insecticides resulting from breeding, including genetic engineering methods, or , Including plants that have modified properties compared to existing plants and can be produced, for example, by traditional breeding methods and / or the development of mutants, or by recombinant procedures.

  Some compositions according to the invention have osmotic action and can therefore be used for the protection of shoots from phytophagous pests and for the treatment of seeds and roots against soil pests. The term “seed treatment” includes all suitable seed treatment techniques known in the art, such as seed dressing, seed coating, seed dusting, seed soaking and seed pelleting.

  In particular, the seeds are tuber-type and bulbous-type vegetables, such as arachacha, kuzukon, artichoke, canna, cassava, carrot, chayote root, chufa, taro, ginger, renren, onion, potato, radish, tanier ), Turmeric, kuzu-imo, yam; leafy vegetables such as amaranth, arugula, cardon, celery, celtas, chervil, chrysanthemum, watercress, dandelion, scallop, endive, fennel, kale, liki, lettuce, spinach, parsley, burdock, radicchio Rhubarb, spinach, chard, hagate, head and stem brassica, such as broccoli, brussels sprouts, cabbage, cauliflower, cavalo broccolo, curly kale, kohlrabi Leafy brassica greens, such as broccoli raab, cabbage, collard, kale, Mizuna, Takana, Komatsuna, Nanohana; fruiting vegetables, such as legumes, chili, postharvest, eggplant, physalis, Pepino, peas, pepper, tomatillo and tomatoes. The seeds are preferably broccoli, carrot, cabbage, particularly Chinese cabbage, red cabbage, chili cabbage, white cabbage, celery, cauliflower, kohlrabi and radish seeds.

  A preferred embodiment of the present invention is a method for protecting or treating cotton from the pests Alabama argillacea or Tetranychus urticae, comprising applying composition A to a cotton plant. Relates to the method of inclusion.

  A preferred embodiment according to the present invention is a method of protecting or treating citrus plants from the pests Brevipalpus phoenicis, Phyllocoptruta oleivora and Polyphagotarsonemus latus. A method comprising applying composition A to a citrus plant.

  A preferred embodiment of the present invention relates to a method for protecting or treating a coffee plant from the pest Brevipalpus phoenicis, comprising applying composition A to the coffee plant.

  A preferred embodiment of the present invention relates to a method for protecting or treating apple plants from the pest Panonychus ulmi, comprising applying composition A to the apple plants.

  Preferred embodiments of the present invention include the pests Anticarsia gemmatalis, Pseudoplusia includens, Tetranychus urticae, and Polyphagotarsonemus latus. The present invention relates to a method for protecting or treating soybean plants from, comprising applying composition A to soybean plants.

  A preferred embodiment of the present invention relates to a method for protecting or treating an onion plant from the pest Thrips tabaci, comprising applying composition A to the onion plant.

  Preferred embodiments of the present invention protect or treat potato plants from the pests Diabrotica speciosa, Liriomyza huidobrensis, Phthhorimaea operculella and Tryps tabaci. The method relates to a method comprising applying composition A to a potato plant.

  A preferred embodiment of the present invention is a method for protecting a cabbage plant from pests such as Ascia monusteorseis, Liriomyza huidobrensis, etc., wherein the composition A is applied to the cabbage plant. Relates to a method comprising:

  A preferred embodiment of the present invention is a method for protecting or treating chrysanthemum plants from the pests Thrips tabac and Tetranychus urticae, comprising applying composition A to the chrysanthemum plant Relates to a method comprising:

  Preferred embodiments of the present invention protect or protect dry bean plants from the pests Diabrotica speciosa, Thrips tabaci, Tetranychus urticae and Bemisia tabaci. A method of treatment, comprising applying composition A to a dry bean plant.

  A preferred embodiment of the present invention relates to a method for protecting or treating a papaya plant from the pest Polyphagotarsonemus latus, comprising applying composition A to the papaya plant.

  A preferred embodiment of the present invention relates to a method of protecting or treating a passion fruit plant from the pest Dione juno juno, comprising applying composition A to the passion fruit plant.

  A preferred embodiment of the present invention relates to a method for protecting or treating a melon or watermelon plant from the pest Thrips tabaci, comprising applying composition A to the melon or watermelon plant.

  A preferred embodiment of the present invention relates to a method of protecting or treating corn plants from the pest Spodoptera frugiperda, comprising applying composition A to the corn plants.

  A preferred embodiment of the present invention relates to a method for protecting or treating pepper plants from the pest Diablotica speciosa, comprising applying composition A to the pepper plants.

  A preferred embodiment of the present invention relates to a method of protecting or treating rose plants from the pest Tetranychus urticae, comprising applying composition A to the rose plant.

  A preferred embodiment of the present invention is a method for protecting or treating tomato plants from the pests Aculops lycopersici, Tetranychus urticae and Tuta absoluta. To a method comprising applying composition A.

  For use according to the invention, the composition or the combination of active compounds I and II can be converted into customary formulations, such as solutions, emulsions, suspensions, powders, powders, pastes and granules. The use form depends on the particular purpose envisaged and in each case should ensure a fine and uniform distribution of the compound according to the invention.

  A preferred embodiment is a method in which the composition according to the invention is applied foliar. As used herein, the term “foliar application” refers to applying the composition to the leaves of a plant via a spray device. Foliar application takes place at all times after plant emergence.

The formulations are prepared in a known manner, for example by developing the active compound in solvents and / or carriers, if desired using emulsifiers and dispersants. Suitable solvents / auxiliaries are in particular the following:
-Water, aromatic solvents (e.g. Solvesso product, xylene), paraffins (e.g. mineral oil fraction), alcohols (e.g. methanol, butanol, pentanol, benzyl alcohol), ketones (e.g. cyclohexanone, γ-butyrolactone), Pyrrolidone (NMP, NOP), acetate (glycol diacetate), glycol, fatty acid dimethylamide, fatty acid and fatty acid ester. In principle, solvent mixtures can be used as well,
-Carriers such as powdered natural minerals (e.g. kaolin, clay, talc, chalk) and powdered synthetic minerals (e.g. highly disperse silica, silicates); emulsifiers such as nonionic and anionic emulsifiers (e.g. polyoxyethylene fatty alcohols) Ethers, alkyl sulfonates and aryl sulfonates) and dispersants such as lignosulfite waste liquors and methylcellulose.

  Suitable surfactants include lignosulfonic acid, naphthalene sulfonic acid, phenol sulfonic acid, dibutyl naphthalene sulfonic acid, alkyl aryl sulfonate, alkyl sulfate, alkyl sulfonate, aliphatic alcohol sulfate, fatty acid, and sulfated aliphatic alcohol glycol. Alkali metal salts, alkaline earth metal salts, and ammonium salts of ethers, and further, condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxy Ethylene octylphenol ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ether, tributylphenol Polyglycol ether, tristearyl phenyl polyglycol ether, alkylaryl polyether alcohol, alcohol and aliphatic alcohol ethylene oxide condensate, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal Sorbitol esters, lignosulfite waste liquors, and methylcellulose.

  Suitable for the preparation of directly sprayable solutions, emulsions, pastes or oil dispersions are medium to high boiling mineral oil fractions, such as kerosene or diesel oil, and also coal tar oil and plant or animal origin Oils, aliphatic, cyclic and aromatic hydrocarbons such as toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalene or derivatives thereof, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, strong solvents For example, dimethyl sulfoxide, N-methylpyrrolidone, and water.

  Furthermore, antifreezing agents such as glycerin, ethylene glycol, propylene glycol and bactericides can be added to the preparation.

  Suitable antifoaming agents are for example antifoaming agents based on silicon or magnesium stearate.

  Suitable preservatives are, for example, dichlorophen and benzyl alcohol hemiformal.

  The seed treatment formulation may further comprise a binder and optionally a colorant.

  Binders can be added to improve the adhesion of the active substance to the seed after treatment. Suitable binders are block copolymer EO / PO surfactants, but polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylate, polymethacrylate, polybutene, polyisobutylene, polystyrene, polyethyleneamine, polyethyleneamide, polyethyleneimine (Lupasol® ), Polymin®), polyethers, polyurethanes, polyvinyl acetate, tyrose and copolymers derived from these polymers.

  In some cases, a colorant may also be included in the formulation. Coloring agents or dyes suitable for seed treatment formulations are Rhodamine B, CI Pigment Red 112, CI Solvent Red 1, Pigment Blue 15: 4, Pigment Blue 15: 3, Pigment Blue 15: 2, Pigment Blue 15: 1, Pigment Blue 80, Pigment Yellow 1, Pigment Yellow 13, Pigment Red 112, Pigment Red 48: 2, Pigment Red 48: 1, Pigment Red 57: 1, Pigment Red 53: 1, Pigment Orange 43, Pigment Orange 34, Pigment Orange 5 , Pigment Green 36, Pigment Green 7, Pigment White 6, Pigment Brown 25, Basic Violet 10, Basic Violet 49, Acid Red 51, Acid Red 52, Acid Red 14, Acid Blue 9, Acid Yellow 23, Basic Red 10, Basic In red 108 is there.

  An example of a gelling agent is carrageenan (Satiagel®).

  Powders, dusting substances and dustable products can be prepared by mixing or co-grinding the active substance and a solid carrier.

  Granules such as coated granules, impregnated granules and homogeneous granules can be prepared by binding the active compound to a solid carrier. Examples of solid carriers are mineral earth, such as silica gel, silicate, talc, kaolin, attaclay, limestone, lime, chalk, block clay, loess, clay, dolomite, diatomaceous earth, calcium sulfate, sulfuric acid Magnesium, magnesium oxide, powdered synthetic materials, fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, etc., and plant-derived products such as cereal meal, bark meal, wood meal and nutshell meal, cellulose powder, and others The solid support.

  In general, the formulations comprise 0.01 to 95% by weight of active compound, preferably 0.1 to 90%. The active compounds are used in a purity of 90% to 100%, preferably 95% to 100% (depending on the NMR spectrum).

  In seed treatment, each formulation can be diluted 2 to 10 times to give an active compound concentration in the ready-to-use preparation of 0.01 to 60% by weight, preferably 0.1 to 40% by weight.

  The following are examples of formulations.

1. Products diluted with water For seed treatment, such products can be applied to the seed diluted or undiluted.

A) Liquid (SL, LS)
10 parts by weight of active compound are dissolved in 90 parts by weight of water or a water-soluble solvent. As an alternative, wetting agents or other auxiliaries are added. The active compound dissolves upon dilution with water. A formulation having an active compound content of 10% by weight is obtained in this way.

B) Dispersion formulation (DC)
20 parts by weight of active compound are dissolved in 70 parts by weight of cyclohexanone by addition of 10 parts by weight of a dispersant, for example polyvinylpyrrolidone. Dilution with water gives a dispersion. The active compound content is 20% by weight.

C) Emulsion (EC)
15 parts by weight of the active compound are dissolved in 75 parts by weight of xylene by the addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). Dilution with water gives an emulsion. The formulation has an active compound content of 15% by weight.

D) Emulsion formulation (EW, EO, ES)
25 parts by weight of the active compound are dissolved in 35 parts by weight of xylene by addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). This mixture is added to 30 parts by weight of water using an emulsifier (eg Ultraturrax) to make a homogeneous emulsion. Dilution with water gives an emulsion. The formulation has an active compound content of 25% by weight.

E) Suspension preparation (SC, OD, FS)
In a stirred ball mill, 20 parts by weight of the active compound is finely pulverized while adding 10 parts by weight of a dispersant and wetting agent and 70 parts by weight of water or an organic solvent to obtain a fine active compound suspension. Give rise to Dilution with water gives a stable suspension of the active compound. The active compound content in the formulation is 20% by weight.

F) Granule wettable powder and granule water solvent (WG, SG)
Finely pulverize 50 parts by weight of the active compound with addition of 50 parts by weight of dispersant and wetting agent and use a special equipment (e.g. extruders, spray towers, fluidized beds) and granulated wettable powders or granular water. Use solvent. Dilution with water gives a stable dispersion or solution of the active compound. The formulation has an active compound content of 50% by weight.

G) Powder wettable powder and powder water solvent (WP, SP, SS, WS)
75 parts by weight of active compound are ground in a rotor stator mill while adding 25 parts by weight of dispersant and wetting agent and silica gel. Dilution with water gives a stable dispersion or solution of the active compound. The active compound content of the formulation is 75% by weight.

H) Gel preparation (GF)
In a ball mill, 20 parts by weight of active compound, 10 parts by weight of dispersant, 1 part by weight of gelling agent and 70 parts by weight of water or organic solvent are ground to form a fine suspension. On dilution with water, a stable suspension with an active compound content of 20% by weight is obtained.

2. Products to be applied undiluted
I) Powder (DP, DS)
5 parts by weight of active compound are ground finely and mixed carefully with 95 parts by weight of finely divided kaolin. This gives a dustable product with an active compound content of 5% by weight.

J) Granules (GR, FG, GG, MG)
0.5 parts by weight of active compound are ground finely and combined with 99.5 parts by weight of support. Current methods are extrusion, spray drying or fluidized bed. This gives granules to be applied undiluted having an active compound content of 0.5% by weight.

K) ULV solution (UL)
10 parts by weight of active compound are dissolved in 90 parts by weight of an organic solvent, for example xylene. This gives a product to be applied undiluted having an active compound content of 10% by weight.

  For seed treatment, usually liquid (LS), suspension (FS), powder (DS), powder wettable powder and powdered water solvent (WS, SS), emulsion (ES), emulsion (EC) and gel formulation (GF) is used. These formulations can be applied to the seed in undiluted form or preferably diluted. Application can be carried out before sowing.

  In a preferred embodiment, the FS formulation is used for seed treatment. Typically, the FS formulation comprises 1-800 g / L active ingredient, 1-200 g / L surfactant, 0-200 g / L cryoprotectant, 0-400 g / L binder, 0-200 g. / L pigment and up to 1 liter of solvent (preferably water).

  The active compounds can be used as such, in the form of their formulations or in the use forms prepared therefrom, for example directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, It can be used by spraying, atomizing, dusting, dusting or watering in the form of dustable products, dusting substances or granules. The use form depends entirely on the intended purpose, which is to ensure in each case the finest possible distribution of the active compounds according to the invention.

  Aqueous use forms can be prepared from emulsions, pastes or wettable powders (sprayable powders, oil dispersions) by adding water. To prepare emulsions, pastes or oil dispersions, the material is homogenized in water using wetters, tackifiers, dispersants or emulsifiers as is or dissolved in oil or solvent. it can. Alternatively, it is possible to prepare concentrated formulations consisting of active substances, wetting agents, tackifiers, dispersants or emulsifiers and, if appropriate, solvents or oils; Suitable for dilution.

  Active compound concentrations in ready-to-use preparations can be varied within a relatively wide range. In general, they are from 0.0001 to 10%, preferably from 0.01 to 1%.

  The active compounds can also be used precisely by the ultra-micro-dispersion method (ULV), which makes it possible to apply formulations containing more than 95% by weight of active compounds, or even active without additives. It is even possible to apply the compound.

  Various types of oils, wetting agents, adjuvants, herbicides, fungicides, other pesticides or bactericides, if appropriate, may be added to the active compound immediately before use. Good (tank mix). These agents can be mixed with the agents according to the invention in a weight ratio of 1: 100 to 100: 1, preferably 1:10 to 10: 1.

  The composition of the present invention comprises other active ingredients such as insecticides, fungicides, herbicides, fertilizers such as ammonium nitrate, urea, potash and superphosphates, plant harmful substances and plant growth regulators, safeners As well as other pesticides, which may be nematicides. These additional ingredients may be used sequentially or in combination with the above-described composition, and may be added immediately before use if appropriate. Good (tank mix). These agents can be mixed with the mixture according to the invention in a weight ratio of 1:10 to 10: 1. For example, the plant (s) can be sprayed with the composition of the present invention either before or after treatment with other active ingredients.

  The compositions and methods according to the present invention are particularly useful for pest control. The compositions and methods according to the present invention are particularly useful for combating pests.

  Methods for controlling and / or controlling pests include treating, in other words, pests, their habitats, breeding grounds, food sources, cultivated plants where the pests are or can grow, A pesticide effective amount of at least one active compound of formula I on the seed, soil, area, substance or environment, or the substance, plant seed, soil, surface or space that is to be protected from attack or spread of pests And contacting with a mixture of at least an active compound of formula II.

  The pesticidal composition according to the invention is suitable for efficiently controlling invertebrate pests, in particular insects, mites and nematodes. They can be applied to any and all developmental stages such as eggs, larvae, willows, and adults.

  The pest contacts the pest itself, its food source, habitat, breeding place or location and a pesticidally effective amount of a mixture of the invention or a composition comprising active compounds I and II. Can be controlled by.

  The term “location” above refers to a plant, seed, soil, area, material or environment in which a pest is growing or can grow.

  In general, a “pesticide effective amount” is the amount required to produce an observable effect on growth, including necrosis, death, delay, prevention, and removal, destruction, or otherwise It means the amount of the composition comprising the active compound according to the invention that is required to attenuate the development and activity of the organism. The pesticidal effective amount can vary for the various mixtures / compositions used in the present invention. The pesticidal effective amount of the mixture / composition will also vary according to general conditions such as desired pesticidal effect and duration, weather, target species, location, mode of application, and the like.

  In the present invention, the term pesticidal effective amount according to the invention always refers to a synergistically effective amount of compounds I and II.

  It will be appreciated from the above that compounds I and II can be applied simultaneously, ie together (eg in the same formulation) or separately (eg in different formulations, eg in kit form) or sequentially. In the case of continuous application, subsequently applied compounds I and II are directed against the subject (e.g. pests, plants or animals) within a time scale that achieves or optimizes the advantageous synergistic effects described above. It will also be understood that this should be applied.

  Compounds I and II are usually 20: 1 to 1:50, in particular 10: 1 to 1:10, in particular 1: 5 to 1: 1, particularly preferably 1: 5 to 1: 3, also preferably 1: 3. ~ 1: 2 weight ratio, mainly 1: 5, or 1: 4, or 1: 3, or 2: 5, or 1: 2, or 2: 4, or 3: 5, or 4: 5 Or in a 1: 1 ratio. A very specific weight ratio of compounds I and II is about 2: 5, respectively.

  Depending on the desired effect, the application rate of the mixture according to the invention is 1 to 2500 g / ha, preferably 5 to 2000 g / ha, more preferably 50 to 1500 g / ha, in particular 50 to 750 g / ha, even more particularly. 5 to 500 g / ha.

  The composition according to the invention is also suitable for protecting seed and seedling roots and shoots from soil pests.

  Conventional seed treatment formulations include, for example, a flowable concentrated formulation FS, a liquid LS, a powder DS for drying treatment, a powder wettable powder WS or a granule for slurry treatment, a powder water solvent SS, and an emulsion formulation ES. Application to seeds is carried out before or after sowing, either directly or after pre-germination of seeds, and at the time of sowing or after sowing. Preference is given to FS formulations.

  For seed treatment, the application rate of the mixtures according to the invention is generally between 0.1 and 10 kg per 100 kg seed, in particular between 1 g and 2 kg per 100 kg seed. Separate or joint application of compounds I and II or a mixture of compounds I and II can be applied to seeds, seedlings, plants or soils before or after plant sowing or before or after plant emergence. Or do by dusting.

  The invention also provides a composition as defined above or a composition containing more active ingredients in addition to the compounds of formulas I and II, or one of the active ingredients of formulas I and II, respectively. It also relates to plant propagation material (especially seeds) comprising a mixture of two or more compositions, ie covered by and / or containing them. Seeds contain the mixture of the invention in an amount of 0.1 g to 10 kg per 100 kg seed, preferably 1 g to 5 kg per 100 kg, most preferably 1 g to 2.5 kg per 100 kg.

  The compositions of the present invention can be applied both by contact (via soil, glass, walls, mosquito nets, carpets, plant parts or animal parts) and feeding (food or plant parts) as well as nutrition. It is also effective by exchange and transfer.

  The composition according to the invention is preferably also effective by foliar contact with respect to plant protection.

  According to a further embodiment of the invention, the pesticidal composition is used by soil application. Soil application is particularly preferred for use against ants, termites, flies, crickets, maggots, root weevil, root beetles or nematodes.

  According to another embodiment of the present invention, for use against non-crop pests such as ants, termites, wasps, flies, mosquitoes, crickets, grasshoppers, or cockroaches, the composition of the present invention is prepared in a bait preparation. The

  The bait preparation can be a liquid, solid, or semi-solid preparation (eg, a gel). The bait preparation used in the composition is a product that is sufficiently attractive to stimulate the insects that eat it, such as ants, termites, wasps, flies, mosquitoes, crickets, etc. or cockroaches. This attractant can be selected from feeding stimulants or pheromone analogs and / or sex pheromones. Suitable feeding stimulants are, for example, from animal and / or vegetable proteins (meat, fish or blood meal, insect parts, cricket powder, egg yolk), from fats and oils from animals and / or plants, or From monosaccharides, oligosaccharides or polyorganosaccharides, in particular from sucrose, lactose, fructose, glucose, glucose, starch, pectin, or even from molasses or honey, or salts such as ammonium sulfate, ammonium carbonate or ammonium acetate Selected from. Fresh or decaying parts of fruits, crops, plants, animals, insects or their specific parts can also serve as feeding stimulants. Pheromones are known to be more insect specific. Specific pheromones are described in the literature and are known to those skilled in the art.

  Formulations of pesticide compositions according to the present invention as aerosols (e.g. in spray cans), oil sprays or pump sprays are used for non-expert users such as flies, fleas, ticks, mosquitoes, grasshoppers or cockroaches. Very suitable for control. Aerosol formulations are preferably active compounds I and II, lower alcohols (eg methanol, ethanol, propanol, butanol), ketones (eg acetone, methyl ethyl ketone), paraffinic hydrocarbons having a boiling point in the range of about 50-250 ° C. (E.g. kerosene), dimethylformamide, N-methylpyrrolidone, dimethyl sulfoxide, aromatic hydrocarbons, e.g. toluene, xylene, water and other solvents, as well as auxiliaries, e.g. emulsifiers e.g. sorbitol monooleate, 3-7 mol Oleyl ethoxylates, aliphatic alcohol ethoxylates with the ethylene oxide, perfume oils such as ether oils, esters of medium chain fatty acids and lower alcohols, aromatic carbonyl compounds, if appropriate stabilizers such as sodium benzoate, amphoteric surface activity Agent, lower epoxide, Ethyl orthoformate, and propellants if necessary, constituted for example propane, butane, nitrogen, compressed air, dimethyl ether, carbon dioxide, nitrous oxide, or mixtures of these gases.

  Oil spray formulations differ from aerosol formulations in that no propellants are used.

  Each of these compositions comprising the combination of compounds and carrier according to the present invention can also be used in mosquito coils and cocoon evaporation coils, smoke cartridges, vaporizer plates, long-term vaporizers, or other non-thermally dependent vaporization systems.

  Methods for inhibiting infectious diseases transmitted by insects (e.g., malaria, dengue and yellow fever, lymphatic filariasis, and leishmaniasis) using the mixtures of the present invention and their respective compositions are also disclosed in huts and houses. It includes treating the surface, air spraying and impregnating curtains, tents, clothing, mosquito nets, tsetse fly traps and the like. Insecticide compositions for application to fibers, wovens, knitted fabrics, nonwovens, nets or foils and tarps preferably include a mixture comprising an insecticide and optionally a dispersant and at least one binder.

  The composition according to the present invention includes not only wooden materials such as trees, board slats and sleepers and buildings such as houses, barns and factories, but also building materials, furniture, leather, textiles, vinyl articles, electric wires and cables. And / or can be used to protect from termites and to prevent ants and termites from harming crops or humans (eg, when pests invade houses and public facilities). The composition according to the invention is not only applied to the surrounding soil surface or in the soil under the floor, in order to protect the wood material, but also wooden articles such as underfloor concrete surfaces, floor columns, beams, plywood, It can also be applied to furniture, etc., wooden articles such as particle boards, half boards and the like, and vinyl articles such as coated electric wires, vinyl sheets, heat insulating materials such as polystyrene foam. In the case of application to ants that cause harm to crops or humans, the ant control composition of the present invention is applied to the ant nest or its surroundings directly or through contact with food.

  The mixture of compounds I and II or the composition according to the invention can also be applied preventively to places where the appearance of pests is expected.

When treating soil or applying to pest dwellings or nests, the amount of active compound-containing composition ranges from 0.0001 to 500 g per 100 m ² , preferably from 0.001 to 20 g per 100 m ² .

Customary application rates in the protection of substances are, for example, from 0.01 g to 1000 g of active compound composition per m ^{2 of} substance to be treated, preferably from 0.1 g to 50 g per m ² .

  Insecticide compositions used by soaking in substances typically contain 0.001 to 95% by weight, preferably 0.1 to 45% by weight, more preferably 1 to 25% by weight of the active compound-containing composition. .

  For use in bait compositions, the typical content of compositions containing active compounds I and II is 0.0001% to 15% by weight, desirably 0.001% to 5% by weight of active compound. The composition used may further comprise other additives such as active substance solvents, fragrances, preservatives, dyes or bittering agents. Its attractiveness can also be enhanced by special colors, shapes or textures.

  For use in spray compositions, the content of the composition containing active compounds I and II is 0.001 to 80% by weight, preferably 0.01 to 50% by weight, most preferably 0.01 to 15% by weight.

  For use in the treatment of agricultural plants, the application rates of the compositions containing active compounds I and II according to the invention range from 0.1 g to 4000 g per hectare, preferably from 25 g to 600 g per hectare, more preferably 1 Can be 50 to 500 g per hectare.

  It was also an object of the present invention to provide a composition suitable for treating, controlling, preventing and protecting warm-blooded animals and fish, including humans, against the spread and transmission of pests. The problems that may be encountered with pest control on or in animal and / or human surfaces are similar to those described at the outset, i.e. dose reduction and / or enhancement of activity spectrum And / or a combination of knockdown activity and long-term control and / or resistance management.

  The present invention further relates to warm-blooded animals and fish, including humans, against the spread and transmission of pests, Hymenoptera, Hemiptera, Diptera, Mite, Lice, and Diptera pests For the treatment, control, prevention and protection of said animal, wherein a pesticidally effective amount of the mixture according to the invention is administered or applied orally, topically or parenterally. A method of including is also provided.

  The present invention further treats and controls warm-blooded animals or fish against the spread or transmission of pests, Hymenoptera, Hemiptera, Diptera, Mite, Lice, and Diptera pests, There is also provided a method for preparing a composition for prevention or protection comprising a pesticidally effective amount of a mixture according to the invention.

  The above methods are particularly useful for inhibiting and preventing the spread and transmission in warm-blooded animals such as cattle, sheep, pigs, camels, deer, horses, poultry, goats, dogs and cats and humans.

  Without limitation, lice, lice, ticks, nasal bots, sheep lice, flies, flies, flies, myasitic fly larva, tsutsugamushi, fly, mosquitoes and fleas The spread in warm-blooded animals and fish can be controlled, prevented or eliminated by the mixtures according to the invention.

  For oral administration to warm-blooded animals, the composition according to the invention comprises animal feed, animal feed premix, animal concentrate, pills, solutions, pastes, suspensions, swallows, gels, tablets, pills and It may be formulated as a capsule. Furthermore, the mixtures according to the invention may be administered to animals in their drinking water. For oral administration, the dosage form selected should provide the animal with 0.01 mg / kg to 100 mg / kg of the mixture per animal body weight per day.

  Alternatively, the composition according to the invention may be administered parenterally to animals, for example by rumen, intramuscular, intravenous or subcutaneous injection. The mixture according to the invention may be dispersed or dissolved in a physiologically acceptable carrier for subcutaneous injection. Alternatively, the composition according to the invention may be formulated to be an implant for subcutaneous administration. Furthermore, the composition according to the invention may be administered transdermally to animals. For parenteral administration, the dosage form chosen should provide the animal with 0.01 mg / kg to 100 mg / kg of the composition per animal body weight per day.

  The composition according to the present invention is applied topically to animals in the form of dip, powder, powder, collar, medallion, spray, spot-on and pour-on. May be. For topical application, dips and sprays usually contain 0.5 ppm to 5,000 ppm, preferably 1 ppm to 3,000 ppm of the compound of the invention. Furthermore, the compositions according to the invention may be formulated as ear tags for animals, in particular for quadrupeds such as cattle and sheep.

  Thus, in a further aspect of the present invention there is provided the use of a composition according to the present invention in the preparation of veterinary drugs, in particular parasiticidal drug products.

  The following experiments are intended to illustrate the synergistic effect of the composition according to the invention. The following tests demonstrate the control effect of the composition of the present invention against specific pests. However, the pest control protection afforded by the compositions of the present invention is not limited to these species. In certain cases, the compositions of the present invention are found to exhibit a synergistic effect against other specific important invertebrate pests.

Examples of Use The purpose of the following examples is to illustrate the compositions according to the invention and their insecticidal activity, but is not intended to limit the invention to these examples.

A synergistic effect can be described as an interaction where the combined effect of two or more compounds is greater than the sum of the individual effects of each compound. The existence of a synergistic effect between two mixing partners in terms of control rate can be calculated using the Limpel's formula, often referred to as the Colby's formula (Richer, 1987; Colby , 1967; Limpel et al., 1962, Calculating Synergistic and Antagonistic Responses in Herbicide Combinations, Weeds, 15, 20-22):
E = X + Y-XY / 100
E =% expected lethality for combination of compounds I and II
X =% lethality of compound X measured independently
Y =% fatality rate for Compound Y measured independently.

A synergistic effect is evident when the% mortality observed at the time of combination is greater than the expected% mortality calculated by the Limpel equation. In other words, the combined effect is synergistic when the observed combined control effect is greater than the expected combined control effect (E).

  Analysis of synergy or antagonism between compositions according to the present invention was determined using the Limpel equation.

  Field tests and foliar applications were carried out using commercial active compounds. The composition according to the invention was applied in the field at a final application rate of 400 liters per hectare using tank mixes at the stated concentrations. The observed results are summarized as follows:

1. Activity of mite pests against Brevipalpus phoenicis in coffee plants The experiment was conducted on coffee plants, and the percentage of lethality observed 10 days after application was determined by the observed effect. expressed. The results are summarized as follows:

2. Activity of mite pests against Anticarsia gemmatalis in soybean plants The experiment was carried out on soybean plants and the observed effect on the percentage of mortality observed 7 days after application Represented by. The results are summarized as follows:

3. Activity of leafworm pests on Pseudoplusia includens in soybean plants The experiment was conducted on soybean plants, and the lethality observed 7 days after application. Percentages were expressed by the observed effect. The results are summarized as follows:

Claims (12)

As an active ingredient
1) Benzoylurea compound of formula I

(Where
R is halogen, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy or C ₁ -C ₄ alkylthio,
R ¹ is hydrogen, halogen, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy or C ₁ -C ₄ alkylthio,
R ² is fluorine,
R ³ is hydrogen, halogen, nitro, cyano, C ₁ -C ₄ alkyl or C ₁ -C ₄ haloalkyl,
n is an integer of 0, 1, 2 or 3,
R ⁴ is halogen or OR ⁵
R ⁵ is substituted with up to 3 groups independently selected from C ₁ -C ₄ haloalkyl, C ₃ -C ₇ halocycloalkyl, halogen, C ₁ -C ₄ haloalkyl group, cyano group or nitro group phenyl or may not be, a halogen atom, C ₁ -C ₄ haloalkyl group, a cyano group or up to three may also be 2-pyridyl not they are substituted with a group selected from nitro groups independently Is)
Or agriculturally acceptable salts thereof, and
2) Compound of formula II

Or its agriculturally acceptable salt,
An insecticidal or acaricidal composition comprising a synergistically effective amount. 2. The compound of formula I is N-[[[4- [2-chloro-4- (trifluoromethyl) phenoxy] -2-fluorophenyl] amino] carbonyl] -2,6-difluorobenzamide. An insecticidal or acaricidal composition as described in 1. 3. Insecticidal or acaricidal composition according to claim 1 or 2, comprising a compound of formula I and a compound of formula II in a weight ratio of 100: 1 to 1: 100. 4. A method for preparing an insecticidal or acaricidal composition according to any one of claims 1 to 3, comprising the step of mixing a compound of formula I and a compound of formula II. Use of the insecticidal or acaricidal composition according to any one of claims 1 to 3 for controlling insects or ticks (except for human use) . A method for controlling insects or ticks, wherein the insects or ticks , their food sources, their habitats or their breeding grounds, or insects or ticks are growing or capable of growing A synergistically effective amount of a plant, seed, soil, area, substance or environment, or a substance, plant, seed, soil, surface or space to be protected from insect or mite attack or spread. A method comprising treating with a composition according to any one of (except for methods for treating humans) . A method for treating and / or protecting a plant against attack or spread of insects or ticks , wherein the plant or the soil or water on which the plant is growing is described in any one of claims 1 to 3. Contacting with a composition of:   8. The method of claim 7, wherein the plant is a crop plant selected from consequential plants, potatoes, rice, cereals, soybeans, dry beans, cotton, vegetables, coffee, sugarcane and horticultural plants.   The method according to any one of claims 6 to 8, wherein the composition comprising the compounds of formulas I and II is applied as a foliar application. A method of protecting plants which grow from the seeds and / or seed, said method comprising the seed is treated with a composition according to any one of claims 1 to 3.   The method according to any one of claims 6 to 10, wherein the composition according to any one of claims 1 to 3 is applied in an amount of 5 to 500 g per hectare for the individual compounds. Compounds I and II according to any one of claims 1 to 3 are applied simultaneously, i.e. together or separately, or sequentially (except for human application) . The method as described in any one of.