JP5664457B2 - FUEL CELL SEPARATOR PLATE, FUEL CELL SEPARATOR, FUEL CELL, AND METHOD FOR PRODUCING FUEL CELL SEPARATOR PLATE - Google Patents

Description

  The present invention relates to a separator plate for a fuel cell, a separator for a fuel cell, a fuel cell, and a method for manufacturing a separator plate for a fuel cell.

  In a solid polymer electrolyte fuel cell, a membrane electrode assembly (MEA) is formed from an ion-permeable electrolyte membrane and an anode-side and cathode-side catalyst layer sandwiching the electrolyte membrane. . In addition, a gas diffusion layer (GDL: Gas Diffusion Layer) for supplying fuel gas or oxidizing gas to the membrane electrode assembly and collecting electricity generated by electrochemical reaction is sandwiched. Thus, an electrode body (MEGA) is formed. A solid polymer electrolyte fuel cell is constructed by arranging the electrode body so as to sandwich a separator having a linear or meandering gas flow path. The fuel cell comprises a stack in which the battery cell stack composed of the MEGA and the separator is fastened and integrated.

In addition, as the separator, there is also a so-called flat type separator in which a gas flow path is formed from a porous metal such as expanded metal and separated from the separator.
When the separator is made of a metal plate, a gas channel for allowing a reaction gas to pass is often formed by processing a channel groove (or protrusion) or the like at the center of the metal plate.

  The separator formed as described above has a thickness that is increased by pushing out the channel groove (or protrusion), while the peripheral portion of the channel groove remains a plate. For this reason, the thickness is adjusted by covering the peripheral portion with a frame-shaped sealing means having a thickness corresponding to the amount of the flow path groove. In this case, it is necessary to provide a passage for passing the gas from the manifold hole provided for introducing or discharging the reaction gas through the end of the separator.

  In patent document 1, the structure of the said channel | path and its manufacturing method are disclosed. The passage of Patent Document 1 will be described with reference to FIGS. 11 and 12. As shown in FIG. 11, the separator 100 made of a metal plate is formed with manifold holes 110, 120, and 130 for circulating a reaction gas (ie, fuel gas, oxidizing gas) and a refrigerant. A support base 104 serving as a support for the MEGA 140 (see FIG. 12) formed by raising the separator surface 100 a of the separator 100 is formed integrally with the peripheral edge of the manifold hole 110 as a part of the separator 100. Yes.

  The support 104 secures a vertical piece 101 rising vertically from the separator 100, a support piece 102 provided horizontally at the tip of the vertical piece 101, and a flow channel groove height between the flow channel 108 and the manifold hole 110. A protrusion 103 that contacts the separator surface 100a and serves as a support for the support base 104, and a plurality of flow holes 105 that serve as flow paths for fuel gas, oxidant gas, and refrigerant that flow between the flow path 108 and the manifold hole 110. Have. The passage hole 105 and the protrusion 103 of the support base 104 serve as a passage for passing gas from the manifold hole 110 to the flow path 108.

  As shown in FIG. 12, the support base 104 serves as a support for the electrode body (MEGA) 140. This prevents the electrode body 140 from being bent, improves the adhesion between the electrode body 140 and the separator 100 and the seal member 150, and improves the sealing performance of the seal member 150 between the MEGA 140 and the separator 100. .

JP 2006-221905 A

  However, in the case of Patent Document 1, the separator configured as described above cannot be manufactured by simply punching a metal plate. That is, it is necessary to provide a passage for passing gas from the manifold hole 110 to the flow path 108 in the separator 100 itself. Therefore, many steps are required to form a passage for passing gas through the separator. Specifically, the step of forming the protrusion 103 in the region where the manifold hole 110 is to be formed in the separator, the step of forming the flow hole 105 in the region where the manifold hole 110 is to be formed, and one side of the region where the manifold hole 110 is to be formed are left. A step of making a substantially U-shaped cut hole, a step of vertically raising a region where the manifold hole is to be formed, and a step where the tip side of the region where the manifold hole is to be formed is opposite to the manifold hole 110 A step of bending to be horizontal is required.

  Thus, conventionally, the support base can prevent the deflection of the electrode body (MEGA) and can improve the adhesion between the electrode body and the separator and the seal member, thereby improving the sealing performance. On the other hand, there are many processes for providing a passage for allowing gas to pass through the support base, and there is a problem that the cost is high because a complicated process is required.

  The object of the present invention is to improve the adhesion between the electrode body, the separator and the seal member by providing a structure for supporting the electrode body for preventing the deflection of the electrode body (MEGA) by solving the above-mentioned problems. For fuel cells, which can improve the sealing performance and can significantly reduce the process for providing a passage for passing gas to the structure supporting the electrode body compared to the conventional one, and can suppress the cost. It is providing a separator plate, a separator for fuel cells, and a fuel cell.

  Another object of the present invention is to increase the adhesion between the electrode body and the separator and the seal member, improve the sealing performance, and pass the gas through the structure supporting the electrode body. It is an object of the present invention to provide a method of manufacturing a separator plate for a fuel cell, which can significantly reduce the steps for providing the fuel cell and can reduce the cost.

In order to solve the above problems, a first aspect of the invention, a plurality of the flow path for flowing the reaction gas for use in a fuel cell, a reaction gas for circulating the reaction gas wherein the respective flow paths In a metal fuel cell separator plate having a supply manifold hole and a reaction gas discharge manifold hole , a flow path is formed between the manifold hole and the flow path. A bulge portion that is formed higher than the region and bulges and supports the electrode body 21 of the fuel cell is formed, and the side surface of the bulge portion on the flow path side communicates with the manifold hole and the flow path. The gist of the separator plate for a fuel cell is characterized in that a gas flow hole is formed.

  The separator plate for a fuel cell according to claim 1 supports the electrode body by a bulging portion formed higher than the flow path formation region between the manifold hole and the flow path, and prevents the deflection of the electrode body (MEGA). Figured. For this reason, the adhesion between the seal member disposed between the electrode body / separator and each of the electrode body and the separator is enhanced, and the sealing performance can be improved. In addition, the formation of the bulging portion can be easily performed by press molding, and the process for providing a passage for passing gas can be significantly reduced as compared with the conventional case.

The invention of claim 2 is characterized in that, in claim 1, the gas flow hole is formed by shearing when the bulging portion is bulged.
The gas flow holes of the separator plate for a fuel cell according to claim 2 are simply formed by shearing when the separator plate is bulged, and the processing of the separator plate is facilitated.

  According to a third aspect of the present invention, the flat plate portion according to the first or second aspect includes the flat plate portion, the manifold hole is formed in the flat plate portion, the flow path is formed, and the bulge portion is formed of the flat plate portion. It is characterized by bulging from the part.

According to the third aspect of the present invention, the operation of the first or second aspect can be easily realized in the separator plate for a fuel cell having the bulging portion formed by bulging from the flat plate portion.
According to a fourth aspect of the present invention, in the first or second aspect, a concave central portion and a frame portion surrounding the periphery of the central portion bulge out from the periphery of the central portion, and the central portion is The flow path forming region includes the flow path, the manifold hole is formed in the frame portion, a part of the frame portion adjacent to the manifold hole is the bulge portion, and the flow channel side of the bulge portion A gas flow hole communicating with the manifold hole and the flow path is formed on the side surface of the gas.

  According to a fourth aspect of the present invention, the operation of the first or second aspect can be easily realized in a fuel cell separator plate having a manifold hole in the frame portion and a part of the frame portion adjacent to the manifold hole being a bulging portion. To do.

  According to a fifth aspect of the present invention, the separator plate for a fuel cell according to any one of the first to fourth aspects is used as a first separator plate, and the first separator plate is provided with a frame-like sealing means via the frame-like sealing means. A separator for a fuel cell in which a second separator plate is laminated on the side opposite to the electrode body supported by the bulging portion, and the separator plate of either the first separator or the second separator plate includes The gist of the fuel cell separator is characterized in that a support means for supporting the bulging portion extends from the opposite side of the bulging portion to the electrode body to the other separator plate.

  The support means is formed so as to extend from one separator plate of the fuel cell separator to the other separator plate, thereby supporting the electrode body together with the bulging portion and preventing the electrode body (MEGA) from being bent. Figured. For this reason, the adhesion between the seal member disposed between the electrode body and the first separator plate and each of the electrode body and the first separator plate is enhanced, and the sealing performance can be improved. Further, the formation of the bulging portion of the first separator plate can be easily performed by press molding, and the process for providing a passage for passing gas can be greatly reduced as compared with the conventional case.

The invention of claim 6 is a pair of fuel cell separators according to claim 5 , wherein the electrode body is attached to the anode side surface and the cathode side surface of the electrode body via frame-like sealing means, respectively. The gist of the present invention is a fuel cell in which a plurality of fuel cells configured to be sandwiched are stacked.
According to the configuration of the invention of claim 6, a fuel cell capable of easily realizing the operation of claim 5 is obtained.

According the invention of claim 7 includes a plurality of flow path for flowing the reaction gas used in the fuel cell, the manifold hole and reactant gas discharge for the reaction gas supply to circulate the reaction gas to the flow paths A method of manufacturing a metal fuel cell separator plate having a manifold hole for a metal plate, and a bulging portion for supporting an electrode body of a fuel cell with respect to a region between the manifold hole and the flow path of the metal plate Swelled by press molding so that each channel is formed or higher than the channel forming region where the channel is formed, and at the time of the press molding, the side surface on the channel side of the bulging portion Further, the gist of the present invention is a method of manufacturing a separator plate for a fuel cell, wherein a gas flow hole communicating with the manifold hole and the flow path is formed.

  According to the configuration of the invention of claim 7, the bulging portion that supports the electrode body of the fuel cell is formed in the region between the manifold hole and the flow path of the metal plate, or each flow path is formed. The swollen portion is obtained simply by swollen by press molding so as to be higher than the flow path forming region in which is formed. And the gas distribution hole connected to a manifold hole and the said flow path is formed at the time of press molding of the bulging portion.

  According to the first aspect of the invention, by providing a structure for supporting the electrode body (MEGA) for preventing the deflection of the electrode body (MEGA), the adhesion between the electrode body and the separator and the seal member is improved, and the sealing performance is improved. Providing a separator plate for a fuel cell that can be improved and can significantly reduce the process for providing a gas passage for the structure that supports the electrode body as compared to the conventional method, thereby reducing costs. it can.

According to the second aspect of the present invention, since the gas flow hole may be simply formed by shearing at the time of the bulging process of the bulging portion, the processing of the separator plate can be facilitated.
According to the invention of claim 3, the effect of claim 1 or claim 2 can be easily realized in the separator plate for a fuel cell having the bulge portion bulged from the flat plate portion.

  According to the invention of claim 4, in the separator plate for a fuel cell, which has a manifold hole in the frame portion and a part of the frame portion adjacent to the manifold hole is a bulging portion, the effect of claim 1 or claim 2 Can be realized easily.

  According to invention of Claim 5, by providing the structure which supports the electrode body for the bending prevention of an electrode body (MEGA), the adhesiveness between an electrode body and a separator, and a sealing member is improved, and sealing performance is improved. A separator assembly for a fuel cell that can be improved and can significantly reduce the process for providing a passage for passing gas to the configuration that supports the electrode body compared to the conventional one, and can suppress the cost. It is to provide.

  According to invention of Claim 6, by providing the structure which supports the electrode body for bending prevention of an electrode body (MEGA), the adhesiveness between an electrode body and a separator, and a sealing member is improved, and sealing performance is improved. It is possible to provide a fuel cell that can be improved, and that a process for providing a passage for allowing gas to pass through the configuration that supports the electrode body can be significantly reduced as compared with the conventional case, and the cost can be suppressed.

  According to the seventh aspect of the present invention, it is possible to improve the adhesion between the electrode body and the separator plate and the seal member, to improve the sealing performance, and to pass the gas through the structure that supports the electrode body. The manufacturing method of the separator plate for fuel cells which can reduce significantly the process for providing this compared with the past, and can suppress cost can be provided.

BRIEF DESCRIPTION OF THE DRAWINGS Schematic of the whole structure of the fuel cell of 1st Embodiment. The principal part expansion disassembled perspective view of the separator assembly of 1st Embodiment. The principal part expanded sectional view of the separator assembly of 1st Embodiment. The principal part expanded sectional view of the separator assembly of 1st Embodiment. The principal part expansion disassembled perspective view of the separator assembly of 2nd Embodiment. The principal part expanded sectional view of the separator assembly of 2nd Embodiment. The principal part expansion disassembled perspective view of the separator assembly of 3rd Embodiment. The principal part expanded sectional view of the separator assembly of 3rd Embodiment. The principal part expansion perspective view of the separator of 4th Embodiment. The principal part expansion perspective view of the separator of 4th Embodiment. The principal part expansion perspective view of the separator of a prior art example. The principal part expansion disassembled perspective view of the separator of a prior art example.

(First embodiment)
A fuel cell according to a first embodiment that embodies a fuel cell, a fuel cell separator, and a fuel cell separator assembly according to the present invention will be described below with reference to FIGS.

In this embodiment, the anode plate 34 constituting the separator 30 is provided with a bulging portion, and the cathode plate 35 is provided with support means.
A fuel cell 10 of the present embodiment shown in FIG. 1 is supplied with a fuel gas containing hydrogen and an oxidizing gas containing oxygen, and referred to as a fuel gas and an oxidizing gas (hereinafter collectively referred to as a reactive gas as necessary). ) And a polymer electrolyte fuel cell that generates electric power through an electrochemical reaction.

  As shown in FIG. 1, the fuel cell 10 includes a plurality of stacked fuel cells 20 and is sandwiched between a pair of end plates 80A and 80B (not shown) from both ends thereof. The end plate 80A is formed with a through hole (not shown) for supplying or discharging a reactive gas or the like, and the reactive gas is introduced into the fuel cell 10 from an external hydrogen tank or compressor (not shown) through the through hole. Supplied without delay.

  As shown in FIGS. 1 and 3, the fuel battery cell 20 includes an electrode body (MEGA) 21 and a pair of separators 30 positioned so as to sandwich the electrode body 21 via frame-shaped seal gaskets 31 and 32. .

  As shown in FIG. 3, the electrode body 21 includes a membrane electrode assembly (MEA) (not shown) and gas diffusion layers provided on both side surfaces of the MEA. The MEA includes an ion-permeable electrolyte membrane and anode-side and cathode-side electrode catalyst layers that sandwich the electrolyte membrane. In the present embodiment, the electrode body 21 is formed in a substantially rectangular shape as shown in FIG.

  The electrolyte membrane is a solid polymer material thin film having proton conductivity and good electrical conductivity in a wet state. Examples of the electrolyte membrane include Nafion. The anode side electrode catalyst layer and the cathode side electrode catalyst layer formed on the surface of the electrolyte membrane carry a catalyst that promotes an electrochemical reaction, for example, platinum.

  The gas diffusion layer is a carbon porous body, and is formed of, for example, carbon cloth or carbon paper. The gas diffusion layer is integrated with the anode side surface and the cathode side surface of the MEA by bonding to form the electrode body 21.

  The anode-side gas diffusion layer diffuses the anode-side reaction gas (that is, fuel gas) in the thickness direction and supplies it to the entire surface of the anode-side electrode catalyst layer. The cathode-side gas diffusion layer diffuses the cathode-side reaction gas (that is, oxidizing gas) in the thickness direction and supplies it to the entire surface of the cathode-side electrode catalyst layer.

  Since the frame portions 31 a and 32 a of the seal gaskets 31 and 32 are arranged along the peripheral edges of both side surfaces of the electrode body 21, a space through which the reaction gas flows is formed between the electrode body 21 and the separator 30. ing.

  The seal gaskets 31 and 32 are made of an insulating resin material made of rubber having elasticity, such as silicon rubber, butyl rubber, and fluorine rubber. The seal gaskets 31 and 32 are formed in a substantially rectangular shape having the same size as the separator 30. As shown in FIG. 1, on both ends in the longitudinal direction of the seal gaskets 31 and 32, there are provided through holes that communicate with the respective flow paths and form a manifold of reaction gas and cooling water. The seal gasket 32 corresponds to a seal member.

Also in the electrode body 21, through holes are formed on both ends in the longitudinal direction so as to communicate with the respective flow paths and to form a manifold of reaction gas and cooling water.
Next, the separator 30 that collects electricity generated by the electrochemical reaction will be described. The separator 30 is configured by laminating an anode plate 34 arranged on the anode side made of a thin metal plate (metal plate) and a cathode plate 35 arranged on the cathode side via a seal gasket 33 as a seal member. ing. The seal gasket 33 corresponds to a sealing means.

The anode plate 34 and the cathode plate 35 are made of a conductive metal material such as stainless steel, titanium, or a titanium alloy.
The anode plate 34 corresponds to a first separator plate, and the cathode plate 35 corresponds to a second separator plate.

  The anode plate 34 is composed of a flat flat plate portion 34a formed in a substantially rectangular shape. A flow path (or a flow path having a corrugated cross section) 37 formed of a plurality of protrusions is formed in the central portion of the flat plate portion 34 a, and the gas diffusion layer on the anode side of the electrode body 21 is formed by the flow path 37. It contacts with an anode side electrocatalyst layer via. As shown in FIG. 1, the flow path 37 is surrounded by a frame portion 32 a of the seal gasket 32, and is positioned in a space in which a reaction gas between the electrode body 21 and the separator 30 flows. The area where the flow path 37 is formed corresponds to the flow path forming area.

  The cathode plate 35 includes a flat flat plate portion 35a formed in a substantially rectangular shape. A flow path (or a flow path having a corrugated cross section) 38 formed of a plurality of protrusions is formed in the central portion of the flat plate portion 35 a, and the gas diffusion layer on the anode side of the electrode body 21 is formed by the flow path 38. It contacts with a cathode side electrode catalyst layer via. In FIG. 1, for the sake of convenience of explanation, the lead line indicated by the reference numeral of the flow path 38 indicates the back side (the upper side in the drawing) of the portion where the flow path is formed.

The channel 38 is surrounded by the frame portion 31a of the seal gasket 31, located in a space reaction gases to flow between the electrode body 21 and the separator 30.
A seal gasket 33 is sandwiched between the anode plate 34 and the cathode plate 35, and cooling is mainly performed by the shape of the back side of the flow paths 37 and 38 so as to be located in a space formed between the seal gasket 33 and both plates. A water flow path is provided.

Manifold holes are formed through the plate portions 34 a and 35 a of the anode plate 34 and the cathode plate 35.
Specifically, as shown in FIG. 1, a fuel gas supply manifold hole 30a and a fuel gas discharge manifold hole 30b are provided on both short sides of the plates 34 and 35, respectively. In addition, an oxidizing gas supply manifold hole 30c and an oxidizing gas discharge manifold hole 30d are provided on both short sides of the plates 34 and 35, respectively. On both short sides of the plates 34 and 35, a manifold hole 30e for supplying cooling water and a manifold hole 30f for discharging cooling water are provided between the manifold holes 30a and 30d and between the manifold holes 30b and 30c. Each is provided.

  For convenience of explanation, FIG. 1 shows all the manifold holes 30 a to 30 f of the anode plate 34, but only the manifold hole 30 b is hidden in the manifold holes of the cathode plate 35. Absent.

  The seal gasket 33 is made of an insulating resin material made of rubber having elasticity, such as silicon rubber, butyl rubber, and fluorine rubber. The seal gasket 33 is substantially the same size as the anode plate 34 and the cathode plate 35 and is formed in a substantially rectangular shape. As shown in FIG. 1, on both ends in the longitudinal direction of the seal gasket 33, there are provided through holes that communicate with the respective flow paths and form a manifold of reaction gas and cooling water.

In the manifold holes 30a and 30b of the anode plate 34, the support portion 40 is formed as a bulging portion bulging from the flat plate portion 34a to the anode side so as to be higher than the height of the flow path forming region. Is provided. The region where the flow path 37 is formed corresponds to the flow path forming region. The support portion 40 includes a pair of leg portions 41 connected to the flat plate portion 34 a and a top portion 42 that connects between the tips of the leg portions 41. The cross-sectional shape of the support portion 40 is not limited, but preferably the anode side surface of the top portion 42 preferably has a flat surface. Support portion 40, upon being bulged molded from the flat plate portion 34a, and the flow path 37 side is sheared, the gas flow hole 44 is formed between the flat plate portion 34a as shown in FIG.

The two support portions 40 support the electrode body 21 by the top portion 42 coming into contact with the anode side surface of the electrode body 21.
On the other hand, in the cathode plate 35, one or a plurality of column portions 43 as support means are provided on the flat plate portion 35a opposite to the support portion 40 as support means formed to protrude from the flat plate portion 35a to the anode side. As shown in FIG. 3, the column portion 43 is press-formed from the cathode side to the anode side of the flat plate portion 35 a to be formed into a bag shape, and is extended to the support portion 40 side.

  The front end surface of the column portion 43 is formed flat and is in contact with the inner surface of the support portion 40. The column portions 43 are arranged along the short side, and between the column portions 43 and between the column portions 43 and the leg portions 41, the reactive gas flowing between the manifold hole 30 a and the flow path 37 of the anode plate 34. It is a gas flow path G. It is preferable that the front end surface of the column part 43 has a flat surface.

Each column portion 43 abuts on the inner surface of the top portion 42 to support the support portion 40 and support the electrode body 21 of the support portion 40.
A single or a plurality of column parts 43 (not shown) that support the support part 40 of the manifold hole 30b of the anode plate 34 are provided at a position proximal to the manifold hole 30b of the cathode plate 35 shown in FIG. It is provided in the same manner as the column part 43 provided proximal to the hole 30a.

Further, as shown in FIG. 4, in the manifold hole 30c of the cathode plate 35, a bulge formed on the flow channel 37 side so as to bulge from the flat plate portion 35a to the cathode side so as to be higher than the height of the flow channel formation region. A support portion 40A as an output portion is provided. The support portion 40A includes a pair of leg portions 41A connected to the flat plate portion 35a and a top portion 42A that connects the tips of the leg portions 41A. The cross-sectional shape of the support portion 40A is not limited in the same manner as the support portion 40. Preferably, the surface of the top portion 42A on the anode side has a flat surface. When the support portion 40A is swelled from the flat plate portion 35a, the flow path 37 side is sheared to form a gas flow hole 44A between the flat plate portion 35a as shown in FIG.

Both support portions 40 </ b> A support the electrode body 21 by the top portion 42 </ b> A contacting the cathode side surface of the electrode body 21.
Although FIG. 4 shows the manifold hole 30c side, a support portion 40A is similarly formed in the manifold hole 30d of the cathode plate 35, though not shown.

  On the other hand, as shown in FIG. 4, in the anode plate 34, the flat plate portion 34 a at a portion facing the support portion 40 A is provided with a single or a plurality of pillar portions 43 A as support means protruding from the flat plate portion 34 a to the cathode side. Is provided. As shown in FIG. 4, the column part 43A is press-molded from the anode side to the cathode side of the flat plate part 34a to be formed into a bag shape, and is extended to the support part 40A side.

  The front end surface of the column portion 43A is formed flat and is in contact with the inner surface of the support portion 40A. Each column portion 43A is arranged so as to be aligned along the short side. Between the column portions 43A and between the column portions 43A and the leg portions 41A, an oxidizing gas gas flows between the manifold hole 30c and the flow path of the cathode plate 35. It is a flow path GA. It is preferable that the front end surface of the column part 43A has a flat surface.

And each pillar part 43A is supporting the support part 40A by contacting the inner surface of 42 A of top parts, and supports the support of the electrode body 21 of 40 A of support parts.
In addition, at a portion proximal to the manifold hole 30d of the anode plate 34, one or a plurality of pillar portions 43A (not shown) that support the support portion 40A of the manifold hole 30d of the cathode plate 35 are close to the manifold hole 30c. It is provided in the same manner as the column part 43A provided at the position. (About the manufacturing method of the anode plate 34 and the cathode plate 35)
Here, a manufacturing method of the anode plate 34 and the cathode plate 35 will be described.

The support portions 40 and 40A are pressed into a metal mold simultaneously with the press forming of the manifold holes 30a to 30f and the flow path 37 with respect to the metal plate.
At the time of the press molding, the manifold holes 30a to 30f are punched by a mold. During this punching process, the area between the manifold hole 30a and the flow path 37, the area between the manifold hole 30b and the flow path 37, the area between the manifold hole 30c and the flow path 37, and between the manifold hole 30d and the flow path 37 Even after the punching of the manifold holes 30a to 30f, the portion corresponding to the region (that is, the region to be the support portions 40 and 40A) is bent and bulged by the mold. When the support portions 40 and 40A are bulged and formed from the flat plate portion 34a in a tunnel shape, the flow passage 37 of the support portions 40 and 40A is sheared to form gas flow holes 44 and 44A.

  In addition, the column portions 43 and 43A are bent by press molding simultaneously with the punching process or in a later process. By laminating and joining the anode plate 34 and the cathode plate 35 thus formed, various fluid flow paths are formed inside the separator 30.

(Operation of the embodiment)
Next, the operation of this embodiment will be described.
As shown in FIG. 3, a part of the fuel gas flowing in the manifold (including the manifold hole) formed by stacking the separator 30 and the seal gaskets 31 and 32 flows through the manifold hole 30a of the cathode plate 35. Supplied to path G. Then, the reaction gas (fuel gas in the present embodiment) that has flowed into the gas flow path G flows into the flow path 37 through the gas flow holes 44 and is subjected to an electrochemical reaction in the electrode body 21.

Further, the reaction gas that has passed through the flow path 37 is led out to the manifold hole 30b via a gas flow hole and a gas flow path of the other support portion (not shown).
Part of the oxidizing gas flowing in the manifold (including the manifold hole) formed by stacking the separator 30 and the seal gaskets 31 and 32 is supplied to the gas flow path GA through the manifold hole 30c of the cathode plate 35. The Then, the oxidizing gas that has flowed into the gas flow path GA flows into the flow path 37 through the gas flow holes 44A, and is subjected to an electrochemical reaction in the electrode body 21.

  The oxidizing gas that has passed through the flow path 37 is led out to the manifold hole 30d through a gas flow hole and a gas flow path of the other support portion (not shown). Further, in the present embodiment, the electrode body 21 is supported by the support portions 40 and 40A and the column portions 43 and 43A of the anode plate 34, and is prevented from being bent, so that the electrode body 21 can be held. For this reason, the adhesiveness between the electrode body 21 and the separator 30 and the seal gasket 32 (seal member) can be improved, and the sealing performance can be improved.

  In addition, the support portions 40 and 40A of the anode plate 34 of the present embodiment can be easily obtained by pressing without complicated processes, and in the formation of the gas flow paths G and GA, Since the gas flow path G is formed by shearing, a special drilling process is not necessary.

This embodiment has the following features.
(1) In the anode plate 34 and the cathode plate 35 of the present embodiment, the channel 37 is provided between the manifold hole 30a (30b) and the channel 37 and between the manifold hole 30c (30d) and the channel 37. Support portions 40 and 40A (bulging portions) that are formed higher than the formed flow path forming region and bulge and support the electrode body 21 of the fuel cell are formed. Gas flow holes 44 and 44 A communicating with the manifold holes 30 a (30 b) and 30 c (30 d) and the flow path 37 are formed on the side surfaces of the support portions 40 and 40 A on the flow path 37 side.

  For this reason, the electrode body is formed by the support portions 40 and 40A formed between the manifold hole 30a (30b) and the flow path 37 and between the manifold hole 30c (30d) and the flow path 37 so as to be higher than the flow path formation region. 21 is supported to prevent the electrode body (MEGA) from being bent. For this reason, the adhesion between the seal gasket 32 (seal member) disposed between the electrode body / separator and each of the electrode body 21 and the separator 30 is enhanced, and the sealing performance can be improved. In addition, the support portions 40 and 40A can be easily formed by press molding, and the process for providing a passage for passing gas can be greatly reduced as compared with the conventional case.

  (2) The anode plate 34 and the cathode plate 35 of the present embodiment can be easily formed because the gas flow holes 44, 44A are formed by shearing when the support portions 40, 40A are bulged. Processing of the anode plate 34 and the cathode plate 35 is facilitated.

  (3) Manifold holes 30a (30b) and 30c (30d) are formed in the flat plate portions 34a and 35a of the anode plate 34 and the cathode plate 35 of the present embodiment, and a flow path 37 is formed. 40A is formed to bulge from the flat plate portions 34a and 35a. As a result, the above effects (1) and (2) can be easily realized in the anode plate 34 and the cathode plate 35 having the support portions 40 and 40A bulged from the flat plate portions 34a and 35a.

  (4) In the fuel cell of the present embodiment, the anode plate 34 and the cathode plate 35 of the separator 30 are provided with column portions 43 and 43A (supports) for supporting the support portion 40 from the opposite side of the electrode body 21 of the support portions 40 and 40A. The means) is formed to extend to the cathode plate 35 and the anode plate 34, so that the electrode body 21 is supported together with the support portions 40 and 40A, and the electrode body 21 (MEGA) is prevented from being bent. Therefore, the seal gaskets 32 and 31 (seal members) disposed between the electrode body and the anode plate 34 and between the electrode body and the cathode plate 35, the electrode body 21 and the anode plate 34, and the electrode body 21 and the cathode plate 35, respectively. The adhesion between the two can be improved and the sealing performance can be improved. In addition, the support portions 40 and 40A of the anode plate 34 and the cathode plate 35 can be easily formed by press molding, and the process for providing a passage for passing gas can be greatly reduced as compared with the prior art.

  (5) In the manufacturing method of the anode plate 34 and the cathode plate 35 of the present embodiment, the electrode body 21 is supported in the region between the manifold holes 30a (30b) and 30c (30d) of the metal plate and the flow path 37. The support portions 40 and 40A are swelled by press molding so as to be higher than the flow path formation region where the flow path 37 is formed, and at the time of the press molding, on the side surface of the support sections 40 and 40A on the flow path 37 side. The gas flow holes 44 communicating with the manifold holes 30a (30b) and 30c (30d) and the flow path 37 are formed.

  For this reason, with respect to the area between the manifold holes 30a (30b) and 30c (30d) of the metal plate and the flow path 37, the support portion 40 that supports the electrode body 21 is higher than the flow path formation area of the flow path 37. Thus, the support portions 40 and 40A can be obtained simply by bulging by press molding. At the same time as the press forming of the support portions 40, 40 </ b> A, the gas flow holes 44 communicating with the manifold holes 30 a to 30 f and the flow path 37 are formed.

  As a result, the adhesiveness between the electrode body 21 and the anode plate 34 and between the seal gaskets 32 and 33 (sealing members) disposed between the electrode body 21 and the cathode plate 35 is improved, and the sealing performance is improved. In addition, the process for providing a passage for allowing gas to pass through the structure that supports the electrode body 21 can be significantly reduced as compared with the prior art, and the cost can be suppressed.

(Second Embodiment)
Next, a second embodiment will be described with reference to FIGS. In the following embodiments including the present embodiment, a description will be given centering on configurations that are different from the embodiments already described, and the same or equivalent configurations as those of the embodiments already described are denoted by the same reference numerals.

  In the following description of the embodiment including this embodiment, the anode plate 34 will be described with a focus on the configuration different from that of the first embodiment, and the cathode plate 35 will be omitted for simplicity of explanation. It should be understood that there are similar configurations different from the first embodiment.

  The present embodiment is different from the first embodiment in that a plurality of column portions 45 are provided from the top 42 of the support portion 40 toward the cathode plate 35 instead of providing the column portions 43 on the cathode plate 35. . That is, as shown in FIG. 6, the column portion 45 is formed by pressing from the flat top portion 42 of the support portion 40 toward the cathode side to form a bag and extending toward the cathode plate 35 side. is there. In the present embodiment, the column portion 45 is formed so as not to reach both ends of the support portion 40 in the direction in which the reaction gas flows through the gas flow path G described later (the left-right direction in FIG. 6).

  The front end surface of the column portion 45 is formed flat and is in contact with the flat plate portion 35 a of the cathode plate 35. Each column portion 45 is arranged so as to be arranged along the short side, and between the column portions 45 and between the column portion 45 and the leg portion 41, there is a reaction gas flowing between the manifold hole 30 a and the flow path 37 of the anode plate 34. It is a gas flow path G. It is preferable that the front end surface of the column part 45 has a flat surface.

  Each column portion 45 abuts the flat plate portion 35ai of the cathode plate 35 to support the support portion 40 and support the electrode body 21 of the support portion 40. In the present embodiment, the column portion 45 corresponds to a support means.

(About the manufacturing method of the anode plate 34)
A method for manufacturing the anode plate 34 of the second embodiment will be described.
The support 40 is pressed into a metal mold simultaneously with the press forming of the manifold holes 30a to 30f and the flow path 37 with respect to the metal plate. At the time of the press molding, the manifold holes 30a to 30f are punched by a mold. At the time of this punching process, even after the punching of the manifold holes 30a to 30f with respect to the part corresponding to the region between the manifold hole 30a and the flow path 37 (that is, the region to be the support portion 40), Bend and bulge. At the same time as this bulging molding, the column portion 45 is recessed toward the side opposite to the bulging direction of the support portion 40 by a mold. When the support portion 40 is formed to bulge out from the flat plate portion 34a in a tunnel shape, the flow path 37 of the support portion 40 is sheared to form the gas flow holes 44.

(Operation of Second Embodiment)
In the present embodiment, the electrode body 21 is supported by the support portion 40 and the column portion 45 of the anode plate 34, is prevented from bending, and can hold the electrode body 21. For this reason, the adhesiveness between the electrode body 21 and the separator 30 and the seal gasket 32 (seal member) can be improved, and the sealing performance can be improved.

This embodiment has the following features.
(1) In the separator 30 of the fuel cell 10 according to the present embodiment, the anode plate 34 (first separator plate) has a column portion 45 (support means) that supports the support portion 40 from the opposite side of the electrode body 21 of the support portion 40. ) Is extended to the cathode plate 35, thereby supporting the electrode body 21 together with the support portion 40 and preventing the electrode body 21 (MEGA) from being bent. For this reason, the adhesiveness between the seal gasket 32 (seal member) disposed between the electrode body / anode plate 34 and each of the electrode body 21 and the anode plate 34 is enhanced, and the sealing performance can be improved. Further, the formation of the support portion 40 of the anode plate 34 can be easily performed by press molding, and the process for providing a passage for passing gas can be greatly reduced as compared with the conventional case.

(Third embodiment)
Next, a third embodiment will be described with reference to FIGS. In the second embodiment, it is formed so as not to reach both ends of the support portion 40 in the direction in which the reaction gas flows through the gas flow path G (the left-right direction in FIG. 6). A difference from the second embodiment is that a plurality of column portions 45A are formed so as to be on the side of the 40 gas flow holes 44.

Also in the present embodiment, the gas flow holes 44 can be sheared simultaneously with press molding by the same manufacturing method as in the second embodiment.
According to the configuration of the third embodiment, since the column portion 45A is provided on the gas circulation hole 44 side, when the fuel cells 20 are stacked and stacked in a compressed state, the gas circulation hole 44 (opening). It is possible to receive the compression load applied to the cover more rigidly. For this reason, the fastening load can be reliably transmitted to the seal gasket 33 (sealing means) located in the vicinity of the gas flow hole 44 (opening), that is, between the anode plate 34 and the cathode plate 35. It can be set as the structure which reliability increases.

(Fourth embodiment)
Next, a fourth embodiment will be described with reference to FIGS.
In the fourth embodiment, the frame portion 39 bulges out so that the square central portion 36 of the anode plate 34 is concave, and the central portion 36 is surrounded by the frame portion 39. This is different from the embodiment and the third embodiment.

A flow path 37 is formed in the central portion 36 to form a flow path forming region.
Manifold holes 30 a to 30 f are formed in the frame portion 39. In FIG. 9, only the manifold holes 30a and 30d are shown for convenience of explanation. The positional relationship between the other manifold holes 30b, 30c, 30e, and 30f is the same as in the first embodiment, and is omitted. A part of the frame portion 39 adjacent to the manifold hole 30 a is a bulging portion 46.

  A gas flow hole 44 that communicates with the manifold hole 30 a and the flow path 37 is formed on the side surface of the bulging portion 46 on the flow path 37 side (that is, the central portion 36). The bulging portion 46 is provided with a plurality of column portions 45 and 45A, respectively, as in the second and third embodiments. The column portions 45 and 45A are in contact with a flat plate portion of a cathode plate (not shown).

Further, a flange portion 48 is formed around the frame portion 39 through a step portion, and a frame-shaped seal gasket (not shown) is disposed.
A central portion 36 of the anode plate 34 is disposed in a space formed in a concave shape from the frame portion 39 in a state where an electrode body 21 (not shown) is bridged, and a gas diffusion layer (GDL) of the electrode body 21 is disposed in the central portion. 36 channels 37 are in contact with each other.

In said 4th Embodiment, there can exist an effect similar to 2nd Embodiment and 3rd Embodiment by pillar part 45A, 45. FIG.
In addition, embodiment of this invention is not limited to the said embodiment, You may change as follows.

  In the manufacturing method of the anode plate 34 (cathode plate 35) in the first embodiment and the second embodiment, the support portion 40 is formed simultaneously with the press forming of the manifold hole 30a and the flow path 37. The manifold hole 30a and the like and the flow path 37 may be press-molded first, and then the support portion 40 may be press-molded and the gas flow hole 44 may be formed.

  In the above embodiment, the gas flow hole 44 is formed by shearing simultaneously with the formation of the support portion 40. However, when forming the manifold holes 30a to 30f, the manifold holes 30a to 30f are formed by drawing and drawing. After forming the support portion 40, the gas flow hole 44 may be formed on the side surface on the flow path 37 side by drilling.

In each of the above embodiments, the column portions 43, 43A, 45, and 45A are provided, but the column portions 43, 43A, 45, and 45A may be omitted.
-It is not limited to providing support parts (40 etc.) in manifold holes 30a (30b), 30c (30d), but support parts (40 etc.) are provided in manifold holes other than manifold holes 30a, 30b. May be. In this case, you may make it provide the pillar part which supports the support part 40 similarly to the said embodiment.

DESCRIPTION OF SYMBOLS 10 ... Fuel cell, 20 ... Fuel cell, 21 ... Electrode body, 30 ... Separator,
31 ... Seal gasket, 32 ... Seal gasket, 33 ... Seal gasket,
34 ... anode plate (first separator plate),
34a ... Flat plate portion, 35 ... Cathode plate (second separator plate),
35a ... Flat plate part, 36 ... Center part, 37 ... Channel, 38 ... Channel,
40, 40A ... support part (bulging part), 41, 41A ... leg part, 42, 42A ... top part,
43, 43A ... pillar portion, 44 ... gas flow hole.

Claims (7)

A plurality of flow path for flowing the reaction gas for use in a fuel cell, equipped with a manifold hole and the manifold holes for the reaction gas exhaust for the reactive gas supply to circulate the reaction gas wherein the respective flow paths In a metal fuel cell separator plate,
Between the manifold hole and the flow path, a bulge portion is formed that is formed higher than the flow path formation region in which each flow path is formed and bulges, and supports the electrode body of the fuel cell, A fuel cell separator plate, wherein a gas flow hole communicating with the manifold hole and the flow path is formed on a side surface of the bulge portion on the flow path side.   2. The fuel cell separator plate according to claim 1, wherein the gas flow hole is formed by shearing when the bulging portion is bulged. 3. With a flat plate,
In the flat plate portion, the manifold hole is formed and the flow path is formed,
3. The fuel cell separator plate according to claim 1, wherein the bulging portion is formed to bulge from the flat plate portion. A central portion formed in a concave shape and a frame portion surrounding the periphery of the central portion are formed to bulge from the peripheral edge of the central portion,
The flow path is provided with the central portion as a flow path forming region,
The manifold hole is formed in the frame portion,
A part of the frame portion adjacent to the manifold hole is the bulging portion,
3. The fuel cell separator plate according to claim 1, wherein a gas flow hole communicating with the manifold hole and the flow path is formed on a side surface of the bulge portion on the flow path side. . 5. The electrode supported by the bulging portion with respect to the first separator plate via a frame-shaped sealing means, wherein the fuel cell separator plate according to claim 1 is a first separator plate. A separator for a fuel cell in which a second separator plate is laminated on the opposite side of the body,
In either one of the first separator plate and the second separator plate, support means for supporting the bulging portion extends from the opposite side of the electrode body to the other separator plate. A fuel cell separator characterized by the above. 6. A pair of fuel cell separators according to claim 5, wherein the electrode body is sandwiched between a side surface on the anode side and a side surface on the cathode side of the electrode body via frame-like sealing means, respectively. A fuel cell comprising a plurality of fuel cells stacked. A plurality of flow path for flowing the reaction gas for use in a fuel cell, equipped with a manifold hole and the manifold holes for the reaction gas exhaust for the reactive gas supply to circulate the reaction gas wherein the respective flow paths A method for manufacturing a metal fuel cell separator plate,
With respect to the area between the manifold hole and the flow path of the metal plate, the bulging portion that supports the electrode body of the fuel cell is formed from the flow path forming area where the flow paths are formed or where the flow paths are formed. Swelled by press molding so as to be higher, and at the time of press molding, a gas flow hole communicating with the manifold hole and the flow path is formed on a side surface of the bulging portion on the flow path side. A method for producing a separator plate for a fuel cell.

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