JP5651053B2 - Cutting edge exchangeable cutting tip, cutting method using the same, and manufacturing method of cutting edge exchangeable cutting tip - Google Patents

Description

  The present invention relates to a blade-tip-exchangeable cutting tip, and particularly to a blade-tip-exchangeable cutting tip used for high-speed steel cutting or a die steel cutting tool.

  2. Description of the Related Art Conventionally, various work materials have been cut by attaching a blade-tip-exchangeable cutting tip to a tip portion (blade tip) of a cutting tool. When the blade-tip-exchangeable cutting tip reaches the end of its life by using the cutting tool for a long period of time, the blade-tip-exchangeable cutting tip is replaced at that time and cutting is continued.

  Such cutting edge-replaceable cutting tips are required not only to have high cutting performance such as wear resistance, toughness, and heat crack resistance, but also to have a tool shape with excellent chip disposal. . In order to satisfy such required performance, a cemented carbide known as a hard material is used for a blade-tip-exchangeable cutting tip.

  The above cemented carbide is prepared by mixing a WC powder containing WC as a main component with a binder phase that binds the WC powders, and then molding the mixture by a pressing method, an injection molding method, or an extrusion method. Thus, a sintered body is produced. Then, as necessary, the surface of the sintered body is subjected to partial polishing or full polishing with a grindstone, and further, blade edge treatment, hard layer coating on the surface of the sintered body, surface treatment after coating, and the like are performed.

  However, in the liquid phase sintering described above, due to the density of the composition due to the part of the molded body and the level of the sintering temperature due to the part of the molded body, the sintering does not proceed uniformly, depending on the part of the molded body. The shrinkage rate is often different. In particular, cemented carbide has a volume shrinkage of about 50% due to liquid phase sintering, so the difference in the amount of shrinkage between the parts is significant, and the shape and dimensions of the sintered body may vary.

  Thus, when there is variation in the shape and dimensions of the sintered body, there is a problem that the position of the cutting edge is slightly shifted before and after the replacement of the cutting edge replacement type cutting tip, and the processing accuracy and the quality of the processed surface are lowered. Such a problem becomes particularly remarkable in milling processing in which a plurality of blade-tip-exchangeable cutting tips are used simultaneously.

  In particular, because the shape of the cutting edge-exchangeable cutting tip has become complicated in recent years, for example, in powder feeding to a die during pressing, a portion where there is a lot of powder feeding, that is, a portion where the molded body density is high, has a small amount of shrinkage due to sintering, The part where the powder supply is small, that is, the part where the pressed body density is low, has a large shrinkage amount due to sintering. As described above, the amount of shrinkage varies depending on the region, and as a result, the sintered body changes from a completely similar shape to a shape having distortion.

  In order to eliminate such variations in the shape and dimensions of the sintered body, a part or all of the surface of the sintered body is polished with a grindstone after sintering to make the size of the sintered body uniform. It is. However, when the surface of the sintered body has a three-dimensionally complicated shape, the dimensions of all the sintered bodies may not be made uniform only by polishing.

  Therefore, in Patent Documents 1 to 8, in order to increase the dimensional accuracy, a dispersant is mixed when forming the molded body to make the density of the molded body as uniform as possible. Moreover, in patent documents 9-13, in order to manufacture a complicated and highly accurate blade-tip-exchange-type cutting tip, the effort which reduces a grinding | polishing location as much as possible is made, or the effort of non-polishing is made.

  However, even with the techniques disclosed in Patent Documents 1 to 13, the distortion (deformation) due to the variation in shrinkage due to the site of the molded body during sintering cannot be solved. At present, the cutting edge-exchangeable cutting tip has not reached a level that satisfies the cutting performance and dimensional accuracy required by the user.

JP 2006-176800 A JP 2001-081525 A JP 2003-293071 A JP 2008-183708 A JP 2008-126403 A Japanese Examined Patent Publication No. 62-056944 JP-T-2004-509773 Special table 2009-519139 gazette JP 2006-075913 A JP 2006-088332 A JP 05-138447 A Japanese Patent Publication No. 07-002284 Japanese Patent Publication No. 01-038602

Liquid Phase Sintering Publisher: Uchida Otsukuru, Inc. ISBN 4-7536-5187-8

  In order to prevent the sintered body from being deformed during liquid phase sintering, it is effective to reduce the mass ratio of the iron-based metal in the sintered body. However, if the mass ratio of the iron-based metal in the sintered body is reduced, the bending strength of the cemented carbide decreases, so that it is not possible to obtain the cutting edge strength required when used as a cutting edge exchangeable cutting tip. Thus, the cutting performance and the dimensional accuracy are in a trade-off relationship, and the advent of a cutting edge-exchangeable cutting tip that satisfies both of them is awaited.

  The present invention has been made in view of the current situation as described above, and an object of the present invention is to provide a blade-tip-exchangeable cutting tip having excellent cutting performance and high dimensional accuracy.

  In order to solve the above-mentioned problems, the present inventors conducted extensive research on the mass ratio of each component constituting the cemented carbide, and as a result, the mass ratio of WC and its average particle diameter, the mass ratio of iron-based metal, and Only when the mass ratio of TaC satisfies a specific formula, it has been found that the cutting performance and dimensional accuracy of the blade-tip-exchangeable cutting tip can be achieved, and the present invention has been completed.

That is, the cutting edge-exchangeable cutting tip of the present invention includes at least a base material, and the base material includes 8.5 to 12.5 mass% of an iron-based metal and 0.55 to 2.3 mass. % Of TaC and inevitable impurities, and the balance is WC, and the WC particles in the structure of the cemented carbide have an average particle size of 0.8 to 3 μm, and the coercive force of the base material Is HC (kA / m), the saturation magnetic flux density is 4πσ (10 ⁻⁷ Tm ³ / kg), and the mass% of Co contained in the substrate is M _Co (mass%), the following formula (I) is obtained: And a phase mainly composed of Ta is precipitated in the structure of the cemented carbide, and the phase mainly composed of Ta has an average particle diameter of 0.4 to 2.4 μm. To do.
−0.7 × 4πσ ÷ M _Co −0.9 × M _Co + 39.15 ≧ HC (I).

The base material preferably contains 0.2 to 0.55% by mass of Cr.
The blade-tip-exchangeable cutting tip of the present invention includes a base material and a film formed on the base material, and the film includes a group IVa element, a group Va element, a group VIa element, Al, and a periodic table. Including at least one element selected from the group consisting of Si, or one or more layers composed of a compound of the element and at least one element selected from the group consisting of carbon, nitrogen, oxygen and boron. preferable.

The coating is preferably formed by physical vapor deposition and / or chemical vapor deposition.
The coating is formed by a physical vapor deposition method and includes a super multi-layer structure layer or a modulation structure layer, and the super multi-layer structure layer includes the IVa group element, the Va group element, the VIa group element, Al, And at least one unit layer composed of a compound consisting of at least one element selected from the group consisting of Si and at least one element selected from the group consisting of carbon, nitrogen, oxygen, and boron, Each of the modulation structure layers has a structure in which the thickness is 0.2 nm or more and 20 nm or less, and the modulation structure layer is composed of a group IVa element, a group Va element, a group VIa element, Al, and Si in the periodic table. A compound composed of at least one element selected from the group and at least one element selected from the group consisting of carbon, nitrogen, oxygen, and boron. Composition ratio preferably has a structure that changes at a period of 0.2nm or 40nm or less in the thickness direction.

  The coating is preferably provided with a compressive residual stress of 0.1 GPa or more. It is preferable that the cutting edge-exchangeable cutting tip of the present invention is used for milling. The present invention is also a cutting method in which cutting is performed using two or more of the above-mentioned blade edge-exchangeable cutting tips at the same time.

  The manufacturing method of the cutting edge exchange-type cutting tip of this invention mixes at least 8.5-12.5 mass% iron-type metal, 0.55-2.3 mass% TaC, and WC at the remainder. A step of producing a raw material powder; a step of producing a molded body by molding the raw material powder; a step of producing a sintered body by maintaining the molded body at 1350 to 1500 ° C .; The step of cooling the sintered body to a temperature not lower than 1150 ° C. and not higher than the liquid phase solidification temperature at a cooling rate of 0.5 to 10 ° C./min, and holding the sintered body at a temperature not lower than 1150 ° C. and not higher than the liquid phase solidification temperature for 10 minutes or longer. And a step of cooling the sintered body at a cooling rate of 15 ° C./min or more in this order.

  The manufacturing method of the cutting edge exchange-type cutting tip of this invention mixes at least 8.5-12.5 mass% iron-type metal, 0.55-2.3 mass% TaC, and WC at the remainder. A step of producing a raw material powder; a step of producing a molded body by molding the raw material powder; a step of producing a sintered body by maintaining the molded body at 1350 to 1500 ° C .; The step of cooling the bonded body to a temperature not lower than the liquid phase solidification temperature and not higher than 1350 ° C. at a cooling rate of 0.5 to 10 ° C./min, and holding the sintered body at a temperature not lower than the liquid phase solidification temperature and not higher than 1350 ° C. for 10 minutes or longer. A step of cooling the sintered body to a temperature not lower than 1150 ° C. and not higher than the liquid phase solidification temperature at a cooling rate of 0.5 to 10 ° C./min, and a temperature not lower than 1150 ° C. and not higher than the liquid phase solidification temperature. For 10 minutes or more When, characterized in that it comprises the step of cooling the sintered body at 15 ° C. / min or more cooling rate in this order.

  The cutting edge replacement type cutting tip of the present invention has the above-described configuration, and thus has an effect of excellent cutting performance and high dimensional accuracy.

Hereinafter, the present invention will be described in more detail.
<Cutting edge type cutting tip>
The cutting edge-exchangeable cutting tip of the present invention includes at least a base material, and the base material is inevitable with 8.5 to 12.5% by mass of iron-based metal, 0.55 to 2.3% by mass of TaC. It is made of a cemented carbide containing impurities and the balance being WC. You may provide with the film formed on the base material which consists of said cemented carbide. As long as such a basic configuration is provided, the shape is not particularly limited, and may have any conventionally known shape.

  Such a blade-tip-exchangeable cutting tip of the present invention includes, for example, drilling, end milling, milling, milling, turning, metal saw processing, cutting tool processing, reaming processing, tapping processing. Or for pin milling of a crankshaft or the like.

  Among the above processes, it is preferable to apply to a milling process using a plurality of blade-tip-exchangeable cutting tips at the same time. This is because when milling is performed using the cutting edge-exchangeable cutting tip of the present invention, not only the work surface quality (gloss and dimensional accuracy) of the work material is improved, but also the chip discharge direction can be stabilized. Because it can. As a result, it is possible to suppress the chipping of the cutting edge due to the biting of the chips during cutting, and it is possible to suppress the occurrence of scratches on the processed surface of the work material due to the collision of the chips. In addition, since the cutting is stabilized and the load variation between the cutting edges is reduced, there is also an advantage that the cutting edge is less likely to be lost.

<Base material>
The base material of the cutting edge-exchangeable cutting tip of the present invention contains 8.5 to 12.5% by mass of iron-based metal, 0.55 to 2.3% by mass of TaC, and inevitable impurities, with the balance being WC. The WC particles in the cemented carbide structure have an average particle diameter of 0.8 to 3 μm, the coercive force of the substrate is HC (kA / m), and the saturation magnetic flux density is When 4πσ (10 ⁻⁷ Tm ³ / kg) is assumed and the mass% of Co contained in the base material is M _Co (mass%), the following formula (I) is satisfied and Ta is the main component in the metal structure. A phase is precipitated, and the phase mainly composed of Ta has an average particle diameter of 0.4 to 2.4 μm.
−0.7 × 4πσ ÷ M _Co −0.9 × M _Co + 39.15 ≧ HC (I).

  The coercive force HC of the above cemented carbide is known to represent the particle size of the WC particles and the thickness of the iron-based metal in the structure. When the coercive force HC satisfies the above formula (I), Deformation of the bonded body can be suppressed, so that the dimensional accuracy of the blade-tip-exchangeable cutting tip can be increased. The coercive force HC may be referred to as “coercive force”, and the saturation magnetic flux density 4πσ may be referred to as “saturation magnetic quantity” or “residual magnetic flux density”.

  Even if the cemented carbide used as such a base material contains an abnormal phase called free carbon or ε phase in the structure, the effect of the present invention is shown. In addition, these base materials may have a modified surface. For example, a β-free layer may be formed on the surface of the cemented carbide, or in the case of cermet, a surface hardened layer may be formed. Even if the surface is modified in this way, the effect of the present invention is demonstrated. It is.

The mass% (M _Co ) of Co contained in the base material is preferably 9 to 12 mass%, more preferably 9.5 to 11.5 mass%. If it is less than 8.5% by mass, the cutting edge strength may be insufficient, which is not preferable. If it exceeds 12.5% by mass, the dimensional accuracy of the sintered body deteriorates, which is not preferable.

Moreover, it is preferable that said base material contains 0.2-0.55 mass% Cr. By adding Cr to the base material, the bending strength of the cemented carbide can be improved. As for such Cr, it is more preferable to contain 0.2-0.5 mass% with respect to a base material, More preferably, it is 0.2-0.45 mass%. If the above Cr is less than 0.2% by mass, the effect of improving the bending strength cannot be sufficiently obtained, and if it exceeds 0.55% by mass, the cemented carbide will be deteriorated. . Note that Cr in the cemented carbide may be introduced by adding Cr metal powder during sintering when producing the cemented carbide, or raw material powder such as Cr ₃ C ₂ or Cr ₂ O ₃ may be used. You may introduce | transduce by adding.

<WC particles>
In the present invention, the structure of the cemented carbide of the base material is a cemented carbide containing WC particles having an average particle diameter of 0.8 to 3 μm. By including the WC particles having such an average particle diameter, the wear resistance and cutting edge strength of the cemented carbide can be improved. The average particle diameter of the WC particles is preferably 1 to 2 μm, more preferably 1 to 1.8 μm. When the average particle diameter of the WC particles is less than 0.8 μm, the wear resistance is lowered, and when it exceeds 3 μm, the blade edge strength is lowered, which is not preferable.

  In addition, the value computed by the method described in CIS019D-2005 shall be employ | adopted for the average particle diameter of said WC particle.

  The base material of the present invention is characterized by containing WC as the balance other than iron-based metal, TaC, and inevitable impurities. The “remainder” specifically includes 84.65 to 90.95% by mass of WC, but preferably includes 86 to 90. 5% by mass of WC. By including WC at such a mass ratio, the strength of the blade edge and the wear resistance can be improved. When WC exceeds 90.95% by mass, the strength of the blade edge decreases, and when it is less than 84.65% by mass, wear resistance decreases, which is not preferable.

<Phase mainly composed of Ta>
In the present invention, the substrate is a cemented carbide containing 0.55 to 2.3% by mass of TaC. When TaC is less than 0.55% by mass, the wear resistance is insufficient, which is not preferable. When it exceeds 2.3% by mass, the sintered body is likely to be deformed during sintering, thereby reducing dimensional accuracy. It is not preferable. The reason why the dimensional accuracy is lowered when the mass ratio of TaC is large is not necessarily clear, but probably due to the fact that the thermal conductivity of TaC is lower than the thermal conductivity of WC, It is speculated that this is due to the variation in the heat distribution. Said TaC exists in the structure | tissue of a cemented carbide as a TaC phase or a phase which has Ta as a main component.

In addition, TaC in the cemented carbide may be introduced by adding Ta metal powder during sintering when producing the cemented carbide, or raw material powder such as TaC, TaN, Ta ₂ O ₅ is added. You may introduce by doing. When the Ta metal powder is mixed, the Ta metal powder and carbon react to form a TaC phase or a phase mainly composed of Ta.

In the present invention, a phase mainly composed of Ta is precipitated in the structure of the cemented carbide, and the phase mainly composed of Ta has an average particle diameter of 0.4 to 2.4 μm. And Thus, wear resistance can be improved by the phase which has Ta as a main component in the structure | tissue of a cemented carbide. When the phase containing Ta as a main component is not precipitated as a single phase in the structure of the cemented carbide, it is not preferable because wear resistance deteriorates remarkably in high-speed cutting of steel and cutting of die steel. Here, the “structure of the cemented carbide” means the third component (TaC, NbC, TiC, in addition to the hard phase (WC) and the binder phase (iron-based metal, Co, etc.) in the cemented carbide. Meaning one containing one or more compounds such as ZrC, ZrCN, TiCN, or a solid solution of the compound and WC). Further, the “phase having Ta as a main component” refers to a region in which Ta in the structure of the cemented carbide includes an atomic ratio exceeding 0.5 with respect to the total volume of the cemented carbide, (Ta _{1− x W x) z (C 1} -y, N y) 1-z, 0 ≦ x ≦ 0.5,0 ≦ y ≦ 1,0 <z < compound represented as 1, or TaC, TaN, TaCN etc. In general, it takes the form of composite carbide or composite carbonitride. In addition, the state that “the phase mainly composed of Ta precipitates in the structure of the cemented carbide” can be confirmed by observing with a metal microscope or an electron microscope.

  The average particle diameter of the above-mentioned phase containing Ta as a main component is preferably 0.5 to 2.0 μm, and more preferably 0.6 to 1.6 μm. If the average particle size of the phase containing Ta as a main component is less than 0.4 μm, the effect of improving the wear resistance cannot be sufficiently obtained, and if it exceeds 2.4 μm, the dimensional accuracy deteriorates, which is not preferable. . The average particle diameter of the phase mainly composed of Ta can be calculated by the same calculation method as the average particle diameter of the WC particles.

<Iron-based metal>
In this invention, the cemented carbide which comprises a base material contains 8.5-12.5 mass% iron-type metal, It is characterized by the above-mentioned. Such an iron-based metal has a role of maintaining strength in the cemented carbide. The iron-based metal is preferably 9 to 12% by mass, and more preferably 9.5 to 11.5% by mass. When the mass ratio of the iron-based metal is less than 8.5% by mass, it is not preferable because sufficient blade edge strength cannot be obtained, and when it exceeds 12.5% by mass, the necessary blade edge accuracy and / or wear resistance is obtained. Is not preferred because it cannot be obtained. Examples of the iron-based metal include Co, Ni, and Fe. Note that the cemented carbide of the present invention does not lose the effect of the present invention even if it contains about 1.0% by mass of one or more compositions of Ti, Nb, Mo, or Zr.

<Manufacturing method of substrate>
In this invention, the manufacturing method of the base material which comprises a blade-tip-exchange-type cutting tip is 8.5-12.5 mass% iron-based metal, 0.55-2.3 mass% TaC, and WC is the balance. To produce a raw material powder, to mold the raw material powder, to produce a molded body, and to hold the molded body at 1350 to 1500 ° C. to produce a sintered body Cooling the sintered body at a cooling rate of 0.5 to 10 ° C./min to a temperature not lower than 1150 ° C. and not higher than the liquid phase solidification temperature, and sintering the sintered body not lower than 1150 ° C. and not higher than the liquid phase solidification temperature. A step of maintaining the temperature for 10 minutes or more and a step of cooling the sintered body at a cooling rate of 15 ° C./min or more are included in this order.

  As a manufacturing method of the cutting edge exchange type cutting tip other than the above manufacturing method, the same process as described above is performed until the step of manufacturing the above sintered body, and thereafter the sintered body is added at 0.5 to 10 ° C./min. The step of cooling to a temperature not lower than the liquid phase solidification temperature and not higher than 1350 ° C. at the cooling rate, the step of maintaining the sintered body at a temperature not lower than the liquid phase solidification temperature and not higher than 1350 ° C. for 10 minutes, A step of cooling to a temperature not lower than 1150 ° C. and not higher than the liquid phase solidification temperature at a cooling rate of 10 ° C./min, a step of holding the sintered body at a temperature not lower than 1150 ° C. and not higher than the liquid phase solidification temperature, and a sintered body; And a step of cooling at a cooling rate of 15 ° C./min or more in this order. By producing the base material by such a production method, deformation of the sintered body can be suppressed.

  As a method for producing a substrate used in the present invention, it is preferable to use a powder metallurgy process. It is because it is easy to produce a blade-tip-exchangeable cutting tip having both cutting performance and dimensional accuracy by producing a base material using such a process.

  In the step of molding the raw material powder, any conventionally known method can be used, and examples thereof include a pressing method, an injection molding method, an extrusion method, and a CIP method.

<Step of cooling the sintered body>
Conventionally, it was thought that the size of the sintered body did not change below the temperature at which the liquid phase solidifies, but the present inventors have a great influence on the size of the sintered body even below the liquid phase solidification temperature of the cemented carbide. Found to give. The cause of the change in the size of the sintered body at such a temperature is not certain, but the ferrous metal immediately after cooling to a temperature below the temperature at which the liquid phase solidifies is probably due to its low hardness. It is guessed that it is due to moving in.

  Based on such inference, it was considered that the cooling condition immediately after the sintering of the molded body was a point for improving the dimensional accuracy. For this reason, this invention is completed by earnestly researching the cooling conditions immediately after sintering which was not paying attention in the prior art. By performing cooling immediately after sintering under the cooling conditions as described above, a desired alloy structure, cutting performance, and deformation suppression can be achieved. The above liquid phase solidification temperature varies depending on the amount of carbon, amount of Co contained in the alloy, sintering conditions, etc., but the influence of the amount of carbon contained in the alloy is particularly large. For example, the book “Cemented carbide and sintered hard material” P97 of “Maruzen” indicates that the liquid phase solidification temperature of the low carbon alloy is 1298 ° C., and the liquid phase solidification temperature of the high carbon alloy is 1357 ° C.

  As described above, since the liquid phase solidification temperature varies depending on the amount of carbon contained in the alloy, it is difficult to uniformly define the liquid phase solidification temperature. A step of cooling to a temperature of 1150 ° C. or higher and a liquid phase solidification temperature or lower at a cooling rate of 0.5 to 10 ° C./min, a step of holding the sintered body at a temperature of 1150 ° C. or higher and a liquid phase solidification temperature or lower for 10 minutes or more, It is essential to include. By satisfying such a cooling condition, it is possible to produce a cemented carbide exhibiting the above-mentioned property of formula (I), so that the cutting performance of the substrate is excellent and the dimensional accuracy can be increased.

  If the cooling rate exceeds 10 ° C./min, the crystal grains become finer and the desired alloy structure cannot be obtained, which is not preferable. If it is less than 0.5 ° C./min, the sintering time is long. Therefore, it is industrially disadvantageous, and the crystal grains grow vigorously, and the WC grain size and TaC grain size may become coarse, and the target alloy structure may not be obtained.

  In addition, regarding the above-mentioned “temperature of 1150 ° C. or higher and liquid phase solidification temperature or lower”, when the liquid phase solidification temperature is intentionally specified, it is preferably 1150 to 1320 ° C., more preferably 1200 to 1310 ° C. Moreover, when the temperature is specified in the same manner with respect to “the temperature of the liquid phase solidification temperature or more and 1350 ° C. or less”, it is preferably 1310 to 1350 ° C., more preferably 1320 to 1350 ° C.

  After the step of maintaining the temperature at 1150 ° C. or higher and the liquid phase solidification temperature or lower, it is necessary to cool to at least 1000 ° C. at a rate faster than 15 ° C./min. The cooling rate when cooling to 1000 ° C. is preferably a cooling rate of 50 ° C./min or more, more preferably a cooling rate of 100 ° C./min or more. A cooling rate of less than 15 ° C./min is not preferable because coarsening of WC particles occurs and an abnormal phase such as a TaC aggregate may occur.

<Coating>
The cutting edge-exchangeable cutting tip of the present invention preferably forms a film on the above base material. Such a film may be formed so as to cover the entire surface of the base material, or may be formed so as to cover only a part of the base material, but the purpose of the formation is to improve various characteristics of the cutting tool. In other words, it is preferable to cover at least a part of the portion that contributes to the improvement of the cutting performance even when the whole surface of the substrate is covered or a part thereof is covered.

  By covering the base material with the coating in this way, it has the effect of improving various characteristics such as wear resistance, oxidation resistance, toughness, and coloring for identifying the used blade edge portion of the cutting edge replaceable cutting tip. The composition is not particularly limited, and a conventionally known composition can be adopted.

  Each layer of such a coating consists of Group IVa elements (Ti, Zr, Hf, etc.), Group Va elements (V, Nb, Ta, etc.), Group VIa elements (Cr, Mo, W, etc.), Al, And at least one element selected from the group consisting of Si and Si, or at least one element selected from the group consisting of carbon, nitrogen, oxygen, and boron It is preferably constituted by a compound.

Examples of such elements or compounds include TiCN, TiN, TiCNO, TiO ₂ , TiNO, TiB ₂ , TiBN, TiSiN, TiSiCN, TiAlN, TiAlCrN, TiAlSiN, TiAlSiCrN, AlCrN, AlCrCN, AlCrVN, TiAlBN, TiBCN, TiAlBCN , TiSiBCN, AlN, AlCN, Al 2 O 3, ZrN, ZrCN, ZrN, ZrO 2, HfC, HfN, HfCN, NbC, NbCN, NbN, Mo 2 C, WC, W 2 C, Cr, Al, Ti, Si , V, etc. Further, the above element or compound may be doped with a small amount of other elements. In these compositions, each atomic ratio follows the above general formula. In the present invention, when the compound is represented by the chemical formula as described above, it is assumed that all the conventionally known atomic ratios are included unless the atomic ratio is particularly limited, and are not necessarily limited to those in the stoichiometric range. . For example, when simply describing “TiCN”, the atomic ratio of “Ti”, “C”, and “N” is not limited to 50:25:25, and also when “TiN” is described, “Ti” and “N” Is not limited to the case of 50:50, and any conventionally known atomic ratio is included. TiCN also includes MT-TiCN using a known CVD method.

  And it is especially preferable that at least one layer of such a coating has a compressive residual stress. Thereby, the extremely excellent effect that the toughness of the coating is remarkably improved and the propagation of cracks generated during the cutting process can be effectively prevented is shown. In this way, at least one layer of the coating has a compressive residual stress, and the coating includes a super multi-layer structure layer or a modulation structure layer, which will be described later, so that they act synergistically and have extremely high wear resistance and toughness. Both can be achieved.

  The coating film of the present invention can be formed by a conventionally known physical vapor deposition method, chemical vapor deposition method, vacuum vapor deposition method, sputtering method, plasma CVD method, etc., but is more preferably formed by chemical vapor deposition method or physical vapor deposition method. The physical vapor deposition method is more preferable in that it is easy to introduce compressive residual stress and can improve the cutting performance.

  As such a physical vapor deposition method, any conventionally known physical vapor deposition method can be adopted and is not particularly limited. Examples of such physical vapor deposition include magnetron sputtering, arc ion plating, holocathode, ion beam, electron beam, balanced magnetron sputtering, unbalanced magnetron sputtering, and dual magnetron sputtering. Can be mentioned.

  Among the methods exemplified above, it is particularly preferable to employ the arc type ion plating method. This is because compressive residual stress can be applied to the coating very effectively. In addition, it is preferable to employ | adopt the apparatus which provided each ion source used for the above methods as an apparatus which performs a physical vapor deposition method. It should be noted that even after the coating is formed, a part of the coating may be removed by brushing, barreling, blasting, diamond grindstone, laser processing, or the surface of the coating may be subjected to surface treatment such as smoothing processing. The effect is not lost. Moreover, you may give a compressive residual stress to a film using surface treatment methods, such as a dry shot blast process, a wet shot blast process, a brush process, a barrel process, and laser processing.

  Here, the compressive residual stress is a kind of internal stress (intrinsic strain) existing in such a film, and is represented by a numerical value “−” (minus) (unit: “GPa” is used in the present invention). Stress. For this reason, the concept that the compressive residual stress is large indicates that the absolute value of the numerical value is large, and the concept that the compressive residual stress is small indicates that the absolute value of the numerical value is small. Incidentally, the tensile residual stress is a kind of internal stress (intrinsic strain) existing in the film, and means a stress represented by a numerical value “+” (plus). Note that the term “residual stress” includes both compressive residual stress and tensile residual stress.

  The compressive residual stress is preferably a stress having an absolute value of 0.1 GPa or more, more preferably 0.2 GPa or more, and further preferably 0.5 GPa or more. If the absolute value is less than 0.1 GPa, sufficient toughness may not be obtained, and the above excellent effects may not be obtained. On the other hand, the larger the absolute value, the better from the viewpoint of imparting toughness. However, when the absolute value exceeds 6 GPa, the layer itself may be broken or peeled off.

Such compressive residual stress (residual stress) can be measured by the sin ² ψ method using an X-ray stress measurement apparatus. Such compressive residual stress is an arbitrary point (one point, preferably two points, more preferably three to five points, and even more preferably ten points) included in the layer to which the compressive residual stress in the chemical vapor deposition layer is applied. Each point when measuring at a plurality of points is preferably selected with a distance of 0.1 mm or more away from each other so that the stress of the layer can be represented))) by the sin ² ψ method, and the average It can be measured by determining the value.

The sin ² ψ method using X-rays is widely used as a method for measuring the residual stress of a polycrystalline material. For example, “X-ray stress measurement method” (Japan Society of Materials Science, 1981 Corporation) The method described in detail on pages 54 to 67 of Yokendo) may be used.

  The compressive residual stress can also be measured by using a method using Raman spectroscopy. Such Raman spectroscopy has the merit that local measurement can be performed in a narrow range, for example, a spot diameter of 1 μm. The measurement of residual stress using such Raman spectroscopy is common, but for example, "Thin film mechanical property evaluation technique" (Sipec (currently renamed Realize Science and Technology Center), published in 1992. ), Pages 264 to 271 can be employed.

  Furthermore, the compressive residual stress can also be measured using synchrotron radiation. In this case, there is a merit that the distribution of residual stress can be obtained in the thickness direction of the coating.

  In addition, it is preferable that the thickness of the film of the present invention (when formed with two or more layers, the total thickness) is 1 μm or more and 30 μm or less, and more preferably 2 μm or more and 20 μm or less. If the thickness is less than 1 μm, the effect of improving the wear resistance is not sufficiently exhibited. On the other hand, if the thickness exceeds 30 μm, no further improvement in various properties is observed, which is not economically advantageous. However, as long as economic efficiency is ignored, the thickness can be 30 μm or more, and the effect of the present invention is shown. As a method of measuring such a thickness, for example, a surface-coated cutting tool is cut, and a cross section thereof is measured by a scanning electron microscope (SEM) or a transmission electron microscope (TEM). To do. The composition of the coating film is measured by an energy dispersive X-ray spectrometer (EDS).

  And it is preferable that the film of this invention contains a super multilayer structure layer or a modulation | alteration structure layer. Hereinafter, these will be described.

<Super multilayer structure layer>
The super multi-layer structure layer of the present invention is composed of IVa group elements (Ti, Zr, Hf, etc.), Va group elements (V, Nb, Ta, etc.), VIa group elements (Cr, Mo, W, etc.), Al, etc. And at least one unit layer composed of a compound comprising at least one element selected from the group consisting of Si and at least one element selected from the group consisting of carbon, nitrogen, oxygen, and boron. , Each of which has a structure in which the layers are periodically and repeatedly stacked with a thickness of 0.2 nm to 20 nm.

  Here, the term “repetitively laminating” means having a certain periodicity, for example, when laminating two types of unit layers alternately up and down, or when laminating three types of unit layers repeatedly upper, middle, and lower. It means to laminate. If the thickness of each unit layer is less than 0.2 nm or exceeds 20 nm, the effect of improving the wear resistance by the super multi-layer structure layer may not be shown. The thickness of each unit layer can be appropriately adjusted depending on the composition constituting the unit layer and the film forming conditions. Each unit layer may have substantially the same thickness or may have a different thickness.

The unit layer is composed of at least one element selected from the group consisting of group IVa elements, group Va elements, group VIa elements, Al, and Si in the periodic table, and carbon, nitrogen, oxygen, and boron. Examples of the compound composed of at least one element selected from the group consisting of TiC, TiN, TiCN, TiNO, TiCNO, TiB ₂ , TiO ₂ , TiBN, TiBNO, TiCBN, ZrC, ZrO ₂ , HfC, HfN, TiAlN , TiAlCrN, TiZrN, TiCrN, AlCrN , CrN, VN, TiSiN, TiSiCN, AlTiCrN, TiAlCN, ZrCN, ZrCNO, Al 2 O 3, AlN, AlCN, ZrN, TiAlC, NbC, NbN, NbCN, Mo 2 C, WC, W ₂ C and the like can be mentioned.

  The number of unit layers constituting the super multi-layer structure layer (total number of layers) is not particularly limited, but is usually preferably 10 or more and 5000 or less. If it is less than 10 layers, the crystal grains in each unit layer are coarsened, so that the hardness of the coating may be reduced. If it exceeds 5000 layers, each unit layer becomes too thin and tends to be mixed. is there.

  Such a super multi-layer structure layer is formed by a conventionally known physical vapor deposition method, and its manufacturing method is not particularly limited. Hereinafter, the case where the arc ion plating method is employed as the physical vapor deposition method will be exemplified.

  First, in the arc ion plating film forming apparatus, targets are set in a plurality of evaporation sources corresponding to the types of unit layers to be formed. Then, the substrate is set in the substrate holder in the chamber of the apparatus, and the target of the evaporation source is evaporated and ionized while rotating the substrate holder so as to face the evaporation source. Form. An example of more specific conditions is as follows.

  That is, the base material is heated by a heater installed in the chamber. Thereafter, the substrate surface is cleaned with argon ions for 1 to 120 minutes by introducing a bias voltage to the substrate while introducing argon gas and maintaining the pressure in the chamber at 1 to 10 Pa.

  Subsequently, after the argon gas in the chamber is exhausted, the reaction gas is introduced, and while maintaining the pressure in the chamber at 2 to 10 Pa, the substrate holder on which the substrate is set is rotated while the bias voltage ( -20 to -200 V) is applied, and the target set in the evaporation source is ionized, and the unit layers are sequentially stacked to form a super multi-layer structure layer.

<Modulation structure layer>
The modulation structure layer of the present invention includes at least one element selected from the group consisting of group IVa elements, group Va elements, group VIa elements, Al, and Si in the periodic table, and carbon, nitrogen, oxygen, and boron. It is comprised by the compound which consists of at least 1 sort (s) of elements chosen from the group which consists of, and the composition or composition ratio of the compound has a structure which changes with a period of 0.2 nm or more and 40 nm or less in the thickness direction. By forming the modulation structure layer as a coating in this way, extremely excellent wear resistance can be imparted in combination with the formation of the super multi-layer structure layer.

  Here, the change in the composition or composition ratio of the compound in the thickness direction with a period of 0.2 nm or more and 40 nm or less means that, for example, the states of A and B types having the same constituent elements but different composition ratios are modulated. In the thickness direction from the base material side to the surface side of the structural layer, first, what was in state A at point X changes gradually to state B at point Y, then gradually changes again to state A at point Z. , The distance between the points X and Z becomes a period (from 0.2 nm to 40 nm) (in this case, the point Y is located at a substantially middle point between the points X and Z), and such a state AB- It means that the change of A is repeated in the same cycle. If the period is less than 0.2 nm or exceeds 40 nm, the effect of improving the wear resistance by the modulation structure layer may not be shown. A more preferable range of the period has an upper limit of 35 nm or less, more preferably 30 nm or less, and a lower limit of 0.5 nm or more, more preferably 1 nm or more.

  At least one element selected from the group consisting of Group IVa element, Group Va element, Group VIa element, Al, and Si of the periodic table constituting such a modulation structure layer, and carbon, nitrogen, oxygen, and boron Examples of the compound composed of at least one element selected from the group consisting of include the same compounds as those exemplified in the super multi-layer structure layer.

  Such a modulation structure layer can be formed by a manufacturing method similar to the manufacturing method of the super multi-layer structure layer described above, and particularly in the case of a modulation structure layer having a structure in which the composition ratio changes in the thickness direction. They can be formed by setting targets with different composition ratios in the evaporation source and controlling the number of rotations of the substrate holder.

  In addition, when the composition changes in the thickness direction, there may be no clear difference between the modulation structure layer and the super multi-layer structure layer, but it is not necessary to clearly distinguish such a difference. These do not depart from the scope of the present invention.

<Evaluation of dimensional accuracy>
As a method for verifying the dimensional accuracy of the blade-tip-exchange-type cutting tip, for example, the blade-tip-exchange-type cutting tip may be measured with a measuring instrument such as a general-purpose micrometer, or a non-contact method using a laser. The shape may be measured by Also, prepare a plurality (for example, 100) of cutting edge-exchangeable cutting tips, attach them to a chip holder (for example, a cutting tool for turning applications, a cutter for milling applications), measure the cutting edge position, and then replace the cutting edge. The cutting edge may be removed and the position of the cutting edge measured several times to verify the variation in the cutting edge position, or the blade runout accuracy is measured by attaching multiple cutting edge replacement cutting tips to a cutter that uses multiple chips simultaneously. The blade runout accuracy may be used by repeating this, or any other method may be used.

  EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated in detail, this invention is not limited to these.

<Example 1>
In the present embodiment, the blade tip replaceable cutting tip No. 101 was produced. WC particles having an average particle diameter of 1.3 μm so that the mass ratio of the base material is 86.74% by mass of WC, 2% by mass of TaC, 0.26% by mass of Cr, and 11% by mass of Co. If, it was blended and TaC powder, a Cr ₃ C ₂ powder, a Co powder. And after granulating and mixing for 7 hours with an attritor in an ethanol solvent, granulated powder was prepared by granulating and drying. In addition, two types of granulated powder (high carbon content and low carbon content) in which the amount of carbon added during blending was changed were prepared. The cutting edge exchange type cutting tip No. No. 101 has a low carbon content, and has a cutting edge exchange type cutting tip No. 101. In 102, a high carbon content was used.

  Next, the obtained granulated powder was press-molded and held at 1380 ° C. for 1 hour in an argon atmosphere of 2 kPa. Thereafter, it is cooled to 1280 ° C. at a rate of −2.5 ° C./min, held at 1280 ° C. for 30 minutes, and finally Ar gas is introduced into the furnace to at least 1000 ° C. at a rate of −100 ° C./min. Cooling was performed.

  Then, by performing SiC brush honing on the edge of the cutting edge, cutting edge processing for imparting a radius (R) having a radius of about 0.05 mm was performed on the intersection of the rake face and the flank face. And the flat grinding | polishing process was performed with respect to the bottom face of a blade-tip-exchange-type cutting tip. As described above, the blade tip replaceable cutting tip No. having the shape of SEMT13T3AGSN-G (manufactured by Sumitomo Electric Industries, Ltd.) is used. 101 substrates were produced.

By forming a coating film having a 3 μm super multi-layer structure layer and a 0.5 μm TiSiCN layer on the base material thus produced by using a known ion plating method, a blade-tip-exchangeable cutting tip is formed. No. 101 was produced. The super multi-layer structure layer was formed by alternately laminating an AlTiSiN layer having a thickness of 8 nm and a TiSiN layer having a thickness of 6 nm. When the compressive residual stress of the coating film thus formed was measured by the sin ² ψ method using an X-ray stress measuring device, it was confirmed that the absolute value of the compressive stress was 0.1 GPa or more. In order to evaluate the dimensional accuracy of the produced cutting edge exchangeable cutting tip, the side surface of the cutting edge exchangeable cutting tip was not polished.

  The above-mentioned blade edge exchange type cutting tip No. Except that the carbon blending amount was increased with respect to 101, the blade tip replaceable cutting tip No. In the same manner as in No. 101, the cutting edge replaceable cutting tip No. 102 was produced. In cemented carbide, generally, the saturation magnetic flux density 4πσ tends to increase and the coercive force HC tends to decrease by increasing the amount of carbon.

  In addition, the above-mentioned blade edge replaceable cutting tip No. 101, except that the sintering conditions were changed as follows. In the same manner as in No. 101, the cutting edge replaceable cutting tip No. 103 was produced. That is, the cutting edge exchange type cutting tip No. In No. 103, after press molding, it was held at 1380 ° C. for 1 hour in an argon atmosphere of 2 kPa, then cooled to 1330 ° C. at a rate of −2.5 ° C./min, held at 1330 ° C. for 30 minutes, and further − Cool to 1280 ° C at a rate of 2.5 ° C / min, hold at 1280 ° C for 30 minutes, and finally introduce Ar gas into the furnace and cool to at least 1000 ° C at a rate of -100 ° C / min. I did it.

  The above-mentioned blade edge exchange type cutting tip No. 103, except that the carbon blending amount was increased. In the same manner as in No. 103, the cutting edge exchange type cutting tip No. 104 was produced.

  In addition, the above-mentioned blade edge replaceable cutting tip No. 101, except that the sintering conditions were changed as follows. In the same manner as in No. 101, the cutting edge replaceable cutting tip No. 105 was produced. That is, the cutting edge exchange type cutting tip No. No. 105 was held at 1380 ° C. for 1 hour in an argon atmosphere of 2 kPa after press molding. Thereafter, Ar gas was introduced into the furnace and cooled to at least 1000 ° C. at a rate of −100 ° C./min.

  The above-mentioned blade edge exchange type cutting tip No. 105, except that the carbon blending amount was increased. In the same manner as in No. 105, the cutting edge replaceable cutting tip No. 106 was produced.

  The cutting edge replacement type cutting tip No. manufactured as described above was used. 101 to 106 were cut and the cut surface was mirror-polished, and then the surface was etched with Murakami reagent. Thirty photographs were taken on the etched surface with a FE-SEM at a magnification of 1500 times. According to the photograph, it was confirmed that a single phase mainly composed of Ta was present in the metal structure. Moreover, the average particle diameter of the phase which has WC particle | grains and Ta as a main component was measured by CIS019D-2005. The results are shown in the “WC” and “Ta phase” columns of “Average particle size” in Table 1. The WC particles having an average particle diameter of 1.3 μm are used as the raw material, but the average particle diameter is reduced by pulverization or grain growth by sintering to “WC” in Table 1. It becomes the average particle diameter shown.

Further, the saturation magnetic flux density (10 ⁻⁷ Tm ³ / kg) of the base material produced as described above was measured, and the result is shown in the column of “4πσ” in Table 1. The upper limit (HC upper limit) of the coercive force of the substrate was calculated by substituting each value thus obtained into the following formula (I). On the other hand, the coercive force of the substrate is shown in the column “HC” in Table 1.
−0.7 × 4πσ ÷ M _Co −0.9 × M _Co + 39.15 ≧ HC (I).

  As is apparent from the evaluation results shown in Table 1, the cutting edge replacement type cutting tip No. 101-104 was what the coercive force of the cemented carbide of a base material is less than the HC upper limit calculated by Formula (I). On the other hand, the cutting edge replacement type cutting tip No. In Nos. 105 and 106, the coercive force of the cemented carbide of the base material exceeded the upper limit of HC calculated by the formula (I).

(Performance evaluation)
The cutting edge replacement type cutting tip No. 1 of Example 1 was used. The following dimensional accuracy evaluation and cutting performance evaluation were performed for 101 to 106. Evaluation of dimensional accuracy was performed by attaching a plurality of blade-tip-exchangeable cutting tips to a cutter (a blade-tip-exchangeable cutting tip holder) and evaluating blade runout. The evaluation results are shown in Table 2 below.

(1) Evaluation of dimensional accuracy The cutting edge replacement type cutting tip No. Dimensional accuracy evaluation was performed using 101-106. First, the cutting edge exchange type cutting tip No. 50 pieces of 101 to 106 were prepared, and 7 cutting edge-exchangeable cutting tips were selected from them, and they were attached to a cutter of model number WGC4160R (manufactured by Sumitomo Electric Industries, Ltd.) having 7 pockets. The pocket for attaching the cutting edge-exchangeable cutting tip to the cutter is No. 1-No. No. 7 is determined. No. 1 on the basis of the position (blade height) of the blade-tip-exchangeable cutting tip attached to the pocket 1. 2-No. The difference in height from the position of the blade-tip-exchangeable cutting tip attached to the 7 pocket was defined as the blade runout width, and the maximum value and the average value were calculated.

  The maximum value and average value of the blade runout width of the cutting edge replacement type cutting tip were measured 10 times by the same method as above, and the maximum value of the height difference was shown in the “Maximum” column of “Dimensional accuracy evaluation” in Table 2. The average value of the height difference is shown in the “average” column of Table 2. In addition, it shows that the dimensional accuracy of a blade-tip-exchange-type cutting tip is higher as the blade runout width is smaller. By the higher dimensional accuracy, the surface roughness is lowered and the surface gloss of the work material is also improved.

  Incidentally, the operation of attaching to each of the seven pockets of the cutter, measuring the position of the blade-tip-exchangeable cutting tip using a master tip for inspection with extremely high dimensional accuracy, and then removing it was repeated seven times. The blade runout width calculated by these seven measurements was 2 μm or less. From this, the influence of blade runout between the pockets of the cutter can be regarded as 2 μm or less.

  Next, using seven inspection master tips with extremely high dimensional accuracy, each was attached to the seven pockets of the cutter used for dimensional accuracy evaluation, and the position and blade runout width of the blade tip replaceable cutting tip were calculated. The blade runout width was 4 μm or less. From this, when the blade tip replacement type cutting tip having substantially the same dimensions is attached to each of the cutter pockets, the influence of the blade runout of the blade tip replacement type cutting tip can be regarded as 4 μm or less.

(2) Cutting performance evaluation (Abrasion resistance test: High-speed milling of steel)
One of the cutting edge-exchangeable cutting tips produced above was set on a cutter of model number WGC4160R (manufactured by Sumitomo Electric Industries, Ltd.), and a high-speed milling test of steel was performed using this. This performance evaluation differs from the dimensional accuracy evaluation described above in that only one blade-tip-exchangeable cutting tip is attached to the cutter instead of seven blade-tip-exchangeable cutting tips. The conditions for high-speed milling were as follows: SCM435 block material (300 mm × 100 mm) was used as the work material, cutting speed = 310 m / min, feed = 0.28 mm / tooth, depth of cut = 1. Cutting was performed for 12 minutes without 5 mm, center cut, and cutting oil. After cutting in this manner, the flank wear amount (V _B ) of the blade-tip-exchangeable cutting tip was measured using a comparator. The results are shown in the column “Steel” of “Abrasion resistance test” in Table 2. In addition, it has shown that it is excellent in abrasion resistance, so that there is little wear width.

(3) Cutting performance evaluation (Abrasion resistance test: Milling of die steel)
One of the cutting edge-exchangeable cutting tips produced above was set on a cutter of model number WGC4160R (manufactured by Sumitomo Electric Industries, Ltd.), and a milling test of die steel was performed using this. This performance evaluation was also performed by attaching only one blade-tip-exchangeable cutting tip to the cutter, as in the high-speed milling of the steel. The milling conditions were as follows: SKD11 raw material block material (300 mm × 100 mm) was used as the work material. Cutting speed = 170 m / min, feed = 0.31 mm / blade, cutting depth ap = Cutting was performed with 3.0 mm, ae = 30 mm, center cut, and water-soluble oil for 5 minutes. After cutting in this manner, the flank wear amount (V _B ) of the blade-tip-exchangeable cutting tip was measured using a comparator. The results are shown in the “Die” column of “Abrasion resistance test” in Table 2. In addition, it has shown that it is excellent in abrasion resistance, so that there is little wear width.

(4) Cutting performance evaluation (toughness test: intermittent cutting of steel)
Seven of the cutting edge-exchangeable cutting tips produced above were set in seven pockets of a cutter of model number WGC4160R (manufactured by Sumitomo Electric Industries, Ltd.), and steel was used for intermittent cutting. This performance evaluation was performed under the condition that the blade runout of the above seven blade-tip-exchangeable cutting tips was within ± 3 μm of the average value of the blade runout. The conditions for the intermittent cutting of steel are as follows: S50C φ10 perforated material block material (300 mm × 100 mm) is used. Cutting speed = 180 m / min, feed = 0.45 mm / tooth Cutting was performed for 2 minutes without a cutting depth of 2.0 mm, a center cut, and no cutting oil. Intermittent cutting was performed four times under these conditions, and the ratio of the cutting edge replaceable cutting tips out of the total 28 cutting edge replaceable cutting tips was calculated as the failure rate (%). The results are shown in the column “Damage rate (%)” in Table 2. The lower the breakage rate, the better the cutting edge strength.

(5) Cutting performance evaluation (workpiece surface test)
Seven of the blade edge-exchangeable cutting tips produced above were set in seven pockets of a cutter of model number WGC4160R (manufactured by Sumitomo Electric Industries, Ltd.), and carbon steel was cut using this. This performance evaluation was performed under the condition that the blade runout of the above seven blade-tip-exchangeable cutting tips was within ± 3 μm of the average value of the blade runout. The cutting conditions of the carbon steel were S15C block material (300 mm × 100 mm) as a work material, and the cutting speed = 175 m / min, feed = 0.3 mm / tooth, cutting depth 1 for this work material. .5 mm, center cut, 1 pass without cutting oil. The surface roughness (Ra) of the processed surface of the work material cut in this way was measured by the method defined in JIS B 0601-1994, and the result is shown in the column of “Surface roughness Ra” in Table 2. . The smaller the surface roughness value, the smoother the processed surface and the better the dimensional accuracy. Further, visual evaluation of the processed surface of the work material processed in this way was performed, and the result is shown in the column “Gloss of processed surface” in Table 2.

  As is apparent from the results shown in Table 2, the cutting edge replacement type cutting tip No. 101-104 are blade-tip-exchangeable cutting tip Nos. Compared to 105-106, the dimensional accuracy and cutting performance are significantly improved. This is a cutting edge replacement type cutting tip No. 101 to 104 satisfy the condition of the formula (I), whereas the blade tip replaceable cutting tip No. It is considered that 105 and 106 do not satisfy the condition of the formula (I).

<Example 2>
In the present embodiment, the blade tip replaceable cutting tip No. 201 was produced. WC particles with an average particle diameter of 1.5 μm so that the composition ratio is WC of 89.27% by mass, 2% by mass of TaC, 0.23% by mass of Cr, and 8.5% by mass of Co. TaC powder, Cr ₃ C ₂ powder, and Co powder were blended. And after granulating and mixing for 7 hours with an attritor in an ethanol solvent, granulated powder was prepared by granulating and drying. In addition, two types of granulated powder (high carbon content and low carbon content) in which the amount of carbon added during blending was changed were prepared.

  Next, after the obtained granulated powder was press-molded, it was held at 1380 ° C. for 1 hour in an argon atmosphere of 2 kPa, and then cooled to 1330 ° C. at a rate of −2.5 ° C./min. Hold for 30 minutes, further cool to 1280 ° C. at a rate of −2.5 ° C./min, hold at 1280 ° C. for 30 minutes, and finally introduce Ar gas into the furnace at a rate of −100 ° C./min And cooled to at least 1000 ° C. Then, by performing SiC brush honing on the edge of the cutting edge, the cutting edge processing for imparting a radius (R) having a radius of about 0.05 mm to the intersection of the rake face and the flank face is performed. A flat polishing process was performed on the bottom surface. As described above, a base material of a blade tip exchangeable cutting tip having a shape of SOMT120408PDER-G (manufactured by Sumitomo Electric Industries, Ltd.) was produced. A coating film was formed on the substrate by the same method as in Example 1.

  The above-mentioned blade edge exchange type cutting tip No. 201, except that the mass ratio of TaC, Cr, Co, and WC was changed as shown in Table 3 below. In the same manner as in 201, the cutting edge replaceable cutting tip No. 203, 205, 207, and 209 to 217 were produced.

  In addition, the above-mentioned blade edge replaceable cutting tip No. 201, 203, 205, and 207, except that the amount of carbon added is different, except that the cutting edge replacement type cutting tip No. In the same manner as in 201, 203, 205, and 207, the cutting edge replacement type cutting tip No. 202, 204, 206, 208 were produced.

  The cutting edge replacement type cutting tip No. manufactured as described above was used. The cemented carbides 201 to 217 were cut along a plane parallel to the pressing direction when pressure-molded, and the cut surface was mirror-polished with a # 250 grindstone, and then the surface was etched with Murakami reagent. Thirty photographs were taken on the etched surface with a FE-SEM at a magnification of 1500 times. According to the photograph, it was confirmed that a single phase mainly composed of Ta was present in the metal structure. Moreover, the average particle diameter of the phase which has WC particle | grains and Ta as a main component was measured by the method described in CIS019D-2005 using the said photograph. The results are shown in the “WC” and “Ta phase” columns of “Average particle diameter” in Table 3.

The saturation magnetic flux density (10 ⁻⁷ Tm ³ / kg) of the substrate produced as described above was measured, and the result is shown in the column of “4πσ” in Table 3. The upper limit (HC upper limit) of the coercive force of the substrate was calculated by substituting each value thus obtained into the following formula (I). On the other hand, the coercive force of the substrate was measured and shown in the column of “HC” in Table 3.
−0.7 × 4πσ ÷ M _Co −0.9 × M _Co + 39.15 ≧ HC (I).

  As is apparent from the evaluation results shown in Table 3, the cutting edge replacement type cutting tip No. In 201-215, 217, the coercive force of the cemented carbide of the base material was lower than the upper limit of HC calculated by the formula (I). On the other hand, the cutting edge replacement type cutting tip No. In 216, the coercive force of the base cemented carbide exceeded the HC upper limit calculated by the formula (I).

(Performance evaluation)
The cutting edge replacement type cutting tip No. 2 of Example 2 produced as described above was used. 201-No. For 217, the following dimensional accuracy evaluation and cutting performance evaluation were performed. The evaluation results are shown in Table 4 below.

(1) Dimensional accuracy evaluation Dimensional accuracy evaluation was performed using the cutting edge exchangeable cutting tip produced above. First, 50 cutting edge-replaceable cutting tips are prepared, and 5 cutting edge-replaceable cutting chips are selected from them, and they are all used as a cutter of model number WFX12100R (manufactured by Sumitomo Electric Industries, Ltd.) having five pockets. Attached. The pocket for attaching the cutting edge-exchangeable cutting tip to the cutter is No. 1-No. No. 5 is determined. No. 1 on the basis of the position (blade height) of the blade-tip-exchangeable cutting tip attached to the pocket 1. 2-No. The difference in height from the position of the blade-tip-exchangeable cutting tip attached to the pocket 5 was defined as the blade run width, and the maximum value and the average value were calculated. The maximum value and average value of the blade runout width of the blade-tip-exchangeable cutting tip were measured 10 times by the same method as described above, and the maximum value of the height difference was shown in the “Maximum” column of Table 4. The average value of the height difference Is shown in the “average” column of Table 4.

  Incidentally, the operation of attaching to each of the seven pockets of the cutter, measuring the position of the blade-tip-exchangeable cutting tip using a master tip for inspection with extremely high dimensional accuracy, and then removing it was repeated seven times. The blade runout width calculated by these seven measurements was 2 μm or less. From this, the influence of blade runout between the pockets of the cutter can be regarded as 2 μm or less.

  Next, using seven inspection master tips with extremely high dimensional accuracy, each was attached to the seven pockets of the cutter used for dimensional accuracy evaluation, and the position and blade runout width of the blade tip replaceable cutting tip were calculated. The blade runout width was 4 μm or less. From this, when the blade tip replacement type cutting tip having substantially the same dimensions is attached to each of the cutter pockets, the influence of the blade runout of the blade tip replacement type cutting tip can be regarded as 4 μm or less.

(2) Cutting performance evaluation (Abrasion resistance test: High-speed milling of steel)
One of the blade-tip-exchangeable cutting tips produced above was set on a cutter of model number WFX12100R (manufactured by Sumitomo Electric Industries, Ltd.), and a high-speed milling test of steel was performed using this. This performance evaluation differs from the dimensional accuracy evaluation described above in that only one cutting edge replacement type cutting tip is attached to the cutter instead of five cutting edge replacement type cutting chips. The conditions for high-speed milling are SCM440 block material (300 mm × 200 mm) as the work material, cutting speed = 220 m / min, feed = 0.15 mm / tooth, cutting depth ap = 5. Cutting was performed for 10 minutes without cutting oil at 0.0 mm, ae = 30 mm.

After cutting in this manner, the flank wear amount (V _B ) of the cutting edge replaceable cutting tip was measured using a comparator, and the result was shown as “Steel” in “Abrasion resistance test” in Table 4. It is shown in the column. In addition, it has shown that it is excellent in abrasion resistance, so that there is little wear width.

(3) Cutting performance evaluation (Abrasion resistance test: Milling of die steel)
One of the cutting edge-exchangeable cutting tips produced above was set on a cutter of model number WFX12100R (manufactured by Sumitomo Electric Industries, Ltd.), and a milling test of die steel was performed using this. This performance evaluation was also performed by attaching only one blade-tip-exchangeable cutting tip to the cutter, as in the high-speed milling of the steel. The conditions for milling are as follows: SKD11 raw material block material (300 mm × 200 mm) is used as the work material. Cutting speed = 160 m / min, feed = 0.15 mm / tooth, cutting depth ap = Cutting was performed for 10 minutes without 5.0 mm, ae = 30 mm, and cutting oil. After cutting in this manner, the flank wear amount (V _B ) of the blade-tip-exchangeable cutting tip was measured using a comparator. The results are shown in the “Die” column of “Abrasion resistance test” in Table 4. In addition, it has shown that it is excellent in abrasion resistance, so that there is little wear width.

(4) Cutting performance evaluation (toughness test: intermittent cutting of steel)
Five of the cutting edge exchangeable cutting tips produced above were set in five pockets of a cutter of model number WFX12100R (manufactured by Sumitomo Electric Industries, Ltd.), and steel was used for intermittent cutting. This performance evaluation was performed under the condition that the blade runout of the five cutting edge-replaceable cutting tips was within ± 3 μm of the average value of the blade runout. The conditions for the intermittent cutting of steel are as follows: S50C φ10 perforated material block material (300 mm × 200 mm) is used. Cutting speed = 200 m / min, feed = 0.40 mm / tooth The cutting amount was ap = 5.0 mm, ae = 50 mm, and cutting was performed for 2 minutes without cutting oil. Intermittent cutting was performed four times under these conditions, and the ratio of the cutting edge-replaceable cutting tips out of the total 20 cutting-edge replacement cutting tips was calculated as the failure rate (%). The results are shown in the column “Damage rate (%)” in Table 4. The lower the breakage rate, the better the cutting edge strength.

(5) Cutting performance evaluation (workpiece surface test)
Five of the cutting edge-exchangeable cutting tips produced above were set in five pockets of a cutter of model number WFX12100R (manufactured by Sumitomo Electric Industries, Ltd.), and die steel was cut using this. This performance evaluation was performed under the condition that the blade runout of the five cutting edge-replaceable cutting tips was within ± 3 μm of the average value of the blade runout. The cutting conditions of the die steel were as follows: SKD11 block material (300 mm x 400 mm) was used as the work material, cutting speed = 200 m / min, feed = 0.15 mm / blade, no cutting oil Then, the cutting amount ap = 8.0 mm and ae = 20 mm were performed for 3 passes. The surface roughness (Ra) of the machined surface of the workpiece cut in this way was measured by the method defined in JIS B 0601-1994, and the result is shown in the column of “Surface roughness Ra” in Table 4. . The smaller the surface roughness value, the smoother the processed surface and the better the dimensional accuracy. Further, visual evaluation of the processed surface of the work material processed in this way was performed, and the result is shown in the column “Gloss of processed surface” in Table 4.

  As is apparent from the results shown in Table 4, the cutting edge exchange type cutting tip No. Nos. 201 to 213 are cutting edge exchange type cutting tip Nos. Compared with 214 to 217, the dimensional accuracy and cutting performance are remarkably improved. This is a cutting edge replacement type cutting tip No. Whereas 201 to 213 satisfy the condition of the formula (I) and the average particle diameter of the WC particles and the average particle diameter of the phase mainly composed of Ta satisfy the predetermined numerical range, the cutting edge exchange type cutting Chip No. The cemented carbide of 214 has an average particle size of a phase containing Ta as a main component of less than 0.4 μm. In the cemented carbide of 215, the blending amount of the phase containing Ta as a main component exceeds 0.55% by mass. 216 does not satisfy the condition of the formula (I). The 217 cemented carbide is thought to be due to the fact that the average particle size of the WC particles exceeded 3 μm.

<Example 3>
In this example, the cutting edge replacement type cutting tip No. 1 of Example 1 was used. A coating was formed on the substrate using chemical vapor deposition (CVD) or physical vapor deposition (PVD) on a substrate prepared by the same method except that the carbon content of 101 was different. . When the average particle size of WC particles and the average particle size of TaC were measured by the same method as in Example 1, they were 1.14 μm and 0.83 μm, respectively.

The saturation magnetic flux density (10 ⁻⁷ Tm ³ / kg) of the substrate was measured and found to be 182 (10 ⁻⁷ Tm ³ / kg). The upper limit (HC upper limit) of the coercive force of the base material was calculated by substituting each value thus obtained into the following formula (I). As a result, 18.17 (10 ⁻⁷ Tm ³ / kg) was calculated. Met. On the other hand, when the coercive force of the substrate was measured, HC was 16.09. Cutting edge exchange type cutting tip No. In 302-303, a film is formed using the CVD method, and the cutting edge exchange type cutting tip No. In 304-309, the film was formed using the PVD method. The compressive residual stress of the film thus formed was measured by the sin ² ψ method using an X-ray stress measuring apparatus, and it was 0.1 GPa or more, and the coating layer formed by the CVD method had a tensile residual stress. It was confirmed that it occurred.

(Performance evaluation)
The cutting edge replacement type cutting tip No. 301-No. The following cutting performance evaluation was performed for 309. The evaluation results are shown in Table 6. In this example, in order to evaluate the performance of the film, the dimensional accuracy evaluation and the work material processed surface test were not performed.

(1) Cutting performance evaluation (Abrasion resistance test: High-speed milling of steel)
One of the cutting edge-exchangeable cutting tips produced above was set on a cutter of model number WGC4160R (manufactured by Sumitomo Electric Industries, Ltd.), and a high-speed milling test of steel was performed using this. This performance evaluation was performed by attaching only one blade-tip-exchangeable cutting tip to the cutter. The conditions for high-speed milling are as follows: SCM440 block material (300 mm × 100 mm) is used as the work material. Cutting speed = 320 m / min, feed = 0.28 mm / tooth, cutting depth 1.5 mm for this work material. , Center cutting, and water-soluble oil for 10 minutes. After cutting in this manner, the flank wear amount (V _B ) of the blade-tip-exchangeable cutting tip was measured using a comparator. The results are shown in the column “Steel” of “Abrasion resistance test” in Table 6. In addition, it has shown that it is excellent in abrasion resistance, so that there is little wear width.

(2) Cutting performance evaluation (Abrasion resistance test: Milling of die steel)
One of the cutting edge-exchangeable cutting tips produced above was set on a cutter of model number WGC4160R (manufactured by Sumitomo Electric Industries, Ltd.), and a milling test of die steel was performed using this. This performance evaluation was also performed by attaching only one blade-tip-exchangeable cutting tip to the cutter, as in the high-speed milling of the steel. The milling conditions were as follows: SKD11 raw material block material (300 mm × 100 mm) was used as the work material, cutting speed = 185 m / min, feed = 0.30 mm / tooth, cutting depth ap = Cutting was performed for 3 minutes without 2.0 mm, ae = 40 mm, center cut, and cutting oil. After cutting in this manner, the flank wear amount (V _B ) of the blade-tip-exchangeable cutting tip was measured using a comparator. The results are shown in the “Die” column of “Abrasion resistance test” in Table 6. In addition, it has shown that it is excellent in abrasion resistance, so that there is little wear width.

(3) Cutting performance evaluation (toughness test: intermittent cutting of steel)
One of the cutting edge-exchangeable cutting tips produced above was set on a cutter of model number WGC4160R (manufactured by Sumitomo Electric Industries, Ltd.), and intermittent cutting of steel was performed using this. The conditions for the intermittent cutting of steel were S45C φ10 perforated block material (300 mm × 100 mm) as the work material, cutting speed = 170 m / min, feed = 0.50 mm / tooth for this work material. Cutting was performed for 3 minutes without a cutting depth of 2.0 mm, a center cut, and no cutting oil. The intermittent cutting process was performed 20 times under these conditions, and the ratio of the cutting edge-replaceable cutting tips out of the total 20 cutting-edge replacement cutting chips was calculated as a failure rate (%). The results are shown in the column “Damage rate (%)” in Table 6. The lower the breakage rate, the better the cutting edge strength. The cutting edge replacement type cutting tip No. The blade runouts 301 to 309 were 27 μm at the maximum and 23 μm on average.

  As is apparent from the results shown in Table 6, the cutting edge replacement type cutting tip No. In 301 to 309, dimensional accuracy and cutting performance are remarkably improved. This is a cutting edge replacement type cutting tip No. It is considered that 301 to 309 satisfy the condition of the formula (I).

  Although the embodiments and examples of the present invention have been described as described above, it is also planned from the beginning to appropriately combine the configurations of the above-described embodiments and examples.

  It should be understood that the embodiments and examples disclosed herein are illustrative and non-restrictive in every respect. The scope of the present invention is defined by the terms of the claims, rather than the description above, and is intended to include any modifications within the scope and meaning equivalent to the terms of the claims.

Claims (9)

A cutting edge exchangeable cutting tip including at least a base material,
The base material includes 8.5 to 12.5% by mass of Co , 0.55 to 2.3% by mass of TaC, 0.2 to 0.55% by mass of Cr, and unavoidable impurities. The balance is made of a cemented carbide with WC, or 11.0% by mass of Co, 2.0% by mass of TaC, and an inevitable impurity, and the balance is made of a cemented carbide with WC.
The WC particles in the cemented carbide structure have an average particle size of 0.8 to 3 μm,
When the coercive force of the substrate is HC (kA / m), the saturation magnetic flux density is 4πσ (10 ⁻⁷ Tm ³ / kg), and the mass% of Co contained in the substrate is M _Co (mass%). , Satisfying the following formula (I), and a phase mainly composed of Ta is precipitated in the structure of the cemented carbide,
The phase having Ta as a main component is a blade-tip-exchangeable cutting tip having an average particle diameter of 0.4 to 2.4 μm.
−0.7 × 4πσ ÷ M _Co −0.9 × M _Co + 39.15 ≧ HC (I) The cutting edge exchange type cutting tip comprises the base material and a coating formed on the base material,
The coating is composed of at least one element selected from the group consisting of group IVa element, group Va element, group VIa element, Al, and Si in the periodic table, or the element, and carbon, nitrogen, oxygen, and boron. The blade tip replaceable cutting tip according to claim 1, comprising one or more layers made of a compound with at least one element selected from the group. The blade tip replaceable cutting tip according to claim 2 , wherein the coating is formed by physical vapor deposition and / or chemical vapor deposition. The coating is formed by physical vapor deposition, and includes a super multi-layer structure layer or a modulation structure layer,
The super multi-layer structure layer includes at least one element selected from the group consisting of group IVa elements, group Va elements, group VIa elements, Al, and Si in the periodic table, and carbon, nitrogen, oxygen, and boron. Two or more types of unit layers composed of a compound composed of at least one element selected from the group have a structure in which each layer is periodically and repeatedly laminated with a thickness of 0.2 nm or more and 20 nm or less,
The modulation structure layer includes at least one element selected from the group consisting of group IVa element, group Va element, group VIa element, Al, and Si in the periodic table, and a group consisting of carbon, nitrogen, oxygen, and boron. 4. The composition according to claim 2 , comprising a compound composed of at least one element selected from the above, wherein the composition or composition ratio of the compound changes in a cycle of 0.2 nm to 40 nm in the thickness direction. Cutting edge exchangeable cutting tip. The blade tip replaceable cutting tip according to any one of claims 2 to 4 , wherein the coating is provided with a compressive residual stress of 0.1 GPa or more. The indexable cutting insert is used milling, indexable insert according to any one of claims 1-5. The cutting method which performs a cutting process simultaneously using two or more blade-tip-exchange-type cutting tips in any one of Claims 1-6 . A method of manufacturing a cutting edge-exchangeable cutting tip including at least a base material,
The base material includes 8.5 to 12.5% by mass of Co, 0.55 to 2.3% by mass of TaC, 0.2 to 0.55% by mass of Cr, and unavoidable impurities. The balance is made of a cemented carbide with WC, or 11.0% by mass of Co, 2.0% by mass of TaC, and inevitable impurities, and the balance is made of a cemented carbide with WC. Producing a raw material powder of the substrate ;
Forming the molded body by molding the raw material powder; and
Maintaining the molded body at 1350-1500 ° C. to produce a sintered body;
Cooling the sintered body at a cooling rate of 0.5 to 10 ° C./min to a temperature not lower than 1150 ° C. and not higher than the liquid phase solidification temperature;
Holding the sintered body at a temperature of 1150 ° C. or higher and a liquid phase solidification temperature or lower for 10 minutes or more;
And a step of cooling the sintered body at a cooling rate of 15 ° C./min or higher in this order. A method of manufacturing a cutting edge-exchangeable cutting tip including at least a base material,
The base material includes 8.5 to 12.5% by mass of Co, 0.55 to 2.3% by mass of TaC, 0.2 to 0.55% by mass of Cr, and unavoidable impurities. The balance is made of a cemented carbide with WC, or 11.0% by mass of Co, 2.0% by mass of TaC, and inevitable impurities, and the balance is made of a cemented carbide with WC. Producing a raw material powder of the substrate ;
Forming the molded body by molding the raw material powder; and
Maintaining the molded body at 1350-1500 ° C. to produce a sintered body;
Cooling the sintered body to a temperature not lower than the liquid phase solidification temperature and not higher than 1350 ° C. at a cooling rate of 0.5 to 10 ° C./min;
Holding the sintered body at a liquid phase solidification temperature or higher and a temperature of 1350 ° C. or lower for 10 minutes or more;
Cooling the sintered body at a cooling rate of 0.5 to 10 ° C./min to a temperature not lower than 1150 ° C. and not higher than the liquid phase solidification temperature;
Holding the sintered body at a temperature of 1150 ° C. or higher and a liquid phase solidification temperature or lower for 10 minutes or more;
And a step of cooling the sintered body at a cooling rate of 15 ° C./min or higher in this order.