JP5893450B2 - Aluminum alloy brazing sheet for header of heat exchanger, method for producing the same, and method for producing heat exchanger - Google Patents

Description

  The present invention relates to a brazing sheet used for a header material, a method for manufacturing the brazing sheet, and a method for manufacturing the heat exchanger in a heat exchanger having a structure in which a plate bending tube is joined via a header material.

  Conventionally, brazing sheets in which an Al—Si alloy brazing material is clad on one or both sides of an Al—Mn alloy core have been used as members of an aluminum alloy heat exchanger. These brazing sheets are molded into a predetermined shape, such as tubes, fins, headers, etc., and the assembled ones are heated at about 600 ° C., so that the brazing material melts and flows to the joining portion, and the fillet is formed. Formed and brazed. Depending on the combination structure of the members and the shape of the brazed joint, a brazing sheet clad with brazing material on both sides or a brazing sheet clad with brazing material on one side is used. Bare materials and extruded materials that do not clad are also applicable.

  A structure called a parallel flow type has become the mainstream of heat exchangers for automobiles. A structure called a parallel flow type will be described with reference to FIGS. FIG. 9 is a schematic perspective view showing an assembly 60 in which the members of the heat exchanger having a parallel flow structure are assembled. FIG. 10 is a diagram of the tube material in FIG. In FIG. 9, in the heat exchanger assembly 60, the tube material 53 having a plurality of fine refrigerant flow paths and a flat outer shape and the fin material 55 subjected to corrugation are alternately laminated to form the tube material 53. Is connected to the header material 51, and the tank material 52 is disposed so as to face the header material 51. The refrigerant from the inlet side piping is distributed to each tube material 53, and from the tube material 53. These refrigerants are gathered and connected to the outlet side piping. Then, the assembly 60 is heated by brazing, whereby a parallel flow type heat exchanger is manufactured.

  Many conventional heat exchangers are made by brazing and joining a heat exchanger core consisting of tubes, fins, and a header, and then crimping and fixing a resin tank to the header. There are an increasing number of brazed joints with cores.

  Flat tubes are broadly classified into extruded tubes, and plate material formed tubes formed by bending, bending, deep drawing, press forming, and the like.

  Since the extruded tube is a multi-hole tube having a plurality of fine holes, a material with high productivity and good extrudability is desired. However, a material having good extrudability has a problem that it is difficult to increase the strength and it is difficult to reduce the thickness of the refrigerant flow path wall.

  Therefore, it is desired to apply a plate material forming tube that is high in strength and easy to reduce the plate thickness. The plate material forming tube is, for example, an aluminum alloy plate cut into strips, bent so that the outer shape becomes flat by roll forming, and both ends of the plate are joined together, and a refrigerant flow path is formed by deep drawing. Further, both ends of the two plate members are joined together, and both ends of the two plate members formed with the refrigerant flow path by press molding are joined together. The plate material forming tube includes a so-called B-type tube in which a part of the plate itself is bent and formed to form an inner pillar, and a so-called inner fin type in which wavy inner fins are inserted.

  In such a plate material forming tube, the end portions at both ends of the plate are joined together by brazing, or the end portions at both ends are roll-formed and bent inward into an L shape, and the outer surfaces are joined together. A seam is formed, for example, by brazing. For example, the tube 53 shown in FIG. 10 is formed with seams 54 at both ends of the plate. Therefore, in manufacturing a heat exchanger using such a tube material, during brazing heating, the amount of molten brazing that tends to flow toward the tube material through the joint of the tube material tends to flow toward the tube material. Since it decreases, a gap is likely to occur at the joint. Further, in the flat tube formed by bending the plate, there is a portion where the clearance of the bent end of the plate must be increased at the joint portion with the header, and it is easy to cause a brazing failure leading to refrigerant leakage. Therefore, brazing was difficult.

  Therefore, for example, Patent Document 1 (Japanese Patent Application Laid-Open No. 2011-224656) discloses a core material made of an Al—Mn alloy and an Al—Si system in which the Fe content is 0.45% by mass or less on one or both surfaces thereof. An aluminum alloy brazing sheet comprising a brazing material made of an alloy, and after brazing at 600 ° C. for 3 minutes, the area ratio of eutectic Si, which is a brazing flow passage in the cross-section of the solidified brazing, is 35% or less. There is disclosed a brazing sheet in which the crystal grain size in the center of the thickness direction of the core material is 80 μm or more in the rolling direction, and it is applied to the tube material and to both the tube material and the plate (header) material Has been shown to do.

JP 2011-224656 A (Claims)

  However, the joint of the plate-formed tube material is easy to form a large fillet because of its shape, and it is easy to cause a capillary phenomenon that sucks a lot of brazing material from other parts, so it is necessary at other joints. There was a problem that brazing was reduced and sufficient bonding strength could not be obtained, and that brazing was liable to occur.

  In particular, in heat exchangers with a structure in which plate-formed tube material and tank material are joined via a header material, the phenomenon that the brazing material of the tank material flows into the tube material through the inner surface of the header material Occurred, the fillet of the brazing part of the tank material and the header material became small, and the joining strength was insufficient.

  FIG. 11 is a schematic cross-sectional view showing a state in which a tube material, a header material, and a tank material are assembled and brazed and heated in manufacturing a conventional heat exchanger. In FIG. 11, one end of a plate material forming tube material 43 in which an aluminum alloy plate for a tube is formed is fitted to a header material 41 in which a brazing material 45 is clad on the inner side. The tank material 42 in which the brazing material 47 is clad on the inner surface and the brazing material 46 is clad on the outer surface is overlapped at the ends. These assemblies 50 are brazed and heated. During this brazing heating, the brazing material 46 and the brazing material 47 of the tank material 42 pass through the inner surface of the header material 41 as shown by the arrows in FIG. Flow into.

  Accordingly, an object of the present invention is to braze a tube material, a header material, and a tank material, which are formed of a plate material tube material, i.e., a plate material, and are formed so that both ends of the plate material are joined together. And a heat exchanger manufacturing method in which the brazing material of the tank material does not flow into the tube material through the surface of the header material, and aluminum for the header used in the heat exchanger manufacturing method. It is to provide an alloy brazing sheet.

  As a result of intensive studies to solve the above problems, the present inventors have (1) reducing or depleting the brazing material of the header material before the brazing material of the tank material flows, thereby The flow of the brazing material of the tank material from the steel material to the tube material can be interrupted, and (2) the brazing material of the header material is made higher than the fluidity of the brazing material of the tank material so that the brazing material of the tank material has a header. Before the brazing material on the surface of the material reaches the brazing material, the brazing material of the header material is caused to flow to the joining portion and the amount of brazing material remaining in the header material is reduced. It is possible to prevent the material from flowing into the tube material through the surface of the material, and (3) by regulating the crystal structure of the core material of the header material and the composition of the brazing material within a specific range, the above-described effects can be obtained. Providing header material that demonstrates Heading, it has led to the completion of the present invention.

That is, in the present invention (1), the brazing material is clad on at least one side of the core material,
The core material contains 0.8 to 2.0% by mass of Mn, 0.01 to 1.0% by mass of Si and 0.01 to 0.7% by mass of Fe, and the balance is made of Al and inevitable impurities. Is the heartwood
The brazing material contains 11.0 to 14.0% by mass of Si and 0.01 to 0.8% by mass of Fe, and the balance is made of Al and inevitable impurities,
The core has an average crystal grain size of 80 μm or more;
An aluminum alloy brazing sheet for a header of a heat exchanger is provided.

  In the present invention (2), the core material further contains any one or two of 0.04 to 1.0% by mass of Cu and 0.01 to 0.2% by mass of Ti. An aluminum alloy brazing sheet for a header of a heat exchanger according to the present invention (1) is provided.

  In addition, the present invention (3) is characterized in that the brazing material further contains 0.001% by mass or more and less than 0.20% by mass of Sr. An aluminum alloy brazing sheet for a header of a heat exchanger is provided.

Moreover, this invention (4) contains 0.8-2.0 mass% Mn, 0.01-1.0 mass% Si and 0.01-0.7 mass% Fe, with the balance being Heat that clads a brazing material containing 11.0 to 14.0% by mass of Si and 0.01 to 0.8% by mass of Fe, with the balance being Al and inevitable impurities, in the core material consisting of Al and inevitable impurities Hot rolling,
Next, intermediate annealing is performed to recrystallize at a temperature of 300 ° C. or higher,
Then, cold working with a working degree of 15-60% is performed,
Next, final annealing is performed by recrystallization at a temperature of 300 ° C. or higher, and the core material is recrystallized , and an O material having an average crystal grain size of 80 μm or more is obtained.
The manufacturing method of the brazing sheet made from the aluminum alloy for headers of the heat exchanger characterized by these is provided.

  In the invention (5), the core material further contains any one or two of 0.04 to 1.0 mass% of Cu and 0.01 to 0.2 mass% of Ti. The manufacturing method of the brazing sheet made from the aluminum alloy for headers of the heat exchanger of this invention (4) characterized by doing is provided.

  Further, the present invention (6) is characterized in that the brazing material further contains 0.001% by mass or more and less than 0.20% by mass of Sr. Manufacturing method of brazing sheet made of aluminum alloy for header of heat exchanger.

Moreover, this invention (7) contains 0.8-2.0 mass% Mn, 0.01-1.0 mass% Si, and 0.01-0.7 mass% Fe, with the balance being Heat that clads a brazing material containing 11.0 to 14.0% by mass of Si and 0.01 to 0.8% by mass of Fe, with the balance being Al and inevitable impurities, in the core material consisting of Al and inevitable impurities Hot rolling,
Next, pre-cold rolling is performed,
Next, intermediate annealing is performed to recrystallize at a temperature of 300 ° C. or higher,
Then, cold working with a working degree of 15-60% is performed,
Next, final annealing is performed by recrystallization at a temperature of 300 ° C. or higher, and the core material is recrystallized , and an O material having an average crystal grain size of 80 μm or more is obtained.
The manufacturing method of the brazing sheet made from the aluminum alloy for headers of the heat exchanger characterized by these is provided.

  In the invention (8), the core material further contains any one or two of 0.04 to 1.0 mass% of Cu and 0.01 to 0.2 mass% of Ti. The manufacturing method of the brazing sheet made from the aluminum alloy for headers of the heat exchanger of the present invention (7) is provided.

  Further, the present invention (9) is characterized in that the brazing material further contains 0.001% by mass or more and less than 0.20% by mass of Sr, either of the present invention (7) or (8) Manufacturing method of brazing sheet made of aluminum alloy for header of heat exchanger.

Further, the present invention (10) includes at least a tube material in which an aluminum alloy plate for a tube is formed into a flat tubular shape and ends of both ends of the aluminum alloy plate for a tube are joined together, and a brazing material on at least one side of the core material A brazing sheet made of aluminum alloy for a header with clad metal is molded into a brazing sheet made of aluminum alloy for a tank with brazing material clad on at least one side of the core material. A heat exchanger manufacturing method for obtaining a heat exchanger by brazing and heating after assembling the tank material,
The header material and the tank material are assembled so that the end of the inner surface or outer surface of the header material overlaps with the end of the inner surface or outer surface of the tank material,
The aluminum alloy brazing sheet for header is the aluminum alloy brazing sheet for header of the heat exchanger of the present invention (1),
The manufacturing method of the heat exchanger characterized by these is provided.

Further, the present invention (11) includes at least a tube material in which an aluminum alloy plate for a tube is formed into a flat tubular shape and ends of both ends of the aluminum alloy plate for a tube are joined together, and a brazing material on at least one side of the core material A brazing sheet made of aluminum alloy for a header with clad metal is molded into a brazing sheet made of aluminum alloy for a tank with brazing material clad on at least one side of the core material. A heat exchanger manufacturing method for obtaining a heat exchanger by brazing and heating after assembling the tank material,
The header material and the tank material are assembled so that the end of the inner surface or outer surface of the header material overlaps with the end of the inner surface or outer surface of the tank material,
The flow coefficient of the brazing material of the aluminum alloy brazing sheet for headers in a heating test at 600 ° C. for 3 minutes is higher than the flow coefficient of the brazing material of the aluminum alloy brazing sheets for tanks in a heating test at 600 ° C. for 3 minutes. And the average crystal grain size of the core material of the aluminum alloy brazing sheet for header is 80 μm or more ,
The manufacturing method of the heat exchanger characterized by these is provided.

Further, the present invention (12) includes at least a tube material in which an aluminum alloy plate for a tube is formed into a flat tubular shape and ends of both ends of the aluminum alloy plate for a tube are joined together, and a brazing material on at least one side of the core material A brazing sheet made of aluminum alloy for a header with clad metal is molded into a brazing sheet made of aluminum alloy for a tank with brazing material clad on at least one side of the core material. A heat exchanger manufacturing method for obtaining a heat exchanger by brazing and heating after assembling the tank material,
The header material and the tank material are assembled so that the end of the inner surface or outer surface of the header material overlaps with the end of the inner surface or outer surface of the tank material,
The thickness of the brazing material remaining on the surface of the core material in the heating test for 3 minutes at 600 ° C. of the aluminum alloy brazing sheet for header is the core material in the heating test for 3 minutes at 600 ° C. of the aluminum alloy brazing sheet for tank. rather smaller than the thickness of the brazing material remaining on the surface, and, the average crystal grain size in the core material of an aluminum alloy brazing sheet for the header is 80μm or more,
The manufacturing method of the heat exchanger characterized by these is provided.

  According to the present invention, in a method of manufacturing a heat exchanger for brazing a plate material forming tube material, a header material, and a tank material, the tank material does not flow into the tube material through the surface of the header material. The manufacturing method of a heat exchanger can be provided, and the brazing sheet made from the aluminum alloy for headers used for it can be provided.

It is a typical perspective view which shows the assembly body with which the tube material, the header material, and the tank material were assembled | attached. It is the figure which looked at the cross section of FIG. 1 from the side. It is a side view which shows arrangement | positioning of the test piece in a heating test (flow test of a brazing material). It is typical sectional drawing which shows the example of a form of a tube material. It is typical sectional drawing which shows the example of a form of a tube material. It is typical sectional drawing which shows the structural example of the assembly | attachment form of a header material and a tank material. It is typical sectional drawing which shows a mode that a brazing material flows in the case of brazing heating. It is sectional drawing which shows the mode of the test material after performing the flow test of a brazing material. It is a typical perspective view which shows the heat exchanger of a parallel flow type structure. It is a figure of the tube material in FIG. It is typical sectional drawing which shows a mode when a tube material, a header material, and a tank material are assembled | attached and the brazing heating is carried out in the manufacturing method of the conventional heat exchanger.

  With reference to FIG.1 and FIG.2, the brazing sheet made from the aluminum alloy for headers of the heat exchanger of this invention is demonstrated. FIG. 1 is a schematic perspective view showing an assembled body in which a tube material, a header material, and a tank material are assembled, in which a part of the assembled body is cut out, and the assembled body before brazing heating FIG. FIG. 2 is a side view of the cross section of FIG. In FIG. 2, the portion of the brazing material clad on the core material is indicated by a thick black line. Moreover, in FIG.1 and FIG.2, description other than a tube material, a header material, and a tank material was abbreviate | omitted.

  1 and 2, the assembly 20 includes a header material 1a, a tank material 2a, a tube material 3a, and an outer fin (not shown).

  The tube material 3a is a tube material obtained by bending an aluminum alloy plate for a tube into a flat tubular shape, and is bent so as to be joined at both ends of the plate. Therefore, in the tube material 3a, a seam 11a is formed at a portion where both ends of the plate are joined. The tube material 3a has a pipe end fitted to the header material 1a. And the clearance gap between the tube material 3a of a fitting part and the header material 2a is the junction part 10. FIG.

  The header material 1a is obtained by processing a brazing sheet made of an aluminum alloy for a header in which a brazing material 13 is clad so that the brazing material 13 is on the inside. Pipe ends of a plurality of tube materials 3a are fitted to the header material 1a. In FIG. 1, only a part of the assembled body 20 is shown, and therefore, only one tube material is shown in the figure. However, the entire assembled body 20 includes a plurality of tube materials 3 a. 1 are assembled in parallel in the left-right direction.

  The tank material 2a is obtained by processing a brazing sheet made of an aluminum alloy for tanks in which a brazing material 12 is clad on one surface of a core material and a brazing material 14 is clad on the other surface. The tank material 2a is assembled to the header material 1a so that the end of the tank material 2a on the joining side with the header material 1a overlaps with the end of the header material 1a on the joining side with the tank material 2a. The overlapping portions of the end portions of the tank material 2a and the header material 1a at this time are the joint portions 15a and 15b.

  Although not shown, in the assembly 20, corrugated outer fins are assembled between adjacent tube members. In addition to the above members, various members are assembled to the assembly 20 as necessary.

  At this time, in the assembly 20, the brazing material 12 of the tank material 2 a faces the brazing material 13 of the header material 1 a.

  The assembly 20 is heated by brazing at a predetermined temperature and time, so that the brazing material 13 of the header material 1a, the brazing material 12 and the brazing material 14 of the tank material 2a are joined together by the joint 11a, the joint portion 10, and the joint portion. It flows to 15a, 15b and other joints to form fillets and these parts are brazed to provide a heat exchanger.

  The aluminum alloy brazing sheet for headers of the heat exchanger of the present invention is an aluminum alloy brazing sheet for headers used in the manufacture of such a heat exchanger.

The brazing sheet made of aluminum alloy for header of the heat exchanger of the present invention has a brazing material clad on at least one side of the core material,
The core material contains 0.8 to 2.0% by mass of Mn, 0.01 to 1.0% by mass of Si and 0.01 to 0.7% by mass of Fe, and the balance is made of Al and inevitable impurities. Is the heartwood
The brazing material contains 11.0 to 14.0% by mass of Si and 0.01 to 0.8% by mass of Fe, and the balance is made of Al and inevitable impurities,
The core has an average crystal grain size of 80 μm or more;
A brazing sheet made of an aluminum alloy for a header of a heat exchanger.

  The brazing sheet made of aluminum alloy for header of the heat exchanger of the present invention is a brazing sheet in which the brazing material A is clad on at least one side of the core material A, that is, on one side or both sides of the core material A.

<Brazing material>
The brazing material A is a brazing material containing 11.0 to 14.0% by mass of Si and 0.01 to 0.8% by mass of Fe, with the balance being Al and inevitable impurities.

  The content of Si in the brazing material A is 11.0 to 14.0% by mass, preferably 11.5 to 13.5% by mass. The Si content in the brazing material affects the fluidity of the brazing material, and the fluidity increases as the Al-Si eutectic composition (Al-12.5 mass% Si) is closer. When the content of Si in the brazing material A is in the above range, the brazing material of the tank material can be prevented from flowing into the tube material through the surface of the header material. On the other hand, if the content of Si in the brazing material A is less than the above range, the fluidity becomes insufficient, and the amount of brazing material remaining on the surface of the core material increases. A melting erosion phenomenon occurs, causing a decrease in strength and corrosion resistance.

  The Fe content in the brazing material A is 0.01 to 0.8 mass%. Fe in the brazing material A serves as a starting point for nucleation during the solidification of the brazing and stabilizes fillet formation, so the Fe content is preferably 0.01% by mass or more. Moreover, since the elongation of a brazing material will become low too much when it exceeds the said range, manufacture of a brazing sheet will become difficult.

The brazing material A can further contain 0.001% by mass or more and less than 0.20% by mass of Sr. Since the Si content in the brazing material A is close to the eutectic composition (Al-12.7 mass% Si), coarse Si grains are easily formed. When coarse Si grains are present, the solder fluidity tends to be low. Therefore, in order to refine the Si grains in the brazing material and increase the fluidity of the brazing material, Sr can be contained in the brazing material. . Therefore, since the brazing material A contains Sr in the above range, the fluidity of the brazing material can be further increased, so that the brazing material of the tank material is prevented from flowing into the tube material through the surface of the header material. The effect is further increased. The effect due to the refinement of the Si grains in the brazing material is particularly remarkable when the number of coarse Si grains having an equivalent circle diameter of 5 μm or more existing in the brazing material is less than 100 per 1 mm ² . However, even if 0.20% by mass or more of Sr is added to the brazing material, the above effect is saturated.

<Heart material>
The core material A contains 0.8 to 2.0% by mass of Mn, 0.01 to 1.0% by mass of Si and 0.01 to 0.7% by mass of Fe, and the balance is made of Al and inevitable impurities. It is a heartwood.

  As the core material A, for example, an Al—Mn alloy represented by A3003 that has been put into practical use or a stronger Al—Mn—Cu alloy is used, but the core material A is not limited thereto.

The Mn content in the core material A is 0.8 to 2.0% by mass . Mn in the core material has an effect of increasing the strength. If the Mn content in the core material A is less than the above range, the tensile strength becomes 100 MPa or less, and the pressure resistance is insufficient except at the joint, and if it exceeds the above range, a coarse intermetallic compound is formed during casting. Therefore, it is difficult to manufacture a normal plate material.

  Content of Fe in the core material A is 0.01-0.7 mass%, Preferably it exceeds 0.35 mass% and is 0.7 mass% or less. If the Fe content in the core material A is less than the above range, recrystallization may not be stable and coarse crystal grains may be generated. If the content exceeds the above range, the average crystal grain size of the core material becomes too small.

  The content of Si in the core material A is 0.01 to 1.0% by mass. When the content of Si in the core material A is less than the above range, the brazing material Si easily diffuses into the core material, so that the fluidity of the brazing material becomes low. When the content exceeds the above range, the average crystal of the core material The particle size becomes too small.

  The average grain size of the core material A is 80 μm or more, preferably 80 to 200 μm. At the time of brazing, Si in the brazing is likely to penetrate into the crystal grain boundaries of the core material when the brazing is molten. When Si in the wax penetrates into the crystal grain boundary of the core material, the Si content is lowered and the fluidity is lowered. In particular, the decrease in fluidity due to diffusion of Si in the brazing material is significant when the average grain size of the core material is less than 80 μm. Therefore, in the present invention, by setting the average grain size of the core material A to 80 μm or more, the tank material can be suppressed by suppressing the diffusion of Si from the brazing material to the core material at the time of brazing and suppressing the decrease in the fluidity of the brazing material. It is possible to prevent the brazing material from flowing into the tube material through the surface of the header material. If the average crystal grain size of the core exceeds 200 μm, the grain boundary and the intra-granular deformation are slightly different when molding into a header shape. Therefore, the average crystal grain size of the core material is preferably 200 μm or less.

  The core material A can further contain 0.04 to 1.0% by mass of Cu.

  The core material A can further contain 0.01 to 0.2% by mass of Ti. When the core material contains Ti, a Ti concentration distribution is formed in the crystal grains generated during casting, and the potential distribution becomes layered by rolling to form a layered shape, and the corrosion form tends to be layered. As a result, the corrosion resistance is improved. If the Ti content in the core material A is less than the above range, it is difficult to form a concentration distribution, and if it exceeds the above range, a coarse compound is formed, so that it is difficult to produce a normal plate material.

  In the brazing sheet made of aluminum alloy for header of the heat exchanger of the present invention, the brazing material A has a high fluidity at the time of brazing. Therefore, in the heating test at 600 ° C. for 3 minutes, the brazing material A remaining on the surface of the core material The thickness is 10 μm or less, preferably 5 μm or less. And the brazing sheet made of aluminum alloy for header of the heat exchanger of the present invention has a thickness of brazing filler metal remaining on the surface of the core material after the test in a heating test at 600 ° C. for 3 minutes, preferably 5 μm or less. As a result, the flow path for the brazing material of the tank material to flow into the tube material can be blocked, so that the brazing material of the tank material can be prevented from flowing into the tube material through the surface of the header material. it can. Further, the smaller the thickness of the remaining brazing material in the heating test at 600 ° C. for 3 minutes, the higher the fluidity of the brazing material. In addition, the thickness of the brazing material made of the aluminum alloy brazing sheet for the header is usually about 50 to 200 μm, but even if the brazing material is different in thickness, if the brazing material has the same fluidity, it is 600. In the heating test at 3 ° C. for 3 minutes, the thickness of the brazing material remaining on the surface of the core material is also comparable.

In the present invention, the heating test at 600 ° C. for 3 minutes is a test shown below. First, as shown in FIG. 3, a brazing sheet test material (cladding material) 21 having a length of 30 mm, a width of 75 mm, and a thickness of 1.0 mm subjected to a heating test is placed on the brazing material 22 on the side where the fluidity is measured. Two aluminum alloy bare plates 23 (for example, 3003 material) having a height of 40 mm, a width of 50 mm, and a thickness of 1.0 mm, on which the brazing material is not clad, are spaced by 10 mm. (Spacing 24) is opened, and each is arranged perpendicular to the brazing sheet test material 21 so that the aluminum alloy bare plates 23 are parallel to each other. Next, after applying Nocolok flux to the brazing sheet test material 21 so as to be 5 g / m ² , the brazing sheet test material 21 is heated in a nitrogen gas atmosphere at 600 ° C. for 3 minutes. Next, after cooling, the vertical cross section of the middle vicinity 25 of the installation position of the two aluminum alloy bare plates 23 is observed, and the thickness of the remaining brazing material 22 is measured. In addition, FIG. 3 is a side view which shows arrangement | positioning of the test piece in a heating test (flow test of a brazing material).

  In the present invention, the thickness of the clad brazing material A varies depending on the clad rate, product plate thickness, etc., but the effect of blocking the flow path of the brazing material of the tank material is the clad brazing material A. This is not affected by the thickness of the brazing material A before brazing heating, but by the thickness of the remaining brazing material A due to brazing heating.

  In the aluminum alloy brazing sheet for headers of the heat exchanger of the present invention, the flow coefficient of the brazing material A in a heating test at 600 ° C. for 3 minutes is preferably 0.8 or more, particularly preferably 0.9 or more. Since the flow coefficient of the brazing material A is in the above range, the brazing material of the header material can be reduced or depleted before the brazing material of the tank material flows to the surface of the header material. The flow path of the brazing material to the tube material can be blocked, and the brazing material of the tank material can be prevented from flowing into the tube material through the surface of the header material. The flow coefficient of the brazing material A is adjusted by appropriately selecting, for example, the composition of the brazing material A, the average crystal grain size of the core material, the Si content of the core material, and the like. The flow coefficient of the brazing material is measured by a drop type fluidity test described in the aluminum brazing handbook.

The aluminum alloy brazing sheet for headers of the heat exchanger of the present invention is only required that the brazing material A having the above composition is clad on at least one side of the core material A, for example,
(Ia) a two-layer material in which the brazing material A is clad only on one surface of the core material A, and nothing is clad on the other surface;
(Ii-a) a three-layer material in which the brazing material A is clad on both surfaces of the core material A;
(Iii-a) A three-layer material in which a brazing material A is clad on one surface of the core material A and a brazing material X different from the core material A is clad on the other surface;
(Iv-a) a three-layer material in which the brazing material A is clad on one surface of the core material A and the sacrificial anode material is clad on the other surface;
Is mentioned.

  In the case of the three-layer material (ii-a), both surfaces of the core material may be clad with the brazing material A having the same composition, or with the brazing material A having a different composition. Good.

  In the case of the three-layer material (iii-a), examples of the brazing material X include an aluminum alloy brazing material (Al-Si brazing material) containing Si. When the brazing material X is an Al—Si based brazing material, the content of Si in the brazing material X is preferably 7.5 to 13 mass%, particularly preferably 10 to 12 mass%. Further, when the brazing material X is an Al—Si based brazing material, the brazing material X can contain Sr in addition to Si, and the content of Sr is preferably 0.01 to 0.20 mass%. Especially preferably, it is 0.01-0.05 mass%. In addition to the Al—Si brazing material, examples of the brazing material X include an Al—Si—Zn brazing material. The composition of the Al—Si—Zn brazing material has a Si content of 1. It is 0-6.0 mass, and Zn content is 0.5-4.0 mass%.

  Further, in the case of the three-layer material (iv-a), the outer surface corrosion resistance is improved by processing the sacrificial anode material so as to be outside the heat exchanger and manufacturing the heat exchanger. Examples of the sacrificial anode material include an aluminum alloy that is lower in potential than the core material, such as a 1000 series aluminum alloy or an Al—Zn series alloy.

  The aluminum alloy brazing sheet for header of the heat exchanger of the present invention is an aluminum alloy brazing sheet for producing a header material. Usually, the header material is produced by drawing an aluminum alloy brazing sheet. Therefore, the aluminum alloy brazing sheet for headers of the heat exchanger of the present invention is an O material. The O material is an aluminum alloy material that is obtained by performing final annealing to be recrystallized at a temperature of 300 ° C. or higher, and the core material is recrystallized.

  The thickness of the core material A is preferably 0.5 to 2.0 mm, particularly preferably 0.5 to 1.2 mm. The thickness of the brazing material A is preferably 0.05 to 0.2 mm, particularly preferably 0.05 to 0.12 mm.

  The production process of the aluminum alloy brazing sheet for header of the heat exchanger of the present invention is not particularly limited, but it is preferably produced by the method for producing the aluminum alloy brazing sheet for header of the heat exchanger of the present invention shown below. Is done.

The manufacturing method of the aluminum alloy brazing sheet for headers of the heat exchanger of the first embodiment of the present invention (hereinafter also referred to as manufacturing method (1) of the aluminum alloy brazing sheet for headers of heat exchangers) is 0. .8 to 2.0% by mass of Mn, 0.01 to 1.0% by mass of Si and 0.01 to 0.7% by mass of Fe, with the balance being Al and inevitable impurities, Hot rolling is performed to clad a brazing material containing 1.0 to 14.0% by mass of Si and 0.01 to 0.8% by mass of Fe, with the balance being Al and inevitable impurities,
Next, intermediate annealing is performed to recrystallize at a temperature of 300 ° C. or higher,
Then, cold working with a working degree of 15-60% is performed,
Next, performing final annealing to recrystallize at a temperature of 300 ° C. or higher to obtain O material in which the core material is recrystallized,
It is a manufacturing method of the brazing sheet made from the aluminum alloy for headers of the heat exchanger characterized by these.

Moreover, the manufacturing method of the aluminum alloy brazing sheet for headers of the heat exchanger of the second embodiment of the present invention (hereinafter also referred to as the manufacturing method (2) of the aluminum alloy brazing sheet for headers of the heat exchanger) is provided. A core material containing 0.8 to 2.0% by mass of Mn, 0.01 to 1.0% by mass of Si and 0.01 to 0.7% by mass of Fe, with the balance being Al and inevitable impurities. 11.0-14.0% by mass of Si and 0.01-0.8% by mass of Fe, with the remainder being hot rolled to clad a brazing material consisting of Al and inevitable impurities,
Next, pre-cold rolling is performed,
Next, intermediate annealing is performed to recrystallize at a temperature of 300 ° C. or higher,
Then, cold working with a working degree of 15-60% is performed,
Next, performing final annealing to recrystallize at a temperature of 300 ° C. or higher to obtain O material in which the core material is recrystallized,
It is a manufacturing method of the brazing sheet made from the aluminum alloy for headers of the heat exchanger characterized by these.

  That is, the manufacturing method (1) of the aluminum alloy brazing sheet for headers of the heat exchanger and the manufacturing method (2) of the aluminum alloy brazing sheet for headers of the heat exchanger are pre-cold working before intermediate annealing. It is the same except that whether or not to perform is different.

  In the hot rolling process according to the manufacturing methods (1) and (2) of the aluminum alloy brazing sheet for header of the heat exchanger, the core material is clad with the brazing material, but the composition of the core material related to the hot rolling process is The composition of the core material A related to the brazing sheet made of aluminum alloy for header of the heat exchanger of the invention is the same as the composition of the brazing material related to hot rolling. The brazing sheet made of aluminum alloy for header of the heat exchanger of the invention This is the same as the composition of the brazing filler metal A.

  In the hot rolling process, in the case of a two-layer material, the ingot having the composition of the core material A is combined with the ingot having the composition of the brazing material A, and in the case of the three-layer material, the core material A A combination of the ingot having the composition with the ingot having the composition of the brazing material A and the ingot having the composition of the material clad together with the brazing material A is hot-rolled to obtain a hot-rolled material. The hot rolling temperature is 400 to 550 ° C.

  In the manufacturing method (2) of the aluminum alloy brazing sheet for headers of the heat exchanger, pre-cold processing is then performed to cold-process the hot-rolled material to obtain the pre-cold-processed material. The processing conditions in the pre-cold processing are appropriately selected.

  The intermediate annealing according to the manufacturing methods (1) and (2) of the aluminum alloy brazing sheet for header of the heat exchanger is annealing performed before the cold working of the next process, and the aluminum for header of the heat exchanger In the case of the alloy brazing sheet manufacturing method (1), the hot-rolled material is heated at a temperature of 300 ° C. or higher and recrystallized to obtain an intermediate annealing material, and the header of the heat exchanger In the case of the production method (2) of the aluminum alloy brazing sheet, the pre-cold work material is heated at a temperature of 300 ° C. or higher and recrystallized to obtain an intermediate annealed material. The intermediate annealing temperature is 300 to 450 ° C.

  The cold working according to the manufacturing methods (1) and (2) of the aluminum alloy brazing sheet for headers of heat exchangers is performed by cold-working the intermediate annealed material at a working degree of 15 to 60%. It is a process to obtain. If the degree of cold work is less than 15%, it will not be completely softened, and sub-crystal grains will remain in the material, which will likely cause brazing defects due to erosion. If it exceeds 60%, the average grain size will be fine. Therefore, in the final annealing, crystal grains having an average grain size of 80 μm or more cannot be obtained stably.

  In the final annealing according to the manufacturing methods (1) and (2) of the aluminum alloy brazing sheet for headers of the heat exchanger, the cold-worked material is heated at a temperature of 300 ° C. or higher and recrystallized to regenerate the core material. This is a process for obtaining a crystallized O material. The final annealing temperature is 300 to 450 ° C.

  In the method for producing an aluminum alloy brazing sheet for a header of a heat exchanger according to the present invention, the composition of the ingot used for hot rolling is changed to a core material according to the aluminum alloy brazing sheet for a header of the heat exchanger according to the present invention, and For the header of the heat exchanger according to the present invention, the core material is recrystallized by final annealing at a temperature of 300 ° C. or higher after having been cold worked at a workability of 15 to 60% with a brazing material composition. An aluminum alloy brazing sheet can be obtained.

The method for producing a heat exchanger according to the present invention includes at least a tube material formed so that an aluminum alloy plate for a tube is formed into a flat tubular shape and ends of both ends of the aluminum alloy plate for a tube are joined, and at least one surface of a core material. A brazing sheet made of an aluminum alloy for a header, clad with a brazing material, and a brazing sheet made of an aluminum alloy for a tank, wherein the brazing material is clad on at least one side of a core material, and a brazing sheet formed with the brazing material side inside A heat exchanger manufacturing method for obtaining a heat exchanger by brazing and heating after assembling a tank material molded with
The header material and the tank material are assembled so that the end of the inner surface or outer surface of the header material overlaps with the end of the inner surface or outer surface of the tank material,
The brazing sheet made of aluminum alloy for header is the brazing sheet made of aluminum alloy for header of the heat exchanger of the present invention,
This is a method for manufacturing a heat exchanger.

  In the method for manufacturing a heat exchanger according to the present invention, first, at least a tube material, a header material, and a tank material are assembled to produce an assembly. In addition to the tube material, the header material, and the tank material, an outer fin and other members as necessary are assembled to the assembly.

  The tube material according to the manufacturing method of the heat exchanger of the present invention is a tube material in which an aluminum alloy plate for a tube is formed into a flat tubular shape, and is formed so that end portions at both ends of the plate are joined together. Tube material. Therefore, a seam, which is a portion where both ends of the plate are joined together by brazing, is formed in the tube material. The method for forming a tube material by forming an aluminum alloy plate for a tube is not particularly limited, and examples thereof include a method for bending and forming a tube aluminum alloy plate, a method for deep drawing, a method for press forming, and the like. .

  FIG.4 and FIG.5 is typical sectional drawing which shows the form example of a tube material, and is sectional drawing when a tube material is cut in a surface perpendicular | vertical with respect to a refrigerant flow path. The tube material 3a shown in FIGS. 1 and 2 is formed so that the outer surface side of one end and the inner surface side of the other end of the aluminum alloy plate 27a for the tube overlap as shown in FIG. However, the tube material which concerns on the manufacturing method of the heat exchanger of this invention is not limited to this. As the tube material, for example, as shown in FIG. 4B, both ends of the tube aluminum alloy plate 27b are bent outward in an L shape, and the inner surface side of one end of the plate overlaps the inner surface side of the other end. Thus, as shown in FIG. 4C, both ends of the tube material 3b and the tube aluminum alloy plate 27c are bent in an L shape toward the inside, and the outer surface side and the other end of one end of the plate The tube material 3c etc. which were shape | molded so that the outer surface side may overlap is mentioned. Moreover, the formation positions of the joints 11a, 11b, and 11c are appropriately selected.

  Moreover, you may have the inner fin 28 in the pipe | tube of a tube material like the tube material 3d shown in FIG. In the tube material 3d, the end portions of the inner fins 28 are brazed together with both end portions of the tube aluminum alloy plate 27d at the joint 11d.

  The aluminum alloy plate for tubes may be an aluminum alloy plate (bare plate) in which the brazing material is not clad, or an aluminum alloy plate (brazing sheet) in which the brazing material is clad on one or both sides of the core material. It may also be an aluminum alloy plate clad with a sacrificial anode material. Whether to braze the brazing material or the sacrificial anode material on the aluminum alloy plate for the tube, whether to clad the brazing material or the sacrificial anode material on the inner surface side or the outer surface side of the tube material, and the like is appropriately selected. .

  The header material according to the manufacturing method of the heat exchanger of the present invention is an aluminum alloy brazing sheet for headers of the heat exchanger of the present invention, that is, an aluminum alloy for headers in which a brazing material A is clad on at least one side of a core material. The brazing sheet is a header material formed so that the brazing material A is on the inside, and pipe ends of a plurality of tube materials are fitted. In addition, although the brazing | wax material A is clad on the inner surface of the header material which concerns on the manufacturing method of the heat exchanger of this invention, although the brazing | wax material is not clad on the outer surface, the outer surface The brazing material A is clad, the brazing material X that is different from the brazing material A is clad on the outer surface, the sacrificial anode material is clad on the outer surface, and the like.

  The tank material according to the heat exchanger of the present invention is a tank material in which a brazing sheet made of aluminum alloy for tanks in which a brazing material is clad on at least one side of a core material is formed.

  The aluminum alloy brazing sheet for tanks is preferably an aluminum alloy brazing sheet in which the brazing material B is clad on at least one surface of the core material B shown below.

  Examples of the aluminum alloy brazing sheet for tanks include those having a thickness of 0.8 to 1.2 mm in which a 4045 alloy is clad on one or both sides of a 3003 alloy.

  The brazing material B is a brazing material containing 7.5% by mass or more and less than 11.0% by mass of Si, with the balance being Al and inevitable impurities.

  The content of Si in the brazing material B is 7.5% by mass or more and less than 11.5% by mass, preferably 9% by mass or more and less than 11% by mass. When the Si content in the brazing material B is less than the above range, it is difficult to form a sufficient fillet. When the Si content exceeds the above range and exceeds the Si content of the brazing material A, the tank material is formed at a low temperature. Since the brazing material flows, the brazing material of the tank material flows into the tube material through the surface of the header material.

  The brazing material B may further contain 0.01 to 0.20% by mass of Sr as necessary. The content of Sr in the brazing material B is 0.01 to 0.20% by mass, preferably 0.01 to 0.05% by mass. When the brazing material B contains Sr, the amount of brazing that can flow is increased, and the fillet can be increased. For this reason, in order to obtain more stable joining properties, it is preferable that the brazing material B contains Sr. However, the effect is saturated even if it exceeds 0.20 mass%.

  The brazing material B may further contain any one or more of Fe of 0.8% by mass or less, Mn of 1.0% by mass or less, and Zn of 5.0% by mass or less. .

  The core material B contains 0.8% by mass or more and less than 2.0% by mass of Mn, 0.01 to 1.0% by mass of Si and 0.01 to 0.7% by mass of Fe, with the balance being Al and An aluminum alloy composed of inevitable impurities.

  The content of Mn in the core material B is preferably 1.0 to 1.7% by mass. The content of Si in the core material B is preferably 0.15 to 0.5% by mass. The content of Fe in the core material B is preferably 0.35 to 0.7% by mass.

  The core material B can further contain one or two of 0.04 to 1.0% by mass of Cu and 0.01 to 0.20% by mass of Ti as necessary.

  The core material B may further contain 2.0% by mass or less of Zn.

  In the aluminum alloy brazing sheet for tanks, the thickness of the brazing material B remaining on the surface of the core material is preferably more than 10 μm, particularly more than 20 μm, in a heating test at 600 ° C. for 3 minutes. preferable. The brazing sheet made of an aluminum alloy for tanks has a thickness of brazing filler metal remaining on the surface of the core material after the test in a heating test at 600 ° C. for 3 minutes. Since it flows before the brazing material of the material, the flow path for the brazing material of the tank material to flow to the tube material is blocked, and the brazing material of the tank material is prevented from flowing into the tube material through the surface of the header material. be able to.

  In the aluminum alloy brazing sheet for tanks, the flow coefficient of the brazing material B is preferably less than 0.8, particularly preferably 0.6 or more and less than 0.8, when heated at 600 ° C. for 3 minutes. Since the flow coefficient of the brazing material B is in the above range, the brazing material of the header material can be reduced or depleted before the brazing material of the tank material flows to the surface of the header material. The flow path of the brazing material to the tube material can be blocked, and the brazing material of the tank material can be prevented from flowing into the tube material through the surface of the header material. The flow coefficient of the brazing material B is adjusted by appropriately selecting, for example, the composition of the brazing material B, the average crystal grain size of the core material, the Si content of the core material, the plate thickness, and the like.

As an aluminum alloy brazing sheet for tanks in which brazing material B having the above composition is clad on at least one surface of core material B, for example,
(Ib) a two-layer material in which the brazing material B is clad only on one surface of the core material B, and nothing is clad on the other surface;
(Ii-b) a three-layer material in which the brazing material B is clad on both surfaces of the core material B;
(Iii-b) a three-layer material in which the brazing material B is clad on one surface of the core material B and the sacrificial anode material is clad on the other surface;
Is mentioned.

  In the case of the three-layer material (ii-b) above, the both sides of the core material may be clad with the brazing material B having the same composition, or with the brazing material B having a different composition. Good.

  In the case of the three-layer material (iii-b), the outer surface corrosion resistance is improved by processing the sacrificial anode material to be outside the heat exchanger and manufacturing the heat exchanger. Examples of the sacrificial anode material include an aluminum alloy that is lower in potential than the core material, such as a 1000 series aluminum alloy or an Al—Zn series alloy.

  In the heat exchanger manufacturing method of the present invention, the tank material is assembled to the header material so that the end portion of the tank material on the joining side with the header material overlaps the end portion of the header material on the joining side with the tank material. It is done. The header material and the tank material are such that the end of the inner surface of the header material and the end of the inner surface of the tank material overlap, or the end of the inner surface of the header material and the end of the outer surface of the tank material are Overlap, or end of outer side of header material and end of inner side of tank material overlap, or end of outer side of header material and end of outer side of tank material overlap Can be assembled. As an assembly form of the header material and the tank material, for example, as shown in FIG. 6A, the end portion on the inner surface side of the header material 1a and the end portion on the outer surface side of the tank material 2a are overlapped. As shown in FIG. 6 (B), the end of the header material 1b and the end of the tank material 2b are bent into an L-shape, and the end on the inner surface side of the header material 1b and the tank material 2b. As shown in FIG. 6C, the outer surface side end portion of the header material 1c and the inner surface side end portion of the tank material 2c are overlapped. Assembling form etc. are mentioned. FIG. 6 is a schematic cross-sectional view showing an example of the form of assembling the header material and the tank material. In FIG. 6, descriptions other than the header material and the tank material are omitted.

  Moreover, in the manufacturing method of the heat exchanger of the present invention, the assembled body includes, in addition to the tube material, the header material, and the tank material, outer fins assembled between adjacent tube materials, and, if necessary, side plates, Piping materials, parts for mounting on the vehicle body, and the like are assembled.

  Next, in the heat exchanger manufacturing method of the present invention, at least a tube material, a header material, and a tank material are assembled by brazing and heating the assembly obtained by assembling at a predetermined temperature and time, Get a heat exchanger.

  In the method for producing a heat exchanger according to the present invention, the maximum reached temperature of brazing heating is 590 to 610 ° C., and the brazing heating time is a holding time at the maximum reached temperature of 5 minutes or less. The atmosphere during brazing heating is an inert gas atmosphere such as a nitrogen gas atmosphere, a helium gas atmosphere, or an argon gas atmosphere, or an inert atmosphere such as a hydrogen gas atmosphere.

  The flow of the brazing material of the header material and the tank material in the manufacturing method of the heat exchanger of the present invention will be described with reference to FIG. FIG. 7 is a schematic cross-sectional view showing how the brazing material flows during brazing heating. FIG. 7A shows the state before the brazing material of the header material flows, and FIG. The state after the material flows is shown. Since the brazing material 13 of the header material has higher fluidity than the brazing material 12 and the brazing material 14 of the tank material, when the brazing heating of the assembly 20 is started, the brazing material 13 of the header material starts to flow first ( (A) in FIG. At this time, the brazing filler metal 12 and the brazing filler metal 14 are not yet flowing. The brazing material 13 of the header material that has started to flow flows to the joint portion 11 of the tube material 3a and the joint portion of the tube material 3a and the header material 1a to form a fret ((B) in FIG. 7). After the brazing filler metal 13 of the header material flows, the brazing filler metal 12 and the brazing filler metal 14 of the tank material begin to flow, but after the brazing filler metal 13 of the header material flows, the tube material 3a and the tank material 2a Since the brazing material 13 remaining on the surface of the header material 1a between them (the portion surrounded by the dotted line indicated by reference numeral 26) is very little or exhausted ((B) in FIG. 7), the tank material The phenomenon that the brazing material 12 and the brazing material 14 flow into the tube material 1a through the surface of the header material 2a does not occur. Therefore, the brazing material 12 and the brazing material 14 of the tank material flow to the part that is originally necessary for joining to form a fillet, and therefore the tank material is reduced by the decrease in the brazing material 12 and the brazing material 14 of the tank material. It is possible to prevent a bonding failure from occurring at the bonding portion 2a.

  Thus, in the method for manufacturing a heat exchanger according to the present invention, the flowability of the brazing material of the header material is made higher than the flowability of the brazing material of the tank material, so that the header is first subjected to the brazing heating. It is possible to reduce or deplete the brazing material remaining on the surface of the header material before the brazing material of the material flows, so that the brazing material of the tank material flows to the surface of the header material. The flow path of the material to the tube material can be blocked. When the brazing material is clad only on one side of the tank material, the fluidity of the brazing material of the header material is made higher than the fluidity of the brazing material clad only on one side of the tank material. Further, when the brazing material is clad on both sides of the tank material, the fluidity of the brazing material of the header material is made higher than the fluidity of any brazing material clad on both sides of the tank material.

That is, the manufacturing method of the heat exchanger of the present invention includes at least a tube material formed such that the aluminum alloy plate for a tube has a flat tubular shape and ends of both ends of the aluminum alloy plate for a tube are joined, and at least a core material. Made of aluminum alloy brazing sheet for header with clad brazing material on one side, made of aluminum alloy for tank with brazing material clad on at least one side of core material, header material molded with brazing material side inside A heat exchanger manufacturing method for obtaining a heat exchanger by brazing and heating after assembling a tank material formed with a brazing sheet,
The header material and the tank material are assembled so that the end of the inner surface or outer surface of the header material overlaps with the end of the inner surface or outer surface of the tank material,
The flow coefficient of the brazing material of the aluminum alloy brazing sheet for headers in a heating test at 600 ° C. for 3 minutes is higher than the flow coefficient of the brazing material of the brazing sheet for aluminum tanks in a heating test at 600 ° C. for 3 minutes. Preferably, the flow coefficient of the brazing material of the aluminum alloy brazing sheet for headers in a heating test at 600 ° C. for 3 minutes is the same as that in the heating test of the brazing material of the aluminum alloy brazing sheet for tanks at 600 ° C. for 3 minutes. It is higher than the flow coefficient by 0.05 or more, and particularly preferably, the flow coefficient of the brazing material of the aluminum alloy brazing sheet for headers in a heating test at 600 ° C. for 3 minutes is that of the brazing material of the aluminum alloy brazing sheet for tanks. Flow coefficient in a heating test at 600 ° C for 3 minutes 0.05 to 0.1 high that,
This is a method for manufacturing a heat exchanger. Preferably, the brazing material of the brazing sheet made of aluminum alloy for headers has a flow coefficient of 0.9 or more in a heating test at 600 ° C. for 3 minutes, and 600 of the brazing material of brazing sheets made of aluminum alloy for tanks. The flow coefficient in a heating test at 3 ° C. for 3 minutes is 0.6 or more and less than 0.8.

Further, the method for producing a heat exchanger of the present invention includes at least a tube material formed such that an aluminum alloy plate for a tube is formed into a flat tubular shape and ends of both ends of the aluminum alloy plate for a tube are joined together, and at least a core material. Made of aluminum alloy brazing sheet for header with clad brazing material on one side, made of aluminum alloy for tank with brazing material clad on at least one side of core material, header material molded with brazing material side inside A heat exchanger manufacturing method for obtaining a heat exchanger by brazing and heating after assembling a tank material formed with a brazing sheet,
The header material and the tank material are assembled so that the end of the inner surface or outer surface of the header material overlaps with the end of the inner surface or outer surface of the tank material,
The thickness of the brazing material remaining on the surface of the core material in the heating test for 3 minutes at 600 ° C. of the aluminum alloy brazing sheet for header is the core material in the heating test for 3 minutes at 600 ° C. of the aluminum alloy brazing sheet for tank. The thickness of the brazing material remaining on the surface of the core material in a heating test at 600 ° C. for 3 minutes of the brazing sheet made of the aluminum alloy for header is preferably smaller than the thickness of the brazing material remaining on the surface of the tank. 10 μm or more smaller than the thickness of the brazing filler metal remaining on the surface of the core material in the heating test of the alloy brazing sheet at 600 ° C. for 3 minutes,
This is a method for manufacturing a heat exchanger. Preferably, the brazing sheet made of aluminum alloy for the header has a thickness of 10 μm or less of the brazing material remaining on the surface of the core material in a heating test at 600 ° C. for 3 minutes, and the aluminum alloy brazing sheet for tanks The thickness of the brazing material remaining on the surface of the core material in the heating test at 600 ° C. for 3 minutes exceeds 10 μm, particularly preferably the core material in the heating test at 600 ° C. for 3 minutes of the brazing sheet made of aluminum alloy for header The thickness of the brazing material remaining on the surface of the brazing sheet is 5 μm or less, and the brazing sheet made of the aluminum alloy for tanks has a thickness of 10 μm remaining on the surface of the core material in a heating test at 600 ° C. for 3 minutes. More than 20 μm.

  Examples of the present invention will be described below in comparison with comparative examples. These examples show one embodiment of the present invention, and the present invention is not limited thereto.

(Example)
Ingots of the core material alloy shown in Table 1, the brazing material alloy shown in Table 2, and the sacrificial anode material alloy shown in Table 3 were manufactured by continuous casting, and the casting of the core material alloy and the sacrificial anode material alloy among the obtained ingots. The lump was homogenized according to a conventional method.
Next, the ingot of the sacrificial anode material and the brazing material alloy is hot-rolled to a predetermined thickness and cut to a predetermined size, and then these hot-rolled plates and the ingot of the core material alloy having a thickness of 30 mm are combined. As a material, it was hot-rolled to obtain a clad material having a two-layer or three-layer structure so that the brazing material clad rate was 10%. Thereafter, cold rolling is performed, intermediate annealing is performed in a batch furnace so that the maximum temperature reached 400 ° C., and then cold rolling is performed at a workability of 15 to 60% to obtain a plate thickness of 1.0 mm. Final annealing was performed in a batch furnace so that the ultimate temperature was 400 ° C. In Example 19, intermediate annealing was performed without performing cold rolling after hot rolling, and then 60% cold rolling was performed to obtain a plate thickness of 1.0 mm, followed by final annealing. In Example 20, final annealing was performed in a batch furnace so that the maximum temperature reached 300 ° C.

  Using the obtained clad material as a test material, the average grain size of the core material is measured by the following method, a heating test at 600 ° C. for 3 minutes, a flowability test of the brazing material (fillet forming ability, brazing thickness after brazing heating) Evaluation) and erosion properties were evaluated. The results are shown in Table 4.

(Measurement of average grain size)
The surface on the core side of the clad material is electropolished for 1 to 3 minutes at a voltage of 30 V in a mixed solution of 400 ml of phosphoric acid, 100 ml of sulfuric acid and 25 g of chromic anhydride, and further 500 ml of pure water, 27 ml of hydrofluoric acid, boric acid In the mixed solution of 11 g, electrolytic polishing was performed at a voltage of 25 to 30 V for 45 to 60 seconds. Thereafter, the polarization microstructure on the core material surface was photographed using an optical microscope, and the average crystal grain size was measured by a comparative method. For comparison, the standard crystal grain size organization chart of ASTM (E112-61) was used.
In addition, about the 3 layer clad material, the said process was performed in the state which removed the brazing | wax material by grind | polishing the surface, and exposed the core part, and measured the average grain size.

<Thickness of residual brazing material (heat test at 600 ° C. for 3 minutes)>
As shown in FIG. 3, a test clad material (brazing sheet test material) 21 having a length of 30 mm, a width of 75 mm, and a thickness of 1.0 mm subjected to a heating test, and a brazing material 22 on the side for measuring fluidity are arranged on the upper side. 2) 3003 material (bearing material) 23 having a height of 40 mm, a width of 50 mm, and a thickness of 1.0 mm, and a 10 mm interval (spacing 24) between them, and a test cladding material. And 3003 materials (bearing materials) were arranged in parallel to each other. Next, after applying the noclock flux to the test clad material 21 at 5 g / m ² , the temperature was raised to 600 ° C. at a temperature rising rate of 70 ° C./min in a nitrogen gas atmosphere, and at 600 ° C. for 3 minutes. After holding, the heater was turned off, and the temperature was lowered at 200 ° C./min after the wax solidified. Next, after cooling, the vertical cross section in the middle vicinity 25 of the installation position of the two aluminum alloy bare plates 23 was observed, and the thickness of the remaining brazing material 22 was measured.
In addition, the clad material 30 in which 4045 is clad on both surfaces of the 3003 core material used in the following brazing material fluidity test, the thickness of the brazing material remaining on the surface of the core material in the heating test at 600 ° C. for 3 minutes is It was 30 μm.

<Flow coefficient of brazing filler metal (heating test at 600 ° C. for 3 minutes)>
The drop type fluidity test described on page 130 of the aluminum brazing handbook published by the Japan Light Metal Welding Structure Association (revised version, published on March 25, 2003) was conducted. First, a test piece having a length of 60 mm, a width of 50 mm, and a thickness of 1.0 mm was prepared using the obtained clad material. Subsequently, it was suspended in the heating furnace so that the surface on the brazing filler metal surface side was vertical. Next, the test piece was heated to 600 ° C. at a temperature rising rate of 50 ° C./min in a nitrogen gas atmosphere and held at 600 ° C. for 3 minutes, then the heater was turned off and the brazing solidified to 200 ° C./min. The temperature was lowered. Next, after cooling, the test piece is cut at a position 3/4 from the top, and the flow is calculated from the weight of the test piece before the test and the weight of the lower quarter of the cut after the test based on the following calculation formula (1). The coefficient was calculated.
Flow coefficient (K) = (4W _B −W ₀ ) / (3W ₀ × Z) (1)
(Wherein, _{W 0} represents the weight (g) of the specimen before the test, _{W B} represents the cutting lower 1/4 of the weight after test (g), Z is "clad ratio (%) / 100 Is shown.)

<Flowability test of brazing filler metal by brazing heating>
(Evaluation of fillet forming ability)
As shown in FIG. 3, a test clad material (brazing sheet test material) 21 having a length of 30 mm, a width of 75 mm, and a width of 1.0 mm subjected to a heating test, and a brazing material 22 on the side for measuring fluidity are arranged on the upper side. A clad material (vertical plate 1) 30 (cladding rate 10%) in which 4045 is clad on both surfaces of a 3003 core material having a height of 40 mm, a width of 50 mm, and a thickness of 1.0 mm, A 3003 bare material (vertical plate 2) 29 having a height of 40 mm, a width of 50 mm, and a thickness of 1.0 mm is spaced apart by a distance of 10 mm (interval 24) and perpendicular to the test clad material 21 and 3003 The material (bare material) and the clad material 30 were arranged in parallel. Next, after applying the noclock flux to the test clad material 21 at 5 g / m ² , the temperature was raised to 600 ° C. at a temperature rising rate of 70 ° C./min in a nitrogen gas atmosphere, and at 600 ° C. for 3 minutes. After holding, the heater was turned off, and the temperature was lowered at 200 ° C./min after the wax solidified. Next, after cooling, cross-sectional observation was performed on the joint portion of the test piece. The fillet forming ability is measured by image analysis of the cross-sectional area of the fillet at the position surrounded by the dotted line 31 in FIG. 8, and the cross-sectional area of the fillet is 5 mm ² or more is good (◯), and the one less than that is bad (X).
In addition, each test piece used this time is one in which each member is arranged so as to correspond to a heat exchanger to which the present invention is applied. The clad material 30 is a tank material, the 3003 material (bearing material) 29 is a tube material, The test clad material 21 corresponds to a header material.

(Evaluation of brazing thickness after brazing heating)
The cross section of the position surrounded by the dotted line 32 in FIG. 8 (near the middle of the two vertical plates) is observed, and the brazing material thickness existing on the surface of the test clad material 21 is 10 μm or less. ) Those exceeding 10 μm were regarded as defective (x).

(Erosion evaluation)
Cross-section observation is performed at the position surrounded by the dotted line 32 in FIG. 8 (near the middle of the two vertical plates), and the penetration of wax into the core material is 3 or less per 100 μm. The thing exceeding a location was made into the defect (x).

(Comparative example)
The core material alloy having the composition shown in Table 1 and the brazing material alloy having the composition shown in Table 2 were ingoted by continuous casting, and the core material alloy was homogenized in accordance with a conventional method.
Subsequently, the ingot of the brazing material alloy is hot-rolled to a predetermined thickness, and the hot-rolled plate and the ingot of the core material alloy (thickness 30 mm) are hot-rolled together to form a brazing material cladding ratio. A clad material having a two-layer structure of 10% was obtained. Then, cold rolling is performed, intermediate annealing is performed in a batch furnace so that the maximum reached temperature is 400 ° C., cold rolling is performed at a work degree of 10 to 90%, and the plate thickness is set to 1.0 mm. The final annealing was performed in a batch furnace so as to be 400 ° C. In addition, No. No. 34 does not perform intermediate annealing. No. 35 is the highest temperature reached in intermediate annealing at 250 ° C. No. 36 performed the highest temperature of final annealing at 270 ° C.
Using the obtained clad material as a test material, the average crystal grain size of the core material is measured in the same manner as in the Examples, a heat test at 600 ° C. for 3 minutes, a fluidity test of the brazing material (fillet forming ability, brazing heating) Later evaluation of the brazing thickness) and evaluation of erosion were performed. The results are shown in Table 5.

As shown in Table 5, no. In Nos. 24 and 25, since the brazing filler metal Si content is too low, the thickness of the remaining brazing filler metal increases, and the brazing filler metal of the clad material 30 flows from the clad material 30 to the 3003 material (bearing material) 29. Was inferior.
No. No. 26 has a thin residual brazing material on the surface, but erosion has occurred because the brazing filler metal Si content is too high. As a result of the flow of the brazing material through the erosion site, the fillet forming ability is inferior. It was.
No. No. 27 had a high degree of cold work before final annealing, and the core crystal grain size was fine, so that erosion occurred, and the fillet forming ability was inferior due to the flow of the brazing material through the erosion site.
No. In No. 28, the Si content of the core material is too high, and the core crystal grain size is fine, so that erosion occurs, and the fillet forming ability is inferior due to the flow of the wax through the erosion site.
No. In No. 29, since the content of the core material Fe was too high, the core material crystal grain size was reduced, erosion occurred, and the fillet forming ability was inferior due to the flow of the brazing material through the erosion site.
No. Since No. 30 had a Mn content of the core material too low, the tensile strength was less than 100 MPa, and the strength was low for use as a header plate material for an aluminum alloy heat exchanger.
No. No. 31 was unable to obtain a normal plate because the Mn content of the core was too high.
No. In No. 32, the Fe content of the brazing material was too high, so that the amount of deformation of the brazing material was insufficient at the time of production, and a satisfactory clad material could not be obtained.
No. In No. 33, since the cold working degree before final annealing was too low, the processed structure remained in the core material, and erosion occurred at the site during brazing, which became a flow path for the brazing material, and the fillet forming ability was inferior.
No. Since No. 34 was not subjected to intermediate annealing, the degree of processing before final annealing was high, the core crystal grain size was small, erosion occurred, and the fillet forming ability was inferior due to the flow of the brazing material through the erosion site.
No. No. 35 was not sufficiently softened after the intermediate annealing because the temperature of the intermediate annealing was too low, and the substantial workability was higher than the workability before the final annealing because of the remaining work structure. , Erosion occurred, and the fillet forming ability was inferior due to the flow of the brazing material through the erosion site.
No. Since the final annealing temperature of 36 is too low, it is not an O material, and the processed structure remains in the core material, and erosion occurs in that portion during brazing, which becomes a flow path of the brazing material and has a poor fillet forming ability. It was.

1a, 1b Header material 2a, 2b Tank material 3a, 3b, 3c, 3d Tube material 10, 15a, 15b Joint 11a, 11b, 11c, 11d Seam 12, 14 Tank material brazing material 13 Header material brazing material 20 Assembly Body 21 Brazing sheet test material (test clad material)
22 Brazing material 23 Aluminum alloy bare plate 24 Interval 25 Middle vicinity 27a, 27b, 27c, 27d Aluminum alloy plate for tube 28 Inner fin 29 Vertical plate 2
30 Vertical plate 1
41, 51 Header material 42, 54 Tank material 43, 53 Tube material 44, 54 Seam 45, 46, 47 Brazing material 50, 60 Assembly 55 Fin material

Claims (24)

A brazing material is clad on at least one side of the core material,
The core material contains 0.8 to 2.0% by mass of Mn, 0.01 to 1.0% by mass of Si and 0.01 to 0.7% by mass of Fe, and the balance is made of Al and inevitable impurities. Is the heartwood
The brazing material contains 11.0 to 14.0% by mass of Si and 0.01 to 0.8% by mass of Fe, and the balance is made of Al and inevitable impurities,
The core has an average crystal grain size of 80 μm or more;
An aluminum alloy brazing sheet for headers of heat exchangers.   The brazing sheet made of an aluminum alloy for a header of a heat exchanger according to claim 1, wherein the brazing material remaining on the surface of the core material is 10 µm or less in a heating test at 600 ° C for 3 minutes. In the heating test for 3 minutes at 600 ° C., according to claim 1 or 2 SL placing aluminum alloy brazing sheet for the header of the heat exchanger, wherein the flow coefficient of the brazing material is 0.8 or more.   The core material further contains any one or two of 0.04 to 1.0 mass% Cu and 0.01 to 0.2 mass% Ti. A brazing sheet made of an aluminum alloy for a header of a heat exchanger according to any one of?   The brazing material made of aluminum alloy for a header of a heat exchanger according to any one of claims 1 to 4, wherein the brazing material further contains 0.001 mass% or more and less than 0.20 mass% Sr. Sheet.   The brazing sheet made of an aluminum alloy for a header of a heat exchanger according to any one of claims 1 to 5, wherein Fe content of the core material is more than 0.35 mass% and not more than 0.7 mass%. .   7. The brazing material is clad on one surface of the core material, and an Al-Si brazing material is clad on the other surface of the core material. An aluminum alloy brazing sheet for a header of a heat exchanger according to claim 1.   7. The brazing material is clad on one surface of the core material, and a sacrificial anode material is clad on the other surface of the core material. Aluminum alloy brazing sheet for headers of heat exchangers. A core material containing 0.8 to 2.0% by mass of Mn, 0.01 to 1.0% by mass of Si and 0.01 to 0.7% by mass of Fe, with the balance being Al and inevitable impurities, Containing 11.0 to 14.0% by mass of Si and 0.01 to 0.8% by mass of Fe, with the remainder being hot rolled to clad a brazing material consisting of Al and inevitable impurities,
Next, intermediate annealing is performed to recrystallize at a temperature of 300 ° C. or higher,
Then, cold working with a working degree of 15-60% is performed,
Next, final annealing is performed by recrystallization at a temperature of 300 ° C. or higher, and the core material is recrystallized , and an O material having an average crystal grain size of 80 μm or more is obtained.
A method for producing an aluminum alloy brazing sheet for a header of a heat exchanger. A core material containing 0.8 to 2.0% by mass of Mn, 0.01 to 1.0% by mass of Si and 0.01 to 0.7% by mass of Fe, with the balance being Al and inevitable impurities, Containing 11.0 to 14.0% by mass of Si and 0.01 to 0.8% by mass of Fe, with the remainder being hot rolled to clad a brazing material consisting of Al and inevitable impurities,
Next, pre-cold rolling is performed,
Next, intermediate annealing is performed to recrystallize at a temperature of 300 ° C. or higher,
Then, cold working with a working degree of 15-60% is performed,
Next, final annealing is performed by recrystallization at a temperature of 300 ° C. or higher, and the core material is recrystallized , and an O material having an average crystal grain size of 80 μm or more is obtained.
A method for producing an aluminum alloy brazing sheet for a header of a heat exchanger. The brazing sheet made of an aluminum alloy for header of the heat exchanger has a brazing filler metal thickness of 10 μm or less remaining on the surface of the core material in a heating test at 600 ° C. for 3 minutes. 0 Symbol manufacturing method of mounting header for aluminum alloy brazing sheet of the heat exchanger.   The aluminum alloy brazing sheet for header of the heat exchanger has a flow coefficient of 0.8 or more in the brazing material in a heating test at 600 ° C for 3 minutes. The manufacturing method of the brazing sheet made from the aluminum alloy for headers of the heat exchanger of description.   The core material further contains any one or two of 0.04 to 1.0 mass% Cu and 0.01 to 0.2 mass% Ti. The manufacturing method of the brazing sheet made from the aluminum alloy for headers of the heat exchanger of any one of -12.   The brazing material made of aluminum alloy for a header of a heat exchanger according to any one of claims 9 to 13, wherein the brazing material further contains 0.001 mass% or more and less than 0.20 mass% Sr. Sheet manufacturing method.   The brazing sheet made of aluminum alloy for a header of a heat exchanger according to any one of claims 9 to 14, wherein the core material has an Fe content of more than 0.35 mass% and not more than 0.7 mass%. Manufacturing method.   16. The brazing material is clad on one surface of the core material, and an Al—Si brazing material is clad on the other surface of the core material. The manufacturing method of the brazing sheet made from the aluminum alloy for headers of the heat exchanger of Claim 1. On one surface of the core, the brazing material are clad on the other surface of the core material, according to claim 9 to 15, wherein any one of the sacrificial anode material is characterized in that it is clad Of producing an aluminum alloy brazing sheet for a header of a heat exchanger of the present invention. At least a tube material in which a tube aluminum alloy plate is formed into a flat tubular shape and ends of both ends of the tube aluminum alloy plate are joined, and an aluminum alloy for a header in which a brazing material is clad on at least one side of a core material After assembling the header material formed with the brazing sheet made of the brazing material on the inner side and the tank material formed with the brazing sheet made of the aluminum alloy for tanks with the brazing material clad on at least one side of the core material A heat exchanger manufacturing method for obtaining a heat exchanger by brazing heating,
The header material and the tank material are assembled so that the end of the inner surface or outer surface of the header material overlaps with the end of the inner surface or outer surface of the tank material,
The aluminum alloy brazing sheet for a header is the aluminum alloy brazing sheet for a header of a heat exchanger according to any one of claims 1 to 8,
The manufacturing method of the heat exchanger characterized by these.   The aluminum alloy brazing sheet for tanks is an aluminum alloy brazing sheet in which the thickness of the brazing filler metal remaining on the surface of the core material exceeds 10 μm in a heating test at 600 ° C. for 3 minutes. The manufacturing method of the heat exchanger of description.   The method for manufacturing a heat exchanger according to claim 18, wherein the aluminum alloy brazing sheet for tanks has a brazing filler fluid coefficient of less than 0.8 in a heating test at 600 ° C for 3 minutes. The aluminum alloy brazing sheet for the tank has a brazing material clad on at least one side of the core material,
The core material contains 0.8 to 2.0% by mass of Mn, 0.01 to 1.0% by mass of Si and 0.01 to 0.7% by mass of Fe, and the balance is made of Al and inevitable impurities. Is the heartwood
The method for manufacturing a heat exchanger according to claim 18, wherein the brazing material contains less than 11.0% by mass of Si, and the balance is Al and inevitable impurities.   The method for manufacturing a heat exchanger according to claim 21, wherein the core material of the aluminum alloy brazing sheet for tanks further contains 0.04 to 1.0 mass% of Cu. At least a tube material in which a tube aluminum alloy plate is formed into a flat tubular shape and ends of both ends of the tube aluminum alloy plate are joined, and an aluminum alloy for a header in which a brazing material is clad on at least one side of a core material After assembling the header material formed with the brazing sheet made of the brazing material on the inner side and the tank material formed with the brazing sheet made of the aluminum alloy for tanks with the brazing material clad on at least one side of the core material A heat exchanger manufacturing method for obtaining a heat exchanger by brazing heating,
The header material and the tank material are assembled so that the end of the inner surface or outer surface of the header material overlaps with the end of the inner surface or outer surface of the tank material,
The flow coefficient of the brazing material of the aluminum alloy brazing sheet for headers in a heating test at 600 ° C. for 3 minutes is higher than the flow coefficient of the brazing material of the aluminum alloy brazing sheets for tanks in a heating test at 600 ° C. for 3 minutes. And the average crystal grain size of the core material of the aluminum alloy brazing sheet for header is 80 μm or more ,
The manufacturing method of the heat exchanger characterized by these. At least a tube material in which a tube aluminum alloy plate is formed into a flat tubular shape and ends of both ends of the tube aluminum alloy plate are joined, and an aluminum alloy for a header in which a brazing material is clad on at least one side of a core material After assembling the header material formed with the brazing sheet made of the brazing material on the inner side and the tank material formed with the brazing sheet made of the aluminum alloy for tanks with the brazing material clad on at least one side of the core material A heat exchanger manufacturing method for obtaining a heat exchanger by brazing heating,
The header material and the tank material are assembled so that the end of the inner surface or outer surface of the header material overlaps with the end of the inner surface or outer surface of the tank material,
The thickness of the brazing material remaining on the surface of the core material in the heating test for 3 minutes at 600 ° C. of the aluminum alloy brazing sheet for header is the core material in the heating test for 3 minutes at 600 ° C. of the aluminum alloy brazing sheet for tank. rather smaller than the thickness of the brazing material remaining on the surface, and, the average crystal grain size in the core material of an aluminum alloy brazing sheet for the header is 80μm or more,
The manufacturing method of the heat exchanger characterized by these.